Publications

As one of the most promising renewable green energies hydrogen power is a popularly accepted option to drive automobiles. Commercial application of fuel cell vehicles has been started since 2015. More and more hydrogen safety concerns have been considered for years. Tunnels are an important part of traffic infrastructure with a mostly confined feature. Hydrogen leak followed possibly by a hydrogen fire is a potential accident scenario which can be triggered trivially by a car accident while hydrogen powered vehicles operate in a tunnel. Water spray is recommended traditionally as a mitigation measure against tunnel fires. The interaction between water spray and hydrogen fire is studied in a way of numerical simulations. By using the computer program of Fire Dynamics Simulator (FDS) tunnel fires of released hydrogen in different scales are simulated coupled with water droplet injections featured in different droplet sizes or varying mass flow rates. The cooling effect of spray on hot gases of hydrogen fires is apparently observed in the simulations. However in some circumstance the turbulence intensified by the water injection can prompt hydrogen combustion which is a negative side-effect of the spray.

The study aims at the development of a safety engineering methodology for the assessment of flame length after full-bore rupture of hydrogen pipeline. The methodology is validated using experimental data on hydrogen jet flame from full-bore pipeline rupture by Acton et al. (2010). The experimental pressure dynamics in the hydrogen pipeline system is simulated using previously developed adiabatic and “isothermal” blowdown models. The hydrogen release area is taken as equal similar to the experiment to doubled pipeline cross-section as hydrogen was coming out from both sides of the ruptured pipe. The agreement with the experimental pressure decay in the piping system was achieved using discharge coefficient CD=0.26 and CD=0.21 for adiabatic and “isothermal” blowdown model respectively that indicates significant friction and minor pressure losses. The hydrogen flame length was calculated using the dimensionless correlation by Molkov and Saffers (2013). The correlation relies on the density of hydrogen in the choked flow at the pipe exit. The maximum experimental flame length between 92 m and 111 m was recorded at 6 s after the pipe rupture under the ground. The calculated by the dimensionless correlation flame length is 110 m and 120 m for the “isothermal” and adiabatic blowdown model respectively. This is an acceptable accuracy for such a large-scale experiment. It is concluded that the methodology can be applied as an engineering tool to assess flame length resulting from ruptured hydrogen pipelines.

Electrolytic hydrogen produced from wind and solar energy is considered a long-term option for multi-sectoral decarbonization. The study objective is to develop a framework for assessing country-level hydrogen technical potential from wind and solar energy. We apply locational suitability and zonal statistical analyses methods in a geographic information system-based environment to derive granular insights on non-captive technically exploitable hydrogen potential in high-resource locations. Seven setback factors were considered for locational suitability and integrated with modules developed for evaluating the wind and solar resource penetration from open-source theoretical renewable resource geospatial data and electricity-to-hydrogen conversion analyses. The technique applied in this study would be a relevant contribution to determining national and regional-wide electrolytic hydrogen production potentials in other jurisdictions with requisite adjustments to data and technical constraints. The results from the case study country Canada – a major hydrogen-producing country – show that the technical hydrogen potentials from wind and solar energy are approximately 1897 and 448 million metric tonnes per year respectively at least 6.3 times greater than global hydrogen demand in 2019. When we integrated locational data on enabling infrastructure we discovered that the lack of access to power transmission lines in low-population-density areas of the country significantly reduces the exploitable wind- and solar-based hydrogen potential by over 80% and 6% respectively. The findings of this study show that in the absence of spatial data on infrastructural constraints the exploitable hydrogen potential in a jurisdiction can be overestimated leading to improper guidance for policy and decision-makers.

Numerical results are presented from two direct numerical simulations (DNS) where a moderate hydrogen leakage is modeled in a typical two-vented fuel cell configuration. The study mimics one of the experimental investigations carried out on the 1 m3 enclosure with a leak flow rate of 10.4 Nl.min−1 [1]. The injection dimensionless Richardson number is at the order of unity and thus characterizes a plume flow which becomes turbulent due to gravitational accelerations. Two large exterior regions are added to the computational domain to model correctly the exchange between the in/out flows at both vents and the outer environment. Two meshes are used in this study; a first consisting of 250 million cells while the second has 2 billion cells to ensure the fine DNS resolution at the level of Kolmogorov and Batchelor length scales. The high performance computation (HPC) platform TRUST is employed where the computational domain is distributed up to 5.104 central processing unit (CPU) cores. A detailed description of the flow structure and the hydrogen dispersion is provided where the sharp effect of the cross-flow on the plume is analyzed. Comparisons versus the experimental measurements show a very good agreement where both the bi-layer Linden regime and the maximal concentration in the top homogeneous layer are correctly reproduced by the DNS. This result is extremely important and breaks the limitations shown previously with statistical RANS approaches and LES models. This study can be considered as a good candidate for any further improvements of the theoretical industrial plume models in general and for the estimation of the non-constant entrainment coefficient in particular.

