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Multi-agent Based Optimal Sizing of Hybrid Renewable Energy Systems and their Significance in Sustainable Energy Development
Nov 2024
Publication
This paper delves into the enhancement and optimization of on-grid renewable energy systems using a variety of renewable energy sources with a particular focus on large-scale applications designed to meet the energy demand of a certain load. As global concerns surrounding climate change continue to mount the urgency of replacing traditional fossil fuel-based power generation with cleaner more cost-effective and dependable alternatives becomes increasingly apparent. In this context a comprehensive investigation is conducted on grid connected hybrid energy system that combines photovoltaic wind and fuel cell technologies. The study employs three state-of-the-art optimization algorithms namely Walrus Optimization Algorithm (WaOA) Coati Optimization Algorithm (COA) and Osprey Optimization Algorithm (OOA) to determine the optimal system size and energy management strategies all aimed at minimizing the cost of energy (COE) for grid-based electricity. The results of the optimization process are compared with the results obtained from the utilization of the Particle swarm optimization (PSO) and Grey Wolf optimizer (GWO). The findings of this study underscore both the practical feasibility and the critical importance of adopting on-grid renewable energy systems to decrease the dependence on traditional energy sources within the grid. The proposed WaOA succeeded to reach the optimal solution of the optimal design process with a COE of 0.51758129611 $//kwh while keeping the loss of power supply probability (LPSP) the reliability index at 7.303681e-19. The practical recommendations and forwardlooking insights provided within this research hold the potential to foster sustainable development and effectively mitigate carbon emissions in the future.
Hydrogen and the Global Energy Transition—Path to Sustainability and Adoption across All Economic Sectors
Feb 2024
Publication
This perspective article delves into the critical role of hydrogen as a sustainable energy carrier in the context of the ongoing global energy transition. Hydrogen with its potential to decarbonize various sectors has emerged as a key player in achieving decarbonization and energy sustainability goals. This article provides an overview of the current state of hydrogen technology its production methods and its applications across diverse industries. By exploring the challenges and opportunities associated with hydrogen integration we aim to shed light on the pathways toward achieving a sustainable hydrogen economy. Additionally the article underscores the need for collaborative efforts among policymakers industries and researchers to overcome existing hurdles and unlock the full potential of hydrogen in the transition to a low-carbon future. Through a balanced analysis of the present landscape and future prospects this perspective article aims to contribute valuable insights to the discourse surrounding hydrogen’s role in the global energy transition.
Exploring Hydrogen–Diesel Dual Fuel Combustion in a Light-Duty Engine: A Numerical Investigation
Nov 2024
Publication
Dual fuel combustion has gained attention as a cost-effective solution for reducing the pollutant emissions of internal combustion engines. The typical approach is combining a conventional high-reactivity fossil fuel (diesel fuel) with a sustainable low-reactivity fuel such as bio-methane ethanol or green hydrogen. The last one is particularly interesting as in theory it produces only water and NOx when it burns. However integrating hydrogen into stock diesel engines is far from trivial due to a number of theoretical and practical challenges mainly related to the control of combustion at different loads and speeds. The use of 3D-CFD simulation supported by experimental data appears to be the most effective way to address these issues. This study investigates the hydrogen-diesel dual fuel concept implemented with minimum modifications in a light-duty diesel engine (2.8 L 4-cylinder direct injection with common rail) considering two operating points representing typical partial and full load conditions for a light commercial vehicle or an industrial engine. The numerical analysis explores the effects of progressively replacing diesel fuel with hydrogen up to 80% of the total energy input. The goal is to assess how this substitution affects engine performance and combustion characteristics. The results show that a moderate hydrogen substitution improves brake thermal efficiency while higher substitution rates present quite a severe challenge. To address these issues the diesel fuel injection strategy is optimized under dual fuel operation. The research findings are promising but they also indicate that further investigations are needed at high hydrogen substitution rates in order to exploit the potential of the concept.
H2 URESONIC: Design of a Solar-Hydrogen University Renewable Energy System for a New and Innovative Campus
Feb 2024
Publication
The necessity to move to sustainable energy solutions has inspired an investigation of innovative technologies for satisfying educational institutions’ sustainable energy needs. The possibility of a solar-hydrogen storage system and its integration into university energy management is investigated in this article. The study opens by providing context noting the growing relevance of renewable energy in universities as well as the necessity for effective energy storage systems. The goal is to delve into solar-hydrogen technology outlining its components operating mechanism and benefits over typical storage systems. The chapter on Integration Design examines current university energy infrastructure identifies problems and provides ways for integrating solar-hydrogen systems seamlessly. This integration relies heavily on technological and economic considerations such as a cost-benefit analysis and scalability studies. Case studies include real-world examples performance measurements and significant insights learned from successful implementations. The chapter Future Prospects investigates new trends in solar-hydrogen technology as well as the impact of government legislation providing a forward-looking viewpoint for colleges considering adoption. The report concludes with a summary of significant findings emphasizing the benefits of solar-hydrogen integration and making recommendations for future implementations. The limitation of this research is that it only focuses on design and simulation as a phase of preliminary study.
Revolution in Renewables: Integration of Green Hydrogen for a Sustainable Future
Aug 2024
Publication
In recent years global efforts towards a future with sustainable energy have intensified the development of renewable energy sources (RESs) such as offshore wind solar photovoltaics (PVs) hydro and geothermal. Concurrently green hydrogen produced via water electrolysis using these RESs has been recognized as a promising solution to decarbonizing traditionally hard-to-abate sectors. Furthermore hydrogen storage provides a long-duration energy storage approach to managing the intermittency of RESs which ensures a reliable and stable electricity supply and supports electric grid operations with ancillary services like frequency and voltage regulation. Despite significant progress the hydrogen economy remains nascent with ongoing developments and persistent uncertainties in economic technological and regulatory aspects. This paper provides a comprehensive review of the green hydrogen value chain encompassing production transportation logistics storage methodologies and end-use applications while identifying key research gaps. Particular emphasis is placed on the integration of green hydrogen into both grid-connected and islanded systems with a focus on operational strategies to enhance grid resilience and efficiency over both the long and short terms. Moreover this paper draws on global case studies from pioneering green hydrogen projects to inform strategies that can accelerate the adoption and large-scale deployment of green hydrogen technologies across diverse sectors and geographies.
The Effects of Hydrogen Research and Innovation on International Hydrogen Trade
Feb 2024
Publication
Climate change and the pressure to decarbonize as well as energy security concerns have drawn the attention of policymakers and the industry to hydrogen energy. To advance the hydrogen economy at a global scale research and innovation progress is of significant importance among others. However previous studies have provided only limited quantitative evidence of the effects of research and innovation on the formation of a global hydrogen market. Instead they postulate rather than empirically support this relationship. Therefore this study analyzes the effects of research and innovation measured by scientific publications patents and standards on bilateral hydrogen trade flows for 32 countries between 1995 and 2019 in a gravity model of trade using regression analyses and Poisson Pseudo Maximum Likelihood (PPML) estimation. The main results of the PPML estimation show that research and innovation progress is indeed associated with increased trade especially with patenting and (international) standardization enhancing hydrogen export volumes. As policy implications we derive that increased public R&D funding can help increase the competitiveness of hydrogen energy and boost market growth along with infrastructure support and harmonized standards and regulations.
A Critical Analysis of Morocco’s Green Hydrogen Roadmap: A Modelling Approach to Assess Country Readiness from the Energy Trilemma Perspective
Apr 2024
Publication
Morocco despite its heavy reliance on imported fossil fuels which made up 68% of electricity generation in 2020 has recognised its significant renewable energy potential. The Nationally Determined Contribution (NDC) commitment is to reduce emissions by 45.5% from baseline levels with international assistance and abstain from constructing new coal plants. Moreover the Green Hydrogen Roadmap aims to export 10 TWh of green hydrogen by 2030 as well as use it for local electricity storage. This paper critically analyses this Roadmap and Morocco’s readiness to reach its ambitious targets focusing specifically on an energy trilemma perspective and using OSeMOSYS (Open-Source energy Modelling System) for energy modelling. The results reveal that the NDC scenario is only marginally more expensive than the least-cost scenario at around 1.3% (approximately USD 375 million) and facilitates a 23.32% emission reduction by 2050. An important note is the continued reliance on existing coal power plants across all scenarios which challenges both energy security and emissions. The assessment of the Green Hydrogen Scenarios highlights that it could be too costly for the Moroccan government to fund the Green Hydrogen Roadmap at this scale which leads to increased imports of polluting fossil fuels for cost reduction. In fact the emission levels are 39% higher in the green hydrogen exports scenario than in the least-cost scenario. Given these findings it is recommended that the Green Hydrogen Roadmap be re-evaluated with a suggestion for a postponement and reduction in scope.
Profitability of Hydrogen Production: Assessment of Investments in Electrolyser Under Various Market Circumstances
Aug 2024
Publication
Although hydrogen is increasingly seen as a crucial energy carrier in future zero-carbon energy system a profitable exploitation of electrolysers requires still high amounts of subsidies. To analyze the profitability of electrolysers attention has to be paid not only to the costs but also to the interaction between electricity and hydrogen markets. Using a model of internationally integrated electricity and hydrogen markets this paper analyses the profitability of electrolysers plants in various future market circumstances. We find that in particular the future supply of renewable electricity the demand for electricity as well as the prices of natural gas and carbon strongly affect the profitability of electrolysis. In order to make massive investments in electrolysers profitable with significantly lower subsidy requirements the amount of renewable electricity generation needs to grow strongly and the carbon prices should be higher while the demand for electricity should not increase accordingly. This research underscores the critical role of market conditions in shaping the viability of hydrogen electrolysis providing valuable insights for policymakers and stakeholders in the transition to a zero-carbon energy system.
A New Integrated System for Carbon Capture and Clean Hydrogen Production for Sustainable Societal Utilization
Oct 2024
Publication
Hydrogen production and carbon dioxide removal are considered two of the critical pieces to achieve ultimate sustainability target. This study proposes and investigates a new variation of potassium hydroxide thermochemical cycle in order to combine hydrogen production and carbon dioxide removal synergistically. An alkali metal redox thermochemical cycle developed where the potassium hydroxide is considered by using a nonequilibrium reaction. Also the multigeneration options are explored by using two stage steam Rankine cycle multi-effect distillation desalination Li-Br absorption chiller which are integrated with potassium hydroxide thermochemical cycle for hydrogen production carbon capture power generation water desalination and cooling purposes. A comparative assessment under different scenarios is carried out. The energy and exergy efficiencies of the hydrogen production thermochemical cycle are 44.2% and 67.66% when the hydrogen generation reaction is carried out at 180°C and the separation reactor temperature set at 400°C. Among the multigeneration scenarios a trigeneration option of hydrogen power and water indicates the highest energy efficiency as 66.02%.
Geomechanics of Hydrogen Storage in a Depleted Gas Field
Feb 2024
Publication
We perform a simulation study of hydrogen injection in a depleted gas reservoir to assess the geomechanical impact of hydrogen storage relative to other commonly injected gases (methane CO2). A key finding is that the differences in hydrogen density compressibility viscosity and thermal properties compared to the other gases result in significantly less thermal perturbation at reservoir level. The risks of fault reactivation and wellbore fractures due to thermally-induced stress changes are significantly lower when storing hydrogen compared to results observed in CO2 scenarios. This implies that hydrogen injection and production has a much smaller geomechanical footprint with benefits for operational safety. We also find that use of nitrogen cushion gas ensures efficient deliverability and phase separation in the reservoir. However in this study a large fraction of cushion gas was back-produced in each cycle demonstrating the need for further studies of the surface processing requirements and economic implications.
Conceptual Design of an Offshore Hydrogen Platform
Feb 2024
Publication
Offshore green hydrogen emerges as a guiding light in the global pursuit of environmental sustainability and net-zero objectives. The burgeoning expansion of offshore wind power faces significant challenges in grid integration. This avenue towards generating offshore green hydrogen capitalises on its ecological advantages and substantial energy potential to efficiently channel offshore wind power for onshore energy demands. However a substantial research void exists in efficiently integrating offshore wind electricity and green hydrogen. Innovative designs of offshore hydrogen platforms present a promising solution to bridge the gap between offshore wind and hydrogen integration. Surprisingly there is a lack of commercially established offshore platforms dedicated to the hydrogen industry. However the wealth of knowledge from oil and gas platforms contributes valuable insights to hydrogen platform design. Diverging from the conventional decentralised hydrogen units catering to individual turbines this study firstly introduces a pioneering centralised Offshore Green Hydrogen Platform (OGHP) which seamlessly integrates modular production storage and offloading modulars. The modular design of facilitates scalability as wind capacity increases. Through a detailed case study centred around a 100-Megawatt floating wind farm the design process of offshore green hydrogen modulars and its floating sub-structure is elucidated. Stability analysis and hydrodynamic analysis are performed to ensure the safety of the OGHP under the operation conditions. The case study will enhance our understanding OGHP and its modularised components. The conceptual design of modular OGHP offers an alternative solution to ‘‘Power-to-X’’ for offshore renewable energy sector.
SSEXHY Experimental Results on Pressure Dynamics from Head-on Reflections of Hydrogen Flames
Sep 2023
Publication
In the past few years CEA has been fully involved at both experimental and modeling levels in projects related to hydrogen safety in nuclear and chemical industries and has carried out a test program using the experimental bench SSEXHY (Structure Submitted to an EXplosion of HYdrogen) in order to build a database of the deformations of simple structures following an internal hydrogen explosion. Different propagation regimes of explosions were studied varying from detonations to slow deflagrations.<br/>During the experimental campaign it was found that high-speed deflagrations corresponding to relatively poor hydrogen-air mixtures resulted in higher specimen deformation compared to those related to detonations of nearly stoichiometric mixtures. This paper explains this counter-intuitive result from qualitative and quantitative points of view. It is shown that the overpressure and impulse from head-on reflections of hydrogen flames corresponding to poor mixtures of specific concentrations could have very high values at the tube end.
Simulations of Blast Wave and Fireball Occurring due to Rupture oj High-Pressure Hydrogen Tank
Jun 2017
Publication
In the present study pilot simulations of the phenomena of blast wave and fireball generated by the rupture of a high-pressure (35 MPa) hydrogen tank (volume 72 L) due to fire were carried out. The computational fluid dynamics (CFD) model includes the realizable k-ε model for turbulence and the eddy dissipation model coupled with the one-step chemical reaction mechanism for combustion. The simulation results were compared with experimental data on a stand-alone hydrogen tank rupture in a bonfire test. The simulations provided insights into the interaction between the blast wave propagation and combustion process. The simulated blast wave decay is approximately identical to the experimental data concerning pressure at various distances. Fireball is first ignited at the ground level which is considered to be due to stagnation flow conditions. Subsequently the flame propagates toward the interface between hydrogen and air.
A Comprehensive Review on the Power Supply System of Hydrogen Production Electrolyzers for Future Integrated Energy Systems
Feb 2024
Publication
Hydrogen energy is regarded as an ideal solution for addressing climate change issues and an indispensable part of future integrated energy systems. The most environmentally friendly hydrogen production method remains water electrolysis where the electrolyzer constructs the physical interface between electrical energy and hydrogen energy. However few articles have reviewed the electrolyzer from the perspective of power supply topology and control. This review is the first to discuss the positioning of the electrolyzer power supply in the future integrated energy system. The electrolyzer is reviewed from the perspective of the electrolysis method the market and the electrical interface modelling reflecting the requirement of the electrolyzer for power supply. Various electrolyzer power supply topologies are studied and reviewed. Although the most widely used topology in the current hydrogen production industry is still single-stage AC/DC the interleaved parallel LLC topology constructed by wideband gap power semiconductors and controlled by the zero-voltage switching algorithm has broad application prospects because of its advantages of high power density high efficiency fault tolerance and low current ripple. Taking into account the development trend of the EL power supply a hierarchical control framework is proposed as it can manage the operation performance of the power supply itself the electrolyzer the hydrogen energy domain and the entire integrated energy system.
