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Experimental Activities on a Hydrogen-Fueled Spark-Ignition Engine for Light-Duty Applications
Nov 2023
Publication
The increase in the overall global temperature and its subsequent impact on extreme weather events are the most critical consequences of human activity. In this scenario transportation plays a significant role in greenhouse gas (GHG) emissions which are the main drivers of climate change. The decline of non-renewable energy sources coupled with the aim of reducing GHG emissions from fossil fuels has forced a shift towards a net-zero emissions economy. As an example of this transition the European Union has set 2050 as the target for achieving carbon neutrality. Hydrogen (H2 ) is gaining increasing relevance as one of the most promising carbon-free energy vectors. If produced from renewable sources it facilitates the integration of various alternative energy sources for achieving a carbon-neutral economy. Recently interest in its application to the transportation sector has grown including different power plant concepts such as fuel cells or internal combustion engines. Despite exhibiting significant drawbacks such as low density combustion instabilities and incompatibilities with certain materials hydrogen is destined to become one of the future fuels. In this publication experimental activities are reported that were conducted on a sparkignition engine fueled with hydrogen at different operating points. The primary objective of this research is to gain a better understanding of the thermodynamic processes that control combustion and their effects on engine performance and pollutant emissions. The results show the emission levels performance and combustion characteristics under different conditions of dilution load and injection strategy and timing.
Deep Reinforcement Learning-Based Energy Management for Liquid Hydrogen-Fueled Hybrid Electric Ship Propulsion System
Oct 2023
Publication
This study proposed a deep reinforcement learning-based energy management strategy (DRL-EMS) that can be applied to a hybrid electric ship propulsion system (HSPS) integrating liquid hydrogen (LH2 ) fuel gas supply system (FGSS) proton-exchange membrane fuel cell (PEMFC) and lithium-ion battery systems. This study analyzed the optimized performance of the DRL-EMS and the operational strategy of the LH2 -HSPS. To train the proposed DRL-EMS a reward function was defined based on fuel consumption and degradation of power sources during operation. Fuel consumption for ship propulsion was estimated with the power for balance of plant (BOP) of the LH2 FGSS and PEMFC system. DRL-EMS demonstrated superior global and real-time optimality compared to benchmark algorithms namely dynamic programming (DP) and sequential quadratic programming (SQP)-based EMS. For various operation cases not used in training DRL-EMS resulted in 0.7% to 9.2% higher operating expenditure compared to DP-EMS. Additionally DRL-EMS was trained to operate 60% of the total operation time in the maximum efficiency range of the PEMFC system. Different hydrogen fuel costs did not affect the optimized operational strategy although the operating expenditure (OPEX) was dependent on the hydrogen fuel cost. Different capacities of the battery system did not considerably change the OPEX.
Eco-Sustainable Energy Production in Healthcare: Trends and Challenges in Renewable Energy Systems
Oct 2023
Publication
The shift from fossil fuels to renewable energy systems represents a pivotal step toward the realization of a sustainable society. This study aims to analyze representative scientific literature on eco-sustainable energy production in the healthcare sector particularly in hospitals. Given hospitals’ substantial electricity consumption the adoption of renewable energy offers a reliable low-CO2 emission solution. The COVID-19 pandemic has underscored the urgency for energyefficient and environmentally-responsible approaches. This brief review analyzes the development of experimental simulation and optimization projects for sustainable energy production in healthcare facilities. The analysis reveals trends and challenges in renewable energy systems offering valuable insights into the potential of eco-sustainable solutions in the healthcare sector. The findings indicate that hydrogen storage systems are consistently coupled with photovoltaic panels or solar collectors but only 14% of the analyzed studies explore this potential within hospital settings. Hybrid renewable energy systems (HRES) could be used to meet the energy demands of healthcare centers and hospitals. However the integration of HRES in hospitals and medical buildings is understudied.
Looking Beyond Compressed Hydrogen Storage for Sweden: Opportunities and Barriers for Chemical Hydrides
Jun 2024
Publication
As Sweden takes its first steps towards a hydrogen-based economy a strategic approach to infrastructure development for both storage and delivery becomes necessary. Although compressed hydrogen is currently the state-of-the-art its low volumetric density and associated high capital costs pose challenges to widespread societal deployment of hydrogen. In order to avoid technological lock-in alternatives storage technologies including chemical hydrides e.g. methanol ammonia methane and LOHC must also be explored. These alternatives offer higher hydrogen densities safer handling and compatibility with existing infrastructure. However each hydride has unique chemical and physical properties requires distinct feedstock and conversion processes and interacts with the energy system in different ways all of which influences their suitability for various applications. Therefore a comprehensive evaluation of these alternative hydrogen storage technologies as carried out in this article is vital to allow for informed investment decisions and pave the way towards a successful and sustainable hydrogen economy.