The NREL Hydrogen Sensor Laboratory was commissioned in 2010 as a resource for the national and international hydrogen community to ensure the availability and proper use of hydrogen sensors. Since then the Sensor Laboratory has provided unbiased verification of hydrogen sensor performance for sensor developers end-users and regulatory agencies and has also provided active support for numerous code and standards development organizations. Although sensor performance assessment remains a core capability the mission of the NREL Sensor Laboratory has expanded toward a more holistic approach regarding the role of hydrogen detection and its implementation strategy for both assurance of facility safety and for process control applications. Active monitoring for detection of unintended releases has been identified as a viable approach for improving facility safety and lowering setbacks. The current research program for the Sensor Laboratory addresses both conventional and advanced developing detection strategies in response to the emerging large-scale hydrogen markets such as those envisioned by H2@Scale. These emerging hydrogen applications may require alternative detection strategies that supplement and may ultimately supplant the use of traditional sensors for monitoring hydrogen releases. Research focus areas for the NREL Sensor Laboratory now encompass the characterization of released hydrogen behavior to optimize detection strategies for both indoor and outdoor applications assess advanced methods of hydrogen leak detection such as hydrogen wide area monitoring for large scale applications implement active monitoring as a risk reduction strategy to improve safety at hydrogen facilities and to provide continuing support of hydrogen safety codes and standards. In addition to assurance of safety detection will be critical for process control applications such as hydrogen fuel quality verification for fuel cell vehicle applications and for monitoring and controlling of hydrogen-natural gas blend composition.

This paper presents a series of experiments on the effectiveness of existing mechanical ventilation systems during accidental hydrogen releases in confined spaces like underground garages. The purpose was to find the mass flow rate limit hence the TPRD diameter limit that will not require a change in the ventilation system. The experiments were performed in a 40 ft ISO container in Norway and hydrogen gas was used in all experiments. The forced ventilation system was installed with a standard outlet 315 mm diameter. The ventilation parameters during the investigation were British Standard with 10 ACH and British Standard with 6 ACH. The hydrogen releases were obtained through 0.5 mm and 1 mm nozzle from different hydrogen reservoir pressures. Both types of mass flow: constant and blowdown were included in the experimental matrix. The analysis of hydrogen concentration of created hydrogen cloud in the container shows the influence of the forced ventilation on hydrogen releases together with TPRD diameter and reservoir pressure. The generated experimental data will be used to validate a CFD model in the next step.

Hydrogen production is the key in utilizing an excess renewable energy. Many studies and projects looked at the energy management systems (EMSs) that allow to couple hydrogen production with renewable generation. In the majority of these studies however hydrogen demand is either produced for powering fuel cells or sold to the external hydrogen market. Hydrogen demand from actual industrial plants is rarely considered. In this paper we propose an EMS based on the industrial cluster of GreenLab Skive (GLS) that can minimize the system’s operational cost or maximize its green hydrogen production. EMS utilizes a conventional and P2X demand response (DR) flexibility from electrolysis plant hydrogen storage tank electric battery and hydrogen-consuming plants to design the optimal schedule with maximized benefits. A potential addition to the existing components at GLS - an ammonia plant is modelled to identify its P2X potential and assess the economic viability of its construction. The results show a potential reduction of 51.5–61.6% for the total operational cost of the system and an increase of the share of green hydrogen by 10.4–37.6% due to EMS operation.