Modelling of a "Hydrogen Valley" to Investigate the Impact of a Regional Pipeline for Hydrogen Supply
Jul 2024
Publication
Introduction: The transition towards electrolysis-produced hydrogen in refineries and chemical industries is expected to have a potent impact on the local energy system of which these industries are part. In this study three urban areas with hydrogen-intense industries are studied regarding how the energy system configuration is affected if the expected future hydrogen demand is met in each node individually as compared to forming a “Hydrogen Valley” in which a pipeline can be used to trade hydrogen between the nodes.<br/>Method: A technoeconomic mixed-integer linear optimization model is used to study the investments in and dispatch of the included technologies with an hourly time resolution while minimizing the total system cost. Four cases are investigated based on the availability of offshore wind power and the possibility to invest in a pipeline.<br/>Results: The results show that investments in a pipeline reduces by 4%–7% the total system cost of meeting the demands for electricity heating and hydrogen in the cases investigated. Furthermore investments in a pipeline result in greater utilization of local variable renewable electricity resources as compared to the cases without the possibility to invest in a pipeline.<br/>Discussion: The different characteristics of the local energy systems of the three nodes in local availability of variable renewable electricity grid capacity and available storage options compared to local demands of electricity heating and hydrogen are found to be the driving forces for forming a Hydrogen Valley.
Artificial Intelligence for Hydrogen-Enabled Integrated Energy Systems: A Systematic Review
Aug 2024
Publication
Hydrogen-enabled Integrated Energy Systems (H-IES) stand out as a promising solution with the potential to replace current non-renewable energy systems. However their development faces challenges and has yet to achieve widespread adoption. These main challenges include the complexity of demand and supply balancing dynamic consumer demand and challenges in integrating and utilising hydrogen. Typical energy management strategies within the energy domain rely heavily on accurate models from domain experts or conventional approaches such as simulation and optimisation approaches which cannot be satisfied in the real-world operation of H-IES. Artificial Intelligence (AI) or Advanced Data Analytics (ADA) especially Machine Learning (ML) has the ability to overcome these challenges. ADA is extensively used across several industries however further investigation into the incorporation of ADA and hydrogen for the purpose of enabling H-IES needs to be investigated. This paper presents a systematic literature review to study the research gaps research directions and benefits of ADA as well as the role of hydrogen in H-IES.
Will Hydrogen and Synthetic Fuels Energize our Future? Their Role in Europe's Climate-neutral Energy System and Power System Dynamics
Aug 2024
Publication
This study evaluates the technoeconomic impacts of direct and indirect electrification on the EU's net-zero emissions target by 2050. By linking the JRC-EU-TIMES long-term energy system model with PLEXOS hourly resolution power system model this research offers a detailed analysis of the interactions between electricity hydrogen and synthetic fuel demand production technologies and their effects on the power sector. It highlights the importance of high temporal resolution power system analysis to capture the synergistic effects of these components often overlooked in isolated studies. Results indicate that direct electrification increases significantly and unimpacted by biomass CCS and nuclear energy assumptions. However indirect electrification in the form of hydrogen varies significantly between 1400 and 2200 TWhH2 by 2050. Synthetic fuels are essential for sector coupling making up 6–12% of total energy consumption by 2050 with the power sector supplying most hydrogen and CO2 for their production. Varying levels of indirect electrification impact electrolysers renewable energy and firm capacities. Higher indirect electrification increases electrolyser capacity factors by 8% leading to more renewable energy curtailment but improves system reliability by reducing 11 TWh unserved energy and increasing flexibility options. These insights inform EU energy policies stressing the need for a balanced approach to electrification biomass use and CCS to achieve a sustainable and reliable net-zero energy system by 2050. We also explore limitations and sensitivities.
Experimental Study on the Effect of the Ignition Location on Vented Deflagration of Hydrogen-air Mixtures in Enclosure
Sep 2023
Publication
No countermeasures exist for accidents that might occur in hydrogen-based facilities (leaks fires explosions etc.). In South Korea discussions are underway regarding measures to ensure safety from such accidents such as the construction of underground hydrogen storage tank facilities. However explosion vents with a minimum ventilation area are required in such facilities to minimize damage to buildings and other structures due to accidental explosions. These explosion vents allow the generated overpressure and flames to be safely dispersed outside; however a safe separation distance must be secured to minimize damage to humans. This study aimed to determine the safe separation distance to minimize human damage after analyzing the dispersed overpressure and flame behavior following a vent explosion. Explosion experiments were conducted to investigate the influence of the ignition source location on internal and external overpressure and external flame behavior using a cuboid concrete structure with a volume of 20.33 m3 filled with a hydrogen-air mixture (29.0 vol.%). The impact on overpressure and flame was increased with the increasing distance of the ignition source from the vent. Importantly depending on the ignition location the incident pressure was up to 24.4 times higher while the reflected pressure was 8.7 times higher. Additionally a maximum external overpressure of 30.01 kPa was measured at a distance of 2.4 m from the vent predicting damage to humans at the “Injury” level (1 % fatality probability). Whereas no significant damage would occur at a distance of 7.4 m or more from the vent.
Study on the Application of a Multi-Energy Complementary Distributed Energy System Integrating Waste Heat and Surplus Electricity for Hydrogen Production
Feb 2024
Publication
To improve the recovery of waste heat and avoid the problem of abandoning wind and solar energy a multi-energy complementary distributed energy system (MECDES) is proposed integrating waste heat and surplus electricity for hydrogen storage. The system comprises a combined cooling heating and power (CCHP) system with a gas engine (GE) solar and wind power generation and miniaturized natural gas hydrogen production equipment (MNGHPE). In this novel system the GE’s waste heat is recycled as water vapor for hydrogen production in the waste heat boiler while surplus electricity from renewable sources powers the MNGHPE. A mathematical model was developed to simulate hydrogen production in three building types: offices hotels and hospitals. Simulation results demonstrate the system’s ability to store waste heat and surplus electricity as hydrogen thereby providing economic benefit energy savings and carbon reduction. Compared with traditional energy supply methods the integrated system achieves maximum energy savings and carbon emission reduction in office buildings with an annual primary energy reduction rate of 49.42–85.10% and an annual carbon emission reduction rate of 34.88–47.00%. The hydrogen production’s profit rate is approximately 70%. If the produced hydrogen is supplied to building through a hydrogen fuel cell the primary energy reduction rate is further decreased by 2.86–3.04% and the carbon emission reduction rate is further decreased by 12.67–14.26%. This research solves the problem of waste heat and surplus energy in MECDESs by the method of hydrogen storage and system integration. The economic benefits energy savings and carbon reduction effects of different building types and different energy allocation scenarios were compared as well as the profitability of hydrogen production and the factors affecting it. This has a positive technical guidance role for the practical application of MECDESs.
Green Hydrogen Production Plants: A Techno-economic Review
Aug 2024
Publication
Green hydrogen stands as a promising clean energy carrier with potential net-zero greenhouse gas emissions. However different system-level configurations for green hydrogen production yield different levels of efficiency cost and maturity necessitating a comprehensive assessment. This review evaluates the components of hydrogen production plants from technical and economic perspectives. The study examines six renewable energy sources—solar photovoltaics solar thermal wind biomass hydro and geothermal—alongside three types of electrolyzers (alkaline proton exchange membrane and solid oxide electrolyzer cells) and five hydrogen storage methods (compressed hydrogen liquid hydrogen metal hydrides ammonia and liquid organic hydrogen carriers). A comprehensive assessment of 90 potential system configurations is conducted across five key performance indicators: the overall system cost efficiency emissions production scale and technological maturity. The most cost-effective configurations involve solar photovoltaics or wind turbines combined with alkaline electrolyzers and compressed hydrogen storage. For enhanced system efficiency geothermal sources or biomass paired with solid oxide electrolyzer cells utilizing waste heat show significant promise. The top technologically mature systems feature combinations of solar photovoltaics wind turbines geothermal or hydroelectric power with alkaline electrolyzers using compressed hydrogen or ammonia storage. The highest hydrogen production scales are observed in systems with solar PV wind or hydro power paired with alkaline or PEM electrolyzers and ammonia storage. Configurations using hydro geothermal wind or solar thermal energy sources paired with alkaline electrolyzers and compressed hydrogen or liquid organic hydrogen carriers yield the lowest life cycle GHG emissions. These insights provide valuable decision-making tools for researchers business developers and policymakers guiding the optimization of system efficiency and the reduction of system costs.
Preliminary Analysis of Refilling Cold-adsorbed Hydrogen Tanks
Sep 2023
Publication
The effective storage of hydrogen is a critical challenge that needs to be overcome for it to become a widely used and clean energy source. Various methods exist for storing hydrogen including compression at high pressures liquefaction through extreme cooling (i.e. -253 °C) and storage with chemical compounds. Each method has its own advantages and disadvantages. MAST3RBoost (Maturing the Production Standards of Ultraporous Structures for High Density Hydrogen Storage Bank Operating on Swinging Temperatures and Low Compression) is a European funded Project aiming to establish a reliable benchmark for cold-adsorbed H2 storage (CAH2) at low compression levels (100 bar or below). This is achieved through the development of advanced ultraporous materials suitable for mobility applications such as hydrogen-powered vehicles used in road railway air and water transportation. The MAST3RBoost Project utilizes cutting-edge materials including Activated Carbons (ACs) and high-density MOFs (Metalorganic Frameworks) which are enhanced by Machine Learning techniques. By harnessing these materials the project seeks to create a groundbreaking path towards meeting industry goals. The project aims to develop the world's first adsorption-based demonstrator at a significant kg-scale. To support the design of the storage tank the project employs Computational Fluid Dynamics (CFD) software which allows for numerical investigations. In this paper a preliminary analysis of the tank refilling process is presented with a focus on the impact of the effect of the tank and hydrogen temperatures on quantity of hydrogen adsorbed.
Hydrogen Production from Wave Power Farms to Refuel Hydrogen-Powered Ships in the Mediterranean Sea
Aug 2024
Publication
The maritime industry is a major source of greenhouse gas (GHG) emissions largely due to ships running on fossil fuels. Transitioning to hydrogen-powered marine transportation in the Mediterranean Sea requires the development of a network of hydrogen refueling stations across the region to ensure a steady supply of green hydrogen. This paper explores the technoeconomic viability of harnessing wave energy from the Mediterranean Sea to produce green hydrogen for hydrogenpowered ships. Four promising island locations—near Sardegna Galite Western Crete and Eastern Crete—were selected based on their favorable wave potential for green hydrogen production. A thorough analysis of the costs associated with wave power facilities and hydrogen production was conducted to accurately model economic viability. The techno-economic results suggest that with anticipated cost reductions in wave energy converters the levelized cost of hydrogen could decrease to as low as 3.6 €/kg 4.3 €/kg 5.5 €/kg and 3.9 €/kg for Sardegna Galite Western Crete and Eastern Crete respectively. Furthermore the study estimates that in order for the hydrogen-fueled ships to compete effectively with their oil-fueled counterparts the levelized cost of hydrogen must drop below 3.5 €/kg. Thus despite the competitive costs further measures are necessary to make hydrogen-fueled ships a viable alternative to conventional diesel-fueled ships.
Techno-Economic Analysis of Cement Decarbonization Techniques: Oxygen Enrichment vs. Hydrogen Fuel
Feb 2024
Publication
The Paris Agreement aims to limit global warming and one of the most polluting sectors is heavy industry where cement production is a significant contributor. This work briefly explores some alternatives recycling reducing clinker content waste heat recovery and carbon capture discussing their advantages and drawbacks. Then it examines the economic viability and benefits of increasing oxygen concentration in the primary burning air from 21 to 27 vol.% which could improve clinker production by 7% and the production of hydrogen through PEM electrolysis to make up 5% of the fuel thermal fraction considering both in a cement plant producing 3000 tons of clinker per day. This analysis used reference values from Secil an international company for cement and building materials to determine the required scale of the oxygen and hydrogen production respectively and calculate the CAPEX of each approach. It is concluded that oxygen enrichment can provide substantial fuel savings for a relatively low cost despite a possible significant increase in NOx emissions. However hydrogen production at this scale is not currently economically viable.
A Multi-agent Optimal Operation Methodology of Electric, Thermal, and Hydrogen Integrated Energy System based on ADMM Algorithm
Aug 2024
Publication
This article presents a study on the distributed optimization operation method for micro-energy grid clusters within an electric thermal and hydrogen integrated energy system. The research focuses on precisely modeling the Power-toHydrogen (P2H) conversion process in electrolytic cells by considering their startup characteristics. An optimization operation model is established with each micro-energy grid as the principal entity to cater to their individual interests and demands. The Alternating Direction Method of Multipliers (ADMM) algorithm is adopted for distributed solution. Case studies demonstrate that the connection topology between micro-energy grids significantly impacts the total operating cost and the effectiveness of the ADMM algorithm is validated through a comparison with centralized optimization approaches.
Modelling the Innovation-decision Process for Hydrogen Homes: An Integrated Model of Consumer Acceptance and Adoption Intention
Nov 2024
Publication
As the global energy transition progresses a range of drivers and barriers will continue to shape consumer attitudes and behavioural intentions towards emerging low-carbon technologies. The innovation-decision process for technologies composing the residential sector such as hydrogen-fuelled heating and cooking appliances is inherently governed by the complex interplay between perceptual cognitive and emotional factors. In response this study responds to the call for an integrated research perspective to advance theoretical and empirical insights on consumer engagement in the domestic hydrogen transition. Drawing on online survey data collected in the United Kingdom where a policy decision on ‘hydrogen homes’ is set for 2026 this study systematically explores whether an integrated modelling approach supports higher levels of explanatory and predictive power. Leveraging the foundations of the unified theory of domestic hydrogen acceptance the analysis suggests that production perceptions public trust perceived relative advantage safety perceptions knowledge and awareness and positive emotions will shape consumer support for hydrogen homes. Conversely perceived disruptive impacts perceived socio-economic costs financial perceptions and negative emotions may impede the domestic hydrogen transition. Consumer acceptance stands to significantly shape deployment prospects for hydrogen boilers and hobs which are perceived to be somewhat advantageous to natural gas appliances from a technological and safety perspective. The study attests to the predictive benefits of adopting an integrated theoretical perspective when modelling the early stages of the innovation-decision process while acknowledging opportunities for leveraging innovative research approaches in the future. As national hydrogen economies gain traction adopting a neuroscience-based approach may help deepen scientific understanding regarding the neural psychological and emotional signatures shaping consumer perspectives towards hydrogen homes.
The Recent Progresses of Electrodes and Electrolysers for Seawater Electrolysis
Jan 2024
Publication
The utilization of renewable energy for hydrogen production presents a promising pathway towards achieving carbon neutrality in energy consumption. Water electrolysis utilizing pure water has proven to be a robust technology for clean hydrogen production. Recently seawater electrolysis has emerged as an attractive alternative due to the limitations of deep-sea regions imposed by the transmission capacity of long-distance undersea cables. However seawater electrolysis faces several challenges including the slow kinetics of the oxygen evolution reaction (OER) the competing chlorine evolution reaction (CER) processes electrode degradation caused by chloride ions and the formation of precipitates on the cathode. The electrode and catalyst materials are corroded by the Cl− under long-term operations. Numerous efforts have been made to address these issues arising from impurities in the seawater. This review focuses on recent progress in developing high-performance electrodes and electrolyser designs for efficient seawater electrolysis. Its aim is to provide a systematic and insightful introduction and discussion on seawater electrolysers and electrodes with the hope of promoting the utilization of offshore renewable energy sources through seawater electrolysis.
