Applications & Pathways
Research Progress on Gas Supply System of Proton Exchange Membrane Fuel Cells
Jun 2024
Publication
Proton exchange membrane fuel cells (PEMFCs) are attracting attention for their green energy-saving and high-efficiency advantages becoming one of the future development trends of renewable energy utilization. However there are still deficiencies in the gas supply system control strategy that plays a crucial role in PEMFCs which limits the rapid development and application of PEMFCs. This paper provides a comprehensive and in-depth review of the PEMFC air delivery system (ADS) and hydrogen delivery system (HDS) operations. For the ADS the advantages and disadvantages of the oxygen excess ratio (OER) oxygen pressure and their decoupling control strategies are systematically described by the following three aspects: single control hybrid control and intelligent algorithm control. Additionally the optimization strategies of the flow field or flow channel for oxygen supply speeds and distribution uniformity are compared and analyzed. For the HDS a systematic review of hydrogen recirculation control strategies purge strategies and hydrogen flow control strategies is conducted. These strategies contribute a lot to improving hydrogen utilization rates. Furthermore hydrogen supply pressure is summarized from the aspects of hybrid control and intelligent algorithm control. It is hoped to provide guidance or a reference for research on the HDS as well as the ADS control strategy and optimization strategy
Enabling Industrial Decarbonization: A MILP Optimization Model for Low-carbon Hydrogen Supply Chains
Jun 2024
Publication
This study develops a an optimization model focused on the layout and dispatch of a low-carbon hydrogen supply chain. The objective is to identify the lowest Levelized Cost of Hydrogen for a given demand. The model considers various elements including electricity supply from the local grid and renewable sources (photovoltaic and wind) alongside hydrogen production compression storage and transportation to end users. Applied to an industrial case study in Sweden the findings indicate that the major cost components are linked to electricity generation and investment in electrolyzers with the LCOH reaching 5.2 EUR/kgH2 under typical demand conditions. Under scenarios with higher peak demands and greater demand volatility the LCOH increases to 6.8 EUR/kgH2 due to the need for additional renewable energy capacity. These results highlight the critical impact of electricity availability and demand fluctuations on the LCOH emphasizing the complex interdependencies within the hydrogen supply chain. This study provides valuable insights into the feasibility and cost-effectiveness of adopting hydrogen as an energy carrier for renewable electricity in the context of decarbonizing industrial processes in the energy system.
Technology Assessment for the Transition to a Renewable Electric Grid
Jun 2024
Publication
To reduce carbon emissions generation of electricity from combustion systems is being replaced by renewable resources. However the most abundant renewable sources – solar and wind – are not dispatchable vary diurnally and are subject to intermittency and produce electricity at times in excess of demand (excess production). To manage this variability and capture the excess renewable energy energy storage technologies are being developed and deployed such as battery energy storage (BES) hydrogen production with electrolyzers (ELY) paired with hydrogen energy storage (HES) and fuel cells (FCs) and renewable natural gas (RNG) production. While BES may be better suited for short duration storage hydrogen is suited for long duration storage and RNG can decarbonize the natural gas system. California Senate Bill 100 (SB100) sets a goal that all retail electricity sold in the State must be sourced from renewable and zero-carbon resources by 2045 raising the questions of which set of technologies and in what proportion are required to meet the 2045 target in the required timeframe as well as the role of the natural gas infrastructure if any. To address these questions this study combines electric grid dispatch modeling and optimization to identify the energy storage and dispatchable technologies in 5-year increments from 2030 to 2045 required to transition from a 60% renewable electric grid in 2035 to a 100% renewable electric grid in 2045. The results show that by utilizing the established natural gas system to store and transmit hydrogen and RNG the deployment of battery energy storage is dramatically reduced. The required capacity for BES in 2045 for example is 40 times lower by leveraging the natural gas infrastructure with a concomitant reduction in cost and associated challenges to transform the electric grid.
