United States
Effects of Surface Modification on a Proton Exchange Membrane for Improvements in Green Hydrogen Production
Oct 2023
Publication
Proton Exchange Membrane (PEM) electrolysis an advanced technique for producing hydrogen with efficiency and environmental friendliness signifies the forefront of progress in this domain. Compared to alkaline cells these electrolytic cells offer numerous advantages such as lower operating temperatures enhanced hydrogen production efficiency and eliminating the need for an aqueous solution. However PEM electrolysis still faces limitations due to the high cost of materials used for the membrane and catalysts resulting in elevated expenses for implementing large-scale systems. The pivotal factor in improving PEM electrolysis lies in the Platinum catalyst present on the membrane surface. Enhancing catalytic efficiency through various methods and advancements holds immense significance for the progress of this technology. This study investigates the use of patterned membranes to improve the performance of PEM electrolytic cells toward green hydrogen production. By increasing the Platinum loading across the membrane surface and enhancing catalytic performance these patterned membranes overcome challenges faced by conventionally fabricated counterparts. The findings of this research indicate that membranes with modified surfaces not only exhibit higher current draw but also achieve elevated rates of hydrogen production.
Underground Storage of Hydrogen and Hydrogen/methane Mixtures in Porous Reservoirs: Influence of Reservoir Factors and Engineering Choices on Deliverability and Storage Operations
Jul 2023
Publication
Seasonal storage of natural gas (NG) which primarily consists of methane (CH4) has been practiced for more than a hundred years at underground gas storage (UGS) facilities that use depleted hydrocarbon reservoirs saline aquifers and salt caverns. To support a transition to a hydrogen (H2) economy similar facilities are envisioned for long-duration underground H2 storage (UHS) of either H2 or H2/CH4 mixtures. Experience with UGS can be used to guide the deployment of UHS so we identify and quantify factors (formation/fluid properties and engineering choices) that influence reservoir behavior (e.g. viscous fingering and gravity override) the required number of injection/withdrawal wells and required storage volume contrasting the differences between the storage of CH4 H2 and H2/CH4 mixtures. The most important engineering choices are found to be the H2 fraction in H2/CH4 mixtures storage depth and injection rate. Storage at greater depths (higher pressure) but with relatively lower temperature is more favorable because it maximizes volumetric energy-storage density while minimizing viscous fingering and gravity override due to buoyancy. To store an equivalent amount of energy storing H2/CH4 mixtures in UHS facilities will require more wells and greater reservoir volume than corresponding UGS facilities. We use our findings to make recommendations about further research needed to guide deployment of UHS in porous reservoirs.
Multiperiod Modeling and Optimization of Hydrogen-Based Dense Energy Carrier Supply Chains
Feb 2024
Publication
The production of hydrogen-based dense energy carriers (DECs) has been proposed as a combined solution for the storage and dispatch of power generated through intermittent renewables. Frameworks that model and optimize the production storage and dispatch of generated energy are important for data-driven decision making in the energy systems space. The proposed multiperiod framework considers the evolution of technology costs under different levels of promotion through research and targeted policies using the year 2021 as a baseline. Furthermore carbon credits are included as proposed by the 45Q tax amendment for the capture sequestration and utilization of carbon. The implementation of the mixed-integer linear programming (MILP) framework is illustrated through computational case studies to meet set hydrogen demands. The trade-offs between different technology pathways and contributions to system expenditure are elucidated and promising configurations and technology niches are identified. It is found that while carbon credits can subsidize carbon capture utilization and sequestration (CCUS) pathways substantial reductions in the cost of novel processes are needed to compete with extant technology pathways. Further research and policy push can reduce the levelized cost of hydrogen (LCOH) by upwards of 2 USD/kg.
Renewable Energy Sources for Green Hydrogen Generation in Colombia and Applicable Case of Studies
Nov 2023
Publication
Electrification using renewable energy sources represents a clear path toward solving the current global energy crisis. In Colombia this challenge also involves the diversification of the electrical energy sources to overcome the historical dependence on hydropower. In this context green hydrogen represents a key energy carrier enabling the storage of renewable energy as well as directly powering industrial and transportation sectors. This work explores the realistic potential of the main renewable energy sources including solar photovoltaics (8172 GW) hydropower (56 GW) wind (68 GW) and biomass (14 GW). In addition a case study from abroad is presented demonstrating the feasibility of using each type of renewable energy to generate green hydrogen in the country. At the end an analysis of the most likely regions in the country and paths to deploy green hydrogen projects are presented favoring hydropower in the short term and solar in the long run. By 2050 this energy potential will enable reaching a levelized cost of hydrogen (LCOH) of 1.7 1.5 3.1 and 1.4 USD/kg-H2 for solar photovoltaic wind hydropower and biomass respectively.
Exploratory Numerical Study of Liquid Hydrogen Hazards
Sep 2023
Publication
Hydrogen is one of a handful of new low carbon solutions that will be critical for the transition to net zero. The upscaling of production and applications entails that hydrogen is likely to be stored in liquid phase (LH2) at cryogenic conditions to increase its energy density. Widespread LH2 use as an alternative fuel will require significant infrastructure upgrades to accommodate increased bulk transport storage and delivery. However current LH2 bulk storage separation distances are based on subjective expert recommendations rather than experimental observations or physical models. Experimental studies of large-scale LH2 release are challenging and costly. The existing large-scale tests are scarce and numerical studies are a viable option to investigate the existing knowledge gaps. Controlled or accidental releases of LH2 for hydrogen refueling infrastructure would result in high momentum two-phase jets or formation of liquid pools depending on release conditions. Both release scenarios lead to a flammable/explosive cloud posing a safety issue to the public.<br/>The manuscript reports exploratory study to numerically determine the safety zone resulting from cryogenic hydrogen releases related to LH2 storage and refueling using the in-house HyFOAM solver further modified for gaseous hydrogen releases at cryogenic conditions and the subsequent atmospheric dispersion and ignition within the platform of OpenFOAM V8.0. The current version of the solver neglects the flashing process by assuming that the temperature of the stored LH2 is equal to the boiling point at the atmospheric condition. Numerical simulations of dispersion and subsequent ignition of LH2 release scenarios with respect to different release orientations release rates release temperatures and weather conditions were performed. Both hydrogen concentration and temperature fields were predicted and the boundary of zones within the flammability limit was also defined. The study also considered the sensitivities of the consequences to the release orientation wind speed ambient temperature and release content etc. The effect of different barrier walls on the deflagration were also evaluated by changing the height and location.
Artificial Intelligence/Machine Learning in Energy Management Systems, Control, and Optimization of Hydrogen Fuel Cell Vehicles
Mar 2023
Publication
Environmental emissions global warming and energy-related concerns have accelerated the advancements in conventional vehicles that primarily use internal combustion engines. Among the existing technologies hydrogen fuel cell electric vehicles and fuel cell hybrid electric vehicles may have minimal contributions to greenhouse gas emissions and thus are the prime choices for environmental concerns. However energy management in fuel cell electric vehicles and fuel cell hybrid electric vehicles is a major challenge. Appropriate control strategies should be used for effective energy management in these vehicles. On the other hand there has been significant progress in artificial intelligence machine learning and designing data-driven intelligent controllers. These techniques have found much attention within the community and state-of-the-art energy management technologies have been developed based on them. This manuscript reviews the application of machine learning and intelligent controllers for prediction control energy management and vehicle to everything (V2X) in hydrogen fuel cell vehicles. The effectiveness of data-driven control and optimization systems are investigated to evolve classify and compare and future trends and directions for sustainability are discussed.
