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A Non-dimensional Surrogate Model of Stratified Filling During Indoor, Plume-look Hydrogen Releases
Sep 2023
Publication
Hydrogen is commonly used as feedstock in industrial processes and is regarded as a potential future energy carrier. However its reactivity and low density make it difficult to handle and store safely. Indoor hydrogen dispersion can cause a fire or explosion hazard if encountering an ignition source. Safety practices often use time expensive modelling techniques to estimate risk associated with hydrogen. A neural network based surrogate model could efficiently replace Computational Fluid Dynamics (CFD) modelling in safety studies. To lower the dimensionality of this surrogate model a dimensional analysis based on Buckingham’s Pi-theorem is proposed. The dimensional analysis examines stratified filling and highlights the functional parameters involved in the process. Stratified filling occurs for buoyancy dominated releases and is characterized by layers of decreasing concentration starting at the ceiling of the enclosure and developing towards the bottom. The study involves four dimensional cases that were simulated using Computational Fluid Dynamics (CFD) to demonstrate the usefulness of the proposed dimensionless time and dimensionless volume. The setup considered in this paper consists of a parallelepiped enclosure with standard atmospheric conditions a single release source and one pressure outlet to ensure constant pressure during the release. The results of the CFD simulations show a distinct pattern in the relation of hydrogen molar fraction and dimensionless time. The pattern depends on the dimensionless height of the measurement location. A five-parameter logistic (5PL) function is proposed to fit the data from the CFD models. Overall the paper provides insights into the functional parameters involved in the evolution of hydrogen mass fractions during stratified filling. It provides a nondimensional surrogate model to compute the evolution of the local concentrations of hydrogen during the development of stratification layers.
Innovative Strategies for Combining Solar and Wind Energy with Green Hydrogen Systems
Oct 2024
Publication
The integration of wind and solar energy with green hydrogen technologies represents an innovative approach toward achieving sustainable energy solutions. This review examines state-ofthe-art strategies for synthesizing renewable energy sources aimed at improving the efficiency of hydrogen (H2 ) generation storage and utilization. The complementary characteristics of solar and wind energy where solar power typically peaks during daylight hours while wind energy becomes more accessible at night or during overcast conditions facilitate more reliable and stable hydrogen production. Quantitatively hybrid systems can realize a reduction in the levelized cost of hydrogen (LCOH) ranging from EUR 3.5 to EUR 8.9 per kilogram thereby maximizing the use of renewable resources but also minimizing the overall H2 production and infrastructure costs. Furthermore advancements such as enhanced electrolysis technologies with overall efficiencies rising from 6% in 2008 to over 20% in the near future illustrate significant progress in this domain. The review also addresses operational challenges including intermittency and scalability and introduces system topologies that enhance both efficiency and performance. However it is essential to consider these challenges carefully because they can significantly impact the overall effectiveness of hydrogen production systems. By providing a comprehensive assessment of these hybrid systems (which are gaining traction) this study highlights their potential to address the increasing global energy demands. However it also aims to support the transition toward a carbon-neutral future. This potential is significant because it aligns with both environmental goals and energy requirements. Although challenges remain the promise of these systems is evident.
Technical and Cost Analysis of Zero-emission High-speed Ferries: Retrofitting from Diesel to Green Hydrogen
Feb 2024
Publication
This paper proposes a technical and cost analysis model to assess the change in costs of a zeroemission high-speed ferry when retrofitting from diesel to green hydrogen. Both compressed gas and liquid hydrogen are examined. Different scenarios explore energy demand energy losses fuel consumption and cost-effectiveness. The methodology explores how variation in the ferry's total weight and equipment efficiency across scenarios impact results. Applied to an existing diesel high-speed ferry on one of Norway's longest routes the study under certain assumptions identifies compressed hydrogen gas as the current most economical option despite its higher energy consumption. Although the energy consumption of the compressed hydrogen ferry is slightly more than the liquid hydrogen counterpart its operating expenses are considerably lower and comparable to the existing diesel ferry on the route. However constructing large hydrogen liquefaction plants could reduce liquid hydrogen's cost and make it competitive with both diesel and compressed hydrogen gas. Moreover liquid hydrogen allows the use of a superconducting motor to enhance efficiency. Operating the ferry with liquid hydrogen and a superconducting motor besides its technical advantages offers promising economic viability in the future comparable to diesel and compressed hydrogen gas options. Reducing the ferry's speed and optimizing equipment improves fuel efficiency and economic viability. This research provides valuable insights into sustainable zero-emission high-speed ferries powered by green hydrogen.
Investigation of a New Holistic Energy System for a Sustainable Airport with Green Hydrogen Fuels
Jun 2024
Publication
The advancement of sustainable solutions through renewable energy sources is crucial to mitigate carbon emissions. This study reports a novel system for an airport utilizing geothermal biomass and PV solar energy sources. The proposed system is capable of producing five useful outputs including electrical power hot water hydrogen kerosene and space heating. In open literature there has been no system reported with these combination of energy sources and outputs. The system is considered for Vancouver Airport using the most recent statistics available. The geothermal sub-system introduced is also unique which utilizes carbon dioxide captured as the heat transfer medium for power generation and heating. The present system is considered using thermodynamic analysis through energetic and exergetic approaches to determine the variation in system performance based on different annual climate conditions. Biomass gasification and kerosene production are evaluated based on the Aspen Plus models. The efficiencies of the geothermal system with the carbon dioxide reservoir are found to have energetic and energetic efficiencies of 78 % and 37 % respectively. The total hydrogen production projection is obtained to be 452 tons on an annual basis. The kerosene production mass flow rate is reported as 0.112 kg/s. The overall energetic and exergetic efficiencies of the system are found to be 41.8 % and 32.9 % respectively. This study offers crucial information for the aviation sector to adopt sustainable solutions more effectively.
Strategic Deployment of Hydrogen Fuel Cell Buses and Fueling Stations: Insights from Fleet Transition Models
Oct 2024
Publication
Establishing new hydrogen value chains is challenging requiring economies of scale and balanced supplydemand dynamics. Municipalities can mitigate this risk through government support and deployment strategies. This study analyzes Edmonton’s transition to zero-emission buses (ZEBs) focusing on hydrogen fuel cell electric vehicles (HFCEVs) and hydrogen fueling stations (HFSs). Using scenario-based modeling and S-curve models for technology diffusion we project the adoption of battery electric vehicles (BEVs) and HFCEVs. Deploying over 1000 ZEBs by 2040 is necessary to meet Net-Zero targets with 310–760 HFCEVs required for the municipal bus inventory. This results in an estimated hydrogen demand of 6.2–14.5 t-H2/day and a reduction of 0.4–1.0 Mt-CO2 in tailpipe emissions by 2050. We use these scenario projections to develop a phased deployment strategy optimizing fleet operations to reduce HFS costs by 50–60% from 8 to 9 C$/kg-H2 to 3–4 C$/kg-H2. The study underscores the importance of strategic planning and infrastructure investment in realizing net-zero goals providing a model applicable globally.
Hydrogen Storage Performance During Underground Hydrogen Storage in Depleted Gas Reservoirs: A Review
Mar 2024
Publication
Hydrogen has emerged as a promising alternative to meet the growing demand for sustainable and renewable energy sources. Underground hydrogen storage (UHS) in depleted gas reservoirs holds significant potential for large-scale energy storage and the seamless integration of intermittent renewable energy sources due to its capacity to address challenges associated with the intermittent nature of renewable energy sources ensuring a steady and reliable energy supply. Leveraging the existing infrastructure and well-characterized geological formations depleted gas reservoirs offer an attractive option for large-scale hydrogen storage implementation. However significant knowledge gaps regarding storage performance hinder the commercialization of UHS operation. Hydrogen deliverability hydrogen trapping and the equation of state are key areas with limited understanding. This literature review critically analyzes and synthesizes existing research on hydrogen storage performance during underground storage in depleted gas reservoirs; it then provides a high-level risk assessment and an overview of the techno-economics of UHS. The significance of this review lies in its consolidation of current knowledge highlighting unresolved issues and proposing areas for future research. Addressing these gaps will advance hydrogen-based energy systems and support the transition to a sustainable energy landscape. Facilitating efficient and safe deployment of UHS in depleted gas reservoirs will assist in unlocking hydrogen’s full potential as a clean and renewable energy carrier. In addition this review aids policymakers and the scientific community in making informed decisions regarding hydrogen storage technologies.
