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Assessment and Recommendations for a Fossil Free Future for Track Work Machinery
Oct 2021
Publication
Current railway track work machinery is mainly operated with diesel fuel. As a result track maintenance of Austrian Federal Railways (OeBB) amounts to nearly 9000 t CO2 equivalent per year according to calculations from Graz University of Technology. OeBB’s total length of railway lines only accounts for 0.56% of the world’s length of lines. This indicates huge potential for mitigating greenhouse gas emissions considering the need for track maintenance worldwide. Environmental concerns have led to the introduction of alternative drives in the transport sector. Until now R&D (Research & Development) of alternative propulsion technologies for track work machinery has been widely neglected. This paper examines the possibility of achieving zero direct emissions during maintenance and construction work in railways by switching to alternative drives. The goal is to analyze alternative propulsion solutions arising from the transport sector and to assess their applicability to track work machinery. Research results together with a calculation tool show that available battery technology is recommendable for energy demands lower than 300 kWh per construction shift. Hydrogen fuel cell technology is an alternative for energy demands higher than 800 kWh. For machinery with energy requirements in between enhancements in battery technology are necessary and desirable for the coming years.
A Comparative Study of CFD-Modelling for Lean Premixed Hydrogen Deflagrations in Large-scale Vented Vessels
Sep 2021
Publication
Hydrogen combustion inside a post-accident nuclear reactor containment may pose a challenge to the containment integrity which could alter the fission-product release source term to the public. Combustion-generated overpressures may be relieved by venting to adjacent compartments through relief panels or existing openings. Thus an improved understanding of the propagation of lean hydrogen deflagrations in inter-connected compartments is essential for the development of appropriate management strategies. GOTHIC is a general purpose lumped parameter thermal-hydraulic code for solving multi-phase compressible flows which is accepted as an industry-standard code for containment safety analyses. Following the Fukushima accident the application of three-dimensional computational fluid dynamics methods to high-fidelity detailed analysis of hydrogen combustion processes has become more widespread. In this study a recently developed large-eddy-simulation (LES) capability is applied to the prediction of lean premixed hydrogen deflagrations in large-scale vented vessels of various configurations. The LES predictions are compared with GOTHIC predictions and experimental data obtained from the large-scale vented combustion test facility at the Canadian Nuclear Laboratories. The LES methodology makes use of a flamelet- or a progress-variable-based combustion model. An empirical burning velocity model is combined with an advanced finite-volume framework and a mesh-independent subfilter-scale model. Descriptions of the LES and GOTHIC modelling approaches used to simulate the hydrogen reactive flows in the vented vessels along with the experimental data sets are given. The potential and limitations of the lumped parameter and LES approaches for accurately describing lean premixed hydrogen deflagrations in vented vessels are discussed.
Recent Combustion Strategies in Gas Turbines for Propulsion and Power Generation toward a Zero-Emissions Future: Fuels, Burners, and Combustion Techniques
Oct 2021
Publication
The effects of climate change and global warming are arising a new awareness on the impact of our daily life. Power generation for transportation and mobility as well as in industry is the main responsible for the greenhouse gas emissions. Indeed currently 80% of the energy is still produced by combustion of fossil fuels; thus great efforts need to be spent to make combustion greener and safer than in the past. For this reason a review of the most recent gas turbines combustion strategy with a focus on fuels combustion techniques and burners is presented here. A new generation of fuels for gas turbines are currently under investigation by the academic community with a specific concern about production and storage. Among them biofuels represent a trustworthy and valuable solution in the next decades during the transition to zero carbon fuels (e.g. hydrogen and ammonia). Promising combustion techniques explored in the past and then abandoned due to their technological complexity are now receiving renewed attention (e.g. MILD PVC) thanks to their effectiveness in improving the efficiency and reducing emissions of standard gas turbine cycles. Finally many advances are illustrated in terms of new burners developed for both aviation and power generation. This overview points out promising solutions for the next generation combustion and opens the way to a fast transition toward zero emissions power generation.