Assessment of a Coupled Electricity and Hydrogen Sector in the Texas Energy System in 2050
Oct 2024
Publication
Due to its ability to reduce emissions in the hard-to-abate sectors hydrogen is expected to play a significant role in future energy systems. This study modifies a sector-coupled dynamic modeling framework for electricity and hydrogen by including policy constraints carbon prices and possible hydrogen pathways and applies it to Texas in 2050. The impact of financial policies including the US clean hydrogen production tax credit on required infrastructure and costs are explored. Due to low natural gas prices financial levers are necessary to promote low-carbon hydrogen production as the optimized solution. The Levelized Costs of Hydrogen are found to be $1.50/kg in the base case (primarily via steam methane reformation production) and lie between $2.10 - 3.10/kg when production is via renewable electrolysis. The supporting infrastructure required to supply those volumes of renewable hydrogen is immense. The hydrogen tax credit was found to be enough to drive production via electrolysis.
Hydrogen Station Prognostics and Health Monitoring Model
Aug 2023
Publication
Hydrogen fuel has shown promise as a clean alternative fuel aiding in the reduction of fossil fuel dependence within the transportation sector. However hydrogen refueling stations and infrastructure remains a barrier and are a prerequisite for consumer adoption of low-cost and low-emission fuel cell electric vehicles (FCEVs). The costs for FCEV fueling include both station capital costs and operation and maintenance (O&M) costs. Contributing to these O&M costs unscheduled maintenance is presently more costly and more frequent than for similar gasoline fueling infrastructure and is asserted to be a limiting factor in achieving FCEV customer acceptance and cost parity. Unscheduled maintenance leads to longer station downtime therefore causing an increase in missed fueling opportunities which forces customers to seek refueling at other operable stations that may be significantly farther away. This research proposes a framework for a hydrogen station prognostics health monitoring (H2S PHM) model that can minimize unexpected downtime by predicting the remaining useful life for primary hydrogen station components within the major station subsystems. The H2S PHM model is a data-driven statistical model based on O&M data collected from 34 retail hydrogen stations located in the U.S. The primary subcomponents studied are the dispenser compressor and chiller. The remaining useful life calculations are used to decide whether or not maintenance should be completed based on the prediction and expected future station use. This paper presents the background method and results for the H2S PHM model as for a means for improving station availability and customer confidence in FCEVs and hydrogen infrastructure
Risk Sensitivity Study as the Basis for Risk-informed Consequence-based Setback Distances for Liquid Hydrogen Storage Systems
Sep 2023
Publication
A quantitative risk assessment on a representative liquid hydrogen storage system was performed to identify the main drivers of individual risk and provide a technical basis for revised separation distances for bulk liquid hydrogen storage systems in regulations codes and standards requirements. The framework in the Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) toolkit was used and multiple relevant inputs to the risk assessment (e.g. system pipe size ignition probabilities) were individually varied. For each set of risk assessment inputs the individual risk as a function of the distance away from the release point was determined and the risk-based separation distance was determined from an acceptable risk criterion. These risk-based distances were then converted to equivalent leak size using consequence models that would result in the same distance to selected hazard criteria (i.e. extent of flammable cloud heat flux and peak overpressure). The leak sizes were normalized to a fraction of the flow area of the source piping. The resulting equivalent fractional hole sizes for each sensitivity case were then used to inform selection of a conservative fractional flow area leak size of 5% that serves as the basis for consequence-based separation distance calculations. This work demonstrates a method for using a quantitative risk assessment sensitivity study to inform the selection of a basis for determining consequence-based separation distances.
Hydrogen Liquefaction: A Review of the Fundamental Physics, Engineering Practice and Future Opportunities
Apr 2022
Publication
Hydrogen is emerging as one of the most promising energy carriers for a decarbonised global energy system. Transportation and storage of hydrogen are critical to its large-scale adoption and to these ends liquid hydrogen is being widely considered. The liquefaction and storage processes must however be both safe and efficient for liquid hydrogen to be viable as an energy carrier. Identifying the most promising liquefaction processes and associated transport and storage technologies is therefore crucial; these need to be considered in terms of a range of interconnected parameters ranging from energy consumption and appropriate materials usage to considerations of unique liquid-hydrogen physics (in the form of ortho–para hydrogen conversion) and boil-off gas handling. This study presents the current state of liquid hydrogen technology across the entire value chain whilst detailing both the relevant underpinning science (e.g. the quantum behaviour of hydrogen at cryogenic temperatures) and current liquefaction process routes including relevant unit operation design and efficiency. Cognisant of the challenges associated with a projected hydrogen liquefaction plant capacity scale-up from the current 32 tonnes per day to greater than 100 tonnes per day to meet projected hydrogen demand this study also reflects on the next-generation of liquid-hydrogen technologies and the scientific research and development priorities needed to enable them.
A Comparative Analysis of Different Hydrogen Production Methods and Their Environmental Impact
Nov 2023
Publication
This study emphasises the growing relevance of hydrogen as a green energy source in meeting the growing need for sustainable energy solutions. It foregrounds the importance of assessing the environmental consequences of hydrogen-generating processes for their long-term viability. The article compares several hydrogen production processes in terms of scalability costeffectiveness and technical improvements. It also investigates the environmental effects of each approach considering crucial elements such as greenhouse gas emissions water use land needs and waste creation. Different industrial techniques have distinct environmental consequences. While steam methane reforming is cost-effective and has a high production capacity it is coupled with large carbon emissions. Electrolysis a technology that uses renewable resources is appealing but requires a lot of energy. Thermochemical and biomass gasification processes show promise for long-term hydrogen generation but further technological advancement is required. The research investigates techniques for improving the environmental friendliness of hydrogen generation through the use of renewable energy sources. Its ultimate purpose is to offer readers a thorough awareness of the environmental effects of various hydrogen generation strategies allowing them to make educated judgements about ecologically friendly ways. It can ease the transition to a cleaner hydrogen-powered economy by considering both technological feasibility and environmental issues enabling a more ecologically conscious and climate-friendly energy landscape.
Innovative Strategies for Combining Solar and Wind Energy with Green Hydrogen Systems
Oct 2024
Publication
The integration of wind and solar energy with green hydrogen technologies represents an innovative approach toward achieving sustainable energy solutions. This review examines state-ofthe-art strategies for synthesizing renewable energy sources aimed at improving the efficiency of hydrogen (H2 ) generation storage and utilization. The complementary characteristics of solar and wind energy where solar power typically peaks during daylight hours while wind energy becomes more accessible at night or during overcast conditions facilitate more reliable and stable hydrogen production. Quantitatively hybrid systems can realize a reduction in the levelized cost of hydrogen (LCOH) ranging from EUR 3.5 to EUR 8.9 per kilogram thereby maximizing the use of renewable resources but also minimizing the overall H2 production and infrastructure costs. Furthermore advancements such as enhanced electrolysis technologies with overall efficiencies rising from 6% in 2008 to over 20% in the near future illustrate significant progress in this domain. The review also addresses operational challenges including intermittency and scalability and introduces system topologies that enhance both efficiency and performance. However it is essential to consider these challenges carefully because they can significantly impact the overall effectiveness of hydrogen production systems. By providing a comprehensive assessment of these hybrid systems (which are gaining traction) this study highlights their potential to address the increasing global energy demands. However it also aims to support the transition toward a carbon-neutral future. This potential is significant because it aligns with both environmental goals and energy requirements. Although challenges remain the promise of these systems is evident.
Methodology for Consequence-based Setback Distance Calculations for Bulk Liquid Hydrogen Storage Systems
Sep 2023
Publication
Updates to the separation distances between different exposures and bulk liquid hydrogen systems are included in the 2023 version of NFPA 2: Hydrogen Technologies Code. This work details the models and calculations leading to those distances. The specific models used including the flow of liquid hydrogen through an orifice within the Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) toolkit are described and discussed to emphasize challenges specific to liquid hydrogen systems. Potential hazards and harm affecting individual exposures (e.g. ignition sources air intakes) for different unignited concentrations overpressures and heat flux levels were considered and exposures were grouped into three bins. For each group the distances to a specific hazard criteria (e.g. heat flux level) for a characteristic leak size informed by a risk-analysis led to a hazard distance. The maximum hazard distance within each group was selected to determine a table of separation distances based on internal pressure and pipe size rather than storage volume similar to the bulk gaseous separation distance tables in NFPA 2. The new separation distances are compared to the previous distances and some implications of the updated distances are given.
