Applications & Pathways
Research Progress on Gas Supply System of Proton Exchange Membrane Fuel Cells
Jun 2024
Publication
Proton exchange membrane fuel cells (PEMFCs) are attracting attention for their green energy-saving and high-efficiency advantages becoming one of the future development trends of renewable energy utilization. However there are still deficiencies in the gas supply system control strategy that plays a crucial role in PEMFCs which limits the rapid development and application of PEMFCs. This paper provides a comprehensive and in-depth review of the PEMFC air delivery system (ADS) and hydrogen delivery system (HDS) operations. For the ADS the advantages and disadvantages of the oxygen excess ratio (OER) oxygen pressure and their decoupling control strategies are systematically described by the following three aspects: single control hybrid control and intelligent algorithm control. Additionally the optimization strategies of the flow field or flow channel for oxygen supply speeds and distribution uniformity are compared and analyzed. For the HDS a systematic review of hydrogen recirculation control strategies purge strategies and hydrogen flow control strategies is conducted. These strategies contribute a lot to improving hydrogen utilization rates. Furthermore hydrogen supply pressure is summarized from the aspects of hybrid control and intelligent algorithm control. It is hoped to provide guidance or a reference for research on the HDS as well as the ADS control strategy and optimization strategy
Enabling Industrial Decarbonization: A MILP Optimization Model for Low-carbon Hydrogen Supply Chains
Jun 2024
Publication
This study develops a an optimization model focused on the layout and dispatch of a low-carbon hydrogen supply chain. The objective is to identify the lowest Levelized Cost of Hydrogen for a given demand. The model considers various elements including electricity supply from the local grid and renewable sources (photovoltaic and wind) alongside hydrogen production compression storage and transportation to end users. Applied to an industrial case study in Sweden the findings indicate that the major cost components are linked to electricity generation and investment in electrolyzers with the LCOH reaching 5.2 EUR/kgH2 under typical demand conditions. Under scenarios with higher peak demands and greater demand volatility the LCOH increases to 6.8 EUR/kgH2 due to the need for additional renewable energy capacity. These results highlight the critical impact of electricity availability and demand fluctuations on the LCOH emphasizing the complex interdependencies within the hydrogen supply chain. This study provides valuable insights into the feasibility and cost-effectiveness of adopting hydrogen as an energy carrier for renewable electricity in the context of decarbonizing industrial processes in the energy system.
Technology Assessment for the Transition to a Renewable Electric Grid
Jun 2024
Publication
To reduce carbon emissions generation of electricity from combustion systems is being replaced by renewable resources. However the most abundant renewable sources – solar and wind – are not dispatchable vary diurnally and are subject to intermittency and produce electricity at times in excess of demand (excess production). To manage this variability and capture the excess renewable energy energy storage technologies are being developed and deployed such as battery energy storage (BES) hydrogen production with electrolyzers (ELY) paired with hydrogen energy storage (HES) and fuel cells (FCs) and renewable natural gas (RNG) production. While BES may be better suited for short duration storage hydrogen is suited for long duration storage and RNG can decarbonize the natural gas system. California Senate Bill 100 (SB100) sets a goal that all retail electricity sold in the State must be sourced from renewable and zero-carbon resources by 2045 raising the questions of which set of technologies and in what proportion are required to meet the 2045 target in the required timeframe as well as the role of the natural gas infrastructure if any. To address these questions this study combines electric grid dispatch modeling and optimization to identify the energy storage and dispatchable technologies in 5-year increments from 2030 to 2045 required to transition from a 60% renewable electric grid in 2035 to a 100% renewable electric grid in 2045. The results show that by utilizing the established natural gas system to store and transmit hydrogen and RNG the deployment of battery energy storage is dramatically reduced. The required capacity for BES in 2045 for example is 40 times lower by leveraging the natural gas infrastructure with a concomitant reduction in cost and associated challenges to transform the electric grid.
Full Load Optimization of a Hydrogen Fuelled Industrial Engine
Jun 2024
Publication
There are a large number of applications in which hydrogen internal combustion engines represent a sensible alternative to battery electric propulsion systems and to fuel cell electric propulsion systems. The main advantages of combustion engines are their high degree of robustness and low manufacturing costs. No critical raw materials are required for production and there are highly developed production plants worldwide. A CO2-free operation is possible when using hydrogen as a fuel. The formation of nitrogen oxides during hydrogen combustion in the engine can be effectively mitigated by a lean-burn combustion process. However achieving low NOx raw emissions conflicts with achieving high power yields. In this work a series industrial diesel engine was converted for hydrogen operation and comprehensive engine tests were carried out. Various measures to improve the trade-off between NOx emissions and performance were investigated and evaluated. The rated power output and the maximum torque of the series diesel engine could be exceeded while maintaining an indicated specific NOx emission of 1 g/kWh along the entire full load curve. In the low-end-torque range however the gap to the full load curve of the series diesel engine could not be fully closed with the hardware used.
Socio-technical Imaginaries of Climate-neutral Aviation
May 2024
Publication
Limiting global warming to 1.5 ◦C is crucial to prevent the worst effects of climate change. This entails also the decarbonization of the aviation sector which is considered to be a “hard-to-abate” sector and thus requires special attention regarding its sustainability transition. However transition pathways to a potentially climateneutral aviation sector are unclear with different stakeholders having diverse imaginations of the sector's future. This paper aims to analyze socio-technical imaginaries of climate-neutral aviation as different perceptions of various stakeholders on this issue have not been sufficiently explored so far. In that sense this work contributes to the current scientific debate on socio-technical imaginaries of energy transitions for the first time studying the case of the aviation sector. Drawing on six decarbonization reports composed by different interest groups (e.g. industry academia and environmental associations) three imaginaries were explored following the process of a thematic analysis: rethinking travel and behavioral change (travel innovation) radical modernization and technological progress (fleet innovation) and transition to alternative fuels and renewable energy sources (fuel innovation). The results reveal how different and partly conflicting socio-technical imaginaries are co-produced and how the emergence and enforceability of these imaginaries is influenced by the situatedness of their creators indicating that the sustainability transition of aviation also raises political issues. Essentially as socio-technical imaginaries act as a driver for change policymakers should acknowledge the existence of alternative and counter-hegemonic visions created by actors from civil society settings to take an inclusive and equitable approach to implementing pathways towards climate-neutral aviation.
Particle Swarm Optimisation for a Hybrid Freight Train Powered by Hydrogen or Ammonia Solid Oxide Fuel Cells
May 2024
Publication
All diesel-only trains in the UK will be phased out by 2040. Hydrogen and ammonia emerge as alternative zerocarbon fuel for greener railway. Solid Oxide Fuel Cells (SOFCs) provide an alternative prime mover option which efficiently convert zero-carbon fuels into electricity without emitting nitrogen oxides (NOx) unlike traditional engines. Superior to Proton Exchange Membrane Fuel Cells (PEMFCs) in efficiency SOFCs fulfil MW-scale power needs and can use ammonia directly. This study investigates innovative strategies for integrating SOFCs into hybrid rail powertrains using hydrogen or ammonia. Utilizing an optimization framework incorporating Particle Swarm Optimization (PSO) the study aims to minimize operational costs while considering capital and replacement expenditures powertrain performance and component sizing. The findings suggest that hybrid powertrains based on ammonia-fueled SOFCs may potentially reduce costs by 30% compared to their hydrogen counterparts albeit requiring additional space for engine compartments. Ammonia-fueled SOFCs trains also exhibit a 5% higher efficiency at End-of-Life (EoL) showing less performance degradation than those powered by hydrogen. The State of Charge (SoC) of the batteries in range of 30–70% for both cases is identified as most costeffective.
The Possibility of Powering a Light Aircraft by Releasing the Energy Stored in Hydrogen within a Fuel Cell Stack
Jun 2024
Publication
In this work we examine the possibility of converting a light propeller-driven aircraft powered by a spark-ignition reciprocating piston and internal combustion engine running on AVGAS into one powered by an electric motor driven by a proton exchange membrane fuel cell stack running on hydrogen. Our studies suggest that storing hydrogen cryogenically is a better option than storing hydrogen under pressure. In comparison to cryogenic tanks high-pressure tanks are extremely heavy and unacceptable for light aircraft. We show that the modified aircraft (including batteries) is no heavier than the original and that the layout of the major components results in lower movement of the aircraft center-of-gravity as the aircraft consumes hydrogen. However we acknowledge that our fuel cell aircraft cannot store the same amount of energy as the original running on AVGAS. Therefore despite the fact that the fuel cell stack is markedly more efficient than an internal combustion engine there is a reduction in the range of the fuel cell aircraft. One of our most important findings is that the quantity of energy that we need to dissipate to the surroundings via heat transfer is significantly greater from a fuel cell stack than from an internal combustion engine. This is particularly the case when we attempt to run the fuel cell stack at high current densities. To control this problem our strategy during the cruise phase is to run the fuel cell stack at its maximum efficiency where the current density is low. We size the fuel cell stack to produce at least enough power for cruise and when we require excess power we add the energy stored in batteries to make up the difference.
Collective Hydrogen Stand-alone Renewable Energy Systems for Buildings in Spain. Towards the Self-sufficiency
May 2024
Publication
The article examines the feasibility of implementing standalone hydrogen-based renewable energy systems in Spanish residential buildings specifically analyzing the optimization of a solar-battery and solar-hydrogen system for a building with 20 dwellings in Spain. The study initially assesses two standalone setups: solarbattery and solar-hydrogen. Subsequently it explores scenarios where these systems are connected to the grid to only generate and sell surplus energy. A scenario involving grid connection for self-consumption without storage serves as a benchmark for comparison. All system optimizations are designed to meet energy demands without interruptions while minimizing costs as determined by a techno-economic analysis. The systems are sized using custom software that incorporates an energy management system and employs the Jaya algorithm for optimization. The findings indicate that selling surplus energy can be economically competitive and enhance the efficiency of grid-connected self-consumption systems representing the study’s main innovation. The conclusion highlights the economic and technical potential of an autonomous hybrid energy system that includes hydrogen with the significant remaining challenge being the development of a regulatory framework to support its technical feasibility in Spain.
An Analysis of Hybrid Renewable Energy-Based Hydrogen Production and Power Supply for Off-Grid Systems
Jun 2024
Publication
Utilizing renewable energy sources to produce hydrogen is essential for promoting cleaner production and improving power utilization especially considering the growing use of fossil fuels and their impact on the environment. Selecting the most efficient method for distributing power and capacity is a critical issue when developing hybrid systems from scratch. The main objective of this study is to determine how a backup system affects the performance of a microgrid system. The study focuses on power and hydrogen production using renewable energy resources particularly solar and wind. Based on photovoltaics (PVs) wind turbines (WTs) and their combinations including battery storage systems (BSSs) and hydrogen technologies two renewable energy systems were examined. The proposed location for this study is the northwestern coast of Saudi Arabia (KSA). To simulate the optimal size of system components and determine their cost-effective configuration the study utilized the Hybrid Optimization Model for Multiple Energy Resources (HOMER) software (Version 3.16.2). The results showed that when considering the minimum cost of energy (COE) the integration of WTs PVs a battery bank an electrolyzer and a hydrogen tank brought the cost of energy to almost 0.60 USD/kWh in the system A. However without a battery bank the COE increased to 0.72 USD/kWh in the same location because of the capital cost of system components. In addition the results showed that the operational life of the fuel cell decreased significantly in system B due to the high hours of operation which will add additional costs. These results imply that long-term energy storage in off-grid energy systems can be economically benefited by using hydrogen with a backup system.
Systems-Based Safety Analysis for Hydrogen-Driven Autonomous Ships
Jun 2024
Publication
In the maritime domain hydrogen fuel cell propulsion and autonomous vessels are two important issues that are yet to be implemented together because of a few challenges. It is obvious that there are several individual safety studies on Maritime Autonomous Surface Ships and hydrogen storage as well as fuel cells based on various risk assessment tools but the combined safety studies that include hydrogen fuel cells on autonomous vessels with recent risk analysis methods are extremely limited. This research chooses the “System-Theoretic Process Analysis” (STPA) method which is a recent method for potential risk identification and mitigation. Both hydrogen and autonomous vessels are analyzed and assessed together with the STPA method. Results are not speculative but rather flexible compared to conventional systems. The study finds a total of 44 unsafe control actions (UCAs) evolved from human and central control unit controllers through STPA. Further the loss scenarios (LS) are identified that lead to those UCAs so that loss scenarios can be assessed and UCAs can be mitigated for safe operation. The objective of this study is to ensure adequate safety for hydrogen fuel cell propulsion on autonomous vessels.
Game-Theory-Based Design and Analysis of a Peer-to-Peer Energy Exchange System between Multi-Solar-Hydrogen-Battery Storage Electric Vehicle Charging Stations
Jun 2024
Publication
As subsidies for renewable energy are progressively reduced worldwide electric vehicle charging stations (EVCSs) powered by renewable energy must adopt market-driven approaches to stay competitive. The unpredictable nature of renewable energy production poses major challenges for strategic planning. To tackle the uncertainties stemming from forecast inaccuracies of renewable energy this study introduces a peer-to-peer (P2P) energy trading strategy based on game theory for solar-hydrogen-battery storage electric vehicle charging stations (SHS-EVCSs). Firstly the incorporation of prediction errors in renewable energy forecasts within four SHS-EVCSs enhances the resilience and efficiency of energy management. Secondly employing game theory’s optimization principles this work presents a day-ahead P2P interactive energy trading model specifically designed for mitigating the variability issues associated with renewable energy sources. Thirdly the model is converted into a mixed integer linear programming (MILP) problem through dual theory allowing for resolution via CPLEX optimization techniques. Case study results demonstrate that the method not only increases SHS-EVCS revenue by up to 24.6% through P2P transactions but also helps manage operational and maintenance expenses contributing to the growth of the renewable energy sector.
Rule-Based Operation Mode Control Strategy for the Energy Management of a Fuel Cell Electric Vehicle
Jun 2024
Publication
Hydrogen due to its high energy density stands out as an energy storage method for the car industry in order to reduce the impact of the automotive sector on air pollution and global warming. The fuel cell electric vehicle (FCEV) emerges as a modification of the electric car by adding a proton exchange membrane fuel cell (PEMFC) to the battery pack and electric motor that is capable of converting hydrogen into electric energy. In order to control the energy flow of so many elements an optimal energy management system (EMS) is needed where rule-based strategies represent the smallest computational burden and are the most widely used in the industry. In this work a rulebased operation mode control strategy for the EMS of an FCEV validated by different driving cycles and several tests at the strategic points of the battery state of charge (SOC) is proposed. The results obtained in the new European driving cycle (NEDC) show the 12 kW battery variation of 2% and a hydrogen consumption of 1.2 kg/100 km compared to the variation of 1.42% and a consumption of 1.08 kg/100 km obtained in the worldwide harmonized light-duty test cycle (WLTC). Moreover battery tests have demonstrated the optimal performance of the proposed EMS strategy
Semi-Solid Forging Process of Aluminium Alloy Connecting Rods for the Hydrogen Internal Combustion Engine
Jun 2024
Publication
As an important piece of equipment for hydrogen energy application the hydrogen internal combustion engine is helpful for the realization of zero carbon emissions where the aluminum connecting rod is one of the key core components. A semi-solid forging forming process for the 7075 aluminum alloy connecting rod is proposed in this work. The influence of process parameters such as the forging ratio sustaining temperature and duration time on the microstructures of the semi-solid blank is experimentally investigated. The macroscopic morphology metallographic structure and physical properties of the connecting-rod parts are analyzed. Reasonable process parameters for preparing the semi-solid blank are obtained from the experimental results. Under the reasonable parameters the average grain size is 41.48~42.57 µm and the average shape factor is 0.80~0.81. The yield strength and tensile strength improvement ratio of the connecting rod produced by the proposed process are 47.07% and 20.89% respectively.