Towards a Sustainable Future: Bio-hydrogen Production from Food Waste for Clean Energy Generation
Jan 2024
Publication
To address climate change energy security and waste management new sustainable energy sources must be developed. This study uses Aspen Plus software to extract bio-H2 from food waste with the goal of efficiency and environmental sustainability. Anaerobic digestion optimised to operate at 20-25°C and keep ammonia at 3% greatly boosted biogas production. The solvent [Emim][FAP] which is based on imidazolium had excellent performance in purifying biogas. It achieved a high level of methane purity while consuming a minimal amount of energy with a solvent flow rate of 13.415 m³/h. Moreover the utilization of higher temperatures (600-700°C) during the bio-H2 generation phase significantly enhanced both the amount and quality of hydrogen produced. Parametric and sensitivity assessments were methodically performed at every stage. This integrated method was practicable and environmentally friendly according to the economic assessment. H2 generation using steam reforming results in a TCC of 1.92×106 USD. The CO2 separation step has higher costs (TCC of 2.15×107 USD) due to ionic liquid washing and CO2 liquefaction. Compressor electricity consumption significantly impacts total operating cost (TOC) totaling 4.73×108 USD. showing its ability to reduce greenhouse gas emissions optimize resource utilization and promote energy sustainability. This study presents a sustainable energy solution that addresses climate and waste challenges.
Optimizing Green Hydrogen Strategies in Tunisia: A Combined SWOT-MCDM Approach
Oct 2024
Publication
Tunisia's rapid industrial expansion and population growth have created a pressing energy deficit despite the country's significant yet largely untapped renewable energy potential. This study addressed this challenge by developing a comprehensive framework to identify and evaluate strategies for promoting green hydrogen production from renewable energy sources in Tunisia. A Strength Weakness Opportunity and Threat (SWOT) analysis incorporating social economic and environmental dimensions was conducted to formulate potential solutions. The Step-wise Weight Assessment Ratio Analysis (SWARA) method facilitated the weighting of SWOT factors and subfactors. Subsequently a multi-criteria decision-making approach employing the gray technique for order preference by similarity to ideal solution (TOPSIS-G) method (validated by gray additive ratio assessment (ARAS-G) gray complex proportional assessment (COPRAS-G) and gray multi-objective optimization by ratio analysis (MOORA-G) was used to rank the identified strategies. The SWOT analysis revealed "Strengths" as the most influential factor with a relative weight of 47.3% followed by "Weaknesses" (26.5%) "Threats" (15.6%) and "Opportunities" (10.6%). Specifically experts emphasized Tunisia's renewable energy potential (21.89%) and robust power system (12.11%) as primary strengths. Conversely high investment costs (11.2%) and political instability (7.77%) posed substantial threat. Positive socio-economic impacts represented a key opportunity with a score of 5.2%. As for the strategies prioritizing criteria production cost ranked first with a score of 13.5% followed by environmental impact (12.8%) renewable energy potential (12.0%) and mitigation costs (11.3%). The gray TOPSIS analysis identified two key strategies: leveraging Tunisia's wind and solar resources and fostering regional cooperation for project implementation. The robustness of these strategies is confirmed by the strong correlation between TOPSIS-G ARAS-G COPRAS-G and MOORA-G results. Overall the study provides a comprehensive roadmap and expert-informed decision-support tools offering valuable insights for policymakers investors and stakeholders in Tunisia and other emerging economies facing similar energy challenges.
Tapping the Conversation on the Meaning of Decarbonization: Discourses and Discursive Agency in EU Politics on Low-Carbon Fuels for Maritime Shipping
Jun 2024
Publication
EU politics on decarbonizing shipping is an argumentative endeavor where different policy actors strive try to influence others to see problems and policy solutions according to their perspectives to gain monopoly on the framing and design of policies. This article critically analyzes by means of argumentative discourse analysis the politics and policy process related to the recent adoption of the FuelEU Maritime regulation the world’s first legislation to set requirements for decarbonizing maritime shipping. Complementing previous research focusing on the roles and agency of policy entrepreneurs and beliefs of advocacy coalitions active in the policy process this paper dives deeper into the politics of the new legislation. It aims to explore and explain the discursive framing and politics of meaning-making. By analyzing the political and social meaning-making of the concept “decarbonizing maritime shipping” this paper helps us understand why the legislation was designed in the way it was. Different narratives storylines and discourses defining different meanings of decarbonization are analyzed. So is the agency of policy actors trying to mutate the different meanings into a new meaning. Two discourses developed in dialectic conversation framed the policy proposals and subsequent debates in the policy process focusing on (i) incremental change and technology neutrality to meet moderate emission reductions and maintain competitiveness and (ii) transformative change and technology specificity to meet zero emissions and gain competitiveness and global leadership in the transition towards a hydrogen economy. Policy actors successfully used discursive agency strategies such as multiple functionality and vagueness to navigate between and resolve conflicts between the two discourses. Both discourses are associated with the overarching ecological modernization discourse and failed to include issue of climate justice and a just transition. The heritage of the ecological modernization discourse creates lock-ins for a broader decarbonization discourse thus stalling a just transition.
Hydrogen-Based Energy Systems: Current Technology Development Status, Opportunities and Challenges
Dec 2023
Publication
The use of hydrogen as an energy carrier within the scope of the decarbonisation of the world’s energy production and utilisation is seen by many as an integral part of this endeavour. However the discussion around hydrogen technologies often lacks some perspective on the currently available technologies their Technology Readiness Level (TRL) scope of application and important performance parameters such as energy density or conversion efficiency. This makes it difficult for the policy makers and investors to evaluate the technologies that are most promising. The present study aims to provide help in this respect by assessing the available technologies in which hydrogen is used as an energy carrier including its main challenges needs and opportunities in a scenario in which fossil fuels still dominate global energy sources but in which renewables are expected to assume a progressively vital role in the future. The production of green hydrogen using water electrolysis technologies is described in detail. Various methods of hydrogen storage are referred including underground storage physical storage and material-based storage. Hydrogen transportation technologies are examined taking into account different storage methods volume requirements and transportation distances. Lastly an assessment of well-known technologies for harnessing energy from hydrogen is undertaken including gas turbines reciprocating internal combustion engines and fuel cells. It seems that the many of the technologies assessed have already achieved a satisfactory degree of development such as several solutions for high-pressure hydrogen storage while others still require some maturation such as the still limited life and/or excessive cost of the various fuel cell technologies or the suitable operation of gas turbines and reciprocating internal combustion engines operating with hydrogen. Costs below 200 USD/kWproduced lives above 50 kh and conversion efficiencies approaching 80% are being aimed at green hydrogen production or electricity production from hydrogen fuel cells. Nonetheless notable advances have been achieved in these technologies in recent years. For instance electrolysis with solid oxide cells may now sometimes reach up to 85% efficiency although with a life still in the range of 20 kh. Conversely proton exchange membrane fuel cells (PEMFCs) working as electrolysers are able to sometimes achieve a life in the range of 80 kh with efficiencies up to 68%. Regarding electricity production from hydrogen the maximum efficiencies are slightly lower (72% and 55% respectively). The combination of the energy losses due to hydrogen production compression storage and electricity production yields overall efficiencies that could be as low as 25% although smart applications such as those that can use available process or waste heat could substantially improve the overall energy efficiency figures. Despite the challenges the foreseeable future seems to hold significant potential for hydrogen as a clean energy carrier as the demand for hydrogen continues to grow particularly in transportation building heating and power generation new business prospects emerge. However this should be done with careful regard to the fact that many of these technologies still need to increase their technological readiness level before they become viable options. For this an emphasis needs to be put on research innovation and collaboration among industry academia and policymakers to unlock the full potential of hydrogen as an energy vector in the sustainable economy.