Overview of International Activities in Hydrogen System Safety in IEA Hydrogen TCP Task 43
Sep 2023
Publication
Safety and reliability have long been recognized as key issues for the development commercialization and implementation of new technologies and infrastructure and hydrogen systems are no exception to this rule. Reliability engineering quantitative risk assessment (QRA) and knowledge exchange each play a key role in proactive addressing safety – before problems happen – and help us learn from problems if they happen. Many international research activities are focusing on both reliability and risk assessment for hydrogen systems. However the element of knowledge exchange is sometimes less visible. To support international collaboration and knowledge exchange the International Energy Agency (IEA) convened a new Technology Collaboration Program “Task 43: Safety and Regulatory Aspects of Emerging Large Scale Hydrogen Energy Applications” started in June 2022. Within Task 43 Subtask E focuses on Hydrogen Systems Safety. This paper discusses the structure of the Hydrogen Systems Safety subtask and the aligned activities and introduces opportunities for future work.
IEA TCP Task 43 - Subtask Safety Distances: State of the Art
Sep 2023
Publication
The large deployment of hydrogen technologies for new applications such as heat power mobility and other emerging industrial utilizations is essential to meet targets for CO2 reduction. This will lead to an increase in the number of hydrogen installations nearby local populations that will handle hydrogen technologies. Local regulations differ and provide different safety and/or separation distances in different geographies. The purpose of this work is to give an insight on different methodologies and recommendations developed for hydrogen (mainly) risk management and consequences assessment of accidental scenarios. The first objective is to review available methodologies and to identify the divergent points on the methodology. For this purpose a survey has been launched to obtain the needed inputs from the subtask participants. The current work presents the outcomes of this survey highlighting the gaps and suggesting the prioritization of the actions to take to bridge these gaps.
Energy Transition Technology Comes With New Process Safety Challenges and Risks
Jul 2023
Publication
This paper intends to give an impression of new technologies and processes that are in development for application to achieve decarbonization and about which less or no experience on associated hazards exists in the process industry. More or less an exception is hydrogen technology because its hazards are relatively known and there is industry experience in handling it safely but problems will arise when it is produced stored and distributed on a large scale. So when its use spreads to communities and it becomes as common as natural gas now measures to control the risks will be needed. And even with hydrogen surprise findings have been shown lately e.g. its BLEVE behavior when in a liquified form stored in a vessel heated externally. Substitutes for hydrogen are not without hazard concern either. The paper will further consider the hazards of energy storage in batteries and the problems to get those hazards under control. Relatively much attention will be paid to the electrification of the process industry. Many new processes are being researched which given green energy will be beneficial to reduce greenhouse gases and enhance sustainability but of which hazards are rather unknown. Therefore as last chapter the developments with respect to the concept of hazard identification and scenario definition will be considered in quite detail. Improvements in that respect are also being possible due to the digitization of the industry and the availability of data and considering the entire life cycle all facilitated by the data model standard ISO 15926 with the scope of integration of life-cycle data for process plants including oil and gas production facilities. Conclusion is that the new technologies and processes entail new process and personal hazards and that much effort is going into renewal but safety analyses are scarce. Right in a period of process renewal attention should be focused on possibilities to implement inherently safer design.
Helping the Climate by Replacing Liquefied Natural Gas with Liquefied Hydrogen or Ammonia?
Apr 2024
Publication
The war in Ukraine caused Europe to more than double its imports of liquefied natural gas (LNG) in only one year. In addition imported LNG remains a crucial source of energy for resource-poor countries such as Japan where LNG imports satisfy about a quarter of the country’s primary energy demand. However an increasing number of countries are formulating stringent decarbonization plans. Liquefied hydrogen and liquefied ammonia coupled with carbon capture and storage (LH2-CCS LNH3-CCS) are emerging as the front runners in the search for low-carbon alternatives to LNG. Yet little is currently known about the full environmental profile of LH2-CCS and LNH3-CCS because several characteristics of the two alternatives have only been analyzed in isolation in previous work. Here we show that the potential of these fuels to reduce greenhouse gas (GHG) emissions throughout the supply chain is highly uncertain. Our best estimate is that LH2-CCS and LNH3-CCS can reduce GHG emissions by 25%–61% relative to LNG assuming a 100 year global warming potential. However directly coupling LNG with CCS would lead to substantial GHG reductions on the order of 74%. Further under certain conditions emissions from LH2-CCS and LNH3-CCS could exceed those of LNG by up to 44%. These results question the suitability of LH2-CCS and LNH3-CCS for stringent decarbonization purposes.
Mitigating Emissions in the Global Steel Industry: Representing CCS and Hydrogen Technologies in Integrated Assessment Modelling
Dec 2023
Publication
We conduct a techno-economic assessment of two low-emissions steel production technologies and evaluate their deployment in emissions mitigation scenarios utilizing the MIT Economic Projection and Policy Analysis (EPPA) model. Specifically we assess direct reduced iron-electric arc furnace with carbon capture and storage (DRI-EAF with CCS) and H2-based direct reduced iron-electric arc furnace (H2 DRI-EAF) which utilizes low carbon hydrogen to reduce CO2 emissions. Our techno-economic analysis based on the current state of technologies found that DRI-EAF with CCS increased costs ~7% relative to the conventional steel technology. H2 DRI-EAF increased costs by ~18% when utilizing Blue hydrogen and ~79% when using Green hydrogen. The exact pathways for hydrogen production in different world regions including the extent of CCS and hydrogen deployment in steelmaking are highly speculative at this point. In illustrative scenarios using EPPA we find that using base cost assumptions switching from BF-BOF to DRI-EAF or scrap EAF can provide significant emissions mitigation within steelmaking. With further reductions in the cost of advanced steelmaking we find a greater role for DRI-EAF with CCS whereas reductions in both the cost of advanced steelmaking and hydrogen production lead to a greater role for H2 DRI-EAF. Our findings can be used to help decision-makers assess various decarbonization options and design economically efficient pathways to reduce emissions in the steel industry. Our cost evaluation can also be used to inform other energy-economic and integrated assessment models designed to provide insights about future decarbonization pathways.
Social Risk Approach for Assessing Public Safety of Large-scale Hydrogen Systems
Sep 2023
Publication
Social risk is a comprehensive concept that considers not only internal/external physical risks but also risks (which are multiple varied and diverse) associated with social activity. It should be considered from diverse perspectives and requires a comprehensive evaluation framework that takes into account the synergistic impact of each element on others rather than evaluating each risk individually. Social risk assessment is an approach that is not limited to internal system risk from an engineering perspective but also considers the stakeholders development stage and societal readiness and resilience to change. This study aimed to introduce a social risk approach to assess the public safety of large-scale hydrogen systems. Guidelines for comprehensive social risk assessment were developed to conduct appropriate risk assessments for advanced science and technology activities with high uncertainties to predict major impacts on society before an accident occurs and to take measures to mitigate the damage and to ensure good governance are in place to facilitate emergency response and recovery in addition to preventive measures. In a case study this approach was applied to a hydrogen refueling station in Japan and risk-based multidisciplinary approaches were introduced. These approaches can be an effective supporting tool for social implementation with respect to large-scale hydrogen systems such as liquefied hydrogen storage tanks. The guidelines for social risk assessment of large-scale hydrogen systems are under the International Energy Agency Technology Collaboration Program Hydrogen Safety Task 43. This study presents potential case studies of social risk assessment for large-scale hydrogen systems for future.
