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Alternative-energy-vehicles Deployment Delivers Climate, Air Quality, and Health Co-benefits when Coupled with Decarbonizing Power Generation in China
Aug 2021
Publication
China is the world’s largest carbon emitter and suffers from severe air pollution which results in approximately one million premature deaths/year. Alternative energy vehicles (AEVs) (electric hydrogen fuel cell and natural gas vehicles) can reduce carbon emissions and improve air quality. However climate air quality and health benefits of AEVs powered with deeply decarbonized power generation are poorly quantified. Here we quantitatively estimate the air quality health carbon emission and economic benefits of replacing internal combustion engine vehicles with various AEVs. We find co-benefits increase dramatically as the electricity grid decarbonizes and hydrogen is produced from non-fossil fuels. Relative to 2015 a conversion to AEVs using largely non-fossil power can reduce air pollution and associated premature mortalities and years of life lost by 329000 persons/year and 1611000 life years/year. Thus maximizing climate air quality and health benefits of AEV deployment in China requires rapid decarbonization of the power system.
Numerical Study on Shockwave Attenuation by Water Mist in Confined Spaces
Sep 2021
Publication
Hydrogen safety has become the first consideration especially after fuel cell automobiles were pushed into commercial auto market. Tunnels are important parts of traffic infrastructure featured in confinement or semi-confinement. Hydrogen detonation is a potential accident scenario while hydrogen fuel cell vehicles are operated in a traffic tunnel with a confined space. Pressure shockwaves are mostly produced by hydrogen detonation and propagate along the tunnel. As a designed safety measure water mist injection is hopefully to mitigate the pressure loads of such shocks. To model the interaction between shockwaves and water droplets a droplet breakup model has been developed for the COM3D code which is a highly validated three-dimensional hydrogen explosion simulation code. By using the model the hydrogen detonation shockwave propagation in confined volumes is simulated in the study. The attenuation effects of water mist on the pressure shocks in the simulations are elaborated and discussed based on the simulation results.
EU Harmonised Testing Procedure: Determination of Water Electrolyser Energy Performance
Jan 2023
Publication
The objective of this pre-normative research (PNR) document is to present a testing procedure for establishing the energy performance of water (steam) electrolyser systems (WE systems) whether grid-connected or off-grid and individual water electrolysers (WEs)/high-temperature electrolysers (HTEs) for the generation of hydrogen by water/steam electrolysis. The WE systems use electricity mostly from variable renewable energy sources. HTE may additionally utilise (waste) heat from energy conversion and other industrial processes. By applying this procedure the determination of the specific energy consumption per unit of hydrogen output under standard ambient temperature and pressure (SATP) conditions allows for an adequate comparison of different WE systems. Also the energy performance potential of WEs or WE systems employing low-temperature water electrolysis (LTWE) technologies compared to HTE employing high-temperature steam electrolysis (HTSEL) technologies may be established under actual hydrogen output conditions by applying this procedure. The test method is to evaluate the specific energy consumption during steady-state operation at specified conditions including rated input power pressure and temperature of hydrogen recommended by the manufacturer of the WE or WE system. The energy efficiency and the electrical efficiency based on higher and lower heating value of hydrogen can be derived from respectively the specific energy consumption and the specific electric energy consumption as additional energy performance indicators (EPIs). In a plant setting the specific energy consumption of an individual water electrolyser including HTE under hydrogen output conditions may also be determined using this testing procedure. This procedure is intended to be used as a general characterisation method for evaluating the energy performance of WEs including HTEs and systems by the research community and industry alike.
Methane Cracking for Hydrogen Production: A Review of Catalytic and Molten Media Pyrolysis
May 2022
Publication
Currently hydrogen is mainly generated by steam methane reforming with significant CO2 emissions thus exacerbating the greenhouse effect. This environmental concern promotes methane cracking which represents one of the most promising alternatives for hydrogen production with theoretical zero CO/CO2 emissions. Methane cracking has been intensively investigated using metallic and carbonaceous catalysts. Recently research has focused on methane pyrolysis in molten metals/salts to prevent both reactor coking and rapid catalyst deactivation frequently encountered in conventional pyrolysis. Another expected advantage is the heat transfer improvement due to the high heat capacity of molten media. Apart from the reaction itself that produces hydrogen and solid carbon the energy source used in this endothermic process can also contribute to reducing environmental impacts. While most researchers used nonrenewable sources based on fossil fuel combustion or electrical heating concentrated solar energy has not been thoroughly investigated to date for pyrolysis in molten media. However it could be a promising innovative pathway to further improve hydrogen production sustainability from methane cracking. After recalling the basics of conventional catalytic methane cracking and the developed solar cracking reactors this review delves into the most significant results of the state-of-the-art methane pyrolysis in melts (molten metals and salts) to show the advantages and the perspectives of this new path as well as the carbon products’ characteristics and the main factors governing methane conversion.