A Comprehensive Review on the Hydrogen–Natural Gas–Diesel Tri-Fuel Engine Exhaust Emissions
Aug 2024
Publication
Natural gas (NG) is favored for transportation due to its availability and lower CO2 emissions than fossil fuels despite drawbacks like poor lean combustion ability and slow burning. According to a few recent studies using hydrogen (H2 ) alongside NG and diesel in Tri-fuel mode addresses these drawbacks while enhancing efficiency and reducing emissions making it a promising option for diesel engines. Due to the importance and novelty of this the continuation of ongoing research and insufficient literature studies on HNG–diesel engine emissions that are considered helpful to researchers this research has been conducted. This review summarizes the recent research on the HNG–diesel Tri-fuel engines utilizing hydrogen-enriched natural gas (HNG). The research methodology involved summarizing the effect of engine design operating conditions fuel mixing ratios and supplying techniques on the CO CO2 NOx and HC emissions separately. Previous studies show that using natural gas with diesel increases CO and HC emissions while decreasing NOx and CO2 compared to pure diesel. However using hydrogen with diesel reduces CO CO2 and HC emissions but increases NOx. On the other hand HNG–diesel fuel mode effectively mitigates the disadvantages of using these fuels separately resulting in decreased emissions of CO CO2 HC and NOx. The inclusion of hydrogen improves combustion efficiency reduces ignition delay and enhances heat release and in-cylinder pressure. Additionally operational parameters such as engine power speed load air–fuel ratio compression ratio and injection parameters directly affect emissions in HNG–diesel Tri-fuel engines. Overall the Tri-fuel approach offers promising emissions benefits compared to using natural gas or hydrogen separately as dual-fuels.
Research on the Dynamic Energy Conversion and Transmission Model of Renewable Energy DC Off-grid Hydrogen System
Sep 2024
Publication
The dynamic response characteristics between the multiple energy flows of electricity-hydrogen-heat in the renewable energy DC off-grid hydrogen production system are highly coupled and nonlinear which leads to the complexity of its energy conversion and transmission law. This study proposes a model to describe the dynamic nonlinear energy conversion and transmission laws specific to such systems. The model develops a nonlinear admittance framework and a conversion characteristic matrix for multi-heterogeneous energy flow subsystems based on the operational characteristics of each subsystem within the DC off-grid hydrogen production system. Building upon this foundation an energy hub model for the hydrogen production system is established yielding the electrical thermal and hydrogen energy outputs along with their respective conversion efficiencies for each subsystem. By discretizing time the energy flow at each time node within the hydrogen production system is computed revealing the system’s dynamic energy transfer patterns. Experiments were conducted using measured wind speed and irradiance data from a specific location in eastern China. Results from selected typical days were analyzed and discussed revealing that subsystem characteristics exhibit nonlinear variation patterns. This highlights the limitations of traditional models in accurately capturing these dynamics. Finally a simulation platform incorporating practical control methods was constructed to validate the model’s accuracy. Validation results demonstrate that the model possesses high accuracy providing a solid theoretical foundation for further in-depth analysis of DC off-grid hydrogen production systems.
A Perspective on Emerging Energy Policy and Economic Research Agenda for Enabling Aviation Climate Action
Sep 2024
Publication
Due to the aviation energy sector's increasing contribution to climate change and the impact of climate change on the aviation sector determining key energy policy and economic research priorities for enabling an effective and equitable aviation climate action is becoming an increasingly important topic. In this perspective we address this research need using a four-pronged methodology. It includes (i) identifying topical matters highlighted in the media (news); (ii) formulating novel and feasible policy and economic research challenges that pertain to these contemporary issues; (iii) cross-referencing the proposed research challenges with academic literature to confirm their novelty and refining them as necessary; and (iv) validating the importance novelty and feasibility of these research challenges through consultation with a diverse group of aviation experts in fuel policy technology and infrastructure fields. Our results highlight twelve main themes. Among these the top emerging policy and economic research challenges as prioritized by expert input are – (i) frameworks for equitable responsibility allocation between developed and developing country airlines for future emissions; (ii) cost analysis of airlines' net-zero by 2050 commitments; (iii) effectiveness and opportunity cost of airlines investing in offsetting relative to reduction measures; (iv) EU aviation policies' historical and potential effects on airfares demand emissions EU air carriers' competitiveness passenger traffic through EU hubs regional economies and social climate funds' ability to mitigate distributional effects of EU aviation policies. These identified priorities can steer both industry and academic research toward creating practical recommendations for policymakers and industry participants. When it comes to future research the ever-changing nature of the challenges in achieving aviation climate action means that our findings might need regular updates.
In-situ Direct Seawater Electrolysis Using Floating Platform in Ocean with Uncontrollable Wave Motion
Jun 2024
Publication
Direct hydrogen production from inexhaustible seawater using abundant offshore wind power offers a promising pathway for achieving a sustainable energy industry and fuel economy. Various direct seawater electrolysis methods have been demonstrated to be effective at the laboratory scale. However larger-scale in situ demonstrations that are completely free of corrosion and side reactions in fluctuating oceans are lacking. Here fluctuating conditions of the ocean were considered for the first time and seawater electrolysis in wave motion environment was achieved. We present the successful scaling of a floating seawater electrolysis system that employed wind power in Xinghua Bay and the integration of a 1.2 Nm3 h−1 -scale pilot system. Stable electrolysis operation was achieved for over 240 h with an electrolytic energy consumption of 5 kWh Nm−3 H2 and a high purity (>99.9%) of hydrogen under fluctuating ocean conditions (0~0.9 m wave height 0~15 m s−1 wind speed) which is comparable to that during onshore water electrolysis. The concentration of impurity ions in the electrolyte was low and stable over a long period of time under complex and changing scenarios. We identified the technological challenges and performances of the key system components and examined the future outlook for this emerging technology.
Optimization of Baseload Electricity and Hydrogen Services by Renewables for a Nuclear-sized District in South Italy
Nov 2024
Publication
We present an optimization model of an energy district in South Italy that supplies baseload electricity and hydrogen services. The district is sized such that a nuclear reactor could provide these services. We define scenarios for 2050 to explore the system effects of discount rate sensitivity vetoes on technologies and cost uncertainties. We address the following issues relevant to decarbonization in South Italy: land-based wind and solar vs. exclusive solar rooftop extra cost of a veto on nuclear conservative assumptions on future storage technology and the role of pumped hydro storage lack of low-cost geological storage of hydrogen and the industrial competitiveness of this carrier and the methanation synergy with the agroforestry sector. Our results quantify the high system cost of vetoes on land-based wind and solar. Nuclear may enter the optimal mix only with a veto against onshore wind and a hypothesis of equal project risk hence an equal discount rate with renewables. Scenarios with land-based wind and solar obtain low-cost hydrogen and thus allow industrial uses for this carrier. The methanation synergy with the agroforestry sector does not offer a system cost advantage but improves the district’s configuration. The extra cost of full decarbonization relative to unregulated fossil gas is small with land-based wind and solar and significant with vetoes to these technologies.
What will be the Hydrogen and Power Demands of the Process Industry in a Climate-neutral Germany?
Apr 2024
Publication
The defossilization of industry has far-reaching implications regarding the future demand for hydrogen and other forms of energy. This paper presents and applies a fundamental bottom-up model that relies on techno-economic data of industrial production processes. Its aim is to identify across a range of scenarios the most cost-effective low-carbon options considering a variety of production systems. Subsequently it derives the hydrogen and electricity demand that would result from the implementation of these least-cost low-carbon options in process industries in Germany. Aligning with the German government's target year for achieving climate neutrality this study’s reference year is 2045. The primary contribution lies in analyzing which hydrogen-based and direct electrification solutions would be cost-effective for a range of energy price levels under climate-neutral industrial production and what the resulting hydrogen and electricity demand would be. To this end the methodology of this paper comprises the following steps: selection of the relevant industries (I) definition of conventional reference production systems and their low-carbon options (II) investigation and processing of the techno-economic data of the standardized production systems (III) establishment of a scenario framework (IV) determination of the least-cost low-carbon solution of a conventional reference production system under the scenario assumptions made (V) and estimation of the resulting hydrogen and electricity demand (VI). According to the results the expected industrial hydrogen consumption in 2045 ranges from 255 TWh for higher hydrogen prices in or above the range of onshore wind-based green hydrogen supply costs to up to 542 TWh for very low hydrogen prices corresponding to typical blue hydrogen production costs. Meanwhile the direct electricity consumption of the process industries in the results ranges from 122 TWh for these rather low hydrogen prices to 368 TWh for the higher hydrogen prices in the region of or above the hydrogen supply costs from the electrolysis of energy from an onshore wind farm. Most of the break-even hydrogen prices that are relevant to the choice of low-carbon options are in the range of the benchmark purchase costs for blue hydrogen and green hydrogen produced from offshore wind power which span between €40 per MWh and €97 per MWh.
Assessment of the Economic Viability, Environmental, and Social Impacts of Green Hydrogen Production: An Algerian Case Study
Aug 2024
Publication
The impacts of climate change are real and in many parts of the world testify to its harsh reality including rampant extreme weather events droughts heat wildfires and flooding which have recorded in places which have not experienced them in recent memory. In the quest to avert such events there is a growing awareness and demand for sustainable processes and operations. Today sustainability encompasses a balance between ecological footprint and human development index taking into consideration economics the green environment safety quality ethics diversity and inclusion (D&I) and communities. This article presents some steps that have been taken by Algeria to balance energetic autonomy and sustainable development and a case study on green hydrogen production employing membrane processes. Algeria’s objective to join the global fight against climate change is to develop its green hydrogen base. Given its resources including available solar and wind power seawater desalination plants building capacity and its favorable location it is developing its green hydrogen economy to supply hydrogen especially to Europe. This presents an opportunity for other developing nations especially in Africa to gain from this experience.
Techno-economic Assessment of Hydrogen-based Energy Storage Systems in Determining the Optimal Configuration of the Nuclear-renewable Hybrid Energy System
Apr 2024
Publication
Population growth and economic development have significantly increased global energy demand. Hence it has raised concerns about the increase in the consumption of fossil fuels and climate change. The present work introduced a new approach to using carbon-free energy sources such as nuclear and renewable to meet energy demand. The idea of using the Nuclear-Renewable Hybrid Energy System (N-R HES) is suggested as a leading solution that couples a nuclear power plant with renewable energy and hydrogen-based storage systems. For this purpose using a meta-heuristic method based on Newton’s laws the configuration of the N-R HES is optimized from an economic and reliability point of view. The optimal system is selected from among six cases with different subsystems such as wind turbine photovoltaic panel nuclear reactor electrolysis fuel cell and hydrogen storage tank. Furthermore the performance of hydrogen-based energy storage systems such as hightemperature electrolysis (HTE) and low-temperature electrolysis (LTE) is evaluated from technical and economic aspects. The results of this work showed that using nuclear energy to supply the base load increases the reliability of the system and reduces the loss of power supply probability to zero. More than 70 % of the power is produced by nuclear reactors which includes more than 80 % of the system costs. The key findings showed that despite HTE’s higher efficiency using LTE as a storage system in N-R HES is more cost-effective. Finally due to recent developments and the safer design of nuclear reactors they can play an important role in combination with renewable energies to support carbon-free energy sectors especially in remote areas for decades to come.
A Complete Assessment of the Emission Performance of an SI Engine Fueled with Methanol, Methane and Hydrogen
Feb 2024
Publication
This study explores the potentiality of low/zero carbon fuels such as methanol methane and hydrogen for motor applications to pursue the goal of energy security and environmental sustainability. An experimental investigation was performed on a spark ignition engine equipped with both a port fuel and a direct injection system. Liquid fuels were injected into the intake manifold to benefit from a homogeneous charge formation. Gaseous fuels were injected in direct mode to enhance the efficiency and prevent abnormal combustion. Tests were realized at a fixed indicated mean effective pressure and at three different engine speeds. The experimental results highlighted the reduction of CO and CO2 emissions for the alternative fuels to an extent depending on their properties. Methanol exhibited high THC and low NOx emissions compared to gasoline. Methane and even more so hydrogen allowed for a reduction in THC emissions. With regard to the impact of gaseous fuels on the NOx emissions this was strongly related to the operating conditions. A surprising result concerns the particle emissions that were affected not only by the fuel characteristics and the engine test point but also by the lubricating oil. The oil contribution was particularly evident for hydrogen fuel which showed high particle emissions although they did not contain carbon atoms.
Utilization of Hydrogen Fuel in Reheating Furnace and its Effect on Oxide Scale Formation of Low-carbon Steels
Nov 2024
Publication
The transition from fossil-based fuel to hydrogen combustion in steel reheating furnaces is a possible way to decrease the process-originated CO2 emissions significantly. This potential change alters the furnace gas atmo sphere’s composition impacting the oxide scale formation of the slab surface. Dynamic heating tests are per formed for three low-carbon steels using different simulated combustion atmospheres including natural gas coke oven gas and hydrogen combustion in air and hydrogen combustion in oxygen. Significant differences are found in the oxidation behavior of steel grades in the simulated hydrogen reheating scenario. A steel grade with low Mn content only has an 18% increase in oxidation between methane-air to hydrogen-oxygen methods while it is 41% for a high Mn and Si steel grade and 65% for a high-Mn steel grade. Thus in terms of material loss increase by oxidation the transition of the heating method causes the least problems for the low-Mn steel grade.
Decarbonising International Shipping - A Life Cycle Perspective on Alternative Fuel Options
Nov 2023
Publication
This study aimed to compare hydrogen ammonia methanol and waste-derived biofuels as shipping fuels using life cycle assessment to establish what potential they have to contribute to the shipping industry’s 100% greenhouse gas emission reduction target. A novel approach was taken where the greenhouse gas emissions associated with one year of global shipping fleet operations was used as a common unit for comparison therefore allowing the potential life cycle greenhouse gas emission reduction from each fuel option to be compared relative to Paris Agreement compliant targets for international shipping. The analysis uses life cycle assessment from resource extraction to use within ships with all GHGs evaluated for a 100-year time horizon (GWP100). Green hydrogen waste-derived biodiesel and bio-methanol are found to have the best decarbonisation po tential with potential emission reductions of 74–81% 87% and 85–94% compared to heavy fuel oil; however some barriers to shipping’s decarbonisation progress are identified. None of the alternative fuels considered are currently produced at a large enough scale to meet shipping’s current energy demand and uptake of alternative fuel vessels is too slow considering the scale of the challenge at hand. The decarbonisation potential from alternative fuels alone is also found to be insufficient as no fuel option can offer the 100% emission reduction required by the sector by 2050. The study also uncovers several sensitives within the life cycles of the fuel options analysed that have received limited attention in previous life cycle investigations into alternative shipping fuels. First the choice of allocation method can potentially double the life cycle greenhouse gas emissions of e-methanol due to the carbon ac counting challenges of using waste carbon dioxide streams during fuel production. This leads to concerns related to the true impact of using carbon dioxide captured from fossil-fuelled processes to produce a combustible product due to the resultant high downstream emissions. Second nitrous oxide emissions from ammonia combustion are found to be highly sensitive due to high greenhouse gas potency potentially offsetting any greenhouse reduction potential compared to heavy fuel oil. Further uncertainties are highlighted due to limited available data on the rate of nitrous oxide production from ammonia engines. The study therefore highlights an urgent need for the shipping sector to consider these factors when investing in new ammonia and methanol engines; failing to do so risks jeopardizing the sector’s progress towards decarbonisation. Finally whilst alternative fuels can offer good decarbonisation potential (particularly waste derived biomethanol and bio-diesel and green hydrogen) this cannot be achieved without accelerated investment in new and retrofit vessels and new fuel supply chains: the research concludes that existing pipeline of vessel orders and fuel production facilities is insufficient. Furthermore there is a need to integrate alternative fuel uptake with other decarbonisation strategies such as slow steaming and wind propulsion.
