Publications

This review explores recent advancements in hydrogen gas (H2 ) safety through the lens of artificial intelligence (AI) techniques. As hydrogen gains prominence as a clean energy source ensuring its safe handling becomes paramount. The paper critically evaluates the implementation of AI methodologies including artificial neural networks (ANN) machine learning algorithms computer vision (CV) and data fusion techniques in enhancing hydrogen safety measures. By examining the integration of wireless sensor networks and AI for real-time monitoring and leveraging CV for interpreting visual indicators related to hydrogen leakage issues this review highlights the transformative potential of AI in revolutionizing safety frameworks. Moreover it addresses key challenges such as the scarcity of standardized datasets the optimization of AI models for diverse environmental conditions etc. while also identifying opportunities for further research and development. This review foresees faster response times reduced false alarms and overall improved safety for hydrogen-related applications. This paper serves as a valuable resource for researchers engineers and practitioners seeking to leverage state-of-the-art AI technologies for enhanced hydrogen safety systems.

Hydrogen is one of a handful of new low carbon solutions that will be critical for the transition to net zero. The upscaling of production and applications entails that hydrogen is likely to be stored in liquid phase (LH2) at cryogenic conditions to increase its energy density. Widespread LH2 use as an alternative fuel will require significant infrastructure upgrades to accommodate increased bulk transport storage and delivery. However current LH2 bulk storage separation distances are based on subjective expert recommendations rather than experimental observations or physical models. Experimental studies of large-scale LH2 release are challenging and costly. The existing large-scale tests are scarce and numerical studies are a viable option to investigate the existing knowledge gaps. Controlled or accidental releases of LH2 for hydrogen refueling infrastructure would result in high momentum two-phase jets or formation of liquid pools depending on release conditions. Both release scenarios lead to a flammable/explosive cloud posing a safety issue to the public.<br/>The manuscript reports exploratory study to numerically determine the safety zone resulting from cryogenic hydrogen releases related to LH2 storage and refueling using the in-house HyFOAM solver further modified for gaseous hydrogen releases at cryogenic conditions and the subsequent atmospheric dispersion and ignition within the platform of OpenFOAM V8.0. The current version of the solver neglects the flashing process by assuming that the temperature of the stored LH2 is equal to the boiling point at the atmospheric condition. Numerical simulations of dispersion and subsequent ignition of LH2 release scenarios with respect to different release orientations release rates release temperatures and weather conditions were performed. Both hydrogen concentration and temperature fields were predicted and the boundary of zones within the flammability limit was also defined. The study also considered the sensitivities of the consequences to the release orientation wind speed ambient temperature and release content etc. The effect of different barrier walls on the deflagration were also evaluated by changing the height and location.

The current political scenario and the concerns for global warming have pushed very harsh regulations on conventional propulsion systems based on the use of fossil fuels. New technologies are being promoted but their current technological status needs further research and development for them to become a competitive substitute for the ever-present internal combustion engine. Hydrogen-fueled internal combustion engines have demonstrated the potential of being a fast way to reach full decarbonization of the transport sector but they still have to face some limitations in terms of the operating range of the engine. For this reason the present work evaluates the potential of reaching full load operation on a conventional diesel engine assuming the minimum modifications required to make it work under H2 combustion. This study shows the methodology through which the combustion model was developed and then used to evaluate a multi-cylinder engine representative of the medium to high duty transport sector. The evaluation included different strategies of dilution to control the combustion performance and the results show that the utilization of EGR brings different benefits to engine operation in terms of efficiency improvement and emissions reduction. Nonetheless the requisites defined for the needed turbocharging system are harsher than expected and result in a potential non-conventional technical solution.