The power management strategy (PMS) is intimately linked to the fuel economy in the hybrid electric vehicle (HEV). In this paper a hybrid power management scheme is proposed; it consists of an adaptive neuro-fuzzy inference method (ANFIS) and the equivalent consumption minimization technique (ECMS). Artificial intelligence (AI) is a key development for managing power among various energy sources. The hybrid power supply is an eco-acceptable system that includes a proton exchange membrane fuel cell (PEMFC) as a primary source and a battery bank and ultracapacitor as electric storage systems. The Haar wavelet transform method is used to calculate the stress (σ) on each energy source. The proposed model is developed in MATLAB/Simulink software. The simulation results show that the proposed scheme meets the power demand of a typical driving cycle i.e. Highway Fuel Economy Test Cycle (HWFET) and Worldwide Harmonized Light Vehicles Test Procedures (WLTP—Class 3) for testing the vehicle performance and assessment has been carried out for various PMS based on the consumption of hydrogen overall efficiency state of charge of ultracapacitors and batteries stress on hybrid sources and stability of the DC bus. By combining ANFIS and ECMS the consumption of hydrogen is minimized by 8.7% compared to the proportional integral (PI) state machine control (SMC) frequency decoupling fuzzy logic control (FDFLC) equivalent consumption minimization strategy (ECMS) and external energy minimization strategy (EEMS).

This paper presents a greedy energy management strategy based on model predictive control (MPC) for a stand-alone microgrid powered by photovoltaic (PV) arrays and equipped with batteries and a power-to-hydrogen-to-power (P2H2P) system. The proposed strategy consists of a day-ahead plan and an intra-day dispatch method. In the planning stage the sequence of plan is to determine the power of each storage device for a certain period which is initially generated under the principle that PV arrays have the highest priority followed by the batteries and finally the P2H2P system using short-term forecast data of both load and solar irradiance. The initial plan can be optimized with objectives of harvesting more PV generation in storage and minimizing unmet load through rescheduling P2H2P system and batteries. Three parameters including reserved capacity of batteries predischarge coefficient of fuel cell (FC) and greedy coefficient of electrolyzer (EL) are introduced during plan optimization process to enhance the robustness against forecast errors. In the dispatching stage the energy dispatch is subject to the scheduled plan and the operational constraints. To demonstrate the capabilities of the proposed strategy a case study is performed for a hotel with a mean power consumption of 1567 kWh/day based on the system configuration optimized by HOMER software in comparison with the load following (LF) strategy and the global optimum solution solved by mixed integer linear programing (MILP). The simulation results show that the annual unmet load using the proposed strategy is reduced from 13434 kWh to 2370 kWh which is 528 kWh lower than the optimum solution. Meanwhile the cost of energy (COE) of the proposed strategy decreases by US$ 0.08/kWh compared to the LF strategy and is equal to the optimum solution. Finally the performance of configuration optimization employing genetic algorithm (GA) under different energy management strategies is investigated with the objective function of minimizing the net present cost (NPC). Furthermore the robustness of the proposed strategy is studied. The results show that the proposed strategy gives an NPC and COE of US$ 2.4 million (Mn) and US$ 0.43/kWh which are 23.4% and 9.7% lower than those of systems utilizing the SoC-based strategy and the LF strategy respectively. The results also demonstrate that the strategy is robust against forecast errors especially for overestimated forecast models.

The near-wall flame structure and pollutant emissions of the laminar premixed biogashydrogen impinging flame were simulated with a detailed chemical mechanism. The spatial distributions of the temperature critical species and pollutant emissions near the wall of the laminar premixed biogas–hydrogen impinging flame were obtained and investigated quantitatively. The results show that the cold wall can influence the premixed combustion process in the flame front which is close to the wall but does not touch the wall and results in the obviously declined concentrations of OH H and O radicals in the premixed combustion zone. After flame quenching a high CO concentration can be observed near the wall at equivalence ratios (ϕ) of both 0.8 and 1.2. Compared with that at ϕ = 1.0 more unburned fuel is allowed to pass through the quenching zone and generate CO after flame quenching near the wall thanks to the suppressed fuel consumption rate near the wall and the excess fuel in the unburned gases at ϕ = 0.8 and 1.2 respectively. By isolating the formation routes of NO production it is found that the fast-rising trend of NO concentration near the wall in the post flame region at ϕ = 0.8 is attributed to the NO transportation from the NNH route primarily while the prompt NO production accounts for more than 90% of NO generation in the wall vicinity at ϕ = 1.2. It is thus known that thanks to the effectively increased surface-to-volume ratio the premixed combustion process in the downsized chamber will be affected more easily by the amplified cooling effects of the cold wall which will contribute to the declined combustion efficiency increased CO emission and improved prompt NO production.