A Review on Biohydrogen Sources, Production Routes, and Its Application as a Fuel Cell
Aug 2023
Publication
More than 80% of the energy from fossil fuels is utilized in homes and industries. Increased use of fossil fuels not only depletes them but also contributes to global warming. By 2050 the usage of fossil fuels will be approximately lower than 80% than it is today. There is no yearly variation in the amount of CO2 in the atmosphere due to soil and land plants. Therefore an alternative source of energy is required to overcome these problems. Biohydrogen is considered to be a renewable source of energy which is useful for electricity generation rather than relying on harmful fossil fuels. Hydrogen can be produced from a variety of sources and technologies and has numerous applications including electricity generation being a clean energy carrier and as an alternative fuel. In this review a detailed elaboration about different kinds of sources involved in biohydrogen production various biohydrogen production routes and their applications in electricity generation is provided.
Technology Assessment for the Transition to a Renewable Electric Grid
Jun 2024
Publication
To reduce carbon emissions generation of electricity from combustion systems is being replaced by renewable resources. However the most abundant renewable sources – solar and wind – are not dispatchable vary diurnally and are subject to intermittency and produce electricity at times in excess of demand (excess production). To manage this variability and capture the excess renewable energy energy storage technologies are being developed and deployed such as battery energy storage (BES) hydrogen production with electrolyzers (ELY) paired with hydrogen energy storage (HES) and fuel cells (FCs) and renewable natural gas (RNG) production. While BES may be better suited for short duration storage hydrogen is suited for long duration storage and RNG can decarbonize the natural gas system. California Senate Bill 100 (SB100) sets a goal that all retail electricity sold in the State must be sourced from renewable and zero-carbon resources by 2045 raising the questions of which set of technologies and in what proportion are required to meet the 2045 target in the required timeframe as well as the role of the natural gas infrastructure if any. To address these questions this study combines electric grid dispatch modeling and optimization to identify the energy storage and dispatchable technologies in 5-year increments from 2030 to 2045 required to transition from a 60% renewable electric grid in 2035 to a 100% renewable electric grid in 2045. The results show that by utilizing the established natural gas system to store and transmit hydrogen and RNG the deployment of battery energy storage is dramatically reduced. The required capacity for BES in 2045 for example is 40 times lower by leveraging the natural gas infrastructure with a concomitant reduction in cost and associated challenges to transform the electric grid.
A Hydrogen Supply-chain Model Powering Australian Isolated Communities
Oct 2023
Publication
This article proposes a supply chain-based green hydrogen microgrid modelling for a number of remote Australian communities. Green hydrogen can be used as an emissions-free fuel source for electricity generation in places where large-scale renewable energy production is impossible due to land availability population or government regulations. This research focuses on the Torres Strait Island communities in northern Australia where the transition from diesel to renewable electricity generation is difficult due to very limited land availability on most islands. Due to geographical constraints low population and smaller electrical load the green hydrogen needs to be sourced from somewhere else. This research presents a green hydrogen supply chain model that leverages the land availability of one island to produce hydrogen to supply other island communities. In addition this research presents a model of producing and transporting green hydrogen while supplying cheaper electricity to the communities at focus. The study has used a transitional scenario planning approach and the HOMER simulation platform to find the least-cost solution. Based on the results a levelised cost of energy range of AU$0.42 and AU$0.44 was found. With the help of a green hydrogen supply chain CO2 emissions at the selected sites could be cut by 90 %. This study can be used as a guide for small clustered communities that could not support or justify large-scale renewable generation facilities but need more opportunities to install renewable generation.