Green hydrogen is a promising alternative to fossil fuels. However current production capacities for electrolyzers and green hydrogen are not in line with national political goals and projected demand. Considering these issues we conducted semi-structured interviews to determine the narratives of different stakeholders during this transformation as well as challenges and opportunities for the green hydrogen value chain. We interviewed eight experts with different roles along the green hydrogen value chain ranging from producers and consumers of green hydrogen to electrolyzer manufacturers and consultants as well as experts from the political sphere. Most experts see the government as necessary for scale-up by setting national capacity targets policy support and providing subsidies. However the experts also accuse the governments of delaying development through overregulation and long implementation times for regulations. The main challenges that were identified are the current lack of renewable electricity and demand for green hydrogen. Demand for green hydrogen is influenced by supply costs which partly depend on prices for electrolyzers. However one key takeaway of the interviews is the skeptical assessments by the experts on the currently discussed estimates for price reduction potential of electrolyzers. While demand supply and prices are all factors that influence each other they result in feedback loops in investment decisions for the energy and manufacturing industries. A second key takeaway is that according to the experts current investment decisions in new production capacities are not solely dependent on short-term financial gains but also based on expected first mover advantages. These include experience and market share which are seen as factors for opportunities for future financial gains. Summarized the results present several challenges and opportunities for green hydrogen and electrolyzers and how to address them effectively. These insights contribute to a deeper understanding of the dynamics of the emerging green hydrogen value chain.

Hydrogen jet fire occurs with high probability when hydrogen leaks from high-pressure equipment. The hydrogen jet fire is characterized by its high velocity and energy. Computational Fluid Dynamics (CFD) numerical analysis is a prominent way to predict the potential hazards associated with hydrogen jet fire. Validation of the CFD model is essential to ensure and quantify the accuracy of numerical results. This study focuses on the validation of the hydrogen jet fire model using Fire Dynamic Simulation (FDS). Hydrogen release is modeled using high-speed Lagrangian particles released from a virtual nozzle thus avoiding the modeling of the actual nozzle. The mesh size sensitivity analysis of the model is carried out in a container-size domain with 0.04m – 0.08m resolution of the jet. The model is validated by comparing gas temperatures and heat fluxes with test data. The promising results demonstrated that the model could predict the hazardous influence of the jet fire.

Solar hydrogen production technology is a key technology for building a clean low-carbon safe and efficient energy system. At present the intermittency and volatility of renewable energy have caused a lot of “wind and light.” By combining renewable energy with electrolytic water technology to produce high-purity hydrogen and oxygen which can be converted into electricity the utilization rate of renewable energy can be effectively improved while helping to improve the solar hydrogen production system. This paper summarizes and analyzes the research status and development direction of solar hydrogen production technology from three aspects. Energy supply mode: the role of solar PV systems and PT systems in this technology is analyzed. System control: the key technology and system structure of different types of electrolytic cells are introduced in detail. System economy: the economy and improvement measures of electrolytic cells are analyzed from the perspectives of cost consumption efficiency and durability. Finally the development prospects of solar hydrogen production systems in China are summarized and anticipated. This article reviews the current research status of photovoltaic-photothermal coupled electrolysis cell systems fills the current research gap and provides theoretical reference for the further development of solar hydrogen production systems.

Shock-flame interactions (SFI) occur in a variety of combustion scenarios of scientific and engineering interest which can distort the flame extend the flame surface area and subsequently enhance heat release. This process is dominated by Richtmyer-Meshkov instability (RMI) that features the perturbation growth of a density-difference interface (flame) after the shock passage. The main mechanism of RMI is the vorticity deposition results from a misalignment between pressure and density gradients. This paper focuses on the multi-dimensional interactions between shock wave and flame in a hydrogen-air mixture. The simulations of this work were conducted by solving three-dimensional fully-compressible reactive Navier-Stokes equations using a high-order numerical method on a dynamically adapting mesh. The effect of wall friction on the SFI was examined by varying wall boundary condition (free-slip/no-slip) on sidewall. The results show that the global flame perturbation grows faster with the effect of wall friction in the no-slip case than that in the free-slip case in the process of SFI. Two effects of wall friction on SFI were found: (1) flame stretching close to the no-slip wall and (2) damping of local flame perturbation at the no-slip wall. The flame stretch effect leads to a significantly higher growth rate in the global flame perturbation. By contrast the damping effect locally moderates the flame perturbation induced by RMI in close proximity to the no-slip wall because less vorticity is deposited on this part of flame during SFI.

