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A Detailed Parametric Analysis of a Solar-Powered Cogeneration System for Electricity and Hydrogen Production
Dec 2022
Publication
Hydrogen has received increased attention in the last decades as a green energy carrier and a promising future fuel. The integration of hydrogen as well as the development of cogeneration plants makes the energy sector more eco-friendly and sustainable. The aim of this paper is the investigation of a solar-fed cogeneration system that can produce power and compressed green hydrogen. The examined unit contains a parabolic trough collector solar field a thermal energy storage tank an organic Rankine cycle and a proton exchange membrane water electrolyzer. The installation also includes a hydrogen storage tank and a hydrogen compressor. The unit is analyzed parametrically in terms of thermodynamic performance and economic viability in steady-state conditions with a developed and accurate model. Taking into account the final results the overall energy efficiency is calculated at 14.03% the exergy efficiency at 14.94% and the hydrogen production rate at 0.205 kg/h. Finally the payback period and the net present value are determined at 9 years and 122 k€ respectively.
Enhancement of Microgrid Frequency Stability Based on the Combined Power-to-Hydrogen-to-Power Technology under High Penetration Renewable Units
Apr 2023
Publication
Recently with the large-scale integration of renewable energy sources into microgrid (µGs) power electronics distributed energy systems have gained popularity. However low inertia reduces system frequency stability and anti-disturbance capabilities exposing power quality to intermittency and uncertainty in photovoltaics or wind turbines. To ensure system stability the virtual inertia control (VIC) is presented. This paper proposes two solutions to overcome the low inertia problem and the surplus in capacities resulting from renewable energy sources. The first solution employs superconducting magnetic energy storage (SMES) which can be deemed as an efficient solution for damping the frequency oscillations. Therefore in this work SMES that is managed by a simple proportional-integral-derivative controller (PID) controller is utilized to overcome the low inertia. In the second solution the hydrogen storage system is employed to maintain the stability of the microgrid by storing surplus power generated by renewable energy sources (RESs). Power-to-Power is a method of storing excess renewable energy as chemical energy in the form of hydrogen. Hydrogen can be utilized locally or delivered to a consumption node. The proposed µG operation demonstrates that the integration of the photovoltaics (PVs) wind turbines (WTs) diesel engine generator (DEG) electrolyzer micro gas turbine (µGT) and SMES is adequate to fulfill the load requirements under transient operating circumstances such as a low and high PV output power as well as to adapt to sudden changes in the load demand. The effectiveness of the proposed schemes is confirmed using real irradiance data (Benban City Egypt) using a MATLAB/SIMULINK environment.
Energy Storage Systems: A Review
Jul 2022
Publication
The world is rapidly adopting renewable energy alternatives at a remarkable rate to address the ever-increasing environmental crisis of CO2 emissions. Renewable Energy Systems (RES) offers enormous potential to decarbonize the environment because they produce no greenhouse gases or other polluting emissions. However the RES relies on natural resources for energy generation such as sunlight wind water geothermal which are generally unpredictable and reliant on weather season and year. To account for these intermittencies renewable energy can be stored using various techniques and then used in a consistent and controlled manner as needed. Several researchers from around the world have made substantial contributions over the last century to developing novel methods of energy storage that are efficient enough to meet increasing energy demand and technological break-throughs. This review attempts to provide a critical review of the advancements in the Energy Storage System (ESS) from 1850–2022 including its evolution classification operating principles and comparison
Hydrogen Storage for a Net-zero Carbon Future
Apr 2023
Publication
If a hydrogen economy is to become a reality along with efficient and decarbonized production and adequate transportation infrastructure deployment of suitable hydrogen storage facilities will be crucial. This is because due to various technical and economic reasons there is a serious possibility of an imbalance between hydrogen supply and demand. Hydrogen storage could also be pivotal in promoting renewable energy sources and facilitating the decarbonization process by providing long duration storage options which other forms of energy storage such as batteries with capacity limitations or pumped hydro with geographical limitations cannot meet. However hydrogen is not the easiest substance to store and handle. Under ambient conditions the extremely low volumetric energy density of hydrogen does not allow for its efficient and economic storage which means it needs to be compressed liquefied or converted into other substances that are easier to handle and store. Currently there are different hydrogen storage solutions at varying levels of technology market and commercial readiness with different applications depending on the circumstances. This paper evaluates the relative merits and techno-economic features of major types of hydrogen storage options: (i) pure hydrogen storage (ii) synthetic hydrocarbons (iii) chemical hydrides (iv) liquid organic hydrogen carriers (v) metal hydrides and (vi) porous materials. The paper also discusses the main barriers to investment in hydrogen storage and highlights key features of a viable business model in particular the policy and regulatory framework needed to address the primary risks to which potential hydrogen storage investors are exposed.