Integration of Renewable Energy Sources in Tandem with Electrolysis: A Technology Review for Green Hydrogen Production
Jun 2024
Publication
The global shift toward sustainable energy solutions emphasises the urgent need to harness renewable sources for green hydrogen production presenting a critical opportunity in the transition to a low-carbon economy. Despite its potential integrating renewable energy with electrolysis to produce green hydrogen faces significant technological and economic challenges particularly in achieving high efficiency and cost-effectiveness at scale. This review systematically examines the latest advancements in electrolysis technologies—alkaline proton exchange membrane electrolysis cell (PEMEC) and solid oxide—and explores innovative grid integration and energy storage solutions that enhance the viability of green hydrogen. The study reveals enhanced performance metrics in electrolysis processes and identifies critical factors that influence the operational efficiency and sustainability of green hydrogen production. Key findings demonstrate the potential for substantial reductions in the cost and energy requirements of hydrogen production by optimising electrolyser design and operation. The insights from this research provide a foundational strategy for scaling up green hydrogen as a sustainable energy carrier contributing to global efforts to reduce greenhouse gas emissions and advance toward carbon neutrality. The integration of these technologies could revolutionise energy systems worldwide aligning with policy frameworks and market dynamics to foster broader adoption of green hydrogen.
A Perspective on Broad Deployment of Hydrogen-fueled Vehicles for Ground Freight Transportation with a Comparison to Electric Vehicles
Oct 2024
Publication
The pressing global challenge of climate change necessitates a concerted effort to limit greenhouse gas emissions particularly carbon dioxide. A critical pathway is to replace fossil fuel sources by electrification including transportation. While electrification of light-duty vehicles is rapidly expanding the heavy-duty vehicle sector is subject to challenges notably the logistical drawbacks of the size and weight of high-capacity batteries required for range as well as the time for battery charging. This Perspective highlights the potential of hydrogen fuel-cell vehicles as a viable alternative for heavy-duty road transportation. We evaluate the implications of hydrogen integration into the freight economy energy dynamics and CO2 mitigation and envision a roadmap for a holistic energy transition. Our critical opinion presented in this Perspective is that federal incentives to produce hydrogen could foster growth in the nascent hydrogen economy. The pathway that we propose is that initial focus on operators of large fleets that could control their own fueling infrastructure. This opinion was formed from private discussions with numerous stakeholders during the formation of one of the awarded hydrogen hubs if they focus on early adopters that could leverage the hydrogen supply chain.
The Hydrogen Economy can Reduce Costs of Climate Change Mitigation by up to 22%
May 2024
Publication
In response to the urgent need to mitigate climate change via net-zero targets many nations are renewing their interest in clean hydrogen as a net-zero energy carrier. Although clean hydrogen can be directly used in various sectors for deep decarbonization the relatively low energy density and high production costs have raised doubts as to whether clean hydrogen development is worthwhile. Here we improve on the GCAM model by including a more comprehensive and detailed representation of clean hydrogen production distribution and demand in all sectors of the global economy and simulate 25 scenarios to explore the costeffectiveness of integrating clean hydrogen into the global energy system. We show that due to costly technical obstacles clean hydrogen can only provide 3%–9% of the 2050 global final energy use. Nevertheless clean hydrogen deployment can reduce overall energy decarbonization costs by 15%–22% mainly via powering ‘‘hard-to-electrify’’ sectors that would otherwise face high decarbonization expenditures. Our work provides practical references for cost-effective clean hydrogen planning.
Developing a Generalized Framework for Assessing Safety of Hydrogen Vehicles in Tunnels
Sep 2023
Publication
For widespread adoption of hydrogen fuel cell powered vehicles such vehicles need to be able to provide similar transportation capabilities as their gasoline/diesel powered counterparts. Meeting this requirement in many regions will necessitate access to tunnels. Previous work completed at Sandia National Laboratories provided high-fidelity consequence modeling of hydrogen vehicle tunnel crashes for a specific fire scenario in selected Massachusetts tunnels. To consider additional tunnels a generalized tunnel safety analysis framework is being developed. This framework aims to be broader than specific fire scenarios in specific tunnels allowing it to be applied to a range of tunnel geometries vehicle types and crash scenarios. Initial steps in the development of the generalized framework are reported within this work. Representative tunnel characteristics are derived based on data for tunnels in the U.S. Tunnel dimensions shapes and traffic levels are among the many characteristics reported within the data that can be used to inform crash scenario specification. Various crash scenario parameters are varied using lower-fidelity consequence modeling to quantify the impact on resulting safety hazards for time-dependent releases. These lower-fidelity models consider the unignited dispersion of hydrogen gas the thermal effects of jet fires and potential impacts of overpressures. Different sizes/classes of vehicles are considered as the total amount of hydrogen onboard may greatly affect scenario-specific consequences. The generalized framework will allow safety assessments to be both more agile and consistent when applied to different types of tunnels.
Adaptive Network Fuzzy Inference System and Particle Swarm Optimization of Biohydrogen Production Process
Sep 2022
Publication
Green hydrogen is considered to be one of the best candidates for fossil fuels in the near future. Bio-hydrogen production from the dark fermentation of organic materials including organic wastes is one of the most cost-effective and promising methods for hydrogen production. One of the main challenges posed by this method is the low production rate. Therefore optimizing the operating parameters such as the initial pH value operating temperature N/C ratio and organic concentration (xylose) plays a significant role in determining the hydrogen production rate. The experimental optimization of such parameters is complex expensive and lengthy. The present research used an experimental data asset adaptive network fuzzy inference system (ANFIS) modeling and particle swarm optimization to model and optimize hydrogen production. The coupling between ANFIS and PSO demonstrated a robust effect which was evident through the improvement in the hydrogen production based on the four input parameters. The results were compared with the experimental and RSM optimization models. The proposed method demonstrated an increase in the biohydrogen production of 100 mL/L compared to the experimental results and a 200 mL/L increase compared to the results obtained using ANOVA.
Hydrogen Equipment Enclosure Risk Reduction through Earlier Detection of Component Failures
Sep 2023
Publication
Hydrogen component reliability and the hazard associated with failure rates is a critical area of research for the successful implementation and growth of hydrogen technology across the globe. The research team has partnered to quantify system risk reduction through earlier detection of hydrogen component failures. A model of hydrogen dispersion in a hydrogen equipment enclosure has been developed utilizing experimentally quantified hydrogen component leak rates as inputs. This model provides insight into the impact of hydrogen safety sensors and ventilation on the flammable mass within a hydrogen equipment enclosure. This model also demonstrates the change in safety sensor response time due to detector placement under various leak scenarios. The team looks to improve overall hydrogen system safety through an improved understanding of hydrogen component reliability and risk mitigation methods. This collaboration fits under the work program of IEA Hydrogen Task 43 Subtask E Hydrogen System Safety.
Batteries or Hydrogen or Both for Grid Electricity Storage Upon Full Electrification of 145 Countries with Wind-Water-Solar?
Jan 2024
Publication
Grids require electricity storage. Two emerging storage technologies are battery storage (BS) and green hydrogen storage (GHS) (hydrogen produced and compressed with clean-renewable electricity stored then returned to electricity with a fuel cell). An important question is whether GHS alone decreases system cost versus BS alone or BS+GHS. Here energy costs are modeled in 145 countries grouped into 24 regions. Existing conventional hydropower (CH) storage is used along with new BS and/or GHS. A method is developed to treat CH for both baseload and peaking power. In four regions only CH is needed. In five CH+BS is lowest cost. Otherwise CH+BS+GHS is lowest cost. CH+GHS is never lowest cost. A metric helps estimate whether combining GHS with BS reduces cost. In most regions merging (versus separating) grid and non-grid hydrogen infrastructure reduces cost. In sum worldwide grid stability may be possible with CH+BS or CH+BS+GHS. Results are subject to uncertainties.