We present a numerical simulation procedure for analyzing hydrogen oxygen and carbon dioxide gases injections mixed with pulverized coals within the tuyeres of blast furnaces. Effective use of H2 rich gas is highly attractive into the steelmaking blastfurnace considering the possibility of increasing the productivity and decreasing the specific emissions of carbon dioxide becoming the process less intensive in carbon utilization. However the mixed gas and coal injection is a complex technology since significant changes on the inner temperature and gas flow patterns are expected beyond to their effects on the chemical reactions and heat exchanges. Focusing on the evaluation of inner furnace status under such complex operation a comprehensive mathematical model has been developed using the multi interaction multiple phase theory. The BF considered as a multiphase reactor treats the lump solids (sinter small coke pellets granular coke and iron ores) gas liquids metal and slag and pulverized coal phases. The governing conservation equations are formulated for momentum mass chemical species and energy and simultaneously discretized using the numerical method of finite volumes. We verified the model with a reference operational condition using pulverized coal of 215 kg per ton of hot metal (kg thm−1). Thus combined injections of varying concentrations of gaseous fuels with H2 O2 and CO2 are simulated with 220 kg thm−1 and 250 kg thm−1 coals injection. Theoretical analysis showed that stable operations conditions could be achieved with productivity increase of 60%. Finally we demonstrated that the net carbon utilization per ton of hot metal decreased 12%.

Because of the pressure to meet carbon neutrality targets carbon reduction has become a challenge for fossil fuel resource-based regions. Even though China has become the most active country in carbon reduction its extensive energy supply and security demand make it difficult to turn away from its dependence on coal-based fossil energy. This paper analyzes the Chinese coal capital—Shanxi Province—to determine whether the green low-carbon energy transition should be focused on coal resource areas. In these locations the selection and effect of transition tools are key to ensuring that China meets its carbon reduction goal. Due to the time window of clean coal utilization the pressure of local governments and the survival demands of local high energy consuming enterprises Shanxi Province chose hydrogen as its important transition tool. A path for developing hydrogen resources has been established through lobbying and corporative influence on local and provincial governments. Based on such policy guidance Shanxi has realized hydrogen applications in large-scale industrial parks regional public transport and the iron and steel industry. This paper distinguishes between the development strategies of gray and green hydrogen. It shows that hydrogen can be an effective development model for resource-based regions as it balances economic stability and energy transition.

In Southern Italy near the Mediterranean Sea mobility services like cars bicycles scooters and materialhandling forklifts are frequently required in addition to multimodal local transportation services such as trains ferry boats and airplanes. This research proposes an innovative concept of hydrogen valley virtually simulated in Matlab/Simulink environment located in Calabria. As a novelty hydrogen is produced centrally and delivered via fuel cell hybrid trains to seven hydrogen refueling stations serving various mobility hubs. The centralized production facility operates with a nominal capacity of about 4 tons/day producing hydrogen via PEM electrolysis and storing hydrogen at 200 bar with a hydrogen compressor. As the size of vehicle fleets and the cost of acquiring renewable energy through power purchase agreements vary the hydrogen valley is examined from both a technical and an economic perspective analyzing: the values of the levelized cost of hydrogen the energy consumption and the energy efficiency of the energy systems. Specifically the levelized cost of hydrogen reached competitive values close to 5 €/kg of hydrogen under the most optimistic scenarios with fleet conversions of more than 60 % and a power purchase agreement price lower than 150 €/MWh. Then the benefits of hydrogen rail transport in terms of emissions reduction and health from an economic standpoint are compared to conventional diesel trains and fully electric trains saving respectively 3.2 ktons/year and 0.4 ktons/year of carbon dioxide equivalent emissions and corresponding economic benefits of respectively 51 and 0.548 million euros.