Operation Strategy for an Integrated Energy System Considering the Slow Dynamic Response Characteristics of Power-to-Gas Conversion
Jun 2024
Publication
Power-to-gas technology provides an emerging pathway for promoting green and lowcarbon transformation of energy systems. Through the processes of electrolyzing water and the methanation reaction it converts surplus renewable energy into hydrogen and natural gas offering an effective approach for large-scale integration of renewable energy sources. However the optimization of existing integrated energy systems has yet to finely model the operational characteristics of power-to-gas technology severely limiting the energy conversion efficiency of systems. To address this issue this paper proposes an integrated energy system operation strategy considering the slow dynamic response characteristics of power-to-gas. Firstly based on the technical features of power-to-gas an operational model for electrolyzing water to produce hydrogen is constructed considering the transition relationships among cold start-up hot start-up and production states of a methanation reaction thereby building a power-to-gas operation model considering slow dynamic response characteristics. This model finely reflects the impact of power-to-gas operational states on methanation facilitating accurate representation of the operational states of methanation. Then considering the energy conversion constraints and power balance of various coupled devices within integrated energy systems an optimization model for the operation of the integrated energy system is constructed with the total daily operation cost of the system as the optimization objective. Finally simulation comparisons are conducted to demonstrate the necessity of considering the slow dynamic response characteristics of power-to-gas technology for integrated energy system operation. The case study results indicate that the proposed power-to-gas operation model can accurately simulate the methanation process facilitating the rational conversion of surplus renewable energy into natural gas energy and avoiding misjudgments in system operation costs and energy utilization efficiency.
Optimal Sizing of Renewables-to-hydrogen Systems in a Suitable-site-selection Geospatial Framework: The Case Study if Italy and Portugal
Jun 2024
Publication
Growing renewable energy deployment worldwide has sparked a shift in the energy landscape with far-reaching geopolitical ramifications. Hydrogen’s role as an energy carrier is central to this change facilitating global trade and the decarbonisation of hard-to-abate sectors. This analysis offers a new method for optimally sizing solar/wind-to-hydrogen systems in specifically suitable locations. These locations are limited to the onshore and offshore regions of selected countries as determined by a bespoke geospatial analysis developed to be location-agnostic. Furthermore the research focuses on determining the best configurations for such systems that minimise the cost of producing hydrogen with the optimisation algorithm expanding from the detailed computation of the classic levelised cost of hydrogen. One of the study’s main conclusions is that the best hybrid configurations obtained provide up to 70% cost savings in some areas. Such findings represent unprecedented achievements for Italy and Portugal and can be a valuable asset for economic studies of this kind carried out by local and national governments across the globe. These results validate the optimisation model’s initial premise significantly improving the credibility of this work by constructively challenging the standard way of assessing large-scale green hydrogen projects.
Internal Combustion Engines and Carbon-Neutral Fuels: A Perspective on Emission Neutrality in the European Union
Mar 2024
Publication
Nowadays there is an intense debate in the European Union (EU) regarding the limits to achieve the European Green Deal to make Europe the first climate-neutral continent in the world. In this context there are also different opinions about the role that thermal engines should play. Furhermore there is no clear proposal regarding the possibilities of the use of green hydrogen in the transport decarbonization process even though it should be a key element. Thus there are still no precise guidelines regarding the role of green hydrogen with it being exclusively used as a raw material to produce E-fuels. This review aims to evaluate the possibilities of applying the different alternative technologies available to successfully complete the process already underway to achieve Climate Neutrality by about 2050 depending on the maturity of the technologies currently available and those anticipated to be available in the coming decades.
Energy Use and Greenhouse Gas Emissions of Traction Alternatives for Regional Railways
Feb 2024
Publication
This paper presents a method for estimating Well-to-Wheel (WTW) energy use and greenhouse gas (GHG) emissions attributed to the advanced railway propulsion systems implemented in conjunction with different energy carriers and their production pathways. The analysis encompasses diesel-electric multiple unit vehicles converted to their hybrid-electric plug-in hybrid-electric fuel cell hybrid-electric or battery-electric counterparts combined with biodiesel or hydrotreated vegetable oil (HVO) as the first and second generation biofuels liquefied natural gas (LNG) hydrogen and/or electricity. The method is demonstrated using non-electrified regional railway network with heterogeneous vehicle fleet in the Netherlands as a case. Battery-electric system utilizing green electricity is identified as the only configuration leading to emission-free transport while offering the highest energy use reduction by 65–71% compared to the current diesel-powered hybrid-electric system. When using grey electricity based on the EU2030 production mix these savings are reduced to about 27–39% in WTW energy use and around 68–73% in WTW GHG emissions. Significant reductions in overall energy use and emissions are obtained for the plug-in hybrid-electric concept when combining diesel LNG or waste cooking oil-based HVO with electricity. The remaining configurations that reduce energy use and GHG emissions are hybrid-electric systems running on LNG or HVO from waste cooking oil. The latter led to approximately 88% lower WTW emissions than the baseline for each vehicle type. When produced from natural gas or EU2030-mix-based electrolysis hydrogen negatively affected both aspects irrespective of the prime mover technology. However when produced via green electricity it offers a GHG reduction of approximately 90% for hybrid-electric and fuel cell hybrid-electric configurations with a further reduction of up to 92–93% if combined with green electricity in plug-in hybrid-electric systems. The results indicate that HVO from waste cooking oil could be an effective and instantly implementable transition solution towards carbon–neutral regional trains allowing for a smooth transition and development of supporting infrastructure required for more energy-efficient and environment-friendly technologies.
Prospective Assessment of Transformation Pathways Toward Low-carbon Steelmaking: Evaluating Economic and Climate Impacts in Germany
Jan 2024
Publication
Due to climate change there is an urgent need to decarbonize high-emission industries. As coal-based operations predominate in primary steelmaking the steel industry offers an exceptionally high potential for reducing greenhouse gas emissions. Alternative processes for almost fully decarbonized primary steelmaking exist but require substantial investments by steelmakers for their implementation while maintaining desired production levels during the transformation periods. In this context the energy carriers required change such that the transformation of the steelmaking processes is deeply intertwined with the transformation of the background system. For the first time we evaluate potential transformation pathways from the steelmakers’ perspective using a prospective life cycle assessment approach. We find that hydrogen may facilitate a reduction of direct emissions by around 96 % compared to conventional steelmaking in 2050. However indirect emissions remain at a high level throughout the transformation period unless the upstream stages of the value chain are transformed accordingly.
A Zero CO2 Emissions Large Ship Fuelled by an Ammonia-hydrogen Blend: Reaching the Decarbonisation Goals
Aug 2023
Publication
To reach the decarbonisation goals a zero CO2 emissions large ship propulsion system is proposed in this work. The ship selected is a large ferry propelled by an internal combustion engine fuelled by an ammonia-hydrogen blend. The only fuel loaded in the vessel will be ammonia. The hydrogen required for the combustion in the engine will be produced onboard employing ammonia decomposition. The heat required for this decomposition section will be supplied by using the hot flue gases of the combustion engine. To address the issues regarding NOx emissions a selective catalytic reduction (SCR) reactor was designed. The main operating variables for all the equipment were computed for engine load values of 25% 50% 75% and 100%. Considering the lowest SCR removal rate (91% at an engine load of 100%) the NOx emissions of the vessel were less than 0.5 g/kWh lower than the IMO requirements. An energy analysis of the system proposed to transform ammonia into energy for shipping was conducted. The global energy and exergy efficiencies were 42.4% and 48.1%. In addition an economic analysis of the system was performed. The total capital cost (CAPEX) for the system can be estimated at 8.66 M€ (784 €/kW) while the operating cost (OPEX) ranges between 210 €/MWh (engine load 100%) and 243 €/MWh (engine load of 25%). Finally a sensitivity analysis for the price of ammonia was performed resulting in the feasibility of reducing the operating cost to below 150 €/MWh in the near horizon.
Towards Energy Freedom: Exploring Sustainable Solutions for Energy Independence and Self-sufficiency using Integrated Renewable Energy-driven Hydrogen System
Jan 2024
Publication
n the pursuit of sustainable energy solutions the integration of renewable energy sources and hydrogen technologies has emerged as a promising avenue. This paper introduces the Integrated Renewable Energy-Driven Hydrogen System as a holistic approach to achieve energy independence and self-sufficiency. Seamlessly integrating renewable energy sources hydrogen production storage and utilization this system enables diverse applications across various sectors. By harnessing solar and/or wind energy the Integrated Renewable EnergyDriven Hydrogen System optimizes energy generation distribution and storage. Employing a systematic methodology the paper thoroughly examines the advantages of this integrated system over other alternatives emphasizing its zero greenhouse gas emissions versatility energy resilience and potential for large-scale hydrogen production. Thus the proposed system sets our study apart offering a distinct and efficient alternative compared to conventional approaches. Recent advancements and challenges in hydrogen energy are also discussed highlighting increasing public awareness and technological progress. Findings reveal a payback period ranging from 2.8 to 6.7 years depending on the renewable energy configuration emphasizing the economic attractiveness and potential return on investment. This research significantly contributes to the ongoing discourse on renewable energy integration and underscores the viability of the Integrated Renewable EnergyDriven Hydrogen System as a transformative solution for achieving energy independence. The employed model is innovative and transferable to other contexts.
Environmental-economic Sustainability of Hydrogen and Ammonia Fuels for Short Sea Shipping Operations
Jan 2024
Publication
Alternative fuels of low or zero carbon content can decarbonise the shipping operations. This study aims at assessing the lifetime environmental-economic sustainability of ammonia and hydrogen as alternatives to diesel fuel for short sea shipping cargo vessels. A model is employed to calculate key performance indicators representing the lifetime financial sustainability and environmental footprint of the case ship using a realistic operating profile and considering several scenarios with different diesel substitution rates. Scenarios meeting the carbon emissions reduction targets set by the International Maritime Organisation (IMO) for 2030 are identified whereas policy measures for their implementation including the emissions taxation are discussed. The derived results demonstrate that the future implementation of carbon emissions taxation in the ranges of 136–965 €/t for hydrogen and 356–2647 €/t for ammonia can support these fuels financial sustainability in shipping. This study provides insights for adopting zero-carbon fuels and as such impacts the de-risking of shipping decarbonisation.
Low Carbon Optimal Operation of Integrated Energy Systems Considering Air Pollution Emissions
Apr 2023
Publication
To reduce carbon sulfur dioxide (SO2) and nitrogen oxide (NOX) emissions from the integrated energy system (IES) a low carbon optimization strategy for the IES is proposed taking into account carbon SO2 and NOX emissions. Firstly hydrogen production storage and use equipment such as methane reactor electrolysis tank hydrogen fuel cell and hydrogen energy storage are added to the traditional IES to build a multi-energy complementary system of electricity gas cooling thermal and hydrogen. Then this paper introduces a stepped carbon trading mechanism and the model of the emissions of SO2 and NOX. Finally to further reduce its pollutant emissions the model of combined heat and power units and hydrogen fuel cells with adjustable thermoelectric ratio is built. To compare and account for the impact of air pollutant emissions on the optimal low-carbon operation of IES this paper construsted three scenarios with the lowest cost of carbon trading the lowest penalty cost for SO2 and NOX emissions and total operation cost as objective functions respectively The results show that the strategy is effective in reducing air pollutant emissions from integrated energy systems and the outputs of CHP and HFC with adjustable thermoelectric ratios are more flexible and can effectively achieve carbon reduction and pollutant emission reduction.
Explaining Varying Speeds of Low-carbon Reorientation in the United Kingdom's Steel, Petrochemical, and Oil Refining Industries: A Multi-dimensional Comparative Analysis and Outlook
Feb 2024
Publication
Accelerated decarbonisation of steelmaking oil refining and petrochemical industries is essential for climate change mitigation. Drawing on three longitudinal case studies of these industries in the UK this synthesis article makes a comparative analysis of their varying low-carbon reorientation speeds. The paper uses the triple embeddedness framework to analyse five factors (policy support international competition financial health technical feasibility corporate strategy and mindset) that explain why UK oil refineries have in recent years been comparatively the fastest in their low-carbon reorientation and UK steelmakers the slowest. We find that policy support has been more beneficial for refining and petrochemicals than for steel although recent government deals with steelmakers addressed this imbalance. International competition has been high for steel and petrochemicals and comparatively lower for refining (meaning that decarbonisation costs are less detrimental for international competitiveness). Financial performance has comparatively been worst for steel and best for oil refining which shapes the economic feasibility of low-carbon options. Hydrogen and carbon-capture-and-storage are technologically feasible for refining and petrochemicals while Electric Arc Furnaces are technically feasible for steelmakers but face wider feasibility problems (with scrap steel supply electricity grids and electricity prices) which is why we question the recent government deals. Corporate strategy and perceptions changed in oil refining with firms seeing economic opportunities in decarbonisation while steelmakers and petrochemical firms still mostly see decarbonisation as a burden and threat. The paper ends with comparative conclusions a discussion of political considerations and future outlooks for the three UK industries policy and research.
Chemical Kinetic Analysis of High-Pressure Hydrogen Ignition and Combustion toward Green Aviation
Jan 2024
Publication
In the framework of the “Multidisciplinary Optimization and Regulations for Low-boom and Environmentally Sustainable Supersonic aviation” project pursued by a consortium of European government and academic institutions coordinated by Politecnico di Torino under the European Commission Horizon 2020 financial support the Italian Aerospace Research Centre is computationally investigating the high-pressure hydrogen/air kinetic combustion in the operative conditions typically encountered in supersonic aeronautic ramjet engines. This task is being carried out starting from the zero-dimensional and one-dimensional chemical kinetic assessment of the complex and strongly pressure-sensitive ignition behavior and flame propagation characteristics of hydrogen combustion through the validation against experimental shock tube and laminar flame speed measurements. The 0D results indicate that the kinetic mechanism by Politecnico di Milano and the scheme formulated by Kéromnès et al. provide the best matching with the experimental ignition delay time measurements carried out in high-pressure shock tube strongly argon-diluted reaction conditions. Otherwise the best behavior in terms of laminar flame propagation is achieved by the Mueller scheme while the other investigated kinetic mechanisms fail to predict the flame speeds at elevated pressures. This confirms the non-linear and intensive pressure-sensitive behavior of hydrogen combustion especially in the critical high-pressure and low-temperature region which is hard to be described by a single all-encompassing chemical model.
Decarbonizing Combustion with Hydrogen Blended Fuels: An Exploratory Study of Impact of Hydrogen on Hydrocarbon Autoignition
Jan 2024
Publication
Blending hydrogen to existing fuel mix represents a major opportunity for decarbonisation. One important consideration for this application is the chemical interaction between hydrogen and hydrocarbon fuels arising from their different combustion chemistries and varying considerably with combustion processes. This paper conducted an exploratory study of hydrogen’s impact on autoignition in several combustion processes where hydrogen is used as a blending component or the main fuel. Case studies are presented for spark ignition engines (H2/natural gas) compression ignition engines (H2/diesel) moderate or intense low-oxygen dilution (MILD) combustors (H2/natural gas) and rotational detonation engines (H2/natural gas). Autoignition reactivity as a function of the hydrogen blending level is investigated numerically using the ignition delay iso-contours and state-of-the-art kinetic models at time scales representative of each application. The results revealed drastically different impact of hydrogen blending on autoignition due to different reaction temperature pressure and time scale involved in these applications leaving hydrocarbon interacting with hydrogen at different ignition branches where the negative pressure/temperature dependency of oxidation kinetics could take place. The resulted non-linear and at times non-monotonic behaviours indicate a rich topic for combustion chemistry and also demonstrates ignition delay iso-contour as a useful tool to scope autoignition reactivity for a wide range of applications.