A Systematic Review: The Role of Emerging Carbon Capture and Conversion Rechnologies for Energy Transition to Clean Hydrogen
Feb 2024
Publication
The exploitation of fossil fuels in various sectors such as power and heat generation and the transportation sector has been the primary source of greenhouse gas (GHG) emissions which are the main contributors to global warming. Qatar's oil and gas sector notably contributes to CO2 emissions accounting for half of the total emissions. Globally it is essential to transition into cleaner fossil fuel production to achieve carbon neutrality on a global scale. In this paper we focus on clean hydrogen considering carbon capture to make hydrogen a viable low carbon energy alternative for the transition to clean energy. This paper systematically reviews emerging technologies in carbon capture and conversion (CCC). First the road map stated by the Intergovernmental Panel on Climate Change (IPCC) to reach carbon neutrality is discussed along with pathways to decarbonize the energy sector in Qatar. Next emerging CO2 removal technologies including physical absorption using ionic liquids chemical looping and cryogenics are explored and analyzed regarding their advancement and limitations CO2 purity scalability and prospects. The advantages limitations and efficiency of the CO2 conversion technology to value-added products are grouped into chemical (plasma catalysis electrochemical and photochemical) and biological (photosynthetic and non-photosynthetic). The paper concludes by analyzing pathways to decarbonize the energy sector in Qatar via coupling CCC technologies for low-carbon hydrogen highlighting the challenges and research gaps.
A Novel Hydrogen Supply Chain Optimization Model - Case Study of Texas and Louisiana
Jun 2024
Publication
The increasing political momentum advocating for decarbonization efforts has led many governments around the world to unveil national hydrogen strategies. Hydrogen is viewed as a potential enabler of deep decarbonization notably in hard-to-abate sectors such as the industry. A multi-modal hourly resolved linear programming model was developed to assess the infrastructure requirements of a low-carbon supply chain over a large region. It optimizes the deployment of infrastructure from 2025 up to 2050 by assessing four years: 2025 2030 2040 and 2050 and is location agnostic. The considered infrastructure encompasses several technologies for production transmission and storage. Model results illustrate supply chain requirements in Texas and Louisiana. Edge cases considering 100% electrolytic production were analyzed. Results show that by 2050 with an assumed industrial demand of 276 TWh/year Texas and Louisiana would require 62 GW of electrolyzers 102 GW of onshore wind and 32 GW of solar panels. The resulting levelized cost of hydrogen totaled $5.6–6.3/kgH2 in 2025 decreasing to $3.2–3.5/ kgH2 in 2050. Most of the electricity production occurs in Northwest Texas thanks to high capacity factors for both renewable technologies. Hydrogen is produced locally and transmitted through pipelines to demand centers around the Gulf Coast instead of electricity being transmitted for electrolytic production co-located with demand. Large-scale hydrogen storage is highly beneficial in the system to provide buffer between varying electrolytic hydrogen production and constant industrial demand requirements. In a system without low-cost storage liquid and compressed tanks are deployed and there is a significant renewable capacity overbuild to ensure greater electrolyzer capacity factors resulting in higher electricity curtailment. A system under carbon constraint sees the deployment of natural gas-derived hydrogen production. Lax carbon constraint target result in an important reliance on this production method due to its low cost while stricter targets enforce a great share of electrolytic production.
Future of Hydrogen in the U.S. Energy Sector: MARKAL Modeling Results
Mar 2024
Publication
Hydrogen is an attractive energy carrier which could play a role in decarbonizing process heat power or transport applications. Though the U.S. already produces about 10 million metric tons of H2 (over 1 quadrillion BTUs or 1% of the U.S. primary energy consumption) production technologies primarily use fossil fuels that release CO2 and the deployment of other cleaner H2 production technologies is still in the very early stages in the U.S. This study explores (1) the level of current U.S. hydrogen production and demand (2) the importance of hydrogen to accelerate a net-zero CO2 future and (3) the challenges that must be overcome to make hydrogen an important part of the U.S. energy system. The study discusses four scenarios and hydrogen production has been shown to increase in the future but this growth is not enough to establish a hydrogen economy. In this study the characteristics of hydrogen technologies and their deployments in the long-term future are investigated using energy system model MARKAL. The effects of strong carbon constraints do not cause higher hydrogen demand but show a decrease in comparison to the business-as-usual scenario. Further according to our modeling results hydrogen grows only as a fuel for hard-to-decarbonize heavy-duty vehicles and is less competitive than other decarbonization solutions in the U.S. Without improvements in reducing the cost of electrolysis and increasing the performance of near-zero carbon technologies for hydrogen production hydrogen will remain a niche player in the U.S. energy system in the long-term future. This article provides the reader with a comprehensive understanding of the role of hydrogen in the U.S. energy system thereby explaining the long-term future projections.
The Role of Hydrogen in the Energy Transition of the Oil and Gas Industry
May 2024
Publication
Hydrogen primarily produced from steam methane reforming plays a crucial role in oil refining and provides a solution for the oil and gas industry's long-term energy transition by reducing CO2 emissions. This paper examines hydrogen’s role in this transition. Firstly experiences from oil and gas exploration including in-situ gasification can be leveraged for hydrogen production from subsurface natural hydrogen reservoirs. The produced hydrogen can serve as fuel for generating steam and heat for thermal oil recovery. Secondly hydrogen can be blended into gas for pipeline transportation and used as an alternative fuel for oil and gas hauling trucks. Additionally hydrogen can be stored underground in depleted gas fields. Lastly oilfield water can be utilized for hydrogen production using geothermal energy from subsurface oil and gas fields. Scaling up hydrogen production faces challenges such as shared use of oil and gas infrastructures increased carbon tax for promoting blue hydrogen and the introduction of financial incentives for hydrogen production and consumption hydrogen leakage prevention and detection.
Very Low-cost Wireless Hydrogen Leak Detection for Hydrogen Infrastructure
Sep 2023
Publication
A unique hydrogen leak detection strategy is the use of powerless indicator wraps for fittings and other pneumatic elements within a hydrogen facility. One transduction mechanism of such indicators is a color change that is induced by a reaction between a pigment and released hydrogen. This is an effective way to detect hydrogen leaks and to identify their source before they become a safety event however this technology requires visual (manual) inspection to identify a color change or leak. One improvement in this strategy would be to improve the communication of the visual response to an end-user. Element One (E1) has previously developed and introduced DetecTape® a self-fusing silicone non-reversible hydrogen leak detecting tape for application to potential leak sites in hydrogen piping valves and fittings and it has been successfully commercialized with excellent feedback. Element One’s sensors can be fabricated using either pigments or thin films which both change color and conductivity. Neither change requires an external power source. The conductivity change may be communicated as a wireless transmission such as passive radio frequency identification devices (RFID) to an appropriate receiving system where it may be remotely monitored to achieve higher levels of safety and reliability at low cost. Element One will report on its recent progress in the commercial development of remotely monitored hydrogen leak detection using several wireless protocols including passive RFID.
Review of the US 2050 Long Term Strategy to Reach Net Zero Carbon Emissions
Jul 2024
Publication
In 2015 during the lead up to the Paris Climate Agreement the United States set forth a Nationally Determined Contribution that outlines national goals for greenhouse gas emission reductions. It was not until 2021 that the US put forth a long-term strategy that lays out the pathway to reach these goals. The US long-term strategy lays the framework for research needs to meet the greenhouse gas emission reduction goals and incentivizes industry to meet the goals using a variety of policies. The five US long term strategy core elements are to decarbonize electricity electrify end uses and switch to clean fuels cut energy waste reduce methane and other non-carbon dioxide greenhouse gas emissions and to scale up carbon dioxide removal. Implementation of the long term strategy has generally been funded by tax incentives and government grants that were approved as part of the Inflation Reduction Act. Political headwinds societal Not in My Backyard resistance long-term economic funding cumbersome permitting requirements and incentives vs. taxation debate are significant policy/nontechnical hurdles. Technical challenges remain regarding effective energy efficiency implementation the use of hydrogen as a fuel cost effective carbon emission treatment nuclear energy expansion renewables expansion and grid integration biofuel integration efficient and safe energy storage and electrical grid adequacy/expansion. This review article condenses the multitude of technical and policy issues facing the US long-term strategy providing readers with an overview of the extent and magnitude of the challenges while outlining possible solutions.
