Transmission, Distribution & Storage
Evaluation of Strength and Fracture Toughness of Ferritic High Strength Steels Under Hydrogen Environments
Sep 2017
Publication
The susceptibility of high strength ferritic steels to hydrogen-assisted fracture in hydrogen gas is usually evaluated by mechanical testing in high-pressure hydrogen gas or testing in air after pre-charging the specimens with hydrogen. We have used this second methodology conventionally known as internal hydrogen. Samples were pre-charged in an autoclave under 195 bar of pure hydrogen at 450ºC for 21 hours.Different chromium-molybdenum ste Read More
Hydrogen Embrittlement of Steel Pipelines During Transients
May 2021
Publication
Blending hydrogen into natural gas pipelines is a recent alternative adopted for hydrogen transportation as a mixture with natural gas. In this paper hydrogen embrittlement of steel pipelines originally designed for natural gas transportation is investigated. Solubility permeation and diffusion phenomena of hydrogen molecules into the crystalline lattice structure of the pipeline material are followed up based on transient evolution of internal pressure applied on Read More
Hydrogen Embrittlement and Notch Tensile Strength of Pearlitic Steel: A Numerical Approach
Dec 2020
Publication
This paper offers a numerical approach to the problem of hydrogen embrittlement and notch tensile strength of sharply notched specimens of high-strength pearlitic steel supplied in the form of hot rolled bars by using the finite element method in order to determine how the notch depth influences the concentration of hydrogen in the steady-state regime for different loading values. Numerical results show that the point of maximum hydrostatic s Read More
Hydrogen Embrittlement in Advanced High Strength Steels and Ultra High Strength Steels: A New Investigation Approach
Dec 2018
Publication
In order to reduce CO2 emissions and fuel consumption and to respect current environmental norms the reduction of vehicles weight is a primary target of the automotive industry. Advanced High Strength Steels (AHSS) and Ultra High Strength Steel (UHSS) which present excellent mechanical properties are consequently increasingly used in vehicle manufacturing. The increased strength to mass ratio compensates the higher cost per kg and AHSS and Read More
Hydrogen-assisted Cracking Paths in Oriented Pearlitic Microstructures: Resembling Donatello Wooden Sculpture Texture (DWST) & Mantegna’s Dead Christ Perspective (MDCP)
Jun 2020
Publication
Progressive cold drawing in eutectoid steel produces a preferential orientation of pearlitic colonies and ferrite/cementite lamellae thus inducing strength anisotropy in the steel and mixed mode propagation. While in the hot rolled steel (not cold drawn) the pearlitic microstructure is randomly oriented and the crack progresses in hydrogen by breaking the ferrite/cementite lamellae in heavily drawn steels the pearlitic microstructure is fully oriented and t Read More
Requirements for Hydrogen Resistance of Materials in CI Engine Toxic Substances Powered by Biofuels
Aug 2019
Publication
It has been described the conception of using platinum catalytic layer in multi hole fuel injector atomizer. The catalytic layer has been placed on not working part of atomizer needle. The aim of modification was activation of dehydrogenation reaction paraffin to olefin hydrocarbons with escape hydrogen molecule in CI engine bio fuel. The modification of atomizer with catalytic layer and reaction process leads to the presence of hydrogen and its influence on Read More
Hydrogen-induced Failure of TiNi Based Alloy with Coarse-grained and Ultrafine-grained Structure
Jul 2016
Publication
The objective of this work is to investigate the effect of hydrogen-induced fracture of TiNi-based alloy. In this report we performed the first studies comparing inelastic properties and fracture of the specimens of the binary alloy of TiNi wire under the action of hydrogen with coarse-grained (CG) and ultrafine-grained (UFG) microstructure. It is shown that hydrogen embrittlement (HE) occurs irrespective of the grain size in the studied specimens at approximatel Read More
Effect of α′ Martensite Content Induced by Tensile Plastic Prestrain on Hydrogen Transport and Hydrogen Embrittlement of 304L Austenitic Stainless Steel
Aug 2018
Publication
Effects of microstructural changes induced by prestraining on hydrogen transport and hydrogen embrittlement (HE) of austenitic stainless steels were studied by hydrogen precharging and tensile testing. Prestrains higher than 20% at 20 °C significantly enhance the HE of 304L steel as they induce severe α′ martensite transformation accelerating hydrogen transport and hydrogen entry during subsequent hydrogen exposure. In contrast 304L steel pre Read More
Hydrogen Assisted Cracking in Pearlitic Steel Rods: The Role of Residual Stresses Generated by Fatigue Precracking
May 2017
Publication
Stress corrosion cracking (SCC) of metals is an issue of major concern in engineering since this phenomenon causes many catastrophic failures of structural components in aggressive environments. SCC is even more harmful under cathodic conditions promoting the phenomenon known as hydrogen assisted cracking (HAC) hydrogen assisted fracture (HAF) or hydrogen embrittlement (HE). A common way to assess the susceptibility of a given material t Read More
Environmentally-Assisted Cracking of Type 316L Austenitic Stainless Steel in Low Pressure Hydrogen Steam Environments
Aug 2019
Publication
A low pressure superheated hydrogen-steam system has been used to accelerate the oxidation kinetics while keeping the electrochemical conditions similar to those of the primary water in a pressurized water reactor. The initiation has been investigated using a Constant Extension Rate Tensile (CERT) test. Tests were performed on flat tapered specimens made from Type 316L austenitic stainless steel with strain rates of 2×10-6 and 2×10-8 ms-1 at room t Read More
Recent Advances on the Thermal Destabilization of Mg-based Hydrogen Storage Materials
Jan 2021
Publication
Magnesium hydride and its compounds have a high hydrogen storage capacity and are inexpensive and thus have been considered as one of the most promising hydrogen storage materials for on-board applications. Nevertheless Mg/MgH2 systems suffer from great drawbacks in terms of kinetics and thermodynamics for hydrogen uptake/release. Over the past decades although significant progress has been achieved with respect to hydrogen s Read More
Engineering Thoughts on Hydrogen Embrittlement
Jul 2018
Publication
Hydrogen Embrittlement (HE) is a topical issue for pipelines transporting sour products. Engineers need a simple and effective approach in materials selection at design stage. In other words they must know if a material is susceptible to cracking to be able of:selecting the right material and apply correct operational measures during the service life.Following ASTM F2078 HE is “a permanent loss of ductility in a metal or alloy caused by hydrogen in combination Read More
Hydrogen Impacts on Downstream Installation and Appliances
Nov 2019
Publication
The report analyses the technical impacts to end-users of natural gas in Australian distribution networks when up to 10% hydrogen (by volume) is mixed with natural gas.The full report can be found at this link.