Low-carbon Planning for Park-level Integrated Energy System Considering Optimal Construction Time Sequence and Hydrogen Energy Facility
Apr 2023
Publication
With the increasing concern about global energy crisis and environmental pollution the integrated renewable energy system has gradually become one of the most important ways to achieve energy transition. In the context of the rapid development of hydrogen energy industry the proportion of hydrogen energy in the energy system has gradually increased. The conversion between various energy sources has also become more complicated which poses challenges to the planning and construction of park-level integrated energy systems (PIES). To solve this problem we propose a bi-level planning model for an integrated energy system with hydrogen energy considering multi-stage investment and carbon trading mechanism. First the mathematical models of each energy source and energy storage in the park are established respectively and the independent operation of the equipment is analyzed. Second considering the operation state of multi-energy coordination a bi-level planning optimization model is established. The upper level is the capacity configuration model considering the variable installation time of energy facilities while the lower level is the operation optimization model considering several typical daily operations. Third considering the coupling relationship between upper and lower models the bi-level model is transformed into a solvable single-level mixed integer linear programming (MILP) model by using Karush–Kuhn–Tucker (KKT) condition and big-M method. Finally the proposed model and solution methods are verified by comprehensive case studies. Simulation results show that the proposed model can reduce the operational cost and carbon emission of PIES in the planning horizon and provide insights for the multi-stage investment of PIES.
An Approach for Sizing a PV-battery-electrolyzer-fuel cell Energy System: A Cast Study at a Field Lab
May 2023
Publication
Hydrogen is becoming increasingly popular as a clean secure and affordable energy source for the future. This study develops an approach for designing a PV–battery–electrolyzer–fuel cell energy system that utilizes hydrogen as a long-term storage medium and battery as a short-term storage medium. The system is designed to supply load demand primarily through direct electricity generation in the summer and indirect electricity generation through hydrogen in the winter. The sizing of system components is based on the direct electricity and indirect hydrogen demand with a key input parameter being the load sizing factor which determines the extent to which hydrogen is used to meet seasonal imbalance. Technical and financial indicators are used to assess the performance of the designed system. Simulation results indicate that the energy system can effectively balance the seasonal variation of renewable generation and load demand with the use of hydrogen. Additionally guidelines for achieving self-sufficiency and system sustainability for providing enough power in the following years are provided to determine the appropriate component size. The sensitivity analysis indicates that the energy system can achieve self-sufficiency and system sustainability with a proper load sizing factor from a technical perspective. From an economic perspective the levelized cost of energy is relatively high because of the high costs of hydrogen-related components at this moment. However it has great economic potential for future self-sufficient energy systems with the maturity of hydrogen technologies.
Investigations on Pressure Dependence of Coriolis Mass Flow Meters Used at Hydrogen Refueling Stations
Sep 2020
Publication
In the framework of the ongoing EMPIR JRP 16ENG01 ‘‘Metrology for Hydrogen Vehicles’’ a main task is to investigate the influence of pressure on the measurement accuracy of Coriolis Mass Flow Meters (CFM) used at Hydrogen Refueling Stations (HRS). At a HRS hydrogen is transferred at very high and changing pressures with simultaneously varying flow rates and temperatures. It is clearly very difficult for CFMs to achieve the current legal requirements with respect to mass flow measurement accuracy at these measurement conditions. As a result of the very dynamic filling process it was observed that the accuracy of mass flow measurement at different pressure ranges is not sufficient. At higher pressures it was found that particularly short refueling times cause significant measurement deviations. On this background it may be concluded that pressure has a great impact on the accuracy of mass flow measurement. To gain a deeper understanding of this matter RISE has built a unique high-pressure test facility. With the aid of this newly developed test rig it is possible to calibrate CFMs over a wide pressure and flow range with water or base oils as test medium. The test rig allows calibration measurements under the conditions prevailing at a 70 MPa HRS regarding mass flows (up to 3.6 kg min−1) and pressures (up to 87.5 MPa).
Subcooled Liquid Hydrogen Technology for Heavy-Duty Trucks
Jan 2024
Publication
Subcooled liquid hydrogen (sLH2) is an onboard storage as well as a hydrogen refueling technology that is currently being developed by Daimler Truck and Linde to boost the mileage of heavy-duty trucks while also improving performance and reducing the complexity of hydrogen refueling stations. In this article the key technical aspects advantages challenges and future developments of sLH2 at vehicle and infrastructure levels will be explored and highlighted.
Decarbonization Pathways, Strategies, and Use Cases to Achieve Net-Zero CO2 Emissions in the Steelmaking Industry
Oct 2023
Publication
The steelmaking industry is responsible for 7% of global CO2 emissions making decarbonization a significant challenge. This review provides a comprehensive analysis of current steel-production processes assessing their environmental impact in terms of CO2 emissions at a global level. Limitations of the current pathways are outlined by using objective criteria and a detailed review of the relevant literature. Decarbonization strategies are rigorously evaluated across various scenarios emphasizing technology feasibility. Focusing on three pivotal areas—scrap utilization hydrogen integration and electricity consumption—in-depth assessments are provided backed by notable contributions from both industrial and scientific fields. The intricate interplay of technical economic and regulatory considerations substantially affects CO2 emissions particularly considering the EU Emissions Trading System. Leading steel producers have established challenging targets for achieving carbon neutrality requiring a thorough evaluation of industry practices. This paper emphasizes tactics to be employed within short- medium- and long-term periods. This article explores two distinct case studies: One involves a hot rolling mill that utilizes advanced energy techniques and uses H2 for the reheating furnace resulting in a reduction of 229 kt CO2 -eq per year. The second case examines DRI production incorporating H2 and achieves over 90% CO2 reduction per ton of DRI.
Performance Assessment and Optimization of the Ultra-High Speed Air Compressor in Hydrogen Fuel Cell Vehicles
Feb 2024
Publication
Air compressors in hydrogen fuel cell vehicles play a crucial role in ensuring the stability of the cathode air system. However they currently face challenges related to low efficiency and poor stability. To address these issues the experimental setup for the pneumatic performance of air compressors is established. The effects of operational parameters on energy consumption efficiency and mass flow rate of the air compressor are revealed based on a Morris global sensitivity analysis. Considering a higher flow rate larger efficiency and lower energy consumption simultaneously the optimal operating combination of the air compressor is determined based on grey relational multi-objective optimization. The optimal combination of operational parameters consisted of a speed of 80000 rpm a pressure ratio of 1.8 and an inlet temperature of 18.3 °C. Compared to the average values the isentropic efficiency achieved a 48.23% increase and the mass flow rate rose by 78.88% under the optimal operational combination. These findings hold significant value in guiding the efficient and stable operation of air compressors. The comprehensive methodology employed in this study is applicable further to investigate air compressors for hydrogen fuel cell vehicles.
Hydrogen-Powered Aircraft at Airports: A Review of the Infrastructure Requirements and Planning Challenges
Nov 2023
Publication
Hydrogen-fueled aircraft are a promising innovation for a sustainable future in aviation. While hydrogen aircraft design has been widely studied research on airport requirements for new infrastructure associated with hydrogen-fueled aircraft and its integration with existing facilities is scarce. This study analyzes the current body of knowledge and identifies the planning challenges which need to be overcome to enable the operation of hydrogen flights at airports. An investigation of the preparation of seven major international airports for hydrogen-powered flights finds that although there is commitment airports are not currently prepared for hydrogen-based flights. Major adjustments are required across airport sites covering land use plans airside development utility infrastructure development and safety security and training. Developments are also required across the wider aviation industry including equipment updates such as for refueling and ground support and supportive policy and regulations for hydrogen-powered aircraft. The next 5–10 years is identified from the review as a critical time period for airports given that the first commercial hydrogen-powered flight is likely to depart in 2026 and that the next generation of short-range hydrogen-powered aircraft is predicted to enter service between 2030 and 2035.
An Exploration of Safety Measures in Hydrogen Refueling Stations: Delving into Hydrogen Equipment and Technical Performance
Feb 2024
Publication
The present paper offers a thorough examination of the safety measures enforced at hydrogen filling stations emphasizing their crucial significance in the wider endeavor to advocate for hydrogen as a sustainable and reliable substitute for conventional fuels. The analysis reveals a wide range of crucial safety aspects in hydrogen refueling stations including regulated hydrogen dispensing leak detection accurate hydrogen flow measurement emergency shutdown systems fire-suppression mechanisms hydrogen distribution and pressure management and appropriate hydrogen storage and cooling for secure refueling operations. The paper therefore explores several aspects including the sophisticated architecture of hydrogen dispensers reliable leak-detection systems emergency shut-off mechanisms and the implementation of fire-suppression tactics. Furthermore it emphasizes that the safety and effectiveness of hydrogen filling stations are closely connected to the accuracy in the creation and upkeep of hydrogen dispensers. It highlights the need for materials and systems that can endure severe circumstances of elevated pressure and temperature while maintaining safety. The use of sophisticated leak-detection technology is crucial for rapidly detecting and reducing possible threats therefore improving the overall safety of these facilities. Moreover the research elucidates the complexities of emergency shut-off systems and fire-suppression tactics. These components are crucial not just for promptly managing hazards but also for maintaining the station’s structural soundness in unanticipated circumstances. In addition the study provides observations about recent technical progress in the industry. These advances effectively tackle current safety obstacles and provide the foundation for future breakthroughs in hydrogen fueling infrastructure. The integration of cutting-edge technology and materials together with the development of upgraded safety measures suggests a positive trajectory towards improved efficiency dependability and safety in hydrogen refueling stations.
A Review of Electrolyzer-based Systems Providing Grid Ancillary Service: Current Status, Market, Challenges and Future Directions
Feb 2024
Publication
Concerns related to climate change have shifted global attention towards advanced sustainable and decarbonized energy systems. While renewable resources such as wind and solar energy offer environmentally friendly alternatives their inherent variability and intermittency present significant challenges to grid stability and reliability. The integration of renewable energy sources requires innovative solutions to effectively balance supply and demand in the electricity grid. This review explores the critical role of electrolyzer systems in addressing these challenges by providing ancillary services to modern electricity grids. Electrolyzers traditionally used only for hydrogen production have now emerged as versatile tools capable of responding quickly to grid load variations. They can consume electricity during excess periods or when integrated with fuel cells generate electricity during peak demand contributing to grid stability. Therefore electrolyzer systems can fulfill the dual function of producing hydrogen for the end-user and offering grid balancing services ensuring greater economic feasibility. This review paper aims to provide a comprehensive view of the electrolyzer systems’ role in the provision of ancillary services including frequency control voltage control congestion management and black start. The technical aspects market projects challenges and future prospects of using electrolyzers to provide ancillary services in modern energy systems are explored.
Numerical Study on a Diesel/Dissociated Methanol Gas Compression Ignition Engine with Exhaust Gas Recirculation
Aug 2023
Publication
Bo Li,
Yihua Chen,
Fei Zhong and
Xu Hao
Hydrogen is the most promising alternative fuel in the field of engines. Exhaust heat assisted methanol dissociation is an attractive approach for generating hydrogen. In this work simulations are conducted on a compression ignition engine fueled with different proportions of diesel-dissociated methanol gas (DMG) blends at intermediate engine speed full load and 0% EGR ratio. The results reveal that the indicated thermal efficiency and indicated mean effective pressure are greatly enhanced combustion efficiency is increased and regular emissions of CO HC and soot are reduced while NOx emissions are reduced with increased DMG substitution. In addition a simulation is conducted at an intermediate engine speed full load 15% DMG substitution ratio and varying EGR ratios of 0–20%. The results indicate that the dual-fuel engine outperforms the original engine with respect to power fuel economy and regular emissions once an optimal EGR rate is adopted.
OIES Podcast - Aviation Fuels and the Potential of Hydrogen
Feb 2024
Publication
In the latest OIES podcast from the Hydrogen Programme James Henderson talks to Abdurahman Alsulaiman about his latest paper entitled “Navigating Turbulence: Hydrogen’s Role in the Decarbonisation of the Aviation Sector.” In the podcast we discuss the current balance of fuels in the aviation sector the importance of increasing efficiency of aero-engines and the impact of increasing passenger miles travelled. The podcast then considers different decarbonisation options for the sector focussing on a change of engine technology to allow the use of alternative fuels such as hydrogen or electricity but also looking at the potential for hydrogen to play an important role in the development of Sustainable Aviation Fuels (SAFs) for use with current engine technology. We also look at Low Carbon Aviation Fuels which are essentially existing fuels derived from a significantly decarbonised supply chain and assess whether they have an important role to play as the aviation sector targets a net zero outcome.
The podcast can be found on their website.
The podcast can be found on their website.
Technoeconomic, Environmental and Multi-criteria Decision Making Investigations for Optimisation of Off-grid Hybrid Renewable Energy System with Green Hydrogen Production
Jan 2024
Publication
The current study presents a comprehensive investigation of different energy system configurations for a remote village community in India with entirely renewable electricity. Excess electricity generated by the systems has been stored using two types of energy storage options: lithium-ion batteries and green hydrogen production through the electrolysers. The hybrid renewable energy system (HRES) configurations have been sized by minimising the levelised cost of energy (LCOE). In order to identify the best-performing HRES configuration economic and environmental performance indicators has been analysed using the multi-criteria decision-making method (MCDM) TOPSIS. Among the evaluated system configurations system-1 with a photovoltaic panel (PV) size of 310.24 kW a wind turbine (WT) size of 690 kW a biogas generator (BG) size of 100 kW a battery (BAT) size of 174 kWh an electrolyser (ELEC) size of 150 kW a hydrogen tank (HT) size of 120 kg and a converter (CONV) size of 106.24 kW has been found to be the best-performing system since it provides the highest relative closeness (RC) value (∼0.817) and also has the lowest fuel consumption rate of 2.31 kg/kWh. However system-6 shows the highest amount of CO2 (143.97 kg/year) among all the studied system configurations. Furthermore a detailed technical economic and environmental analysis has been conducted on the optimal HRES configuration. The minimum net present cost (NPC) LCOE and cost of hydrogen (COH) for system 1 has been estimated to be $1960584 $0.44/kWh and $22.3/kg respectively.
Optimal Hydrogen Infrastructure Planning for Heat Decarbonisation
Feb 2024
Publication
Energy decarbonisation is essential to achieve Net-Zero emissions goal by 2050. Consequently investments in alternative low-carbon pathways and energy carriers for the heat sector are required. In this study we propose an optimisation framework for the transition of heat sector in Great Britain focusing on hydrogen infrastructure decisions. A spatially-explicit mixed-integer linear programming (MILP) evolution model is developed to minimise the total system’s cost considering investment and operational decisions. The optimisation framework incorporates both long-term planning horizon of 5-year steps from 2035 to 2050 and typical days with hourly resolution. Aiming to alleviate the computational effort of such multiscale model two hierarchical solution approaches are suggested that result in computational time reduction. From the optimisation results it is shown that the installation of gas reforming hydrogen production technologies with CCS and biomass gasification with CCS can provide a cost-effective strategy achieving decarbonisation goal. What-if analysis is conducted to demonstrate further insights for future hydrogen infrastructure investments. Results indicate that as cost is highly dependent on natural gas price Water Electrolysis capacity increases significantly when gas price rises. Moreover the introduction of carbon tax policy can lead to lower CO2 net emissions.