Quantifying the Impacts of Heat Decarbonisation Pathways on the Future Electricity and Gas Demand
May 2022
Publication
The decarbonisation of heat supply will play a critical role in meeting the emissions reduction target. There is however great uncertainty associated with the achievable levels of heat decarbonisation and the optimal heat technology mix which can have serious implications for the future electricity and gas demand. This work employs an integrated gas electricity and heat supply model to quantify the impacts of heat decarbonisation pathways on the future electricity and gas demand. A case study in the Great Britain is performed considering two heat decarbonisation scenarios in 2050: one is the predominantly electrified heat supply and the other is the predominantly hydrogen-based heat supply. The electricity demand becomes more volatile in the electrified heat scenario as the peak surges to 107.3 GW compared to 51.1 GW in the 2018 reference scenario while the peak in hydrogen-based heat scenario is 78.4 GW. The peak gas demand declines from 247.6 GW for 2018 to 81.7 GW for electrified heat scenario and to 85.1 GW for hydrogen-based heat scenario confirming that the seasonality associated with heat demand is shifting away from the gas network and towards electricity network. Moreover a sensitivity analysis shows that the future electricity demand is highly sensitive to parameters such as relative heat demand coefficient of performance of air source heat pumps and share of electricity in hydrogen production. Finally the application of a load shifting strategy demonstrates that demand-side flexibility has the potential to maintain the electricity system balance and minimise the generation and network infrastructure requirements arising from heat electrification. While the case study presented in this paper is based on the Great Britain the findings regarding the future electricity and gas demand are relevant for the global energy transition.
Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
Oct 2021
Publication
Consumption of fossil fuels especially in transport and energy-dependent sectors has led to large greenhouse gas production. Hydrogen is an exciting energy source that can serve our energy purposes and decrease toxic waste production. Decomposition of methane yields hydrogen devoid of COx components thereby aiding as an eco-friendly approach towards large-scale hydrogen production. This review article is focused on hydrogen production through thermocatalytic methane decomposition (TMD) for hydrogen production. The thermodynamics of this approach has been highlighted. Various methods of hydrogen production from fossil fuels and renewable resources were discussed. Methods including steam methane reforming partial oxidation of methane auto thermal reforming direct biomass gasification thermal water splitting methane pyrolysis aqueous reforming and coal gasification have been reported in this article. A detailed overview of the different types of catalysts available the reasons behind their deactivation and their possible regeneration methods were discussed. Finally we presented the challenges and future perspectives for hydrogen production via TMD. This review concluded that among all catalysts nickel ruthenium and platinum-based catalysts show the highest activity and catalytic efficiency and gave carbon-free hydrogen products during the TMD process. However their rapid deactivation at high temperatures still needs the attention of the scientific community.
Jet Zero Strategy: Delivering Net Zero Aviation by 2050
Jul 2022
Publication
The Jet Zero strategy sets out how we will achieve net zero aviation by 2050.<br/>It focuses on the rapid development of technologies in a way that maintains the benefits of air travel whilst maximising the opportunities that decarbonisation can bring to the UK.<br/>The Jet Zero strategy includes a 5-year delivery plan setting out the actions that will need to be taken in the coming years to support the delivery of net zero aviation by 2050. We will be monitoring progress and reviewing and updating our strategy every 5 years.<br/>The strategy is informed by over 1500 responses to the Jet Zero consultation and the Jet Zero further technical consultation to which we have issued a summary of responses and government response.<br/>The Jet Zero investment flightpath is part of a series of roadmaps to be published over the course of 2022 for each sector of the Prime Minister’s Ten point plan for a green industrial revolution.<br/>It showcases the UK’s leading role in the development and commercialisation of new low and zero emission aviation technologies. It also highlights investment opportunities across systems efficiencies sustainable aviation fuels and zero emission aircraft.
The EU Green Deal (2022 ed.)
Jan 2023
Publication
In this report we focus on the fundamentals of energy and climate policy as reformulated in the EU Green Deal. The 2022 edition includes updates following the publication of the Fit for 55 Package and the EU Hydrogen and Decarbonised Gas Markets Package. The reader is guided through the landscape of EU climate and energy policy. Starting with the big picture of the foundations of energy and climate policy we then move to discussing in more detail European climate policy security of supply and energy networks. We continue with energy wholesale and retail markets and finish with a closer look at energy innovation. Each chapter is divided into several sections aiming to give the reader a broad overview of the areas of climate and energy policy that are impacted by the EU Green Deal. The references at the end of each section serve as suggestions for further reading on each topic.