Nowadays with the need for clean and sustainable energy at its historical peak new equipment strategies and methods have to be developed to reduce environmental pollution. Drastic steps and measures have already been taken on a global scale. Renewable energy sources (RESs) are being installed with a growing rhythm in the power grids. Such installations and operations in power systems must also be economically viable over time to attract more investors thus creating a cycle where green energy e.g. green hydrogen production will be both environmentally friendly and economically beneficial. This work presents a management method for assessing wind–solar– hydrogen (H2 ) energy systems. To optimize component sizing and calculate the cost of the produced H2 the basic procedure of the whole management method includes chronological simulations and economic calculations. The proposed system consists of a wind turbine (WT) a photovoltaic (PV) unit an electrolyzer a compressor a storage tank a fuel cell (FC) and various power converters. The paper presents a case study of green hydrogen production on Sifnos Island in Greece through RES together with a scenario where hydrogen vehicle consumption and RES production are higher during the summer months. Hydrogen stations represent H2 demand. The proposed system is connected to the main power grid of the island to cover the load demand if the RES cannot do this. This study also includes a cost analysis due to the high investment costs. The levelized cost of energy (LCOE) and the cost of the produced H2 are calculated and some future simulations correlated with the main costs of the components of the proposed system are pointed out. The MATLAB language is used for all simulations.

The inherent intermittency of upstream solar and wind power can result in fluctuating electrolytic hydrogen production which is incompatible with the feedstock requirements of many downstream hydrogen storage and utilisation applications. Suitable backup power or storage (hydrogen or energy) strategies are thus needed in overall system design. This work conducts technoeconomic modelling to design electrolytic production systems featuring stable hydrogen output for various locations across Australia based on hourly weather data and determines the levelised cost of hydrogen (LCOH) emissions intensities and annual electrolyser usage factors. A stable truly green hydrogen supply is consistently achieved by imposing annual usage factor requirements on the system which forces the system modules (i.e. solar wind electrolyser and hydrogen storage) to be oversized in order to achieve the desired usage factor. Whilst the resultant system designs are however very location-specific a design that ensures a 100% usage factor costs approximately 22% more on average than a system design which is optimised for cost alone.

High fluctuations in the combustion process from one cycle to another referred to as cycle-by-cycle variations can have adverse effects on internal combustion engine performances particularly in spark ignition (SI) engines. These effects encompass incomplete combustion the potential for misfires and adverse impacts on fuel economy. Furthermore the cycle-by-cycle variations can also affect a vehicle’s drivability and overall comfort especially when operating under lean-burn conditions. Although many cycle-by-cycle analyses have been investigated extensively in the past there is limited in-depth knowledge available regarding the causes of cycle-by-cycle (CbC) variations in hydrogen lean-burn SI engines. Trying to contribute to this topic the current study presents a comprehensive analysis of the CbC variations based on the cylinder pressure data. The study was carried out employing a hydrogen single-cylinder research SI engine. The experiments were performed by varying more than fifty operating conditions including the variations in lambda spark advance boost pressure and exhaust gas recirculation however the load and speed were kept constant throughout the experimental campaign. The results indicate that pressure exhibits significant variations during the combustion process and minor variations during non-combustion processes. In the period from the inlet valve close till the start of combustion pressure exhibits the least variations. The coefficient of variation of pressure (COVP) curve depicts three important points in H2-ICE as well: global minima global maxima and second local minima. The magnitude of the COVP curve changes across all the operating conditions however the shape of the COVP curve remains unchanged across all the operating conditions indicating its independence from the operating condition in an H2-ICE. This study presents an alternative approach for a quick combustion analysis of hydrogen engines. Without the need for more complex methodologies like heat release rate analysis the presented cylinder pressure cycle-by-cycle analysis enables a quick and precise identification of primary combustion features (start of combustion center of combustion end of combustion and operation condition stability). Additionally the engine control unit could implement these procedures to automatically adjust cycle-by-cycle variations therefore increasing engine efficiency.