Thermodynamic Modelling and Optimisation of a Green Hydrogen-blended Syngas-fueled Integrated PV-SOFC System
Sep 2023
Publication
Developing an effective energy transition roadmap is crucial in the face of global commitments to achieve net zero emissions. While renewable power generation systems are expanding challenges such as curtailments and grid constraints can lead to energy loss. To address this surplus electricity can be converted into green hydrogen serving as a key component in the energy transition. This research explores the use of renewable solar energy for powering a proton exchange membrane electrolyser to produce green hydrogen while a downdraft gasifier fed by municipal solid waste generates hydrogen-enriched syngas. The blended fuel is then used to feed a Solid Oxide Fuel Cell (SOFC) system. The study investigates the impact of hydrogen content on the performance of the fuel cell-based power plant from thermodynamics and exergoeconomic perspectives. Multiobjective optimisation using a genetic algorithm identifies optimal operating conditions for the system. Results show that blending hydrogen with syngas increases combined heat and power efficiency by up to 3% but also raises remarkably the unit product cost and reduces carbon dioxide emissions. Therefore the optimal values for hydrogen content current density temperatures and other parameters are determined. These findings contribute to the design and operation of an efficient and sustainable energy generation system.
Integration of Microgrids in Chemical Industries with Hydrogen as a Byproduct: Styrene Production Case Study
Feb 2024
Publication
The chemical industry serves as a global economic backbone and it is an intensive consumer of conventional energy. Due to the depletion of fossil fuels and the emission of greenhouse gases it is necessary to analyze energy supply solutions based on renewable energy sources in this industrial sector. Unlike other sectors such as residential or service industries which have been thoroughly analyzed by the scientific community the use of renewable energies in the chemical industry remains comparatively less examined by the scientific community. This article studies the use of an energy supply system based on photovoltaic technology or a PEM fuel cell for a styrene production industry analyzing the integration of energy storage systems such as batteries as well as different uses for the surplus hydrogen produced by the facility. The most interesting conclusions of the article are: (1) the renewable microgrid considered is viable both technically and economically with a discounted payback period between 5.4 and 6.5 years using batteries as an energy storage system; and (2) the use of hydrogen as energy storage system for a styrene industry is not yet a viable option from an economic point of view.
Identification of Hydrogen-Energy-Related Emerging Technologies Based on Text Mining
Dec 2023
Publication
As a versatile energy carrier hydrogen possesses tremendous potential to reduce greenhouse emissions and promote energy transition. Global interest in producing hydrogen from renewable energy sources and transporting storing and utilizing hydrogen is rising rapidly. However the high costs of producing clean hydrogen and the uncertain application scenarios for hydrogen energy result in its relatively limited utilization worldwide. It is necessary to find new promising technological paths to drive the development of hydrogen energy. As part of technological innovation emerging technologies have vital features such as prominent impact novelty relatively fast growth etc. Identifying emerging hydrogen-energy-related technologies is important for discovering innovation opportunities during the energy transition. Existing research lacks analysis of the characteristics of emerging technologies. Thus this paper proposes a method combining the latent Dirichlet allocation topic model and hydrogen-energy expert group decision-making. This is used to identify emerging hydrogen-related technology regarding two features of emerging technologies novelty and prominent impact. After data processing topic modeling and analysis the patent dataset was divided into twenty topics. Six emerging topics possess novelty and prominent impact among twenty topics. The results show that the current hotspots aim to promote the application of hydrogen energy by improving the performance of production catalysts overcoming the wide power fluctuations and large-scale instability of renewable energy power generation and developing advanced hydrogen safety technologies. This method efficiently identifies emerging technologies from patents and studies their development trends. It fills a gap in the research on emerging technologies in hydrogen-related energy. Research achievements could support the selection of technology pathways during the low-carbon energy transition.
Alternative Gaseous Fuels for Marine Vessels towards Zero-Carbon Emissions
Nov 2023
Publication
The maritime industry is recognized as a major pollution source to the environment. The use of low- or zero-carbon marine alternative fuel is a promising measure to reduce emissions of greenhouse gases and toxic pollutants leading to net-zero carbon emissions by 2050. Hydrogen (H2 ) fuel cells particularly proton exchange membrane fuel cell (PEMFC) and ammonia (NH3 ) are screened out to be the feasible marine gaseous alternative fuels. Green hydrogen can reduce the highest carbon emission which might amount to 100% among those 5 types of hydrogen. The main hurdles to the development of H2 as a marine alternative fuel include its robust and energy-consuming cryogenic storage system highly explosive characteristics economic transportation issues etc. It is anticipated that fossil fuel used for 35% of vehicles such as marine vessels automobiles or airplanes will be replaced with hydrogen fuel in Europe by 2040. Combustible NH3 can be either burned directly or blended with H2 or CH4 to form fuel mixtures. In addition ammonia is an excellent H2 carrier to facilitate its production storage transportation and usage. The replacement of promising alternative fuels can move the marine industry toward decarbonization emissions by 2050.
Conversion of a Small-Size Passenger Car to Hydrogen Fueling: 0D/1D Simulation of EGR and Related Flow Limitations
Jan 2024
Publication
Hydrogen is seen as a prime choice for complete replacement of gasoline so as to achieve zero-emissions energy and mobility. Combining the use of this alternative fuel with a circular economy approach for giving new life to the existing fleet of passenger cars ensures further benefits in terms of cost competitiveness. Transforming spark ignition (SI) engines to H2 power requires relatively minor changes and limited added components. Within this framework the conversion of a small-size passenger car to hydrogen fueling was evaluated based on 0D/1D simulation. One of the methods to improve efficiency is to apply exhaust gas recirculation (EGR) which also lowers NOx emissions. Therefore the previous version of the quasi-dimensional model was modified to include EGR and its effects on combustion. A dedicated laminar flame speed model was implemented for the specific properties of hydrogen and a purpose-built sub-routine was implemented to correctly model the effects of residual gas at the start of combustion. Simulations were performed in several operating points representative of urban and highway driving. One of the main conclusions was that highpressure recirculation was severely limited by the minimum flow requirements of the compressor. Low-pressure EGR ensured wider applicability and significant improvement of efficiency especially during partial-load operation specific to urban use. Another benefit of recirculation was that pressure rise rates were predicted to be more contained and closer to the values expected for gasoline fueling. This was possible due to the high tolerance of H2 to the presence of residual gas.
Analysis of CO2 Emissions Reduction on the Future Hydrogen Supply Chain Network for Dubai Buses
Apr 2023
Publication
There is an impetus to decarbonize transportation sector and mitigate climate change. This study examines the effect of adopting hydrogen (H2) as a fuel for Dubai Buses at different penetration scales on carbon dioxide (CO2) emissions reduction. A H2 supply-chain system dynamics model is developed to conduct life cycle cost and environmental analysis and evaluate the efficacy of different carbon prices and subsidies. Gray green and mixed H2 production scenarios were considered. The results show that gray hydrogen reduces 7.1 million tons of CO2 which is half of green hydrogen buses. Replacing diesel fleet at end of lifetime with mixed hydrogen bus fleet was the optimal approach to promote green hydrogen at pump reaching $4/kg in a decade. This gradual transition reduces 62% of the well-to-wheel CO2 emissions of the new bus fleet and creates mass for economies of scale as carbon prices and subsidies cannot promote green hydrogen alone.
Deploying Green Hydrogen to Decarbonize China's Coal Chemical Sector
Dec 2023
Publication
China’s coal chemical sector uses coal as both a fuel and feedstock and its increasing greenhouse gas (GHG) emissions are hard to abate by electrification alone. Here we explore the GHG mitigation potential and costs for onsite deployment of green H2 and O2 in China’s coal chemical sector using a lifecycle assessment and techno-economic analyses. We estimate that China’s coal chemical production resulted in GHG emissions of 1.1 gigaton CO2 equivalent (GtCO2eq) in 2020 equal to 9% of national emissions. We project GHG emissions from China’s coal chemical production in 2030 to be 1.3 GtCO2eq ~50% of which can be reduced by using solar or wind power-based electrolytic H2 and O2 to replace coal-based H2 and air separation-based O2 at a cost of 10 or 153 Chinese Yuan (CNY)/tCO2eq respectively. We suggest that provincial regions determine whether to use solar or wind power for water electrolysis based on lowest cost options which collectively reduce 53% of the 2030 baseline GHG emissions at a cost of 9 CNY/tCO2eq. Inner Mongolia Shaanxi Ningxia and Xinjiang collectively account for 52% of total GHG mitigation with net cost reductions. These regions are well suited for pilot policies to advance demonstration projects.
Hydrogen Fuel Cell as an Electric Generator: A Case Study for a General Cargo Ship
Feb 2024
Publication
In this study real voyage data and ship specifications of a general cargo ship are employed and it is assumed that diesel generators are replaced with hydrogen proton exchange membrane fuel cells. The effect of the replacement on CO2 NOX SOX and PM emissions and the CII value is calculated. Emission calculations show that there is a significant reduction in emissions when hydrogen fuel cells are used instead of diesel generators on the case ship. By using hydrogen fuel cells there is a 37.4% reduction in CO2 emissions 32.5% in NOX emissions 37.3% in SOX emissions and 37.4% in PM emissions. If hydrogen fuel cells are not used instead of diesel generators the ship will receive an A rating between 2023 and 2026 a B rating in 2027 a C rating in 2028–2029 and an E rating in 2030. On the other hand if hydrogen fuel cells are used the ship will always remain at an A rating between 2023 and 2030. The capital expenditure (CAPEX) and operational expenditure (OPEX) of the fuel cell system are USD 1305720 and USD 2470320 respectively for a 15-year lifetime and the hydrogen fuel expenses are competitive at USD 260981 while marine diesel oil (MDO) fuel expenses are USD 206435.
Multiperiod Modeling and Optimization of Hydrogen-Based Dense Energy Carrier Supply Chains
Feb 2024
Publication
The production of hydrogen-based dense energy carriers (DECs) has been proposed as a combined solution for the storage and dispatch of power generated through intermittent renewables. Frameworks that model and optimize the production storage and dispatch of generated energy are important for data-driven decision making in the energy systems space. The proposed multiperiod framework considers the evolution of technology costs under different levels of promotion through research and targeted policies using the year 2021 as a baseline. Furthermore carbon credits are included as proposed by the 45Q tax amendment for the capture sequestration and utilization of carbon. The implementation of the mixed-integer linear programming (MILP) framework is illustrated through computational case studies to meet set hydrogen demands. The trade-offs between different technology pathways and contributions to system expenditure are elucidated and promising configurations and technology niches are identified. It is found that while carbon credits can subsidize carbon capture utilization and sequestration (CCUS) pathways substantial reductions in the cost of novel processes are needed to compete with extant technology pathways. Further research and policy push can reduce the levelized cost of hydrogen (LCOH) by upwards of 2 USD/kg.
Experimental Study of a Homogeneous Charge Compression Ignition Engine Using Hydrogen at High-Altitude Conditions
Feb 2024
Publication
One of the key factors of the current energy transition is the use of hydrogen (H2 ) as fuel in energy transformation technologies. This fuel has the advantage of being produced from the most primary forms of energy and has the potential to reduce carbon dioxide (CO2 ) emissions. In recent years hydrogen or hydrogen-rich mixtures in internal combustion engines (ICEs) have gained popularity with numerous reports documenting their use in spark ignition (SI) and compression ignition (CI) engines. Homogeneous charge compression ignition (HCCI) engines have the potential for substantial reductions in nitrogen oxides (NOx) and particulate matter (PM) emissions and the use of hydrogen along with this kind of combustion could substantially reduce CO2 emissions. However there have been few reports using hydrogen in HCCI engines with most studies limited to evaluating technical feasibility combustion characteristics engine performance and emissions in laboratory settings at sea level. This paper presents a study of HCCI combustion using hydrogen in a stationary air-cooled Lombardini 25 LD 425-2 modified diesel engine located at 1495 m above sea level. An experimental phase was conducted to determine the intake temperature requirements and equivalence ratios for stable HCCI combustion. These results were compared with previous research carried out at sea level. To the best knowledge of the authors this is the first report on the combustion and operational limits for an HCCI engine fueled with hydrogen under the mentioned specific conditions. Equivalence ratios between 0.21 and 0.28 and intake temperatures between 188 ◦C and 235 ◦C effectively achieved the HCCI combustion. These temperature values were on average 100 ◦C higher than those reported in previous studies. The maximum value for the indicated mean effective pressure (IMEPn) was 1.75 bar and the maximum thermal efficiency (ITEn) was 34.5%. The achieved results are important for the design and implementation of HCCI engines running solely on hydrogen in developing countries located at high altitudes above sea level.
Low-carbon Economic Operation of IES Based on Life Cycle Method and Hydrogen Energy Utilization
Aug 2023
Publication
The Integrated Energy System (IES) that coordinates multiple energy sources can effectively improve energy utilization and is of great significance to achieving energy conservation and emission reduction goals. In this context a low-carbon and economic dispatch model for IES is proposed. Firstly a hydrogen energy-based IES (H2-IES) is constructed to refine the utilization process of hydrogen energy. Secondly the carbon emissions of different energy chains throughout their life cycle are analyzed using the life cycle assessment method (LCA) and the carbon emissions of the entire energy supply and demand chain are considered. Finally a staged carbon trading mechanism is adopted to promote energy conservation and emission reduction. Based on this an IES low-carbon and economic dispatch model is constructed with the optimization goal of minimizing the sum of carbon trading costs energy procurement costs and hydrogen sales revenue while considering network constraints and constraints on key equipment. By analyzing the model under different scenarios the introduction of life cycle assessment staged carbon trading and hydrogen energy utilization is shown to promote low-carbon and economic development of the comprehensive energy system.
A Techno-economic Analysis of Ammonia-fuelled Powertrain Systems for Rail Freight
Apr 2023
Publication
All diesel-only trains in the UK will be removed from services by 2040. High volumetric density rapid refuelling ability and sophisticated experience in infrastructure and logistics make ammonia a perfect hydrogen carrying fuel for rail freight which urgently requires an economically viable solution. This study conducted a novel techno-economic study of ammonia-fuelled fuel cell powertrains to be compared with current diesel engine-based system and emerging direct hydrogen-fuelled fuel cell system. The results demonstrate that hydrogen-fuelled Proton Exchange Membrane Fuel Cells (PEMFCs) and ammonia-fuelled PEMFCs (using an ammonia cracker) are more cost-effective in terms of Levelized Cost of Electricity. The ammonia fuel storage requires 61.5-75 % less space compared to the hydrogen storage. Although the ammonia-fuelled Solid Oxide Fuel Cells (SOFCs) powertrain has the highest electricity generation efficiency (56%) the overall cost requires a major reduction by 70% before it could be considered as an economically viable solution.
