United Kingdom
NanoSIMS Analysis of Hydrogen and Deuterium in Metallic Alloys: Artefacts and Best Practice
Apr 2021
Publication
Hydrogen embrittlement can cause catastrophic failure of high strength alloys yet determining localised hydrogen in the microstructure is analytically challenging. NanoSIMS is one of the few techniques that can map hydrogen and deuterium in metal samples at microstructurally relevant length scales. Therefore it is essential to understand the artefacts and determine the optimum methodology for its reliable detection. An experimental methodology/protocol for NanoSIMS analysis of deuterium (as a proxy for hydrogen) has been established uncovering unreported artefacts and a new approach is presented to minimise these artefacts in mapping hydrogen and deuterium in alloys. This method was used to map deuterium distributions in electrochemically charged austenitic stainless steel and precipitation hardened nickel-based alloys. Residual deuterium contamination was detected in the analysis chamber as a result of deuterium outgassing from the samples and the impact of this deuterium contamination was assessed by a series of NanoSIMS experiments. A new analysis protocol was developed that involves mapping deuterium in the passive oxide layer thus mitigating beam damage effects that may prevent the detection of localised deuterium signals when the surface is highly deuterated.
Investigation into the Cross-sensitivity of Domestic Carbon Monoxide Alarms to Hydrogen
Sep 2021
Publication
Preliminary research suggests domestic carbon monoxide detectors with an electrochemical sensor are approximately 10 -20% sensitive to hydrogen atmospheres in their factory configuration. That is the display on a carbon monoxide detector would give a carbon monoxide reading of approximately 10-20% of the concentration of hydrogen it is exposed to. Current British standards require detectors to sound an alarm within three minutes when subjected to a continuous concentration of ≥ 300 ppm CO. This would equate to a concentration of 1500-3000 ppm hydrogen in air or approximately 3.75 – 7% %LEL. The current evacuation criteria for a natural gas leak in a domestic property is 20 %LEL indicating that standard carbon monoxide detectors could be used as cheap and reliable early warning systems for hydrogen leaks. Given the wide use of carbon monoxide detectors and the affordability of the devices the use of carbon monoxide detectors for hydrogen detection is of particular interest as the UK drives towards energy decarbonisation. Experiments to determine the exact sensitivity of a range of the most common domestic carbon monoxide detectors have been completed by DNV Spadeadam Research & Testing. Determining the effects of repeated exposure to varying concentrations of hydrogen in air on the sensitivity of electrochemical sensors allows recommendations to be made on their adoption as hydrogen detectors. Changing the catalysts used within the electrochemical cell would improve the sensitivity to hydrogen however simply calibrating the sensor to report a concentration of hydrogen rather than carbon monoxide would represent no additional costs to manufacturers. Having determined the suitability of such sensors at an early stage; the technology can then be linked with other technological developments required for the change to hydrogen for domestic heating (e.g. change in metering equipment and appliances). This report finds that from five simple and widely available carbon monoxide detectors the lowest sensitivity to hydrogen measured at the concentration required to sound an alarm within three minutes was approximately 10%. It was also discovered that as the hydrogen concentration was increased over the range tested the sensitivity to hydrogen also increased. It is proposed that coupling these devices with other elements of the domestic gas system would allow actions such as remote meter isolation or automatic warning signals sent to response services would provide a reliable and inherently safe system for protecting occupants as gas networks transition to net-zero greenhouse gas emissions. In this respect it is noted that wireless linking of smoke and heat detectors for domestic application is already widely available in low-cost devices. This could be extended to CO detectors adapted for hydrogen use.
Hydrogen Power Focus Shifts from Cars to Heavy Vehicles
Oct 2020
Publication
Hydrogen has been hailed as a promising energy carrier for decades. But compared to the thriving success of hybrid and plug-in electric cars the prospects for cars powered by hydrogen fuel cells have recently diminished mostly due to challenges in bringing down the costs of fuel cells and developing a broad network of fuelling stations.<br/>Beginning in March 2020 three major auto manufacturers—Daimler AG] Volkswagen and General Motors (GM)]—followed the April 2019 move by Honda to back out of the hydrogen-powered passenger car market. Instead these companies and others are looking to develop the technology as an emission-free solution to power heavy commercial and military vehicles with refuelling taking place at centralized locations.
Hydrogen/Manganese Hybrid Redox Flow Battery
Dec 2018
Publication
Electrochemical energy storage is a key enabling technology for further integration of renewables sources. Redox flow batteries(RFBs) are promising candidates for such applications as a result of their durability efficiency and fast response. However deployment of existing RFBs is hindered by the relatively high cost of the (typically vanadium-based) electrolyte. Manganese is an earth-abundant and inexpensive element that is widely used in disposable alkaline batteries. However it has hitherto been little explored for RFBs due to the instability of Mn(III) leading to precipitation of MnO2 via a disproportionation reaction. Here we show that by combining the facile hydrogen negative electrode reaction with electrolytes that suppress Mn(III) disproportionation it is possible to construct a hydrogen/manganese hybrid RFB with high round trip energy efficiency (82%) and high power and energy density (1410 mW cm−2 33 Wh l−1 ) at an estimated 70% cost reduction compared to vanadium redox flow batteries.
Fuel Cell Power Systems for Maritime Applications: Progress and Perspectives
Jan 2021
Publication
Fuel cells as clean power sources are very attractive for the maritime sector which is committed to sustainability and reducing greenhouse gas and atmospheric pollutant emissions from ships. This paper presents a technological review on fuel cell power systems for maritime applications from the past two decades. The available fuels including hydrogen ammonia renewable methane and methanol for fuel cells under the context of sustainable maritime transportation and their pre-processing technologies are analyzed. Proton exchange membrane molten carbonate and solid oxide fuel cells are found to be the most promising options for maritime applications once energy efficiency power capacity and sensitivity to fuel impurities are considered. The types layouts and characteristics of fuel cell modules are summarized based on the existing applications in particular industrial or residential sectors. The various research and demonstration projects of fuel cell power systems in the maritime industry are reviewed and the challenges with regard to power capacity safety reliability durability operability and costs are analyzed. Currently power capacity costs and lifetime of the fuel cell stack are the primary barriers. Coupling with batteries modularization mass production and optimized operating and control strategies are all important pathways to improve the performance of fuel cell power systems.
Hy4Heat Safety Assessment: Conclusions Report (Incorporating Quantitative Risk Assessment) - Work Package 7
May 2021
Publication
The Hy4Heat Safety Assessment has focused on assessing the safe use of hydrogen gas in certain types of domestic properties and buildings. The summary reports (the Precis and the Safety Assessment Conclusions Report) bring together all the findings of the work and should be looked to for context by all readers. The technical reports should be read in conjunction with the summary reports. While the summary reports are made as accessible as possible for general readers the technical reports may be most accessible for readers with a degree of technical subject matter understanding. All of the safety assessment reports have now been reviewed by the HSE.<br/><br/>A comparative risk assessment of natural gas versus hydrogen gas including a quantitative risk assessment; and identification of control measures to reduce risk and manage hydrogen gas safety for a community demonstration.
Modelling of Boil‐Off and Sloshing Relevant to Future Liquid Hydrogen Carriers
Mar 2022
Publication
This study presents an approach for estimating fuel boil‐off behaviour in cryogenic energy carrier ships such as future liquid hydrogen (LH2) carriers. By relying on thermodynamic model‐ ling and empirical formulas for ship motion and propulsion the approach can be used to investigate boil‐off as a function of tank properties weather conditions and operating velocities during a laden voyage. The model is first calibrated against data from a liquefied natural gas (LNG) carrier and is consequently used to investigate various design configurations of an LH2 ship. Results indicate that an LH2 ship with the same tank volume and glass wool insulation thickness as a conventional LNG carrier stores 40% of the fuel energy and is characterised by a boil‐off rate nine times higher and twice as sensitive to sloshing. Adding a reliquefaction unit can reduce the LH2 fuel depletion rate by at least 38.7% but can increase its variability regarding velocity and weather conditions. In calm weather LH2 boil‐off rates can only meet LNG carrier standards by utilising at least 6.6 times the insulation thickness. By adopting fuel cell propulsion in an LH2 ship a 1.1% increase in fuel delivery is expected. An LH2 ship with fuel cells and reliquefaction is required to be at least 1.7 times larger than an existing LNG carrierto deliverthe same energy. Further comparison of alternative scenarios indicates that LH2 carriers necessitate significant redesigns if LNG carrier standards are desired. The present approach can assist future feasibility studies featuring other vessels and propulsion technologies and can be seen as an extendable framework that can predict boil‐off in real‐time.
Preliminary Analysis of Compression System Integrated Heat Management Concepts Using LH2-Based Parametric Gas Turbine Model
Apr 2021
Publication
The investigation of the various heat management concepts using LH2 requires the development of a modeling environment coupling the cryogenic hydrogen fuel system with turbofan performance. This paper presents a numerical framework to model hydrogen-fueled gas turbine engines with a dedicated heat-management system complemented by an introductory analysis of the impact of using LH2 to precool and intercool in the compression system. The propulsion installations comprise Brayton cycle-based turbofans and first assessments are made on how to use the hydrogen as a heat sink integrated into the compression system. Conceptual tubular compact heat exchanger designs are explored to either precool or intercool the compression system and preheat the fuel to improve the installed performance of the propulsion cycles. The precooler and the intercooler show up to 0.3% improved specific fuel consumption for heat exchanger effectiveness in the range 0.5–0.6 but higher effectiveness designs incur disproportionately higher pressure losses that cancel-out the benefits.
Methodologies for Representing the Road Transport Sector in Energy System Models
Dec 2013
Publication
Energy system models are often used to assess the potential role of hydrogen and electric powertrains for reducing transport CO2 emissions in the future. In this paper we review how different energy system models have represented both vehicles and fuel infrastructure in the past and we provide guidelines for their representation in the future. In particular we identify three key modelling decisions: the degree of car market segmentation the imposition of market share constraints and the use of lumpy investments to represent infrastructure. We examine each of these decisions in a case study using the UK MARKAL model. While disaggregating the car market principally affects only the transition rate to the optimum mix of technologies market share constraints can greatly change the optimum mix so should be chosen carefully. In contrast modelling infrastructure using lumpy investments has little impact on the model results. We identify the development of new methodologies to represent the impact of behavioural change on transport demand as a key challenge for improving energy system models in the future.
Climate Change Committee: Progress in Reducing Emissions, 2022 Report to Parliament
Jun 2022
Publication
This statutory report provides a comprehensive overview of the UK Government’s progress to date in reducing emissions. It is accompanied by a new Monitoring Framework which details the CCC’s updated approach to tracking real-world progress through a host of new indicators.<br/>This is a pivotal point in the UK’s journey to Net Zero. The UK is one of the few countries with emissions targets in line with the long-term temperature goal of the Paris Agreement. Policy ambition has moved substantially with the publication of the UK’s Net Zero Strategy. Now is the time to deliver the promised action.
Conversion of the UK Gas System to Transport Hydrogen
May 2013
Publication
One option to decarbonise residential heat in the UK is to convert the existing natural gas networks to deliver hydrogen. We review the technical feasibility of this option using semistructured interviews underpinned by a literature review and we assess the potential economic benefits using the UK MARKAL energy systems model. We conclude that hydrogen can be transported safely in the low-pressure pipes but we identify concerns over the reduced capacity of the system and the much lower linepack storage compared to natural gas. New hydrogen meters and sensors would have to be fitted to every building in a hydrogen conversion program and appliances would have to be converted unless the government was to legislate to make them hydrogen-ready in advance. Converting the gas networks to hydrogen is a lower-cost residential decarbonisation pathway for the UK than those identified previously. The cost-optimal share of hydrogen is sensitive to the conversion cost and to variations in the capital costs of heat pumps and micro-CHP fuel cells. With such small cost differentials between technologies the decision to convert the networks will also depend on non-economic factors including the relative performance of technologies and the willingness of the government to organise a conversion program.
Hydrogen Generation on Orkney: Integrating Established Risk Management Best Practice to Emerging Clean Energy Sector
Sep 2021
Publication
The European Marine Energy Centre’s (EMEC) ITEG project (Integrating Tidal Energy into the European Grid) funded by Interreg NWE combines a tidal energy and hydrogen production solution to address grid constraints on the island of Eday in Orkney. The project will install a 0.5MW electrolyser at EMEC’s existing hydrogen production plant. EMEC and Risktec collaboratively applied best practice risk assessment and management techniques to assess and manage hydrogen safety. Hazard identification (HAZID) workshops were conducted collaboratively with design engineers through which a comprehensive hazard register was developed. Risktec applied bowtie analysis to each major accident hazard identified from the hazard register via virtual workshop with design engineers. The bowties promoted a structured review of each hazard’s threat and consequence identifying and reviewing the controls in place against good practice standards. The process revealed some recommendations for further improvement and risk reduction exemplifying a systematic management of risks associated with hydrogen hazards to as low as reasonably practicable (ALARP). Hardware based barriers preventing or mitigating loss of control of these hazards were logged as safety critical elements (SCE) and procedural barriers as safety critical activities (SCA). To ensure that all SCEs and SCAs identified through the risk assessment process are managed throughout the facility’s operational lifetime a safety management system is created giving assurance of overall safety management system continued effectiveness. The process enables the demonstration that design risks are managed to ALARP during design and throughout operational lifetime. More importantly enabling ITEG to progress to construction and operation in 2021.
Characterisation, Dispersion and Electrostatic Hazards of Liquid Hydrogen for the PRESLHY Project
Sep 2021
Publication
Liquid hydrogen has the potential to form part of the energy strategy in the future due to the need to decarbonise and replace fossil fuels and therefore could see widespread use. Adoption of LH2 means that the associated hazards need to be understood and managed. In recognition of this the European Union Fuel Cells and Hydrogen Joint Undertaking co-funded project PRESLHY undertook prenormative research for the safe use of cryogenic liquid hydrogen in non-industrial settings. Several key scenarios were identified as knowledge gaps and both theoretical and experimental studies were conducted to provide insight into these scenarios. This included experiments studying the evolution/dispersion of a hydrogen cloud following a liquid release and the generation of electrostatic charges in hydrogen plumes and pipework each of which are described and discussed. In addition assessment of the physical phase of the hydrogen flow within the pipework (i.e. liquid gas or two phase) was investigated. The objectives experimental set up and result summary are provided. Data generated from these experiments is to be used to generate and validate theoretical models and ultimately contribute to the development of regulations codes and standards for the storage handling and use of liquid hydrogen.
UK Low Carbon Hydrogen Standard: Guidance on the Greenhouse Gas Emissions and Sustainability Criteria
Apr 2022
Publication
The Low Carbon Hydrogen Standard sets a maximum threshold for the amount of greenhouse gas emissions allowed in the production process for hydrogen to be considered ‘low carbon hydrogen’. Compliance with the standard will help ensure new low carbon hydrogen production makes a direct contribution to our carbon reduction targets.
This guidance sets out the methodology for calculating the emissions associated with hydrogen production and the steps producers should take to prove that the hydrogen they produce is compliant with the standard.
It is for use by hydrogen producers seeking support from government schemes and policies that have adopted the standard.
The standard requires hydrogen producers to:
This guidance sets out the methodology for calculating the emissions associated with hydrogen production and the steps producers should take to prove that the hydrogen they produce is compliant with the standard.
It is for use by hydrogen producers seeking support from government schemes and policies that have adopted the standard.