Marine Renewable-Driven Green Hydrogen Production Toward a Sustainable Solution and a Low-carbon Future in Morocco
May 2024
Publication
Oceanic energy sources notably offshore wind and wave power present a significant opportunity to generate green hydrogen through water electrolysis. This approach allows for offshore hydrogen production which can be efficiently transported through existing pipelines and stored in various forms offering a versatile solution to tackle the intermittency of renewable energy sources and potentially revolutionize the entire electrical grid infrastructure. This research focusses on assessing the technical and economic feasibility of this method in six strategic coastal regions in Morocco: Laayoune Agadir Essaouira Eljadida Casablanca and Larache. Our proposed system integrates offshore wind turbines oscillating water column wave energy converters and PEM electrolyzers to meet energy demands while aligning with global sustainability objectives. Significant electricity production estimates are observed across these regions ranging from 14 MW to 20 MW. Additionally encouraging annual estimates of hydrogen production varying between 20 and 40 tonnes for specific locations showcase the potential of this approach. The system’s performance demonstrates promising efficiency rates ranging from 13% to 18% while maintaining competitive production costs. These findings underscore the ability of oceanic energy-driven green hydrogen to diversify Morocco’s energy portfolio bolster water resilience and foster sustainable development. Ultimately this research lays the groundwork for comprehensive energy policies and substantial infrastructure investments positioning Morocco on a trajectory towards a decarbonized future powered by innovative and clean technologies.
Utilization of Hydrogen and Methane as Energy Carriers with Exhaust Gas Recirculation for Sustainable Diesel Engines
May 2024
Publication
Hydrogen and methane as secondary fuels in diesel engines can be promising solutions to meet energy demand. The current study investigated the effect of the specialty gases of different compositions on diesel engine performance and exhaust gases. Four gases with various compositions of exhaust gas recirculation (Carbon monoxide Carbon dioxide and Nitrogen) and fuels (Hydrogen and Methane) were used at various mass flow rates of 10 20 and 25 LPM (liter per minute) and various engine speeds of 2000 2500 3000 and 3500 rpm (revolutions per minute). The procured results revealed that adding specialty gases improved brake thermal efficiency and power. Similarly the brake-specific fuel consumption was also massively retarded compared to diesel due to the influence of the hydrogen and methane composition. However the fuel with the higher nitrogen reported less BTE (brake thermal efficiency) and comparatively higher exhaust gas temperature owing to the higher presence of nitrogen in their composition. Regarding emissions including exhaust gas recirculation dropped the formation of pollutants efficiently compared to diesel. Among various fuels Case 1 (30 % H2 5 % CH4 5 CO2 and 60 % CO) reported the lowest emission of NOx and Case 2 (25 % H2 5 % CH4 5 CO2 30 % CO and 35 % N2) of CO and CO2 emissions. Generally specialty gases with a variable composition of exhaust gas recirculation gases can be a promising sustainable replacement for existing fossil fuels.
Hydrogen in Burners: Economic and Environmental Implications
Nov 2024
Publication
For centuries fossil fuels have been the primary energy source but their unchecked use has led to significant environmental and economic challenges that now shape the global energy landscape. The combustion of these fuels releases greenhouse gases which are critical contributors to the acceleration of climate change resulting in severe consequences for both the environment and human health. Therefore this article examines the potential of hydrogen as a sustainable alternative energy source capable of mitigating these climate impacts. It explores the properties of hydrogen with particular emphasis on its application in industrial burners and furnaces underscoring its clean combustion and high energy density in comparison to fossil fuels and also examines hydrogen production through thermochemical and electrochemical methods covering green gray blue and turquoise pathways. It discusses storage and transportation challenges highlighting methods like compression liquefaction chemical carriers (e.g. ammonia) and transport via pipelines and vehicles. Hydrogen combustion mechanisms and optimized burner and furnace designs are explored along with the environmental benefits of lower emissions contrasted with economic concerns like production and infrastructure costs. Additionally industrial and energy applications safety concerns and the challenges of large-scale adoption are addressed presenting hydrogen as a promising yet complex alternative to fossil fuels.
A Data-Driven Scheduling Approach for Hydrogen Penetrated Energy System Using LSTM Network
Nov 2019
Publication
Intra-day control and scheduling of energy systems require high-speed computation and strong robustness. Conventional mathematical driven approaches usually require high computation resources and have difficulty handling system uncertainties. This paper proposes two data-driven scheduling approaches for hydrogen penetrated energy system (HPES) operational scheduling. The two data-driven approaches learn the historical optimization results calculated out using the mixed integer linear programing (MILP) and conditional value at risk (CVaR) respectively. The intra-day rolling optimization mechanism is introduced to evaluate the proposed data-driven scheduling approaches MILP data-driven approach and CVaR data-driven approach along with the forecasted renewable generation and load demands. Results show that the two data-driven approaches have lower intra-day operational costs compared with the MILP based method by 1.17% and 0.93%. In addition the combined cooling and heating plant (CCHP) has a lower frequency of changing the operational states and power output when using the MILP data-driven approach compared with the mathematical driven approaches.
Uncovering an Emerging Policy Direction for Australian Energy and Future Fuels Using a "Participatory Decision-Making" Framework
Aug 2024
Publication
Introduction: An online deliberative engagement process was undertaken with members of the general public to understand what they value or would like to change about the energy system within the broader context of decarbonizing Australia's energy networks identifying a role for future fuels (hydrogen and biogas). Citizens developed a set of principles that could guide Australia's path toward a low-carbon energy future reflecting on expectations they place upon energy transition. Next citizens' principles were shared with policy-makers in government and policy-influencers from the energy industry using an online interactive workshop.<br/>Methods: This study analyses policy-makers and -influencers response to citizens' guiding principles using the 'diamond of participatory decision-making' framework for analysis. Convergence and divergence in diverse complex and rich views across cohorts and implications thereupon energy policy were identified.<br/>Results: Although considerable alignment between multi-stakeholders' views was noted key areas of divergence or what is called the “groan zone” were easily identified in relation to social and environmental justice issues. This groan zone highlights the struggles that energy policy-makers face -the need to listen and respond to citizens' voices vs. the need for practical and workable policies that also support overarching government or industry objectives.<br/>Discussion: Policy making when the views of different stakeholders align is relatively straightforward. However this is not the case where the expectations diverge. More creative measures will be needed to address divergent views and expectations whilst maintaining procedural fairness in this case using democratic deliberative engagement processes. While the use of deliberative processes is gaining momentum worldwide particularly concerning climate change and energy transition policies this paper also highlights the benefits of conducting a robust post facto analysis of the content of the processes. Areas of alignment where policy can be made and implemented relatively easily without contention are identified. Other areas (such as making electrification mandatory) might be more complex or have unwanted negative social and environmental justice effects. Overall this paper bridges an analytical gap between “expectation studies” and participatory research. By borrowing terminology from a participatory research framework we sharpen the concepts in “expectation studies” from a consensus inclusion and diversity standpoint.
The Role of Hydrogen as Enabler of Industrial Port Area Decarbonoization
Nov 2023
Publication
To meet environmental goals while maintaining economic competitiveness worldwide ports have increased the amount of renewable energy production and have focused in optimizing performances and energy efficiency. However carbon-neutral operation of industrial port areas (IPA) is challenging and requires the decarbonization of industrial processes and heavy transport systems. This study proposes a comprehensive review of decarbon ization strategies for IPA with a particular focus on the role that green hydrogen could play when used as renewable energy carrier. Much information on existing and future technologies was also derived from the analysis of 74 projects (existing and planned) in 36 IPAs 80 % of which are in Europe concerning hydrogenbased decarbonization strategies. The overall review shows that engine operation of ships at berth are respon sible of more than 70 % of emissions in ports. Therefore onshore power supply (OPS) seems to be one of the main strategies to reduce port pollution. Nevertheless OPS powered by hydrogen is not today easily achievable. By overcoming the current cost-related and regulation barriers hydrogen can also be used for the import/export of green energy and the decarbonization of hard-to-abate sectors. The technical and economic data regarding hydrogen-based technologies and strategies highlighted in this paper are useful for further research in the field of definition and development of decarbonization strategies in the IPA.
Green Hydrogen Production by Water Electrolysis: Current Status and Challenges
Apr 2024
Publication
The scientific and industrial communities worldwide have recently achieved impressive technical advances in developing innovative electrocatalysts and electrolysers for water and seawater splitting. The viability of water electrolysis for commercial applications however remains elusive and the key barriers are durability cost performance materials manufacturing and system simplicity especially with regard to running on practical water sources like seawater. This paper therefore primarily aims to provide a concise overview of the most recent disruptive water-splitting technologies and materials that could reshape the future of green hydrogen production. Starting from water electrolysis fundamentals the recent advances in developing durable and efficient electrocatalysts for modern types of electrolysers such as decoupled electrolysers seawater electrolysers and unconventional hybrid electrolysers have been represented and precisely annotated in this report. Outlining the most recent advances in water and seawater splitting the paper can help as a quick guide in identifying the gap in knowledge for modern water electrolysers while pointing out recent solutions for cost-effective and efficient hydrogen production to meet zero-carbon targets in the short to near term.
Probabilistic Analysis of Electricity Production from a Photovoltaic–Wind Energy Mix for Sustainable Transport Needs
Nov 2024
Publication
Renewable Energy Sources (RESs) are characterized by high unevenness cyclicality and seasonality of energy production. Due to the trends in the production of electricity itself and the utilization of hydrogen distributed generation systems are preferred. They can be connected to the energy distribution network or operate without its participation (off-grid). However in both cases such distributed energy sources should be balanced in terms of power generation. According to the authors it is worth combining different RESs to ensure the stability of energy production from such a mix. Within the mix the sources can complement and replace each other. According to the authors an effective system for generating energy from RESs should contain at least two different sources and energy storage. The purpose of the analyses and calculations performed is to determine the characteristics of energy generation from a photovoltaic system and a wind turbine with a specific power and geographical location in the Lublin region in Poland. Another important goal is to determine the substitutability of the sources studied. Probabilistic analysis will be used to determine the share of given energy sources in the energy mix and will allow us to estimate the size of the stationary energy storage. The objective of these procedures is to strive for the highest possible share of renewable energy in the total energy required to charge electric vehicle fleets and to produce low-emission hydrogen for transportation. The article proves that the appropriately selected components of the photovoltaic and wind energy mix located in the right place lead to the self-balancing of the local energy network using a small energy storage. The conclusions drawn from the conducted research can be used by RES developers who intend to invest in new sources of power generation to produce low-emission hydrogen. This is in line with the current policy of the European Union aimed at climate and energy transformation of many companies using green hydrogen.
The Case of Renewable Methane by and with Green Hydrogen as the Storage and Transport Medium for Intermittent Wind and Solar PV Energy
May 2024
Publication
Long-duration energy storage is the key challenge facing renewable energy transition in the future of well over 50% and up to 75% of primary energy supply with intermittent solar and wind electricity while up to 25% would come from biomass which requires traditional type storage. To this end chemical energy storage at grid scale in the form of fuel appears to be the ideal option for wind and solar power. Renewable hydrogen is a much-considered fuel along with ammonia. However these fuels are not only difficult to transport over long distances but they would also require totally new and prohibitively expensive infrastructure. On the other hand the existing natural gas pipeline infrastructure in developed economies can not only transmit a mixture of methane with up to 20% hydrogen without modification but it also has more than adequate long-duration storage capacity. This is confirmed by analyzing the energy economies of the USA and Germany both possessing well-developed natural gas transmission and storage systems. It is envisioned that renewable methane will be produced via well-established biological and/or chemical processes reacting green hydrogen with carbon dioxide the latter to be separated ideally from biogas generated via the biological conversion of biomass to biomethane. At the point of utilization of the methane to generate power and a variety of chemicals the released carbon dioxide would be also sequestered. An essentially net zero carbon energy system would be then become operational. The current conversion efficiency of power to hydrogen/methane to power on the order of 40% would limit the penetration of wind and solar power. Conversion efficiencies of over 75% can be attained with the on-going commercialization of solid oxide electrolysis and fuel cells for up to 75% penetration of intermittent renewable power. The proposed hydrogen/methane system would then be widely adopted because it is practical affordable and sustainable.
Model-based Analysis and Optimization of Pressurised Alkaline Water Electrolysis Powered by Renewable Energy
Jul 2023
Publication
Alkaline water electrolysis is a key technology for large-scale hydrogen production. In this process safety and efficiency are among the most essential requirements. Hence optimization strategies must consider both aspects. While experimental optimization studies are the most accurate solution model-based approaches are more cost and time-efficient. However validated process models are needed which consider all important influences and effects of complete alkaline water electrolysis systems. This study presents a dynamic process model for a pressurized alkaline water electrolyzer consisting of four submodels to describe the system behavior regarding gas contamination electrolyte concentration cell potential and temperature. Experimental data from a lab-scale alkaline water electrolysis system was used to validate the model which could then be used to analyze and optimize pressurized alkaline water electrolysis. While steady-state and dynamic solutions were analyzed for typical operating conditions to determine the influence of the process variables a dynamic optimization study was carried out to optimize an electrolyte flow mode switching pattern. Moreover the simulation results could help to understand the impact of each process variable and to develop intelligent concepts for process optimization
Critical Challenges in Biohydrogen Production Processes from the Organic Feedstocks
Aug 2020
Publication
The ever-increasing world energy demand drives the need for new and sustainable renewable fuel to mitigate problems associated with greenhouse gas emissions such as climate change. This helps in the development toward decarbonisation. Thus in recent years hydrogen has been seen as a promising candidate in global renewable energy agendas where the production of biohydrogen gains more attention compared with fossil-based hydrogen. In this review biohydrogen production using organic waste materials through fermentation biophotolysis microbial electrolysis cell and gasification are discussed and analysed from a technological perspective. The main focus herein is to summarise and criticise through bibliometric analysis and put forward the guidelines for the potential future routes of biohydrogen production from biomass and especially organic waste materials. This research review claims that substantial efforts currently and in the future should focus on biohydrogen production from integrated technology of processes of (i) dark and photofermentation (ii) microbial electrolysis cell (MEC) and (iii) gasification of combined different biowastes. Furthermore bibliometric mapping shows that hydrogen production from biomethanol and the modelling process are growing areas in the biohydrogen research that lead to zero-carbon energy soon.
The Green Hydrogen Revolution
Jul 2023
Publication
Green hydrogen is considered the most suitable choice for the future energy market both as energy storage media energy vector and fuel for transportation industry and other applications. In the last twenty years increasing efforts have been dedicated to green hydrogen technologies development but still today a number of issues are claimed in justifying the delay in its large scale application and the star vation of its market. Moreover some new questions seem ready to be put on the table for justifying the delay in green hydrogen technologies applications. In this paper a critical analysis of recent literature and institutional reports is carried out with the aim of understanding what is the real state of the play. In particular peculiar advantages and shortcomings of different green hydrogen technologies (biomass pyrolysis and gasification water electrolysis etc.) have been analysed and compared with a focus on the electrolysis process as the most promising method for large scale and distributed generation of hydrogen. Some geopolitical and economic aspects associated with the transition to a green hydrogen economy - including the feared exacerbation of the water crisis - have been widely examined and discussed with the purpose of identifying approaches and solutions to accelerate the mentioned transition.
Recent Progress on Rational Design of Catalysts for Fermentative Hydrogen Production
May 2022
Publication
The increasingly severe energy crisis has strengthened the determination todevelop environmentally friendly energy. And hydrogen has emerged as a candi-date for clean energy. Among many hydrogen generation methods biohydrogenstands out due to its environmental sustainability simple operating environ-ment and cost advantages. This review focuses on the rational design of catalystsfor fermentative hydrogen production. The principles of microbial dark fermen-tation and photo-fermentation are elucidated exhaustively. Various strategiesto increase the efficiency of fermentative hydrogen production are summa-rized and some recent representative works from microbial dark fermentationand photo-fermentation are described. Meanwhile perspectives and discussionson the rational design of catalysts for fermentative hydrogen production areprovided.