Full Load Optimization of a Hydrogen Fuelled Industrial Engine
Jun 2024
Publication
There are a large number of applications in which hydrogen internal combustion engines represent a sensible alternative to battery electric propulsion systems and to fuel cell electric propulsion systems. The main advantages of combustion engines are their high degree of robustness and low manufacturing costs. No critical raw materials are required for production and there are highly developed production plants worldwide. A CO2-free operation is possible when using hydrogen as a fuel. The formation of nitrogen oxides during hydrogen combustion in the engine can be effectively mitigated by a lean-burn combustion process. However achieving low NOx raw emissions conflicts with achieving high power yields. In this work a series industrial diesel engine was converted for hydrogen operation and comprehensive engine tests were carried out. Various measures to improve the trade-off between NOx emissions and performance were investigated and evaluated. The rated power output and the maximum torque of the series diesel engine could be exceeded while maintaining an indicated specific NOx emission of 1 g/kWh along the entire full load curve. In the low-end-torque range however the gap to the full load curve of the series diesel engine could not be fully closed with the hardware used.
Socio-technical Imaginaries of Climate-neutral Aviation
May 2024
Publication
Limiting global warming to 1.5 ◦C is crucial to prevent the worst effects of climate change. This entails also the decarbonization of the aviation sector which is considered to be a “hard-to-abate” sector and thus requires special attention regarding its sustainability transition. However transition pathways to a potentially climateneutral aviation sector are unclear with different stakeholders having diverse imaginations of the sector's future. This paper aims to analyze socio-technical imaginaries of climate-neutral aviation as different perceptions of various stakeholders on this issue have not been sufficiently explored so far. In that sense this work contributes to the current scientific debate on socio-technical imaginaries of energy transitions for the first time studying the case of the aviation sector. Drawing on six decarbonization reports composed by different interest groups (e.g. industry academia and environmental associations) three imaginaries were explored following the process of a thematic analysis: rethinking travel and behavioral change (travel innovation) radical modernization and technological progress (fleet innovation) and transition to alternative fuels and renewable energy sources (fuel innovation). The results reveal how different and partly conflicting socio-technical imaginaries are co-produced and how the emergence and enforceability of these imaginaries is influenced by the situatedness of their creators indicating that the sustainability transition of aviation also raises political issues. Essentially as socio-technical imaginaries act as a driver for change policymakers should acknowledge the existence of alternative and counter-hegemonic visions created by actors from civil society settings to take an inclusive and equitable approach to implementing pathways towards climate-neutral aviation.
Particle Swarm Optimisation for a Hybrid Freight Train Powered by Hydrogen or Ammonia Solid Oxide Fuel Cells
May 2024
Publication
All diesel-only trains in the UK will be phased out by 2040. Hydrogen and ammonia emerge as alternative zerocarbon fuel for greener railway. Solid Oxide Fuel Cells (SOFCs) provide an alternative prime mover option which efficiently convert zero-carbon fuels into electricity without emitting nitrogen oxides (NOx) unlike traditional engines. Superior to Proton Exchange Membrane Fuel Cells (PEMFCs) in efficiency SOFCs fulfil MW-scale power needs and can use ammonia directly. This study investigates innovative strategies for integrating SOFCs into hybrid rail powertrains using hydrogen or ammonia. Utilizing an optimization framework incorporating Particle Swarm Optimization (PSO) the study aims to minimize operational costs while considering capital and replacement expenditures powertrain performance and component sizing. The findings suggest that hybrid powertrains based on ammonia-fueled SOFCs may potentially reduce costs by 30% compared to their hydrogen counterparts albeit requiring additional space for engine compartments. Ammonia-fueled SOFCs trains also exhibit a 5% higher efficiency at End-of-Life (EoL) showing less performance degradation than those powered by hydrogen. The State of Charge (SoC) of the batteries in range of 30–70% for both cases is identified as most costeffective.
The Possibility of Powering a Light Aircraft by Releasing the Energy Stored in Hydrogen within a Fuel Cell Stack
Jun 2024
Publication
In this work we examine the possibility of converting a light propeller-driven aircraft powered by a spark-ignition reciprocating piston and internal combustion engine running on AVGAS into one powered by an electric motor driven by a proton exchange membrane fuel cell stack running on hydrogen. Our studies suggest that storing hydrogen cryogenically is a better option than storing hydrogen under pressure. In comparison to cryogenic tanks high-pressure tanks are extremely heavy and unacceptable for light aircraft. We show that the modified aircraft (including batteries) is no heavier than the original and that the layout of the major components results in lower movement of the aircraft center-of-gravity as the aircraft consumes hydrogen. However we acknowledge that our fuel cell aircraft cannot store the same amount of energy as the original running on AVGAS. Therefore despite the fact that the fuel cell stack is markedly more efficient than an internal combustion engine there is a reduction in the range of the fuel cell aircraft. One of our most important findings is that the quantity of energy that we need to dissipate to the surroundings via heat transfer is significantly greater from a fuel cell stack than from an internal combustion engine. This is particularly the case when we attempt to run the fuel cell stack at high current densities. To control this problem our strategy during the cruise phase is to run the fuel cell stack at its maximum efficiency where the current density is low. We size the fuel cell stack to produce at least enough power for cruise and when we require excess power we add the energy stored in batteries to make up the difference.