Numerical Simulations of Atmospheric Dispersion of Large-scale Liquid Hydrogen Releases
Sep 2021
Publication
Numerical simulations have been conducted for LH2 massive releases and the subsequent atmospheric dispersion using an in-house modified version of the open source computational fluid dynamics (CFD) code OpenFOAM. A conjugate heat transfer model has been added for heat transfer between the released LH2 and the ground. Appropriate interface boundary conditions are applied to ensure the continuities of temperature and heat fluxes. The significant temperature difference between the cryogenic hydrogen and the ground means that the released LH2 will instantly enter in a boiling state resulting in a hydrogen- air gaseous cloud which will initially behave like a dense gas. Numerical predictions have been conducted for the subsequent atmospheric dispersion of the vaporized LH2 for a series of release scenarios - with and without retention pits - to limit the horizontal spread of the LH2 on the ground. The considered cases included the instantaneous release of 1 10 and 50 tons of LH2 under neutral (D) and stable (F) weather conditions. More specifically 3F and 5D conditions were simulated with the former representing stable weather conditions under wind speed of 3 m/s at 10 m above the ground and the later corresponding to neutral weather conditions under 5 m/s wind speed (10 m above the ground). Specific numerical tests have also been conducted for selected scenarios under different ambient temperatures from 233 up to 313 K. According to the current study although the retention pit can extend the dispersion time it can significantly reduce the extent of hazards due to much smaller cloud size within both the flammability and explosion limits. While the former has negative impact on safety the later is beneficial. The use of retention pit should hence be considered with caution in practical applications.
Stand-off Detection of Hydrogen Concentration
Sep 2021
Publication
The ability to remotely monitor hydrogen and map its concentration is a pressing challenge in large scale production and distribution as well as other sectors such as nuclear storage. We present a photonicsbased approach for the stand-off sensing and mapping of hydrogen concentration capable of detecting and locating <0.1% concentrations at 100m distance. The technique identifies the wavelength of light resulting from interaction with laser pulses via Raman scattering and can identify a range of other gas species e.g. hydrocarbons ammonia by the spectroscopic analysis of the wavelengths present in the return signal. LIDAR Light Detection and Ranging – analogous to Radar is used for ranging. Laserbased techniques for the stand-off detection of hydrocarbons frequently employ absorption of light at specific wavelengths which are characteristic of the gas species. Unfortunately Hydrogen does not exhibit strong absorption however it does exhibit strong Raman scattering when excited in the UV wavelength range. Raman scattering is a comparatively weak effect. However the use of solid-state detectors capable of detecting single photons known as SPADS (Single Photon Avalanche Photodiode) enables the detection of low concentrations at range while making use of precise time-of-flight range location correlation. The initial safety case which necessitated our development of stand-off hydrogen sensing was the condition monitoring of stored nuclear waste supported and funded by Sellafield and the National Nuclear Laboratory in the UK. A deployable version of the device has been developed and hydrogen characterisation has been carried out in an active nuclear store. Prior to deployment a full ignition risk assessment was carried out. To the best of our knowledge this technique is the strongest candidate for the remote stand-off sensing of hydrogen.
Everything About Hydrogen Podcast: Show Me the Money!
Jul 2020
Publication
This week on the show the team catch up with Alena Fargere Principal at SWEN Capital Partners and a former special advisor to the World Energy Council on Hydrogen projects. As one of the few current project finance funds in Europe with a green gas mandate and a dedicated allocation for investing in hydrogen project finance SWEN Capital Partners provide an invaluable perspective on the challenges and opportunities for hydrogen project investment in Europe and the synergies that exist from Green Gas funds that support biogas and hydrogen opportunities. On the show our hosts discuss the rationale for this fund the profile of projects SWEN are considering and Alena’s broader perspective on the hydrogen market. All this and many more themes this week so don’t miss this episode!
