Publications

Fuel cells (FCs) and hydrogen technologies are emerging renewable energy sources with promising results when applied to wastewater treatment (WWT). These devices serve not only for power generation but some specific FCs can be employed for degradation of pollutants and synthesis of intermediates needed in WWT. Microbial FCs are potent devices for WWT even containing refractory pollutants. Despite being a nascent technology with high capital expenses the use of cost-effective materials reduction of operational cost and increased generation of energy and value-added chemicals such as hydrogen will facilitate the market penetration through selected niches and hybridization with alternative WWT technologies.

Technological change is often seen as part of the solution to problems of global sustainability. A wide-ranging literature on how path dependent—often fossil fuel-based—socio-technical configurations can be overcome by more sustainable configurations has emerged over the last two decades. One potential transition pathway to transform electricity heat and mobility systems as well as industrial production is the use of hydrogen. In recent years hydrogen has received increasing attention as part of decarbonisation strategies in many countries as well as by international organisations such as the International Energy Agency or the International Renewable Energy Agency. Also in Germany it has become a central component of climate change policy and is seen by some actors almost as a kind of panacea where the use of hydrogen is expected to decarbonise a wide range of sectors. Policy makers have the ambition for Germany to become a leader in hydrogen development and therefore help to contribute to what Grubler called ‘grand patterns of technological change’. The aim of this paper is to analyse whether relevant actors share expectations for transition pathways based on hydrogen which would foster wide diffusion. Our empirical analysis shows that there are multiple contested pathways both in terms of how hydrogen is produced as well as in which applications or sectors it is to be used. This causes uncertainty and slows down hydrogen developments in Germany. We contribute to an emerging literature on the politics of contested transition pathways and also critically engage with Grubler’s ‘grand patterns’ argument. Results support the idea that the concept of socio-technical pathways allows to expose tensions between competing values and interests. The German government is under considerable pressure regarding competing visions on hydrogen transition pathways. A targeted political prioritisation of hydrogen applications could mitigate tensions and support a shared vision.

This paper proposes a systematic optimization framework to jointly determine the optimal location and sizing decisions of renewables and hydrogen storage in a power network to achieve the transition to low-carbon networks efficiently. We obtain these strategic decisions based on the multi-period alternating current optimal power flow (AC MOPF) problem that jointly analyzes power network renewable and hydrogen storage interactions at the operational level by considering the uncertainty of renewable output seasonality of electricity demand and electricity prices. We develop a tailored solution approach based on second-order cone programming within a Benders decomposition framework to provide globally optimal solutions. In a test case we show that the joint integration of renewable sources and hydrogen storage and consideration of the AC MOPF model significantly reduces the operational cost of the power network. In turn our findings can provide quantitative insights to decision-makers on how to integrate renewable sources and hydrogen storage under different settings of the hydrogen selling price renewable curtailment cost emission tax price and conversion efficiency.

To reduce carbon dioxide emissions from the steel industry efforts are made to introduce a steelmaking route based on hydrogen reduction of iron ore instead of the commonly used cokebased reduction in a blast furnace. Changing fundamental pieces of steelworks affects the functions of most every system unit involved and thus warrants the question of how such a transition could optimally take place over time and no rigorous attempts have until now been made to tackle this problem mathematically. This article presents a steel plant optimization model written as a mixed-integer non-linear programming problem where aging blast furnaces and basic oxygen furnaces could potentially be replaced with shaft furnaces and electric arc furnaces minimizing costs or emissions over a long-term time horizon to identify possible transition pathways. Example cases show how various parameters affect optimal investment pathways stressing the necessity of appropriate planning tools for analyzing diverse cases.

A proton exchange membrane electrolyzer can effectively utilize the electricity generated by intermittent solar power. Different methods of generating electricity may have different efficiencies and hydrogen production rates. Two coupled systems namely PV/T- and CPV/T-coupling PEMEC respectively are presented and compared in this study. A maximum power point tracking algorithm for the photovoltaic system is employed and simulations are conducted based on the solar irradiation intensity and ambient temperature of a specific location on a particular day. The simulation results indicate that the hydrogen production is relatively high between 11:00 and 16:00 with a peak between 12:00 and 13:00. The maximum hydrogen production rate is 99.11 g/s and 29.02 g/s for the CPV/T-PEM and PV/T-PEM systems. The maximum energy efficiency of hydrogen production in CPV/T-PEM and PV/T-PEM systems is 66.7% and 70.6%. Under conditions of high solar irradiation intensity and ambient temperature the system demonstrates higher total efficiency and greater hydrogen production. The CPV/T-PEM system achieves a maximum hydrogen production rate of 2240.41 kg/d with a standard coal saving rate of 15.5 tons/day and a CO2 reduction rate of 38.0 tons/day. Compared to the PV/T-PEM system the CPV/T-PEM system exhibits a higher hydrogen production rate. These findings provide valuable insights into the engineering application of photovoltaic/thermal-coupled hydrogen production technology and contribute to the advancement of this field.