Collective Hydrogen Stand-alone Renewable Energy Systems for Buildings in Spain. Towards the Self-sufficiency
May 2024
Publication
The article examines the feasibility of implementing standalone hydrogen-based renewable energy systems in Spanish residential buildings specifically analyzing the optimization of a solar-battery and solar-hydrogen system for a building with 20 dwellings in Spain. The study initially assesses two standalone setups: solarbattery and solar-hydrogen. Subsequently it explores scenarios where these systems are connected to the grid to only generate and sell surplus energy. A scenario involving grid connection for self-consumption without storage serves as a benchmark for comparison. All system optimizations are designed to meet energy demands without interruptions while minimizing costs as determined by a techno-economic analysis. The systems are sized using custom software that incorporates an energy management system and employs the Jaya algorithm for optimization. The findings indicate that selling surplus energy can be economically competitive and enhance the efficiency of grid-connected self-consumption systems representing the study’s main innovation. The conclusion highlights the economic and technical potential of an autonomous hybrid energy system that includes hydrogen with the significant remaining challenge being the development of a regulatory framework to support its technical feasibility in Spain.
An Analysis of Hybrid Renewable Energy-Based Hydrogen Production and Power Supply for Off-Grid Systems
Jun 2024
Publication
Utilizing renewable energy sources to produce hydrogen is essential for promoting cleaner production and improving power utilization especially considering the growing use of fossil fuels and their impact on the environment. Selecting the most efficient method for distributing power and capacity is a critical issue when developing hybrid systems from scratch. The main objective of this study is to determine how a backup system affects the performance of a microgrid system. The study focuses on power and hydrogen production using renewable energy resources particularly solar and wind. Based on photovoltaics (PVs) wind turbines (WTs) and their combinations including battery storage systems (BSSs) and hydrogen technologies two renewable energy systems were examined. The proposed location for this study is the northwestern coast of Saudi Arabia (KSA). To simulate the optimal size of system components and determine their cost-effective configuration the study utilized the Hybrid Optimization Model for Multiple Energy Resources (HOMER) software (Version 3.16.2). The results showed that when considering the minimum cost of energy (COE) the integration of WTs PVs a battery bank an electrolyzer and a hydrogen tank brought the cost of energy to almost 0.60 USD/kWh in the system A. However without a battery bank the COE increased to 0.72 USD/kWh in the same location because of the capital cost of system components. In addition the results showed that the operational life of the fuel cell decreased significantly in system B due to the high hours of operation which will add additional costs. These results imply that long-term energy storage in off-grid energy systems can be economically benefited by using hydrogen with a backup system.
Systems-Based Safety Analysis for Hydrogen-Driven Autonomous Ships
Jun 2024
Publication
In the maritime domain hydrogen fuel cell propulsion and autonomous vessels are two important issues that are yet to be implemented together because of a few challenges. It is obvious that there are several individual safety studies on Maritime Autonomous Surface Ships and hydrogen storage as well as fuel cells based on various risk assessment tools but the combined safety studies that include hydrogen fuel cells on autonomous vessels with recent risk analysis methods are extremely limited. This research chooses the “System-Theoretic Process Analysis” (STPA) method which is a recent method for potential risk identification and mitigation. Both hydrogen and autonomous vessels are analyzed and assessed together with the STPA method. Results are not speculative but rather flexible compared to conventional systems. The study finds a total of 44 unsafe control actions (UCAs) evolved from human and central control unit controllers through STPA. Further the loss scenarios (LS) are identified that lead to those UCAs so that loss scenarios can be assessed and UCAs can be mitigated for safe operation. The objective of this study is to ensure adequate safety for hydrogen fuel cell propulsion on autonomous vessels.