Cost Benefit Analysis for Green Hydrogen Production from Treated Effluent: The Case Study of Oman
Nov 2022
Publication
Recently the management of water and wastewater is gaining attention worldwide as a way of conserving the natural resources on the planet. The traditional wastewater treatment in Oman is such that the treated effluent produced is only reused for unfeasible purposes such as landscape irrigation cooling or disposed of in the sea. Introducing more progressive reuse applications can result in achieving a circular economy by considering treated effluent as a source of producing new products. Accordingly wastewater treatment plants can provide feedstock for green hydrogen production processes. The involvement of the wastewater industry in the green pathway of production scores major points in achieving decarbonization. In this paper the technical and economic feasibility of green hydrogen production in Oman was carried out using a new technique that would help explore the benefits of the treated effluent from wastewater treatment in Oman. The feasibility study was conducted using the Al Ansab sewage treatment plant in the governate of Muscat in Wilayat (region) Bousher. The results have shown that the revenue from Al Ansab STP in a conventional case is 7.02 million OMR/year while sustainable alternatives to produce hydrogen from the Proton Exchange Membrane (PEM) electrolyzer system for two cases with capacities of 1500 kg H2/day and 50000 kg H2/day would produce revenue of 8.30 million OMR/year and 49.73 million OMR/year respectively.
A Review of Hydrogen Technologies and Engineering Solutions for Railway Vehicle Design and Operations
Oct 2021
Publication
Interest in hydrogen-powered rail vehicles has gradually increased worldwide over recent decades due to the global pressure on reduction in greenhouse gas emissions technology availability and multiple options of power supply. In the past research and development have been primarily focusing on light rail and regional trains but the interest in hydrogen-powered freight and heavy haul trains is also growing. The review shows that some technical feasibility has been demonstrated from the research and experiments on proof-of-concept designs. Several rail vehicles powered by hydrogen either are currently operating or are the subject of experimental programmes. The paper identifies that fuel cell technology is well developed and has obvious application in providing electrical traction power while hydrogen combustion in traditional IC engines and gas turbines is not yet well developed. The need for on-board energy storage is discussed along with the benefits of energy management and control systems.
Hydrogen Europe Podcast: The Commision's Support to the Hydrogen Ecosystem
Jul 2022
Publication
In this episode titled "The Commission's support to the hydrogen ecosystem" our CEO Jorgo Chatzimarkakis discusses with Rosalinde van der Vlies Clean Planet Director DG RTD - European Commission. Starting off on how Rosalinde joined the Commission the two speakers discuss the Commission's support in developing a hydrogen ecosystem also in light of its participation in the Clean Hydrogen Partnership and the implications arising from the REPowerEU.