The NREL Sensor Laboratory: Hydrogen Leak Detection for Large Scale Deployments
Sep 2023
Publication
The NREL Hydrogen Sensor Laboratory was commissioned in 2010 as a resource for sensor developers end-users and regulatory agencies within the national and international hydrogen community. The Laboratory continues to provide as its core capability the unbiased verification of hydrogen sensor performance to assure sensor availability and their proper use. However the mission and strategy of the NREL Sensor Laboratory has evolved to meet the needs of the growing hydrogen market. The Sensor Laboratory program has expanded to support research in conventional and alternative detection methods as hydrogen use expands to large-scale markets as envisioned by the DOE National Clean Hydrogen Strategy and Roadmap. Current research encompasses advanced methods of hydrogen leak detection including stand-off and wide area monitoring approaches for large scale and distributed applications. In addition to safety applications low-level detection strategies to support the potential environmental impacts of hydrogen and hydrogen product losses along the value chain are being explored. Many of these applications utilize detection strategies that supplement and may supplant the use of traditional point sensors. The latest results of the hydrogen detection strategy research at NREL will be presented.
Alternative Fuels in Sustainable Logistics—Applications, Challenges, and Solutions
Sep 2024
Publication
Logistics is becoming more cost competitive while customers and regulatory bodies pressure businesses to disclose their carbon footprints creating interest in alternative fuels as a decarbonization strategy. This paper provides a thematic review of the role of alternative fuels in sustainable air land and sea logistics their challenges and potential mitigations. Through an extensive literature survey we determined that biofuels synthetic kerosene natural gas ammonia alcohols hydrogen and electricity are the primary alternative fuels of interest in terms of environmental sustainability and techno-economic feasibility. In air logistics synthetic kerosene from hydrogenated esters and fatty acids is the most promising route due to its high technical maturity although it is limited by biomass sourcing. Electrical vehicles are favorable in road logistics due to cheaper green power and efficient vehicle designs although they are constrained by recharging infrastructure deployment. In sea logistics liquified natural gas is advantageous owing to its supply chain maturity but it is limited by methane slip control and storage requirements. Overall our examination indicates that alternative fuels will play a pivotal role in the logistics networks of the future.
Fuelling the Future: An In-depth Review of Recent Trends, Challenges and Opportunities of Hydrogen Fuel Cell for a Sustainable Hydrogen Economy
Sep 2023
Publication
Hydrogen has gained tremendous momentum worldwide as an energy carrier to transit to a net zero emission energy sector. It has been widely adopted as a promising large-scale renewable energy (RE) storage solution to overcome RE resources’ variability and intermittency nature. The fuel cell (FC) technology became in focus within the hydrogen energy landscape as a cost-effective pathway to utilize hydrogen for power generation. Therefore FC technologies’ research and development (R&D) expanded into many pathways such as cost reduction efficiency improvement fixed and mobile applications lifetime safety and regulations etc. Many publications and industrial reports about FC technologies and applications are available. This raised the necessity for a holistic review study to summarize the state-of-the-art range of FC stacks such as manufacturing the balance of plant types technologies applications and R&D opportunities. At the beginning the principal technologies to compare the well known types followed by the FC operating parameters are presented. Then the FC balance of the plant i.e. building components and materials with its functionality and purpose types and applications are critically reviewed with their limitations and improvement opportunities. Subsequently the electrical properties of FCs with their key features including advantages and disadvantages were investigated. Applications of FCs in different sectors are elaborated with their key characteristics current status and future R&D opportunities. Economic attributes of fuel cells with a pathway towards low cost are also presented. Finally this study identifies the research gaps and future avenues to guide researchers and the hydrogen industry.
Supply and Demand Drivers of Global Hydrogen Deployment in the Transition Toward a Decarbonized Energy System
Nov 2023
Publication
The role of hydrogen in energy system decarbonization is being actively examined by the research and policy communities. We evaluate the potential “hydrogen economy” in global climate change mitigation scenarios using the Global Change Analysis Model (GCAM). We consider major hydrogen production methods in conjunction with delivery options to understand how hydrogen infrastructure affects its deployment. We also consider a rich set of hydrogen end-use technologies and vary their costs to understand how demand technologies affect deployment. We find that the availability of hydrogen transmission and distribution infrastructure primarily affects the hydrogen production mix particularly the share produced centrally versus on-site whereas assumptions about end-use technology primarily affect the scale of hydrogen deployment. In effect hydrogen can be a source of distributed energy enabled by on-site renewable electrolysis and to a lesser extent by on-site production at industrial facilities using natural gas with carbon capture and storage (CCS). While the share of hydrogen in final energy is small relative to the share of other major energy carriers in our scenarios hydrogen enables decarbonization in difficult-to-electrify end uses such as industrial high-temperature heat. Hydrogen deployment and in turn its contribution to greenhouse gas mitigation increases as the climate objective is tightened.
Meeting the Challenges of Large-scale Carbon Storage and Hydrogen Production
Mar 2023
Publication
There is a pressing need to rapidly and massively scale up negative carbon strategies such as carbon capture and storage (CCS). At the same time large-scale CCS can enable ramp-up of large-scale hydrogen production a key component of decarbonized energy systems. We argue here that the safest and most practical strategy for dramatically increasing CO2 storage in the subsurface is to focus on regions where there are multiple partially depleted oil and gas reservoirs. Many of these reservoirs have adequate storage capacity are geologically and hydrodynamically well understood and are less prone to injection-induced seismicity than saline aquifers. Once a CO2 storage facility is up and running it can be used to store CO2 from multiple sources. Integration of CCS with hydrogen production appears to be an economically viable strategy for dramatically reducing greenhouse gas emissions over the next decade particularly in oil- and gas-producing countries where there are numerous depleted reservoirs that are potentially suitable for large-scale carbon storage.
Low-temperature Water Electrolysis: Fundamentals, Progress, and New Strategies
May 2022
Publication
Water electrolysis is a promising technology for sustainable energy conversion and storage of intermittent and fluctuating renewable energy sources and production of high-purity hydrogen for fuel cells and various industrial applications. Low-temperature electrochemical water splitting technologies include alkaline proton exchange membrane and anion exchange membrane water electrolyses which normally consist of two coupled half reactions: the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Despite the advances over decades formidable challenges still exist and hinder the practical application of large-scale energy-efficient and economically viable water electrolysis including large energy penalty sluggish kinetics high cost of precious metal based electrocatalysts possible H2/O2 gas crossover difficulty in storage and distribution of H2. Herein we first briefly introduce the fundamentals of water electrolysis summarize the recommended standardized electrochemical characterization protocols and demonstrate the metrics and key performance indicators that are used to evaluate the performances of HER and OER electrocatalysts and electrolyser cells. Then we present six new strategies to mitigate the technical challenges in conventional water electrolysis. These emerging strategies for disruptive innovation of water electrolysis technology include overall water electrolysis based on bifunctional nonprecious electrocatalysts (or pre-catalysts) magnetic field-assisted water electrolysis decoupled water electrolysis hybrid water electrolysis acid/alkaline asymmetric electrolyte electrolysis and tandem water electrolysis. Finally the remaining challenges perspectives and future directions are discussed. This review will provide guidance and inspire more endeavours to deepen the mechanistic understanding and advance the development of water electrolysis.