Lab-Scale Investigation of the Integrated Backup/Storage System for Wind Turbines Using Alkaline Electrolyzer
Apr 2023
Publication
The depletion of fossil fuel sources has encouraged the authorities to use renewable resources such as wind energy to generate electricity. A backup/storage system can improve the performance of wind turbines due to fluctuations in power demand. The novelty of this study is to utilize a hybrid system for a wind farm using the excess electricity generated by the wind turbines to produce hydrogen in an alkaline electrolyzer (AEL). The hydrogen storage tank stores the produced hydrogen and provides hydrogen to the proton-exchange membrane fuel cell (PEMFC) to generate electricity once the power demand is higher than the electricity generated by the wind turbines. The goal of this study is to use the wind profile of a region in Iran namely the Cohen region to analyze the performance of the suggested integrated system on a micro scale. The output results of this study can be used as a case study for construction in the future based on the exact specification of NTK300 wind turbines. The results indicate that with the minimum power supply of 30 kW from the wind turbines on a lab scale the generated power by the PEMFC will be 1008 W while the maximum generated hydrogen will be 304 mL/h.
An Energy Systems Model of a Large Commercial Liquid Hydrogen Aircraft in a Low-carbon Future
Apr 2023
Publication
Liquid hydrogen (LH2) aircraft have the potential to achieve carbon neutrality. However if the hydrogen is produced using electricity grids that utilise fossil fuel they have a non-zero carbon dioxide (CO2) emission associated with their well-to-wing pathway. To assess the potential of LH2 in aviation decarbonisation an energy systems comparison of large commercial LH2 liquified natural gas (LNG) conventional Jet-A and LH2 dual-fuel aircraft is presented. The performance of each aircraft is compared towards 2050 over which three system changes occur: (1) LH2 aircraft technology develops; (2) both world average and region-specific grid electricity which is used to produce the hydrogen decarbonises; and (3) the International Air Transportation Association (IATA) emissions targets which are used to restrict the passenger-range performance of each aircraft tighten. In 2050 the emissions of all aircraft are thus constrained to 0.063 kg-CO2/p-km relative to 0.110 kg-CO2/p-km for the unconstrained Jet A fuelled Boeing 787-8. It is estimated that in this year an LH2 aircraft powered by fuel cells and sourcing world average electricity can travel 6000 km 20% further than the conventional Jet A aircraft that is also constrained to meet the IATA targets but not as far as the LNG aircraft. At its maximum range the LH2 aircraft carries 84% of the Jet A passenger demand. Analysis using region-specific hydrogen indicates that LH2 aircraft can travel further than LNG aircraft in North America only accounting for 17% of the global demand. 1.59 times the current aviation energy consumption is required if all conventional aircraft are replaced with LH2 designs. Under stricter emissions constraints than those outlined by the IATA LH2 outperforms LNG in Europe and the Americas accounting for 41% of the global demand. Also in these regions the range energy consumption and passenger capacity of LH2 aircraft can be improved upon by combining the advantages of LH2 with LNG in dual-fuel aircraft concepts. The use of LH2 is therefore advantageous within several prominent niches of a future decarbonising aviation system.
Eco-Sustainable Energy Production in Healthcare: Trends and Challenges in Renewable Energy Systems
Oct 2023
Publication
The shift from fossil fuels to renewable energy systems represents a pivotal step toward the realization of a sustainable society. This study aims to analyze representative scientific literature on eco-sustainable energy production in the healthcare sector particularly in hospitals. Given hospitals’ substantial electricity consumption the adoption of renewable energy offers a reliable low-CO2 emission solution. The COVID-19 pandemic has underscored the urgency for energyefficient and environmentally-responsible approaches. This brief review analyzes the development of experimental simulation and optimization projects for sustainable energy production in healthcare facilities. The analysis reveals trends and challenges in renewable energy systems offering valuable insights into the potential of eco-sustainable solutions in the healthcare sector. The findings indicate that hydrogen storage systems are consistently coupled with photovoltaic panels or solar collectors but only 14% of the analyzed studies explore this potential within hospital settings. Hybrid renewable energy systems (HRES) could be used to meet the energy demands of healthcare centers and hospitals. However the integration of HRES in hospitals and medical buildings is understudied.
Review on Ammonia as a Potential Fuel: From Synthesis to Economics
Feb 2021
Publication
Ammonia a molecule that is gaining more interest as a fueling vector has been considered as a candidate to power transport produce energy and support heating applications for decades. However the particular characteristics of the molecule always made it a chemical with low if any benefit once compared to conventional fossil fuels. Still the current need to decarbonize our economy makes the search of new methods crucial to use chemicals such as ammonia that can be produced and employed without incurring in the emission of carbon oxides. Therefore current efforts in this field are leading scientists industries and governments to seriously invest efforts in the development of holistic solutions capable of making ammonia a viable fuel for the transition toward a clean future. On that basis this review has approached the subject gathering inputs from scientists actively working on the topic. The review starts from the importance of ammonia as an energy vector moving through all of the steps in the production distribution utilization safety legal considerations and economic aspects of the use of such a molecule to support the future energy mix. Fundamentals of combustion and practical cases for the recovery of energy of ammonia are also addressed thus providing a complete view of what potentially could become a vector of crucial importance to the mitigation of carbon emissions. Different from other works this review seeks to provide a holistic perspective of ammonia as a chemical that presents benefits and constraints for storing energy from sustainable sources. State-of-the-art knowledge provided by academics actively engaged with the topic at various fronts also enables a clear vision of the progress in each of the branches of ammonia as an energy carrier. Further the fundamental boundaries of the use of the molecule are expanded to real technical issues for all potential technologies capable of using it for energy purposes legal barriers that will be faced to achieve its deployment safety and environmental considerations that impose a critical aspect for acceptance and wellbeing and economic implications for the use of ammonia across all aspects approached for the production and implementation of this chemical as a fueling source. Herein this work sets the principles research practicalities and future views of a transition toward a future where ammonia will be a major energy player.
H2-powered Aviation - Design and Economics of Green LH2 Supply for Airports
Aug 2023
Publication
The economic competitiveness of hydrogen-powered aviation highly depends on the supply costs of green liquid hydrogen to enable true-zero CO2 flying. This study uses non-linear energy system optimization to analyze three main liquid hydrogen (LH2) supply pathways for five locations. Final liquid hydrogen costs at the dispenser supply costs could reach 2.04 USD/kgLH2 in a 2050 base case scenario for locations with strong renewable energy source conditions. This could lead to cost-competitive flying with hydrogen. Reflecting techno-economic uncertainties in two additional scenarios the liquid hydrogen cost span at all five airport locations ranges between 1.37–3.48 USD/kgLH2 if hydrogen import options from larger hydrogen markets are also available. Import setups are of special importance for airports with a weaker renewable energy source situation e.g. selected Central European airports. There on-site supply might not only be too expensive but space requirements for renewable energy sources could be too large for feasible implementation in densely populated regions. Furthermore main costs for liquid hydrogen are caused by renewable energy sources electrolysis systems and liquefaction plants. Seven detailed design rules are derived for optimized energy systems for these and the storage components. This and the cost results should help infrastructure planners and general industry and policy players prioritize research and development needs
Impact of Climate and Geological Storage Potential on Feasibility of Hydrogen Fuels
Apr 2023
Publication
Electrofuels including hydrogen methane and ammonia have been suggested as one pathway in achieving net-zero greenhouse gas energy systems. They can play a role in providing an energy storage and fuel or feedstock to hard-to-abate sectors. In future energy systems their role is often studied in case studies adhering to specific region. In this study we study their role by defining multiple archetypal energy systems which represent approximations of real systems in different regions. Comparing the role of electrofuels across the cost-optimized systems relying only on renewable energy in power generation we found that hydrogen was a significant energy vector in all systems with its annual quantity approaching the classic electricity demand. The role of renewable methane was very limited. Electrofuel storages were needed in all systems and their capacity was the highest in the northern Hemiboreal system. Absence of cavern storage potential did not hamper the significance of electrofuels but increased the role of ammonia and led to average 5.5 % systemic cost increase. Systems where reservoir hydropower was scarce or level of electricity consumption was high needed more fuel storages. The findings of this study can help for better understanding of what kind of storage and generation technologies will be most useful in future carbon-neutral systems in different types of regions.
A Multi-energy Multi-microgrid System Planning Model for Decarbonisation and Decontamination of Isolated Systems
May 2023
Publication
Decarbonising and decontaminating remote regions in the world presents several challenges. Many of these regions feature isolation dispersed demand in large areas and a lack of economic resources that impede the development of robust and sustainable networks. Furthermore isolated systems in the developing world are mostly based on diesel generation for electricity and firewood and liquefied petroleum gas for heating as these options do not require a significant infrastructure cost. In this context we present a stochastic multi-energy multi-microgrid system planning model that integrates electricity heat and hydrogen networks in isolated systems. The model is stochastic to capture uncertainty in renewable generation outputs particularly hydro and wind and thus design a multi-energy system proved secured against such uncertainty. The model also features two distinct constraints to limit the emissions of CO2 (for decarbonisation) and particulate matter (for decontamination) and incorporates firewood as a heating source. Moreover given that the focus is on low-voltage networks we introduce a fully linear AC power flow equations set allowing the planning model to remain tractable. The model is applied to a real-world case study to design a multi-energy multi-microgrid system in an isolated region in Chilean Patagonia. In a case with a zero limit over direct CO2 emissions the total system’s cost increases by 34% with respect to an unconstrained case. In a case with a zero limit over particulate matter emissions the total system’s cost increases by 189%. Finally although an absolute zero limit over both particulate matter and direct CO2 emissions leads to a total system’s cost increase of 650% important benefits in terms of decarbonisation and decontamination can be achieved at marginal cost increments.
Life-Cycle and Applicational Analysis of Hydrogen Production and Powered Inland Marine Vessels
Aug 2023
Publication
Green energy is at the forefront of current policy research and engineering but some of the potential fuels require either a lot of deeper research or a lot of infrastructure before they can be implemented. In the case of hydrogen both are true. This report aims to analyse the potential of hydrogen as a future fuel source by performing a life-cycle assessment. Through this the well-to-tank phase of fuel production and the usage phase of the system have been analysed. Models have also been created for traditional fuel systems to best compare results. The results show that hydrogen has great potential to convert marine transport to operating off green fuels when powered through low-carbon energy sources which could reduce a huge percentage of the international community’s greenhouse gas emissions. Hydrogen produced through wind powered alkaline electrolysis produced emission data 5.25 g of CO2 equivalent per MJ compared to the 210 g per MJ produced by a medium efficiency diesel equivalent system a result 40 times larger. However with current infrastructure in most countries not utilising a great amount of green energy production the effects of hydrogen usage could be more dangerous than current fuel sources owing to the incredible energy requirements of hydrogen production with even grid (UK) powered electrolysis producing an emission level of 284 g per MJ which is an increase against standard diesel systems. From this the research concludes that without global infrastructure change hydrogen will remain as a potential fuel rather than a common one.
How to Connect Energy Islands: Trade-offs Between Hydrogen and Electricity Infrastructure
Apr 2023
Publication
In light of offshore wind expansions in the North and Baltic Seas in Europe further ideas on using offshore space for renewable-based energy generation have evolved. One of the concepts is that of energy islands which entails the placement of energy conversion and storage equipment near offshore wind farms. Offshore placement of electrolysers will cause interdependence between the availability of electricity for hydrogen production and for power transmission to shore. This paper investigates the trade-offs between integrating energy islands via electricity versus hydrogen infrastructure. We set up a combined capacity expansion and electricity dispatch model to assess the role of electrolysers and electricity cables given the availability of renewable energy from the islands. We find that the electricity system benefits more from connecting close-to-shore wind farms via power cables. In turn electrolysis is more valuable for far-away energy islands as it avoids expensive long-distance cable infrastructure. We also find that capacity investment in electrolysers is sensitive to hydrogen prices but less to carbon prices. The onshore network and congestion caused by increased activity close to shore influence the sizing and siting of electrolysers.
Optimal Operation Strategy of PV-Charging-Hydrogenation Composite Energy Station Considering Demand Response
Apr 2023
Publication
Traditional charging stations have a single function which usually does not consider the construction of energy storage facilities and it is difficult to promote the consumption of new energy. With the gradual increase in the number of new energy vehicles (NEVs) to give full play to the complementary advantages of source-load resources and provide safe efficient and economical energy supply services this paper proposes the optimal operation strategy of a PV-charging-hydrogenation composite energy station (CES) that considers demand response (DR). Firstly the operation mode of the CES is analyzed and the CES model including a photovoltaic power generation system fuel cell hydrogen production hydrogen storage hydrogenation and charging is established. The purpose is to provide energy supply services for electric vehicles (EVs) and hydrogen fuel cell vehicles (HFCVs) at the same time. Secondly according to the travel law of EVs and HFCVs the distribution of charging demand and hydrogenation demand at different periods of the day is simulated by the Monte Carlo method. On this basis the following two demand response models are established: charging load demand response based on the price elasticity matrix and interruptible load demand response based on incentives. Finally a multi-objective optimal operation model considering DR is proposed to minimize the comprehensive operating cost and load fluctuation of CES and the maximum–minimum method and analytic hierarchy process (AHP) are used to transform this into a linearly weighted single-objective function which is solved via an improved moth–flame optimization algorithm (IMFO). Through the simulation examples operation results in four different scenarios are obtained. Compared with a situation not considering DR the operation strategy proposed in this paper can reduce the comprehensive operation cost of CES by CNY 1051.5 and reduce the load fluctuation by 17.8% which verifies the effectiveness of the proposed model. In addition the impact of solar radiation and energy recharge demand changes on operations was also studied and the resulting data show that CES operations were more sensitive to energy recharge demand changes.
Advancements in Hydrogen Production, Storage, Distribution and Refuelling for a Sustainable Transport Sector: Hydrogen Fuel Cell Vehicles
Jul 2023
Publication
Hydrogen is considered as a promising fuel in the 21st century due to zero tailpipe CO2 emissions from hydrogen-powered vehicles. The use of hydrogen as fuel in vehicles can play an important role in decarbonising the transport sector and achieving net-zero emissions targets. However there exist several issues related to hydrogen production efficient hydrogen storage system and transport and refuelling infrastructure where the current research is focussing on. This study critically reviews and analyses the recent technological advancements of hydrogen production storage and distribution technologies along with their cost and associated greenhouse gas emissions. This paper also comprehensively discusses the hydrogen refuelling methods identifies issues associated with fast refuelling and explores the control strategies. Additionally it explains various standard protocols in relation to safe and efficient refuelling analyses economic aspects and presents the recent technological advancements related to refuelling infrastructure. This study suggests that the production cost of hydrogen significantly varies from one technology to others. The current hydrogen production cost from fossil sources using the most established technologies were estimated at about $0.8–$3.5/kg H2 depending on the country of production. The underground storage technology exhibited the lowest storage cost followed by compressed hydrogen and liquid hydrogen storage. The levelised cost of the refuelling station was reported to be about $1.5–$8/kg H2 depending on the station's capacity and country. Using portable refuelling stations were identified as a promising option in many countries for small fleet size low-to-medium duty vehicles. Following the current research progresses this paper in the end identifies knowledge gaps and thereby presents future research directions.