Techno-economic Analysis of Hydrogen Production from PV Plants
Jan 2022
Publication
Hydrogen production through electrolysis from renewable sources is expected to play an important role to achieve the reduction targets of carbon dioxide emissions set for the next decades. Electrolysers can use the renewable energy surplus to produce green hydrogen and contribute to making the electrical grid more stable. Hydrogen can be used as medium-long term energy storage converted into other fuels or used as feedstock in industry thus contributing to decarbonise hard-to-abate-sectors. However due to the intermittent and variable nature of solar and wind power the direct coupling of electrolysers with renewables may lead to high production fluctuations and frequent shutdowns. As a consequence accelerated electrolyser degradation and safety issues related to low load operation may arise. In this study simulations of hydrogen production with an electrolyser fed by a PV system are performed in Matlab for a reference year. The effect of PV power fluctuations on the electrolyser operation and production is investigated. The impact of the electrolyser size for a fixed nominal power of the PV plant is also analysed from both energetic and economic points of view.
Decarbonisation of Heat and the Role of ‘Green Gas’ in the United Kingdom
May 2018
Publication
This paper looks at the possible role of ‘green gas’ in the decarbonisation of heat in the United Kingdom. The option is under active discussion at the moment because of the UK’s rigorous carbon reduction targets and the growing realisation that there are problems with the ‘default’ option of electrifying heat. Green gas appears to be technically and economically feasible. However as the paper discusses there are major practical and policy obstacles which make it unlikely that the government will commit itself to developing ‘green gas’ in the foreseeable future.
Energy Sustainability Analysis (ESA) of Energy-Producing Processes: A Case Study on Distributed H2 Production
Sep 2019
Publication
In the sustainability context the performance of energy-producing technologies using different energy sources needs to be scored and compared. The selective criterion of a higher level of useful energy to feed an ever-increasing demand of energy to satisfy a wide range of endo- and exosomatic human needs seems adequate. In fact surplus energy is able to cover energy services only after compensating for the energy expenses incurred to build and to run the technology itself. This paper proposes an energy sustainability analysis (ESA) methodology based on the internal and external energy use of a given technology considering the entire energy trajectory from energy sources to useful energy. ESA analysis is conducted at two levels: (i) short-term by the use of the energy sustainability index (ESI) which is the first step to establish whether the energy produced is able to cover the direct energy expenses needed to run the technology and (ii) long-term by which all the indirect energy-quotas are considered i.e. all the additional energy requirements of the technology including the energy amortization quota necessary for the replacement of the technology at the end of its operative life. The long-term level of analysis is conducted by the evaluation of two indicators: the energy return per unit of energy invested (EROI) over the operative life and the energy payback-time (EPT) as the minimum lapse at which all energy expenditures for the production of materials and their construction can be repaid to society. The ESA methodology has been applied to the case study of H2 production at small-scale (10–15 kWH2) comparing three different technologies: (i) steam-methane reforming (SMR) (ii) solar-powered water electrolysis (SPWE) and (iii) two-stage anaerobic digestion (TSAD) in order to score the technologies from an energy sustainability perspective.
Modelling and Evaluation of PEM Hydrogen Technologies for Frequency Ancillary Services in Future Multi-energy Sustainable Power Systems
Mar 2019
Publication
This paper examines the prospect of PEM (Proton Exchange Membrane) electrolyzers and fuel cells to partake in European electrical ancillary services markets. First the current framework of ancillary services is reviewed and discussed emphasizing the ongoing European harmonization plans for future frequency balancing markets. Next the technical characteristics of PEM hydrogen technologies and their potential uses within the electrical power system are discussed to evaluate their adequacy to the requirements of ancillary services markets. Last a case study based on a realistic representation of the transmission grid in the north of the Netherlands for the year 2030 is presented. The main goal of this case study is to ascertain the effectiveness of PEM electrolyzers and fuel cells for the provision of primary frequency reserves. Dynamic generic models suitable for grid simulations are developed for both technologies including the required controllers to enable participation in ancillary services markets. The obtained results show that PEM hydrogen technologies can improve the frequency response when compared to the procurement with synchronous generators of the same reserve value. Moreover the fast dynamics of PEM electrolyzers and fuel cells can help mitigate the negative effects attributed to the reduction of inertia in the system.