The standard requires hydrogen producers to:
- meet a GHG emissions intensity of 20g CO2e/MJLHV of produced hydrogen or less for the hydrogen to be considered low carbon
- calculate their greenhouse gas (GHG) emissions up to the ‘point of production’
- set out a risk mitigation plan for fugitive hydrogen emissions
- meet additional requirements for the use of biogenic inputs where relevant and as appropriate for the feedstock source and classification
Comparative Sustainability Study of Energy Storage Technologies Using Data Envelopment Analysis
Mar 2022
Publication
The transition to energy systems with a high share of renewable energy depends on the availability of technologies that can connect the physical distances or bridge the time differences between the energy supply and demand points. This study focuses on energy storage technologies due to their expected role in liberating the energy sector from fossil fuels and facilitating the penetration of intermittent renewable sources. The performance of 27 energy storage alternatives is compared considering sustainability aspects by means of data envelopment analysis. To this end storage alternatives are first classified into two clusters: fast-response and long-term. The levelized cost of energy energy and water consumption global warming potential and employment are common indicators considered for both clusters while energy density is used only for fast-response technologies where it plays a key role in technology selection. Flywheel reveals the highest efficiency between all the fast-response technologies while green ammonia powered with solar energy ranks first for long-term energy storage. An uncertainty analysis is incorporated to discuss the reliability of the results. Overall results obtained and guidelines provided can be helpful for both decision-making and research and development purposes. For the former we identify the most appealing energy storage options to be promoted while for the latter we report quantitative improvement targets that would make inefficient technologies competitive if attained. This contribution paves the way for more comprehensive studies in the context of energy storage by presenting a powerful framework for comparing options according to multiple sustainability indicators.
Optimising Air Quality Co-benefits in a Hydrogen Economy: A Case for Hydrogen-specific Standards for NOx Emissions
Jun 2021
Publication
A global transition to hydrogen fuel offers major opportunities to decarbonise a range of different energyintensive sectors from large-scale electricity generation through to heating in homes. Hydrogen can be deployed as an energy source in two distinct ways in electrochemical fuel cells and via combustion. Combustion seems likely to be a major pathway given that it requires only incremental technological change. The use of hydrogen is not however without side-effects and the widely claimed benefit that only water is released as a by-product is only accurate when it is used in fuel cells. The burning of hydrogen can lead to the thermal formation of nitrogen oxides (NOx – the sum of NO + NO2) via a mechanism that also applies to the combustion of fossil fuels. NO2 is a key air pollutant that is harmful in its own right and is a precursor to other pollutants of concern such as fine particulate matter and ozone. Minimising NOx as a by-product from hydrogen boilers and engines is possible through control of combustion conditions but this can lead to reduced power output and performance. After-treatment and removal of NOx is possible but this increases cost and complexity in appliances. Combustion applications therefore require optimisation and potentially lower hydrogen-specific emissions standards if the greatest air quality benefits are to derive from a growth in hydrogen use
Thermodynamic Performance and Creep Life Assessment Comparing Hydrogen- and Jet-Fueled Turbofan Aero Engine
Apr 2021
Publication
There is renewed interest in hydrogen as an alternative fuel for aero engines due to their perceived environmental and performance benefits compared to jet fuel. This paper presents a cycle thermal performance energy and creep life assessment of hydrogen compared with jet fuel using a turbofan aero engine. The turbofan cycle performance was simulated using a code developed by the authors that allows hydrogen and jet fuel to be selected as fuel input. The exergy assessment uses both conservations of energy and mass and the second law of thermodynamics to understand the impact of the fuels on the exergy destruction exergy efficiency waste factor ratio environmental effect factor and sustainability index for a turbofan aero engine. Finally the study looks at a top-level creep life assessment on the high-pressure turbine hot section influenced by the fuel heating values. This study shows performance (64% reduced fuel flow rate better SFC) and more extended blade life (15% increase) benefits using liquefied hydrogen fuel which corresponds with other literary work on the benefits of LH2 over jet fuel. This paper also highlights some drawbacks of hydrogen fuel based on previous research work and gives recommendations for future work aimed at maturing the hydrogen fuel concept in aviation.
HyDeploy Report: Summary of European Hydrogen Blending Projects
Jun 2018
Publication
Across Europe permitted blend levels of hydrogen blending into the gas grid are appreciably higher than that currently permitted in the UK up to 12% mol/mol compared with 0.1% mol/mol. Whilst there is some routine blending undertaking – typically power to gas applications three major projects have been undertaken to demonstrate operation of a gas distribution network at higher blend levels of hydrogen.<br/>A Dutch project was completed in 2011 which demonstrated successful operation into a network with new appliances at 20% mol/mol. A German project was completed in 2015 which demonstrated successful operation into an existing gas network with existing appliances at their permitted level of 10% mol/mol. In France an extensive programme is underway to inject hydrogen into a network at 20% mol/mol due to commence injection in 2018.<br/>Each of these projects undertook extensive pre-trial activities and operational data was collected during the Dutch and German trials. The programme of pre-trial work for the French project was particularly extensive and mirrored the work done by HyDeploy. This led to a permit being granted for the French project at 20% mol/mol with injection into the network imminent.<br/>The HyDeploy team has engaged with each of the project teams who have been very co-operative; this has enabled scientific sharing of best practice. In all cases the projects were successful. The participants in the Dutch project were particularly keen to have been able to undertake a similar trial to HyDeploy; a larger trial into existing appliances. However political changes in Holland have precluded that at this time such progress was not limited by technical findings from the work.<br/>A high level overview of the projects and the data provided is summarised in this report. More detailed information is referenced and covered in more detail where required in the appropriate individual topic reports supporting the Exemption.<br/>Click on supplements tab to view the other documents from this report
Reference Standard for Low Pressure Hydrogen Utilisation
May 2021
Publication
This standard has been created for the specific purposes of the Hy4Heat programme. The standard was commissioned in 2018 and this version was considered and approved by the relevant IGEM committees in May of 2020. This version of the standard was developed using the latest publicly available information at that time and may include some conservative requirements which further research may deem not necessary. The supplement will be updated regularly following the publication of new research into the application of hydrogen.
This Reference Standard aims to identify and discuss the principles required for the safety and integrity of Hydrogen installation and utilisation in premises.
This document intends to:
The standard is available to download through the IGEM website here.
This Reference Standard aims to identify and discuss the principles required for the safety and integrity of Hydrogen installation and utilisation in premises.
This document intends to:
- provide a point of reference for those requiring an understanding of the implications of using hydrogen as a distributed gas in properties
- detail the characteristics of Hydrogen
- detail the comparisons between hydrogen and Natural Gas (NG)
- discuss the safety implications of using hydrogen
- discuss the implications for materials when using hydrogen
- discuss the implications for the installation and use of using hydrogen in domestic & smaller commercial buildings.
The standard is available to download through the IGEM website here.
Review of IGEM/SR/25 for Use with Hydrogen
Jan 2021
Publication
This report presents the findings of the initial gap analysis and technical review of IGEM/SR/25 undertaken as a collaborative effort between HSE and DNV GL. The review is intended to help understand the steps which would be involved in updating the standard to include data appropriate for installations using H2 or an H2/NG blend. Furthermore the report highlights where additional research and updated data applicable to H2 installations is needed to enable development of an H2-specific supplement to the standard.<br/>A review of alternative approaches for area classification is presented. This review is aimed at determining whether existing standards or guidance provide methodologies which could be used as an alternative to IGEM/SR/25 for area classification of systems using either H2 or H2/NG blends. The review covers IGEM/SR/25 IGE/SR/23 EI15 BCGA guidance BS EN 60079:10:1 (including Quadvent) NFPA 497 API RP 505 and EIGA Doc. 121/14. Some of these are general like the British Standard BS EN 60079-10-1:2015 while others are industry specific like IGEM/SR/25 and EI15.<br/>Consideration is given to the methodology that each area classification approach presents for establishing the zone and zone size with particular focus on how factors such as ventilation and gas buoyancy are accounted for in the methods. The findings of the review indicate that none of the alternative approaches evaluated in the study provide an approach that is suitable for the gas industry for the area classification of gas network installations involving H2 or an H2/NG blend.
Decarbonising UK Transport: Implications for Electricity Generation, Land Use and Policy
Dec 2022
Publication
To ensure the UK’s net zero targets are met the transition from conventionally fueled transport to low emission alternatives is necessary. The impact from increased decarbonised electricity generation on ecosystem services (ES) and natural capital (NC) are not currently quantified with decarbonisation required to minimise impacts from climate change. This study aims to project the future electric and hydrogen energy demand between 2020 and 2050 for car bus and train to better understand the land/sea area that would be required to support energy generation. In this work predictions of the geospatial impact of renewable energy (onshore/offshore wind and solar) nuclear and fossil fuels on ES and NC were made considering generation mix number of generation installations and energy density. Results show that electric transport will require ~136599 GWh for all vehicle types analysed in 2050 much less than hydrogen transport at ~425532 GWh. We estimate that to power electric transport at least 1515 km2 will be required for solar 1672 km2 for wind and 5 km2 for nuclear. Hydrogen approximately doubles this requirement. Results provide an approximation of the future demands from the transport sector on land and sea area use indicating that a combined electric and hydrogen network will be needed to accommodate a range of socio-economic requirements. While robust assessments of ES and NC impacts are critical in future policies and planning significant reductions in energy demands through a modal shift to (low emission) public transport will be most effective in ensuring a sustainable transport future.
Mitigation of CO Poisoning Hazard in Malfunctioning Gas Appliances Through Use of Hydrogen Blended Gas
Sep 2021
Publication
The HyDeploy project [1] has undertaken an extensive research programme to assess safety and performance of the existing UK gas appliances population fueled with natural gas / hydrogen admixtures (hydrogen blended gas). The first stage of this work [2] focused on well maintained and normally functioning appliances. This work demonstrated that unmodified gas appliances can operate safely with hydrogen blended gas (up to 20 vol% hydrogen) and the key hazard areas of carbon monoxide (CO) production light back and flame out and the operation of flame failure devices are unaffected. It is widely recognized that due to aging and variable degrees of maintenance that the combustion performance of a gas appliance will depreciate over time. In extreme cases this can lead to situations where high levels of CO may be released back into the dwelling resulting in CO poisoning to the occupants. To obtain a universal appreciation of the effect of hydrogen addition on the safety and performance of all gas appliances operation under sub optimal conditions is required and therefore it is important that the operation of malfunctioning appliances fuelled with hydrogen blended gas is assessed. A review of failure modes identified six key scenarios where the composition of the fuel gas may lead to changes in safety performance - these primarily related to the resulting composition of the flue gas but also included delayed ignition. Gas appliance faults that will increase the CO production were tested through a series of experiments to simulate fault conditions and assess the effect of hydrogen blended gas. The fault modes examined included linting flame chilling incorrect appliance set up and modification of gas valve operation. The programme utilized six different appliances tested with three methane-hydrogen fuel blends (containing 0 20 and 28.4 vol% hydrogen). In all cases the switch to hydrogen blended gas reduced CO production. The change in CO production when using hydrogen blended gas is a consequence of a decrease in the theoretical air requirement to achieve complete combustion. In some cases the amount of CO produced was identical to the nonfault baseline performance on methane thereby fully mitigating the consequence of the malfunction. In the case of very high CO production a 90% reduction was recorded when using 20 vol% hydrogen blended gas. In situations such as non-optimal boiler set up the addition of hydrogen to the gas supply would prevent the production of high levels of CO. The findings here together with the results from HyDeploy 1 [2] indicate that the safety and performance of unmodified existing UK gas appliances are not detrimentally affected when using hydrogen blended gas. Furthermore the addition of hydrogen to the fuel gas has been shown to reduce CO production under fault conditions therefore the introduction of hydrogen into the gas network may serve to mitigate the hazard posed by existing faulty appliances that are producing elevated levels of CO.
Regional Insights into Low-carbon Hydrogen Scale Up: World Energy Insights Working Paper
May 2022
Publication
Following the release of the “Hydrogen on the Horizon” series in July and September 2021 the World Energy Council in collaboration with EPRI and PwC led a series of regional deep dives to understand regional differences within low-carbon hydrogen development. These regional deep dives aimed to uncover regional perspectives and differing dynamics for low-carbon hydrogen uptake.<br/>Although each region presents its own distinctive challenges and opportunities the deep dives revealed that the “regional paths” provide new insights into the global scaling up of low-carbon hydrogen in the coming years. In addition each region holds its own unique potential in achieving the Sustainable Development Goals.<br/>Key Takeaways:<br/>1. Our new regional insights indicate that low-carbon hydrogen can play a significant role by 2040 across the world by supporting countries’ efforts towards achieving Paris Agreement goals whilst contributing to the diversity and security of their energy portfolios. This would require significant global trade flows of hydrogen and hydrogen-based fuels.<br/>2. The momentum for hydrogen-based fuels is continuing to grow worldwide but differences are seen between regions – based on differing market activities and opportunities.<br/>3. Today moving from “whether” to “how” to develop low-carbon hydrogen highlights significant uncertainties which need to be addressed if hydrogen is to reach its full potential.<br/>Can the challenges in various supply chain options be overcome?<br/>Can hydrogen play a role in tackling climate change in the short term?<br/>Can bankable projects emerge and the gap between engineers and financers be bridged? Can the stability of supply of the main low-carbon hydrogen production sources be guaranteed?<br/>4. Enabling low-carbon hydrogen at scale would notably require greater coordination and cooperation amongst stakeholders worldwide to better mobilise public and private finance and to shift the focus to end-users and people through the following actions:<br/>Moving from production cost to end-use price<br/>Developing Guarantees of Origin schemes with sustainability requirements<br/>Developing a global monitoring and reporting tool on low-carbon hydrogen projects<br/>Better consideration of social impacts alongside economic opportunities
Catalysing Hydrogen Investment: What the Market Needs to Deliver Investment in Hydrogen Infrastructure
Oct 2021
Publication
Written by Arup in collaboration with the GIIA this report is centred on the opinions of investors from around the world gathered through a survey of GIIA members and in-depth interviews. It therefore presents the sentiments of the world’s leading fund managers insurance investors pension funds and a sovereign wealth fund. Their opinions matter because these are the decision makers that hold the purse strings when it comes to private sector investment in hydrogen infrastructure. Many of the facts about hydrogen are well-known to many readers and these are presented in this report drawing on Arup’s research and experience as a global infrastructure advisory firm. However the novelty of this report is that it looks at hydrogen through the uncompromising eyes of investors with analysis of feedback which identifies barriers to investment in the infrastructure required to enable the hydrogen economy. Perhaps most importantly it also proposes interventions that policymakers and regulators could take to overcome the barriers currently faced.<br/>Introduction The sentiments of investors are at the heart of this study with results from the survey presented at the beginning of each section to serve as a launch pad for Arup’s analysis. But we want it to be more than an interesting read; it is a call to action for policy makers to create the right environment to catalyse private sector investment and kickstart the hydrogen economy.