Investigation of a Community-based Clean Energy System Holistically with Renewable and Hydrogen Energy Options for Better Sustainable Development
Jan 2024
Publication
This study develops a novel community-based integrated energy system where hydrogen and a combination of renewable energy sources are considered uniquely for implementation. In this regard three different communities situated in Kenya the United States and Australia are studied for hydrogen production and meeting the energy demands. To provide a variety of energy demands this study combines a multigenerational geothermal plant with a hybrid concentrated solar power and photovoltaic solar plant. Innovations in hydrogen production and renewable energy are essential for reducing carbon emissions. By combining the production of hydrogen with renewable energy sources this system seeks to move away from the reliance on fossil fuels and toward sustainability. The study investigates various research subjects using a variety of methods. The performance of the geothermal source is considered through energetic and exergetic thermodynamic analysis. The software System Advisor Model (SAM) and RETscreen software packages are used to analyze the other sub-systems including Concentrate Solar PV solar and Combined Heat and Power Plant. Australian American and Kenyan communities considered for this study were found to have promising potential for producing hydrogen and electricity from renewable sources. The geothermal output is expected to be 35.83 MW 122.8 MW for space heating 151.9 MW for industrial heating and 64.25 MW for hot water. The overall geothermal energy and exergy efficiencies are reported as 65.15% and 63.54% respectively. The locations considered are expected to have annual solar power generation and hydrogen production capacities of 158MW 237MW 186MW 235 tons 216 tons and 313 tons respectively.
Hydrogen Energy Systems: Technologies, Trends, and Future Prospects
May 2024
Publication
This review critically examines hydrogen energy systems highlighting their capacity to transform the global energy framework and mitigate climate change. Hydrogen showcases a high energy density of 120 MJ/kg providing a robust alternative to fossil fuels. Adoption at scale could decrease global CO2 emissions by up to 830 million tonnes annually. Despite its potential the expansion of hydrogen technology is curtailed by the inefficiency of current electrolysis methods and high production costs. Presently electrolysis efficiencies range between 60 % and 80 % with hydrogen production costs around $5 per kilogram. Strategic advancements are necessary to reduce these costs below $2 per kilogram and push efficiencies above 80 %. Additionally hydrogen storage poses its own challenges requiring conditions of up to 700 bar or temperatures below −253 °C. These storage conditions necessitate the development of advanced materials and infrastructure improvements. The findings of this study emphasize the need for comprehensive strategic planning and interdisciplinary efforts to maximize hydrogen's role as a sustainable energy source. Enhancing the economic viability and market integration of hydrogen will depend critically on overcoming these technological and infrastructural challenges supported by robust regulatory frameworks. This comprehensive approach will ensure that hydrogen energy can significantly contribute to a sustainable and low-carbon future.
Research on Fast Frequency Response Control Strategy of Hydrogen Production Systems
Mar 2024
Publication
With the large-scale integration of intermittent renewable energy generation presented by wind and photovoltaic power the security and stability of power system operations have been challenged. Therefore this article proposes a control strategy of a hydrogen production system based on renewable energy power generation to enable the fast frequency response of a grid. Firstly based on the idea of virtual synchronous control a fast frequency response control transformation strategy for the grid-connected interface of hydrogen production systems for renewable energy power generation is proposed to provide active power support when the grid frequency is disturbed. Secondly based on the influence of VSG’s inertia and damping coefficient on the dynamic characteristics of the system a VSG adaptive control model based on particle swarm optimization is designed. Finally based on the Matlab/Simulink platform a grid-connected simulation model of hydrogen production systems for renewable energy power generation is established. The results show that the interface-transformed electrolytic hydrogen production device can actively respond to the frequency disturbances of the power system and participate in primary frequency control providing active support for the frequency stability of the power system under high-percentage renewable energy generation integration. Moreover the system with parameter optimization has better fast frequency response control characteristics.
Effect of Gas Composition and Initial Turbulence on the Propagation Dynamics of Premixed Flames of Hydrogen-blended Natural Gas Fuel
Jul 2024
Publication
In order to reduce carbon emissions the effects of gas composition and initial turbulence on the premixed flame dynamics of hydrogen-blended natural gas were investigated. The results show that an increase in hydrogen content leads to earlier formation of flame wrinkles. When the equivalence ratio is 1 and hydrogen blending ratio is below 20% Tulip flames appear approximately 2.25 m away from the ignition point. When hydrogen blending ratio exceeds 20% Tulip flames appear approximately 1.3 m away from the ignition point and twisted Tulip flames appear approximately 2.5 m away from the ignition position. During the 0.05 m process of flame propagation downstream from ignition point flame propagation velocity increases by about 2 m/s for every 10% increase in hydrogen content. The increase in hydrogen content has the most significant impact on the flame propagation velocity during the ignition stage. The average flame propagation velocity increases with the increase of hydrogen blending ratio. The greater the initial turbulence the more obvious the stretching deformation of flame front structure. With the increase of wind speed the flame propagation velocity first increases and then decreases. At a wind speed of 3 m/s the flame propagation velocity reaches its maximum value.
Comparative Study of Electric and Hydrogen Mobility Infrastructures for Sustainable Public Transport: A PyPSA Optimization for a Remote Island Context
Jul 2024
Publication
Decarbonizing road transportation is vital for addressing climate change given that the sector currently contributes to 16% of global GHG emissions. This paper presents a comparative analysis of electric and hydrogen mobility infrastructures in a remote context i.e. an off-grid island. The assessment includes resource assessment and sizing of renewable energy power plants to facilitate on-site self-production. We introduce a comprehensive methodology for sizing the overall infrastructure and carry out a set of techno-economic simulations to optimize both energy performance and cost-effectiveness. The levelized cost of driving at the hydrogen refueling station is 0.40 e/km i.e. 20% lower than the electric charging station. However when considering the total annualized cost the battery-electric scenario (110 ke/year) is more favorable compared to the hydrogen scenario (170 ke/year). To facilitate informed decision-making we employ a multi-criteria decision-making analysis to navigate through the techno-economic findings. When considering a combination of economic and environmental criteria the hydrogen mobility infrastructure emerges as the preferred solution. However when energy efficiency is taken into account electric mobility proves to be more advantageous.
Overview and Prospects of Low-emissions Hydrogen (H2) Energy Systems: Roadmap for a Sustainable H2 Economy
Jul 2024
Publication
Hydrogen (2 ) has a big role to play in energy transition to achieve net-zero carbon emissions by 2050. For 2 to compete with other fuels in the energy market more research is required to mitigate key issues like greenhouse gas (GHG) emissions safety and end-use costs. For these reasons a software-supported technical overview of 2 production storage transportation and utilisation is introduced. Drawbacks and mitigation approaches for 2 technologies were highlighted. The recommended areas include solar thermal or renewable-powered plasma systems for feedstock preheating and oxy-hydrogen combustion to meet operating temperatures and heat duties due to losses; integration of electrolysis of 2 into hydrocarbon reforming methods to replace air separation unit (ASU); use of renewable power sources for electrical units and the introduction of thermoelectric units to maximise the overall efficiency. Furthermore a battolyser system for small-scale energy storage; new synthetic hydrides with lower absorption and desorption energy; controlled parameters and steam addition to the combustor/cylinder and combustors with fitted heat exchangers to reduce emissions and improve the overall efficiency are also required. This work also provided detailed information on any of these systems implementations based on location factors and established a roadmap for 2 production and utilisation. The proposed 2 production technologies are hybrid pyrolysis-electrolysis and integrated AD-MEC and DR systems using renewable bioelectrochemical and low-carbon energy systems. Production and utilisation of synthetic natural gas (NG) using renewablepowered electrolysis of 2 oxy-fuel and direct air capture (DAC) is another proposed 2 energy system for a sustainable 2 economy. By providing these factors and information researchers can work towards pilot development and further efficiency enhancement.
Pressure Decline and Gas Expansion in Underground Hydrogen Storage: A Pore-scale Percolation Study
Aug 2024
Publication
Using high-resolution micro-CT imaging at 2.98 μm/voxel we compared the percolation of hydrogen in gas injection with gas expansion for a hydrogen-brine system in Bentheimer sandstone at 1 MPa and 20 ◦C representing hydrogen storage in an aquifer. We introduced dimensionless numbers to quantify the contribution of advection and expansion to displacement. We analysed the 3D spatial distribution of gas and its displacement in both cases and demonstrated that in gas injection hydrogen can only advance from a connected cluster in an invasion-percolation type process while in gas expansion hydrogen can access more of the pore space even from disconnected clusters. The average gas saturation in the sample increased from 30% to 50% by gas expansion and we estimated that 10% of the expanded volume is attributed to hydrogen exsolution from the brine. This work emphasises the importance of studying the combined effects of pressure decline and gas withdrawal in hydrogen storage to assess the influence of gas expansion on remobilising trapped gases.