Recent Advances of Metal Borohydrides for Hydrogen Storage
Aug 2022
Publication
Hydrogen energy is an excellent carrier for connecting various renewable energy sources and has many advantages. However hydrogen is flammable and explosive and its density is low and easy to escape which brings inconvenience to the storage and transportation of hydrogen. Therefore hydrogen storage technology has become one of the key steps in the application of hydrogen energy. Solid-state hydrogen storage method has a very high volumetric hydrogen density compared to the traditional compressed hydrogen method. The main issue of solid-state hydrogen storage method is the development of advanced hydrogen storage materials. Metal borohydrides have very high hydrogen density and have received much attention over the past two decades. However high hydrogen sorption temperature slow kinetics and poor reversibility still severely restrict its practical applications. This paper mainly discusses the research progress and problems to be solved of metal borohydride hydrogen storage materials for solid-state hydrogen storage.
Prospects and Challenges of Green Hydrogen Economy via Multi-Sector Global Symbiosis in Qatar
Jan 2021
Publication
Low carbon hydrogen can be an excellent source of clean energy which can combat global climate change and poor air quality. Hydrogen based economy can be a great opportunity for a country like Qatar to decarbonize its multiple sectors including transportation shipping global energy markets and industrial sectors. However there are still some barriers to the realization of a hydrogen-based economy which includes large scale hydrogen production cost infrastructure investments bulk storage transport & distribution safety consideration and matching supply-demand uncertainties. This paper highlights how the aforementioned challenges can be handled strategically through a multi-sector industrial-urban symbiosis for the hydrogen supply chain implementation. Such symbiosis can enhance the mutual relationship between diverse industries and urban planning by exploring varied scopes of multi-purpose hydrogen usage (i.e. clean energy source as a safer carrier industrial feedstock and intermittent products vehicle and shipping fuel and international energy trading etc.) both in local and international markets. It enables individual entities and businesses to participate in the physical exchange of materials by-products energy and water with strategic advantages for all participants. Besides waste/by-product exchanges several different kinds of synergies are also possible such as the sharing of resources and shared facilities. The diversified economic base regional proximity and the facilitation of rules strategies and policies may be the key drivers that support the creation of a multi-sector hydrogen supply chain in Qatar.
What is Stored, Why, and How? Mental Models, Knowledge, and Public Acceptance of Hydrogen Storage
Nov 2016
Publication
Although electricity storage plays a decisive role for the German “Energiewende” and it has become evident that the successful diffusion of technologies is not only a question of technical feasibility but also of social acceptance research on electricity storage technologies from a social science point of view is still scarce. This study therefore empirically explores laypersons’ mindsets and knowledge related to storage technologies focusing on hydrogen. While the results indicate overall supportive attitudes and trust in hydrogen storage some misconceptions a lack of information as well as concerns were identified which should be addressed in future communication concepts.
Electric Aircraft Fueled by Liquid Hydrogen and Liquefied Natural Gas
Jul 2021
Publication
The paper is a review of the opportunities and challenges of cryogenic power devices of electric aircraft and the ongoing research and development efforts of the government agencies and the industry. Liquid Hydrogen (LH2) and Liquefied Natural Gas (LNG) are compared to support high temperature superconducting (HTS) and normal metal devices respectively. The power devices were assumed to operate at the normal boiling point of the fuel used. The efficiencies of the electrical devices are estimated based on state-of-the-art technology. The mass flow rates and total fuel requirements for both the cryogenic fuels required to maintain the operating temperatures of the devices were simulated using thermal network models. A twin-aisle 300 passenger aircraft with a 5.5 h flight duration was used for the models. The results show that the required masses of LH2 and LNG are 744 kg and 13638 kg respectively for the cooling requirement. The corresponding volumes of LH2 and LNG required are 9760 and 30300 L respectively. In both cases the estimated mass of the fuel needed for the aircraft is more than what is needed to maintain the cryogenic environment of the power devices. It was concluded that an electric aircraft with LNG cooled normal metal devices is feasible. However an aircraft with HTS devices and cooled with LH2 is more attractive if the ongoing R&D efforts on HTS devices and LH2 infrastructure are successful. The emission reductions would be substantially higher with LH2 particularly when H2 is produced using renewable energy sources.