Total Cost of Ownership Analysis of Fuel Cell Electric Bus with Different Hydrogen Supply Alternatives
Dec 2023
Publication
In the transition to sustainable public transportation with zero-emission buses hydrogen fuel cell electric buses have emerged as a promising alternative to traditional diesel buses. However assessing their economic viability is crucial for widespread adoption. This study carries out a comprehensive examination encompassing both sensitivity and probabilistic analyses to assess the total cost of ownership (TCO) for the bus fleet and its corresponding infrastructure. It considers various hydrogen supply options encompassing on-site electrolysis on-site steam methane reforming and off-site hydrogen procurement with both gaseous and liquid delivery methods. The analysis covers critical cost elements encompassing bus acquisition costs infrastructure capital expenses and operational and maintenance costs for both buses and infrastructure. This paper conducted two distinct case studies: one involving a current small bus fleet of five buses and another focusing on a larger fleet set to launch in 2028. For the current small fleet the off-site gray hydrogen purchase with a gaseous delivery option is the most cost-effective among hydrogen alternatives but it still incurs a 26.97% higher TCO compared to diesel buses. However in the case of the expanded 2028 fleet the steam methane-reforming method without carbon capture emerges as the most likely option to attain the lowest TCO with a high probability of 99.5%. Additionally carbon emission costs were incorporated in response to the growing emphasis on environmental sustainability. The findings indicate that although diesel buses currently represent the most economical option in terms of TCO for the existing small fleet steam methane reforming with carbon capture presents a 69.2% likelihood of being the most cost-effective solution suggesting it is a strong candidate for cost efficiency for the expanded 2028 fleet. Notably substantial investments are required to increase renewable energy integration in the power grid and to enhance electrolyzer efficiency. These improvements are essential to make the electrolyzer a more competitive alternative to steam methane reforming. Overall the findings in this paper underscore the substantial impact of the hydrogen supply chain and carbon emission costs on the TCO of zero-emission buses.
Entropy Production and Filling Time in Hydrogen Refueling Stations: An Economic Assessment
Aug 2024
Publication
A multi-objective optimization is performed to obtain fueling conditions in hydrogen stations leading to improved filling times and thermodynamic efficiency (entropy production) of the de facto standard of operation which is defined by the protocol SAE J2601. After finding the Pareto frontier between filling time and total entropy production it was found that SAE J2601 is suboptimal in terms of these process variables. Specifically reductions of filling time from 47 to 77% are possible in the analyzed range of ambient temperatures (from 10 to 40 °C) with higher saving potential the hotter the weather conditions. Maximum entropy production savings with respect to SAE J2601 (7% for 10 °C 1% for 40 °C) demand a longer filling time that increases with ambient temperature (264% for 10 °C 350% for 40 °C). Considering average electricity prices in California USA the operating cost of the filling process can be reduced between 8 and 28% without increasing the expected filling time.
An Exploration of Safety Measures in Hydrogen Refueling Stations: Delving into Hydrogen Equipment and Technical Performance
Feb 2024
Publication
The present paper offers a thorough examination of the safety measures enforced at hydrogen filling stations emphasizing their crucial significance in the wider endeavor to advocate for hydrogen as a sustainable and reliable substitute for conventional fuels. The analysis reveals a wide range of crucial safety aspects in hydrogen refueling stations including regulated hydrogen dispensing leak detection accurate hydrogen flow measurement emergency shutdown systems fire-suppression mechanisms hydrogen distribution and pressure management and appropriate hydrogen storage and cooling for secure refueling operations. The paper therefore explores several aspects including the sophisticated architecture of hydrogen dispensers reliable leak-detection systems emergency shut-off mechanisms and the implementation of fire-suppression tactics. Furthermore it emphasizes that the safety and effectiveness of hydrogen filling stations are closely connected to the accuracy in the creation and upkeep of hydrogen dispensers. It highlights the need for materials and systems that can endure severe circumstances of elevated pressure and temperature while maintaining safety. The use of sophisticated leak-detection technology is crucial for rapidly detecting and reducing possible threats therefore improving the overall safety of these facilities. Moreover the research elucidates the complexities of emergency shut-off systems and fire-suppression tactics. These components are crucial not just for promptly managing hazards but also for maintaining the station’s structural soundness in unanticipated circumstances. In addition the study provides observations about recent technical progress in the industry. These advances effectively tackle current safety obstacles and provide the foundation for future breakthroughs in hydrogen fueling infrastructure. The integration of cutting-edge technology and materials together with the development of upgraded safety measures suggests a positive trajectory towards improved efficiency dependability and safety in hydrogen refueling stations.
Evaluating Reservoir Suitability for Large-scale Hydrogen Storage: A Preliminary Assesment Considering Reservoir Properties
May 2024
Publication
With rising demand for clean energy global focus turns to finding ideal sites for large-scale underground hydrogen storage (UHS) in depleted petroleum reservoirs. A thorough preliminary reservoir evaluation before hydrogen (H2) injection is crucial for UHS success and safety. Recent criteria for UHS often emphasize economics and chemistry neglecting key reservoir attributes. This study introduces a comprehensive framework for the reservoir-scale preliminary assessment specifically tailored for long-term H2 storage within depleted gas reservoirs. The evaluation criteria encompass critical components including reservoir geometry petrophysical properties tectonics and formation fluids. To illustrate the practical application of this approach we assess the Barnett shale play reservoir parameters. The assessment unfolds through three key stages: (1) A systematic evaluation of the reservoir's properties against our comprehensive screening criteria determines its suitability for H2 storage. (2) Using both homogeneous and multilayered gas reservoir models we explore the feasibility and efficiency of H2 storage. This phase involves an in-depth examination of reservoir behavior during the injection stage. (3) To enhance understanding of UHS performance sensitivity analyses investigate the impact of varying reservoir dimensions and injection/production pressures. The findings reveal the following: (a) Despite potential challenges associated with reservoir compaction and aquifer support the reservoir exhibits substantial promise as an H2 storage site. (b) Notably a pronounced increase in reservoir pressure manifests during the injection stage particularly in homogeneous reservoirs. (c) Furthermore optimizing injection-extraction cycle efficiency can be achieved by augmenting reservoir dimensions while maintaining a consistent thickness. To ensure a smooth transition to implementation further comprehensive investigations are advised including experimental and numerical studies to address injectivity concerns and explore storage site development. This evaluation framework is a valuable tool for assessing the potential of depleted gas reservoirs for large-scale hydrogen storage advancing global eco-friendly energy systems.
Techno-economic Analysis and Optmization of Intensified, Large-scale Hydrogen Production with Membrane Reactors
Oct 2023
Publication
Steam methane reforming (SMR) currently supplies 76% of the world’s hydrogen (H2) demand totaling ∼70 million tonnes per year. Developments in H2 production technologies are required to meet the rising demand for cleaner less costly H2. Therefore palladium membrane reactors (Pd-MR) have received significant attention for their ability to increase the efficiency of traditional SMR. This study performs novel economic analyses and constrained nonlinear optimizations on an intensified SMR process with a Pd-MR. The optimization extends beyond the membrane’s operation to present process set points for both the conventional and intensified H2 processes. Despite increased compressor and membrane capital costs along with electric utility costs the SMR-MR design offers reductions in the natural gas usage and annual costs. Economic comparisons between each plant show Pd membrane costs greater than $25 000/m2 are required to break even with the conventional design for membrane lifetimes of 1–3 years. Based on the optimized SMR-MR process this study concludes with sensitivity analyses on the design operational and cost parameters for the intensified SMR-MR process. Overall with further developments of Pd membranes for increased stability and lifetime the proposed SMR-MR design is thus profitable and suitable for intensification of H2 production.
Advances in Photothermal Catalysts for Solar-driven Hydrogen Production
Nov 2024
Publication
Hydrogen is increasingly recognized as a pivotal energy storage solution and a transformative alternative to conventional energy sources. This review summarizes the evolving landscape of global H2 production and consumption markets focusing on the crucial role of photothermal catalysts (PTCs) in driving Hydrogen evolution reactions (HER) particularly with regards to oxide selenide and telluride-based PTCs. Within this exploration the mechanisms of PTCs take center stage elucidating the intricacies of light absorption localized heating and catalytic activation. Essential optimization parameters ranging from temperature and irradiance to catalyst composition and pH are detailed for their paramount role in enhancing catalytic efficiency. This work comprehensively explores photothermal catalysts (PTCs) for hydrogen production by assessing their synthesis techniques and highlighting the current research gaps particularly in optimizing catalytic stability light absorption and scalability. The energy-efficient nature of oxide selenide and telluride-based PTCs makes them prime candidates for sustainable H2 production when compared to traditional materials. By analyzing a range of materials we summarize key performance metrics including hydrogen evolution rates ranging from 0.47 mmolh− 1 g− 1 for Ti@TiO2 to 22.50 mmolh− 1 g− 1 for Mn0.2Cd0.8S/NiSe2. The review concludes with a strategic roadmap aimed at enhancing PTC performance to meet the growing demand for renewable hydrogen as well as a critical literature review addressing challenges and prospects in deploying PTCs.