Transitioning to a Renewable Hydrogen System: Optimal Infrastructure for Self-sufficient Hydrogen Supply in Austria by 2030
Aug 2024
Publication
In this study we employ an optimization model to optimally design a self-sufficient independent of any imports and exports hydrogen infrastructure for Austria by 2030. Our approach integrates key hydrogen technologies within a detailed spatial investment and operation model – coupled with a European scale electricity market model. We focus on optimizing diverse infrastructure componentsincluding trailers pipelines electrolyzers and storages to meet Austria's projected hydrogen demand. To accurately estimate this demand in hourly resolution we combine existing hydrogen strategies and projections to account for developments in various industrial sectors consider demand driven by the transport sector and integrate hydrogen demand arising from its use in gas-powered plants. Accounting for the inherent uncertainty linked to such projections we run the analysis for two complementary scenarios. Our approach addresses the challenges of integrating large quantities of renewable hydrogen into a future energy system by recognizing the critical role of domestic production in the early market stages. The main contribution of this work is to address the gap in optimizing hydrogen infrastructure for effective integration of domestic renewable hydrogen production in Austria by 2030 considering sector coupling potentials optimal electrolyzer placement and the design of local hydrogen networks.
Hydrogen Blending in Natural Gas Grid: Energy, Environmental, and Economic Implications in the Residential Sector
Jul 2024
Publication
The forthcoming implementation of national policies towards hydrogen blending into the natural gas grid will affect the technical and economic parameters that must be taken into account in the design of building heating systems. This study evaluates the implications of using hydrogenenriched natural gas (H2NG) blends in condensing boilers and Gas Adsorption Heat Pumps (GAHPs) in a residential building in Rome Italy. The analysis considers several parameters including nonrenewable primary energy consumption CO2 emissions Levelized Cost of Heat (LCOH) and Carbon Abatement Cost (CAC). The results show that a 30% hydrogen blend achieves a primary energy consumption reduction of 12.05% and 11.19% in boilers and GAHPs respectively. The presence of hydrogen in the mixture exerts a more pronounced influence on the reduction in fossil primary energy and CO2 emissions in condensing boilers as it enhances combustion efficiency. The GAHP system turns out to be more cost-effective due to its higher efficiency. At current hydrogen costs the LCOH of both technologies increases as the volume fraction of hydrogen increases. The forthcoming cost reduction in hydrogen will reduce the LCOH and the decarbonization cost for both technologies. At low hydrogen prices the CAC for boilers is lower than for GAHPs; therefore replacing boilers with other gas technologies rather than electric heat pumps increases the risk of creating stranded assets. In conclusion blending hydrogen into the gas grid can be a useful policy to reduce emissions from the overall natural gas consumption during the process of end-use electrification while stimulating the development of a hydrogen economy.
Forecasting the Development of Clean Energy Vehicles in Large Cities: A System Dynamics Perspective
Jan 2024
Publication
Clean energy vehicles (CEVs) e.g. battery electric vehicles (BEVs) and fuel cell electric vehicles (FCEVs) are being adopted gradually to substitute for internal combustion engine vehicles (ICEVs) around the world. The fueling infrastructure is one of the key drivers for the development of the CEV market. When the government develops funding policies to support the fueling infrastructure development for FCEVs and BEVs it has to assess the effectiveness of different policy options and identify the optimal policy combination which is very challenging in transportation research. In this paper we develop a system dynamics model to study the feedback mechanism between the fueling infrastructure funding policies and the medium- to long-term diffusion of FCEVs and BEVs and the competition between FCEVs and BEVs based on relevant policy and market data in Guangzhou China. The results of the modeling analysis are as follows. (1) Funding hydrogen refueling stations and public charging piles has positive implications for achieving the substitution of CEVs for ICEVs. (2) Adjusting the funding ratio of hydrogen refueling stations and public charging piles or increasing the funding budget and extending the funding cycle does not have a significant impact on the overall substitution of CEVs for ICEVs but only impacts the relative competitive advantage between FCEVs and BEVs. (3) An equal share of funding for hydrogen refueling stations and public charging piles would have better strategic value for future net-zero-emissions urban transportation. (4) Making a moderate-level full investment in hydrogen refueling stations coupled with hydrogen refueling subsidies can provide the ideal conditions for FCEV diffusion.
Impact of Green Hydrogen on Climate Change in Peru: An Analysis of Perception, Policies, and Cooperation
Oct 2024
Publication
This research analyzed the impact of green hydrogen (GH) on the dynamics of combating climate change (CC) in Peru for the year 2024 contributing to Sustainable Development Goal 7 focused on affordable and clean energy. The study quantitative and non-experimental in nature used a cross-sectional design and focused on a sample composed of public and private sector officials energy experts and academics evaluating their perception and knowledge about GH and its application in climate policies. The data collection instrument showed good internal consistency with a Cronbach’s alpha value of 0.793. The results revealed that although the adoption of GH is in its early stages it is already considered a vital component in national CC mitigation strategies. A medium positive correlation was identified using the Spearman coefficient (0.418) between GH usage and the effectiveness of mitigation policies as well as its capacity to influence public awareness and promote interinstitutional cooperation. Furthermore it was concluded that the success of GH largely depends on the strengthening of regulatory frameworks investment in infrastructure and the promotion of strategic alliances to facilitate its integration into the national energy matrix. These findings highlight the importance of continuing to develop public policies that promote the use of GH ensuring its sustainability and effectiveness in the fight against climate change in Peru.
A Review of Hydrogen Leak Detection Regulations and Technologies
Aug 2024
Publication
Hydrogen (H2 ) is positioned as a key solution to the decarbonization challenge in both the energy and transportation sectors. While hydrogen is a clean and versatile energy carrier it poses significant safety risks due to its wide flammability range and high detonation potential. Hydrogen leaks can occur throughout the hydrogen value chain including production storage transportation and utilization. Thus effective leak detection systems are essential for the safe handling storage and transportation of hydrogen. This review aims to survey relevant codes and standards governing hydrogen-leak detection and evaluate various sensing technologies based on their working principles and effectiveness. Our analysis highlights the strengths and limitations of the current detection technologies emphasizing the challenges in achieving sensitive and specific hydrogen detection. The results of this review provide critical insights into the existing technologies and regulatory frameworks informing future advancements in hydrogen safety protocols.
Critical Perspective on Green Hydrogen-based Seasonal Operation of Energy-intensive Industry Sectors with Solid Products
Nov 2024
Publication
In the light of a future decarbonized power grid based primarily on non-dispatchable renewable energy sources the operation of industrial plants should be decarbonized and flexible. An innovative novel concept combining industrial plants with (i) a water electrolysis unit (ii) a hydrogen storage unit and (iii) a fuel cell unit would enable seasonal supply-demand balancing in the local power grid and storage of surplus energy in the form of stable solid products. The feasibility of this concept was demonstrated in a case study taking into account the overall energy balance and economics. The characteristics of the local power grid and the hydrogen round-trip efficiency must be carefully considered when dimensioning the hydrogen units. It was found that industries producing iron and steel cement ceramics glass aluminum paper and other metals have the potential for seasonal operation. Future research efforts in the fields of technology economics and social sciences should support the sustainable flexibility transition of energy-intensive industries with solid products.