Due to its ability to reduce emissions in the hard-to-abate sectors hydrogen is expected to play a significant role in future energy systems. This study modifies a sector-coupled dynamic modeling framework for electricity and hydrogen by including policy constraints carbon prices and possible hydrogen pathways and applies it to Texas in 2050. The impact of financial policies including the US clean hydrogen production tax credit on required infrastructure and costs are explored. Due to low natural gas prices financial levers are necessary to promote low-carbon hydrogen production as the optimized solution. The Levelized Costs of Hydrogen are found to be $1.50/kg in the base case (primarily via steam methane reformation production) and lie between $2.10 - 3.10/kg when production is via renewable electrolysis. The supporting infrastructure required to supply those volumes of renewable hydrogen is immense. The hydrogen tax credit was found to be enough to drive production via electrolysis.

While fossil fuels continue to be used and to increase air pollution across the world hydrogen gas has been proposed as an alternative energy source and a carrier for the future by scientists. Water electrolysis is a renewable and sustainable chemical energy production method among other hydrogen production methods. Hydrogen production via water electrolysis is a popular and expensive method that meets the high energy requirements of most industrial electrolyzers. Scientists are investigating how to reduce the price of water electrolytes with different methods and materials. The electrolysis structure equations and thermodynamics are first explored in this paper. Water electrolysis systems are mainly classified as high- and low-temperature electrolysis systems. Alkaline PEM-type and solid oxide electrolyzers are well known today. These electrolyzer materials for electrode types electrolyte solutions and membrane systems are investigated in this research. This research aims to shed light on the water electrolysis process and materials developments.

Hydrogen is a promising fuel because it has good capabilities to operate gas turbines. Due to its ignition speed which exceeds the ignition of traditional fuel it achieves a higher thermal efficiency while the resulting emissions are low. So it was used as a clean and sustainable energy source. This paper reviews the most important research that was concerned with studying the characteristics of hydrogen combustion within incinerators and power generation equipment where hydrogen was used as a fuel mixed with traditional fuel in the combustion chambers of gas turbines. It also includes an evaluation of the combustion processes and flame formation resulting from the enrichment of gaseous fuels with hydrogen and partial oxidation. A large amount of theoretical and experimental work in this field has been reviewed. This review summarizes the predictive and experimental results of various research interests in the field of hydrogen combustion and also production.

An energy source transition is necessary to realize carbon neutrality emphasizing the importance of a hydrogen economy. The transportation sector accounted for 27% of annual carbon emissions in 2019 highlighting the increasing importance of transitioning to hydrogen vehicles and establishing hydrogen refueling stations (HRSs). In particular HRSs need to be prioritized for deploying hydrogen vehicles and developing hydrogen supply chains. Thus research on HRS is important for achieving carbon neutrality in the transportation sector. In this study we improved the efficiency and scaled up the capacity of an on-site HRS (based on steam methane reforming with a hydrogen production rate of 30 Nm3/h) in Seoul Korea. This HRS was a prototype with low efficiency and capacity. Its efficiency was increased through thermodynamic analysis and heat exchanger network synthesis. Furthermore the process was scaled up from 30 Nm3/h to 150 Nm3/h to meet future hydrogen demand. The results of exergy analysis indicated that the exergy destruction in the reforming reactor and heat exchanger accounted for 58.1% and 19.8% respectively of the total exergy destruction. Thus the process was improved by modifying the heat exchanger network to reduce the exergy losses in these units. Consequently the thermal and exergy efficiencies were increased from 75.7% to 78.6% and from 68.1% to 70.4% respectively. The improved process was constructed and operated to demonstrate its performance. The operational and simulation data were similar within the acceptable error ranges. This study provides guidelines for the design and installation of low-carbon on-site HRSs.