Life Cycle Net Energy Assessment of Sustainable H2 Production and Hydrogenation of Chemicals in a Coupled Photoelectrochemical Device
Feb 2023
Publication
Green hydrogen has been identified as a critical enabler in the global transition to sustainable energy and decarbonized society but it is still not economically competitive compared to fossil-fuel-based hydrogen. To overcome this limitation we propose to couple photoelectrochemical (PEC) water splitting with the hydrogenation of chemicals. Here we evaluate the potential of coproducing hydrogen and methyl succinic acid (MSA) by coupling the hydrogenation of itaconic acid (IA) inside a PEC water splitting device. A negative net energy balance is predicted to be achieved when the device generates only hydrogen but energy breakeven can already be achieved when a small ratio (~2%) of the generated hydrogen is used in situ for IA-to-MSA conversion. Moreover the simulated coupled device produces MSA with much lower cumulative energy demand than conventional hydrogenation. Overall the coupled hydrogenation concept offers an attractive approach to increase the viability of PEC water splitting while at the same time decarbonizing valuable chemical production.
Green Hydrogen Generation in Alkaline Solution Using Electrodeposited Ni-Co-nano-graphene Thin Film Cathode
Apr 2024
Publication
Green hydrogen generation technologies are currently the most pressing worldwide issues ofering promising alternatives to existing fossil fuels that endanger the globe with growing global warming. The current research focuses on the creation of green hydrogen in alkaline electrolytes utilizing a Ni-Co-nano-graphene thin flm cathode with a low overvoltage. The recommended conditions for creating the target cathode were studied by electrodepositing a thin Ni-Co-nano-graphene flm in a glycinate bath over an iron surface coated with a thin copper interlayer. Using a scanning electron microscope (SEM) and energy-dispersive X-ray (EDX) mapping analysis the obtained electrode is physically and chemically characterized. These tests confrm that Ni Co and nano-graphene are homogeneously dispersed resulting in a lower electrolysis voltage in green hydrogen generation. Tafel plots obtained to analyze electrode stability revealed that the Ni-Co-nano-graphene cathode was directed to the noble direction with the lowest corrosion rate. The Ni-Co-nano-graphene generated was used to generate green hydrogen in a 25% KOH solution. For the production of 1 kg of green hydrogen utilizing Ni-Co-nano-graphene electrode the electrolysis efciency was 95.6% with a power consumption of 52 kwt h−1 whereas it was 56.212. kwt h−1 for pure nickel thin flm cathode and 54. kwt h−1 for nickel cobalt thin flm cathode respectively.
Hydrogen in the Strategies of the European Union Member States
Jan 2021
Publication
Energy and environmental challenges are two key issues related to the sustainable development of the Earth. Fossil fuels (oil coal and natural gas) still supply more than 85% of world energy consumption. Several nations around the globe are striving to provide access to clean and sustainable energy by 2030 (Hostettler et al. 2015). When the Paris Agreement entered into force in 2016 many countries have recently announced serious commitments to significantly reduce their carbon dioxide emissions promising to achieve “net zero” by 2050. he main goal is to limit global warming to well below 2 degrees Celsius preferably to 1.5 degrees Celsius compared to pre-industrial levels (IEA 2021). his requires a total transformation of the energy systems that underpin our economies. In the case of renewable energy technology deployment hydrogen may provide a complementary solution due to its flexibility as an energy carrier and storage medium. The European Union (EU) a signatory to the Paris Agreement demonstrated interest in hydrogen as an invaluable raw material in considerably reducing CO2 emissions. Hydrogen inthe EU energy mix is estimated to increase from the current level (less than 2%) to 13–14% in 2050 (EC 2018).
A Pan-Asian Energy Transition? The New Rationale for Decarbonization Policies in the World’s Largest Energy Exporting Countries: A Case Study of Qatar and Other GCC Countries
Jul 2024
Publication
Climate change has become a major agenda item in international relations and in national energy policy-making circles around the world. This review studies the surprising evolution of the energy policy and more particularly the energy transition currently happening in the Arabian Gulf region which features some of the world’s largest exporters of oil and gas. Qatar Saudi Arabia and other neighboring energy exporters plan to export blue and green hydrogen across Asia as well as towards Europe in the years and decades to come. Although poorly known and understood abroad this recent strategy does not threaten the current exports of oil and gas (still needed for a few decades) but prepares the evolution of their national energy industries toward the future decarbonized energy demand of their main customers in East and South Asia and beyond. The world’s largest exporter of Liquefied Natural Gas Qatar has established industrial policies and projects to upscale CCUS which can enable blue hydrogen production as well as natural carbon sinks domestically via afforestation projects.
A Multi-Zone Model for Hydrogen Accumulation and Ventilation in Enclosures
Sep 2023
Publication
Due to the small characteristic molecular size of hydrogen small leaks are more common in hydrogen systems compared to similar systems with hydrocarbons. This together with the high reactivity makes an efficient ventilation system very important in hydrogen applications. There are several models available for ventilation sizing that are based on either a well-mixed assumption or a fully stratified situation. However experiments show that many realistic releases will be neither and therefore additional models are needed. One possibility is to use CFD-models but the small release sizes for pinhole releases (<<1 mm) make it difficult to find an appropriate mesh without excessive computational time (especially since the simulations need to be iterated to find the optimum ventilation size). An alternative approach which is described and benchmarked in the current paper is to use a multi-zone model where the domain is divided into several large cells where the mass exchange is simplified compared to CFD and thus simulation time is reduced. The flow in the model is governed by mass conservation and density differences due to concentration gradients using the Bernoulli equation. The release of gas generates a plume which is modelled based on an empirical plume model which gives the entrainment and hydrogen source term for each cell. The model has a short run time and will therefore allow optimization in a short time frame. The model is benchmarked against five experiments with helium at the Canadian Nuclear Laboratories (CNL) in Canada and one hydrogen experiment performed at Lodz University of Technology in Poland. The result shows that the model can reasonably well reproduce accumulation in the experiments with small release without ventilation but appears to slightly underestimate the level of stratification and the interface height for ventilated cases where the source is elevated from the floor level.
Techno-economic Analysis of the Effect of a Novel Price-based Control System on the Hydrogen Production of an Offshore 1.5 GW Wind-hydrogen System
Feb 2024
Publication
The cost of green hydrogen production is very dependent on the price of electricity. A control system that can schedule hydrogen production based on forecast wind speed and electricity price should therefore be advantageous for large-scale wind-hydrogen systems. This work presents a novel price-based control system integrated in a techno-economic analysis of hydrogen production from offshore wind. A polynomial regression model that predicts wind power production from wind speed input was developed and tested with real-world datasets from a 2.3 MW floating offshore wind turbine. This was combined with a mathematical model of a PEM electrolyzer and used to simulate hydrogen production. A novel price-based control system was developed to decide when the system should produce hydrogen and when it should sell electricity to the grid. The model and control system can be used in real-world wind-hydrogen systems and require only the forecast wind speed electricity price and selling price of hydrogen as inputs. 11 test scenarios based on 10 years of real-world wind speed and electricity price data are proposed and used to evaluate the effect the price-based control system has on the levelized cost of hydrogen (LCOH). Both current and future (2050) costs and technologies are used and the results show that the novel control system lowered the LCOH in all scenarios by 10–46%. The lowest LCOH achieved with current technology and costs was 6.04 $/kg H2. Using the most optimistic forecasts for technology improvements and cost reductions in 2050 the model estimated a LCOH of 0.96 $/kg H2 for a grid-connected offshore wind farm and onshore hydrogen production 0.82 $/kg H2 using grid electricity (onshore) and 4.96 $/kg H2 with an offgrid offshore wind-hydrogen system. When the electricity price from the period 2013–2022 was used on the 2050 scenarios the resulting LCOH was approximately twice as high.
Regional Disparities and Strategic Implications of Hydrogen Production in 27 European Countries
Aug 2024
Publication
This study examines hydrogen production across 27 European countries highlighting disparities due to varying energy policies and industrial capacities. Germany leads with 109 plants followed by Poland France Italy and the UK. Mid-range contributors like the Netherlands Spain Sweden and Belgium also show substantial investments. Countries like Finland Norway Austria and Denmark known for their renewable energy policies have fewer plants while Estonia Iceland Ireland Lithuania and Slovenia are just beginning to develop hydrogen capacities. The analysis also reveals that a significant portion of the overall hydrogen production capacity in these countries remains underutilized with an estimated 40% of existing infrastructure not operating at full potential. Many countries underutilize their production capacities due to infrastructural and operational challenges. Addressing these issues could enhance output supporting Europe’s energy transition goals. The study underscores the potential of hydrogen as a sustainable energy source in Europe and the need for continued investment technological advancements supportive policies and international collaboration to realize this potential.
Hydrogen Supply Chain for Future Hydrogen-fuelled Railway in the UK: Transport Sector Focused
Aug 2024
Publication
Though being attractive on railway decarbonisation for regional lines excessive cost caused by immature hydrogen supply chain is one of the significant hurdles for promoting hydrogen traction to rolling stocks. Therefore we conduct bespoke research on the UK’s hydrogen supply chain for railway concentrating on hydrogen transportation. Firstly a map for the planned hydrogen production plants and potential hydrogen lines is developed with the location capacity and usage. A spatially explicit model for the hydrogen supply chain is then introduced which optimises the existing grid-based methodology on accuracy and applicability. Compressed hydrogen at three pressures and liquid hydrogen are considered as the mediums incorporating by road and rail transport. Furthermore three scenarios for hydrogen rail penetration are simulated respectively to discuss the levelised cost and the most suitable national transport network. The results show that the developed model with mix-integer linear programming (MILP) can well design the UK’s hydrogen distribution for railway traction. Moreover the hydrogen transport medium and vehicle should adjust to suit for different era where the penetration of hydrogen traction varies. The levelised cost of hydrogen (LCOH) decreases from 6.13 £/kg to 5.13 £/kg on average from the conservative scenario to the radical scenario. Applying different transport combinations according to the specific situation can satisfy the demand while reducing cost for multi-supplier and multitargeting hydrogen transport.
Development of a Method for Evaluating H2-Filling Stations
Nov 2024
Publication
To expedite the development of the infrastructural expansion for hydrogen applications the research project “THEWA” was founded. Within this project the development of hydrogen-refueling stations is being advanced so that the hydrogen strategy for mobility in Germany can move forward. One development point of the project is to develop an evaluation model that recommends a concept for hydrogen-refueling stations for initial individual situations. In this work an evaluation method is developed that provides an appropriate recommendation. For this purpose basics such as the general structure of hydrogen-refueling stations their classification into functional areas and alreadyexisting evaluation methods for multi-criteria decisions are shown. The method for the evaluation of hydrogen-refueling stations will be developed in a component-based manner for which a selection of influencing factors of hydrogen-refueling stations will be explained and categorized. With the help of an expert workshop these are scaled so that the result is an evaluation method based on an expert assessment and the consideration of individual customer requirements. In addition the method is implemented in a tool so that it can be used more easily.
Fuelling a Clean Future: A Systematic Review of Techno-Economic and Life Cycle Assessments in E-Fuel Development
Aug 2024
Publication
The transition to sustainable energy has ushered in the era of electrofuels (e-fuels) which are synthesised using electricity from renewable sources water and CO2 as a sustainable alternative to fossil fuels. This paper presents a systematic review of the techno-economic (TEA) and life cycle assessments (LCAs) of e-fuel production. We critically evaluate advancements in production technologies economic feasibility environmental implications and potential societal impacts. Our findings indicate that while e-fuels offer a promising solution to reduce carbon emissions their economic viability depends on optimising production processes and reducing input material costs. The LCA highlights the necessity of using renewable energy for hydrogen production to ensure the genuine sustainability of e-fuels. This review also identifies knowledge gaps suggesting areas for future research and policy intervention. As the world moves toward a greener future understanding the holistic implications of e-fuels becomes paramount. This review aims to provide a comprehensive overview to guide stakeholders in their decision-making processes.
Off-grid Hydrogen Production: Analysing Hydrogen Producton and Supply Costs Considering Country-specifics and Transport to Europe
Jul 2024
Publication
Hydrogen plays a pivotal role in transitioning to CO2-free energy systems yet challenges regarding costs and sourcing persist in supplying Europe with renewable hydrogen. Our paper proposes a simulation-based approach to determine cost-optimal combinations of electrolyser power and renewable peak power for off-grid hydrogen production considering location and energy source dependencies. Key findings include easy estimation of Levelized Costs of Hydrogen (LCOH) and optimal plant sizing based on the regional energy yield and source. Regional investment risks influence the LCOH by 7.9 % per 1 % change of the Weighted Average Cost of Capital. In Central Europe (Austria) hydrogen production costs range from 7.4 €/kg to 8.6 €/kg whereas regions like Chile exhibit cheaper costs at 5.1 €/kg to 6.8 €/kg. Despite the favourable energy yields in regions like Chile or the UAE domestically produced hydrogen can be cost-competitive when location-specific risks and transport costs are taken into account. This underlines the critical role of domestic hydrogen production and cost-effective hydrogen transport for Europe’s future hydrogen supply.
Thermodynamic Evaluation of Solar Energy-based Methanol and Hydrogen Production and Power Generation Pathways: A Comparative Study
Sep 2024
Publication
This work presents a comparative novel evaluation of two distinct fuels methanol and hydrogen production and power generation routes via fuel cells. The first route includes the methanol production from direct partial oxidation of methane to methanol where the methanol is condensed stored and sent to a direct methanol fuel cell. The second route is hydrogen production from solar methane cracking (named as turquoise hydrogen) where heat is supplied from concentrated solar power and hydrogen is stored and directed to a hydrogen fuel cell. This study aims to provide insights into these fuel's production conditions storage methods energy and exergy efficiencies. The proposed system is simulated using the Engineering Equation Solver software and a thermodynamic analysis of the entire system including all the equipment and process streams is performed. The methanol and hydrogen route's overall energy and exergy efficiencies are 39.75% 38.35% 35.84% and 34.58% respectively. The highest exergy destruction rate of 1605 kW is observed for the partial oxidation of methane to methanol. The methanol and hydrogen routes generate 32.087 MWh and 11.582 MWh of electricity for 16-hour of fuel cell operation respectively. Sensitivity analysis has been performed to observe the effects of different parameters such as operating temperature and mass flow rate of fuels on the electricity production and energy efficiencies of the systems.
Analysis of Hydrogen Value Chain Events: Implications for Hydrogen Refueling Stations’ Safety
Apr 2024
Publication
Renewable hydrogen is emerging as the key to a sustainable energy transition with multiple applications and uses. In the field of transport in addition to fuel cell vehicles it is necessary to develop an extensive network of hydrogen refueling stations (hereafter HRSs). The characteristics and properties of hydrogen make ensuring the safe operation of these facilities a crucial element for their successful deployment and implementation. This paper shows the outcomes of an analysis of hydrogen incidents and accidents considering their potential application to HRSs. For this purpose the HIAD 2.0 was reviewed and a total of 224 events that could be repeated in any of the major industrial processes related to hydrogen refueling stations were analyzed. This analysis was carried out using a mixed methodology of quantitative and qualitative techniques considering the following hydrogen value chain: production storage delivery and industrial use. The results provide general information segmented by event frequency damage classes and failure typology. The analysis shows the main processes of the value chain allow the identification of key aspects for the safety management of refueling facilities.