Innovative Hybrid Energy Storage Systems with Sustainable Integration of Green Hydrogen and Energy Management Solutions for Standalone PV Microgrids Based on Reduced Fractional Gradient Descent Algorithm
Oct 2024
Publication
This paper investigates innovative solutions to enhance the performance and lifespan of standalone photovoltaic (PV)-based microgrids with a particular emphasis on off-grid communities. A major challenge in these systems is the limited lifespan of batteries. To overcome this issue researchers have created hybrid energy storage systems (HESS) along with advanced power management strategies. This study introduces innovative multi-level HESS approaches and a related energy management strategy designed to alleviate the charge/discharge stress on batteries. Comprehensive Matlab Simulink models of various HESS topologies within standalone PV microgrids are utilized to evaluate system performance under diverse weather conditions and load profiles for rural site. The findings reveal that the proposed HESS significantly extends battery life expectancy compared to existing solutions. Furthermore the paper presents a novel energy management strategy based on the Reduced Fractional Gradient Descent (RFGD) algorithm optimization tailored for hybrid systems that include photovoltaic fuel cell battery and supercapacitor components. This strategy aims to minimize hydrogen consumption of Fuel Cells (FCs) thereby supporting the production of green ammonia for local industrial use. The RFGD algorithm is selected for its minimal user-defined parameters and high convergence efficiency. The proposed method is compared with other algorithms such as the Lyrebird Optimization Algorithm (LOA) and Osprey Optimization Algorithm (OOA). The RFGD algorithm exhibits superior accuracy in optimizing energy management achieving a 15% reduction in hydrogen consumption. Its efficiency is evident from the reduced computational time compared to conventional algorithms. Although minor losses in computational resources were observed they were substantially lower than those associated with traditional optimization techniques. Overall the RFGD algorithm offers a robust and efficient solution for enhancing the performance of hybrid energy systems.
Capacity Expansion Planning of Hydrogen-Enabled Industrial Energy Systems for Carbon Dioxide Peaking
Jul 2024
Publication
As the main contributor of carbon emissions the low-carbon transition of the industrial sector is important for achieving the goal of carbon dioxide peaking. Hydrogen-enabled industrial energy systems (HIESs) are a promising way to achieve the low-carbon transition of industrial energy systems since the hydrogen can be well coordinated with renewable energy sources and satisfy the high and continuous industrial energy demand. In this paper the long-term capacity expansion planning problem of the HIES is formulated from the perspective of industrial parks and the targets of carbon dioxide peaking and the gradual decommissioning of existing equipment are considered as constraints. The results show that the targets of carbon dioxide peaking before different years or with different emission reduction targets can be achieved through the developed method while the economic performance is ensured to some extent. Meanwhile the overall cost of the strategy based on purchasing emission allowance is three times more than the cost of the strategy obtained by the developed method while the emissions of the two strategies are same. In addition long-term carbon reduction policies and optimistic expectations for new energy technologies will help industrial parks build more new energy equipment for clean transformation.
Closed Loop Model Predictive Control of a Hybrid Battery-Hydrogen Energy Storage System using Mixed-Integer Linear Programming
Mar 2024
Publication
The derivation of an efficient operational strategy for storing intermittent renewable energies using a hybrid battery-hydrogen energy storage system is a difficult task. One approach for deriving an efficient operational strategy is using mathematical optimization in the context of model predictive control. However mathematical optimization derives an operational strategy based on a non-exact mathematical system representation for a specified prediction horizon to optimize a specified target. Thus the resulting operational strategies can vary depending on the optimization settings. This work focuses on evaluating potential improvements in the operational strategy for a hybrid batteryhydrogen energy storage system using mathematical optimization. To investigate the operation a simulation model of a hybrid energy storage system and a tailor-made mixed integer linear programming optimization model of this specific system are utilized in the context of a model predictive control framework. The resulting operational strategies for different settings of the model predictive control framework are compared to a rule-based controller to show the potential benefits of model predictive control compared to a conventional approach. Furthermore an in-depth analysis of different factors that impact the effectiveness of the model predictive controller is done. Therefore a sensitivity analysis of the effect of different electricity demands and resource sizes on the performance relative to a rule-based controller is conducted. The model predictive controller reduced the energy consumption by at least 3.9 % and up to 17.9% compared to a rule-based controller. Finally Pareto fronts for multi-objective optimizations with different prediction and control horizons are derived and compared to the results of a rule-based controller. A cost reduction of up to 47 % is achieved by a model predictive controller with a prediction horizon of 7 days and perfect foresight. Keywords: Model Predictive Control Optimization Mixed Integer Linear Programming Hybrid Battery-Hydrogen Energy Storage System
Generalized Thermodynamic Modelling of Hydrogen Storage Tankes for Truck Application
Mar 2024
Publication
Hydrogen-driven heavy-duty trucks are a promising technology for reducing CO2 emissions in the transportation sector. Thus storing hydrogen efficiently onboard is vital. The three available or currently developed physical hydrogen storage technologies (compressed gaseous subcooled liquid and cryo-compressed hydrogen) are promising solutions. For a profound thermodynamic comparison of these storage systems a universally applicable model is required. Thus this article introduces a generalized thermodynamic model and conducts thermodynamic comparisons in terms of typical drive cycle scenarios. Therefore a model introduced by Hamacher et al. [1] for cryo-compressed hydrogen tanks is generalized by means of an explicit model formulation using the property ��2� from REFPROP [2] which is understood as a generic specific isochoric two-phase heat capacity. Due to an implemented decision logic minor changes to the equation system are automatically made whenever the operation mode or phase of the tank changes. The resulting model can simulate all three storage tank systems in all operating scenarios and conditions in the single- and two-phase region. Additionally the explicit model formulation provides deeper insights into the thermodynamic processes in the tank. The model is applied to the three physical hydrogen storage technologies to compare drive cycles heat requirement dormancy behavior and optimal usable density. The highest driving ranges were achieved with cryo-compressed hydrogen however it also comes with higher heating requirements compared to subcooled liquid hydrogen.
Shorter Message, Stronger Framing Increases Societal Acceptance for Hydrogen
Feb 2024
Publication
With the question of ‘can short messages be effective in increasing public support for a complex new technology (hydrogen)?‘ this study uses a representative national survey in Australia to analyze the differences and variations in subjective support for hydrogen in response to four differently framed short messages. The findings of this study show that short messages can increase social acceptance but the effects depend on how strongly the message is framed in terms of its alignment with either an economic or environmental values framework. Furthermore the effects depend on the social and cultural context of the receiver of the message.
The Technical and Economic Aspects of Integrating Energy Sectors for Climate Neutrality
Sep 2024
Publication
With the development of an energy sector based on renewable primary sources structural changes are emerging for the entire national energy system. Initially it was estimated that energy generation based on fossil fuels would decrease until its disappearance. However the evolution of CO2 capture capacity leads to a possible coexistence for a certain period with the renewable energy sector. The paper develops this concept of the coexistence of the two systems with the positioning of green hydrogen not only within the renewable energy sector but also as a transformation vector for carbon dioxide captured in the form of synthetic fuels such as CH4 and CH3OH. The authors conducted pilot-scale research on CO2 capture with green H2 both for pure (captured) CO2 and for CO2 found in combustion gases. The positive results led to the respective recommendation. The research conducted by the authors meets the strict requirements of the current energy phase with the authors considering that wind and solar energy alone are not sufficient to meet current energy demand. The paper also analyzes the economic aspects related to price differences for energy produced in the two sectors as well as their interconnection. The technical aspect as well as the economic aspect of storage through various other solutions besides hydrogen has been highlighted. The development of the renewable energy sector and its demarcation from the fossil fuel energy sector even with the transcendent vector represented by green hydrogen leads to the deepening of dispersion aspects between the electricity sector and the thermal energy sector a less commonly mentioned aspect in current works but of great importance. The purpose of this paper is to highlight energy challenges during the current transition period towards climate neutrality along with solutions proposed by the authors to be implemented in this phase. The current stage of combustion of the CH4 − H2 mixture imposes requirements for the capture of the resulting CO2.
Active Energy Management Based on Meta-Heuristic Algorithms of Fuel Cell/Battery/Supercapacitor Energy Storage System for Aircraft
Mar 2021
Publication
This paper presents the application of an active energy management strategy to a hybrid system consisting of a proton exchange membrane fuel cell (PEMFC) battery and supercapacitor. The purpose of energy management is to control the battery and supercapacitor states of charge (SOCs) as well as minimizing hydrogen consumption. Energy management should be applied to hybrid systems created in this way to increase efficiency and control working conditions. In this study optimization of an existing model in the literature with different meta-heuristic methods was further examined and results similar to those in the literature were obtained. Ant lion optimizer (ALO) moth-flame optimization (MFO) dragonfly algorithm (DA) sine cosine algorithm (SCA) multi-verse optimizer (MVO) particle swarm optimization (PSO) and whale optimization algorithm (WOA) meta-heuristic algorithms were applied to control the flow of power between sources. The optimization methods were compared in terms of hydrogen consumption and calculation time. Simulation studies were conducted in Matlab/Simulink R2020b (academic license). The contribution of the study is that the optimization methods of ant lion algorithm moth-flame algorithm and sine cosine algorithm were applied to this system for the first time. It was concluded that the most effective method in terms of hydrogen consumption and computational burden was the sine cosine algorithm. In addition the sine cosine algorithm provided better results than similar meta-heuristic algorithms in the literature in terms of hydrogen consumption. At the same time meta-heuristic optimization algorithms and equivalent consumption minimization strategy (ECMS) and classical proportional integral (PI) control strategy were compared as a benchmark study as done in the literature and it was concluded that meta-heuristic algorithms were more effective in terms of hydrogen consumption and computational time.