The hydrogen sector is envisaged as one of the key enablers of the energy transition that the European Union is facing to accomplish its decarbonization targets. However regarding the technologies that enable the deployment of a hydrogen economy a growing concern exists about potential burden-shifting across sustainability dimensions. In this sense social life cycle assessment arises as a promising methodology to evaluate the social implications of hydrogen technologies along their supply chains. In the context of the European projects eGHOST and SH2E this study seeks to advance on key methodological aspects of social life cycle assessment when it comes to guiding the ecodesign of two relevant hydrogen-related products: a 5 kW solid oxide electrolysis cell stack for hydrogen production and a 48 kW proton-exchange membrane fuel cell stack for mobility applications. Based on the social life cycle assessment results for both case studies under alternative approaches the definition of a product-specific supply chain making use of appropriate cut-off criteria was found to be the preferable choice when addressing system boundaries definition. Moreover performing calculations according to the activity variable approach was found to provide valuable results in terms of social hotspots identification to support subsequent decision-making processes on ecodesign while the direct calculation approach is foreseen as a complement to ease the interpretation of social scores. It is concluded that advancements in the formalization of such suitable practices could foster the integration of social metrics into the sustainable-by-design framework of hydrogen-related products.

This study investigated the pressure-dependent CO2 effect on the hydrogen embrittlement of X80 and GB20# pipeline steels by combining experiments and first-principles calculations. Results revealed that the CO2 effect enhanced the fatigue crack growth for GB20# steel in 10 MPa CO₂-enriched hydrogen mixtures. However the improved degree by the CO₂ effect at 10 MPa was less pronounced than at 0.4 MPa which was found for the first time. This was attributed to the decreased adsorption rate of CO₂ on iron as hydrogen pressure increased. Therefore in high-pressure CO₂-enriched hydrogen mixtures CO2 could not significantly accelerate the inherent rapid hydrogen uptake at high pressure.

To cope with the growing penetration rate of renewable energy and to enhance the absorption capacity of wind power this paper investigates the applications of an Integrated Energy System (IES) Hydrogen Compressed Natural Gas (HCNG) and power-to-hydrogen (P2H) devices within the IES. It employs power-to-gas and gas blending with hydrogen to construct an efficient electricity–gas–electricity energy flow loop establishing a Natural Gas–Electricity Coupling System (NGECS) model. On this basis a coordinated scheduling method for gas–electric coupling systems using gas blended with hydrogen is proposed. A carbon trading mechanism is introduced to constrain carbon emissions further reducing the system’s carbon footprint. Multiple scenarios are set up for a comparative analysis in order to validate the effectiveness of the proposed model. This study also analyzes the impact of different hydrogen blending ratios and methods on the low-carbon and economic performance of IES.

Climate change has prompted the international community to invest heavily in renewable energy sources in order to gradually replace fossil fuels. Whilst energy systems will be increasingly based on non-programmable renewable sources hydrogen is the main player when it comes to the role of energy reserve. This change has triggered a fast development of hydrogen production technologies with increasing use and installation of hydrogen generators (electrolyzers) in both the civil and industrial sector. The implementation of such investments requires the need for accurate design and verification of hydrogen systems with particular attention on fire safety. Due to its chemical-physical characteristics hydrogen is highly flammable and is often stored at very high-pressure levels. ISO 22734 and NFPA 2 are the main international standards which are currently available for the design of hydrogen generators and systems both of which include fire safety requirements. This paper analyses the main existing Regulations Codes and Standards (RCS) for hydrogen generators with the purpose of evaluating and comparing fire safety measures with focus on both active protection (detection systems extinguishing systems) and passive protection (safety distances separation walls). The scope of the paper is to identify safety measures which can be considered generally applicable and provide a reference for further fire safety regulations. The analysis carried out identifies potential gaps in RCS and suggests areas for potential future research.

The carbon-neutrality target set by the European Union for 2050 drives the increasing relevance of green hydrogen as key player in the energy transition. This work uses the JRC-EU-TIMES energy system model to assess opportunities and challenges for green hydrogen trade from North Africa to Europe analysing to what extent it can support its decarbonization. An important novelty is addressing uncertainty regarding hydrogen economy development. Alternative scenarios are built considering volumes available for import production costs and transport options affecting hydrogen cost-effectiveness. Both pipelines and ships are modelled assuming favourable market conditions and pessimistic ones. From 2040 on all available North African hydrogen is imported regardless of its costs. In Europe this imported hydrogen is mainly converted into synfuels and heat. The study aims to support policymakers to implement effective strategies focusing on the crucial role of green hydrogen in the decarbonization process if new competitive cooperations are developed.