Ab Initio Study of the Combined Effects of Alloying Elements and H on Grain Boundary Cohesion in Ferritic Steels
Mar 2019
Publication
Hydrogen enhanced decohesion is expected to play a major role in ferritic steels especially at grain boundaries. Here we address the effects of some common alloying elements C V Cr and Mn on the H segregation behaviour and the decohesion mechanism at a Σ5(310)[001] 36.9∘ grain boundary in bcc Fe using spin polarized density functional theory calculations. We find that V Cr and Mn enhance grain boundary cohesion. Furthermore all elements Read More
Quantification of Temperature Dependence of Hydrogen Embrittlement in Pipeline Steel
Feb 2019
Publication
The effects of temperature on bulk hydrogen concentration and diffusion have been tested with the Devanathan–-Stachurski method. Thus a model based on hydrogen potential diffusivity loading frequency and hydrostatic stress distribution around crack tips was applied in order to quantify the temperature’s effect. The theoretical model was verified experimentally and confirmed a temperature threshold of 320 K to maximize the crack growth. The model sug Read More
Hydrogen Embrittlement Susceptibility of Prestressing Steel Wires: The Role of the Cold-drawing Conditions
Jul 2016
Publication
Prestressing steel wires are highly susceptible to hydrogen embrittlement (HE). Residual stress-strain state produced after wire drawing plays an essential role since hydrogen damage at certain places of the material is directly affected by stress and strain fields. Changes in wire drawing conditions modify the stress and strain fields and consequently the HE susceptibility and life in service of these structural components in the presence of a hydrogenatin Read More
Hydrogen Effect on the Cyclic Behavior of a Superelastic NiTi Archwire
Mar 2019
Publication
In this work we are interested in examining the strain rate effect on the mechanical behavior of Ni–Ti superelastic wires after hydrogen charging and ageing for 24 h. Specimens underwent 50 cycles of loading-unloading reaching an imposed deformation of 7.6%. During loading strain rates from 10−4 s−1 to 10−2 s−1 were achieved. With a strain rate of 10−2 s−1 the specimens were charged by hydrogen for 6 h and aged for one day showed a superelastic Read More
Effects of Thermomechanical Processing on Hydrogen Embrittlement Properties of Ultrahigh-Strength TRIP-Aided Bainitic Ferrite Steels
Jan 2022
Publication
The effects of thermomechanical processing on the microstructure and hydrogen embrittlement properties of ultrahigh-strength low-alloy transformation-induced plasticity (TRIP)-aided bainitic ferrite (TBF) steels were investigated to apply to automobile forging parts such as engine and drivetrain parts. The hydrogen embrittlement properties were evaluated by conducting conventional tensile tests after hydrogen charging and constant load four-point Read More
Effects of Hydrogen Pressure, Test Frequency and Test Temperature on Fatigue Crack Growth Properties of Low-carbon Steel in Gaseous Hydrogen
Jul 2016
Publication
Fatigue crack growth (FCG) tests for compact tension (CT) specimens of an annealed low-carbon steel JIS-SM490B were performed under various combinations of hydrogen pressures ranging from 0.1 to 90 MPa test frequencies from 0.001 to 10 Hz and test temperatures of room temperature (RT) 363 K and 423 K. In the hydrogen pressures of 0.1 0.7 and 10 MPa at RT the FCG rate increased with a decrease in the test frequency; then peaked out. I Read More
Hydrogen Embrittlement in a 2101 Lean Duplex Stainless Steel
Sep 2019
Publication
Duplex Stainless Steels (DSSs) are an attractive class of materials characterized by a strong corrosion resistance in many aggressive environments. Thanks to the high mechanical performances DSSs are widely used for many applications in petrochemical industry chemical and nuclear plants marine environment desalination etc.Among the DSSs critical aspects concerning the embrittlement process it is possible to remember the steel sensitization and the h Read More
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