Game-Theory-Based Design and Analysis of a Peer-to-Peer Energy Exchange System between Multi-Solar-Hydrogen-Battery Storage Electric Vehicle Charging Stations
Jun 2024
Publication
As subsidies for renewable energy are progressively reduced worldwide electric vehicle charging stations (EVCSs) powered by renewable energy must adopt market-driven approaches to stay competitive. The unpredictable nature of renewable energy production poses major challenges for strategic planning. To tackle the uncertainties stemming from forecast inaccuracies of renewable energy this study introduces a peer-to-peer (P2P) energy trading strategy based on game theory for solar-hydrogen-battery storage electric vehicle charging stations (SHS-EVCSs). Firstly the incorporation of prediction errors in renewable energy forecasts within four SHS-EVCSs enhances the resilience and efficiency of energy management. Secondly employing game theory’s optimization principles this work presents a day-ahead P2P interactive energy trading model specifically designed for mitigating the variability issues associated with renewable energy sources. Thirdly the model is converted into a mixed integer linear programming (MILP) problem through dual theory allowing for resolution via CPLEX optimization techniques. Case study results demonstrate that the method not only increases SHS-EVCS revenue by up to 24.6% through P2P transactions but also helps manage operational and maintenance expenses contributing to the growth of the renewable energy sector.
Rule-Based Operation Mode Control Strategy for the Energy Management of a Fuel Cell Electric Vehicle
Jun 2024
Publication
Hydrogen due to its high energy density stands out as an energy storage method for the car industry in order to reduce the impact of the automotive sector on air pollution and global warming. The fuel cell electric vehicle (FCEV) emerges as a modification of the electric car by adding a proton exchange membrane fuel cell (PEMFC) to the battery pack and electric motor that is capable of converting hydrogen into electric energy. In order to control the energy flow of so many elements an optimal energy management system (EMS) is needed where rule-based strategies represent the smallest computational burden and are the most widely used in the industry. In this work a rulebased operation mode control strategy for the EMS of an FCEV validated by different driving cycles and several tests at the strategic points of the battery state of charge (SOC) is proposed. The results obtained in the new European driving cycle (NEDC) show the 12 kW battery variation of 2% and a hydrogen consumption of 1.2 kg/100 km compared to the variation of 1.42% and a consumption of 1.08 kg/100 km obtained in the worldwide harmonized light-duty test cycle (WLTC). Moreover battery tests have demonstrated the optimal performance of the proposed EMS strategy
Semi-Solid Forging Process of Aluminium Alloy Connecting Rods for the Hydrogen Internal Combustion Engine
Jun 2024
Publication
As an important piece of equipment for hydrogen energy application the hydrogen internal combustion engine is helpful for the realization of zero carbon emissions where the aluminum connecting rod is one of the key core components. A semi-solid forging forming process for the 7075 aluminum alloy connecting rod is proposed in this work. The influence of process parameters such as the forging ratio sustaining temperature and duration time on the microstructures of the semi-solid blank is experimentally investigated. The macroscopic morphology metallographic structure and physical properties of the connecting-rod parts are analyzed. Reasonable process parameters for preparing the semi-solid blank are obtained from the experimental results. Under the reasonable parameters the average grain size is 41.48~42.57 µm and the average shape factor is 0.80~0.81. The yield strength and tensile strength improvement ratio of the connecting rod produced by the proposed process are 47.07% and 20.89% respectively.
Operation Strategy for an Integrated Energy System Considering the Slow Dynamic Response Characteristics of Power-to-Gas Conversion
Jun 2024
Publication
Power-to-gas technology provides an emerging pathway for promoting green and lowcarbon transformation of energy systems. Through the processes of electrolyzing water and the methanation reaction it converts surplus renewable energy into hydrogen and natural gas offering an effective approach for large-scale integration of renewable energy sources. However the optimization of existing integrated energy systems has yet to finely model the operational characteristics of power-to-gas technology severely limiting the energy conversion efficiency of systems. To address this issue this paper proposes an integrated energy system operation strategy considering the slow dynamic response characteristics of power-to-gas. Firstly based on the technical features of power-to-gas an operational model for electrolyzing water to produce hydrogen is constructed considering the transition relationships among cold start-up hot start-up and production states of a methanation reaction thereby building a power-to-gas operation model considering slow dynamic response characteristics. This model finely reflects the impact of power-to-gas operational states on methanation facilitating accurate representation of the operational states of methanation. Then considering the energy conversion constraints and power balance of various coupled devices within integrated energy systems an optimization model for the operation of the integrated energy system is constructed with the total daily operation cost of the system as the optimization objective. Finally simulation comparisons are conducted to demonstrate the necessity of considering the slow dynamic response characteristics of power-to-gas technology for integrated energy system operation. The case study results indicate that the proposed power-to-gas operation model can accurately simulate the methanation process facilitating the rational conversion of surplus renewable energy into natural gas energy and avoiding misjudgments in system operation costs and energy utilization efficiency.