As an important energy source to achieve carbon neutrality green hydrogen has always faced the problems of high use cost and unsatisfactory environmental benefits due to its remote production areas. Therefore a liquid-gaseous cascade green hydrogen delivery scheme is proposed in this article. In this scheme green hydrogen is liquefied into high-density and low-pressure liquid hydrogen to enable the transport of large quantities of green hydrogen over long distances. After longdistance transport the liquid hydrogen is stored and then gasified at transfer stations and converted into high-pressure hydrogen for distribution to the nearby hydrogen facilities in cities. In addition this study conducted a detailed model evaluation of the scheme around the actual case of hydrogen energy demand in Chengdu City in China and compared it with conventional hydrogen delivery methods. The results show that the unit hydrogen cost of the liquid-gaseous cascade green hydrogen delivery scheme is only 51.58 CNY/kgH2 and the dynamic payback periods of long- and short-distance transportation stages are 13.61 years and 7.02 years respectively. In terms of carbon emissions this scheme only generates indirect carbon emissions of 2.98 kgCO2/kgH2 without using utility electricity. In sum both the economic and carbon emission analyses demonstrate the advantages of the liquidgaseous cascade green hydrogen delivery scheme. With further reductions in electricity prices and liquefication costs this scheme has the potential to provide an economically/environmentally superior solution for future large-scale green hydrogen applications.

Hydrogen globally recognized as the most efficient and clean energy carrier holds the potential to transform future energy systems through its use as a fuel and chemical resource. Although progress has been made in reversible hydrogen adsorption and release challenges in storage continue to impede widespread adoption. This review explores recent advancements in hydrogen storage materials and synthesis methods emphasizing the role of nanotechnology and innovative synthesis techniques in enhancing storage performance and addressing these challenges to drive progress in the field. The review provides a comprehensive overview of various material classes including metal hydrides complex hydrides carbon materials metal-organic frameworks (MOFs) and porous materials. Over 60 % of reviewed studies focused on metal hydrides and alloys for hydrogen storage. Additionally the impact of nanotechnology on storage performance and the importance of optimizing synthesis parameters to tailor material properties for specific applications are summarized. Various synthesis methods are evaluated with a special emphasis on the role of nanotechnology in improving storage performance. Mechanical milling emerges as a commonly used and cost-effective method for fabricating intermetallic hydrides capable of adjusting hydrogen storage properties. The review also explores hydrogen storage tank embrittlement mechanisms particularly subcritical crack growth and examines the advantages and limitations of different materials for various applications supported by case studies showcasing real-world implementations. The challenges underscore current limitations in hydrogen storage materials highlighting the need for improved storage capacity and kinetics. The review also explores prospects for developing materials with enhanced performance and safety providing a roadmap for ongoing advancements in the field. Key findings and directions for future research in hydrogen storage materials emphasize their critical role in shaping future energy systems.

According to the European Hydrogen Strategy hydrogen will solve many of the problems with energy storage for balancing variable renewable energy sources (RES) supply and demand. At the same time we can see increasing popularity of the so-called energy communities (e.g. cooperatives) which (i) enable groups of entities to invest in manage and benefit from shared RES energy infrastructure; (ii) are expected to increase the energy independence of local communities from large energy corporations and increase the share of RES. Analyses were conducted on 2000 randomly selected energy cooperatives and four energy cooperatives formed on the basis of actual data. The hypotheses assumed in the research and positively verified in this paper are as follows: (i) there is a relationship between hydrogen storage capacity and the power of RES which allows an energy community to build energy independence; (ii) the type of RES generating source is meaningful when optimizing hydrogen storage capacity. The paper proves it is possible to build “island energy independence” at the local level using hydrogen storage and the efficiency of the power-to-power chain. The results presented are based on simulations carried out using a dedicated optimization model implemented by mixed integer programming. The authors’ next research projects will focus on optimizing capital expenditures and operating costs using the Levelized Cost of Electricity and Levelized Cost of Hydrogen methodologies.