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Measuring and Modelling Unsteady Radiation of Hydrogen Combustion
Sep 2005
Publication
Burning hydrogen emits thermal radiation in UV NIR and IR spectral range. Especially in the case of large cloud explosion the risk of heat radiation is commonly underestimated due to the non-visible flame of hydrogen-air combustion. In the case of a real explosion accident organic substances or inert dust might be entrained from outer sources to produce soot or heated solids to substantially increase the heat release by continuum radiation. To inves Read More
Reducing Emissions in Scotland – 2016 Progress Report
Sep 2016
Publication
This is the Committee’s fifth report on Scotland’s progress towards meeting emission reduction targets as requested by Scottish Ministers under the Climate Change (Scotland) Act 2009.The Scottish Act sets a long-term target to reduce emissions of greenhouse gases (GHGs) by at least 80% in 2050 relative to 1990 with an interim target to reduce emissions by 42% in 2020. Secondary legislation passed in October 2010 and October 2011 also set a series Read More
Hydrogen in Aluminium-Coated Steels Exposed to Synthetic Seawater
Jul 2020
Publication
Thermally sprayed aluminium (TSA) coatings provide protection to offshore steel structures without the use of external cathodic protection (CP) systems. These coatings provide sacrificial protection in the same way as a galvanic anode and thus hydrogen embrittlement (HE) becomes a major concern with the use of high strength steels. The effect of TSA on the HE of steel seems to remain largely unknown. Further the location of hydrogen in TSA-coated Read More
Hydrogen – Analysis
Jun 2020
Publication
Hydrogen technologies maintained strong momentum in 2019 awakening keen interest among policy makers. It was a record year for electrolysis capacity becoming operational and several significant announcements were made for upcoming years. The fuel cell electric vehicle market almost doubled owing to outstanding expansion in China Japan and Korea. However low-carbon production capacity remained relatively constant and is still off track with th Read More
Towards Hydrogen Safety Education and Training
Sep 2005
Publication
The onset and further development of the hydrogen economy are known to be constrained by safety barriers as well as by the level of public acceptance of new applications. Educational and training programmes in hydrogen safety which are currently absent in Europe are considered to be a key instrument in lifting these limitations and to ensure the safe introduction of hydrogen as an energy carrier. Therefore the European Network of Excellence ‘Safe Read More
The Techno-economics Potential of Hydrogen Interconnectors for Electrical Energy Transmission and Storage
Dec 2021
Publication
This research introduces a ‘Hydrogen Interconnector System’ (HIS) as a novel method 7 for transporting electrical energy over long distances. The system takes electricity from 8 stranded renewable energy assets converts it to hydrogen in an electrolyser plant transports 9 hydrogen to the demand centre via pipeline where it is reconverted to electricity in either a 10 gas turbine or fuel cell plant. This paper evaluates the competitiveness of the technolo Read More
Pathways to Net-Zero: Decarbonising the Gas Networks in Great Britain
Oct 2019
Publication
Natural gas plays a central role in the UK energy system today but it is also a significant source of greenhouse gas (GHG) emissions. The UK committed in 2008 to reduce GHG emissions by at least 80% compared to 1990 levels by 2050. In June 2019 a more ambitious target was adopted into law and the UK became the first major economy to commit to “net-zero” emissions by 2050. In this context the Energy Networks Association (ENA) commissioned Read More
Analysis Methodology for Hydrogen Behaviour in Accident Scenarios
Sep 2005
Publication
Hydrogen is not more dangerous than current fossil energy carriers but it behaves differently. Therefore hydrogen specific analyses and countermeasures will be needed to support the development of safe hydrogen technologies. A systematic step-by-step procedure for the mechanistic analysis of hydrogen behaviour and mitigation in accidents is presented. The procedure can be subdivided into four main parts:1) 3D modelling of the H2-air mixture ge Read More
Hybrid Water Electrolysis: A New Sustainable Avenue for Energy-Saving Hydrogen Production
Oct 2021
Publication
Developing renewable energy-driven water splitting for sustainable hydrogen production plays a key role in achieving the carbon neutrality goal. Nevertheless the efficiency of traditional pure water electrolysis is severely hampered by the anodic oxygen evolution reaction (OER) due to its sluggish kinetics. In this context replacing OER with thermodynamically more favorable oxidation reactions to produce hydrogen via hybrid water electrolysis becomes an Read More
Quantitative Evaluations of Hydrogen Diffusivity in V-X (X = Cr, Al, Pd) Alloy Membranes Based on Hydrogen Chemical Potential
Jan 2021
Publication
Vanadium (V) has higher hydrogen permeability than Pd-based alloy membranes but exhibits poor resistance to hydrogen-induced embrittlement. The alloy elements are added to reduce hydrogen solubility and prevent hydrogen-induced embrittlement. To enhance hydrogen permeability the alloy elements which improve hydrogen diffusivity in V are more suitable. In the present study hydrogen diffusivity in V-Cr V-Al and V-Pd alloy membranes was investigat Read More
Theoretical Insights into the Hydrogen Evolution Reaction on the Ni3N Electrocatalyst
Jun 2021
Publication
Ni-based catalysts are attractive alternatives to noble metal electrocatalysts for the hydrogen evolution reaction (HER). Herein we present a dispersion-corrected density functional theory (DFT-D3) insight into HER activity on the (111) (110) (001) and (100) surfaces of metallic nickel nitride (Ni3N). A combination of water and hydrogen adsorption was used to model the electrode interactions within the water splitting cell. Surface energies were Read More
Effect of Hydrogen on the Deformation Behavior and Localization of Plastic Deformation of the Ultrafine-Grained Zr–1Nb Alloy
Oct 2020
Publication
In this paper comparison studies of the hydrogen effect on the structural and phase state deformation behavior and mechanical properties of the fine- (average grain size 4 µm) and ultrafine-grained (average element size 0.3 and 0.4 µm) Zr–1wt.%Nb (hereinafter Zr–1Nb) alloy under tension at temperatures in the range of 293–873 K were conducted. The formation of an ultrafine-grained structure is established to increase the strength characteristics Read More
PRD Hydrogen Release and Dispersion, a Comparison of CFD Results Obtained from Using Ideal and Real Gas Law Properties.