Optimal Sizing of Renewables-to-hydrogen Systems in a Suitable-site-selection Geospatial Framework: The Case Study if Italy and Portugal
Jun 2024
Publication
Growing renewable energy deployment worldwide has sparked a shift in the energy landscape with far-reaching geopolitical ramifications. Hydrogen’s role as an energy carrier is central to this change facilitating global trade and the decarbonisation of hard-to-abate sectors. This analysis offers a new method for optimally sizing solar/wind-to-hydrogen systems in specifically suitable locations. These locations are limited to the onshore and offshore regions of selected countries as determined by a bespoke geospatial analysis developed to be location-agnostic. Furthermore the research focuses on determining the best configurations for such systems that minimise the cost of producing hydrogen with the optimisation algorithm expanding from the detailed computation of the classic levelised cost of hydrogen. One of the study’s main conclusions is that the best hybrid configurations obtained provide up to 70% cost savings in some areas. Such findings represent unprecedented achievements for Italy and Portugal and can be a valuable asset for economic studies of this kind carried out by local and national governments across the globe. These results validate the optimisation model’s initial premise significantly improving the credibility of this work by constructively challenging the standard way of assessing large-scale green hydrogen projects.
Internal Combustion Engines and Carbon-Neutral Fuels: A Perspective on Emission Neutrality in the European Union
Mar 2024
Publication
Nowadays there is an intense debate in the European Union (EU) regarding the limits to achieve the European Green Deal to make Europe the first climate-neutral continent in the world. In this context there are also different opinions about the role that thermal engines should play. Furhermore there is no clear proposal regarding the possibilities of the use of green hydrogen in the transport decarbonization process even though it should be a key element. Thus there are still no precise guidelines regarding the role of green hydrogen with it being exclusively used as a raw material to produce E-fuels. This review aims to evaluate the possibilities of applying the different alternative technologies available to successfully complete the process already underway to achieve Climate Neutrality by about 2050 depending on the maturity of the technologies currently available and those anticipated to be available in the coming decades.
Energy Use and Greenhouse Gas Emissions of Traction Alternatives for Regional Railways
Feb 2024
Publication
This paper presents a method for estimating Well-to-Wheel (WTW) energy use and greenhouse gas (GHG) emissions attributed to the advanced railway propulsion systems implemented in conjunction with different energy carriers and their production pathways. The analysis encompasses diesel-electric multiple unit vehicles converted to their hybrid-electric plug-in hybrid-electric fuel cell hybrid-electric or battery-electric counterparts combined with biodiesel or hydrotreated vegetable oil (HVO) as the first and second generation biofuels liquefied natural gas (LNG) hydrogen and/or electricity. The method is demonstrated using non-electrified regional railway network with heterogeneous vehicle fleet in the Netherlands as a case. Battery-electric system utilizing green electricity is identified as the only configuration leading to emission-free transport while offering the highest energy use reduction by 65–71% compared to the current diesel-powered hybrid-electric system. When using grey electricity based on the EU2030 production mix these savings are reduced to about 27–39% in WTW energy use and around 68–73% in WTW GHG emissions. Significant reductions in overall energy use and emissions are obtained for the plug-in hybrid-electric concept when combining diesel LNG or waste cooking oil-based HVO with electricity. The remaining configurations that reduce energy use and GHG emissions are hybrid-electric systems running on LNG or HVO from waste cooking oil. The latter led to approximately 88% lower WTW emissions than the baseline for each vehicle type. When produced from natural gas or EU2030-mix-based electrolysis hydrogen negatively affected both aspects irrespective of the prime mover technology. However when produced via green electricity it offers a GHG reduction of approximately 90% for hybrid-electric and fuel cell hybrid-electric configurations with a further reduction of up to 92–93% if combined with green electricity in plug-in hybrid-electric systems. The results indicate that HVO from waste cooking oil could be an effective and instantly implementable transition solution towards carbon–neutral regional trains allowing for a smooth transition and development of supporting infrastructure required for more energy-efficient and environment-friendly technologies.