Impact Assessment of Hydrogen on Transmission Pipeline BPDs in IGEM/TD/1
Jul 2021
Publication
As part of the LTS Futures HyTechnical project IGEM requested that DNV GL undertake an assessment of the possible impact of hydrogen transmission on BPDs to support the development of supplements to the existing suite of natural gas standards to accommodate the possible future use of hydrogen. The current state of knowledge of the behaviour of large scale high pressure hydrogen releases is limited in comparison with the considerable body of data from research and operational experience of natural gas but is adequate to undertake an impact assessment to take account of the different gas outflow and fire characteristics of 100% hydrogen vs. natural gas.<br/>Calculations of the BPDs for 100% hydrogen pipeline fires on an equivalent basis to those in IGEM/TD/1 for natural gas have been performed with a degree of confidence in the results and demonstrated that the equivalent BPDs for 100% hydrogen are approximately 10% smaller than for natural gas. The results are presented graphically in this report.<br/>However hydrogen introduces the potential for substantially higher overpressures than natural gas due to the higher flame speed and wider flammable limits if delayed ignition is a credible event. The overpressure estimates presented in this report are intended to be scoping calculations to put the likely overpressures into context. The results suggest that significant overpressures are possible at the BPDs but there is a lack of evidence to support the estimation of the overpressures following delayed ignition of a large turbulent hydrogen release in the open (in contrast to explosions in confined or congested regions) and there is a high degree of uncertainty in the predictions presented here. It is therefore recommended that large scale pipeline rupture experiments are performed similar to those undertaken previously for hydrogen natural gas and natural gas/hydrogen mixtures but with ignition engineered to take place after a short delay in order to measure the overpressures and provide the means to validate or refine the predictions made.<br/>The analysis has highlighted limitations in the original method of calculating BPDs in IGEM/TD/1 which reflects the techniques available at the time approximately 40 years ago. Since then understanding of the hazards from pipeline failures and the ability to model the consequences and predict the associated risks to people in the surrounding area have advanced very considerably facilitated by software tools and documented in standards such as IGEM/TD/2. These methods allow the highly transient nature of a high pressure gas pipeline rupture release to be modelled more accurately and for the thermal effects of fires on people and buildings to be calculated taking account of the time-varying thermal dose.<br/>For these reasons a simple comparison of the possible overpressure effects of delayed ignition of a 100% hydrogen release at the BPDs can be misleading and implies that the overpressure hazards could be more severe than those for fires which may not be the case. Example calculations have been performed for a representative pipeline case which indicate that using current methods the predicted thermal hazard distances for 100% hydrogen pipeline fires (house burning and escape for people) are substantially greater than those estimated for overpressures following delayed ignition for similar levels of vulnerability. This report addresses buried pipelines only – the potential for more severe explosion overpressure effects for hydrogen releases may be more significant for Above Ground Installations (AGIs) especially where congestion or confinement may be present. It is recommended that similar studies are conducted to quantify the effect of hydrogen conversion on the consequences and risks associated with hydrogen releases at AGIs.<br/>Finally it is stressed that the analysis in this report does not consider the relative risks for 100% hydrogen and the equivalent natural gas pipelines. There remain uncertainties in the failure frequencies for steel pipelines transporting hydrogen and particularly the probability of immediate and delayed ignition. The likelihood of delayed ignition of a large turbulent high pressure hydrogen gas pipeline rupture release may be very low due to the wider flammability limits and lower minimum ignition energy for hydrogen compared with natural gas. Additional research is currently ongoing or planned to address the gaps in knowledge for 100% hydrogen which should allow more robust comparisons of the relative risks to be made in the future.
Hydrogen-electricity Hybrid Energy Pipelines for Railway Transportation: Design and Economic Evaluation
Mar 2024
Publication
With the decarbonization and electrification of modern railway transportation the demand for both the highcapacity electrical energy and hydrogen fuel energy is increasingly high. A novel scheme was proposed from liquid hydrogen production by surplus wind and solar energy to liquid hydrogen-electricity hybrid energy transmission for railway transportation. The 100 MW hybrid energy transmission pipeline was designed with the 10 kA/1.5 kV superconducting DC cable for electricity and cryogenic layers for liquid hydrogen and liquid nitrogen showing strong capability in transmitting “electricity + cold energy + chemical energy” simultaneously. Economic evaluation was performed with respect to the energy equipment capacity and costs with sensitivity and profitability analysis. With the discount rate 8% the dynamic payback period of the hybrid energy pipeline was 7.1 years. Results indicated that the shortest dynamic payback period of the hybrid energy pipeline was 4.8 years with the maximum transmission distance 93 km. Overall this article shows the novel concept and design of liquid hydrogen-electricity hybrid energy pipelines and proves the technical and economic feasibilities for future bulk hybrid energy transmission for railway transportation.
Demonstration of a kW-scale Solid Oxide Fuel Cell-calciner for Power Generation and Production of Calcined Materials
Aug 2019
Publication
Carbonate looping (CaL) has been shown to be less energy-intensive when compared to mature carbon capture technologies. Further reduction in the efficiency penalties can be achieved by employing a more efficient source of heat for the calcination process instead of oxy-fuel combustion. In this study a kW-scale solid oxide fuel cell (SOFC)-integrated calciner was designed and developed to evaluate the technical feasibility of simultaneously generating power and driving the calcination process using the high-grade heat of the anode off-gas. Such a system can be integrated with CaL systems or employed as a negative-emission technology where the calcines are used to capture CO2 from the atmosphere. The demonstration unit consisted of a planar SOFC stack operating at 750 °C and a combined afterburner/calciner to combust hydrogen slip from the anode off-gas and thermally decompose magnesite dolomite and limestone. The demonstrator generated up to 2 kWelDC power achieved a temperature in the range of 530–550 °C at the inlet of the afterburner and up to 678 °C in the calciner which was sufficient to demonstrate full calcination of magnesite and partial calcination of dolomite. However in order to achieve the temperature required for calcination of limestone further scale-up and heat integration are needed. These results confirmed technical feasibility of the SOFC-calciner concept for production of calcined materials either for the market or for direct air capture (DAC).
Everything About Hydrogen Podcast: Electron Stewardship in the Orkney Islands
Nov 2019
Publication
On this weeks episode the team are talking all things hydrogen in the Orkneys with Adele Lidderdale (Hydrogen Officer for Orkney Island Council) and Jon Clipsham (Hydrogen Manager EMEC). While the islands are best known for their exceptional wildlife whisky and cruise ships the Orkney islands have also emerged as a hub for the green hydrogen economy. Working alongside local government community groups research agencies and private sector partners the islands have deployed hydrogen solutions to heat a school power ferries in port move local council workers from A to B and in the future perhaps make Gin?! All this and more on the show.
The podcast can be found on their website
The podcast can be found on their website
IGEM/TD/1 Edition 6 Supplement 2 - High Pressure Hydrogen Pipelines
Nov 2021
Publication
This Supplement gives additional requirements and qualifications for the transmission of Hydrogen including Natural Gas/Hydrogen blended mixtures (subsequently referred to as NG/H blends) and for the repurposing of Natural Gas (NG) pipelines to Hydrogen service. For the purposes of this document any NG/H blend above 10% MOL is considered to be an equivalence to 100% hydrogen. For blends below 10% MOL there is no evidence to confirm that blends containing up to 10 mol.% hydrogen do not cause material degradation but it is considered that the risk is low.
This Supplement covers the design construction inspection testing operation and maintenance of steel pipelines and certain associated installations in Hydrogen service and the repurposing of NG pipelines to Hydrogen service at maximum operating pressure (MOP) exceeding 7 bar and not exceeding 137.9 bar.
This standard can be purchased here
This Supplement covers the design construction inspection testing operation and maintenance of steel pipelines and certain associated installations in Hydrogen service and the repurposing of NG pipelines to Hydrogen service at maximum operating pressure (MOP) exceeding 7 bar and not exceeding 137.9 bar.
This standard can be purchased here
Condensed Phase Explosions Involving Liquid Hydrogen
Sep 2021
Publication
Liquid hydrogen may have an important role in the storage and transportation of hydrogen energy. It may also provide the best option for some users of hydrogen energy notably the aviation sector. In the 1960’s liquid hydrogen spillages in open uncongested conditions sometimes produced violent condensed phase explosions as well as the familiar gas phase flash and sustained pool fire. Testing showed that burning mixtures of LH2 and solid oxygen/nitrogen readily transitioned to detonation for oxygen concentrations in the solid phase at or above 50%. Such explosive events have been observed in more recent research work on LH2 spillage and the pressure effects could be significant in some accident scenarios. There is a need to understand how solids are produced following spillage and what factors determine the level of oxygen enrichment. This paper describes the physical processes involved in the accumulation of solids during a horizontal discharge at ground level based on observations made in a recent HSE test that led to a condensed phase explosion. Areas where solids accumulated but remained in intimate contact with LH2 are identified. The paper also includes a thermodynamic and fluid mechanical analysis of the condensation process that includes the calculation of densities of mixtures of LH2 and air in different proportions. When the difference in flow speed between air and underlying LH2 is low a stable condensation layer can develop above the liquid where the temperature is just under the initial condensation point of air allowing sustained oxygen enrichment of condensate.
Hydrogen-assisted Fatigue Crack Growth: Pre-charging vs In-situ Testing in Gaseous Environments
Mar 2023
Publication
We investigate the implications of conducting hydrogen-assisted fatigue crack growth experiments in a hydrogen gas environment (in-situ hydrogen charging) or in air (following exposure to hydrogen gas). The study is conducted on welded 42CrMo4 steel a primary candidate for the future hydrogen transport infrastructure allowing us to additionally gain insight into the differences in behavior between the base steel and the coarse grain heat affected zone. The results reveal significant differences between the two testing approaches and the two weld regions. The differences are particularly remarkable for the comparison of testing methodologies with fatigue crack growth rates being more than one order of magnitude higher over relevant loading regimes when the samples are tested in a hydrogen-containing environment relative to the pre-charged samples. Aided by finite element modelling and microscopy analysis these differences are discussed and rationalized. Independent of the testing approach the heat affected zone showed a higher susceptibility to hydrogen embrittlement. Similar microstructural behavior is observed for both testing approaches with the base metal exhibiting martensite lath decohesion while the heat affected zone experienced both martensite lath decohesion and intergranular fracture.
HyDeploy: Demonstrating Non-destructive Carbon Savings Through Hydrogen Blending
Aug 2021
Publication
The project has successfully developed the safety case and delivered a hydrogen blend via the gas network into customers’ homes. The demonstration of safety for the specific network was based on robust evidence and clear operational procedures. Alongside the enabling safety case the HyDeploy project has demonstrated the first steps of hydrogen deployment are safe technically feasible and non-disruptive both for the network and domestic users.
The key outcomes of the HyDeploy project were:
The key outcomes of the HyDeploy project were:
- Successful achievement of the first regulatory approval from the HSE to operate a live gas network above the current hydrogen limit of 0.1 vol%. The approval allowed blending up to 20 vol%.
- Development of the technical and procedural precedents to generate evidence for review by the HSE which have informed subsequent safety case submissions through HyDeploy2 and the wider hydrogen safety case industry.
- The design fabrication installation and operation of the UK’s first hydrogen grid entry unit.
- Integration of novel hydrogen production and blending technologies to create the first hydrogen delivery system based on electrolytic generation into a live gas grid.
- Safe delivery of the UK’s first hydrogen blend trial to 100 homes and 30 faculty buildings. The trial delivered over 42000 cubic metres of hydrogen and abated over 27 tonnes of CO2.
- Collaboration with appliance and equipment providers to build a robust evidence base to demonstrate equipment suitability.
- Evidencing the suitability of hydrogen blends with domestic appliances as well as larger commercial appliances including catering equipment and boilers up to 600 kW.
- Evidencing the suitability of hydrogen blends with medium and low-pressure distribution systems relating to key performance metrics such as: pressure control; odour intensity and uniform gas compositions.
- Promotion of supply chain innovation through facilitating trials to develop gas detection and analysis technologies.
- Establishing a robust social science evidence base to understand the attitudes and experience of consumers actually using hydrogen blends.
HydroGenerally - Episode 2: Where Should Hydrogen Be Used?
Apr 2022
Publication
The Innovate UK KTN Hydrogen Innovation Network is bringing you this second episode with Steffan Eldred and Simon Buckley from Innovate UK KTN who continue their ‘back to basics' approach and delve deeper to understand where hydrogen should be used with their special guest Joanna Richart Head of Hydrogen Business at Ricardo. As with any technology or fuel discussions can get carried away implying they are the solution to all things but at Innovate UK KTN we strongly believe that we should ensure hydrogen is used where it can be most effective for decarbonising energy industrial and chemical industries.
The podcast can be found on their website
The podcast can be found on their website
A Multi-objective MILP Model for the Design and Operation of Future Integrated Multi-vector Energy Networks Capturing Detailed Spatio-temporal Dependencies
Dec 2017
Publication
A multi-objective optimisation model based on mixed integer linear programming is presented that can simultaneously determine the design and operation of any integrated multi-vector energy networks. It can answer variants of the following questions: What is the most effective way in terms of cost value/profit and/or emissions of designing and operating the integrated multi-vector energy networks that utilise a variety of primary energy sources to deliver different energy services such as heat electricity and mobility given the availability of primary resources and the levels of demands and their distribution across space and time? When to invest in technologies where to locate them; what resources should be used where when and how to convert them to the energy services required; how to transport the resources and manage inventory? Scenarios for Great Britain were examined involving different primary energy sources such as natural gas biomass and wind power in order to satisfy demands for heat electricity and mobility via various energy vectors such as electricity natural gas hydrogen and syngas. Different objectives were considered such as minimising cost maximising profit minimising emissions and maximising renewable energy production subject to the availability of suitable land for biomass and wind turbines as well as the maximum local production and import rates for natural gas. Results suggest that if significant mobility demands are met by hydrogen-powered fuel cell vehicles then hydrogen is the preferred energy vector over natural gas for satisfying heat demands. If natural gas is not used and energy can only be generated from wind power and biomass electricity and syngas are the preferred energy carriers for satisfying electricity and heat demands.
HydroGenerally - Episode 4: Hydrogen in a Global Maritime Industry: Plain Sailing or a Rough Ride?
May 2022
Publication
In this fourth episode Simon Buckley and Matthew Moss from Innovate UK KTN are exploring the use of hydrogen in the global maritime industry alongside their special guest Chester Lewis Business Development Manager at Ryze Hydrogen.
This podcast can be found on their website
This podcast can be found on their website
Assessment of Operability and Inspection, Maintenance and Repair Requirements for Transmission Pipelines and Installations in Hydrogen Service
Apr 2021
Publication
This report has been prepared for Hytechnical work programme to support the technical strategy for repurposing existing transmission pipelines and installations for the transportation and distribution of hydrogen and natural gas / hydrogen blends. The aim of the Hytechnical work programme is to support the implementation of the IGEM supplements to the standards TD/1 TD/13 TD/3 and TD/4.<br/>The report covers a desk study into the requirements for the inspection maintenance operation and repair of above 7 bar natural gas pipelines and installations designed and operated in accordance with the standards existing IGEM/TD/1 and IGEM/TD/13 which are repurposed for hydrogen service.
Gas Goes Green: A System for All Seasons
Oct 2021
Publication
‘A System For All Seasons’ analyses Britain’s electricity generation and consumption trends concluding that the country’s wind and solar farms will have enough spare electricity generated in spring and summer when demand is lower to produce green hydrogen to the equivalent capacity of 25 Hinkley Point C nuclear power plants.
The hydrogen stored would provide the same amount of energy needed for every person in the UK to charge a Tesla Model S electric vehicle more than 21 times in the autumn and winter months when energy demand is highest creating a clean energy buffer that avoids having to manage limited energy supplies on the international markets.
Crucially the research finds that the UK has enough capacity to store the hydrogen in a combination of salt caverns and disused oil and gas fields in the North Sea as well other locations to meet this demand.
The research also finds that using renewable hydrogen will help reduce the total number of wind farms needed in 2050 by more than 75% because it will ensure electricity generated by Britain’s wind farms is used as efficiently as possible by avoiding surplus electricity going to waste.
‘A System For All Seasons’ finds that:
The hydrogen stored would provide the same amount of energy needed for every person in the UK to charge a Tesla Model S electric vehicle more than 21 times in the autumn and winter months when energy demand is highest creating a clean energy buffer that avoids having to manage limited energy supplies on the international markets.
Crucially the research finds that the UK has enough capacity to store the hydrogen in a combination of salt caverns and disused oil and gas fields in the North Sea as well other locations to meet this demand.
The research also finds that using renewable hydrogen will help reduce the total number of wind farms needed in 2050 by more than 75% because it will ensure electricity generated by Britain’s wind farms is used as efficiently as possible by avoiding surplus electricity going to waste.
‘A System For All Seasons’ finds that:
- Britain’s wind and solar farms could generate between 60-80GW of renewable hydrogen - the equivalent capacity of 25 Hinkley Point C nuclear power plants - from spare renewable electricity generated in the spring and summer months between May and October each year.
- Running the energy system this way will reduce the need for the total electricity generating capacity of UK wind farms from 500-600GW by 2050 down to 140-190GW – a reduction of up to 76%.
- It would mean Great Britain would be using spare renewable electricity that would otherwise go to waste to produce green hydrogen. Under the alternative scenario additional wind farms would need to be built to accommodate for autumn and wind energy demand peaks but be left unused during other times of the year.