Machine Learning Models for the Prediction of Turbulent Combustion Speed for Hydrogen-natural Gas Spark Ignition Engines
May 2024
Publication
The work carried out in this paper focused on “Machine learning models for the prediction of turbulent combustion speed for hydrogen-natural gas spark ignition engines”. The aim of this work is to develop and verify the ability of machine learning models to solve the problem of estimating the turbulent flame speed for a spark-ignition internal combustion engine operating with a hydrogen-natural gas mixture then evaluate the relevance of these models in relation to the usual approaches. The novelty of this work is the possibility of a direct calculation of turbulent combustion speed with a good precision using only machine learning model. The obtained models are also compared to each other by considering in turn as a comparison criterion: the precision of the result calculation time and the ability to assimilate original data (which has not undergone preprocessing). An important particularity of this work is that the input variables of the machine learning models were chosen among the variables directly measurable experimentally based on the opinion of experts in combustion in internal combustion engines and not on the usual approaches to dimensionality reduction on a dataset. The data used for this work was taken from a MINSEL 380 a 380-cc single-cylinder engine. The results show that all the machine learning models obtained are significantly faster than the usual approach and Random Forest (R2: R-squared = 0.9939 and RMSE: Root Mean Square Error = 0.4274) gives the best results. With a forecasting accuracy of over 90 % both approaches can make reasonable predictions for most industrial applications such as designing engine monitoring and control systems firefighting systems simulation and prototyping tools.
Renewable Hydrogen Production Steps Up Wastewater Treatment under Low-carbon Electricity Sources - A Call Forth Approach
Sep 2024
Publication
Switching to renewable resources for hydrogen production is essential. Present hydrogen resources such as coal oil and natural gas are depleted and rapidly moving to a dead state and they possess a high carbon footprint. Wastewater is a promising avenue in searching for a renewable hydrogen production resource. Profuse techniques are preferred for hydrogen production. Among them electrolysis is great with wastewater against biological processes by hydrogen purity. Present obstacles behind the process are conversion efficiency intensive energy and cost. This review starts with hydrogen demand wastewater availability and their H2 potential then illustrates the three main types of electrolysis. The main section highlights renewable energy-assisted electrolysis because of its low carbon footprint and zero emission potential for various water electrolysis. High-temperature steam solid oxide electrolysis is a viable option for future scaling due to the versatile adoption of photo electric and thermal energy. A glance at some effective aspirations to large-scale H2 economics such as co-generation biomass utilization Microbial electrolysis waste to low-cost green electrode Carbon dioxide hydrogenation and minerals recovery. This study gives a broader view of facing challenges via versatile future perspectives to eliminate the obstacles above. renewable green H2 along with a low carbon footprint and cost potential to forward the large-scale wastewater electrolysis H2 production in addition to preserving the environment from wastewater and fossil fuel. Geographical and seasonal availability constraints are unavoidable; therefore energy storage and coupling of power sources is essential to attain consistent supply. The lack of regulations and policies supporting the development and adoption of these technologies did not reduce the gap between research and implementation. Life cycle assessment of this electrolysis process is rarely available so we need to focus on the natural effect of this process on the environment.
Evaluation of the Impact of Gaseous Hydrogen on Pipeline Steels Utilizing Hollow Specimen Technique and μCT
Feb 2024
Publication
The high potential of hydrogen as a key factor on the pathway towards a climate neutral economy leads to rising demand in technical applications where gaseous hydrogen is used. For several metals hydrogen-metal interactions could cause a degradation of the material properties. This is especially valid for low carbon and highstrength structural steels as they are commonly used in natural gas pipelines and analyzed in this work. This work provides an insight to the impact of hydrogen on the mechanical properties of an API 5L X65 pipeline steel tested in 60 bar gaseous hydrogen atmosphere. The analyses were performed using the hollow specimen technique with slow strain rate testing (SSRT). The nature of the crack was visualized thereafter utilizing μCT imaging of the sample pressurized with gaseous hydrogen in comparison to one tested in an inert atmosphere. The combination of the results from non-conventional mechanical testing procedures and nondestructive imaging techniques has shown unambiguously how the exposure to hydrogen under realistic service pressure influences the mechanical properties of the material and the appearance of failure.
Cost-optimal Design and Operation of Hydrogen Refueling Stations with Mechanical and Electrochemical Hydrogen Compressors
Sep 2024
Publication
Hydrogen refueling stations (HRS) can cause a significant fraction of the hydrogen refueling cost. The main cost contributor is the currently used mechanical compressor. Electrochemical hydrogen compression (EHC) has recently been proposed as an alternative. However its optimal integration in an HRS has yet to be investigated. In this study we compare the performance of a gaseous HRS equipped with different compressors. First we develop dynamic models of three process configurations which differ in the compressor technology: mechanical vs. electrochemical vs. combined. Then the design and operation of the compressors are optimized by solving multi-stage dynamic optimization problems. The optimization results show that the three configurations lead to comparable hydrogen dispensing costs because the electrochemical configuration exhibits lower capital cost but higher energy demand and thus operating cost than the mechanical configuration. The combined configuration is a trade-off with intermediate capital and operating cost.
Technical Failures in Green Hydrogen Production and Reliability Engineering Responses: Insights from Database Analysis and a Literature Review
Nov 2024
Publication
Green hydrogen represents a promising solution for renewable energy application and carbon footprint reduc tion. However its production through renewable energy powered water electrolysis is hindered by significant cost arising from repair maintenance and economic losses due to unexpected downtimes. Although reliability engineering is highly effective in addressing such issues there is limited research on its application in the hydrogen field. To present the state-of-the-art research this study aims to explore the potential of reducing these events through reliability engineering a widely adopted approach in various industries. For this purpose it examines past accidents occurred in water electrolysis plants from the hydrogen incident and accident database (HIAD 2.1). Besides a literature review is performed to analyze the state-of-the-art application of reliability engineering techniques such as failure analysis reliability assessment and reliability-centered maintenance in the hydrogen sector and similar industries. The study highlights the contributions and potentials of reliability engineering for efficient and stable green hydrogen production while also discussing the gaps in applying this approach. The unique challenges posed by hydrogen’s physical properties and innovative technologies in water electrolysis plants necessitate advancement and specialized approaches for reliability engineering.
Identification of Hydrogen-Energy-Related Emerging Technologies Based on Text Mining
Dec 2023
Publication
As a versatile energy carrier hydrogen possesses tremendous potential to reduce greenhouse emissions and promote energy transition. Global interest in producing hydrogen from renewable energy sources and transporting storing and utilizing hydrogen is rising rapidly. However the high costs of producing clean hydrogen and the uncertain application scenarios for hydrogen energy result in its relatively limited utilization worldwide. It is necessary to find new promising technological paths to drive the development of hydrogen energy. As part of technological innovation emerging technologies have vital features such as prominent impact novelty relatively fast growth etc. Identifying emerging hydrogen-energy-related technologies is important for discovering innovation opportunities during the energy transition. Existing research lacks analysis of the characteristics of emerging technologies. Thus this paper proposes a method combining the latent Dirichlet allocation topic model and hydrogen-energy expert group decision-making. This is used to identify emerging hydrogen-related technology regarding two features of emerging technologies novelty and prominent impact. After data processing topic modeling and analysis the patent dataset was divided into twenty topics. Six emerging topics possess novelty and prominent impact among twenty topics. The results show that the current hotspots aim to promote the application of hydrogen energy by improving the performance of production catalysts overcoming the wide power fluctuations and large-scale instability of renewable energy power generation and developing advanced hydrogen safety technologies. This method efficiently identifies emerging technologies from patents and studies their development trends. It fills a gap in the research on emerging technologies in hydrogen-related energy. Research achievements could support the selection of technology pathways during the low-carbon energy transition.
An Assessment of Decarbonisation Pathways for Intercontinental Deep-sea Shipping Using Power-to-X Fuels
Aug 2024
Publication
Shipping corridors act as the arteries of the global economy. The maritime shipping sector is also a major source of greenhouse gas emissions accounting for 2.9% of the global total. The international nature of the shipping sector combined with issues surrounding the use of battery technology means that these emissions are considered difficult to eliminate. This work explores the transition to renewable fuels by examining the use of electrofuels (in the form of liquid hydrogen methane methanol ammonia and Fischer-Tropsch fuel) to decarbonise large container ships from a technical economic and environmental perspective. For an equivalent range to current fossil fuel vessels the cargo capacity of vessels powered by electrofuels decreases by between 3% and 16% depending on the fuel of choice due to the lower energy density compared with conventional marine fuels. If vessel operators are willing to sacrifice range cargo space can be preserved by downsizing onboard energy storage which necessitates more frequent refuelling. For a realistic green hydrogen cost of €3.5/kg (10.5 €c/kWh) in 2030 the use of electrofuels in the shipping sector results in an increase in the total cost of ownership of between 124% and 731% with liquid hydrogen in an internal combustion engine being the most expensive and methanol in an internal combustion engine resulting in the lowest cost increase. Despite this we find that the increased transportation costs of some consumer goods to be relatively small adding for example less than €3.27 to the cost of a laptop. In general fuels which do not require cryogenic storage and can be used in internal combustion engines result in the lowest cost increases. For policymakers reducing the environmental impact of the shipping sector is a key priority. The use of liquid hydrogen which results in the largest cost increase offers a 70% reduction in GHG emissions for an electricity carbon intensity of 80 gCO2e/ kWh which is the greatest reduction of all fuels assessed in this work. A minimum carbon price of €400/tCO2 is required to allow these fuels to reach parity with conventional shipping operations. To meet European Union emissions reductions targets electricity with an emissions intensity below 40 gCO2e/kWh is required which suggests that for electrofuels to be truly sustainable direct connection with a source of renewable electricity is required.
Characterizing Hydrogen-diesel Dual-fuel Performance and Emissions in a Commercial Heavy-duty Diesel Truck
Sep 2024
Publication
This study investigates hydrogen (H2) as a supplementary fuel in heavy-duty diesel engines using pre-manifold injection. A H2-diesel dual-fuel (H2DF) system was implemented on a commercial class-8 heavy-duty diesel truck without modifying the original diesel injection system and engine control unit (ECU). Tests were conducted on a chassis dynamometer at engine speeds between 1000 and 1400 rpm with driver-demanded torques from 10 to 75%. The hydrogen energy fraction (HEF) was strategically controlled in the range between 10 and 30%. Overall CO2 reduction (comparable to the HEF level) was achieved with similar brake-specific energy consumption (BSEC) at all loads and speeds. To maintain the same shaft torque the driver-demanded torque was reduced in H2DF operation which resulted in a lower boost pressure. At higher loads engine-out BSNOx slightly decreased while BSCO and black carbon (BC) increased significantly due to lower oxygen concentration resulting from the lower boost pressure. At lower loads engine-out BSCO and BSBC decreased moderately while NO2/NO ratio increased substantially in H2DF operation. Deliberate air path and diesel injection control are expected to enable higher HEF and GHG reductions.
Assessment of the Role of the Green Hydrogen as the Commodity Enabling a New Green Dialogue Among the Mediterranean Shores
Apr 2024
Publication
The Mediterranean basin has been characterized by a net flow of fossil commodities from the North African shore to Southern Europe and the Middle East for decades; however decarbonizing the energy system implies to substantially modify this situation turning the current “black dialogue” into a “green dialogue” (i.e. based on the exchange of renewable electricity and green hydrogen). This paper presents a feasibility study conducted to estimate the potential green hydrogen production by electrolysis in three Tunisian sites. It shows and compares several plant layouts varying the size and typology of renewable electricity generators and electrolyzers. The work adopts local weather data and technical features of the technologies in the computations and accounts for site specific topographical and infrastructural constraints such as land available for construction and local power grid connection capacities. It shows that configurations able to produce large quantities of green hydrogen may not be compliant with such constraints basically nullifying their contribution in any hydrogen strategy. Finally results show that the LCOH lies in the range 1.34 $/kgH2 and 4.06 $/kgH2 depending on both the location and the combination of renewable electricity generators and electrolyzers.
Renewable Fuels of Nob-biological Origin in the European Union - Status Report on Technology Development, Trends, Value Chains & Markets
Jan 2024
Publication
This report investigates the status and trend of Renewable Fuels of Non-Biological Origin (RFNBO) except hydrogen which are needed to cover part of the EU’s demand for low carbon renewable fuels in the coming years. The report is an update of the CETO 2023 report. Most of the conversion technologies investigated have been already demonstrated at small-scale and the current EU legislative framework under the recast of the Renewable Energy Directive (EU) 2018/2001 (Directive EU 2023/2413) sets specific targets for their use. As a pre-requisite well-established solid hydrogen supply chains are needed together with carbon capture technologies to provide carbon dioxide as Carbon Capture and Use (CCU). Fuels that may be produced starting from H2 and CO2 or N2 are hydrocarbons alcohols and ammonia. RFNBO may play a crucial role in the energytransition towards decarbonisation especially in hard-to-abate sectors where direct electrification is not possible. In addition most RFNBO can use existing infrastructure. The growing interest in these fuels is witnessed by the many funding programmes which are today available. Moreover EU leads the sector in terms of patents companies and demonstration activities. Finally the report considers the major challenges and the opportunities for a rapid market uptake of such fuels.
Greening of European Sea Ports - Final Report
Mar 2024
Publication
The report addresses the environmental challenges faced by European sea ports and aims to provide guidance to smaller ports for improving their environmental performance while achieving sustainability goals through experiences gained by implementing noteworthy green initiatives in practice. Larger ports possess significant advantages in terms of financial resources risk tolerance and organisational capacity. They often have the means to invest in innovative solutions and actively participate in research and development projects leading to co-funded pilot implementation of green initiatives. They typically have more skilled personnel stronger influence and stakeholder leverage which position them better to lead the way in sustainability efforts. Finally larger ports often form robust collaborations to drive collective action towards sustainable goals. Smaller ports face unique challenges stemming from typically limited resources and risk aversion. They often prioritise mature solutions relying on tested practices to mitigate potential risks. They may lack internal expertise requiring guidance and capacity-building programmes to navigate the selection and implementation of green practices. Also they require financial and technical support particularly as they may underutilise available funding mechanisms and have limited participation in R&D programmes. They may benefit from partnerships with other ports and stakeholders to create synergies and gain experience from their lessons learned to boost their capacity to implement green practices
Power-to-X Economy: Green E-hydrogen, E-fuels, E-chemicals, and E-materials Opportunities in Africa
Aug 2024
Publication
Africa has enormous potential to produce low-cost e-fuels e-chemicals and e-materials required for complete defossilisation using its abundant renewable resources widely distributed across the continent. This research builds on techno-economic investigations using the LUT Energy System Transition Model and related tools to assess the power-to-X potential in Africa for meeting the local demand and exploring the export potential of power-to-products applications. In this context we analysed the economic viability of exporting green e-fuel echemicals and e-materials from Africa to Europe. We also present the core elements of the Power-to-X Economy i.e. renewable electricity and hydrogen. The results show that hydrogen will likely not be traded simply due to high transport costs. However there is an opportunity for African countries to export e-ammonia e-methanol ekerosene jet fuel e-methane e-steel products and e-plastic to Europe at low cost. The results show that Africa’s low-cost power-to-X products backed by low-cost renewable electricity mainly supplied by solar photovoltaics is the basis for Africa’s vibrant export business opportunities. Therefore the Power-to-X Economy could more appropriately be called a Solar-to-X Economy for Africa. The Power-to-X Economy will foster socio-economic growth in the region including new industrial opportunities new investment portfolios boost income and stimulate local technical know-how thereby delivering a people-driven energy economy. Research on the topic in Africa is limited and at a nascent stage. Thus more studies are required in future to guide investment decisions and cater to policy decisions in achieving carbon neutrality with e-fuels e-chemicals and e-materials.