Uncertainty Quantification in Hydrogen Tank Exchange: Estimating Maintenance Costs for New Aircraft Concepts
Apr 2024
Publication
The increasing demand for sustainable air mobility has led to the development of innovative aircraft designs necessitating a balance between environmental responsibility and profitability. However despite technological advancements there is still limited understanding of the maintenance implications for hydrogen systems in aviation. The aim of this study is to estimate the maintenance costs of replacing the hydrogen storage system in an aircraft as part of its life cycle costs. To achieve this we compared conventional and hydrogenpowered aircraft. As there is insufficient data for new aircraft concepts typical probabilistic methods are not applicable. However by combining global sensitivity analysis with Dempster–Shafer Theory of Evidence and discrete event simulation it is possible to identify key uncertainties that impact maintenance costs and economic efficiency. This innovative framework offers an early estimate of maintenance costs under uncertainty enhancing understanding and assisting in decision-making when integrating hydrogen storage systems and new aviation technologies.
Knock Mitigation and Power Enhancement of Hydrogen Spark-Ignition Engine through Ammonia Blending
Jun 2023
Publication
Hydrogen and ammonia are primary carbon-free fuels that have massive production potential. In regard to their flame properties these two fuels largely represent the two extremes among all fuels. The extremely fast flame speed of hydrogen can lead to an easy deflagration-to-detonation transition and cause detonation-type engine knock that limits the global equivalence ratio and consequently the engine power. The very low flame speed and reactivity of ammonia can lead to a low heat release rate and cause difficulty in ignition and ammonia slip. Adding ammonia into hydrogen can effectively modulate flame speed and hence the heat release rate which in turn mitigates engine knock and retains the zero-carbon nature of the system. However a key issue that remains unclear is the blending ratio of NH3 that provides the desired heat release rate emission level and engine power. In the present work a 3D computational combustion study is conducted to search for the optimal hydrogen/ammonia mixture that is knock-free and meanwhile allows sufficient power in a typical spark-ignition engine configuration. Parametric studies with varying global equivalence ratios and hydrogen/ammonia blends are conducted. The results show that with added ammonia engine knock can be avoided even under stoichiometric operating conditions. Due to the increased global equivalence ratio and added ammonia the energy content of trapped charge as well as work output per cycle is increased. About 90% of the work output of a pure gasoline engine under the same conditions can be reached by hydrogen/ammonia blends. The work shows great potential of blended fuel or hydrogen/ammonia dual fuel in high-speed SI engines.
Greenhouse Gas Emissions Performance of Electric, Hydrogen and Fossil-Fuelled Freight Trucks with Uncertainty Estimates Using a Probabilistic Life-Cycle Assessment (pLCA)
Jan 2024
Publication
This research conducted a probabilistic life-cycle assessment (pLCA) into the greenhouse gas (GHG) emissions performance of nine combinations of truck size and powertrain technology for a recent past and a future (largely decarbonised) situation in Australia. This study finds that the relative and absolute life-cycle GHG emissions performance strongly depends on the vehicle class powertrain and year of assessment. Life-cycle emission factor distributions vary substantially in their magnitude range and shape. Diesel trucks had lower life-cycle GHG emissions in 2019 than electric trucks (battery hydrogen fuel cell) mainly due to the high carbon-emission intensity of the Australian electricity grid (mainly coal) and hydrogen production (mainly through steam–methane reforming). The picture is however very different for a more decarbonised situation where battery electric trucks in particular provide deep reductions (about 75–85%) in life-cycle GHG emissions. Fuel-cell electric (hydrogen) trucks also provide substantial reductions (about 50–70%) but not as deep as those for battery electric trucks. Moreover hydrogen trucks exhibit the largest uncertainty in emissions performance which reflects the uncertainty and general lack of information for this technology. They therefore carry an elevated risk of not achieving the expected emission reductions. Battery electric trucks show the smallest (absolute) uncertainty which suggests that these trucks are expected to deliver the deepest and most robust emission reductions. Operational emissions (on-road driving and vehicle maintenance combined) dominate life-cycle emissions for all vehicle classes. Vehicle manufacturing and upstream emissions make a relatively small contribution to life-cycle emissions from diesel trucks (
The Impact of the Russian War against Ukraine on the German Hydrogen Discourse
Jan 2024
Publication
This contribution delves into the transformative effects of the Russian–Ukrainian war on the discourse surrounding German hydrogen. Employing structural topical modeling (STM) on a vast dataset of 2192 newspaper articles spanning from 2019 to 2022 it aims to uncover thematic shifts attributed to the Russian invasion of Ukraine. The onset of the war in February 2022 triggered a significant pivot in the discourse shifting it from sustainability and climate-change mitigation to the securing of energy supplies through new partnerships particularly in response to Russia’s unreliability. Germany started exploring alternative energy trading partners like Canada and Australia emphasizing green hydrogen development. The study illustrates how external shocks can expedite the uptake of new technologies. The adoption of the “H2 readiness” concept for LNG terminals contributes to the successful implementation of green hydrogen. In summary the Russian–Ukrainian war profoundly impacted the German hydrogen discourse shifting the focus from sustainability to energy supply security underscoring the interconnectedness of energy security and sustainability in Germany’s hydrogen policy.