- With 140-190GW of wind generation capacity 115 to 140TWh of green hydrogen would be stored – enough energy for every person in the UK to charge a Tesla Model S more than 21 times.
- The potential storage volume from Britain’s salt fields ranges from >1TWh up to 30TWh. For disused oil and gas fields the potential storage volume for individual sites ranges from ~1TWh up to 330TWh.
HyDeploy2: Appliance Testing Summary and Interpretation
Apr 2021
Publication
In order to inform the Quantified Risk Assessment (QRA) and procedures for the Winlaton trial the HyDeploy 2 project has undertaken a second programme of work focused on assessing the safe operation of gas appliances with hydrogen blended gas. This work extends the initial programme of work undertaken in HyDeploy 1 in 2018. Collectively these two projects provide an evidence base to support the project objective to demonstrate that there are no overarching safety concerns for the addition of up to 20 % mol/mol hydrogen to the GB natural gas distribution network.<br/>Click on the supplements tab to view the other documents from this report
Hydrogen Production in the Light of Sustainability: A Comparative Study on the Hydrogen Production Technologies Using the Sustainability Index Assessment Method
Sep 2021
Publication
Hydrogen as an environmentally friendly energy carrier has received special attention to solving uncertainty about the presence of renewable energy and its dependence on time and weather conditions. This material can be prepared from different sources and in various ways. In previous studies fossil fuels have been used in hydrogen production but due to several limitations especially the limitation of the access to this material in the not-too-distant future and the great problem of greenhouse gas emissions during hydrogen production methods. New methods based on renewable and green energy sources as energy drivers of hydrogen production have been considered. In these methods water or biomass materials are used as the raw material for hydrogen production. In this article after a brief review of different hydrogen production methods concerning the required raw material these methods are examined and ranked from different aspects of economic social environmental and energy and exergy analysis sustainability. In the following the current position of hydrogen production is discussed. Finally according to the introduced methods their advantages and disadvantages solar electrolysis as a method of hydrogen production on a small scale and hydrogen production by thermochemical method on a large scale are introduced as the preferred methods.
Technology Roadmaps for Transition Management: The Case of Hydrogen Energy
Oct 2011
Publication
Technology roadmaps are increasingly used by governments to inform and promote technological transitions such as a transition to a hydrogen energy system. This paper develops a framework for understanding how current roadmapping practice relates to emerging theories of the governance of systems innovation. In applying this framework to a case study of hydrogen roadmaps the paper finds that roadmapping for transitions needs to place greater emphasis on ensuring good quality and transparent analytic and participatory procedures. To be most useful roadmaps should be embedded within institutional structures that enable the incorporation of learning and re-evaluation but in practice most transition roadmaps are one-off exercises
Establishing the State of the Art for the Definition of Safety Distances for Hydrogen Refuelling Stations
Sep 2021
Publication
Hydrogen is widely considered a clean source of energy from the viewpoint of reduction in carbon dioxide emissions as a countermeasure against global warming and air pollution. Various efforts have been made to develop hydrogen as a viable energy carrier including the implementation of fuel cell vehicles (FCVs) and hydrogen refuelling stations (HRSs). A good network of hydrogen refuelling stations is essential for operating FCVs and several hydrogen refuelling stations have been constructed and are in operation worldwide [1]. However despite the potential benefits of hydrogen its flammability creates significant safety concerns. Furthermore even though the energy density of hydrogen is lower than that of gasoline and there is no carbon present which means the amount of radiant heat flux released during combustion is relatively small hydrogen must be handled at high pressure in order to make the cruising range of a fuel cell vehicle (FCV) equal to that of gasoline-powered vehicles. Therefore it is essential to properly evaluate these safety concerns and take reasonable and effective countermeasures. Approximately 50 accidents and incidents involving HRSs have been reported globally [2]. Sakamoto et al. [2] analysed accidents and incidents at HRSs in Japan and the USA to identify the safety issues. Most types of accidents and incidents are small leakages of hydrogen but some have led to serious consequences such as fire and explosion. Recently there was a serious incident in Norway at Kjørbo where a strong explosion was observed [3] – indeed this was within a short time of two other serious incidents in the USA and South Korea showing that the frequency of such incidents may be higher as deployments increase. Use of hydrogen forklifts (and the associated refuelling infrastructure) is another challenge to consider. Hydrogen refuelling stations are often installed in urban areas facing roads and are readily accessible to everyone. Therefore a key measure to approve the hydrogen refuelling stations is safety distances between the hydrogen infrastructure and the surrounding structures such as office buildings or residential dwellings. Whilst a lot of work has been carried out on safety distances (see e.g. [4-6) the accident scenario assumptions and safety distances varied widely in those studies. As a result no consensus has yet emerged on the safety distances to be used and efforts are still needed to bridge the gap between international standards and local regulations (see e.g. [7-8]). The paper analyses this issue and provides guidance on the way forward.
Hy4Heat Annex To Site Specific Safety Case for Hydrogen Community Demonstration - Work Package 7
May 2021
Publication
The Hy4Heat Safety Assessment has focused on assessing the safe use of hydrogen gas in certain types of domestic properties and buildings. The summary reports (the Precis and the Safety Assessment Conclusions Report) bring together all the findings of the work and should be looked to for context by all readers. The technical reports should be read in conjunction with the summary reports. While the summary reports are made as accessible as possible for general readers the technical reports may be most accessible for readers with a degree of technical subject matter understanding. All of the safety assessment reports have now been reviewed by the HSE<br/>Annex prepared to support Site Specific Safety Cases for hydrogen gas community demonstrations based on work undertaken by the Hy4Heat programme. It covers a collection of recommended risk reduction measures for application downstream of the Emergency Control Valve (ECV)
Extreme Energetic Materials at Ultrahigh Pressures
Jul 2020
Publication
Owing to their extremely high energy density single-bonded polymeric nitrogen and atomic metallic hydrogen are generally regarded as the ultimate energetic materials. Although their syntheses normally require ultrahigh pressures of several hundred gigapascals (GPa) which prohibit direct materials application research on their stability metastability and fundamental properties are valuable for seeking extreme energetic materials through alternative synthetic routes. Various crystalline and amorphous polymeric nitrogens have been discovered between 100 and 200 GPa. Metastability at ambient conditions has been demonstrated for some of these phases. Cubic-gauche and black-phosphorus polymorphs of single-bonded nitrogen are two particularly interesting phases. Their large hystereses warrant further application-inspired basic research of nitrogen. In contrast although metallic hydrogen contains the highest-estimated energy density its picosecond lifetime and picogram quantity make its practical material application impossible at present. “Metallic hydrogen” remains a curiosity-driven basic research pursuit focusing on the pressure-induced evolution of the molecular hydrogen crystal and its electronic band structure from a low-density insulator with a very wide electronic band gap to a semiconductor with a narrow gap to a dense molecular metal and atomic metal and eventually to a previously unknown exotic state of matter. This great experimental challenge is driving relentless advancement in ultrahigh-pressure science and technology.
HyDeploy2 Report: Exemption
Jun 2021
Publication
Exemption is requested by Northern Gas Networks Ltd (NGN) from the obligation set out in Regulation 8(1) of the Gas Safety (Management) Regulations 1996 (GSMR) to convey only natural gas that is compliant with the Interchangeability requirements of Part I of Schedule 3 of the GSMR within a section of the NGN gas distribution network near Winlaton (the “field trial area”). The field trial area is owned and operated by Northern Gas Networks Ltd. The proposed conveyance of non-compliant gas (hereafter called the “Winlaton Field Trial”) will last for one year and is part of the Network Innovation Competition Project “HyDeploy2”.<br/>The project the first two phases of which are funded under the UK Network Innovation Competition scheme aims to demonstrate that natural gas containing levels of hydrogen beyond the upper limit set out in Schedule 3 of in the Gas Safety (Management) Regulations (GSMR) can be distributed and utilised safely and efficiently in the UK gas distribution networks. The first phase of the HyDeploy project is currently underway and includes a 10-month field trial that of hydrogen injection into part of a private gas distribution system owned and operated by Keele University. The second phase of the HyDeploy project (HyDeploy2) continues on from the work of the first phase and is scheduled to conclude with two 12-month field trials in which hydrogen will be injected into public gas networks owned and operated by NGN and Cadent Gas.<br/>Click on the supplements tab to view the other documents from this report
Navigating Algeria Towards a Sustainable Green Hydrogen Future to Empower North Africa and Europe's Clean Hydrogen Transition
Mar 2024
Publication
Algeria richly-endowed with renewable resources is well-positioned to become a vital green hydrogen provider to Europe. Aiming to aid policymakers stakeholders and energy sector participants this study embodies the first effort in literature to investigate the viability and cost-effectiveness of implementing green hydrogen production projects destined for exports to Europe via existing pipelines. A land suitability analysis utilizing multi-criteria decision making (MCDM) coupled with geographical information system (GIS) identified that over 43.55% of Algeria is highly-suitable for hydrogen production. Five optimal locations were investigated utilizing Hybrid Optimization of Multiple Electric Renewables (HOMER) with solar-hydrogen proving the most cost-effective option. Wind-based production offering higher output volumes reaching 968 kg/h requires turbine cost reductions of 17.50% (Ain Salah) to 54.50% (Djanet) to achieve a competitive levelized cost of hydrogen (LCOH) of $3.85/kg with PV systems. A techno-economic sensitivity analysis was conducted identifying Djanet as the most promising location for a 100 MW solar-hydrogen plant with a competitive LCOH ranging from $1.96/kg to $4.85/kg.
A Financial Model for Lithium-ion Storage in a Photovoltaic and Biogas Energy System
May 2019
Publication
Electrical energy storage (EES) such as lithium-ion (Li-ion) batteries can reduce curtailment of renewables maximizing renewable utilization by storing surplus electricity. Several techno-economic analyses have been performed on EES but few have investigated the financial performance. This paper presents a state-of-the-art financial model obtaining novel and significative financial and economics results when applied to Li-ion EES. This work is a significant step forward since traditional analysis on EES are based on oversimplified and unrealistic economic models. A discounted cash flow model for the Li-ion EES is introduced and applied to examine the financial performance of three EES operating scenarios. Real-life solar irradiance load and retail electricity price data from Kenya are used to develop a set of case studies. The EES is coupled with photovoltaics and an anaerobic digestion biogas power plant. The results show the impact of capital cost: the Li-ion project is unprofitable in Kenya with a capital cost of 1500 $/kWh but is profitable at 200 $/kWh. The study shows that the EES will generate a higher profit if it is cycled more frequently (hence a higher lifetime electricity output) although the lifetime is reduced due to degradation.
HydroGenerally - Episode 3: Lift Off for Hydrogen in Aviation
Apr 2022
Publication
In this third episode Steffan Eldred and Hannah Abson from Innovate UK KTN are exploring the scale of the opportunity that hydrogen and aviation present alongside their special guest Katy Milne Head of Industrial Strategy at FlyZero.
The podcast can be found on their website
The podcast can be found on their website
What is the Energy Balance of Electrofuels Produced Through Power-to-fuel Integration with Biogas Facilities?
Nov 2021
Publication
The need to reduce the climate impact of the transport sector has led to an increasing interest in the utilisation of alternative fuels. Producing advanced fuels through the integration of anaerobic digestion and power-to-fuel technologies may offer a solution to reduce greenhouse gas emissions from difficult to decarbonise modes of transport such as heavy goods vehicles shipping and commercial aviation while also offering wider system benefits. This paper investigates the energy balance of power-to-fuel (power-to-methane power-to-methanol power-to-Fischer-Tropsch fuels) production integrated with a biogas facility co-digesting grass silage and dairy slurry. Through the integration of power-to-methane with anaerobic digestion an increase in system gross energy of 62.6% was found. Power-to-methanol integration with the biogas system increased the gross energy by 50% while power-to-Fischer-Tropsch fuels increased the gross energy yield by 32%. The parasitic energy demand for hydrogen production was highlighted as the most significant factor for integrated biogas and power-to-fuel facilities. Consuming electricity that would otherwise have been curtailed and optimising the anaerobic digestion process were identified as key to improving the energetic efficiency of all system configurations. However the broad cross-sectoral benefits of the overarching cascading circular economy system such as providing electrical grid stability and utilising waste resources must also be considered for a comprehensive perspective on the integration of anaerobic digestion and power-to-fuel.
IGEM/TD/13 Edition 3 Supplement 1 - Pressure Regulating Installations for Hydrogen at Pressures Exceeding 7 Bar
Nov 2021
Publication
IGEM/TD/13 Standard applies to the safe design construction inspection testing operation and maintenance of pressure regulating installations (PRIs) in accordance with current knowledge and operational experience.
This Supplement provides additional requirements for new PRIs to be used for the transmission of Hydrogen including Natural Gas/Hydrogen blended mixtures (subsequently referred to as NG/H blends) and for the repurposing of Natural Gas (NG) PRIs for Hydrogen service.
NG/H blends are considered to be equivalent to 100 mol % Hydrogen with respect to limits on design stresses the potential effect on the material properties and damage and defect categories and acceptance levels unless an additional technical evaluation is carried out to qualify the materials.
NG/H blends containing in excess of 10 mol % Hydrogen are considered to be equivalent to 100 mol.% Hydrogen with respect to all other requirements except for hazardous areas.
This Supplement gives additional recommendations for PRIs and installations
You can purchase the standard here
This Supplement provides additional requirements for new PRIs to be used for the transmission of Hydrogen including Natural Gas/Hydrogen blended mixtures (subsequently referred to as NG/H blends) and for the repurposing of Natural Gas (NG) PRIs for Hydrogen service.
NG/H blends are considered to be equivalent to 100 mol % Hydrogen with respect to limits on design stresses the potential effect on the material properties and damage and defect categories and acceptance levels unless an additional technical evaluation is carried out to qualify the materials.
NG/H blends containing in excess of 10 mol % Hydrogen are considered to be equivalent to 100 mol.% Hydrogen with respect to all other requirements except for hazardous areas.
This Supplement gives additional recommendations for PRIs and installations
- with an upstream maximum operating pressure (MOP) not greater than 100 bar
- with an outlet pressure greater than or equal to 7 bar
- for use with Hydrogen or NG/H blends with a Hydrogen content greater than 10 %
- operating with a temperature range between -20°C and 120°C.
You can purchase the standard here
A Novel Framework for Development and Optimisation of Future Electricity Scenarios with High Penetration of Renewables and Storage
May 2019
Publication
Although electricity supply is still dominated by fossil fuels it is expected that renewable sources will have a much larger contribution in the future due to the need to mitigate climate change. Therefore this paper presents a new framework for developing Future Electricity Scenarios (FuturES) with high penetration of renewables. A multi-period linear programming model has been created for power-system expansion planning. This has been coupled with an economic dispatch model PowerGAMA to evaluate the technical and economic feasibility of the developed scenarios while matching supply and demand. Application of FuturES is demonstrated through the case of Chile which has ambitious plans to supply electricity using only renewable sources. Four cost-optimal scenarios have been developed for the year 2050 using FuturES: two Business as usual (BAU) and two Renewable electricity (RE) scenarios. The BAU scenarios are unconstrained in terms of the technology type and can include all 11 options considered. The RE scenarios aim to have only renewables in the mix including storage. The results show that both BAU scenarios have a levelised cost of electricity (LCOE) lower than or equal to today’s costs ($72.7–77.3 vs $77.6/MWh) and include 81–90% of renewables. The RE scenarios are slightly more expensive than today’s costs ($81–87/MWh). The cumulative investment for the BAU scenarios is $123-$145 bn compared to $147-$157 bn for the RE. The annual investment across the scenarios is estimated at $4.0 ± 0.4 bn. Both RE scenarios show sufficient flexibility in matching supply and demand despite solar photovoltaics and wind power contributing around half of the total supply. Therefore the FuturES framework is a powerful tool for aiding the design of cost-efficient power systems with high penetration of renewables.