CFD Model of Refuelling through the Entire Equipment of a Hydrogen Refuelling Station
Dec 2023
Publication
This paper aims at the development and validation of a computational fluid dynamic (CFD) model for simulations of the refuelling process through the entire equipment of the hydrogen refuelling station (HRS). The absence of such models hinders the design of inherently safer refuelling protocols for an arbitrary combination of HRS equipment hydrogen storage parameters and environmental conditions. The CFD model is validated against the complete process of refuelling lasting 195s in Test No.1 performed by the National Renewable Energy Laboratory (NREL). The test equipment includes high-pressure tanks of HRS pressure control valve (PCV) valves pipes breakaway hose and nozzle all the way up to three onboard tanks. The model accurately reproduced hydrogen temperature and pressure through the entire line of HRS equipment. A standout feature of the CFD model distinguishing it from simplified models is the capability to predict temperature non-uniformity in onboard tanks a crucial factor with significant safety implications.
Optimizing Alkaline Water Electrolysis: A Dual-Model Approach for Enhanced Hydrogen Production Efficiency
Nov 2024
Publication
This study develops a semi-empirical model of an alkaline water electrolyzer (AWE) based on thermodynamic and electrochemical principles to investigate cell voltage behavior during electrolysis. By importing polarization curve test data under specific operational conditions eight undefined parameters are precisely fitted demonstrating the model’s high accuracy in describing the voltage characteristics of alkaline electrolyzers. Additionally an AWE system model is introduced to examine the influence of various operational parameters on system efficiency. This innovative approach not only provides detailed insights into the operational dynamics of AWE systems but also offers a valuable tool for optimizing performance and enhancing efficiency advancing the understanding and optimization of AWE technologies.
Techno-economic Analysis of Direct Air Carbon Capture and Hydrogen Production Integrated with a Small Modular Reactor
Dec 2023
Publication
This study aims to explore the techno-economic potential of harnessing waste heat from a Small Modular Reactor (SMR) to fuel Direct Air Carbon Capture (DACC) and High Temperature Steam Electrolysis (HTSE) technologies. The proposed system’s material flows and energy demands are modelled via the ASPEN Plus v12.1 where results are utilised to provide estimates of the Levelised Cost of DACC (LCOD) and Levelised Cost of Hydrogen (LCOH). The majority of thermal energy and electrical utilities are assumed to be supplied directly by the SMR. A sensitivity analysis is then performed to investigate the effects of core operational parameters of the system. Key results indicate levelised costs of 4.66 $/kgH2 at energy demands of 34.37 kWh/kgH2 and 0.02 kWh/kgH2 thermal for HTSE hydrogen production and 124.15 $/tCO2 at energy demands of 31.67 kWh/tCO2 and 126.33 kWh/tCO2 thermal for carbon capture; parameters with most impact on levelised costs are air intake and steam feed for LCOD and LCOH respectively. Both levelised costs i.e. LCOD and LCOH would decrease with the production scale. The study implies that an integrated system of DACC and HTSE provided the best cost-benefit results however the cost-benefit analysis is heavily subjective to geography politics and grid demand.
Pathways to the Hydrogen Economy: A Multidimensional Analysis of the Technological Innovation Systems of Germany and South Korea
Aug 2023
Publication
The global trend towards decarbonization and the demand for energy security have put hydrogen energy into the spotlight of industry politics and societies. Numerous governments worldwide are adopting policies and strategies to facilitate the transition towards hydrogen-based economies. To assess the determinants of such transition this study presents a comparative analysis of the technological innovation systems (TISs) for hydrogen technologies in Germany and South Korea both recognized as global front-runners in advancing and implementing hydrogen-based solutions. By providing a multi-dimensional assessment of pathways to the hydrogen economy our analysis introduces two novel and crucial elements to the TIS analysis: (i) We integrate the concept of ‘quality infrastructure’ given the relevance of safety and quality assurance for technology adoption and social acceptance and (ii) we emphasize the social perspective within the hydrogen TIS. To this end we conducted 24 semi-structured expert interviews applying qualitative open coding to analyze the data. Our results indicate that the hydrogen TISs in both countries have undergone significant developments across various dimensions. However several barriers still hinder the further realization of a hydrogen economy. Based on our findings we propose policy implications that can facilitate informed policy decisions for a successful hydrogen transition.
Performance and Cost Analysis of Hydrogen Production from Steam Reforming and Dehydrogenation of Ethanol
Aug 2020
Publication
Mitigation of carbon dioxide (CO2) emission has been a worldwide concern. Decreasing CO2 emission by converting it into higher value products such as methanol can be a promising way. However hydrogen (H2) cost and availability are one of key barriers to CO2 conversion. Ethanol can be a sustainable source for H2 due to its renewable nature and easy conversion to H2-rich gas mixtures through ethanol steam reforming process. Nevertheless steam reforming of ethanol generates CO2. Hence this research is focused on different methods of H2 productions about a 1665.47 t/y from ethanol for supplying to methanol plants was performed using Aspen PLUS V10. The ethanol steam reforming process required the lowest required ethanol feed for a certain amount of H2. In contrast the ethanol steam reforming process presented significant amount of CO2 emission from reaction and electricity consumption. But the ethanol dehydrogenation of ethanol not only generates H2 without CO2 emission from the reaction but also ethyl acetate or acetaldehyde which are value chemicals. However ethanol dehydrogenation processes in case II and III presented relatively higher cost because by-products (ethyl acetate or acetaldehyde) were rather difficult to be separated.
Thermodynamic Analysis of the Combustion Process in Hydrogen-Fueled Engines with EGR
Jun 2024
Publication
This article presents a novel approach to the analysis of heat release in a hydrogen-fueled internal combustion spark-ignition engine with exhaust gas recirculation (EGR). It also discusses aspects of thermodynamic analysis common to modeling and empirical analysis. This new approach concerns a novel method of calculating the specific heat ratio (cp/cv) and takes into account the reduction in the number of moles during combustion which is characteristic of hydrogen combustion. This reduction in the number of moles was designated as a molar contraction. This is particularly crucial when calculating the average temperature during combustion. Subsequently the outcomes of experimental tests including the heat-release rate the initial combustion phase (denoted CA0- 10) and the main combustion phase (CA10-90) are presented. Furthermore the impact of exhaust gas recirculation on the combustion process in the engine is also discussed. The efficacy of the proposed measures was validated by analyzing the heat-release rate and calculating the mean combustion temperature in the engine. The application of EGR in the range 0-40% resulted in a notable prolongation of both the initial and main combustion phases which consequently influenced the mean combustion temperature.
Impact of Large-scale Hydrogen Electrification and Retrofitting of Natural Gas Infrastructure on the European Power System
Nov 2023
Publication
In this paper we aim to analyse the impact of hydrogen production decarbonisation and electrification scenarios on the infrastructure development generation mix CO2 emissions and system costs of the European power system considering the retrofit of the natural gas infrastructure. We define a reference scenario for the European power system in 2050 and use scenario variants to obtain additional insights by breaking down the effects of different assumptions. The scenarios were analysed using the European electricity market model COMPETES including a proposed formulation to consider retrofitting existing natural gas networks to transport hydrogen instead of methane. According to the results 60% of the EU’s hydrogen demand is electrified and approximately 30% of the total electricity demand will be to cover that hydrogen demand. The primary source of this electricity would be non-polluting technologies. Moreover hydrogen flexibility significantly increases variable renewable energy investment and production and reduces CO2 emissions. In contrast relying on only electricity transmission increases costs and CO2 emissions emphasising the importance of investing in an H2 network through retrofitting or new pipelines. In conclusion this paper shows that electrifying hydrogen is necessary and cost-effective to achieve the EU’s objective of reducing long-term emissions.