Hydrogen Role in the Valorization of Integrated Steelworks Process Off-gases through Methane and Methanol Syntheses
Jun 2021
Publication
The valorization of integrated steelworks process off-gases as feedstock for synthesizing methane and methanol is in line with European Green Deal challenges. However this target can be generally achieved only through process off-gases enrichment with hydrogen and use of cutting-edge syntheses reactors coupled to advanced control systems. These aspects are addressed in the RFCS project i3 upgrade and the central role of hydrogen was evident from the first stages of the project. First stationary scenario analyses showed that the required hydrogen amount is significant and existing renewable hydrogen production technologies are not ready to satisfy the demand in an economic perspective. The poor availability of low-cost green hydrogen as one of the main barriers for producing methane and methanol from process off-gases is further highlighted in the application of an ad-hoc developed dispatch controller for managing hydrogen intensified syntheses in integrated steelworks. The dispatch controller considers both economic and environmental impacts in the cost function and although significant environmental benefits are obtainable by exploiting process off-gases in the syntheses the current hydrogen costs highly affect the dispatch controller decisions. This underlines the need for big scale green hydrogen production processes and dedicated green markets for hydrogen-intensive industries which would ensure easy access to this fundamental gas paving the way for a C-lean and more sustainable steel production.
Numerical Study on Thermodynamic Coupling Characteristics of Fluid Sloshing in a Liquid Hydrogen Tank for Heavy-Duty Trucks
Feb 2023
Publication
The large-amplitude sloshing behavior of liquid hydrogen in a tank for heavy-duty trucks may have adverse effects on the safety and stability of driving. With successful application of liquid hydrogen in the field of new energy vehicles the coupled thermodynamic performance during liquid hydrogen large-amplitude sloshing becomes more attractive. In this paper a three-dimensional numerical model is established to simulate the thermodynamic coupling characteristics during liquid hydrogen sloshing in a horizontal tank for heavy-duty trucks. The calculation results obtained by the developed model are in good agreement with experimental data for liquid hydrogen. Based on the established 3D model the large-amplitude sloshing behavior of liquid hydrogen under extreme acceleration as well as the effects of acceleration magnitude and duration on liquid hydrogen sloshing is numerically determined. The simulation results show that under the influence of liquid hydrogen large-amplitude sloshing the convective heat transfer of fluid in the tank is greatly strengthened resulting in a decrease in the vapor temperature and an increase in the liquid temperature. In particular the vapor condensation caused by the sloshing promotes a rapid reduction of pressure in the tank. When the acceleration magnitude is 5 g with a duration of 200 ms the maximum reduction of ullage pressure is 1550 Pa and the maximum growth of the force on the right wall is 3.89 kN. Moreover the acceleration magnitude and duration have a remarkable influence on liquid hydrogen sloshing. With the increase in acceleration magnitude or duration there is a larger sloshing amplitude for the liquid hydrogen. When the duration of acceleration is 200 ms compared with the situation at the acceleration magnitude of 5 g the maximum reductions of ullage pressure decrease by 9.46% and 55.02% and the maximum growth of forces on the right wall decrease by 80.57% and 99.53% respectively at 2 g and 0.5 g. Additionally when the acceleration magnitude is 5 g in contrast with the situation at a duration of acceleration of 200 ms the maximum-ullage-pressure drops decrease by 8.17% and 21.62% and the maximum increase in forces on the right wall decrease by 71.80% and 88.63% at 100 ms and 50 ms respectively. These results can provide a reference to the safety design of horizontal liquid hydrogen tanks for heavy-duty trucks.