The Upfront Cost of Decarbonising Your Home
Nov 2021
Publication
The objective of this report is to analyse the upfront capital costs facing consumers when considering the installation of new low carbon heating technology solutions for their homes today including the cost of any associated home upgrades that will likely be required. The UK Government have recently published its Heat and Buildings Strategy which sets out plans to significantly cut carbon emissions from the existing housing stock and new homes. Whilst the Strategy points to a future role for a variety of technologies such as heat pumps hydrogen and heat networks the success of this Strategy will largely be determined by the ability to achieve installed cost reductions for heat pumps of at least 25-50% by 2025 with the view to achieving cost parity with a gas boiler by 2030. The purpose of this report is to launch a series which tracks the upfront costs of these respective technologies over time to establish whether the cost reduction targets mooted by government and heat pump stakeholders are being delivered and the implications this has on our ability to decarbonise the UK housing stock.
How to Decarbonise the UKs Freight Sector by 2050
Dec 2020
Publication
To achieve the UK’s net zero target vehicles including heavy-duty vehicles (HDVs) will need to be entirely decarbonised. The UK government has announced that it plans to phase out the sale of all new cars and vans with engines between 2030 and 2035. It has also announced its intention to consult on a similar phase-out for diesel-powered heavy-goods vehicles (HGVs). This study analyses policies and technologies which can contribute to the decarbonisation of the UK's inland freight sector.
It comprises an emissions modelling exercise and a cost analysis for total cost of ownership (TCO) of long-haul trucks. The study shows that for urban and regional deliveries battery electric trucks offer the best option to decarbonise. It also shows that battery electric trucks and those using an overhead catenary infrastructure are likely to be the most cost-effective pathway to decarbonise long-haul trucks by 2050 but that renewable hydrogen could also be an option.
Link to Document Download on Transport & Environment website
It comprises an emissions modelling exercise and a cost analysis for total cost of ownership (TCO) of long-haul trucks. The study shows that for urban and regional deliveries battery electric trucks offer the best option to decarbonise. It also shows that battery electric trucks and those using an overhead catenary infrastructure are likely to be the most cost-effective pathway to decarbonise long-haul trucks by 2050 but that renewable hydrogen could also be an option.
Link to Document Download on Transport & Environment website
The Implications of Ambitious Decarbonisation of Heat and Road Transport for Britain’s Net Zero Carbon Energy Systems
Oct 2021
Publication
Decarbonisation of heating and road transport are regarded as necessary but very challenging steps on the pathway to net zero carbon emissions. Assessing the most efficient routes to decarbonise these sectors requires an integrated view of energy and road transport systems. Here we describe how a national gas and electricity transmission network model was extended to represent multiple local energy systems and coupled with a national energy demand and road transport model. The integrated models were applied to assess a range of technologies and policies for heating and transport where the UK’s 2050 net zero carbon emissions target is met. Overall annual primary energy use is projected to reduce by between 25% and 50% by 2050 compared to 2015 due to ambitious efficiency improvements within homes and vehicles. However both annual and peak electricity demands in 2050 are more than double compared with 2015. Managed electric vehicle charging could save 14TWh/year in gas-fired power generation at peak times and associated emissions whilst vehicle-to-grid services could provide 10GW of electricity supply during peak hours. Together managed vehicle charging and vehicle-to-grid supplies could result in a 16% reduction in total annual energy costs. The provision of fast public charging facilities could reduce peak electricity demand by 17GW and save an estimated £650 million annually. Although using hydrogen for heating and transport spreads the hydrogen network costs between homeowners and motorists it is still estimated to be more costly overall compared to an all-electric scenario. Bio-energy electricity generation plants with carbon capture and storage are required to drive overall energy system emissions to net zero utilisation of which is lowest when heating is electrified and road transport consists of a mix of electric and hydrogen fuel-cell vehicles. The analysis demonstrates the need for an integrated systems approach to energy and transport policies and for coordination between national and local governments.
Life Cycle Assessment and Water Footprint of Hydrogen Production Methods: From Conventional to Emerging Technologies
Oct 2020
Publication
A common sustainability issue arising in production systems is the efficient use of resources for providing goods or services. With the increased interest in a hydrogen (H2) economy the life-cycle environmental performance of H2 production has special significance for assisting in identifying opportunities to improve environmental performance and to guide challenging decisions and select between technology paths. Life cycle impact assessment methods are rapidly evolving to analyze multiple environmental impacts of the production of products or processes. This study marks the first step in developing process-based streamlined life cycle analysis (LCA) of several H2 production pathways combining life cycle impacts at the midpoint (17 problem-oriented) and endpoint (3 damage-oriented) levels using the state-of-the-art impact assessment method ReCiPe 2016. Steam reforming of natural gas coal gasification water electrolysis via proton exchange membrane fuel cell (PEM) solid oxide electrolyzer cell (SOEC) biomass gasification and reforming and dark fermentation of lignocellulosic biomass were analyzed. An innovative aspect is developed in this study is an analysis of water consumption associated with H2 production pathways by life-cycle stage to provide a better understanding of the life cycle water-related impacts on human health and natural environment. For water-related scope Water scarcity footprint (WSF) quantified using Available Water Remaining (AWARE) method was applied as a stand-alone indicator. The paper discusses the strengths and weaknesses of each production pathway identify the drivers of environmental impact quantify midpoint environmental impact and its influence on the endpoint environmental performance. The findings of this study could serve as a useful theoretical reference and practical basis to decision-makers of potential environmental impacts of H2 production systems.
Evaluating the Opportunity to Repurpose Gas Transmission Assets for Hydrogen Transportation
Sep 2021
Publication
The UK National Transmission System (NTS) is a key enabler to decarbonise the gas network in Great Britain (GB) in order to meet the UK government’s target of net-zero emissions by 2050. FutureGrid is National Grid’s research programme assessing the capability of the transmission system to transport hydrogen. Our goal is to accelerate the decarbonisation of power industry and heat by delivering a safe supply of energy to all customers both during and after the energy transition. FutureGrid will lead to a better understanding of what the technical parameters are around the ultimate role of the NTS in the energy system and how the transition can be managed. Under FutureGrid National Grid will construct a NTS hydrogen test facility at DNV’s Spadeadam testing and research site. NTS assets due to be decommissioned in early RIIO2 will be reconstructed to create a test network that can be used to answer some of the fundamental questions around safety and operation of a converted network. Flows of hydrogen/natural gas blends including 100% hydrogen will be tested for the first time in GB at transmission pressures. This system will connect to the existing H21 distribution network test facility at Spadeadam to prove a complete beach-to-meter network can be decarbonised to develop a comprehensive programme for the hydrogen transition. The project will provide a transmission facility which is a key enabler for more advanced hydrogen testing on industrial equipment such as hydrogen separation technology hydrogen compressors and/or purification of hydrogen for transport. Our paper will detail the current position and aims of the project.
Detection of Contaminants in Hydrogen Fuel for Fuel Cell Electrical Vehicles with Sensors—Available Technology, Testing Protocols and Implementation Challenges
Dec 2021
Publication
Europe’s low-carbon energy policy favors a greater use of fuel cells and technologies based on hydrogen used as a fuel. Hydrogen delivered at the hydrogen refueling station must be compliant with requirements stated in different standards. Currently the quality control process is performed by offline analysis of the hydrogen fuel. It is however beneficial to continuously monitor at least some of the contaminants onsite using chemical sensors. For hydrogen quality control with regard to contaminants high sensitivity integration parameters and low cost are the most important requirements. In this study we have reviewed the existing sensor technologies to detect contaminants in hydrogen then discussed the implementation of sensors at a hydrogen refueling stations described the state-of-art in protocols to perform assessment of these sensor technologies and finally identified the gaps and needs in these areas. It was clear that sensors are not yet commercially available for all gaseous contaminants mentioned in ISO14687:2019. The development of standardized testing protocols is required to go hand in hand with the development of chemical sensors for this application following a similar approach to the one undertaken for air sensors.
Milford Haven: Energy Kingdom - System Architecture Report: A Prospering from the Energy Revolution Project
Nov 2021
Publication
Milford Haven: Energy Kingdom is a two-year project exploring what a decarbonised smart local energy system could look like for Milford Haven Pembroke and Pembroke Dock.
The project explores the potential of hydrogen as part of a multi-vector approach to decarbonisation. Central to the project and to achieving Net Zero is a commitment to engage with the community and local industry providing insight and opportunities for growth.
The ambition is to gather detailed insight into the whole energy system around Milford Haven to identify and design a future smart local energy system based on a truly multi-vector approach and comprehensive energy systems architecture.
The transition to Net Zero requires action across the economy. As the UK’s largest energy port Milford Haven is an industrial cluster that can handle 30% of total UK gas demand is home to Europe’s largest gas power station powering 3.5 million homes and businesses has ambitions to build 90MW of floating offshore wind supports 5000 jobs and injects £324m to the Pembrokeshire economy.
This work describes the outcomes of the effort to define designs of future energy system architectures combining; technology the interconnectivity between them and data; with markets trading platforms and policies; with business models and defined organisational governance. The aim of these designs is to provide:
The project explores the potential of hydrogen as part of a multi-vector approach to decarbonisation. Central to the project and to achieving Net Zero is a commitment to engage with the community and local industry providing insight and opportunities for growth.
The ambition is to gather detailed insight into the whole energy system around Milford Haven to identify and design a future smart local energy system based on a truly multi-vector approach and comprehensive energy systems architecture.
The transition to Net Zero requires action across the economy. As the UK’s largest energy port Milford Haven is an industrial cluster that can handle 30% of total UK gas demand is home to Europe’s largest gas power station powering 3.5 million homes and businesses has ambitions to build 90MW of floating offshore wind supports 5000 jobs and injects £324m to the Pembrokeshire economy.
This work describes the outcomes of the effort to define designs of future energy system architectures combining; technology the interconnectivity between them and data; with markets trading platforms and policies; with business models and defined organisational governance. The aim of these designs is to provide:
- The basis for a roadmap for the next phases of development and implementation
- Confidence to innovators and investors in the future longevity of investments in hydrogen and
- A common basis of understanding for all stakeholders wishing to contribute to the Milford Haven: Energy Kingdom.
Decarbonising Heat in Buildings: Putting Consumers First
Apr 2021
Publication
From an evaluation of the GB housing stock it is clear that a mosaic of low carbon heating technologies will be needed to reach net zero. While heat pumps are an important component of this mix our analysis shows that it is likely to be impractical to heat many GB homes with heat pumps only. A combination of lack of exterior space and/or the thermal properties of the building fabric mean that a heat pump is not capable of meeting the space heating requirement of 8 to 12m homes (or 37% to 54% of the 22.7m homes assessed in this report) or can do so only through the installation of highly disruptive and intrusive measures such as solid wall insulation. Hybrid heat pumps that are designed to optimise efficiency of the system do not have the same requirements of a heat pump and may be a suitable solution for some of these homes. This is likely to mean that decarbonised gas networks are therefore critical to delivery of net zero. 3 to 4m homes1 (or 14% to 18% of homes assessed in our analysis) could be made suitable for heat pump retrofit through energy efficiency measures such as cavity wall insulation. For 7 to 10m homes there are no limiting factors and they require minimal/no upgrade requirements to be made heat pump-ready. Nevertheless given firstly the levels of disruption to the floors and interiors of homes caused by the installation of heat pumps and secondly the cost and disruption associated with the requirement to significantly upgrade the electricity distribution networks to cope with large numbers of heat pumps operating at peak demand times - combined with the availability of a decarbonised gas network which requires a simple like-for-like boiler replacement - is likely to mean that many of these ‘swing’ properties will be better served through a gas based technology such as hydrogen (particularly when consumer choice is factored in) or a hybrid system. A recent trial run in winter 2018-19 by the Energy System Catapult revealed that all participants were reluctant to make expensive investments to improve the energy efficiency of their homes just to enhance the performance of their heat pump. They were more interested in less costly upgrades and tangible benefits such as lower bills or greater comfort. This means that renewable gases including hydrogen as heating fuels are a crucial component of the journey to net zero and the UK’s hydrogen ambitions should be reflective of this. The analysis presented in this paper focuses on the external fabric of the buildings further analysis should be undertaken to consider the internal system changes that would be required for heat pumps and hydrogen boilers for example BEIS Domestic Heat Distribution Systems: Gathering Report from February 2021 which considers the suitability of radiators for the low carbon transition.
A Review of Energy Systems Models in the UK: Prevalent Usage and Categorisation
Feb 2016
Publication
In this paper a systematic review of academic literature and policy papers since 2008 is undertaken with an aim of identifying the prevalent energy systems models and tools in the UK. A list of all referenced models is presented and the literature is analysed with regards sectoral coverage and technological inclusion as well as mathematical structure of models. The paper compares available models using an appropriate classification schema the introduction of which is aimed at making the model landscape more accessible and perspicuous thereby enhancing the diversity of models within use. The distinct classification presented in this paper comprises three sections which specify the model purpose and structure technological detail and mathematical approach. The schema is not designed to be comprehensive but rather to be a broad classification with pertinent level of information required to differentiate between models. As an example the UK model landscape is considered and 22 models are classified in three tables as per the proposed schema.
Development of a Hydrogen Supplement for use with IGEM/SR/25
Jun 2022
Publication
In response to the UK Government’s commitment to achieve net-zero carbon emissions by 2050 a range of research and demonstration projects are underway to investigate the feasibility of using hydrogen in place of natural gas within the national transmission and distribution system. In order for these projects to achieve their full scope of work a mechanism for performing hazardous area classification for hydrogen installations is required. At present IGEM/SR/25 is used to undertake such assessments for natural gas installations but the standard is not currently applicable to hydrogen or hydrogen/natural gas blends.<br/>This report presents updated data and a summary of the recommended methodologies for hazardous area classification of installations using hydrogen or blends of up to 20% hydrogen in natural gas. The contents of this report are intended to provide a technical commentary and the data for a hydrogen-specific supplement to IGEM/SR/25. The supplement will specifically cover 100% hydrogen and a 20/80% by volume blend of hydrogen/natural gas. Reference to intermediate blends is included in this report where appropriate to cover the anticipated step-wise introduction of hydrogen into the natural gas network.<br/>This report is divided into a series of appendices each of which covers a specific area of the IGEM standard. Each appendix includes a summary of specific recommendations made to enable IGEM/SR/25 to be applied to hydrogen and blends of up to 20% hydrogen in natural gas. The reader is encouraged to review the individual appendices for specific conclusions associated with the topic areas addressed in this report.<br/>In general the existing methodologies and approaches used for area classification in IGEM/SR/25 have been deemed appropriate for installations using either hydrogen or blends of up to 20% hydrogen in natural gas. Where necessary revised versions of the equations and zoning distances used in the standard are presented which account for the influence of material property differences between natural gas and the two alternative fuels considered in this work.
Ammonia–methane Combustion in Tangential Swirl Burners for Gas Turbine Power Generation
Feb 2016
Publication
Ammonia has been proposed as a potential energy storage medium in the transition towards a low-carbon economy. This paper details experimental results and numerical calculations obtained to progress towards optimisation of fuel injection and fluidic stabilisation in swirl burners with ammonia as the primary fuel. A generic tangential swirl burner has been employed to determine flame stability and emissions produced at different equivalence ratios using ammonia–methane blends. Experiments were performed under atmospheric and medium pressurised conditions using gas analysis and chemiluminescence to quantify emission concentrations and OH production zones respectively. Numerical calculations using GASEQ and CHEMKIN-PRO were performed to complement compare with and extend experimental findings hence improving understanding concerning the evolution of species when fuelling on ammonia blends. It is concluded that a fully premixed injection strategy is not appropriate for optimised ammonia combustion and that high flame instabilities can be produced at medium swirl numbers hence necessitating lower swirl and a different injection strategy for optimised power generation utilising ammonia fuel blends.