Hydrogen Production from Municipal Waste and Low Grade Lignite Blend
Nov 2024
Publication
The updraft rotating bed gasifier (URBG) offers a sustainable solution for waste-to-energy conversion utilizing low-grade lignite and municipal solid waste (MSW) from metropolitan dumping sites. This study investigates the co-gasification of lignite with various MSW components demonstrating a significant enhancement in gasification efficiency due to the synergistic effects arising from their higher hydrogen-to-carbon (H/C) ratios. We find feedstock blending is key to maximizing gasification efficiency from 11% to 52% while reducing SO emissions from 739 mg/kg to 155 mg/kg. Increasing the combustion zone temperature to 1100 K resulted in a peak hydrogen yield which was 19% higher than at 800 K. However steam management is complicated as increasing it improves hydrogen fraction in produced gas but gasification efficiency is compromised. These findingsshowcase the URBG’s potential to address both energy production and waste management challenges guiding fossil-reliant regions toward a more sustainable energy future.
Diverse Decarbonization Pathways under Near Cost-optimal Futures
Sep 2024
Publication
Energy system optimization models offer insights into energy and emissions futures through least-cost optimization. However real-world energy systems often deviate from deterministic scenarios necessitating rigorous uncertainty exploration in macro-energy system modeling. This study uses modeling techniques to generate diverse near cost-optimal net-zero CO2 pathways for the United States’ energy system. Our findings reveal consistent trends across these pathways including rapid expansion of solar and wind power generation substantial petroleum use reductions near elimination of coal combustion and increased end-use electrification. We also observe varying deployment levels for natural gas hydrogen direct air capture of CO2 and synthetic fuels. Notably carbon-captured coal and synthetic fuels exhibit high adoption rates but only in select decarbonization pathways. By analyzing technology adoption correlations we uncover interconnected technologies. These results demonstrate that diverse pathways for decarbonization exist at comparable system-level costs and provide insights into technology portfolios that enable near cost-optimal net-zero CO2 futures.
Assessing the Cost-effectiveness of Carbon Neutrality for Light-duty Vehicle Sector in China
Nov 2023
Publication
China’s progress in decarbonizing its transportation particularly vehicle electrification is notable. However the economically effective pathways are underexplored. To find out how much cost is necessary for carbon neutrality for the light-duty vehicle (LDV) sector this study examines twenty decarbonization pathways combining the New Energy and Oil Consumption Credit model and the China-Fleet model. We find that the 2060 zero-greenhouse gas (GHG) emission goal for LDVs is achievable via electrification if the battery pack cost is under CNY483/kWh by 2050. However an extra of CNY8.86 trillion internal subsidies is needed under pessimistic battery cost scenarios (CNY759/kWh in 2050) to eliminate 246 million tonnes of CO2-eq by 2050 ensuring over 80% market penetration of battery electric vehicles (BEVs) in 2050. Moreover the promotion of fuel cell electric vehicles is synergy with BEVs to mitigate the carbon abatement difficulties decreasing up to 34% of the maximum marginal abatement internal investment.
Designing an Inherently Safe H2 Infrastructure: Combining Analytical, Experimental, and Numerical Investigations to Optimize H2 Refuelling Stations Safety by Passive Mitigation
Sep 2023
Publication
Natural ventilation is a well-known passive mitigation method to limit hydrogen build-up in confined spaces in case of accidental release [1-3]. In most cases a basic design of H2 infrastructure is adopted and vents installed for natural ventilation are adjusted according to safety targets and constraints of the considered structure. With the growing H2 mobility market the demand for H2 refueling infrastructure in our urban environment is on the rise. In order to meet both safety requirements and societal acceptance the design of such infrastructure is becoming more important. In this study a novel design concept is proposed for the hydrogen refueling station (HRS) by modifying physical structure while keeping safety consideration as the top priority of the concept. In this collaborative project between Air Liquide and the University of Delaware an extensive evaluation was performed on new structures of the processing container and dispenser of HRS by integrating safety protocols via passive means. Through a SWOT analysis combined with the most relevant approaches including analytical engineering models numerical simulations [4] and dedicated experimental trials an optimized design was obtained and its safety enhancement was fully evaluated. A small-scale processing container and an almost full-scale dispenser were built and tested to validate the design concepts by simulating accidental H2 release scenarios and assessing the associated consequences in terms of accumulation and potential flammable volumes formation. A conical dispenser and a V-shaped roof-top processing container which were easy to build and implement were designed and tested for this proof-of-concept study. This unique methodology from conception fundamental analysis investigation and validation through experimental design execution and evaluation is fully described in this study.
Hydrogen-powered Aircraft: Fundamental Concepts, Key Technologies, and Environmental Impacts
Sep 2024
Publication
Civil aviation provides an essential transportation network that connects the world and supports global economic growth. To maintain these benefits while meeting environmental goals next-generation aircraft must have drastically reduced climate impacts. Hydrogen-powered aircraft have the potential to fly existing routes with no carbon emissions and reduce or eliminate other emissions. This paper is a comprehensive guide to hydrogen-powered aircraft that explains the fundamental physics and reviews current technologies. We discuss the impact of these technologies on aircraft design cost certification and environment. In the long term hydrogen aircraft appear to be the most compelling alternative to today’s kerosene-powered aircraft. Using hydrogen also enables novel technologies such as fuel cells and superconducting electronics which could lead to aircraft concepts that are not feasible with kerosene. Hydrogen-powered aircraft are technologically feasible but require significant research and development. Lightweight liquid hydrogen tanks and their integration with the airframe is one of the critical technologies. Fuel cells can eliminate in-flight emissions but must become lighter more powerful and more durable to make large fuel cell-powered transport aircraft feasible. Hydrogen turbofans already have these desirable characteristics but produce some emissions albeit much less damaging than kerosene turbofans. Beyond airframe and propulsion technologies the viability of hydrogen aircraft hinges on low-cost green hydrogen production which requires massive investments in the energy infrastructure.
Carbon Neutrality in Malaysia and Kuala Lumpur: Insights from Stakeholder-driven Integrated Assessment Modelling
Apr 2024
Publication
Introduction: Several cities in Malaysia have established plans to reduce their CO2 emissions in addition to Malaysia submitting a Nationally Determined Contribution to reduce its carbon intensity (against GDP) by 45% in 2030 compared to 2005. Meeting these emissions reduction goals will require ajoint effort between governments industries and corporations at different scales and across sectors.<br/>Methods: In collaboration with national and sub-national stakeholders we developed and used a global integrated assessment model to explore emissions mitigation pathways in Malaysia and Kuala Lumpur. Guided by current climate action plans we created a suite of scenarios to reflect uncertainties in policy ambition level of adoption and implementation for reaching carbon neutrality. Through iterative engagement with all parties we refined the scenarios and focus of the analysis to best meet the stakeholders’ needs.<br/>Results: We found that Malaysia can reduce its carbon intensity and reach carbon neutrality by 2050 and that action in Kuala Lumpur can play a significant role. Decarbonization of the power sector paired with extensive electrification energy efficiency improvements in buildings transportation and industry and the use of advanced technologies such as hydrogen and carbon capture and storage will be Major drivers to mitigate emissions with carbon dioxide removal strategies being key to eliminate residual emissions.<br/>Discussion: Our results suggest a hopeful future for Malaysia’s ability to meet its climate goals recognizing that there may be technological social and financial challenges along the way. This study highlights the participatory process in which stakeholders contributed to the development of the model and guided the analysis as well as insights into Malaysia’s decarbonization potential and the role of multilevel governance.
No more items...