Global warming’s major cause is the emission of greenhouse-effect gases (GHG) especially carbon dioxide (CO2) whose main source is the combustion of fossil fuels. Fossil fuels serve as the primary energy source in many industries including shipping which is the focus of this study. One of the measures proposed to tackle GHG emissions is the development of green shipping corridors - carbon-free shipping routes that require the transition to alternative fuels which are gaining competitiveness. One of the reasons for that is carbon pricing which taxes CO2 emissions. However the lack of consensus on the most cost-advantageous alternative fuel in the long run results in the delay of the implementation of green shipping corridors. To make it more accessible for stakeholders to conduct an economic analysis of the various options a framework to determine and minimize the costs of transitioning from fossil fuels to any alternative fuel is proposed over the period of one voyage considering the lost opportunity cost the deployment cost of bunkering vessels at the necessary call ports the cost of converting the vessel the car-bon emissions tax cost and the fuel cost. This will allow stakeholders to choose the most economical alternative fuel accelerating the development of green shipping corridor initiatives. To validate the effectiveness of the framework it was applied in a case study involving a shipowner seeking to transition from heavy fuel oil (HFO) to Ammonia Hydrogen Liquefied Natural Gas (LNG) or Methanol. This study faced limitations due to the unknown costs of installing bunkering vessels for Ammonia and Hydrogen. However it evaluates the cost-effectiveness of alternative fuels providing insights into their short-term economic viability. The results showed that Hydrogen is the most costadvantageous fuel until a deployment cost per bunkering vessel of 1990285$ for a sailing speed of 22 knots and 2190171$ for a sailing speed of 18 knots is reached after which LNG becomes the most economical option regardless of variations in the carbon tax. Moreover a sensitivity analysis was conducted to determine the effects of variations in parameters such as carbon tax fuel prices and vessel conversion costs in the total cost of each fuel option. Results highlighted that even though HFO remains the most economical fuel option even when considering a high increase in carbon tax the cost gap between HFO and alternative fuels narrows significantly with the increase in carbon tax. Furthermore the sailing speed impacts the fuels’ competitiveness as the cost difference between HFO and alternative fuels decreases at higher speeds.

Nanomaterials have attracted great interest in recent years because of the unusual mechanical electrical electronic opticalmagnetic and surface properties. The high surface/volume ratio of these materials has significant implications with respectto energy storage. Both the high surface area and the opportunity for nanomaterial consolidation are key attributes of thisnew class of materials for hydrogen storage devices. Nanostructured systems including carbon nanotubes nano-magnesiumbased hydrides complex hydride/carbon nanocomposites boron nitride nanotubes TiS2/MoS2 nanotubes alanates polymernanocomposites and metal organic frameworks are considered to be potential candidates for storing large quantities of hydrogen.Recent investigations have shown that nanoscale materials may offer advantages if certain physical and chemical effects related tothe nanoscale can be used efficiently. The present review focuses the application of nanostructured materials for storing atomicor molecular hydrogen. The synergistic effects of nanocrystalinity and nanocatalyst doping on the metal or complex hydrides forimproving the thermodynamics and hydrogen reaction kinetics are discussed. In addition various carbonaceous nanomaterialsand novel sorbent systems (e.g. carbon nanotubes fullerenes nanofibers polyaniline nanospheres and metal organic frameworksetc.) and their hydrogen storage characteristics are outlined.

Hydrogen has a key role to play in decarbonising industry and other sectors of society. It is important to develop low-carbon hydrogen production technologies that are cost-effective and energy-efficient. Sorption-enhanced steam methane reforming (SE-SMR) is a developing low-carbon (blue) hydrogen production process which enables combined hydrogen production and carbon capture. Despite a number of key benefits the process is yet to be fully realised in terms of efficiency. In this work a sorption-enhanced steam methane reforming process has been intensified via exergy analysis. Assessing the exergy efficiency of these processes is key to ensuring the effective deployment of low-carbon hydrogen production technologies. An exergy analysis was performed on an SE-SMR process and was then subsequently used to incorporate process improvements developing a process that has theoretically an extremely high CO2 capture rate of nearly 100 % whilst simultaneously demonstrating a high exergy efficiency (77.58 %) showcasing the potential of blue hydrogen as an effective tool to ensure decarbonisation in an energy-efficient manner.

Combining electrolytic hydrogen production with wind–photovoltaic power can effectively smooth the fluctuation of power and enhance the schedulable wind–photovoltaic power which provides an effective solution to solve the problem of wind–photovoltaic power accommodation. In this paper the optimization operation strategy is studied for the wind–photovoltaic power-based hydrogen production system. Firstly to make up for the deficiency of the existing research on the multi-state and nonlinear characteristics of electrolyzers the three-state and power-current nonlinear characteristics of the electrolyzer cell are modeled. The model reflects the difference between the cold and hot starting time of the electrolyzer and the linear decoupling model is easy to apply in the optimization model. On this basis considering the operation constraints of the electrolyzer hydrogen storage tank battery and other equipment the optimization operation model of the wind–photovoltaic power-based hydrogen production system is developed based on the typical scenario approach. It also considers the cold and hot starting time of the electrolyzer with the daily operation cost as the goal. The results show that the operational benefits of the system can be improved through the proposed strategy. The hydrogen storage tank capacity will have an impact on the operation income of the wind–solar hydrogen coupling system and the daily operation income will increase by 0.32% for every 10% (300 kg) increase in the hydrogen storage tank capacity.

This study reviews existing simulation models and describes a selected model for analysing combustion dynamics in hydrogen and natural gas mixtures specifically within non-ferrous melting furnaces. The primary objectives are to compare the combustion characteristics of these two energy carriers and assess the impact of hydrogen integration on furnace operation and efficiency. Using computational fluid dynamics (CFD) simulations incorporating actual furnace geometries and a detailed combustion and NOx emission prediction model this research aims to accurately quantify the effects of hydrogen blending. Experimental tests on furnaces using only natural gas confirmed the validity of these simulations. By providing precise predictions for temperature distribution and NOx emissions this approach reduces the need for extensive laboratory testing facilitates broader exploration of design modifications accelerates the design process and ultimately lowers product development costs.