Although recent studies have shown the possibility of running ‘standard’ spark-ignition engines with 6 pure ammonia the operating range remains limited mainly due to the unfavorable characteristics of 7 ammonia for premixed combustion and often requires the addition of a complementary fuel such as H2 8 to extend it. As the best way to add H2 is to crack ammonia directly on-board this paper focuses on 9 the impact of the upstream cracking level of ammonia on the performance and emissions of a single 10 cylinder spark ignition engine. Experiments were performed over several equivalence ratios 11 dissociation rates and load conditions. It is confirmed that only a slight rate of ammonia dissociation 12 (10%) upstream of the combustion considerably enhances the engine's operating range thanks to a 13 better combustion stability. In terms of pollutant emissions the partial dissociation of ammonia 14 especially for slightly lean mixtures induces a very clear trade-off between high NOx and high 15 unburned ammonia level for high and low ammonia dissociation rates respectively. Therefore 16 cracking NH3 does not only improve the operating range of ammonia-fueled spark ignition engines but 17 can also help to reduce NH3. However to reach the same engine output work higher ammonia fuel 18 consumption will be necessary since the global system efficiency is lower using fuel dissociation. In 19 addition the global warming effect is increased with dissociation level since a higher level of N2O is 20 generated by the hydrogen contribution.

This paper aims to analyse two energy storage methods—batteries and hydrogen storage technologies—that in some cases are treated as complementary technologies but in other ones they are considered opposed technologies. A detailed technical description of each technology will allow to understand the evolution of batteries and hydrogen storage technologies: batteries looking for higher energy capacity and lower maintenance while hydrogen storage technologies pursuing better volumetric and gravimetric densities. Additionally as energy storage systems a mathematical model is required to know the state of charge of the system. For this purpose a mathematical model is proposed for conventional batteries for compressed hydrogen tanks for liquid hydrogen storage and for metal hydride tanks which makes it possible to integrate energy storage systems into management strategies that aim to solve the energy balance in plants based on hybrid energy storage systems. From the technical point of view most batteries are easier to operate and do not require special operating conditions while hydrogen storage methods are currently functioning at the two extremes (high temperatures for metal and complex hydrides and low temperatures for liquid hydrogen or physisorption). Additionally the technical comparison made in this paper also includes research trends and future possibilities in an attempt to help plan future policies.

Europe has set ambitious targets to reduce the final energy consumption of buildings in concerning the degree of electrification energy efficiency and penetration of renewable energy sources (RES). So far hydrogen is becoming an increasingly important energy vector offering huge opportunities to promote the share of intermittent RES. Thus this manuscript proposes an energy model for the complete decarbonization of the estimated electricity consumed by the Spanish building stock in 2030 and 2050 scenarios; the model is based on the combination of photovoltaic and wind primary sources and hydrogen technologies considering both distributed and centralized configurations applying also geospatial criteria for their optimal allocation. Large-scale RES generation centralized hydrogen production and re-electrification along with underground hydrogen storage result in the lowest levelized cost of energy (LCOE) hydrogen production costs (HPC) and the highest overall efficiency (μSYS). Wind energy is mainly harvested in the north of Spain while large PV farms are deployed in the mid-south. Furthermore reinforcement of underground hydrogen storage enhances the overall system performance reducing surplus energy and the required RES generation capacity. Finally all the considered scenarios achieve LCOE below the Spanish utility grid benchmark apart from accomplishing the decarbonization goals established for the year 2030.

This paper performs a technoeconomic comparison of two hybrid renewable energy supplies (HRES) for a specific location in Ghana and suggests the optimal solution in terms of cost energy generation capacity and emissions. (e two HRES considered in this paper were wind/hydrogen/fuel-cell and wind/battery storage respectively. (e necessity of this study was derived from the rise and expansion of hybrid renewable energy supply in a decentralised network. (e readiness to embrace these new technologies is apparently high but the best combination for a selected location that brings optimum benefits is not obvious and demands serious technical knowledge of their technical and economic models. In the methodology an analytical model of energy generation by the various RE sources was first established and data were collected about a rural-urban community in Doderkope Ghana to test the models. HOMER software was used to design the two hybrid systems based on the same load profiles and results were compared. It turns out that the HRES 1 (wind/hydrogen/fuel-cell) had the lowest net present cost (NPC) and levelized cost of electricity (COE) over the project life span of 25 years. (e energy reserve with the HRES 2 (wind/battery storage) was huge compared to that with the HRES 1 about 270% bigger. Furthermore with respect to the emissions the HRES 2 was environmentally friendlier than the HRES 1. Even though the battery storage seems to be more cost-effective than the hydrogen fuel cell technology the latter presents some merits regarding system capacity and emission that deserve greater attention as the world looks into more sustainable energy storage systems.