Hydrogen in Natural Gas Grids: Prospects and Recommendations About Gas Flow Meters
Aug 2024
Publication
To inject green hydrogen (H2) into the existing natural gas (NG) infrastructure is one way to decarbonize the European energy system. However asset readiness is necessary to be successful. Preliminary analysis and experimental results about the compatibility of hydrogen and natural gas mixtures (H2NG) with the actual gas grids make the scientific community confident about the feasibility. Nevertheless specific technical questions need more research. A significant topic of debate is the impact of H2NG mixtures on the performance of state-ofthe-art fiscal measuring devices which are essential for accurate billing. Identifying and addressing any potential degradation in their metrological performance due to H2NG is critical for decision-making. However the literature lacks data about the gas meters’ technologies currently installed in the NG grids such as a comprehensive overview of their readiness at different concentrations while data are fragmented among different sources. This paper addresses these gaps by analyzing the main characteristics and categorizing more than 20000 gas meters installed in THOTH2 project partners’ grids and by summarizing the performance of traditional technologies with H2NG mixtures and pure H2 based on literature review operators experience and manufacturers knowledge. Based on these insights recommendations are given to stakeholders on overcoming the identified barriers to facilitate a smooth transition.
Data Hub for Life Cycle Assessment of Climate Change Solutions—Hydrogen Case Study
Nov 2024
Publication
Life cycle assessment which evaluates the complete life cycle of a product is considered the standard methodological framework to evaluate the environmental performance of climate change solutions. However significant challenges exist related to datasets used to quantify these environmental indicators. Although extensive research and commercial data on climate change technologies pathways and facilities exist they are not readily available to practitioners of life cycle assessment in the right format and structure using an open platform. In this study we propose a new open data hub platform for life cycle assessment considering a hierarchical data flow starting with raw data collected on climate change technologies at laboratory pilot demonstration or commercial scales to provide the information required for policy and decision-making. This platform makes data accessible at multiple levels for practitioners of life cycle assessment while making data interoperable across platforms. The proposed data hub platform and workflow are explained through the polymer electrolyte membrane electrolysis hydrogen production as a case study. The climate change environment impact of 1.17 ± 0.03 kg CO2 eq./kg H2 was calculated for the case study. The current data hub platform is limited to evaluating environmental impacts; however future additions of economic and social aspects are envisaged.
Green Transformation of Mining towards Energy Self-Sufficiency in a Circular Economy—A Case Study
Jul 2024
Publication
This article presents the concept of green transformation of the coal mining sector. Pump stations that belong to Spółka Restrukturyzacji Kopal´n S.A. (SRK S.A. Bytom Poland) pump out approximately 100 million m3 of mine water annually. These pump stations protect neighboring mines and lower-lying areas from flooding and protect subsurface aquifers from contamination. The largest cost component of maintaining a pumping station is the expenditure for purchasing electricity. Investment towards renewable energy sources will reduce the environmental footprint of pumping station operation by reducing greenhouse gas emissions. The concept of liquidation of an exemplary mining site in the context of a circular economy by proposing the development/revitalization of a coal mine site is presented. This concept involves the construction of a complex consisting of photovoltaic farms combined with efficient energy storage in the form of green hydrogen produced by water electrolysis. For this purpose the potential of liquidated mining sites will be utilized including the use of pumped mine wastewater. This article is conceptual. In order to reach the stated objective a body of literature and legal regulations was analyzed and an empirical study was conducted. Various scenarios for the operation of mine pumping stations have been proposed. The options presented provide full or nearly full energy self-sufficiency of the proposed pumping station operation concept. The effect of applying any option for upgrading the pumping station could result in the creation of jobs that are alternatives to mining jobs and a guarantee of efficient asset management.
Experimental Study on Dynamic Response Performance of Hydrogen Sensor in Confined Space under Ceiling
Oct 2024
Publication
With the advancement of Fuel Cell Vehicles (FCVs) detecting hydrogen leaks is critically important in facilities such as hydrogen refilling stations. Despite its significance the dynamic response performance of hydrogen sensors in confined spaces particularly under ceilings has not been comprehensively assessed. This study utilizes a catalytic combustion hydrogen sensor to monitor hydrogen leaks in a confined area. It examines the effects of leak size and placement height on the distribution of hydrogen concentrations beneath the ceiling. Results indicate that hydrogen concentration rapidly decreases within a 0.5–1.0 m range below the ceiling and declines more gradually from 1.0 to 2.0 m. The study further explores the attenuation pattern of hydrogen concentration radially from the hydrogen jet under the ceiling. By normalizing the radius and concentration it was determined that the distribution conforms to a Gaussian model akin to that observed in open space jet flows. Utilizing this Gaussian assumption the model is refined by incorporating an impact reflux term thereby enhancing the accuracy of the predictive formula.
A Thermodynamically Consistent Methodology to Develop Predictive Simplified Kinetics for Detonation Simulations
Sep 2023
Publication
The number of species and elementary reactions needed for describing the oxidation of fuels increases with the size of the molecule and in turn the complexity of detailed mechanisms. Although the kinetics for conventional fuels (H2 CH4 C3H8...) are somewhat well-established chemical integration in detonation applications remains a major challenge. Significant efforts have been made to develop reduction techniques that aim to keep the predictive capabilities of detailed mechanisms intact while minimizing the number of species and reactions required. However as their starting point of development is based on homogeneous reactors or ZND profiles reduced mechanisms comprising a few species and reactions are not predictive. The methodology presented here relies on defining virtual chemical species such that the thermodynamic equilibrium of the ZND structure is properly recovered thereby circumventing the need to account for minor intermediate species. A classical asymptotic expression relating the ignition delay time with the reaction rate constant is then used to fit the Arrhenius coefficients targeting computations carried out with detailed kinetics. The methodology was extended to develop a three-step mechanism in which the Arrhenius coefficients were optimized to accurately reproduce the one-dimensional laminar ZND structure and the D−κ curves for slightly-curved quasi-steady detonation waves. Two-dimensional simulations performed with the three-step mechanism successfully reproduce the spectrum of length scales present in soot foils computed with detailed kinetics (i.e. cell regularity and size). Results attest for the robustness of the proposed methodology/approximation and its flexibility to be adapted to different configurations.
Experimental Study on the Ignition of Hydrogen Containing Atmospheres by Mechanical Impacts
Sep 2023
Publication
In international regulations on explosion protection mechanical friction impact or abrasion is usually named as one of 13 ignition sources that must be avoided in hazardous zones with explosive atmospheres. In different studies it is even identified as one of the most frequent ignition sources in practice. The effectiveness of mechanical impacts as ignition source is dependent from several parameters including the minimum ignition energy of the explosive atmosphere the properties of the material pairing the kinetic impact energy or the impact velocity. By now there is no standard procedure to determine the effectiveness of mechanical impacts as ignition source. In some previous works test procedures with poor reproducibility or undefined kinetic impact energy were applied for this purpose. In other works only homogeneous material pairings were considered. In this work the effectiveness of mechanical impacts with defined and reproducible kinetic impact energy as ignition source for hydrogen containing atmospheres was studied systematically in dependence from the inhomogeneous material pairing considering materials with practical relevance like stainless steel low alloy steel concrete and non-iron-metals. It was found that ignition can be avoided if non-iron metals are used in combination with different metallic materials but in combination with concrete even the impact of non-iron-metals can be an effective ignition source if the kinetic impact energy is not further limited. Moreover the consequence of hydrogen admixture to natural gas on the effectiveness of mechanical impacts as ignition source was studied. In many cases ignition of atmospheres containing natural gas by mechanical impacts is rather unlikely. No influence could be observed for admixtures up to 25% hydrogen and even more. The results are mainly relevant in the context of repurposing the natural gas grid or adding hydrogen to the natural gas grid. Based on the test results it can be evaluated under which circumstances the use of tools made of non-iron-metals or other non-sparking materials can be an effective measure to avoid ignition sources in hazardous zones containing hydrogen for example during maintenance work.
Review of the Hydrogen Supply Chain and Use in Africa
Oct 2024
Publication
The high potential in renewable energy sources (RES) and the availability of strategic minerals for green hydrogen technologies place Africa in a promising position for the development of a climate-compatible economy leveraging on hydrogen. This study reviews the potential hydrogen value chain in Africa considering production and final uses while addressing perspectives on policies possible infrastructures and facilities for hydrogen logistics. Through scientific studies research and searching in relevant repositories this review features the collection analysis of technical data and georeferenced information about key aspects of the hydrogen value chain. Detailed maps and technical data for gas transport infrastructure and liquefaction terminals in the continent are reported to inform and elaborate findings about readiness for hydrogen trading and domestic use in Africa. Specific maps and technical data have been also collected for the identification of potential hydrogen offtakers focusing on individual industrial installations to produce iron and steel chemicals and oil refineries. Finally georeferenced data are presented for main road and railway corridors as well as for most important African ports as further end-use and logistic platforms. Beyond technical information this study collects and discusses more recent perspectives about policies and implementation initiatives specifically addressing hydrogen production logistics and final use also introducing potential criticalities associated with environmental and social impacts.
Investments in Green Hydrogen as a Flexibility Source for the European Power System by 2050: Does it Pay Off?
Oct 2024
Publication
The European Union aims to deploy a high share of renewable energy sources in Europe’s power system by 2050. Large-scale intermittent wind and solar power production requires flexibility to ensure an adequate supply–demand balance. Green hydrogen (GH) can increase power systems’ flexibility and decrease renewable energy production’s curtailment. However investing in GH is costly and dependent on electricity prices which are important for operational costs in electrolysis. Moreover the use of GH for power system flexibility might not be economically viable if there is no hydrogen demand from the hydrogen market. If so questions would arise as to what would be the incentives to introduce GH as a source of flexibility in the power system and how would electrolyzer costs hydrogen demand and other factors affect the economic viability of GH usage for power system flexibility. The paper implements a European power system model formulated as a stochastic program to address these questions. The authors use the model to compare various instances with hydrogen in the power system to a no-hydrogen instance. The results indicate that by 2050 deployment of approximately 140 GW of GH will pay off investments and make the technology economically viable. We find that the price of hydrogen is estimated to be around €30/MWh.
Energy-saving Hydrogen Production by Seawater Electrolysis Coupling Tip-enhanced Electric Field Promoted Electrocatalytic Sulfion Oxidation
Jul 2024
Publication
Hydrogen production by seawater electrolysis is significantly hindered by high energy costs and undesirable detrimental chlorine chemistry in seawater. In this work energy-saving hydrogen production is reported by chlorine-free seawater splitting coupling tip-enhanced electric field promoted electrocatalytic sulfion oxidation reaction. We present a bifunctional needle-like Co3S4 catalyst grown on nickel foam with a unique tip structure that enhances the kinetic rate by improving the current density in the tip region. The assembled hybrid seawater electrolyzer combines thermodynamically favorable sulfion oxidation and cathodic seawater reduction can enable sustainable hydrogen production at a current density of 100 mA cm−2 for up to 504 h. The hybrid seawater electrolyzer has the potential for scale-up industrial implementation of hydrogen production by seawater electrolysis which is promising to achieve high economic efficiency and environmental remediation.
Elevating Sustainability with a Multi-Renewable Hydrogen Generation System Empowered by Machine Learning and Multi-objective Optimisation
Apr 2024
Publication
The global energy landscape is rapidly shifting toward cleaner lower-carbon electricity generation necessitating a transition to alternate energy sources. Hydrogen particularly green hydrogen looks to be a significant solution for facilitating this transformation as it is produced by water electrolysis with renewable energy sources such as solar irradiations wind speed and biomass residuals. Traditional energy systems are costly and produce energy slowly due to unpredictability in resource supply. To address this challenge this work provides a novel technique that integrates a multi-renewable energy system using multi objective optimization algorithm to meets the machine learning-based forecasted load model. Several forecasting models including Autoregressive Integrated Moving Average(ARIMA) Random Forest and Long Short-Term Memory Recurrent Neural Network (LSTMRNN) are assessed for develop the statistical metrics values such as RMSE MAE and MAPE. The selected Non-Sorting Moth Flame Optimization (NSMFO) algorithm demonstrates technological prowess in efficiently achieving global optimization particularly when handling multiple objective functions. This integrated method shows enormous promise in technological economic and environmental terms emphasizing its ability to promote energy sustainability targets.
Probabilistic Analysis of Green Hydrogen Production from a Mix of Solar and Wind Energy
Sep 2024
Publication
This article describes an example of using the measurement data from photovoltaic systems and wind turbines to perform practical probabilistic calculations around green hydrogen generation. First the power generated in one month by a ground-mounted photovoltaic system with a peak power of 3 MWp is described. Using the Metalog family of probability distributions the probability of generating selected power levels corresponding to the amount of green hydrogen produced is calculated. Identical calculations are performed for the simulation data allowing us to determine the power produced by a wind turbine with a maximum power of 3.45 MW. After interpolating both time series of the power generated by the renewable energy sources to a common sampling time they are summed. For the sum of the power produced by the photovoltaic system and the wind turbine the probability of generating selected power levels corresponding to the amount of green hydrogen produced is again calculated. The presented calculations allow us to determine with probability distribution accuracy the amount of hydrogen generated from the energy sources constituting a mix of photovoltaics and wind. The green hydrogen production model includes the hardware and the geographic context. It can be used to determine the preliminary assumptions related to the production of large amounts of green hydrogen in selected locations. The calculations presented in this article are a practical example of Business Intelligence.
Hydrogen Refueling Station Cost Model Applied to Five Real Case Studies for Fuel Cell buses
Oct 2021
Publication
Hydrogen Refueling Stations (HRS) are a key infrastructure to the successful deployment of hydrogen mobility. Their cost-effectiveness will represent an increasingly crucial issue considering the foreseen growth of vehicle fleets from few captive fleets to large-scale penetration of hydrogen vehicles. In this context a detailed component-oriented cost model is important to assess HRS costs for different design concepts layout schemes and possible customizations respect to aggregate tools which are mostly available in literature. In this work an improved version of a previously developed component-oriented scale-sensitive HRS cost model is applied to 5 different European HRS developed within the 3Emotion project with different refueling capacities (kgH2/day) hydrogen supply schemes (in-situ production or delivery) storage volumes and pressures and operational strategies. The model output allows to assess the upfront investment cost (CAPEX) the annual operational cost (OPEX) and the Levelized Cost of Hydrogen (LCOH) at the dispenser and identify the most crucial cost components. The results for the five analyzed HRS sites show an LCOH at the nozzle of around 8-9 €/kg for delivery based HRSs which are mainly dominated by the H2 retail price and transport service price and around 11-12 €/kg for on-site producing HRS for which the electrolyzer CAPEX and electricity price plays a key role in the cost structure. The compression storage and dispensing sections account for between 1-3 €/kg according to the specific design & performance requirements of the HRS. The total LCOH values are comparable with literature standard market prices for similar scale HRSs and with the 3Emotion project targets.
Integrated Battery and Hydrogen Energy Storage for Enhanced Grid Power Savings and Green Hydrogen Utilization
Aug 2024
Publication
This study explores the integration and optimization of battery energy storage systems (BESSs) and hydrogen energy storage systems (HESSs) within an energy management system (EMS) using Kangwon National University’s Samcheok campus as a case study. This research focuses on designing BESSs and HESSs with specific technical specifications such as energy capacities and power ratings and their integration into the EMS. By employing MATLAB-based simulations this study analyzes energy dynamics grid interactions and load management strategies under various operational scenarios. Real-time data from the campus are utilized to examine energy consumption renewable energy generation grid power fluctuations and pricing dynamics providing key insights for system optimization. This study finds that a BESS manages energy fluctuations between 0.5 kWh and 3.7 kWh over a 24 h period with battery power remaining close to 4 W for extended periods. Grid power fluctuates between −5 kW and 75 kW while grid prices range from 75 to 120 USD/kWh peaking at 111 USD/kWh. Hydrogen energy storage varies from 1 kWh to 8 kWh with hydrogen power ranging from −40 kW to 40 kW. Load management keeps power stable at around 35 kW and PV power integration peaks at 48 kW by the 10th h. The findings highlight that BESSs and HESSs effectively manage energy distribution and storage improving system efficiency reducing energy costs by approximately 15% and enhancing grid stability by 20%. This study underscores the potential of BESSs and HESSs in stabilizing grid operations and integrating renewable energy. Future directions include advancements in storage technologies enhanced EMS capabilities through artificial intelligence and machine learning and the development of smart grid infrastructures. Policy recommendations stress the importance of regulatory support and stakeholder collaboration to drive innovation and scale deployment ensuring a sustainable energy future.