Optimal Decarbonization Strategies for an Industrial Port Area by Using Hydrogen as Energy Carrier
Jul 2023
Publication
This article discusses possible strategies for decarbonizing the energy systems of an existing port. The approach consists in creating a complete superstructure that includes the use of renewable and fossil energy sources the import or local production of hydrogen vehicles and other equipment powered by Diesel electricity or hydrogen and the associated refuelling and storage units. Two substructures are then identified one including all these options the other considering also the addition of the energy demand of an adjacent steel industry. The goal is to select from each of these two substructures the most cost-effective configurations for 2030 and 2050 that meet the emission targets for those years under different cost scenarios for the energy sources and conversion/storage units obtained from the most reliable forecasts found in the literature. To this end the minimum total cost of all the energy conversion and storage units plus the associated infrastructures is sought by setting up a Mixed Integer Linear Programming optimization problem where integer variables handle the inclusion of the different generation and storage units and their activation in the operational phases. The comprehensive picture of possible solutions set allows identifying which options can most realistically be realized in the years to come in relation to the different assumed cost scenarios. Optimization results related to the scenario projected to 2030 indicate the key role played by Diesel hybrid and electric systems while considering the most stringent or much more stringent scenarios for emissions in 2050 almost all vehicles energy demand and industry hydrogen demand is met by hydrogen imported as ammonia by ship.
Performance Evaluation of Renewable Energy Systems: Photovoltaic, Wind Turbine, Battery Bank, and Hydrogen Storage
Sep 2023
Publication
The analysis aims to determine the most efficient and cost-effective way of providing power to a remote site. The two primary sources of power being considered are photovoltaics and small wind turbines while the two potential storage media are a battery bank and a hydrogen storage fuel cell system. Subsequently the hydrogen is stored within a reservoir and employed as required by the fuel cell. This strategy offers a solution for retaining surplus power generated during peak production phases subsequently utilizing it during periods when the renewable power sources are generating less power. To evaluate the performance of the hydrogen storage system the analysis included a sensitivity analysis of the wind speed and the cost of the hydrogen subsystem. In this analysis the capital and replacement costs of the electrolyzer and hydrogen storage tank were linked to the fuel cell capital cost. As the fuel cell cost decreases the cost of the electrolyzer and hydrogen tank also decreases. The optimal system type graph showed that the hydrogen subsystem must significantly decrease in price to become competitive with the battery bank.
Conceptual Design of a Hydrogen-Hybrid Dual-Fuel Regional Aircraft Retrofit
Jan 2024
Publication
A wide range of aircraft propulsion technologies is being investigated in current research to reduce the environmental impact of commercial aviation. As the implementation of purely hydrogenpowered aircraft may encounter various challenges on the airport and vehicle side combined hydrogen and kerosene energy sources may act as an enabler for the first operations with liquid hydrogen propulsion technologies. The presented studies describe the conceptual design of such a dual-fuel regional aircraft featuring a retrofit derived from the D328eco under development by Deutsche Aircraft. By electrically assisting the sustainable aviation fuel (SAF) burning conventional turboprop engines with the power of high-temperature polymer-electrolyte fuel cells the powertrain architecture enables a reduction of SAF consumption. All aircraft were modeled and investigated using the Bauhaus Luftfahrt Aircraft Design Environment. A description of this design platform and the incorporated methods to model the hydrogen-hybrid powertrain is given. Special emphasis was laid on the implications of the hydrogen and SAF dual-fuel system design to be able to assess the potential benefits and drawbacks of various configurations with the required level of detail. Retrofit assumptions were applied particularly retaining the maximum takeoff mass while reducing payload to account for the propulsion system mass increase. A fuel cell power allocation of 20% led to a substantial 12.9% SAF consumption decrease. Nonetheless this enhancement necessitated an 18.1% payload reduction accompanied by a 34.5% increment in propulsion system mass. Various additional studies were performed to assess the influence of the power split. Under the given assumptions the design of such a retrofit was deemed viable.
Economic Evaluation and Technoeconomic Resilience Analysis of Two Routes for Hydrogen Production via Indirect Gasification in North Colombia
Nov 2023
Publication
Hydrogen has become a prospective energy carrier for a cleaner more sustainable economy offering carbon-free energy to reduce reliance on fossil fuels and address climate change challenges. However hydrogen production faces significant technological and economic hurdles that must be overcome to reveal its highest potential. This study focused on evaluating the economics and technoeconomic resilience of two large-scale hydrogen production routes from African palm empty fruit bunches (EFB) by indirect gasification. Computer-aided process engineering (CAPE) assessed multiple scenarios to identify bottlenecks and optimize economic performance indicators like gross profits including depreciation after-tax profitability payback period and net present value. Resilience for each route was also assessed considering raw material costs and the market price of hydrogen in relation to gross profits and after-tax profitability. Route 1 achieved a gross profit (DGP) of USD 47.12 million and a profit after taxes (PAT) of USD 28.74 million while Route 2 achieved a DGP of USD 46.53 million and a PAT of USD 28.38 million. The results indicated that Route 2 involving hydrogen production through an indirect gasification reactor with a Selexol solvent unit for carbon dioxide removal demonstrated greater resilience in terms of raw material costs and product selling price.
Comprehensive Overview of Recent Research and Industrial Advancements in Nuclear Hydrogen Production
Jun 2024
Publication
As new sources of energy and advanced technologies are used there is a continuous evolution in energy supply demand and distribution. Advanced nuclear reactors and clean hydrogen have the opportunity to scale together and diversify the hydrogen production market away from fossil fuel-based production. Nevertheless the technical uncertainties surrounding nuclear hydrogen processes necessitate thorough research and a solid development effort. This paper aims to position pink hydrogen for nuclear hydrogen production at the forefront of sustainable energy-related solutions by offering a comprehensive review of recent advancements in nuclear hydrogen production covering both research endeavors and industrial applications. It delves into various pink hydrogen generation methodologies elucidating their respective merits and challenges. Furthermore this paper analyzes the evolving landscape of pink hydrogen in terms of its levelized cost by comparatively assessing different production pathways. By synthesizing insights from academic research and industrial practices this paper provides valuable perspectives for stakeholders involved in shaping the future of nuclear hydrogen production.
Sustainable E-Fuels: Green Hydrogen, Methanol and Ammonia for Carbon-Neutral Transportation
Dec 2023
Publication
Increasingly stringent sustainability and decarbonization objectives drive investments in adopting environmentally friendly low and zero-carbon fuels. This study presents a comparative framework of green hydrogen green ammonia and green methanol production and application in a clear context. By harnessing publicly available data sources including from the literature this research delves into the evaluation of green fuels. Building on these insights this study outlines the production process application and strategic pathways to transition into a greener economy by 2050. This envisioned transformation unfolds in three progressive steps: the utilization of green hydrogen green ammonia and green methanol as a sustainable fuel source for transport applications; the integration of these green fuels in industries; and the establishment of mechanisms for achieving the net zero. However this research also reveals the formidable challenges of producing green hydrogen green ammonia and green methanol. These challenges encompass technological intricacies economic barriers societal considerations and far-reaching policy implications necessitating collaborative efforts and innovative solutions to successfully develop and deploy green hydrogen green ammonia and green methanol. The findings unequivocally demonstrate that renewable energy sources play a pivotal role in enabling the production of these green fuels positioning the global transition in the landscape of sustainable energy.
Methodology for Consequence-based Setback Distance Calculations for Bulk Liquid Hydrogen Storage Systems
Sep 2023
Publication
Updates to the separation distances between different exposures and bulk liquid hydrogen systems are included in the 2023 version of NFPA 2: Hydrogen Technologies Code. This work details the models and calculations leading to those distances. The specific models used including the flow of liquid hydrogen through an orifice within the Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) toolkit are described and discussed to emphasize challenges specific to liquid hydrogen systems. Potential hazards and harm affecting individual exposures (e.g. ignition sources air intakes) for different unignited concentrations overpressures and heat flux levels were considered and exposures were grouped into three bins. For each group the distances to a specific hazard criteria (e.g. heat flux level) for a characteristic leak size informed by a risk-analysis led to a hazard distance. The maximum hazard distance within each group was selected to determine a table of separation distances based on internal pressure and pipe size rather than storage volume similar to the bulk gaseous separation distance tables in NFPA 2. The new separation distances are compared to the previous distances and some implications of the updated distances are given.