The podcast can be found on their website
The podcast can be found on their website
Biological Hydrogen Methanation Systems – An Overview of Design and Efficiency
Oct 2019
Publication
The rise in intermittent renewable electricity production presents a global requirement for energy storage. Biological hydrogen methanation (BHM) facilitates wind and solar energy through the storage of otherwise curtailed or constrained electricity in the form of the gaseous energy vector biomethane. Biological methanation in the circular economy involves the reaction of hydrogen – produced during electrolysis – with carbon dioxide in biogas to produce methane (4H2 + CO2 = CH4 + 2H2) typically increasing the methane output of the biogas system by 70%. In this paper several BHM systems were researched and a compilation of such systems was synthesized facilitating comparison of key parameters such as methane evolution rate (MER) and retention time. Increased retention times were suggested to be related to less efficient systems with long travel paths for gases through reactors. A significant lack of information on gas-liquid transfer co-efficient was identified
Everything About Hydrogen Podcast: Using Hydrogen to Decarbonise Steel Manufacturing
Mar 2022
Publication
Hydrogen could be used in many hard-to-decarbonize sectors. Foremost amongst them is the steel manufacturing industry. On this episode of EAH we speak with Dr. Martin Pei Executive Vice President and CTO of SSAB and the first Chairman of the Board for Hybrit Development AB. SSAB is a global steel company with a leading position in high-strength steels and related services. Together with their partners LKAB and Vattenfall SSAB are making a unique joint effort to change the Swedish iron and steel industry fundamentally. With HYBRIT technology SSAB aims to be the first steel company in the world to bring fossil-free steel to the market already in 2026 and largely eliminate carbon dioxide emissions from the company's own operations as soon as 2030.
The podcast can be found on their website.
The podcast can be found on their website.
Stand-Alone Microgrid with 100% Renewable Energy: A Case Study with Hybrid Solar PV-Battery-Hydrogen
Mar 2020
Publication
A 100% renewable energy-based stand-alone microgrid system can be developed by robust energy storage systems to stabilize the variable and intermittent renewable energy resources. Hydrogen as an energy carrier and energy storage medium has gained enormous interest globally in recent years. Its use in stand-alone or off-grid microgrids for both the urban and rural communities has commenced recently in some locations. Therefore this research evaluates the techno-economic feasibility of renewable energy-based systems using hydrogen as energy storage for a stand-alone/off-grid microgrid. Three case scenarios in a microgrid environment were identified and investigated in order to select an optimum solution for a remote community by considering the energy balance and techno-economic optimization. The “HOMER Pro” energy modelling and simulating software was used to compare the energy balance economics and environmental impact amongst the proposed scenarios. The simulation results showed that the hydrogen-battery hybrid energy storage system is the most cost-effective scenario though all developed scenarios are technically possible and economically comparable in the long run while each has different merits and challenges. It has been shown that the proposed hybrid energy systems have significant potentialities in electrifying remote communities with low energy generation costs as well as a contribution to the reduction of their carbon footprint and to ameliorating the energy crisis to achieve a sustainable future.
Multi-Criteria Comparative Analysis of Clean Hydrogen Production Scenarios
Aug 2020
Publication
Different hydrogen production scenarios need to be compared in regard to multiple and often distinct aspects. It is well known that hydrogen production technologies based on environmentally-friendly renewable energy sources have higher values of the economic indicators than methods based on fossil fuels. Therefore how should this decision criterion (environmental) prevail over the other types of decision criteria (technical and economic) to make a scenario where hydrogen production only uses renewable energy sources the most attractive option for a decision-maker? This article presents the results of a multi-variant comparative analysis of scenarios to annually produce one million tons of pure hydrogen (99.999%) via electrolysis in Poland. The compared variants were found to differ in terms of electricity sources feeding the electrolyzers. The research demonstrated that the scenario where hydrogen production uses energy from photovoltaics only becomes the best option for the environmental criterion weighting value at 61%. Taking the aging effect of photovoltaic installation (PV) panels and electrolyzers after 10 years of operation into account the limit value of the environmental criterion rises to 63%. The carried out analyses may serve as the basis for the creation of systems supporting the development of clean and green hydrogen production technologies.