Combined Ammonia Recovery and Solid Oxide Fuel Cell Use at Wastewater Treatment Plants for Energy and Greenhouse Gas Emission Improvements
Feb 2019
Publication
Current standard practice at wastewater treatment plants (WWTPs) involves the recycling of digestate liquor produced from the anaerobic digestion of sludge back into the treatment process. However a significant amount of energy is required to enable biological breakdown of ammonia present in the liquor. This biological processing also results in the emission of damaging quantities of greenhouse gases making diversion of liquor and recovery of ammonia a noteworthy option for improving the sustainability of wastewater treatment. This study presents a novel process which combines ammonia recovery from diverted digestate liquor for use (alongside biomethane) in a solid oxide fuel cell (SOFC) system for implementation at WWTPs. Aspen Plus V.8.8 and numerical steady state models have been developed using data from a WWTP in West Yorkshire (UK) as a reference facility (750000p.e.). Aspen Plus simulations demonstrate an ability to recover 82% of ammoniacal nitrogen present in digestate liquor produced at the WWTP. The recovery process uses a series of stripping absorption and flash separation units where water is recovered alongside ammonia. This facilitates effective internal steam methane as a case of study has the potential to make significant impacts energetically and environmentally; findings suggest the treatment facility could transform from a net consumer of electricity to a net producer. The SOFC has been demonstrated to run at an electrical efficiency of 48% with NH3 contributing 4.6% of its power output. It has also been demonstrated that 3.5 kg CO2e per person served by the WWTP could be mitigated a year due to a combination of emissions savings by diversion of ammonia from biological processing and lifecycle emissions associated with the lack of reliance on grid electricity.
Solar Energy: Applications, Trends Analysis, Bibliometric Analysis and Research Contribution to Sustainable Development Goals (SDGs)
Jan 2023
Publication
Over the past decade energy demand has witnessed a drastic increase mainly due to huge development in the industry sector and growing populations. This has led to the global utilization of renewable energy resources and technologies to meet this high demand as fossil fuels are bound to end and are causing harm to the environment. Solar PV (photovoltaic) systems are a renewable energy technology that allows the utilization of solar energy directly from the sun to meet electricity demands. Solar PV has the potential to create a reliable clean and stable energy systems for the future. This paper discusses the different types and generations of solar PV technologies available as well as several important applications of solar PV systems which are “Large-Scale Solar PV” “Residential Solar PV” “Green Hydrogen” “Water Desalination” and “Transportation”. This paper also provides research on the number of solar papers and their applications that relate to the Sustainable Development Goals (SDGs) in the years between 2011 and 2021. A total of 126513 papers were analyzed. The results show that 72% of these papers are within SDG 7: Affordable and Clean Energy. This shows that there is a lack of research in solar energy regarding the SDGs especially SDG 1: No Poverty SDG 4: Quality Education SDG 5: Gender Equality SDG 9: Industry Innovation and Infrastructure SDG 10: Reduced Inequality and SDG 16: Peace Justice and Strong Institutions. More research is needed in these fields to create a sustainable world with solar PV technologies.
HyDeploy2: Gas Characteristics Summary and Interpretation
Jun 2020
Publication
In order to inform the Quantified Risk Assessment (QRA) and procedures for the Winlaton trial the gas characteristics relating to the behaviour of the flammable gas have been reviewed for blended natural gas mixtures containing 20% mol/mol hydrogen (hereby referred to as “blend”) for normal operation and 50% mol/mol for fault conditions. This work builds on the findings of the previous HyDeploy gas characteristics report HyD-Rep04-V02-Characteristics.<br/>Click on the supplements tab to view the other documents from this report
Performance of Hydrogen Storage Tanks of Type IV in a Fire: Effect of the State of Charge
Sep 2021
Publication
The use of hydrogen storage tanks at 100% of nominal working pressure (NWP) is expected only after refuelling. Driving between refuellings is characterised by the state of charge SoC <100%. There is experimental evidence that Type IV tanks tested in a fire at initial pressures below 1/3 NWP leaked without rupture. This paper aims at understanding this phenomenon. The numerical research has demonstrated that the heat transfer from fire through the composite overwrap at storage pressures below NWP/3 is sufficient to melt the polymer liner. This melting initiates hydrogen microleaks through the composite before it loses the load-bearing ability. The fire-resistance rating (FRR) is defined as the time to rupture in a fire of a tank without or with blocked thermally activated pressure relief device. The dependence of a FRR on the SoC is demonstrated for the tanks with defined material properties and volumes in the range of 36–244 L. A composite wall thickness variation is shown to cause a safety issue by reducing the tank’s FRR and is suggested to be addressed by tank manufacturers and OEMs. The effect of a tank’s burst pressure ratio on the FRR is investigated. Thermal parameters of the composite wall i.e. decomposition heat and temperatures are shown in simulations of a tank failure in a fire to play an important role in its FRR.
IGEM/SR/23 Review of Thermal Radiation and Noise for Hydrogen Venting
Nov 2021
Publication
IGEM/SR/23 (“Venting of natural gas”) provides recommendations for the conceptual design operation and safety aspects of permanent temporary and emergency venting of natural gas. The document was originally developed many years ago and the current edition dates to 1995. The document is due to be reviewed and updated for application to natural gas but the aim of this study is not to review the applicability of the document for natural gas but to assess the possible impact of 100% hydrogen on specific aspects of the existing guidance.<br/>A key element of the guidance concerns the safe dispersion distances for natural gas as vents are intended to provide a means of safely dispersing gas in the atmosphere without ignition. Guidance on safe dispersion distances for venting are provided in Section 6.6 accompanied by graphs showing the relationship between the mass flow rate through the vent and the safe (horizontal) dispersion distance. Details of the model used to predict the dispersion distances are given in Appendix 1. However for dispersion the guidance in IGEM/SR/23 has been superseded by similar guidance on hazard distances for unignited releases in IGEM/SR/25 (“Hazardous area classification of natural gas installations”) [2]. A comprehensive review of the applicability of IGEM/SR/25 to hydrogen is already underway for the LTS Futures project and is not duplicated here.<br/>However IGEM/SR/23 contains guidance on other important aspects relevant to the safe design and operation of vents which are not addressed elsewhere in the IGEM suite of standards; in particular guidance on hazard ranges for thermal radiation (in the event of an unplanned ignition of the venting gas) and noise.<br/>The main aim of this report is to assess the potential impact of replacing natural gas with 100% hydrogen on the guidance in IGEM/SR/23 concerned with thermal hazards with a secondary objective of assessing the available information to comment on the possible influence of hydrogen on noise.
Crack Management of Hydrogen Pipelines
Sep 2021
Publication
The climate emergency is one of the biggest challenges humanity must face in the 21st century. The global energy transition faces many challenges when it comes to ensuring a sustainable reliable and affordable energy supply. A likely outcome is decarbonizing the existing gas infrastructure. This will inevitably lead to greater penetration of hydrogen. While the introduction of hydrogen into natural gas transmission and distribution networks creates challenges there is nothing new or inherently impossible about the concept. Indeed more than 4000 kilometers of hydrogen pipelines are currently in operation. These pipelines however were (almost) all built and operated exclusively in accordance with specific hydrogen codes which tend to be much more restrictive than their natural gas equivalents. This means that the conversion of natural gas pipelines which have often been in service for decades and have accumulated damage and been subject to cracking threats (e.g. fatigue or stress corrosion cracking (SCC)) throughout their lifetime can be challenging. This paper will investigate the impact of transporting hydrogen on the crack management of existing natural gas pipelines from an overall integrity perspective. Different cracking threats will be described including recent industry experience of those which are generic to all steel pipelines but exacerbated by hydrogen and those which are hydrogen specific. The application of a Hydrogen Framework to identify characterise and manage credible cracking threats to pipelines in order to help enable the safe economic and successful introduction of hydrogen into the natural gas network will be discussed.
A Hydrogen Fuelled LH2 Tanker Ship Design
May 2021
Publication
This study provides a detailed philosophical view and evaluation of a viable design for a large liquid hydrogen tanker fuelled by liquid hydrogen. Established methods for determining tank sizing ship stability and ship characteristics were used to evaluate the preliminary design and performance of the liquefied hydrogen tanker named ‘JAMILA’ designed specifically to transport liquid hydrogen. JAMILA is designed around four large liquid hydrogen tanks with a total capacity of ∼280000 m3 and uses the boil-off gas for propulsion for the loaded leg of the journey. The ship is 370 m long 75 m wide and draws 10.012 m at full load. It has a fully loaded displacement tonnage of 232000 tonnes to carry 20000 tonnes of hydrogen. Its propulsion system contains a combined-cycle gas turbine of approximately 50 MW. The volume of the hydrogen cargo pressurised to 0.5 MPa primarily determines the size and displacement of the ship.
Technologies and Policies to Decarbonize Global Industry: Review and Assessment of Mitigation Drivers Through 2070
Mar 2020
Publication
Jeffrey Rissman,
Chris Bataille,
Eric Masanet,
Nate Aden,
William R. Morrow III,
Nan Zhou,
Neal Elliott,
Rebecca Dell,
Niko Heeren,
Brigitta Huckestein,
Joe Cresko,
Sabbie A. Miller,
Joyashree Roy,
Paul Fennell,
Betty Cremmins,
Thomas Koch Blank,
David Hone,
Ellen D. Williams,
Stephane de la Rue du Can,
Bill Sisson,
Mike Williams,
John Katzenberger,
Dallas Burtraw,
Girish Sethi,
He Ping,
David Danielson,
Hongyou Lu,
Tom Lorber,
Jens Dinkel and
Jonas Helseth
Fully decarbonizing global industry is essential to achieving climate stabilization and reaching net zero greenhouse gas emissions by 2050–2070 is necessary to limit global warming to 2 °C. This paper assembles and evaluates technical and policy interventions both on the supply side and on the demand side. It identifies measures that employed together can achieve net zero industrial emissions in the required timeframe. Key supply-side technologies include energy efficiency (especially at the system level) carbon capture electrification and zero-carbon hydrogen as a heat source and chemical feedstock. There are also promising technologies specific to each of the three top-emitting industries: cement iron & steel and chemicals & plastics. These include cement admixtures and alternative chemistries several technological routes for zero-carbon steelmaking and novel chemical catalysts and separation technologies. Crucial demand-side approaches include material-efficient design reductions in material waste substituting low-carbon for high-carbon materials and circular economy interventions (such as improving product longevity reusability ease of refurbishment and recyclability). Strategic well-designed policy can accelerate innovation and provide incentives for technology deployment. High-value policies include carbon pricing with border adjustments or other price signals; robust government support for research development and deployment; and energy efficiency or emissions standards. These core policies should be supported by labeling and government procurement of low-carbon products data collection and disclosure requirements and recycling incentives. In implementing these policies care must be taken to ensure a just transition for displaced workers and affected communities. Similarly decarbonization must complement the human and economic development of low- and middle-income countries.
Dedicated Large-scale Floating Offshore Wind to Hydrogen: Assessing Design Variables in Proposed Typologies
Mar 2022
Publication
To achieve the Net-Zero Emissions goal by 2050 a major upscale in green hydrogen needs to be achieved; this will also facilitate use of renewable electricity as a source of decarbonised fuel in hard-to-abate sectors such as industry and transport. Nearly 80% of the world’s offshore wind resource is in waters deeper than 60 m where bottom-fixed wind turbines are not feasible. This creates a significant opportunity to couple the high capacity factor floating offshore wind and green hydrogen. In this paper we consider dedicated large-scale floating offshore wind farms for hydrogen production with three coupling typologies; (i) centralised onshore electrolysis (ii) decentralised offshore electrolysis and (iii) centralised offshore electrolysis. The typology design is based on variables including for: electrolyser technology; floating wind platform; and energy transmission vector (electrical power or offshore hydrogen pipelines). Offshore hydrogen pipelines are assessed as economical for large and distant farms. The decentralised offshore typology employing a semi-submersible platform could accommodate a proton exchange membrane electrolyser on deck; this would negate the need for an additional separate structure or hydrogen export compression and enhance dynamic operational ability. It is flexible; if one electrolyser (or turbine) fails hydrogen production can easily continue on the other turbines. It also facilities flexibility in further expansion as it is very much a modular system. Alternatively less complexity is associated with the centralised offshore typology which may employ the electrolysis facility on a separate offshore platform and be associated with a farm of spar-buoy platforms in significant water depth locations.
Hydrogen Blending and the Gas Commercial Framework - Report on Conclusions of NIA study
Sep 2020
Publication
Blending hydrogen into the gas grid could be an important stepping stone during the transition to a sustainable net zero system. In particular it may: provide a significant and reliable source of demand for hydrogen producers supporting the investment case for hydrogen; provide learnings and incremental change towards what could potentially become a 100% hydrogen grid; and immediately decarbonise a portion of the gas flowing through the grid. Technical questions relating to hydrogen blending are being taken forward by the industry (e.g. through the HyDeploy project in relation to the maximum potential blend of hydrogen that can be accommodated without end user appliances needing to be altered or replaced). But if blending is to take place changes to commercial arrangements will be necessary as today these assume a relatively uniform gas quality. In particular the commercial framework will need to ensure that limits on the percentage of hydrogen that can safely be blended (currently expected to be around 20% by volume) are not exceeded. We have been commissioned by Cadent to undertake a Network Innovation Allowance (NIA) project to identify the changes required to the gas commercial framework that will enable hydrogen blending in the GB gas grid and to set out a roadmap for how these can be delivered. This report sets out our recommendations.
The Effect of Hydrogen Containing Fuel Blends Upon Flashback in Swirl Burners
Feb 2011
Publication
Lean premixed swirl combustion is widely used in gas turbines and many other combustion Processes due to the benefits of good flame stability and blow off limits coupled with low NOx emissions. Although flashback is not generally a problem with natural gas combustion there are some reports of flashback damage with existing gas turbines whilst hydrogen enriched fuel blends especially those derived from gasification of coal and/or biomass/industrial processes such as steel making cause concerns in this area. Thus this paper describes a practical experimental approach to study and reduce the effect of flashback in a compact design of generic swirl burner representative of many systems. A range of different fuel blends are investigated for flashback and blow off limits; these fuel mixes include methane methane/hydrogen blends pure hydrogen and coke oven gas. Swirl number effects are investigated by varying the number of inlets or the configuration of the inlets. The well known Lewis and von Elbe critical boundary velocity gradient expression is used to characterise flashback and enable comparison to be made with other available data. Two flashback phenomena are encountered here. The first one at lower swirl numbers involves flashback through the outer wall boundary layer where the crucial parameter is the critical boundary velocity gradient Gf. Values of Gf are of similar magnitude to those reported by Lewis and von Elbe for laminar flow conditions and it is recognised that under the turbulent flow conditions pertaining here actual gradients in the thin swirl flow boundary layer are much higher than occur under laminar flow conditions. At higher swirl numbers the central recirculation zone (CRZ) becomes enlarged and extends backwards over the fuel injector to the burner baseplate and causes flashback to occur earlier at higher velocities. This extension of the CRZ is complex being governed by swirl number equivalence ratio and Reynolds Number. Under these conditions flashback occurs when the cylindrical flame front surrounding the CRZ rapidly accelerates outwards to the tangential inlets and beyond especially with hydrogen containing fuel mixes. Conversely at lower swirl numbers with a modified exhaust geometry hence restricted CRZ flashback occurs through the outer thin boundary layer at much lower flow rates when the hydrogen content of the fuel mix does not exceed 30%. The work demonstrates that it is possible to run premixed swirl burners with a wide range of hydrogen fuel blends so as to substantially minimise flashback behaviour thus permitting wider used of the technology to reduce NOx emissions.