An Artificial Neural Network-Based Fault Diagnostics Approach for Hydrogen-Fueled Micro Gas Turbines
Feb 2024
Publication
The utilization of hydrogen fuel in gas turbines brings significant changes to the thermophysical properties of flue gas including higher specific heat capacities and an enhanced steam content. Therefore hydrogen-fueled gas turbines are susceptible to health degradation in the form of steam-induced corrosion and erosion in the hot gas path. In this context the fault diagnosis of hydrogen-fueled gas turbines becomes indispensable. To the authors’ knowledge there is a scarcity of fault diagnosis studies for retrofitted gas turbines considering hydrogen as a potential fuel. The present study however develops an artificial neural network (ANN)-based fault diagnosis model using the MATLAB environment. Prior to the fault detection isolation and identification modules physics-based performance data of a 100 kW micro gas turbine (MGT) were synthesized using the GasTurb tool. An ANN-based classification algorithm showed a 96.2% classification accuracy for the fault detection and isolation. Moreover the feedforward neural network-based regression algorithm showed quite good training testing and validation accuracies in terms of the root mean square error (RMSE). The study revealed that the presence of hydrogen-induced corrosion faults (both as a single corrosion fault or as simultaneous fouling and corrosion) led to false alarms thereby prompting other incorrect faults during the fault detection and isolation modules. Additionally the performance of the fault identification module for the hydrogen fuel scenario was found to be marginally lower than that of the natural gas case due to assumption of small magnitudes of faults arising from hydrogen-induced corrosion.
Progress in Energy Storage Technologies and Methods for Renewable Energy Systems Application
May 2023
Publication
This paper provides a comprehensive review of the research progress current state-ofthe-art and future research directions of energy storage systems. With the widespread adoption of renewable energy sources such as wind and solar power the discourse around energy storage is primarily focused on three main aspects: battery storage technology electricity-to-gas technology for increasing renewable energy consumption and optimal configuration technology. The paper employs a visualization tool (CiteSpace) to analyze the existing works of literature and conducts an in-depth examination of the energy storage research hotspots in areas such as electrochemical energy storage hydrogen storage and optimal system configuration. It presents a detailed overview of common energy storage models and configuration methods. Based on the reviewed articles the future development of energy storage will be more oriented toward the study of power characteristics and frequency characteristics with more focus on the stability effects brought by transient shocks. This review article compiles and assesses various energy storage technologies for reference and future research.
Equivalent Minimum Hydrogen Consumption of Fuzzy Control-Based Fuel Cells: Exploration of Energy Management Strategies for Ships
Feb 2024
Publication
Aiming to solve the problems of insufficient dynamic responses the large loss of energy storage life of a single power cell and the large fluctuation in DC (direct current) bus voltage in fuel cell vessels this study takes a certain type of fuel cell ferry as the research object and proposes an improved equivalent minimum hydrogen consumption energy management strategy based on fuzzy logic control. First a hybrid power system including a fuel cell a lithium–iron–phosphate battery and a supercapacitor is proposed with the simulation of the power system of the modified mother ship. Second a power system simulation model and a double-closed-loop PI (proportion integration) control model are established in MATLAB/Simulink to design the equivalent hydrogen consumption model and fuzzy logic control strategy. The simulation results show that under the premise of meeting the load requirements the control strategy designed in this paper improves the Li-ion battery’s power the Li-ion battery’s SOC (state of charge) the bus voltage stability and the equivalent hydrogen consumption significantly compared with those before optimization which improves the stability and economy of the power system and has certain practical engineering value.
Thermal Design of a System for Mobile Powersupply
Sep 2023
Publication
Ever more stringent emission regulations for vehicles encourage increasing numbers of battery electric vehicles on the roads. A drawback of storing electric energy in a battery is the comparable low energy density low driving range and the higher propensity to deplete the energy storage before reaching the destination especially at low ambient temperatures. When the battery is depleted stranded vehicles can either be towed or recharged with a mobile recharging station. Several technologies of mobile recharging stations already exist however most of them use fossil fuels to recharge battery electric vehicles. The proposed novel zero emission solution for mobile charging is a combined high voltage battery and hydrogen fuel cell charging station. Due to the thermal characteristics of the fuel cell and high voltage battery (which allow only comparable low coolant temperatures) the thermal design for this specific application (available heat exchanger area zero vehicle speed air flow direction) becomes challenging and is addressed in this work. Experimental methods were used to obtain reliable thermal and electric power measurement data of a 30 kW fuel cell system which is used in the Mobile Hydrogen Powersupply. Subsequently simulation methods were applied for the thermal design and optimisation of the coolant circuits and heat exchangers. It is shown that an battery electric vehicle charging power of 22 kW requires a heat exchanger area of 1 m2 of which 60 % is used by the fuel cell heat exchanger and the remainder by the battery heat exchanger to achieve steady state operation at the highest possible ambient temperature of 436 °C. Furthermore the simulation showed that when the charging power of 22 kW is solely provided by the high voltage battery the highest possible ambient temperature is 42 °C. When the charging power is decreased operation up to the maximum ambient temperatures of 45 °C can be achieved. The results of maximum charging power and limiting ambient temperature give insights for further system improvements which are: sizing of fuel cell or battery trailer design and heat exchanger area operation strategy of the system (power split between high voltage battery and fuel cell) as well as possible dynamic operation scenarios.
Techno-Economic Analysis of Cement Decarbonization Techniques: Oxygen Enrichment vs. Hydrogen Fuel
Feb 2024
Publication
The Paris Agreement aims to limit global warming and one of the most polluting sectors is heavy industry where cement production is a significant contributor. This work briefly explores some alternatives recycling reducing clinker content waste heat recovery and carbon capture discussing their advantages and drawbacks. Then it examines the economic viability and benefits of increasing oxygen concentration in the primary burning air from 21 to 27 vol.% which could improve clinker production by 7% and the production of hydrogen through PEM electrolysis to make up 5% of the fuel thermal fraction considering both in a cement plant producing 3000 tons of clinker per day. This analysis used reference values from Secil an international company for cement and building materials to determine the required scale of the oxygen and hydrogen production respectively and calculate the CAPEX of each approach. It is concluded that oxygen enrichment can provide substantial fuel savings for a relatively low cost despite a possible significant increase in NOx emissions. However hydrogen production at this scale is not currently economically viable.
Experimental Activities on a Hydrogen-Fueled Spark-Ignition Engine for Light-Duty Applications
Nov 2023
Publication
The increase in the overall global temperature and its subsequent impact on extreme weather events are the most critical consequences of human activity. In this scenario transportation plays a significant role in greenhouse gas (GHG) emissions which are the main drivers of climate change. The decline of non-renewable energy sources coupled with the aim of reducing GHG emissions from fossil fuels has forced a shift towards a net-zero emissions economy. As an example of this transition the European Union has set 2050 as the target for achieving carbon neutrality. Hydrogen (H2 ) is gaining increasing relevance as one of the most promising carbon-free energy vectors. If produced from renewable sources it facilitates the integration of various alternative energy sources for achieving a carbon-neutral economy. Recently interest in its application to the transportation sector has grown including different power plant concepts such as fuel cells or internal combustion engines. Despite exhibiting significant drawbacks such as low density combustion instabilities and incompatibilities with certain materials hydrogen is destined to become one of the future fuels. In this publication experimental activities are reported that were conducted on a sparkignition engine fueled with hydrogen at different operating points. The primary objective of this research is to gain a better understanding of the thermodynamic processes that control combustion and their effects on engine performance and pollutant emissions. The results show the emission levels performance and combustion characteristics under different conditions of dilution load and injection strategy and timing.
Decarbonization with Induced Technical Change: Exploring the Niche Potential of Hydrogen in Heavy Transportation
Jan 2024
Publication
Fuel cells and electric batteries are competing technologies for the energy transition in heavy transportation. We explore the conditions for the survival of a unique technology in the long term. Learning by doing suggests focusing on a single technology while differentiation and decreasing return to scale (cost convexity) favor diversification. Exogenous technical change also plays a role. The interaction between these factors is analyzed in a general model. It is proved that in absence of convexity and exogenous technical change only one technology is used for the whole transition. We then apply this framework to analyze the competition between fuel-cell electric buses (FCEBs) and battery electric buses (BEB) in the European bus sector. There are both learning by doing and exogenous technical change. The model is calibrated and solved. It is shown that the existence of a niche for FCEBs critically depends on the speed at which cost reductions are achieved. The speed depends both on the size of the niche and the rate of learning by doing for FCEBs. Public policies to decentralize the socially optimal trajectory in terms of taxes (carbon) and subsidies (learning by doing) are derived.
Solar-driven (Photo)electrochemical Devices for Green Hydrogen Production and Storage: Working Principles and Design
Feb 2024
Publication
The large-scale deployment of technologies that enable energy from renewables is essential for a successful transition to a carbon-neutral future. While photovoltaic panels are one of the main technologies commonly used for harvesting energy from the Sun storage of renewable solar energy still presents some challenges and often requires integration with additional devices. It is believed that hydrogen – being a perfect energy carrier – can become one of the broadly utilised storage alternatives that would effectively mitigate the energy supply and demand issues associated with the intermittent nature of renewable energy sources. Current pathways in the development of green technologies indicate the need for more sustainable material utilisation and more efficient device operation. To address this requirement integration of various technologies for renewable energy harvesting conversion and storage in a single device appears as an advantageous option. From the hydrogen economy perspective systems driven by green solar electricity that allow for (photo)electrochemical water splitting would generate hydrogen with the minimal CO2 footprint. If at the same time one of the device electrodes could store the generated gas and release it on demand the utilisation of critical and often costly elements would be reduced with possible gain in more effective device operation. Although conceptually attractive this cross-disciplinary concept has not gained yet enough attention and only limited number of experimental setups have been designed tested and reported. This review presents the first exhaustive overview and critical examination of various laboratory-scale prototype setups that attempt to combine both the hydrogen production and storage processes in a single unit via integration of a metal hydride-based electrode into a photoelectrochemical cell. The architectures of presented configurations enables direct solar energy to hydrogen conversion and its subsequent storage in a single device which – in some cases – can also release the stored (hydrogen) energy on demand. In addition this work explores perspectives and challenges related with the potential upscaling of reviewed solar-to-hydrogen storage systems trying to map and indicate the main future directions of their technological development and optimization. Finally the review also combines information and expertise scattered among various research fields with the aim of stimulating much-needed exchange of knowledge to accelerate the progress in the development and deployment of optimum green hydrogen-based solutions.
H2 URESONIC: Design of a Solar-Hydrogen University Renewable Energy System for a New and Innovative Campus
Feb 2024
Publication
The necessity to move to sustainable energy solutions has inspired an investigation of innovative technologies for satisfying educational institutions’ sustainable energy needs. The possibility of a solar-hydrogen storage system and its integration into university energy management is investigated in this article. The study opens by providing context noting the growing relevance of renewable energy in universities as well as the necessity for effective energy storage systems. The goal is to delve into solar-hydrogen technology outlining its components operating mechanism and benefits over typical storage systems. The chapter on Integration Design examines current university energy infrastructure identifies problems and provides ways for integrating solar-hydrogen systems seamlessly. This integration relies heavily on technological and economic considerations such as a cost-benefit analysis and scalability studies. Case studies include real-world examples performance measurements and significant insights learned from successful implementations. The chapter Future Prospects investigates new trends in solar-hydrogen technology as well as the impact of government legislation providing a forward-looking viewpoint for colleges considering adoption. The report concludes with a summary of significant findings emphasizing the benefits of solar-hydrogen integration and making recommendations for future implementations. The limitation of this research is that it only focuses on design and simulation as a phase of preliminary study.
Environmental Implications and Levelized Cost Analysis of E-fuel Production under Photovoltaic Energy, Direct Air Capture, and Hydrogen
Jan 2024
Publication
The ecological transition in the transport sector is a major challenge to tackle environmental pollution and European legislation will mandate zero-emission new cars from 2035. To reduce the impact of petrol and diesel vehicles much emphasis is being placed on the potential use of synthetic fuels including electrofuels (e-fuels). This research aims to examine a levelised cost (LCO) analysis of e-fuel production where the energy source is renewable. The energy used in the process is expected to come from a photovoltaic plant and the other steps required to produce e-fuel: direct air capture electrolysis and Fischer-Tropsch process. The results showed that the LCOe-fuel in the baseline scenario is around 3.1 €/l and this value is mainly influenced by the energy production component followed by the hydrogen one. Sensitivity scenario and risk analyses are also conducted to evaluate alternative scenarios and it emerges that in 84% of the cases LCOe-fuel ranges between 2.8 €/l and 3.4 €/l. The findings show that the current cost is not competitive with fossil fuels yet the development of e-fuels supports environmental protection. The concept of pragmatic sustainability incentive policies technology development industrial symbiosis economies of scale and learning economies can reduce this cost by supporting the decarbonisation of the transport sector.
Research on the Technical Scheme of Multi-stack Common Rail Fuel Cell Engine Based on the Demand of Commercial Vehicle
Feb 2024
Publication
At present most fuel cell engines are single-stack systems and high-power single-stack systems have bottlenecks in meeting the power requirements of heavy-duty trucks mainly because the increase in the single active area and the excessive number of cells will lead to poor distribution uniformity of water gas and heat in the stack which will cause local attenuation and reduce the performance of the stack. This paper introduces the design concept of internal combustion engine takes three-stack fuel cell engine as an example designs multi-stack fuel cell system scheme and serialized high-voltage scheme. Through Intelligent control technology of independent hydrogen injection based on multi-stack coupling the hydrogen injection inflow of each stack is controlled online according to the real-time anode pressure to achieve accurate fuel injection of a single stack and ensure the consistency between multiple stacks. proves the performance advantage of multi-stack fuel cell engine through theoretical designintelligent control and test verification and focuses on analyzing the key technical problems that may exist in multi-stack consistency. The research results provide a reference for the design of multi-stack fuel cell engines and have important reference value for the powertrain design of long-distance heavy-duty and high-power fuel cell trucks.
Batteries or Hydrogen or Both for Grid Electricity Storage Upon Full Electrification of 145 Countries with Wind-Water-Solar?
Jan 2024
Publication
Grids require electricity storage. Two emerging storage technologies are battery storage (BS) and green hydrogen storage (GHS) (hydrogen produced and compressed with clean-renewable electricity stored then returned to electricity with a fuel cell). An important question is whether GHS alone decreases system cost versus BS alone or BS+GHS. Here energy costs are modeled in 145 countries grouped into 24 regions. Existing conventional hydropower (CH) storage is used along with new BS and/or GHS. A method is developed to treat CH for both baseload and peaking power. In four regions only CH is needed. In five CH+BS is lowest cost. Otherwise CH+BS+GHS is lowest cost. CH+GHS is never lowest cost. A metric helps estimate whether combining GHS with BS reduces cost. In most regions merging (versus separating) grid and non-grid hydrogen infrastructure reduces cost. In sum worldwide grid stability may be possible with CH+BS or CH+BS+GHS. Results are subject to uncertainties.
Hydrogen Fuel Cell Electric Trains: Technologies, Current Status, and Future
Feb 2024
Publication
Trains have been a crucial part of modern transport and their high energy efficiency and low greenhouse gas emissions make them ideal candidates for the future transport system. Transitioning from diesel trains to hydrogen fuel cell electric trains is a promising way to decarbonize rail transport. That’s because the fuel cell electric trains have several advantages over other electric trains such as lower life-cycle emissions and shorter refueling time than battery ones and less requirements for wayside infrastructure than the ones with overhead electric wires. However hydrogen fuel technology still needs to be advanced in areas including hydrogen production storage refueling and on-board energy management. Currently there are several pilot projects of hydrogen fuel cell electric trains across the globe especially in developed countries including one commercialized and permanent route in Germany. The experiences from the pilot projects will promote the technological and economic feasibility of hydrogen fuel in rail transport.