Cold Start Cycling Durability of Fuel Cell Stacks for Commercial Automotive Applications
Sep 2022
Publication
System durability is crucial for the successful commercialization of polymer electrolyte fuel cells (PEFCs) in fuel cell electric vehicles (FCEVs). Besides conventional electrochemical cycling durability during long-term operation the effect of operation in cold climates must also be considered. Ice formation during start up in sub-zero conditions may result in damage to the electrocatalyst layer and the polymer electrolyte membrane (PEM). Here we conduct accelerated cold start cycling tests on prototype fuel cell stacks intended for incorporation into commercial FCEVs. The effect of this on the stack performance is evaluated the resulting mechanical damage is investigated and degradation mechanisms are proposed. Overall only a small voltage drop is observed after the durability tests only minor damage occurs in the electrocatalyst layer and no increase in gas crossover is observed. This indicates that these prototype fuel cell stacks successfully meet the cold start durability targets for automotive applications in FCEVs.
Sustainable Ammonia Production Processes
Mar 2021
Publication
Due to the important role of ammonia as a fertilizer in the agricultural industry and its promising prospects as an energy carrier many studies have recently attempted to find the most environmentally benign energy efficient and economically viable production process for ammonia synthesis. The most commonly utilized ammonia production method is the Haber-Bosch process. The downside to this technology is the high greenhouse gas emissions surpassing 2.16 kgCO2-eq/kg NH3 and high amounts of energy usage of over 30 GJ/tonne NH3 mainly due to the strict operational conditions at high temperature and pressure. The most widely adopted technology for sustainable hydrogen production used for ammonia synthesis is water electrolysis coupled with renewable technologies such as wind and solar. In general a water electrolyzer requires a continuous supply of pretreated water with high purity levels for its operation. Moreover for production of 1 tonne of hydrogen 9 tonnes of water is required. Based on this data for the production of the same amount of ammonia through water electrolysis 233.6 million tonnes/yr of water is required. In this paper a critical review of different sustainable hydrogen production processes and emerging technologies for sustainable ammonia synthesis along with a comparative life cycle assessment of various ammonia production methods has been carried out. We find that through the review of each of the studied technologies either large amounts of GHG emissions are produced or high volumes of pretreated water is required or a combination of both these factors occur.
On the Road to Sustainable Transport: Acceptance and Preferences for Renewable Fuel Production Infrastructure
Sep 2022
Publication
To abate climate change and ameliorate the air quality in urban areas innovative solutions are required to reduce CO2 and pollutant emissions from traffic. Alternative fuels made from biomass or CO2 and hydrogen can contribute to these goals by substituting fossil gasoline or diesel in combustion engines. Using a conjoint analysis approach the current study investigates preferences of laypeople (n = 303) for fuel production facilities in terms of siting location plant size raw material used in the production and raw material transport. The location was most decision-relevant followed by raw material transport whereas plant size and type of raw material played a less prominent role for the preference choice. The best-case scenario from the point of view of acceptance would be the installation of a rather small bio-hybrid fuel production plant in an industrial area (instead of an agricultural or pristine environment). No transport or transport via underground pipeline were preferred over truck/tank car or overground pipeline. The findings can be used as a basis for planning and decision-making for designing production networks for new fuel types.
Low-carbon Economic Dispatch of Power Systems Based on Mobile Hydrogen Storage
Mar 2022
Publication
To alleviate the global warming crisis carbon reduction is an inevitable trend of sustainable development. The energy carrier with Hydrogen (H2) is considered to be one of the promising choices for realizing a low-carbon economy. With the increasing penetration level of wind power generation and for well-balancing wind generation fluctuations this paper proposes a low-carbon economic dispatch method for power systems based on mobile hydrogen storage(MHS). The wind power surplus during off-peak load periods is first utilized to generate green H2. Afterward the green H2 is optimally transported to multiple hydrogen storage(HS) stations for generating power electricity by flexibly controlling the electrolysis(EL) methanation(ME) carbon capture(CCS) and H2 power generation processes in such a way the wind power is coordinated with the hydrogen production transport and utilization to reduce the total carbon emission and minimize the operation cost of power systems. Finally the proposed power system low-carbon economic dispatch model is verified by case studies.