Sep 2005
Publication
In this paper CFD techniques were applied to the simulations of hydrogen release from a 400-bar tank to ambient through a Pressure Relieve Device (PRD) 6 mm (¼”) opening. The numerical simulations using the TOPAZ software developed by Sandia National Laboratory addressed the changes of pressure density and flow rate variations at the leak orifice during release while the PHOENICS software package predicted extents of various hydrogen concentrati Read More
Hydrogen Embrittlement of Medium Mn Steels
Feb 2021
Publication
Recent research efforts to develop advanced–/ultrahigh–strength medium-Mn steels have led to the development of a variety of alloying concepts thermo-mechanical processing routes and microstructural variants for these steel grades. However certain grades of advanced–/ultrahigh–strength steels (A/UHSS) are known to be highly susceptible to hydrogen embrittlement due to their high strength levels. Hydrogen embrittlement characteristics of mediu Read More
Dynamic modelling of a direct internal reforming solid oxide fuel cell stack based on single cell experiments
May 2018
Publication
Direct internal reforming enables optimal heat integration and reduced complexity in solid oxide fuel cell (SOFC) systems but thermal stresses induced by the increased temperature gradients may inflict damage to the stack. Therefore the development of adequate control strategies requires models that can accurately predict the temperature profiles in the stack. A 1D dynamic modelling platform is developed in this study and used to simulate SOFCs i Read More
Study on the Explosion of the Hydrogen Fuel Tank of Fuel Cell Electric Vehicles in Semi-Enclosed Spaces
Dec 2022
Publication
The rise in hydrogen fuel cell electric vehicles (FCEVs) is expected to pose a variety of hazards on the road. Vehicles using hydrogen could cause significant damage owing to hydrogen vapor cloud explosions jet fires caused by leakage or hydrogen tank explosions. This risk is expected to further increase in semi-enclosed spaces such as underground parking lots and road tunnels. Therefore it is necessary to study the fire safety of hydrogen vehicles in semi Read More
Effects of CO2 sequestration on lipid and biomass productivity in microalgal biomass production
Mar 2017
Publication
The study is focused on the technology and manipulation of production strategies for the cultivation of biomass from four strains of microalgae. Species of microalgae studied are: Chlorella vulgaris Dunaliella Scenedesmus quadricauda and Synechococcus spp. The effects of the rate and amount of CO2 removal from the atmosphere and sequestration with dissolved oxygen on lipid production from accumulated biomass were studied. Also the rate of seque Read More
High-stability, High-capacity Oxygen Carriers: Iron Oxide-perovskite Composite Materials for Hydrogen Production by Chemical Looping
Jun 2015
Publication
Iron oxide has been widely used as an oxygen carrier material (OCM) for hydrogen production by chemical looping due to its favourable thermodynamic properties. In spite of this iron oxide loses much of its activity after redox cycling mainly due to sintering and agglomeration. Perovskites such as La0.7Sr0.3FeO3-d (LSF731) have been suggested as potential candidate OCMs for hydrogen production due to their excellent oxygen transport pr Read More
Electrochemical and Mechanical Stability of Catalyst Layers in Anion Exchange Membrane Water Electrolysis
Dec 2021
Publication
Anion exchange membrane (AEM) water electrolysis is considered a promising solution to future cost reduction of electrochemically produced hydrogen. We present an AEM water electrolyzer with CuCoOx as the anode catalyst and Aemion as membrane and electrode binder. Full cell experiments in pure water and 0.1 M KOH revealed that the optimum binder content depended on the type of electrolyte employed. Online dissolution measurements sugge Read More
Hydrogen Fuelling Station, CEP-Berlin – Safety Risk Assessment and Authority Approval Experience and Lessons Learned
Sep 2005
Publication
The CEP (Clean Energy Partnership) – Berlin is one of the most diversified hydrogen demonstration projects at present. The first hydrogen fuelling station serving 16 cars is fully integrated in an ordinary highly frequented Aral service station centrally located at Messedamm in Berlin. Hydro has supplied and is the owner of the electrolyser with ancillary systems. This unit produces gaseous hydrogen at 12 bar with use of renewable energy presently servin Read More
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