Decarbonizing the German Industrial Thermal Energy Use with Solar, Hydrogen, and Other Options - Recommendations for the World
Nov 2022
Publication
This paper is based on a position paper of the German Industry Association Concentrated Solar Power e.V. to the German government and discusses options on how to decarbonize the heat demand of the domestic industry. Among other option concentration solar collectors are a suitable option in Germany which has not been expected by many experts. The paper derives requirements that are needed to ensure a quick and sustainable way to decarbonize industrial heat demand. They are considered to also be relevant for many other countries that follow the same ambition to become climate neutral in the next decades. They major statements are: A mix of different renewable energy technologies in conjunction with efficiency measures is needed to ensure a secure climate-friendly and cost-efficient heat supply for the industry; The different technology options for the provision of heat from renewable sources through electrification and through hydrogen can and must be combined and integrated with each other. In this context concentrating solar thermal represents an important part of the hybrid supply portfolio of a decarbonized industry This requires: The definition of an expansion target for process heat and the flanking measures; Ensuring the equivalence of renewable heat renewable electricity and green hydrogen - also as hybrid solutions; The promotion of concentrating solar thermal reference projects as an impetus for market ramp-up in Germany; The launch of an information campaign for heat consumers and the establishment of a pool of consultants.
Seasonal Storage and Alternative Carriers: A Flexible Hydrogen Supply Chain Model
May 2017
Publication
A viable hydrogen infrastructure is one of the main challenges for fuel cells in mobile applications. Several studies have investigated the most cost-efficient hydrogen supply chain structure with a focus on hydrogen transportation. However supply chain models based on hydrogen produced by electrolysis require additional seasonal hydrogen storage capacity to close the gap between fluctuation in renewable generation from surplus electricity and fuelling station demand. To address this issue we developed a model that draws on and extends approaches in the literature with respect to long-term storage. Thus we analyse Liquid Organic Hydrogen Carriers (LOHC) and show their potential impact on future hydrogen mobility. We demonstrate that LOHC-based pathways are highly promising especially for smaller-scale hydrogen demand and if storage in salt caverns remains uncompetitive but emit more greenhouse gases (GHG) than other gaseous or hydrogen ones. Liquid hydrogen as a seasonal storage medium offers no advantage compared to LOHC or cavern storage since lower electricity prices for flexible operation cannot balance the investment costs of liquefaction plants. A well-to-wheel analysis indicates that all investigated pathways have less than 30% GHG-emissions compared to conventional fossil fuel pathways within a European framework.
Energy Transition on Sifnos: An Approach to Economic and Social Transition and Development
Mar 2022
Publication
This article aims to present the potential of energy transition in insular systems for social and economic transition and development when planned and implemented appropriately with the active involvement of local communities. To this end the example of Sifnos Energy Community is examined and presented as a pilot case. It proves that energy transition apart from its obvious energy conservation and climate necessity can provide a strong contribution to the development of remote areas and the remedying of crucial issues especially in insular communities such as unemployment low standards of living isolation and energy supply security. Energy transition on Sifnos has been undertaken by the Sifnos Energy Community (SEC) with the target to achieve 100% energy independency through effective and rational projects. The major project is a centralized hybrid power plant consisting of a wind park and a pumped hydro storage system. It was designed to fully cover the current electricity demand and the anticipated forthcoming load due to the overall transition to e-mobility for the transportation sector on the island. Through the exploitation of the excess electricity production with the production of potable water and hydrogen energy transition can facilitate the development of new professional activities on the island and reduce the local economy’s dependence on tourism. Additionally a daily link to the neighboring larger Cyclades islands can be established with a hydrogen powered-passenger vessel ensuring the secure and cheap overseas transportation connection of Sifnos throughout the whole year. The overall energy transition process is executed with the active involvement of the Sifnos citizens ensuring wide public acceptance and the minimization of the projects’ impacts on the natural and human environment. At the same time the anticipated benefits for the insular communities are maximized highlighting the energy transition process on Sifnos as a new sustainable development pattern. For all this effort and the already achieved results Sifnos has been declared as one of the six pilot islands of the European Community’s initiative “Clean Energy for EU Islands”.