China and Italy’s Energy Development Trajectories: Current Landscapes and Future Cooperation Potential
Feb 2024
Publication
In order to achieve the ambitious goal of “carbon neutrality” countries around the world are striving to develop clean energy. Against this background this paper takes China and Italy as representatives of developing and developed countries to summarize the energy structure composition and development overview of the two countries. The paper analyzes the serious challenges facing the future energy development of both countries and investigates the possibilities of energy cooperation between the two countries taking into account their respective advantages in energy development. By comparing the policies issued by the two governments to encourage clean energy development this paper analyzes the severe challenges faced by the two countries’ energy development in the future and combines their respective energy development advantages to look forward to the possibility of energy cooperation between the two countries in the future. This lays the foundation for China and Italy to build an “Energy Road” after the “Silk Road”.
Strategic Raw Material Requirements for Large-scale Hydrogen Production in Portugal and European Union
Nov 2024
Publication
Global attention is being given to hydrogen as it is seen as a versatile energy carrier and a flexible energy vector in transitioning to a low-carbon economy. Hydrogen production/storage/conveyance is metal intensive and it is crucial to understand if there is material availability to fulfil the committed plans. Using the material intensity of electrolysers pipelines and desalinators along with the projected Portuguese and European Union roadmaps we are able to identify possible bottlenecks in the supply chains. The availability of the vast majority of raw materials does not represent a threat to hydrogen technologies implementation with electrolysers requiring almost up to 3 Mt of raw materials and pipelines up to 2.5 Mt. The evident exception is iridium although representing less than 0.001 % of the material requirements it may hinder the widespread implementation of proton exchange membrane electrolysers. Desalinators have the least material footprint of the studied infrastructure.
Levelised Cost of Hydrogen Production in Northern Africa and Europe in 2050: A Monte Carlo Simulation for Germany, Norway, Spain, Algeria, Morocco, and Egypt
May 2024
Publication
The production of green hydrogen through electrolysis utilizing renewable energies is recognized as a pivotal element in the pursuit of decarbonization. In order to attain cost competitiveness for green hydrogen reasonable generation costs are imperative. To identify cost-effective import partners for Germany given its limited green hydrogen production capabilities this study undertakes an exhaustive techno-economic analysis to determine the potential Levelized Cost of Hydrogen in Germany Norway Spain Algeria Morocco and Egypt for the year 2050 which represents a critical milestone in European decarbonization efforts. Employing a stochastic approach with Monte Carlo simulations the paper marks a significant contribution for projecting future cost ranges acknowledging the multitude of uncertainties inherent in related cost parameters and emphasizing the importance of randomness in these assessments. Country-specific Weighted Average Cost of Capital are calculated in order to create a refined understanding of political and economic influences on cost formation rather than using a uniform value across all investigated nations. Key findings reveal that among the evaluated nations PV-based hydrogen emerges as the most cost-efficient alternative in all countries except Norway with Spain presenting the lowest Levelized Cost of Hydrogen at 1.66 €/kg to 3.12 €/kg followed by Algeria (1.72 €/kg to 3.23 €/kg) and Morocco (1.73 €/kg to 3.28 €/kg). Consequently for economically favorable import options Germany is advised to prioritize PV-based hydrogen imports from these countries. Additionally hydrogen derived from onshore wind in Norway (2.24 €/kg to 3.73 €/kg) offers a feasible import alternative. To ensure supply chain diversity and reduce dependency on a single source a mixed import strategy is advisable. Despite having the lowest electricity cost Egypt shows the highest Levelized Cost of Hydrogen primarily due to a significant Weighted Average Cost of Capital.
Techno-economic Assessment of Liquid Carrier Methods for Intercontinental Shipping of Hydrogen: A Case Study
Nov 2024
Publication
As global economies seek to transition to low-carbon energy systems to achieve net zero targets hydrogen has potential to play a key role to decarbonise sectors that are unsuited to electrification or where long-term energy storage is required. Hydrogen can also assist in enabling decentralized renewable power generation to satisfy higher electricity demand to match the scale-up of electrified technologies. In this context suitable transport storage and distribution networks will be essential to connect hydrogen generation and utilisation sites. This paper presents a techno-economic impact evaluation of international marine hydrogen transportation between Canada and the Netherlands comparing liquid hydrogen ammonia and a dibenzyl toluene liquid organic hydrogen carrier (LOHC) as potential transport vectors. Economic costs energy consumption and losses in each phase of the transportation system were analysed for each vector. Based on the devised scenarios our model suggests levelised costs of hydrogen of 6.35–9.49 $2022/kgH2 and pathway efficiencies of 55.6–71.9%. While liquid hydrogen was identified as the most cost-competitive carrier sensitivity analysis revealed a merit order for system optimisation strategies based upon which LOHC could outperform both liquid hydrogen and ammonia in the future.
Technical–Economic Analysis of Renewable Hydrogen Production from Solar Photovoltaic and Hydro Synergy in a Pilot Plant in Brazil
Sep 2024
Publication
Renewable hydrogen obtained from renewable energy sources especially when produced through water electrolysis is gaining attention as a promising energy vector to deal with the challenges of climate change and the intermittent nature of renewable energy sources. In this context this work analyzes a pilot plant that uses this technology installed in the Itumbiara Hydropower Plant located between the states of Goiás and Minas Gerais Brazil from technical and economic perspectives. The plant utilizes an alkaline electrolyzer synergistically powered by solar photovoltaic and hydro sources. Cost data for 2019 when the equipment was purchased and 2020–2023 when the plant began continuous operation are considered. The economic analysis includes annualized capital maintenance and variable costs which determines the levelized cost of hydrogen (LCOH). The results obtained for the pilot plant’s LCOH were USD 13.00 per kilogram of H2 with an efficiency loss of 2.65% for the two-year period. Sensitivity analysis identified the capacity factor (CF) as the main determinant of the LCOH. Even though the analysis specifically applies to the Itumbiara Hydropower Plant the CF can be extrapolated to larger plants as it directly influences hydrogen production regardless of plant size or capacity
Optimal Integration of Hybrid Renewable Energy Systems for Decarbonized Urban Electrification and Hydrogen Mobility
Aug 2024
Publication
This study addresses cost-optimal sizing and energy management of a grid-integrated solar photovoltaic wind turbine hybrid renewable energy system integrated with electrolyzer and hydrogen storage tank to simultaneously meet electricity and hydrogen demands considering the case study of Dijon France. Mixed Integer Linear Programming optimization problem is formulated to evaluate two objective case scenarios: single objective and multi-objective minimizing total annual costs and grid carbon emission footprint. The study incorporates various technical economic and environmental indicators focusing on the impact of sensitivity lying on various grid electricity purchase rates within the French electricity market prices. The results highlight that rising grid prices drive increased integration of renewable sources while lower prices favor ultimate grid dependency. Constant hydrogen demand necessitates the installation of two electrolyzers. Notably grid electricity prices above 60 e/MWh result increase in the size of the hydrogen tank and electrolyzer operation to prevent renewable energy losses. Grid prices above 140 e/MWh depict 70% of electrical and 80% of electrolyzer demand provided by the renewable generation resulting in a carbon emission below 0.0416 Mt of CO2 and 0.643 kgCO2 /kgH2 . Conversely grid prices below 20 e/MWh lead ultimately to 100% grid dependency with a higher carbon emission of approximately 0.14 Mt of CO2 and 4.13 kgCO2 /kgH2 reducing the total annual cost to 41.63 Million e. Increase in grid prices from 20e/MWh to 180 e/MWh resulted in increase of hydrogen specific costs from 1.23 to 3.58 e/kgH2 . Finally the Pareto front diagram is employed to illustrate the trade-off between total annual cost and carbon emission due to grid imports aiding in informed decision-making.
Solar-driven, Highly Sustained Splitting of Seawater into Hydrogen and Oxygen Fuels
Mar 2019
Publication
Electrolysis of water to generate hydrogen fuel is an attractiverenewable energy storage technology. However grid-scale fresh-water electrolysis would put a heavy strain on vital water re-sources. Developing cheap electrocatalysts and electrodes that cansustain seawater splitting without chloride corrosion could ad-dress the water scarcity issue. Here we present a multilayer anodeconsisting of a nickel–iron hydroxide (NiFe) electrocatalyst layeruniformly coated on a nickel sulfide (NiSx) layer formed on porousNi foam (NiFe/NiSx-Ni) affording superior catalytic activity andcorrosion resistance in solar-driven alkaline seawater electrolysisoperating at industrially required current densities (0.4 to 1 A/cm2)over 1000 h. A continuous highly oxygen evolution reaction-active NiFe electrocatalyst layer drawing anodic currents towardwater oxidation and an in situ-generated polyatomic sulfate andcarbonate-rich passivating layers formed in the anode are respon-sible for chloride repelling and superior corrosion resistance of thesalty-water-splitting anode.
Advancing the Affordable and Clean Energy in Large Energy-consuming Economies: The Role of Green Transition, Complexity-based, and Geostrategy Policy
Aug 2023
Publication
With decreasing costs of the clean technologies the balanced scales of the Sustainable Development Goal 7 targets e.g. energy equity (EE) energy security (ES) and environmental sustainability (EVS) are quickly changing. This fundamental balancing process is a key requirement for a net-zero future. Accordingly this research analyzes the regime-switching effect of Hydrogen economy as the green transition sharing economy and economic complexity as the complexity-based and geopolitical risks and energy prices as the geostrategy policies on the Goal 7 targets. To this end a Markov-switching panel vector autoregressive method with regime-heteroskedasticity is applied to study advancing the Goal 7 in the world's twenty-five large energy consumers during 2004–2020. Concerning the parameters and statistics of the model the results refer to the existence of two regimes associated with the Goal 7 corners called “upward and downward” regimes for EE and “slightly upward and sharply upward” regimes for ES and EVS. It is revealed that the vulnerability of EE and ES targets is considerably reduced when the regime switches to the dominant regime that is “downward” and “slightly upward” regimes respectively and that of the EVS target remains unaffected. Through the impulse-response analysis the findings denote that the first hypothesis of the efficiency of the Hydrogen economy in promoting the Goal 7 targets is insignificant. However the significant short-term and dynamic shock effects of the complexity-based and geostrategy policies on the Hydrogen economy are detected which will be a feasible alternative assessment in advancing the Goal 7. Further the complexity-based policies support the Goal 7 targets under different regimes especially in the short- and medium-term. Hence the second hypothesis regarding the effectiveness of the complexity-based policies in promoting Goal 7 targets is confirmed. The third hypothesis concerning the complexity of the impact of geostrategy policies on the Goal 7 targets is verified. Particularly the switching process towards the Goal 7 may not necessarily be restricted by the geopolitical risks. Moreover EE is supported through energy prices in the short-term under both regimes while they are non-conductive to promote ES and EVS through time. Accordingly the decision-makers should acknowledge adopting a regime-switching path forward for ensuring the time-varying balanced growth of the Goal 7 targets as the impact of the suggested policy instruments is asymmetric.
Research on the Optimal Scheduling Strategy of the Integrated Energy System of Electricity to Hydrogen under the Stepped Carbon Trading Mechanism
Sep 2024
Publication
Under the guidance of energy-saving and emission reduction goals a lowcarbon economic operation method for integrated energy systems (IES) has been proposed. This strategy aims to enhance energy utilization efficiency bolster equipment operational flexibility and significantly cut down on carbon emissions from the IES. Firstly a thorough exploration of the two-stage operational framework of Power-to-Gas (P2G) technology is conducted. Electrolyzers methane reactors and hydrogen fuel cells (HFCs) are introduced as replacements for traditional P2G equipment with the objective of harnessing the multiple benefits of hydrogen energy. Secondly a cogeneration and HFC operational strategy with adjustable heat-to-electricity ratio is introduced to further enhance the IES’s low-carbon and economic performance. Finally a step-by-step carbon trading mechanism is introduced to effectively steer the IES towards carbon emission control.
Power Converters for Green Hydrogen: State of the Art and Perspectives
Nov 2024
Publication
This paper provides a comprehensive review and outlook on power converters devised for supplying polymer electrolyte membrane (PEM) electrolyzers from photovoltaic sources. The produced hydrogen known as green hydrogen is a promising solution to mitigate the dependence on fossil fuels. The main topologies of power conversion systems are discussed and classified; a loss analysis emphasizes the issues concerning the electrolyzer supply. The attention is focused on power converters of rated power up to a tenth of a kW since it is a promising field for a short-term solution implementing green hydrogen production as a decentralized. It is also encouraged by the proliferation of relatively cheap photovoltaic low-power plants. The main converters proposed by the literature in the last few years and realized for practical applications are analyzed highlighting their key characteristics and focusing on the parameters useful for designers. Future perspectives are addressed concerning the availability of new wide-bandgap devices and hard-to-abate sectors with reference to the whole conversion chain.
The Impact of Impurity Gases on the Hydrogen Embrittlement Behavior of Pipeline Steel in High-Pressure H2 Environments
May 2024
Publication
The use of hydrogen-blended natural gas presents an efficacious pathway toward the rapid large-scale implementation of hydrogen energy with pipeline transportation being the principal method of conveyance. However pipeline materials are susceptible to hydrogen embrittlement in high-pressure hydrogen environments. Natural gas contains various impurity gases that can either exacerbate or mitigate sensitivity to hydrogen embrittlement. In this study we analyzed the mechanisms through which multiple impurity gases could affect the hydrogen embrittlement behavior of pipeline steel. We examined the effects of O2 and CO2 on the hydrogen embrittlement behavior of L360 pipeline steel through a series of fatigue crack growth tests conducted in various environments. We analyzed the fracture surfaces and assessed the fracture mechanisms involved. We discovered that CO2 promoted the hydrogen embrittlement of the material whereas O2 inhibited it. O2 mitigated the enhancing effect of CO2 when both gases were mixed with hydrogen. As the fatigue crack growth rate increased the influence of impurity gases on the hydrogen embrittlement of the material diminished.
Modelling and Simulation of an Integrated Coupled Reactor for Hydrogen Production and Carbon Dioxide Utilisation in an Integrated Fuel Cell Power System
Dec 2024
Publication
In today’s world the need for sustainable energy solutions is paramount to address the ongoing crisis of increasing greenhouse gas emissions and global warming. Industries heavily reliant on fossil fuels must explore alternative energy sources. Hydrogen with its high heating value and zero direct emissions has emerged as a promising fuel for the future. Electrolytic hydrogen production has gained significance as it enables demand-side response grid stabilization using excess energy and the mitigation of curtailment from intermittent renewable energy sources (RES) such as solar and wind. Advanced combined heat and power (CHP) systems comprise of Solid oxide fuel cell (SOFC) module and a coupled reforming reactor to capture energy contained in the SOFC exhaust gases from SOFC. In present work 3D CFD model of an experimental coupled reactor used for onsite hydrogen production is developed and implemented into ANSYS Fluent® software. The study is aimed at opti mizing the reactor performance by identifying appropriate kinetic models for reforming and combustion re actions. SOFC anode off-gas (AOG) comprising mainly of unconverted hydrogen is combined with methane combustion to enhance thermal efficiency of the reactor and hence the CHP system. Kinetic models for catalytic reforming and combustion are implemented into ANSYS Fluent® through custom-built user defined functions (UDFs) written in C programming language. Simulation results are validated with experimental data and found in good agreement. AOG assisted combustion of methane shows a substantial improvement in thermal efficiency of the system. Improvement in thermal efficiency and reduction in carbon-based fuel demand AOG utilization contributes to sustainable hydrogen production and curtailment of greenhouse gas emissions.
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