Solid oxide fuel cells are an emerging energy conversion technology suitable for high-temperature power generation with proper auxiliary heat. Combining SOFCs and polygeneration has produced practical applications for modern energy system designs. Even though many researchers have reviewed these systems’ technologies opportunities and challenges reviews regarding the optimal strategy for designing and operating the systems are limited. Polygeneration is more complicated than any other energy generation type due to its ability to generate many types of energy from various prime movers. Moreover integration with other applications such as vehicle charging and fueling stations increases the complication in making the system optimally serve the loads. This study elaborates on the energy planning and guidelines for designing a polygeneration system especially for residential applications. The review of polygeneration technologies also aligns with the current research trend of developing green technology for modern and smart homes in residential areas. The proposed guideline is expected to solve the complication in other applications and technologies and design the polygeneration system optimally.

The blending of hydrogen gas into natural gas pipelines is an effective way of achieving the goal of carbon neutrality. Due to the large differences in the calorific values of natural gas from different sources the calorific value of natural gas after mixing with hydrogen may not meet the quality requirements of natural gas and the quality of natural gas entering long-distance natural gas and urban gas pipelines also has different requirements. Therefore it is necessary to study the effect of multiple gas sources and different pipe network types on the differences in the calorific values of natural gas following hydrogen admixing. In this regard this study aimed to determine the quality requirements and proportions of hydrogen-mixed gas in natural gas pipelines at home and abroad and systematically determined the quality requirements for natural gas entering both long-distance natural gas and urban gas pipelines in combination with national standards. Taking the real calorific values of the gas supply cycle of seven atmospheric sources as an example the calorific and Wobbe Index values for different hydrogen admixture ratios in a one-year cycle were calculated. The results showed that under the requirement of natural gas interchangeability there were great differences in the proportions of natural gas mixed with hydrogen from different gas sources. When determining the proportion of hydrogen mixed with natural gas both the factors of different gas sources and the factors of the gas supply cycle should be considered.

Fuel transition can decarbonize shipping and help meet IMO 2050 goals. In this paper HFO with CCS LNG with CCS bio-methanol biodiesel hydrogen ammonia and electricity were studied using empirical ship design models from a fleet-level perspective and at the Tank-ToWake level to assist operators technology developers and policy makers. The cargo attainment rate CAR (i.e. cargo that must be displaced due to the low-C propulsion system) the ES (i.e. TTW energy needed per ton*n.m.) the CS (economic cost per ton*n.m.) and the carbon intensity index CII (gCO2 per ton*n.m.) were calculated so that the potential of the various alternatives can be compared quantitatively as a function of different criteria. The sensitivity of CAR towards ship type fuel type cargo type and voyage distance were investigated. All ship types had similar CAR estimates which implies that considerations concerning fuel transition apply equally to all ships (cargo containership tankers). Cargo type was the most sensitive factor that made a ship either weight or volume critical indirectly impacting on the CAR of different fuels; for example a hydrogen ship is weight-critical and has 2.3% higher CAR than the reference HFO ship at 20000 nm. Voyage distance and fuel type could result in up to 48.51% and 11.75% of CAR reduction. In addition to CAR the ES CS and CII for a typical mission were calculated and it was found that HFO and LNG with CCS gave about 20% higher ES and CS than HFO and biodiesel had twice the cost while ammonia methanol and hydrogen had 3–4 times the CS of HFO and electricity about 20 times suggesting that decarbonisation of the world’s fleet will come at a large cost. As an example of including all factors in an effort to create a normalized scoring system an equal weight was allocated to each index (CAR ES CS and CII). Biodiesel achieved the highest score (80%) and was identified as the alternative with the highest potential for a deep-seagoing containership followed by ammonia hydrogen bio-methanol and CCS. Electricity has the lowest normalized score of 33%. A total of 100% CAR is achievable by all alternative fuels but with compromises in voyage distance or with refuelling. For example a battery containership carrying an equal amount of cargo as an HFO-fuelled containership can only complete 13% of the voyage distance or needs refuelling seven times to complete 10000 n.m. The results can guide decarbonization strategies at the fleet level and can help optimise emissions as a function of specific missions.