Technical Evaluation of the Flexibility of Water Electrolysis Systems to Increase Energy Flexibility: A Review
Jan 2023
Publication
The goal of achieving water electrolysis on a gigawatt scale faces numerous challenges regarding technological feasibility and market application. Here the flexibility of operation scenarios such as load changes and capacity of electrolysis plays a key role. This raises the question of how flexible electrolysis systems currently are and what possibilities there are to increase flexibility. In order to be able to answer this question in the following a systematic literature research was carried out with the aim to show the current technical possibilities to adapt load and capacity of electrolysis technologies and to determine limits. The result of the systematic literature research is an overview matrix of the electrolysis types AEL PEMEL HTEL and AEMEL already applied in the market. Technical data on the operation of the respective electrolysis stacks as well as details and materials for the respective stack structure (cathode anode electrolyte) were summarized. The flexibility of the individual technologies is addressed by expressing it in values such as load flexibility and startup-times. The overview matrix contains values from various sour1ces in order to make electrolysis comparable at the stack level and to be able to make statements about flexibility. The result of the overview article shows the still open need for research and development to make electrolysis more flexible.
Prospect of Green Hydrogen Generation from Hybrid Renewable Energy Sources: A Review
Feb 2023
Publication
Hydrogen is one of the prospective clean energies that could potentially address two pressing areas of global concern namely energy crises and environmental issues. Nowadays fossil‐ based technologies are widely used to produce hydrogen and release higher greenhouse gas emis‐ sions during the process. Decarbonizing the planet has been one of the major goals in the recent decades. To achieve this goal it is necessary to find clean sustainable and reliable hydrogen pro‐ duction technologies with low costs and zero emissions. Therefore this study aims to analyse the hydrogen generation from solar and wind energy sources and observe broad prospects with hybrid renewable energy sources in producing green hydrogen. The study mainly focuses on the critical assessment of solar wind and hybrid‐powered electrolysis technologies in producing hydrogen. Furthermore the key challenges and opportunities associated with commercial‐scale deployment are addressed. Finally the potential applications and their scopes are discussed to analyse the important barriers to the overall commercial development of solar‐wind‐based hydrogen production systems. The study found that the production of hydrogen appears to be the best candidate to be employed for multiple purposes blending the roles of fuel energy carrier and energy storage modality. Further studies are recommended to find technical and sustainable solutions to overcome the current issues that are identified in this study.
Renewable Hydrogen Implementations for Combined Energy Storage, Transportation and Stationary Applications
Dec 2019
Publication
The purpose of this paper is to discuss the potential of hydrogen obtained from renewable sources for energy generation and storage systems. The first part of analysis will address such issues as various methods of green hydrogen production storage and transportation. The review of hydrogen generation methods will be followed by the critical analysis and the selection of production method. This selection is justified by the results of the comparative research on alternative green hydrogen generation technologies with focus on their environmental impacts and costs. The comparative analysis includes the biomass-based methods as well as water splitting and photo-catalysis methods while water electrolysis is taken as a benchmark. Hydrogen storage and transportation issues will be further discussed in purpose to form the list of recommended solutions. In the second part of the paper the technology readiness and technical feasibility for joint hydrogen applications will be analysed. This will include the energy storage and production systems based on renewable hydrogen in combination with hydrogen usage in mobility systems as well as the stationary applications in buildings such as combined heat and power (CHP) plants or fuel cell electric generators. Based on the analysis of the selected case studies the author will discuss the role of hydrogen for the carbon emission reduction with the stress on the real value of carbon footprint of hydrogen depending on the gas source storage transportation and applications.
A Comprehensive Review on Recent Advancements in Thermochemical Processes for Clean Hydrogen Production to Decarbonize the Energy Sector
Sep 2022
Publication
Hydrogen is a source of clean energy as it can produce electricity and heat with water as a by-product and no carbon content is emitted when hydrogen is used as burning fuel in a fuel cell. Hydrogen is a potential energy carrier and powerful fuel as it has high flammability fast flame speed no carbon content and no emission of pollutants. Hydrogen production is possible through different technologies by utilizing several feedstock materials but the main concern in recent years is to reduce the emission of carbon dioxide and other greenhouse gases from energy sectors. Hydrogen production by thermochemical conversion of biomass and greenhouse gases has achieved much attention as researchers have developed several novel thermochemical methods which can be operated with low cost and high efficiency in an environmentally friendly way. This review explained the novel technologies which are being developed for thermochemical hydrogen production with minimum or zero carbon emission. The main concern of this paper was to review the advancements in hydrogen production technologies and to discuss different novel catalysts and novel CO2 -absorbent materials which can enhance the hydrogen production rate with zero carbon emission. Recent developments in thermochemical hydrogen production technologies were discussed in this paper. Biomass gasification and pyrolysis steam methane reforming and thermal plasma are promising thermochemical processes which can be further enhanced by using catalysts and sorbents. This paper also reviewed the developments and influences of different catalysts and sorbents to understand their suitability for continuous clean industrial hydrogen production.
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