Low Platinum Fuel Cell as Enabler for the Hydrogen Fuel Cell Vehicle
Feb 2024
Publication
In this work the design and modeling of a fuel cell vehicle using low-loading platinum catalysts were investigated. Data from single fuel cells with low Pt-loading cathode catalysts were scaled up to fuel cell stacks and systems implemented in a vehicle and then compared to a commercial fuel cell vehicle. The low-loading Pt systems have shown lower efficiency at high loads compared to the commercial systems suggesting less stable materials. However the analysis showed that the vehicle comprising low-loading Pt catalysts achieves similar or higher efficiency compared to the commercial fuel cell vehicle when being scaled up for the same number of cells. When the systems were scaled up for the same maximum power as the commercial fuel cell vehicle all the low-loading Pt fuel cell systems showed higher efficiencies. In this case more cells are needed but still the amount of Pt is significantly reduced compared to the commercial one. The high-efficiency results can be associated with the vehicle’s power range operation that meets the region where the low-loading Pt fuel cells have high performance. The results suggested a positive direction towards the reduction of Pt in commercial fuel cell vehicles supporting a cost-competitive clean energy transition based on hydrogen.
On the Green Transformation of the Iron and Steel Industry: Market and Competition Aspects of Hydrogen Biomass Options
Feb 2024
Publication
The iron and steel industry is a major emitter of carbon dioxide globally. To reduce their carbon footprint the iron and steel industry pursue different decarbonization strategies including deploying bio-based materials and energy carriers for reduction carburisation and/or energy purposes along their value-chains. In this study two potential roles for biomass were analysed: (a) substituting for fossil fuels in iron-ore pellets induration and (b) carburisation of DRI (direct reduced iron) produced via fully hydrogen-based reduction. The purpose of the study was to analyse the regional demand-driven price and allocative effects of biomass assortments under different biomass demand scenarios for the Swedish iron and steel industry. Economic modelling was used in combination with spatial biomass supply assessments to predict the changes on relevant biomass markets. The results showed that the estimated demand increases for forest biomass will have significant regional price effects. Depending on scenario the biomass demand will increase up to 25 percent causing regional prices to more than doubling. In general the magnitude of the price effects was driven by the volumes and types of biomasses needed in the different scenarios with larger price effects for harvesting residues and industrial by-products compared to those of roundwood. A small price effect of roundwood means that the incentives for forest-owners to increase their harvests and thus also the availability of harvest residues are small. Flexibility in the feedstock sourcing (both regarding quality and geographic origin) will thus be important if forest biomass is to satisfy demands in iron and steel industry.
Study on the Application of a Multi-Energy Complementary Distributed Energy System Integrating Waste Heat and Surplus Electricity for Hydrogen Production
Feb 2024
Publication
To improve the recovery of waste heat and avoid the problem of abandoning wind and solar energy a multi-energy complementary distributed energy system (MECDES) is proposed integrating waste heat and surplus electricity for hydrogen storage. The system comprises a combined cooling heating and power (CCHP) system with a gas engine (GE) solar and wind power generation and miniaturized natural gas hydrogen production equipment (MNGHPE). In this novel system the GE’s waste heat is recycled as water vapor for hydrogen production in the waste heat boiler while surplus electricity from renewable sources powers the MNGHPE. A mathematical model was developed to simulate hydrogen production in three building types: offices hotels and hospitals. Simulation results demonstrate the system’s ability to store waste heat and surplus electricity as hydrogen thereby providing economic benefit energy savings and carbon reduction. Compared with traditional energy supply methods the integrated system achieves maximum energy savings and carbon emission reduction in office buildings with an annual primary energy reduction rate of 49.42–85.10% and an annual carbon emission reduction rate of 34.88–47.00%. The hydrogen production’s profit rate is approximately 70%. If the produced hydrogen is supplied to building through a hydrogen fuel cell the primary energy reduction rate is further decreased by 2.86–3.04% and the carbon emission reduction rate is further decreased by 12.67–14.26%. This research solves the problem of waste heat and surplus energy in MECDESs by the method of hydrogen storage and system integration. The economic benefits energy savings and carbon reduction effects of different building types and different energy allocation scenarios were compared as well as the profitability of hydrogen production and the factors affecting it. This has a positive technical guidance role for the practical application of MECDESs.
A Complete Assessment of the Emission Performance of an SI Engine Fueled with Methanol, Methane and Hydrogen
Feb 2024
Publication
This study explores the potentiality of low/zero carbon fuels such as methanol methane and hydrogen for motor applications to pursue the goal of energy security and environmental sustainability. An experimental investigation was performed on a spark ignition engine equipped with both a port fuel and a direct injection system. Liquid fuels were injected into the intake manifold to benefit from a homogeneous charge formation. Gaseous fuels were injected in direct mode to enhance the efficiency and prevent abnormal combustion. Tests were realized at a fixed indicated mean effective pressure and at three different engine speeds. The experimental results highlighted the reduction of CO and CO2 emissions for the alternative fuels to an extent depending on their properties. Methanol exhibited high THC and low NOx emissions compared to gasoline. Methane and even more so hydrogen allowed for a reduction in THC emissions. With regard to the impact of gaseous fuels on the NOx emissions this was strongly related to the operating conditions. A surprising result concerns the particle emissions that were affected not only by the fuel characteristics and the engine test point but also by the lubricating oil. The oil contribution was particularly evident for hydrogen fuel which showed high particle emissions although they did not contain carbon atoms.
Economic Prospects of Taxis Powered by Hydrogen Fuel Cells in Palestine
Feb 2024
Publication
Recently major problems related to fuel consumption and greenhouse gas (GHG) emissions have arisen in the transportation sector. Therefore developing transportation modes powered by alternative fuels has become one of the main targets for car manufacturers and governments around the world. This study aimed to investigate the economic prospects of using hydrogen fuel cell technology in taxi fleets in Westbank. For this purpose a model that could predict the number of taxis was developed and the expected economic implications of using hydrogen fuel cell technology in taxi fleets were determined based on the expected future fuel consumption and future fuel cost. After analysis of the results it was concluded that a slight annual increase in the number of taxis in Palestine is expected in the future due to the government restrictions on issuing new taxi permits in order to get this sector organized. Furthermore using hydrogen fuel cells in taxi fleets is expected to become more and more feasible over time due to the expected future increase in oil price and the expected significant reduction in hydrogen cost as a result of the new technologies that are expected to be used in the production and handling of hydrogen.
A Systematic Review: The Role of Emerging Carbon Capture and Conversion Rechnologies for Energy Transition to Clean Hydrogen
Feb 2024
Publication
The exploitation of fossil fuels in various sectors such as power and heat generation and the transportation sector has been the primary source of greenhouse gas (GHG) emissions which are the main contributors to global warming. Qatar's oil and gas sector notably contributes to CO2 emissions accounting for half of the total emissions. Globally it is essential to transition into cleaner fossil fuel production to achieve carbon neutrality on a global scale. In this paper we focus on clean hydrogen considering carbon capture to make hydrogen a viable low carbon energy alternative for the transition to clean energy. This paper systematically reviews emerging technologies in carbon capture and conversion (CCC). First the road map stated by the Intergovernmental Panel on Climate Change (IPCC) to reach carbon neutrality is discussed along with pathways to decarbonize the energy sector in Qatar. Next emerging CO2 removal technologies including physical absorption using ionic liquids chemical looping and cryogenics are explored and analyzed regarding their advancement and limitations CO2 purity scalability and prospects. The advantages limitations and efficiency of the CO2 conversion technology to value-added products are grouped into chemical (plasma catalysis electrochemical and photochemical) and biological (photosynthetic and non-photosynthetic). The paper concludes by analyzing pathways to decarbonize the energy sector in Qatar via coupling CCC technologies for low-carbon hydrogen highlighting the challenges and research gaps.
Fuel Cell-based Hybrid Electric Vehicles: An Integrated Review of Current Status, Key Challenges, Recommended Policies, and Future Prospects
Aug 2023
Publication
Battery electric vehicles (BEVs) and fuel cell electric vehicles (FCEVs) whose exhaust pipes emit nothing are examples of zero-emission automobiles. FCEVs should be considered an additional technology that will help battery-powered vehicles to reach the aspirational goal of zero-emissions electric mobility particularly in situations where the customers demand for longer driving ranges and where using batteries would be insufficient due to bulky battery trays and time-consuming recharging. This study stipulates a current evaluation of the status of development and challenges related to (i) research gap to promote fuel-cell based HEVs (ii) key barriers of fuel-cell based HEVs (iii) advancement of electric mobility and their power drive (iv) electrochemistry of fuel cell technology for FCEVs (v) power transformation topologies communication protocols and advanced charging methods (vi) recommendations and future prospects of fuel-cell HEVs and (vii) current research trends of EVs and FCEVs. This article discusses key challenges with fuel cell electric mobility such as low fuel cell performance cold starts problems with hydrogen storage cost-reduction safety concerns and traction systems. The operating characteristics and applications of several fuel-cell technologies are investigated for FCEVs and FCHEVs. An overview of the fuel cell is provided which serves as the primary source of energy for FCHEVs along with comparisons and its electrochemistry. The study of power transformation topologies communication protocols and enhanced charging techniques for FCHEVs has been studied analytically. Recent technology advancements and the prospects for FCHEVs are discussed in order to influence the future vehicle market and to attain the aim of zero emissions.
The ATHENA Framework: Analysis and Design of a Strategic Hydrogen Refuelling Infrastructure
Apr 2023
Publication
With the pressured timescale in determining effective and viable net zero solutions within the transport sector it is important to understand the extent of implementing a new refuelling infrastructure for alternative fuel such as hydrogen. The proposed ATHENA framework entails three components which encapsulates the demand data analysis an optimisation model in determining the minimal cost hydrogen refuelling infrastructure design and an agent-based model simulating the operational system. As a case study the ATHENA framework is applied to Northern England focusing on the design of a hydrogen refuelling infrastructure for heavy goods vehicles. Analysis is performed in calibrating parameters and investigating different scenarios within the optimisation and agent-based simulation models. For this case study the system optimality is limited by the feasible number of tube trailer deliveries per day which suggests an opportunity for alternative delivery methods.
A Newly Proposed Method for Hydrogen Storage in a Metal Hydride Storage Tank Intended for Maritime and Inland Shipping
Aug 2023
Publication
The utilisation of hydrogen in ships has important potential in terms of achieving the decarbonisation of waterway transport which produces approximately 3% of the world’s total emissions. However the utilisation of hydrogen drives in maritime and inland shipping is conditioned by the efficient and safe storage of hydrogen as an energy carrier on ship decks. Regardless of the type the constructional design and the purpose of the aforesaid vessels the preferred method for hydrogen storage on ships is currently high-pressure storage with an operating pressure of the fuel storage tanks amounting to tens of MPa. Alternative methods for hydrogen storage include storing the hydrogen in its liquid form or in hydrides as adsorbed hydrogen and reformed fuels. In the present article a method for hydrogen storage in metal hydrides is discussed particularly in a certified low-pressure metal hydride storage tank—the MNTZV-159. The article also analyses the 2D heat conduction in a transversal cross-section of the MNTZV-159 storage tank for the purpose of creating a final design of the shape of a heat exchanger (intensifier) that will help to shorten the total time of hydrogen absorption into the alloy i.e. the filling process. Based on the performed 3D calculations for heat conduction the optimisation and implementation of the intensifier into the internal volume of a metal hydride alloy will increase the performance efficiency of the shell heat exchanger of the MNTZV-159 storage tank. The optimised design increased the cooling power by 46.1% which shortened the refuelling time by 41% to 2351 s. During that time the cooling system which comprised the newly designed internal heat transfer intensifier was capable of eliminating the total heat from the surface of the storage tank thus preventing a pressure increase above the allowable value of 30 bar.
Design of Gravimetric Primary Standards for Field-testing of Hydrogen Refuelling Stations
Apr 2020
Publication
The Federal Institute of Metrology METAS developed a Hydrogen Field Test Standard (HFTS) that can be used for field verification and calibration of hydrogen refuelling stations. The testing method is based on the gravimetric principle. The experimental design of the HFTS as well as the description of the method are presented here.
On the Design and Optimization of Distributed Energy Resources for Sustainable Grid-integrated Microgrid in Ethiopia
Apr 2023
Publication
This paper presents a study that focuses on alleviating the impacts of grid outages in Ethiopia. To deal with grid outages most industrial customers utilize backup diesel generators (DG) which are environmentally unfriendly and economically not viable. Grid integration of hybrid renewable energy systems (HRES) might be a possible solution to enhance grid reliability and reduce environmental and economic impacts of utilizing DG. In this study an optimization of grid integrated HRES is carried out for different dispatch and control strategies. The optimal power supply option is determined by performing comparative analysis of the different configurations of grid integrated HRES. The result of the study shows that grid integrated HRES consisting of photovoltaic and wind turbine as renewable energy sources and battery and hydrogen as hybrid energy storage systems is found to be the optimal system to supply the load demand. From the hydrogen produced on-site the FC generator and FCEVs consume 143 620 kg/yr of hydrogen which is equivalent to 394 955 kg/yr gasoline fuel consumption. This corresponds to saving 1 184 865 kg/yr of CO2 emissions and 605 703 $/yr revenue. Besides this system yields 547 035.4 $/yr revenue by injecting excess electricity to the grid. The study clearly shows the economic and environmental viability of this new technology for implementation.
Recent Advances in Sustainable and Safe Marine Engine Operation with Alternative Fuels
Nov 2022
Publication
Pursuing net-zero emission operations in the shipping industry are quintessential for this sector to mitigate the environmental impact caused by hydrocarbon fuel combustion. Significant contributions to this are expected from the substitution of conventional marine fuels by alternative emission-free fuels with lower emission footprints. This study aims to conduct a comprehensive literature review for delineating the main characteristics of the considered alternative fuels specifically focusing on hydrogen methanol and ammonia which have recently attracted attention from both industry and academia. This study comparatively assesses the potential of using these fuels in marine engines and their subsequent performance characteristics as well as the associated environmental benefits. In addition the required storage conditions space as well as the associated costs are reviewed. Special attention is given to the safety characteristics and requirements for each alternative fuel. The results of this study demonstrate that the environmental benefits gained from alternative fuel use are pronounced only when renewable energy is considerably exploited for their production whereas the feasibility of each fuel depends on the vessel type used and pertinent storage constraints. Hydrogen ammonia and methanol are considered best-fit solutions for small scale shipping requiring minimal on-board storage. In addition the need for comparative assessments between diesel and alternative fuels is highlighted and sheds light on marine engines’ operational characteristics. Moreover using combinations of alternative and diesel fuels is identified as a direction towards decarbonisation of the maritime sector; intensifying the need for optimisation studies on marine engine design and operation. This study concludes with recommendations for future research directions thus contributing to fuel research concepts that can facilitate the shipboard use of alternative fuels.
Performance Analysis of Hybrid Solar/H2/Battery Renewable Energy System for Residential Electrification
Mar 2019
Publication
Due to the privileged location of Ecuador in terms of solar radiation the analysis and use of renewable energy system (RES) using solar energy has been of great interest during the last years. At the same time the supply support of RES in terms of direct current (DC) can be faced by using fuel cell (FC) systems which can give to the systems fully autonomy from fossil fuels. The aim of this paper is to propose the design of a hybrid photovoltaic-fuel cell-battery (PV-FC-B) system to supply the required electrical energy for residential use in the city of Guayaquil. The feasibility analysis constitutive elements of the system and adjusted variables are computed and presented using a computational tool. The results evidence that this system is not economically viable since the cost of energy (COE) in Ecuador is low compared to the COE of the proposed system. However a more detailed analysis considering the inherent benefits of no emission of pollutant gases is required to have a complete outlook.