Technical and Commercial Challenges of Proton-Exchange Membrane (PEM) Fuel Cells
Dec 2020
Publication
This review critically evaluates the latest trends in fuel cell development for portable and stationary fuel cell applications and their integration into the automotive industry. Fast start-up high efficiency no toxic emissions into the atmosphere and good modularity are the key advantages of fuel cell applications. Despite the merits associated with fuel cells the high cost of the technology remains a key factor impeding its widespread commercialization. Therefore this review presents detailed information into the best operating conditions that yield maximum fuel cell performance. The paper recommends future research geared towards robust fuel cell geometry designs as this determines the cell losses and material characterization of the various cell components. When this is done properly it will support a total reduction in the cost of the cell which in effect will reduce the total cost of the system. Despite the strides made by the fuel cell research community there is a need for public sensitization as some people have reservations regarding the safety of the technology. This hurdle can be overcome if there is a well-documented risk assessment which also needs to be considered in future research activities.
Beyond the triangle of renewable Energy Acceptance: The Five Dimensions of Domestic Hydrogen Acceptance
Aug 2022
Publication
The ‘deep’ decarbonization of the residential sector is a priority for meeting national climate change targets especially in countries such as the UK where natural gas has been the dominant fuel source for over half a century. Hydrogen blending and repurposing the national grid to supply low-carbon hydrogen gas may offer respective short- and long-term solutions to achieving emissions reduction across parts of the housing sector. Despite this imperative the social acceptance of domestic hydrogen energy technologies remains underexplored by sustainability scholars with limited insights regarding consumer perceptions and expectations of the transition. A knowledge deficit of this magnitude is likely to hinder effective policymaking and may result in sub-optimal rollout strategies that derail the trajectory of the net zero agenda. Addressing this knowledge gap this study develops a conceptual framework for examining the consumer-facing side of the hydrogen transition. The paper affirms that the spatiotemporal patterns of renewable energy adoption are shaped by a range of interacting scales dimensions and factors. The UK’s emerging hydrogen landscape and its actor-network is characterized as a heterogenous system composed of dynamic relationships and interdependencies. Future studies should engage with domestic hydrogen acceptance as a co-evolving multi-scalar phenomenon rooted in the interplay of five distinct dimensions: attitudinal socio-political community market and behavioral acceptance. If arrived to behavioral acceptance helps realize the domestication of hydrogen heating and cooking established on grounds on cognitive sociopolitical and sociocultural legitimacy. The research community should internalize the complexity and richness of consumer attitudes and responses through a more critical and reflexive approach to the study of social acceptance.
Perspective on the Hydrogen Economy as a Pathway to Reach Net-zero CO2 Emissions in Europe
Jan 2022
Publication
The envisioned role of hydrogen in the energy transition – or the concept of a hydrogen economy – has varied through the years. In the past hydrogen was mainly considered a clean fuel for cars and/or electricity production; but the current renewed interest stems from the versatility of hydrogen in aiding the transition to CO2 neutrality where the capability to tackle emissions from distributed applications and complex industrial processes is of paramount importance. However the hydrogen economy will not materialise without strong political support and robust infrastructure design. Hydrogen deployment needs to address multiple barriers at once including technology development for hydrogen production and conversion infrastructure co-creation policy market design and business model development. In light of these challenges we have brought together a group of hydrogen researchers who study the multiple interconnected disciplines to offer a perspective on what is needed to deploy the hydrogen economy as part of the drive towards net-zero-CO2 societies. We do this by analysing (i) hydrogen end-use technologies and applications (ii) hydrogen production methods (iii) hydrogen transport and storage networks (iv) legal and regulatory aspects and (v) business models. For each of these we provide key take home messages ranging from the current status to the outlook and needs for further research. Overall we provide the reader with a thorough understanding of the elements in the hydrogen economy state of play and gaps to be filled.
Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel System
Aug 2022
Publication
Sudden releases of pressurised hydrogen may spontaneously ignite by the so-called “diffusion ignition” mechanism. Several experimental and numerical studies have been performed on spontaneous ignition for compressed hydrogen at ambient temperature. However there is no knowledge of the phenomenon for compressed hydrogen at cryogenic temperatures. The study aims to close this knowledge gap by performing numerical experiments using a computational fluid dynamics model validated previously against experiments at atmospheric temperatures to assess the effect of temperature decrease from ambient 300 K to cryogenic 80 K. The ignition dynamics is analysed for a T-shaped channel system. The cryo-compressed hydrogen is initially separated from the air in the T-shaped channel system by a burst disk (diaphragm). The inertia of the burst disk is accounted for in the simulations. The numerical experiments were carried out to determine the hydrogen storage pressure limit leading to spontaneous ignition in the configuration under investigation. It is found that the pressure limit for spontaneous ignition of the cryo-compressed hydrogen at temperature 80 K is 9.4 MPa. This is more than 3 times larger than pressure limit for spontaneous ignition of 2.9 MPa in the same setup at ambient temperature of 300 K.
Solar Hydrogen Fuel Generation from Wastewater—Beyond Photoelectrochemical Water Splitting: A Perspective
Oct 2022
Publication
Green hydrogen—a carbon-free renewable fuel—has the capability to decarbonise a variety of sectors. The generation of green hydrogen is currently restricted to water electrolysers. The use of freshwater resources and critical raw materials however limits their use. Alternative water splitting methods for green hydrogen generation via photocatalysis and photoelectrocatalysis (PEC) have been explored in the past few decades; however their commercial potential still remains unexploited due to the high hydrogen generation costs. Novel PEC-based simultaneous generation of green hydrogen and wastewater treatment/high-value product production is therefore seen as an alternative to conventional water splitting. Interestingly the organic/inorganic pollutants in wastewater and biomass favourably act as electron donors and facilitate the dual-functional process of recovering green hydrogen while oxidising the organic matter. The generation of green hydrogen through the dual-functional PEC process opens up opportunities for a “circular economy”. It further enables the end-of-life commodities to be reused recycled and resourced for a better life-cycle design while being economically viable for commercialisation. This review brings together and critically analyses the recent trends towards simultaneous wastewater treatment/biomass reforming while generating hydrogen gas by employing the PEC technology. We have briefly discussed the technical challenges associated with the tandem PEC process new avenues techno-economic feasibility and future directions towards achieving net neutrality.
Hydrogen vs. Batteries: Comparative Safety Assessments for a High-Speed Passenger Ferry
Mar 2022
Publication
Batteries and hydrogen constitute two of the most promising solutions for decarbonising international shipping. This paper presents the comparison between a battery and a proton-exchange membrane hydrogen fuel cell version of a high-speed catamaran ferry with a main focus on safety. The systems required for each version are properly sized and fitted according to the applicable rules and their impact on the overall design is discussed. Hazards for both designs were identified; frequency and consequence indexes for them were input qualitatively following Novel Technology Qualification and SOLAS Alternative Designs and Arrangements while certain risk control options were proposed in order to reduce the risks of the most concerned accidental events. The highest ranked risks were analysed by quantitative risk assessments in PyroSim software. The gas dispersion analysis performed for the hydrogen version indicated that it is crucial for the leakage in the fuel cell room to be stopped within 1 s after being detected to prevent the formation of explosive masses under full pipe rupture of 33 mm diameter even with 120 air changes per hour. For the battery version the smoke/fire simulation in the battery room indicated that the firefighting system could achieve a 30% reduction in fire duration with firedoors closed and ventilation shut compared to the scenario without a firefighting system.
Stochastic Low-order Modelling of Hydrogen Autoignition in a Turbulent Non-premixed Flow
Jul 2022
Publication
Autoignition risk in initially non-premixed flowing systems such as premixing ducts must be assessed to help the development of low-NOx systems and hydrogen combustors. Such situations may involve randomly fluctuating inlet conditions that are challenging to model in conventional mixture-fraction-based approaches. A Computational Fluid Dynamics (CFD)-based surrogate modelling strategy is presented here for fast and accurate predictions of the stochastic autoignition behaviour of a hydrogen flow in a hot air turbulent co-flow. The variability of three input parameters i.e. inlet fuel and air temperatures and average wall temperature is first sampled via a space-filling design. For each sampled set of conditions the CFD modelling of the flame is performed via the Incompletely Stirred Reactor Network (ISRN) approach which solves the reacting flow governing equations in post-processing on top of a Large Eddy Simulation (LES) of the inert hydrogen plume. An accurate surrogate model namely a Gaussian Process is then trained on the ISRN simulations of the burner and the final quantification of the variability of autoignition locations is achieved by querying the surrogate model via Monte Carlo sampling of the random input quantities. The results are in agreement with the observed statistics of the autoignition locations. The methodology adopted in this work can be used effectively to quantify the impact of fluctuations and assist the design of practical combustion systems. © 2022 The Authors. Published by Elsevier Inc. on behalf of The Combustion Institute.
Prospects of Fuel Cell Combined Heat and Power Systems
Aug 2020
Publication
Combined heat and power (CHP) in a single and integrated device is concurrent or synchronized production of many sources of usable power typically electric as well as thermal. Integrating combined heat and power systems in today’s energy market will address energy scarcity global warming as well as energy-saving problems. This review highlights the system design for fuel cell CHP technologies. Key among the components discussed was the type of fuel cell stack capable of generating the maximum performance of the entire system. The type of fuel processor used was also noted to influence the systemic performance coupled with its longevity. Other components equally discussed was the power electronics. The thermal and water management was also noted to have an effect on the overall efficiency of the system. Carbon dioxide emission reduction reduction of electricity cost and grid independence were some notable advantages associated with fueling cell combined heat and power systems. Despite these merits the high initial capital cost is a key factor impeding its commercialization. It is therefore imperative that future research activities are geared towards the development of novel and cheap materials for the development of the fuel cell which will transcend into a total reduction of the entire system. Similarly robust systemic designs should equally be an active research direction. Other types of fuel aside hydrogen should equally be explored. Proper risk assessment strategies and documentation will similarly expand and accelerate the commercialization of this novel technology. Finally public sensitization of the technology will also make its acceptance and possible competition with existing forms of energy generation feasible. The work in summary showed that proton exchange membrane fuel cell (PEM fuel cell) operated at a lower temperature-oriented cogeneration has good efficiency and is very reliable. The critical issue pertaining to these systems has to do with the complication associated with water treatment. This implies that the balance of the plant would be significantly affected; likewise the purity of the gas is crucial in the performance of the system. An alternative to these systems is the PEM fuel cell systems operated at higher temperatures.
Does the United Kingdom Have Sufficient Geological Storage Capacity to Support a Hydrogen Economy? Estimating the Salt Cavern Storage Potential of Bedded Halite Formations
Jun 2022
Publication
Hydrogen can be used to enable decarbonisation of challenging applications such as provision of heat and as a fuel for heavy transport. The UK has set out a strategy for developing a new low carbon hydrogen sector by 2030. Underground storage will be a key component of any regional or national hydrogen network because of the variability of both supply and demand across different end-use applications. For storage of pure hydrogen salt caverns currently remain the only commercially proven subsurface storage technology implemented at scale. A new network of hydrogen storage caverns will therefore be required to service a low carbon hydrogen network. To facilitate planning for such systems this study presents a modelling approach used to evaluate the UK's theoretical hydrogen storage capacity in new salt caverns in bedded rock salt. The findings suggest an upper bound potential for hydrogen storage exceeding 64 million tonnes providing 2150 TWh of storage capacity distributed in three discrete salt basins in the UK. The modelled cavern capacity has been interrogated to identify the practical inter-seasonal storage capacity suitable for integration in a hydrogen transmission system. Depending on cavern spacing a peak load deliverability of between 957 and 1876 GW is technically possible with over 70% of the potential found in the East Yorkshire and Humber region. The range of geologic uncertainty affecting the estimates is approximately ±36%. In principle the peak domestic heating demand of approximately 170 GW across the UK can be met using the hydrogen withdrawn from caverns alone albeit in practice the storage potential is unevenly distributed. The analysis indicates that the availability of salt cavern storage potential does not present a limiting constraint for the development of a low-carbon hydrogen network in the UK. The general framework presented in this paper can be applied to other regions to estimate region-specific hydrogen storage potential in salt caverns.
Hydrogen Jet Fire from a Thermally Activated Pressure Relief Device (TPRD) from Onboard Storage in a Naturally Ventilated Covered Car Park
Aug 2021
Publication
Hydrogen jet fires from a thermally activated pressure relief device (TPRD) on onboard storage are considered for a vehicle in a naturally ventilated covered car park. Computational Fluid Dynamics was used to predict behaviour of ignited releases from a 70 MPa tank into a naturally ventilated covered car park. Releases through TPRD diameters 3.34 2 and 0.5 mm were studied to understand effect on hazard distances from the vehicle. A vertical release and downward releases at 0° 30° and 45° for TPRD diameters 2 and 0.5 mm were considered accounting for tank blowdown. direction of a downward release was found to significantly contribute to decrease of temperature in a hot cloud under the ceiling. Whilst the ceiling is reached by a jet exceeding 300 °C for a release through a TPRD of 2 mm for inclinations of either 0° 30° or 45° an ignited release through a TPRD of 0.5 mm and angle of 45° did not produce a cloud with a temperature above 300 °C at the ceiling during blowdown. The research findings specifically regarding the extent of the cloud of hot gasses have implications for the design of mechanical ventilation systems.
Future Energy Scenarios 2021
Jul 2022
Publication
Our Future Energy Scenarios (FES) draw on hundreds of experts’ views to model four credible energy pathways for Britain over coming decades. Matthew Wright our head of strategy and regulation outlines what the 2021 outlook means for consumers society and the energy system itself.<br/>This year’s Future Energy Scenarios insight reveals a glimpse of a Britain that is powered with net zero carbon emissions.<br/>Our analysis shows that our country can achieve its legally-binding carbon reduction targets: in three out of four scenarios in the analysis the country reaches net zero carbon emissions by 2050 with Leading the Way – our most ambitious scenario – achieving it in 2047 and becoming net negative by 2050.
An Energy Systems Model of a Large Commercial Liquid Hydrogen Aircraft in a Low-carbon Future
Apr 2023
Publication
Liquid hydrogen (LH2) aircraft have the potential to achieve carbon neutrality. However if the hydrogen is produced using electricity grids that utilise fossil fuel they have a non-zero carbon dioxide (CO2) emission associated with their well-to-wing pathway. To assess the potential of LH2 in aviation decarbonisation an energy systems comparison of large commercial LH2 liquified natural gas (LNG) conventional Jet-A and LH2 dual-fuel aircraft is presented. The performance of each aircraft is compared towards 2050 over which three system changes occur: (1) LH2 aircraft technology develops; (2) both world average and region-specific grid electricity which is used to produce the hydrogen decarbonises; and (3) the International Air Transportation Association (IATA) emissions targets which are used to restrict the passenger-range performance of each aircraft tighten. In 2050 the emissions of all aircraft are thus constrained to 0.063 kg-CO2/p-km relative to 0.110 kg-CO2/p-km for the unconstrained Jet A fuelled Boeing 787-8. It is estimated that in this year an LH2 aircraft powered by fuel cells and sourcing world average electricity can travel 6000 km 20% further than the conventional Jet A aircraft that is also constrained to meet the IATA targets but not as far as the LNG aircraft. At its maximum range the LH2 aircraft carries 84% of the Jet A passenger demand. Analysis using region-specific hydrogen indicates that LH2 aircraft can travel further than LNG aircraft in North America only accounting for 17% of the global demand. 1.59 times the current aviation energy consumption is required if all conventional aircraft are replaced with LH2 designs. Under stricter emissions constraints than those outlined by the IATA LH2 outperforms LNG in Europe and the Americas accounting for 41% of the global demand. Also in these regions the range energy consumption and passenger capacity of LH2 aircraft can be improved upon by combining the advantages of LH2 with LNG in dual-fuel aircraft concepts. The use of LH2 is therefore advantageous within several prominent niches of a future decarbonising aviation system.