As a non-profit UNIDO project funded 100% by the Turkish Ministry of Energy and Natural Resources International Center for Hydrogen Energy Technologies (ICHET) has been implementing pilot demonstration projects providing applied R&D funding; organizing workshops education and training activities in Turkey and other developing countries to show potential benefits of “hydrogen and fuel cell systems”. It is important to leap-frog developing countries to hydrogen for eliminating detrimental effect of fossil fuels. To achieve its mission ICHET implements pilot demonstration projects in combination with renewable energy systems to encourage local industry to manufacture similar systems and explore market potential for such use. Support is provided to selected industrial partners in Turkey for developing products or for early demonstrations including a fuel cell forklift a fuel cell boat a fuel cell passenger cart with PV integrated roof-top renewable integrated mobile house fuel cell based UPS installations. As more and more systems demonstrated public awareness on applications of hydrogen and fuel cell technologies will increase and viability of such systems will be realized to change public perception.

In this paper a kind of on-board liquid hydrogen (LH2 ) cold energy utilization system for a heavy-duty fuel cell hybrid truck is proposed. Through this system the cold energy of LH2 is used for cooling the inlet air of a compressor and the coolant of the accessories cooling system sequentially to reduce the parasitic power including the air compressor water pump and radiator fan power. To estimate the cold energy utilization ratio and parasitic power saving capabilities of this system a model based on AMESim software was established and simulated under different ambient temperatures and fuel cell stack loads. The simulation results show that cold energy utilization ratio can keep at a high level except under extremely low ambient temperature and light load. Compared to the original LH2 system without cold energy utilization the total parasitic power consumption can be saved by up to 15% (namely 1.8 kW).

The development of a hydrogen energy-based society is becoming the solution for more and more countries. Fuel cell electric vehicles are the best carriers for developing a hydrogen energy-based society. The current research on hydrogen leakage and the diffusion of fuel cell electric vehicles has been sufficient. However the study of hydrogen safety has not reduced the safety concerns for society and government management departments concerning the large-scale promotion of fuel cell electric vehicles. Hydrogen safety is both a technical and psychological issue. This paper aims to provide a comprehensive overview of fuel cell electric vehicles’ hydrogen dispersion and the burning behavior and introduce the relevant work of international standardization and global technical regulations. The CFD simulations in tunnels underground car parks and multistory car parks show that the hydrogen escape performance is excellent. At the same time the research verifies that the flow the direction of leakage and the vehicle itself are the most critical factors affecting hydrogen distribution. The impact of the leakage location and leakage pore size is much smaller. The relevant studies also show that the risk is still controllable even if the hydrogen leakage rate is increased ten times the limit of GTR 13 to 1000 NL/min and then ignited. Multi-vehicle combustion tests of fuel cell electric vehicles showed that adjacent vehicles were not ignited by the hydrogen. This shows that as long as the appropriate measures are taken the risk of a hydrogen leak or the combustion of fuel cell electric vehicles is controllable. The introduction of relevant standards and regulations also indirectly proves this point. This paper will provide product design guidelines for R&D personnel offer the latest knowledge and guidance to the regulatory agencies and increase the public’s acceptance of fuel cell electric vehicles.

The paper explores options for a 2050 carbon free energy future for India. Onshore wind and solar sources are projected as the dominant primary contributions to this objective. The analysis envisages an important role for so-called green hydrogen produced by electrolysis fueled by these carbon free energy sources. This hydrogen source can be used to accommodate for the intrinsic variability of wind and solar complementing opportunities for storage of power by batteries and pumped hydro. The green source of hydrogen can be used also to supplant current industrial uses of grey hydrogen produced in the Indian context largely from natural gas with important related emissions of CO2. The paper explores further options for use of green hydrogen to lower emissions from otherwise difficult to abate sectors of both industry and transport. The analysis is applied to identify the least cost options to meet India’s zero carbon future.