Proactive Emergency Response Strategies for First Responders to Hydrogen Gas Leakages in Vehicles
Feb 2024
Publication
The widespread use of fossil fuels in automobiles has become a concern particularly in light of recent frequent natural disasters prompting a shift towards eco-friendly vehicles to mitigate greenhouse gas emissions. This shift is evident in the rapidly increasing registration rates of hydrogen vehicles. However with the growing presence of hydrogen vehicles on roads a corresponding rise in related accidents is anticipated posing new challenges for first responders. In this study computational fluid dynamics analysis was performed to develop effective response strategies for first responders dealing with high-pressure hydrogen gas leaks in vehicle accidents. The analysis revealed that in the absence of blower intervention a vapor cloud explosion from leaked hydrogen gas could generate overpressure exceeding 13.8 kPa potentially causing direct harm to first responders. In the event of a hydrogen vehicle accident requiring urgent rescue activities the appropriate response strategy must be selected. The use of blowers can aid in developing a variety of strategies by reducing the risk of a vapor cloud explosion. Consequently this study offers a tailored response strategy for first responders in hydrogen vehicle leak scenarios emphasizing the importance of situational assessment at the incident site.
Optimal Sizing of Renewables-to-hydrogen Systems in a Suitable-site-selection Geospatial Framework: The Case Study if Italy and Portugal
Jun 2024
Publication
Growing renewable energy deployment worldwide has sparked a shift in the energy landscape with far-reaching geopolitical ramifications. Hydrogen’s role as an energy carrier is central to this change facilitating global trade and the decarbonisation of hard-to-abate sectors. This analysis offers a new method for optimally sizing solar/wind-to-hydrogen systems in specifically suitable locations. These locations are limited to the onshore and offshore regions of selected countries as determined by a bespoke geospatial analysis developed to be location-agnostic. Furthermore the research focuses on determining the best configurations for such systems that minimise the cost of producing hydrogen with the optimisation algorithm expanding from the detailed computation of the classic levelised cost of hydrogen. One of the study’s main conclusions is that the best hybrid configurations obtained provide up to 70% cost savings in some areas. Such findings represent unprecedented achievements for Italy and Portugal and can be a valuable asset for economic studies of this kind carried out by local and national governments across the globe. These results validate the optimisation model’s initial premise significantly improving the credibility of this work by constructively challenging the standard way of assessing large-scale green hydrogen projects.
Numerical Analysis of Dual Fuel Combustion in a Medium Speed Marine Engine Supplied with Methane/Hydrogen Blends
Sep 2023
Publication
Compression ignition engines will still be predominant in the naval sector: their high efficiency high torque and heavy weight perfectly suit the demands and architecture of ships. Nevertheless recent emission legislations impose limitations to the pollutant emissions levels in this sector as well. In addition to post-treatment systems it is necessary to reduce some pollutant species and therefore the study of combustion strategies and new fuels can represent valid paths for limiting environmental harmful emissions such as CO2 . The use of methane in dual fuel mode has already been implemented on existent vessels but the progressive decarbonization will lead to the utilization of carbon-neutral or carbon-free fuels such as in the last case hydrogen. Thanks to its high reactivity nature it can be helpful in the reduction of exhaust CH4 . On the contrary together with the high temperatures achieved by its oxidation hydrogen could cause uncontrolled ignition of the premixed charge and high emissions of NOx. As a matter of fact a source of ignition is still necessary to have better control on the whole combustion development. To this end an optimal and specific injection strategy can help to overcome all the before-mentioned issues. In this study three-dimensional numerical simulations have been performed with the ANSYS Forte® software (version 19.2) in an 8.8 L dual fuel engine cylinder supplied with methane hydrogen or hydrogen–methane blends with reference to experimental tests from the literature. A new kinetic mechanism has been used for the description of diesel fuel surrogate oxidation with a set of reactions specifically addressed for the low temperatures together with the GRIMECH 3.0 for CH4 and H2 . This kinetics scheme allowed for the adequate reproduction of the ignition timing for the various mixtures used. Preliminary calculations with a one-dimensional commercial code were performed to retrieve the initial conditions of CFD calculations in the cylinder. The used approach demonstrated to be quite a reliable tool to predict the performance of a marine engine working under dual fuel mode with hydrogen-based blends at medium load. As a result the system modelling shows that using hydrogen as fuel in the engine can achieve the same performance as diesel/natural gas but when hydrogen totally replaces methane CO2 is decreased up to 54% at the expense of the increase of about 76% of NOx emissions.
Assessing the Implications of Hydrogen Blending on the European Energy System towards 2050
Dec 2023
Publication
With the aim of reducing carbon emissions and seeking independence from Russian gas in the wake of the conflict in Ukraine the use of hydrogen in the European Union is expected to rise in the future. In this regard hydrogen transport via pipeline will become increasingly crucial either through the utilization of existing natural gas infrastructure or the construction of new dedicated hydrogen pipelines. This study investigates the effects of hydrogen blending in existing pipelines on the European energy system by the year 2050 by introducing hydrogen blending sensitivities to the Global Energy System Model (GENeSYS-MOD). Results indicate that hydrogen demand in Europe is inelastic and limited by its high costs and specific use cases with hydrogen production increasing by 0.17% for 100%-blending allowed compared to no blending allowed. The availability of hydrogen blending has been found to impact regional hydrogen production and trade with countries that can utilize existing natural gas pipelines such as Norway experiencing an increase in hydrogen and synthetic gas exports from 44.0 TWh up to 105.9 TWh in 2050 as the proportion of blending increases. Although the influence of blending on the overall production and consumption of hydrogen in Europe is minimal the impacts on the location of production and dependence on imports must be thoroughly evaluated in future planning efforts.
Recent Developments in Methane Decomposition over Heterogenous Catalysts: An Overview
Apr 2020
Publication
The production of hydrogen to be used as an alternative renewable energy has been widely explored. Among various methods for producing hydrogen from hydrocarbons methane decomposition is suitable for generating hydrogen with zero greenhouse gas emissions. The use of high temperatures as a result of strong carbon and hydrogen (C–H) bonds may be reduced by utilizing a suitable catalyst with appropriate catalyst support. Catalysts based on transition metals are preferable in terms of their activeness handling and low cost in comparison with noble metals. Further development of catalysts in methane decomposition has been investigated. In this review the recent progress on methane decomposition in terms of catalytic materials preparation method the physicochemical properties of the catalysts and their performance in methane decomposition were presented. The formation of carbon as part of the reaction was also discussed.
Safety of Cryogenic Liquid Hydrogen Bunkering Operations - The Gaps Between Existing Knowhow and Industry Needs
Sep 2023
Publication
Hydrogen plays an important role in the global transition towards Net-Zero emission. While pipelines are a viable option to transport large quantities of compressed hydrogen over long distances it is not always practical in many applications. In such situations a viable option is to transport and deliver large quantities of hydrogen as cryogenic liquid. The liquefaction process cools hydrogen to cryogenic temperatures below its boiling point of -259.2 0C. Such extreme low temperature implies specific hazards and risks which are different from those associated with the relatively well-known compressed gaseous hydrogen. Managing these specific issues brings new challenges for the stakeholders.<br/>Furthermore the transfer of liquid hydrogen (LH2) and its technical handling is relatively well known for industrial gas or space applications. Experience with LH2 in public and populated areas such as truck and aircraft refuelling stations or port bunkering stations for example is limited or non-existent. Safety requirements in these applications which involve or are in proximity of untrained public are different from rocket/aerospace industry.<br/>The manuscript reviews knowhow already gained by the international hydrogen safety community; and on such basis elucidate the gaps which are yet to be filled to meet industry needs to design and operate inherently safe LH2 operations including the implications for regulations codes and standards (RCS). Where relevant the associated gaps in some underpinning sciences will be mentioned; and the need to contextualise the information and safety practices from NASA1/ESA2/JAXA3 to inform risk adoption will be summarised.
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