Purging Hydrogen Distribution Pipelines: Literature Review, Description of Recent Experiments and Proposed Future Work
Sep 2023
Publication
The aim of the H21 project is to undertake measurements analysis and field trials to support the safe repurposing of Great Britain’s natural gas distribution network for hydrogen. As part of this project work has been ongoing to identify aspects of existing natural gas procedures that will need to be modified for hydrogen and to support the development of new procedures. This has included a review of the scientific basis of current displacement purging practices analysis of the potential implications of switching from natural gas to hydrogen and experimental support work. The reduced density and viscosity of hydrogen means that minimum purging velocities should (in principle) be higher for hydrogen to avoid stratification and ensure adequate removal of the purged gas during pipeline purging operations. A complicating factor is the high molecular diffusivity of hydrogen (roughly three times that of natural gas) which causes hydrogen to mix over short distances more rapidly than natural gas. Current models for pipeline purging do not take into account the mixing effect related to molecular diffusion. The wider flammable limits lower ignition energy and greater potential for combustion to transition from deflagration to detonation with hydrogen means that indirect purging with nitrogen is currently being investigated for distribution pipelines. This paper reviews the ongoing analysis of hydrogen pipeline purging and discusses a potential future scientific programme of work aimed at developing a new pipeline purging model that accounts for molecular diffusion effects.
Decarbonisation of Heat in Great Britain
Oct 2021
Publication
This study was conducted for a group of 15 clients in the public and private sectors interested in potential pathways for decarbonising residential heating and the impact of these pathways on the energy system. The ambition for all new heating installations to be low carbon from 2035 is essential to meeting the net zero target in 2050 and our study found that electricity demand for home heating is set to quadruple by 2050 as part of the shift away from gas-fired boilers.
The key findings from the study include:
The key findings from the study include:
- Phasing out natural gas boiler installations by 2035 is crucial for eliminating CO2 from home heating; delaying to 2040 could leave us with ¼ of today’s home heat emissions in 2050
- Achieving deployment of 600k heat pumps per year by 2028 will require policy intervention both to lower costs and to inform and protect consumers Almost £40bn could be saved in cumulative system costs by 2050 through adoption of more efficient and flexible electric heating technologies like networked heat pumps and storage
- Electricity demand from heating could quadruple by 2050 to over 100TWh per year almost a third of Great Britain’s current total annual electricity demand Using hydrogen for a share of heating could lower peak power demand although producing most of this hydrogen from electrolysis would raise overall power demand.
The Role of Hydrogen in Powering Industry: APPG on Hydrogen report
Jul 2021
Publication
The APPG on Hydrogen has published its report urging the Government to deliver beyond its existing net zero commitments and set ambitious hydrogen targets in forthcoming strategies to reach net zero by 2050.
The All-Party Parliamentary Group (APPG) on Hydrogen’s report on the role of ‘Hydrogen in powering industry’ sets out 10 recommendations to support and accelerate the growth of the UK’s hydrogen sector and enable a sustainable energy transition.
The All-Party Parliamentary Group (APPG) on Hydrogen’s report on the role of ‘Hydrogen in powering industry’ sets out 10 recommendations to support and accelerate the growth of the UK’s hydrogen sector and enable a sustainable energy transition.
- The Government must continue to expand beyond its existing commitments of 5GW production in the forthcoming Hydrogen Strategy.
- Any forthcoming Government and devolved policies must be complementary of the wider UK low-carbon commitments.
- Industrial clusters should be prioritised for hydrogen use and will be the key catalyst for driving forward the UK’s decarbonisation of industry.
- The Government must commit to incentivising hydrogen production within the UK as opposed to importing this.
- The Government must align hydrogen production pathways with nuclear technology to enhance hydrogen production.
- The Government must develop a UK wide hydrogen network to support the transport sector including a larger-scale implementation of hydrogen refuelling stations.
- Regulators must act quickly to update energy regulations and guidance to support hydrogen’s role in powering industry.
- For hydrogen to expand in the UK a technology neutral approach is required for all types of energy systems.
- Significant and long-term financial support is required for the development deployment and operation of hydrogen technologies.
- Ofgem must ensure the hydrogen market is subject to effective competition to drive down prices for consumers.
Rational Design and Application of Covalent Organic Frameworks for Solar Fuel Production
Jul 2021
Publication
Harnessing solar energy and converting it into renewable fuels by chemical processes such as water splitting and carbon dioxide (CO2 ) reduction is a highly promising yet challenging strategy to mitigate the effects arising from the global energy crisis and serious environmental concerns. In recent years covalent organic framework (COF)-based materials have gained substantial research interest because of their diversified architecture tunable composition large surface area and high thermal and chemical stability. Their tunable band structure and significant light absorption with higher charge separation efficiency of photoinduced carriers make them suitable candidates for photocatalytic applications in hydrogen (H2) generation CO2 conversion and various organic transformation reactions. In this article we describe the recent progress in the topology design and synthesis method of COF-based nanomaterials by elucidating the structure-property correlations for photocatalytic hydrogen generation and CO2 reduction applications. The effect of using various kinds of 2D and 3D COFs and strategies to control the morphology and enhance the photocatalytic activity is also summarized. Finally the key challenges and perspectives in the field are highlighted for the future development of highly efficient COF-based photocatalysts.
Life Cycle Costing Analysis: Tools and Applications for Determining Hydrogen Production Cost for Fuel Cell Vehicle Technology
Jul 2021
Publication
This work investigates life cycle costing analysis as a tool to estimate the cost of hydrogen to be used as fuel for Hydrogen Fuel Cell vehicles (HFCVs). The method of life cycle costing and economic data are considered to estimate the cost of hydrogen for centralised and decentralised production processes. In the current study two major hydrogen production methods are considered methane reforming and water electrolysis. The costing frameworks are defined for hydrogen production transportation and final application. The results show that hydrogen production via centralised methane reforming is financially viable for future transport applications. The ownership cost of HFCVs shows the highest cost among other costs of life cycle analysis.
Hy4Heat Safety Assessment: Precis - Work Package 7
May 2021
Publication
The Hy4Heat Safety Assessment has focused on assessing the safe use of hydrogen gas in certain types of domestic properties and buildings. The summary reports (the Precis and the Safety Assessment Conclusions Report) bring together all the findings of the work and should be looked to for context by all readers. The technical reports should be read in conjunction with the summary reports. While the summary reports are made as accessible as possible for general readers the technical reports may be most accessible for readers with a degree of technical subject matter understanding. All of the safety assessment reports have now been reviewed by the HSE.<br/><br/>This document is an overview of the Safety Assessment work undertaken as part of the Hy4Heat programme
Net Zero after Covid: Behavioural Principles for Building Back Better
Dec 2020
Publication
Alongside our Sixth Carbon Budget Advice the Climate Change Committee (CCC) are publishing a paper from Professor Nick Chater the Committee’s behavioural science specialist. This paper considers three behavioural principles that explain how people have adapted so rapidly and how we might “build back better” as we emerge from the pandemic with a particular focus on meeting the challenge of dramatically reducing greenhouse gas (GHG) emissions over the coming decades. The principles are:
- The power law of practice: People organizations and whole industries learn to adapt to new ways of working following a surprisingly predictable pattern. This can help predict where adaptation to new ways of living and working is likely to succeed or fail.
- The status quo effect: People and organizations tend to prefer the current status quo but can often adjust rapidly to prefer a new status quo. However we tend to systematically underestimate such effects and therefore can sometimes resist changes that in retrospect we may ultimately prefer.
- Unwritten rules: Our social behaviour is guided by implicit guidelines about what is “appropriate” which can be somewhat independent of our personal values. Changing these implicit rules alongside changes in regulation and the law is crucial to adapting to new circumstances—and the pandemic has shown that rapid change is possible though sometimes resisted (e.g. new norms about mask wearing and social distancing).
Performance and Emission Optimisation of an Ammonia/ Hydrogen Fuelled Linear Joule Engine Generator
Mar 2024
Publication
This paper presents a Linear Joule Engine Generator (LJEG) powered by ammonia and hydrogen co-combustion to tackle decarbonisation in the electrification of transport propulsion systems. A dynamic model of the LJEG which integrates mechanics thermodynamics and electromagnetics sub-models as well as detailed combustion chemistry analysis for emissions is presented. The dynamic model is integrated and validated and the LJEG performance is optimised for improved performance and reduced emissions. At optimal conditions the engine could generate 1.96 kWe at a thermal efficiency of 34.3% and an electrical efficiency of 91%. It is found that the electromagnetic force of the linear alternator and heat addition from the external combustor and engine valve timing have the most significant influences on performance whereas the piston stroke has a lesser impact. The impacts of hydrogen ratio oxygen concentration inlet pressure and equivalence ratio of ammonia-air on nitric oxide (NO) formation and reduction are revealed using a detailed chemical kinetic analysis. Results indicated that rich combustion and elevated pressure are beneficial for NO reduction. The rate of production analysis indicates that the equivalence ratio significantly changes the relative contribution among the critical NO formation and reduction reaction pathways.
The Role of Hydrogen and Batteries in Delivering Net Zero in the UK by 2050
Apr 2023
Publication
This report presents an analysis of how hydrogen and battery technologies are likely to be utilised in different sectors within the UK including transportation manufacturing the built environment and power. In particular the report compares the use of hydrogen and battery technology across these sectors. In addition it evaluates where these technologies will be in competition where one technology will dominate and where a combination of the two may be used. This sector analysis draws on DNV’s knowledge and experience within both the battery and hydrogen industries along with a review of studies available in the public domain. The analysis has been incorporated into DNV’s Energy Transition Outlook model an integrated system-dynamics simulation model covering the energy system which provides an independent view of the energy outlook from now until 2050. The modelling which includes data on costs demand supply policy population and economic indicators enables the non-linear interdependencies between different parameters to be considered so that decisions made in one sector influence the decision made in another.
Underground Hydrogen Storage to Balance Seasonal Variations in Energy Demand: Impact of Well Configuration on Storage Performance in Deep Saline Aquifers
Mar 2023
Publication
Grid-scale underground hydrogen storage (UHS) is essential for the decarbonization of energy supply systems on the path towards a zero-emissions future. This study presents the feasibility of UHS in an actual saline aquifer with a typical dome-shaped anticline structure to balance the potential seasonal mismatches between energy supply and demand in the UK domestic heating sector. As a main requirement for UHS in saline aquifers we investigate the role of well configuration design in enhancing storage performance in the selected site via numerical simulation. The results demonstrate that the efficiency of cyclic hydrogen recovery can reach around 70% in the short term without the need for upfront cushion gas injection. Storage capacity and deliverability increase in successive storage cycles for all scenarios with the co-production of water from the aquifer having a minimal impact on the efficiency of hydrogen recovery. Storage capacity and deliverability also increase when additional wells are added to the storage site; however the distance between wells can strongly influence this effect. For optimum well spacing in a multi-well storage scenario within a dome-shaped anticline structure it is essential to attain an efficient balance between well pressure interference effects at short well distances and the gas uprising phenomenon at large distances. Overall the findings obtained and the approach described can provide effective technical guidelines pertaining to the design and optimization of hydrogen storage operations in deep saline aquifers.
Hydrogenerally - Episode 9: Nuclear Hydrogen
Jan 2023
Publication
In this episode of the podcast Debra Jones Chemistry Knowledge Transfer Manager and Ray Chegwin Nuclear Knowledge Transfer Manager from Innovate UK KTN talk about nuclear uses for hydrogen with special guest Allan Simpson Technical Lead at the National Nuclear Laboratory.
The podcast can be found on their website.
The podcast can be found on their website.
Refuelling Infrastructure Requirements for Renewable Hydrogen Road Fuel through the Energy Transition
Nov 2022
Publication
Current commercially available options for decarbonisation of road transport are battery electric vehicles or hydrogen fuel cell electric vehicles. BEVs are increasingly deployed while hydrogen is in its infancy. We examine the infrastructure necessary to support hydrogen fuelling to various degrees of market penetration. Scotland makes a good exemplar of transport transition with a world leading Net-Zero ambition and proven pathways for generating ample renewable energy. We identified essential elements of the new transport systems and the associated capital expenditure. We developed nine scenarios based on the pace of change and the ultimate market share of hydrogen and constructed a model to analyse their infrastructure requirements. This is a multi-period model incorporating Monte Carlo and Markov Chain elements. A “no-regrets” initial action is rapid deployment of enough hydrogen infrastructure to facilitate the early years of a scenario where diesel fuel becomes replaced with hydrogen. Even in a lower demand scenario of only large and heavy goods vehicles using hydrogen the same infrastructure would be required within a further two years. Subsequent investment in infrastructure could be considered in the light of this initial development.
Ammonia as a Suitable for Fuel Cells
Aug 2014
Publication
Ammonia an important basic chemical is produced at a scale of 150 million tons per year. Half of hydrogen produced in chemical industry is used for ammonia production. Ammonia containing 17.5 wt% hydrogen is an ideal carbon-free fuel for fuel cells. Compared to hydrogen ammonia has many advantages. In this mini-review the suitability of ammonia as fuel for fuel cells the development of different types of fuel cells using ammonia as the fuel and the potential applications of ammonia fuel cells are briefly reviewed.
The Hydrogen Bike: Communicating the Production and Safety of Green Hydrogen
Mar 2021
Publication
As the international community aims to reduce its reliance on fossil fuels green hydrogen has great potential to replace methane as a clean source of fuel. A novel public engagement activity The Hydrogen Bike has been developed to demonstrate the production and use of green hydrogen from water. The aim of the activity is to educate entertain and inform young people and adults so that they have an opportunity to form an opinion about the use of hydrogen as a fuel. Using a novel two-part data collection system participants are briefly surveyed for their opinion on hydrogen before and after participating in The Hydrogen Bike activity. Through this we have found that most participants (73%) are considered to have no opinion or a neutral opinion on hydrogen before participating in The Hydrogen Bike activity. After participation 88% of those who were originally neutral or had no opinion on hydrogen self-reported a positive feeling about hydrogen. The method of data collection was quick intuitive and suitable for an audience attracted from passing footfall.
Propulsion System Integration for a First-generation Hydrogen Civil Airliner?
May 2021
Publication
An unusual philosophical approach is proposed here to decarbonise larger civil aircraft that fly long ranges and consume a large fraction of civil aviation fuel. These inject an important amount of carbon emissions into the atmosphere and holistic decarbonising solutions must consider this sector. A philosophical–analytical investigation is reported here on the feasibility of an airliner family to fly over long ranges and assist in the elimination of carbon dioxide emissions from civil aviation. Backed by state-of-the-art correlations and engine performance integration analytical tools a family of large airliners is proposed based on the development and integration of the body of a very large two-deck four-engine airliner with the engines wings and flight control surfaces of a very long-range twin widebody jet. The proposal is for a derivative design and not a retrofit. This derivative design may enable a swifter entry to service. The main contribution of this study is a philosophical one: a carefully evaluated aircraft family that appears to have very good potential for first-generation hydrogen-fuelled airliners using gas turbine engines for propulsion. This family offers three variants: a 380-passenger aircraft with a range of 3300nm a 330-passenger aircraft with a range of 4800nm and a 230- passenger aircraft with a range of 5500nm. The latter range is crucially important because it permits travel from anywhere in the globe to anywhere else with only one stop. The jet engine of choice is a 450kN high-bypass turbofan.
Hydrogen Production, Storage, Utilisation and Environmental Impacts: A Review
Oct 2021
Publication
Dihydrogen (H2) commonly named ‘hydrogen’ is increasingly recognised as a clean and reliable energy vector for decarbonisation and defossilisation by various sectors. The global hydrogen demand is projected to increase from 70 million tonnes in 2019 to 120 million tonnes by 2024. Hydrogen development should also meet the seventh goal of ‘affordable and clean energy’ of the United Nations. Here we review hydrogen production and life cycle analysis hydrogen geological storage and hydrogen utilisation. Hydrogen is produced by water electrolysis steam methane reforming methane pyrolysis and coal gasification. We compare the environmental impact of hydrogen production routes by life cycle analysis. Hydrogen is used in power systems transportation hydrocarbon and ammonia production and metallugical industries. Overall combining electrolysis-generated hydrogen with hydrogen storage in underground porous media such as geological reservoirs and salt caverns is well suited for shifting excess of-peak energy to meet dispatchable on-peak demand.
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