Severe accidents in nuclear power plants are potentially dangerous to both humans and the environment. To prevent and/or mitigate the consequences of these accidents it is paramount to have adequate accident management measures in place. During a severe accident combustible gases — especially hydrogen and carbon monoxide — can be released in significant amounts leading to a potential explosion risk in the nuclear containment building. These gases need to be managed to avoid threatening the containment integrity which can result in the releases of radioactive material into the environment. The main objective of the AMHYCO project is to propose innovative enhancements in the way combustible gases are managed in case of a severe accident in currently operating reactors. For this purpose the AMHYCO project pursues three specific activities including experimental investigations of relevant phenomena related to hydrogen / carbon monoxide combustion and mitigation with PARs (Passive Autocatalytic Recombiners) improvement of the predictive capabilities of analysis tools used for explosion hazard evaluation inside the reactor containment as well as enhancement of the Severe Accident Management Guidelines (SAMGs) with respect to combustible gases risk management based on theoretical and experimental results. Officially launched on 1 October 2020 AMHYCO is an EU-funded Horizon 2020 project that will last 4 years from 2020 to 2024. This international project consists of 12 organizations (six from European countries and one from Canada) and is led by the Universidad Politécnica de Madrid (UPM). AMHYCO will benefit from the worldwide experts in combustion science accident management and nuclear safety in its Advisory Board. The paper will give an overview of the work program and planned outcome of the project.

The free-piston engine is a type of none-crank engine that could be operated under variable compression ratio and this provides it flexible fuel applicability and low engine emission potential. In this work several 1-D engine models including conventional gasoline engines free-piston gasoline engines and free-piston hydrogen engines have been established. Both engine performance and emission performance under engine speeds between 5–11 Hz and with different equivalent ratios have been simulated and compared. Results indicated that the free-piston engine has remarkable potential for NOx reduction and the largest reduction is 57.37% at 6 Hz compared with a conventional gasoline engine. However the figure of NOx from the hydrogen free-piston engine is slightly higher than that of the gasoline free-piston engine and the difference increases with the increase of engine speed. In addition several factors and their relationships related to hydrogen combustion in the free-piston engine have been investigated and results show that the equivalent ratio ϕ = 0.88 is a vital point that affects NOx production and the ignition advance timing could also affect combustion duration the highest in-cylinder temperature and NOx production to a large extent.

Combustion during a nuclear reactor accident can result in pressure loads that are potentially fatal for the structural integrity of the reactor containment or its safety equipment. Enabling efficient modelling of such safety-critical scenarios is the goal of ongoing work. In this paper attention is given to capturing early phases of flame propagation. Transient simulations that are not prohibitively expensive for use at industrial scale are required given that a typical flame propagation study takes a large number of simulation time steps to complete. An improved numerical method used in this work is based on explicit time integration by means of Strong Stability Preserving (SSP) Runge-Kutta schemes. These allow an increased time step size for a given level of accuracy—reducing the overall computational effort. Furthermore a wide range of flow conditions is encountered in analysis of accelerating flames: from incompressible to potentially supersonic. In contrast numerical schemes for spatial discretization would often prove lacking in either stability or accuracy outside the intended flow regime—with density-based schemes being traditionally designed and applied to compressible (Ma>0.3) flows. In the present work a formulation of an all-speed density-based numerical flux scheme is used for simulation of slow flames starting from ignition. Validation was carried out using experiments with spherical lean hydrogen flames at laboratory scale. Turbulence conditions in the experiments correspond to those that can arise in a nuclear reactor containment during an accident. Results show that the new numerical method has the potential to predict flame speed and pressure rise at a reduced computational effort.

To efficiently convert and utilize intermittent solar energy a novel solar-driven ethanol steam reforming (ESR) system integrated with a membrane reactor is proposed. It has the potential to convert low-grade solar thermal energy into high energy level chemical energy. Driven by chemical potential hydrogen permeation membranes (HPM) can separate the generated hydrogen and shift the ESR equilibrium forward to increase conversion and thermodynamic efficiency. The thermodynamic and environmental performances are analyzed via numerical simulation under a reaction temperature range of 100–400 ◦C with permeate pressures of 0.01–0.75 bar. The highest theoretical conversion rate is 98.3% at 100 ◦C and 0.01 bar while the highest first-law efficiency solar-to-fuel efficiency and exergy efficiency are 82.3% 45.3% and 70.4% at 215 ◦C and 0.20 bar. The standard coal saving rate (SCSR) and carbon dioxide reduction rate (CDRR) are maximums of 101 g·m−2 ·h −1 and 247 g·m−2 ·h −1 at 200 ◦C and 0.20 bar with a hydrogen generation rate of 22.4 mol·m−2 ·h −1 . This study illustrates the feasibility of solar-driven ESR integrated with a membrane reactor and distinguishes a novel approach for distributed hydrogen generation and solar energy utilization and upgradation.