Review on the Safe Use of Ammonia Fuel Cells in the Maritime Industry
May 2021
Publication
In April 2018 the International Maritime Organisation adopted an ambitious plan to contribute to the global efforts to reduce the Greenhouse Gas emissions as set by the Paris Agreement by targeting a 50% reduction in shipping’s Green House Gas emissions by 2050 benchmarked to 2008 levels. To meet these challenging goals the maritime industry must introduce environmentally friendly fuels with negligible or low SOX NOX and CO2 emissions. Ammonia use in maritime applications is considered promising due to its high energy density low flammability easy storage and low production cost. Moreover ammonia can be used as fuel in a variety of propulsors such as fuel cells and can be produced from renewable sources. As a result ammonia can be used as a versatile marine fuel exploiting the existing infrastructure and having zero SOX and CO2 emissions. However there are several challenges to overcome for ammonia to become a compelling fuel towards the decarbonisation of shipping. Such factors include the selection of the appropriate ammonia-fuelled power generator the selection of the appropriate system safety assessment tool and mitigating measures to address the hazards of ammonia. This paper discusses the state-of-the-art of ammonia fuelled fuel cells for marine applications and presents their potential and challenges.
New Combustion Modelling Approach for Methane-Hydrogen Fueled Engines Using Machine Learning and Engine Virtualization
Oct 2021
Publication
The achievement of a carbon-free emissions economy is one of the main goals to reduce climate change and its negative effects. Scientists and technological improvements have followed this trend improving efficiency and reducing carbon and other compounds that foment climate change. Since the main contributor of these emissions is transportation detaching this sector from fossil fuels is a necessary step towards an environmentally friendly future. Therefore an evaluation of alternative fuels will be needed to find a suitable replacement for traditional fossil-based fuels. In this scenario hydrogen appears as a possible solution. However the existence of the drawbacks associated with the application of H2 -ICE redirects the solution to dual-fuel strategies which consist of mixing different fuels to reduce negative aspects of their separate use while enhancing the benefits. In this work a new combustion modelling approach based on machine learning (ML) modeling is proposed for predicting the burning rate of different mixtures of methane (CH4 ) and hydrogen (H2). Laminar flame speed calculations have been performed to train the ML model finding a faster way to obtain good results in comparison with actual models applied to SI engines in the virtual engine model framework.
Decarbonizing Natural Gas: A Review of Catalytic Decomposition and Carbon Formation Mechanisms
Apr 2022
Publication
In the context of energy conservation and the reduction of CO2 emissions inconsistencies between the inevitable emission of CO2 in traditional hydrogen production methods and eco-friendly targets have become more apparent over time. The catalytic decomposition of methane (CDM) is a novel technology capable of producing hydrogen without releasing CO2 . Since hydrogen produced via CDM is neither blue nor green the term “turquoise” is selected to describe this technology. Notably the by-products of methane cracking are simply carbon deposits with different structures which can offset the cost of hydrogen production cost should they be harvested. However the encapsulation of catalysts by such carbon deposits reduces the contact area between said catalysts and methane throughout the CDM process thereby rendering the continuous production of hydrogen impossible. This paper mainly covers the CDM reaction mechanisms of the three common metal-based catalysts (Ni Co Fe) from experimental and modelling approaches. The by-products of carbon modality and the key parameters that affect the carbon formation mechanisms are also discussed.