Prospective Assessment of Transformation Pathways Toward Low-carbon Steelmaking: Evaluating Economic and Climate Impacts in Germany
Jan 2024
Publication
Due to climate change there is an urgent need to decarbonize high-emission industries. As coal-based operations predominate in primary steelmaking the steel industry offers an exceptionally high potential for reducing greenhouse gas emissions. Alternative processes for almost fully decarbonized primary steelmaking exist but require substantial investments by steelmakers for their implementation while maintaining desired production levels during the transformation periods. In this context the energy carriers required change such that the transformation of the steelmaking processes is deeply intertwined with the transformation of the background system. For the first time we evaluate potential transformation pathways from the steelmakers’ perspective using a prospective life cycle assessment approach. We find that hydrogen may facilitate a reduction of direct emissions by around 96 % compared to conventional steelmaking in 2050. However indirect emissions remain at a high level throughout the transformation period unless the upstream stages of the value chain are transformed accordingly.
A Zero CO2 Emissions Large Ship Fuelled by an Ammonia-hydrogen Blend: Reaching the Decarbonisation Goals
Aug 2023
Publication
To reach the decarbonisation goals a zero CO2 emissions large ship propulsion system is proposed in this work. The ship selected is a large ferry propelled by an internal combustion engine fuelled by an ammonia-hydrogen blend. The only fuel loaded in the vessel will be ammonia. The hydrogen required for the combustion in the engine will be produced onboard employing ammonia decomposition. The heat required for this decomposition section will be supplied by using the hot flue gases of the combustion engine. To address the issues regarding NOx emissions a selective catalytic reduction (SCR) reactor was designed. The main operating variables for all the equipment were computed for engine load values of 25% 50% 75% and 100%. Considering the lowest SCR removal rate (91% at an engine load of 100%) the NOx emissions of the vessel were less than 0.5 g/kWh lower than the IMO requirements. An energy analysis of the system proposed to transform ammonia into energy for shipping was conducted. The global energy and exergy efficiencies were 42.4% and 48.1%. In addition an economic analysis of the system was performed. The total capital cost (CAPEX) for the system can be estimated at 8.66 M€ (784 €/kW) while the operating cost (OPEX) ranges between 210 €/MWh (engine load 100%) and 243 €/MWh (engine load of 25%). Finally a sensitivity analysis for the price of ammonia was performed resulting in the feasibility of reducing the operating cost to below 150 €/MWh in the near horizon.
Towards Energy Freedom: Exploring Sustainable Solutions for Energy Independence and Self-sufficiency using Integrated Renewable Energy-driven Hydrogen System
Jan 2024
Publication
n the pursuit of sustainable energy solutions the integration of renewable energy sources and hydrogen technologies has emerged as a promising avenue. This paper introduces the Integrated Renewable Energy-Driven Hydrogen System as a holistic approach to achieve energy independence and self-sufficiency. Seamlessly integrating renewable energy sources hydrogen production storage and utilization this system enables diverse applications across various sectors. By harnessing solar and/or wind energy the Integrated Renewable EnergyDriven Hydrogen System optimizes energy generation distribution and storage. Employing a systematic methodology the paper thoroughly examines the advantages of this integrated system over other alternatives emphasizing its zero greenhouse gas emissions versatility energy resilience and potential for large-scale hydrogen production. Thus the proposed system sets our study apart offering a distinct and efficient alternative compared to conventional approaches. Recent advancements and challenges in hydrogen energy are also discussed highlighting increasing public awareness and technological progress. Findings reveal a payback period ranging from 2.8 to 6.7 years depending on the renewable energy configuration emphasizing the economic attractiveness and potential return on investment. This research significantly contributes to the ongoing discourse on renewable energy integration and underscores the viability of the Integrated Renewable EnergyDriven Hydrogen System as a transformative solution for achieving energy independence. The employed model is innovative and transferable to other contexts.
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