Current Status and Economic Analysis of Green Hydrogen Energy Industry Chain
Feb 2024
Publication
Under the background of the power system profoundly reforming hydrogen energy from renewable energy as an important carrier for constructing a clean low-carbon safe and efficient energy system is a necessary way to realize the objectives of carbon peaking and carbon neutrality. As a strategic energy source hydrogen plays a significant role in accelerating the clean energy transition and promoting renewable energy. However the cost and technology are the two main constraints to green hydrogen energy development. Herein the technological development status and economy of the whole industrial chain for green hydrogen energy “production-storage-transportation-use” are discussed and reviewed. After analysis the electricity price and equipment cost are key factors to limiting the development of alkaline and proton exchange membrane hydrogen production technology; the quantity scale and distance of transportation are key to controlling the costs of hydrogen storage and transportation. The application of hydrogen energy is mainly concentrated in the traditional industries. With the gradual upgrading and progress of the top-level design and technology the application of hydrogen energy mainly including traffic transportation industrial engineering energy storage power to gas and microgrid will show a diversified development trend. And the bottleneck problems and development trends of the hydrogen energy industry chain are also summarized and viewed.
Thermodynamic Evaluation and Carbon Footprint Analysis of the Application of Hydrogen-Based Energy-Storage Systems in Residential Buildings
Sep 2016
Publication
This study represents a thermodynamic evaluation and carbon footprint analysis of the application of hydrogen based energy storage systems in residential buildings. In the system model buildings are equipped with photovoltaic (PV) modules and a hydrogen storage system to conserve excess PV electricity from times with high solar irradiation to times with low solar irradiation. Short-term storages enable a degree of self-sufficiency of approximately 60% for a single-family house (SFH) [multifamily house (MFH): 38%]. Emissions can be reduced by 40% (SFH) (MFH: 30%) compared to households without PV modules. These results are almost independent of the applied storage technology. For seasonal storage the degree of self-sufficiency ranges between 57 and 83% (SFH). The emission reductions highly depend on the storage technology as emissions caused by manufacturing the storage dominate the emission balance. Compressed gas or liquid organic hydrogen carriers are the best options enabling emission reductions of 40%.
The Heat Transfer Potential of Compressor Vanes on a Hydrogen Fueled Turbofan Engine
Sep 2023
Publication
Hydrogen is a promising fuel for future aviation due to its CO2-free combustion. In addition its excellent cooling properties as it is heated from cryogenic conditions to the appropriate combustion temperatures provides a multitude of opportunities. This paper investigates the heat transfer potential of stator surfaces in a modern high-speed low-pressure compressor by incorporating cooling channels within the stator vane surfaces where hydrogen is allowed to flow and cool the engine core air. Computational Fluid Dynamics simulations were carried out to assess the aerothermal performance of this cooled compressor and were compared to heat transfer correlations. A core air temperature drop of 9.5 K was observed for this cooling channel design while being relatively insensitive to the thermal conductivity of the vane and cooling channel wall thickness. The thermal resistance was dominated by the air-side convective heat transfer and more surface area on the air-side would therefore be required in order to increase overall heat flow. While good agreement with established heat transfer correlations was found for both turbulent and transitional flow the correlation for the transitional case yielded decent accuracy only as long as the flow remains attached and while transition was dominated by the bypass mode. A system level analysis indicated a limited but favorable impact at engine performance level amounting to a specific fuel consumption improvement of up to 0.8% in cruise and an estimated reduction of 3.6% in cruise NOx. The results clearly show that although it is possible to achieve high heat transfer rate per unit area in compressor vanes the impact on cycle performance is constrained by the limited available wetted area in the low-pressure compressor.
Experimental Investigation on Knock Characteristics from Pre-Chamber Gas Engine Fueled by Hydrogen
Feb 2024
Publication
Hydrogen-fueled engines require large values of the excess air ratio in order to achieve high thermal efficiency. A low value of this coefficient promotes knocking combustion. This paper analyzes the conditions for the occurrence of knocking combustion in an engine with a turbulent jet ignition (TJI) system with a passive pre-chamber. A single-cylinder engine equipped with a TJI system was running with an air-to-fuel equivalence ratio λ in the range of 1.25–2.00 and the center of combustion (CoC) was regulated in the range of 2–14 deg aTDC (top dead center). Such process conditions made it possible to fully analyze the ascension of knock combustion until its disappearance with the increase in lambda and CoC. Measures of knock in the form of maximum amplitude pressure oscillation (MAPO) and integral modulus of pressure oscillation (IMPO) were used. The absolute values of these indices were pointed out which can provide the basis for the definition of knock combustion. Based on our own work the MAPO index > 1 bar was defined determining the occurrence of knocking (without indicating its quality). In addition taking into account MAPO it was concluded that IMPO > 0.13 bar·deg is the quantity responsible for knocking combustion.
Emission Reduction and Cost-benefit Analysis of the Use of Ammonia and Green Hydrogen as Fuel for Marine Applications
Dec 2023
Publication
Increasingly stringent emission standards have led shippers and port operators to consider alternative energy sources which can reduce emissions while minimizing capital investment. It is essential to understand whether there is a certain economic investment gap for alternative energy. The present work mainly focuses on the simulation study of ships using ammonia and hydrogen fuels arriving at Guangzhou Port to investigate the emission advantages and cost-benefit analysis of ammonia and hydrogen as alternative fuels. By collecting actual data and fuel consumption emissions of ships arriving at Guangzhou Port the present study calculated the pollutant emissions and cost of ammonia and hydrogen fuels substitution. As expected it is shown that with the increase of NH3 in fuel mixed fuels will effectively reduce CO and CO2 emissions. Compared to conventional fuel the injection of NH3 increases the NOx emission. However the cost savings of ammonia fuel for CO2 SOx and PM10 reduction are higher than that for NOx. In terms of pollutants ammonia is less expensive than conventional fuels when applied to the Guangzhou Port. However the cost of fuel supply is still higher than conventional energy as ammonia has not yet formed a complete fuel supply and storage system for ships. On the other hand hydrogen is quite expensive to store and transport resulting in higher overall costs than ammonia and conventional fuels even if no pollutants are produced. At present conventional fuels still have advantage in terms of cost. With the promotion of ammonia fuel technology and application the cost of supply will be reduced. It is predicted that by 2035 ammonia will not only have emission reduction benefits but also will have a lower overall economic cost than conventional fuels. Hydrogen energy will need longer development and technological breakthroughs due to the limitation of storage conditions.
Techno-Economic Analysis of a Hydrogen-Based Power Supply Backup System for Tertiary Sector Buildings: A Case Study in Greece
May 2023
Publication
In view of the European Union’s strategy on hydrogen for decarbonization and buildings’ decarbonization targets the use of hydrogen in buildings is expected in the future. Backup power in buildings is usually provided with diesel generators (DGs). In this study the use of a hydrogen fuel cell (HFC) power supply backup system is studied. Its operation is compared to a DG and a techno-economic analysis of the latter’s replacement with an HFC is conducted by calculating relevant key performance indicators (KPIs). The developed approach is presented in a case study on a school building in Greece. Based on the school’s electricity loads which are calculated with a dynamic energy simulation and power shortages scenarios the backup system’s characteristics are defined and the relevant KPIs are calculated. It was found that the HFC system can reduce the annual CO2 emissions by up to 400 kg and has a lower annual operation cost than a DG. However due to its high investment cost its levelized cost of electricity is higher and the replacement of an existing DG is unviable in the current market situation. The techno-economic study reveals that subsidies of around 58–89% are required to foster the deployment of HFC backup systems in buildings.
Power Sector Effects of Green Hydrogen Production in Germany
Aug 2023
Publication
The use of green hydrogen can support the decarbonization of sectors which are difficult to electrify such as industry or heavy transport. Yet the wider power sector effects of providing green hydrogen are not well understood so far. We use an open-source electricity sector model to investigate potential power sector interactions of three alternative supply chains for green hydrogen in Germany in the year 2030. We distinguish between model settings in which Germany is modeled as an electric island versus embedded in an interconnected system with its neighboring countries as well as settings with and without technology-specific capacity bounds on wind energy. The findings suggest that large-scale hydrogen storage can provide valuable flexibility to the power system in settings with high renewable energy shares. These benefits are more pronounced in the absence of flexibility from geographical balancing. We further find that the effects of green hydrogen production on the optimal generation portfolio strongly depend on the model assumptions regarding capacity expansion potentials. We also identify a potential distributional effect of green hydrogen production at the expense of other electricity consumers of which policy makers should be aware.
Progress and Prospect of the Novel Integrated SOFC-ICE Hybrid Power System: System Design, Mass and Heat Integration, System Optimization and Techno-economic Analysis
Jan 2023
Publication
This paper presents a review of system design and analysis control strategy optimization and heat and mass integration of integrated solid oxide fuel cell (SOFC) and reciprocating internal combustion engine (ICE) system. Facing the future power-fuel-power path both SOFC and ICE can adapt to a variety of fuels which is one evidence that ICE is amenable to integration with SOFC while SOFC is more efficient cleaner and quieter than ICE. Different system topologies are classified whose dynamic performances are also analyzed. In addition the heat and mass integration of system is discussed. Moreover the combustion modes of ICE which can be applied to steady combustion high efficiency and low emissions are analyzed and compared. Meanwhile the potential and methods of system waste heat recovery are discussed. The exergy analysis energy density and techno-economy are discussed. Finally the results are discussed in the last section with the final conclusion that SOFC-ICE systems are very suitable for long-distance transportation such as maritime and aviation which can also solve problems of the carbon and pollutant emissions with the background of engine cannot be replaced in maritime while the system can adapt a variety of alternative fuels.
Technology Roadmap for Hydrogen-fuelled Transportation in the UK
Apr 2023
Publication
Transportation is the sector responsible for the largest greenhouse gas emission in the UK. To mitigate its impact on the environment and move towards net-zero emissions by 2050 hydrogen-fuelled transportation has been explored through research and development as well as trials. This article presents an overview of relevant technologies and issues that challenge the supply use and marketability of hydrogen for transportation application in the UK covering on-road aviation maritime and rail transportation modes. The current development statutes of the different transportation modes were reviewed and compared highlighting similarities and differences in fuel cells internal combustion engines storage technologies supply chains and refuelling characteristics. In addition common and specific future research needs in the short to long term for the different transportation modes were suggested. The findings showed the potential of using hydrogen in all transportation modes although each sector faces different challenges and requires future improvements in performance and cost development of innovative designs refuelling stations standards and codes regulations and policies to support the advancement of the use of hydrogen.
The Role of Hydrogen for the Defossilization of the German Chemical Industry
Apr 2023
Publication
Within the European Green Deal the European industry is summoned to transform towards a green and circular economy to reduce CO2-emissions and reach climate goals. Special focus is on the chemical industry to boost recycling processes for plastics exploit resource efficiency potentials and switch to a completely renewable feedstock (defossilization). Despite common understanding that drastic changes have to take place it is yet unknown how the industrial transformation should be accomplished. This work explains how a cost-optimal defossilization of the chemical industry in the context of national greenhouse gas (GHG) mitigation strategies look like. The central part of this investigation is based on a national energy system model to optimize the future energy system design of Germany as a case study for a highly industrialized country. A replacement of fossil-based feedstocks by renewable feedstocks leads to a significant increase in hydrogen demand by þ40% compared to a reference scenario. The resulting demand of hydrogen-based energy carriers including the demand for renewable raw materials must be produced domestically or imported. This leads to cumulative additional costs of the transformation that are 32% higher than those of a reference scenario without defossilization of the industry. Fischer-Tropsch synthesis and the methanol-to-olefins route can be identified as key technologies for the defossilization of the chemical industry.
A Review on Biohydrogen Sources, Production Routes, and Its Application as a Fuel Cell
Aug 2023
Publication
More than 80% of the energy from fossil fuels is utilized in homes and industries. Increased use of fossil fuels not only depletes them but also contributes to global warming. By 2050 the usage of fossil fuels will be approximately lower than 80% than it is today. There is no yearly variation in the amount of CO2 in the atmosphere due to soil and land plants. Therefore an alternative source of energy is required to overcome these problems. Biohydrogen is considered to be a renewable source of energy which is useful for electricity generation rather than relying on harmful fossil fuels. Hydrogen can be produced from a variety of sources and technologies and has numerous applications including electricity generation being a clean energy carrier and as an alternative fuel. In this review a detailed elaboration about different kinds of sources involved in biohydrogen production various biohydrogen production routes and their applications in electricity generation is provided.
Fast Sizing Methodology and Assessment of Energy Storage Configuration on the Flight Time of a Multirotor Aerial Vehicle
Apr 2023
Publication
Urban air mobility (UAM) defined as safe and efficient air traffic operations in a metropolitan area for manned aircraft and unmanned aircraft systems is being researched and developed by industry academia and government. This kind of mobility offers an opportunity to construct a green and sustainable sub-sector building upon the lessons learned over decades by aviation. Thanks to their non-polluting operation and simple air traffic management electric vertical take-off and landing (eVTOL) aircraft technologies are currently being developed and experimented with for this purpose. However to successfully complete the certification and commercialization stage several challenges need to be overcome particularly in terms of performance such as flight time and endurance and reliability. In this paper a fast methodology for sizing and selecting the propulsion chain components of an eVTOL multirotor aerial vehicle was developed and validated on a reduced-scale prototype of an electric multirotor vehicle with a GTOW of 15 kg. This methodology is associated with a comparative study of energy storage system configurations in order to assess their effect on the flight time of the aerial vehicle. First the optimal pair motor/propeller was selected using a global nonlinear optimization in order to maximize the specific efficiency of these components. Second five energy storage technologies were sized in order to evaluate their influence on the aerial vehicle flight time. Finally based on this sizing process the optimized propulsion chain gross take-off weight (GTOW) was evaluated for each energy storage configuration using regression-based methods based on propulsion chain supplier data.
Assessment of Hydrogen Gas Turbine-fuel Cell Powerplant for Rotorcraft
Jul 2023
Publication
Conventional turboshaft engines are high power density movers suffering from low efficiency at part power operation and producing significant emissions. This paper presents a design exploration and feasibility assessment of a hybrid hydrogen-fueled powerplant for Urban Air Mobility (UAM) rotorcraft. A multi-disciplinary approach is devised comprising models for rotorcraft performance tank and subsystems sizing and engine performance. The respective trade-offs between payload-range and mission level performance are quantified for kerosene-fueled and hybrid hydrogen tilt-rotor variants. The effects of gas turbine scaling and fuel cell pressurization are evaluated for different hybridization degrees. Gas turbine scaling with hybridization (towards the fuel cell) results in up to 21% benefit in energy consumption relative to the non-scaled case with the benefits being more pronounced at high hybridization degrees. Pressurizing the fuel cell has shown significant potential as cell efficiency can increase up to 10% when pressurized to 6 bar which translates to a 6% increase in overall efficiency. The results indicate that current fuel cells (1 kW/kg) combined with current hydrogen tank technology severely limit the payload range capability of the tilt-rotor. However for advanced fuel cell technology (2.5 kW/kg) and low ranges hybrid powerplant show the potential to reduce energy consumption and reduce emissions footprint.
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