Combustion Characteristics of Hydrogen in a Noble Gas Compression Ignition Engine
Jul 2021
Publication
Hydrogen eliminates carbon emissions from compression ignition (CI) engines while noble gases eliminate nitrogen oxide (NOx) emissions by replacing nitrogen. Noble gases can increase the in-cylinder temperature during the compression stroke due to their high specific heat ratio. This paper aims to find the optimum parameters for hydrogen combustion in an argon–oxygen atmosphere and to study hydrogen combustion in all noble gases providing hydrogen combustion data with suitable engine parameters to predict hydrogen ignitability under different conditions. Simulations are performed with Converge CFD software based on the Yanmar NF19SK direct injection CI (DICI) engine parameters. The results are validated with the experimental results of hydrogen combustion in an argon–oxygen atmosphere with a rapid compression expansion machine (RCEM) and modifications of the hydrogen injection timing and initial temperature are proposed. Hydrogen ignition in an argon atmosphere is dependent on a minimum initial temperature of 340 K but the combustion is slightly unstable. Helium and neon are found to be suitable for hydrogen combustion in low compression ratio (CR) engines. However krypton and xenon require temperature modification and a high CR for stable ignition. Detailed parameter recommendations are needed to improve hydrogen ignitability in conventional diesel engines with the least engine modification.
Renewable Energy Potentials and Roadmap in Brazil, Austria, and Germany
Mar 2024
Publication
The emerging energy transition is particularly described as a move towards a cleaner lower-carbon system. In the context of the global shift towards sustainable energy sources this paper reviews the potential and roadmap for hydrogen energy as a crucial component of the clean energy landscape. The primary objective is to present a comprehensive literature overview illuminating key themes trends and research gaps in the scientific discourse concerning hydrogen production and energy policy. This review focuses particularly on specified geographic contexts with an emphasis on understanding the unique energy policies related to renewable energy in Brazil Austria and Germany. Given their distinct social systems and developmental stages this paper aims to delineate the nuanced approaches these countries adopt in their pursuit of renewable energy and the integration of hydrogen within their energy frameworks. Brazil exhibits vast renewable energy potential particularly in wind and solar energy sectors positioning itself for substantial growth in the coming years. Germany showcases a regulatory framework that promotes innovation and technological expansion reflecting its highly developed social system and commitment to transitioning away from fossil fuels. Austria demonstrates dedication to decarbonization particularly through the exploration of biomethane for residential heating and cooling.
Revolutionising Energy Storage: The Latest Breakthrough in Liquid Organic Hydrogen Carriers
Mar 2024
Publication
Liquid organic hydrogen carriers (LOHC) can be used as a lossless form of hydrogen storage at ambient conditions. The storage cycle consists of the exothermic hydrogenation of a hydrogen-lean molecule at the start of the transport usually the hydrogen production site becoming a hydrogen-rich molecule. This loaded molecule can be transported long distances or be used as long-term storage due to its ability to not lose hydrogen over long periods of time. At the site or time of required hydrogen production the hydrogen can be released through an endothermic dehydrogenation reaction. LOHCs show similar properties to crude oils such as petroleum and diesel allowing easy handling and possibilities of integration with current infrastructure. Using this background this paper reviews a variety of aspects of the LOHC life cycle with a focus on currently studied materials. Important factors such as the hydrogenation and dehydrogenation requirements for each material are analysed to determine their ability to be used in current scenarios. Toluene and dibenzyltoluene are attractive options with promising storage attributes however their dehydrogenation enthalpies remain a problem. The economic feasibility of LOHCs being used as a delivery device were briefly analysed. LOHCs have been shown to be the cheapest option for long distance transport (>200 km) and are cheaper than most at shorter distances in terms of specifically transport costs. The major capital cost of an LOHC delivery chain remains the initial investment for the raw materials and the cost of equipment for performing hydrogenation and dehydrogenation. Finally some studies in developing the LOHC field were discussed such as microwave enhancing parts of the process and mixing LOHCs to acquire more advantageous properties.