A Positive Shift in the Public Acceptability of a Low-Carbon Energy Project After Implementation: The Case of a Hydrogen Fuel Station
Apr 2019
Publication
Public acceptability of low-carbon energy projects is often measured with one-off polls. This implies that opinion-shifts over time are not always taken into consideration by decision makers relying on these polls. Observations have given the impression that public acceptability of energy projects increases after implementation. However this positive shift over time has not yet been systematically studied and is not yet understood very well. This paper aims to fill this gap. Based on two psychological mechanisms loss aversion and cognitive dissonance reduction we hypothesize that specifically people who live in proximity of a risky low-carbon technology—a hydrogen fuel station (HFS) in this case—evaluate this technology as more positive after its implementation than before. We conducted a survey among Dutch citizen living nearby a HFS and indeed found a positive shift in the overall evaluation of HFS after implementation. We also found that the benefits weighed stronger and the risks weaker after the implementation. This shift did not occur for citizens living further away from the HFS. The perceived risks and benefits did not significantly change after implementation neither for citizens living in proximity nor for citizens living further away. The societal implications of the findings are discussed.
Everything About Hydrogen Podcast: Ending on a Hy Note
Jul 2021
Publication
This week's show is the last episode of Season 2! To celebrate we invited our friend and colleague Markus Wilthaner partner at McKinsey & Company to come speak with us. Markus has been a leader in the hydrogen space for the past ten years and has drafted a number of the Hydrogen Council's reports since its founding including the newly released - and highly anticipated - Hydrogen Insights 2021 (link below). In this episode we speak with Markus about the state of the market and the innovation he has seen in the last couple of years that make hydrogen a critical part of the energy transition. We had a lot of fun recording this interview and it was the perfect way to end a fantastic EAH season!
The podcast can be found on their website
The podcast can be found on their website
Hydrogen Separation and Purification from Various Gas Mixtures by Means of Electrochemical Membrane Technology in the Temperature Range 100–160 ◦C
Apr 2021
Publication
This paper reports on an experimental evaluation of the hydrogen separation performance in a proton exchange membrane system with Pt-Co/C as the anode electrocatalyst. The recovery of hydrogen from H2/CO2 H2/CH4 and H2/NH3 gas mixtures were determined in the temperature range of 100–160 ◦C. The effects of both the impurity concentration and cell temperature on the separation performance of the cell and membrane were further examined. The electrochemical properties and performance of the cell were determined by means of polarization curves limiting current density open-circuit voltage hydrogen permeability hydrogen selectivity hydrogen purity and cell efficiencies (current voltage and power efficiencies) as performance parameters. High purity hydrogen (>99.9%) was obtained from a low purity feed (20% H2 ) after hydrogen was separated from H2/CH4 mixtures. Hydrogen purities of 98–99.5% and 96–99.5% were achieved for 10% and 50% CO2 in the feed respectively. Moreover the use of proton exchange membranes for electrochemical hydrogen separation was unsuccessful in separating hydrogen-rich streams containing NH3 ; the membrane underwent irreversible damage.
A Review of Hydrogen Direct Injection for Internal Combustion Engines: Towards Carbon-Free Combustion
Nov 2018
Publication
A paradigm shift towards the utilization of carbon-neutral and low emission fuels is necessary in the internal combustion engine industry to fulfil the carbon emission goals and future legislation requirements in many countries. Hydrogen as an energy carrier and main fuel is a promising option due to its carbon-free content wide flammability limits and fast flame speeds. For spark-ignited internal combustion engines utilizing hydrogen direct injection has been proven to achieve high engine power output and efficiency with low emissions. This review provides an overview of the current development and understanding of hydrogen use in internal combustion engines that are usually spark ignited under various engine operation modes and strategies. This paper then proceeds to outline the gaps in current knowledge along with better potential strategies and technologies that could be adopted for hydrogen direct injection in the context of compression-ignition engine applications—topics that have not yet been extensively explored to date with hydrogen but have shown advantages with compressed natural gas.
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