Environmental Benefit and Investment Value of Hydrogen-Based Wind-Energy Storage System
Mar 2021
Publication
Alongside the rapid expansion of wind power installation in China wind curtailment is also mounting rapidly due to China’s energy endowment imbalance. The hydrogen-based wind-energy storage system becomes an alternative to solve the puzzle of wind power surplus. This article introduced China’s energy storage industry development and summarized the advantages of hydrogen-based wind-energy storage systems. From the perspective of resource conservation it estimated the environmental benefits of hydrogen-based wind-energy storages. This research also builds a valuation model based on the Real Options Theory to capture the distinctive flexible charging and discharging features of the hydrogen-based wind-energy storage systems. Based on the model simulation results including the investment value and operation decision of the hydrogen energy storage system with different electricity prices system parameters and different levels of subsidies are presented. The results show that the hydrogen storage system fed with the surplus wind power can annually save approximately 2.19–3.29 million tons of standard coal consumption. It will reduce 3.31–4.97 million tons of CO2 SO2 NOx and PM saving as much as 286.6–429.8 million yuan of environmental cost annually on average. The hydrogen-based wind-energy storage system’s value depends on the construction investment and operating costs and is also affected by the meanreverting nature and jumps or spikes in electricity prices. The market-oriented reform of China’s power sector is conducive to improve hydrogen-based wind-energy storage systems’ profitability. At present subsidies are still essential to reduce initial investment and attract enterprises to participate in hydrogen energy storage projects.
Technological Pathways for Decarbonizing Petroleum Refining
Sep 2021
Publication
This paper discusses the technical specifications of how U.S. petroleum refineries can reduce facility emissions and shift to produce low-carbon fuels for hard to abate sectors by utilizing existing innovative technologies.
Advances in Hydrogen Storage Materials: Harnessing Innovative Technology, from Machine Learning to Computational Chemistry, for Energy Storage Solutions
Mar 2024
Publication
The demand for clean and sustainable energy solutions is escalating as the global population grows and economies develop. Fossil fuels which currently dominate the energy sector contribute to greenhouse gas emissions and environmental degradation. In response to these challenges hydrogen storage technologies have emerged as a promising avenue for achieving energy sustainability. This review provides an overview of recent advancements in hydrogen storage materials and technologies emphasizing the importance of efficient storage for maximizing hydrogen’s potential. The review highlights physical storage methods such as compressed hydrogen (reaching pressures of up to 70 MPa) and material-based approaches utilizing metal hydrides and carboncontaining substances. It also explores design considerations computational chemistry high-throughput screening and machine-learning techniques employed in developing efficient hydrogen storage materials. This comprehensive analysis showcases the potential of hydrogen storage in addressing energy demands reducing greenhouse gas emissions and driving clean energy innovation.
Analysis of the Levelized Cost of Renewable Hydrogen in Austria
Mar 2023
Publication
Austria is committed to the net-zero climate goal along with the European Union. This requires all sectors to be decarbonized. Hereby hydrogen plays a vital role as stated in the national hydrogen strategy. A report commissioned by the Austrian government predicts a minimum hydrogen demand of 16 TWh per year in Austria in 2040. Besides hydrogen imports domestic production can ensure supply. Hence this study analyses the levelized cost of hydrogen for an off-grid production plant including a proton exchange membrane electrolyzer wind power and solar photovoltaics in Austria. In the first step the capacity factors of the renewable electricity sources are determined by conducting a geographic information system analysis. Secondly the levelized cost of electricity for wind power and solarphotovoltaics plants in Austria is calculated. Thirdly the most cost-efficient portfolio of wind power and solar photovoltaics plants is determined using electricity generation profiles with a 10-min granularity. The modelled system variants differ among location capacity factors of the renewable electricity sources and the full load hours of the electrolyzer. Finally selected variables are tested for their sensitivities. With the applied model the hydrogen production cost for decentralized production plants can be calculated for any specific location. The levelized cost of hydrogen estimates range from 3.08 EUR/kg to 13.12 EUR/kg of hydrogen whereas it was found that the costs are most sensitive to the capacity factors of the renewable electricity sources and the full load hours of the electrolyzer. The novelty of the paper stems from the model applied that calculates the levelized cost of renewable hydrogen in an off-grid hydrogen production system. The model finds a cost-efficient portfolio of directly coupled wind power and solar photovoltaics systems for 80 different variants in an Austria-specific context.
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