Numerical Study on a Diesel/Dissociated Methanol Gas Compression Ignition Engine with Exhaust Gas Recirculation
Aug 2023
Publication
Bo Li,
Yihua Chen,
Fei Zhong and
Xu Hao
Hydrogen is the most promising alternative fuel in the field of engines. Exhaust heat assisted methanol dissociation is an attractive approach for generating hydrogen. In this work simulations are conducted on a compression ignition engine fueled with different proportions of diesel-dissociated methanol gas (DMG) blends at intermediate engine speed full load and 0% EGR ratio. The results reveal that the indicated thermal efficiency and indicated mean effective pressure are greatly enhanced combustion efficiency is increased and regular emissions of CO HC and soot are reduced while NOx emissions are reduced with increased DMG substitution. In addition a simulation is conducted at an intermediate engine speed full load 15% DMG substitution ratio and varying EGR ratios of 0–20%. The results indicate that the dual-fuel engine outperforms the original engine with respect to power fuel economy and regular emissions once an optimal EGR rate is adopted.
Techno-economic Modelling of AEM Electrolysis Systems to Identify Ideal Current Density and Aspects Requiring Further Research
Aug 2023
Publication
Hydrogen produced by water electrolysis using renewable energy is a sustainable alternative to steam reformation. As a nascent commercial technology performance and economic comparisons of anion exchange membrane water electrolyzers (AEMWE) to other electrolyzer technology benchmarks are not available. We present a techno-economic model estimating AEMWE's baseline levelized cost of hydrogen (LCOH) at $5.79/kg considering trade-offs between current density efficiency stability capital and operating costs. The optimal current density is 1.38 A cm2 balancing stability and performance for the lowest LCOH. Using low-cost electricity and larger stack sizes AEMWE could achieve $2/kg low-carbon hydrogen. Technical improvements targeting system efficiency particularly reducing overpotentials in hydrogen and oxygen evolution reactions could further reduce LCOH to $1.29/kg approaching U.S. Department of Energy cost targets. There are hopes this model could raise the profile of AEMWE's economic potential to produce green hydrogen and highlight its suitability for decarbonizing the energy sector.
Heat Pumps for Germany—Additional Pressure on the Supply–Demand Equilibrium and How to Cope with Hydrogen
Jun 2024
Publication
In the context of the German Energiewende the current government intends to install six million heat pumps by 2030. Replacing gas heating by power has significant implications on the infrastructure. One of the biggest advantages of using gas is the existing storage portfolio. It has not been clarified yet how power demand should be structured on an annual level—especially since power storage is already a problem and solar power is widely promoted to fuel heat pumps despite having an inverse profile. In this article three different solutions namely hydrogen batteries and carbon capture and storage are discussed with respect to resources energy and financial demand. It shows that relying solely on batteries or hydrogen is not solving the structuring problem. A combination of all existing technologies (including fossil fuels) is required to structure the newly generated electricity demand
Maximisation of PV Energy Use and Performance Analysis of a Stand-alone PV-hydrogen System
Sep 2023
Publication
The development of clean hydrogen and photovoltaic (PV) systems is lagging behind the goals set in the Net Zero Emissions scenario of the International Energy Agency. For this reason efficient hydrogen production systems powered from renewable energy need to be deployed faster. This work presents an optimization procedure for a stand-alone fully PVpowered alkaline electrolysis system. The approach is based on the Particle Swarm Optimization algorithm to obtain the best configuration of the PV plant that powers the electrolyzer and its compressor. The best configuration is determined with one of three indicators: cost efficiency or wasted energy. The PV plant needs to be oversized 2.63 times with respect to the electrolyzer to obtain minimum cost while for high efficiency this number increases by 2%. Additionally the configuration that minimizes cost wasted energy or maximizes efficiency does not correspond to the configuration that maximizes the annual PV yield. Optimizing for cost results also leads to the best operation of the electrolyzer at partial loads than optimizing for efficiency or wasted energy.
System-Level Offshore Wind Energy and Hydrogen Generation Availability and Operations and Maintenance Costs
May 2024
Publication
With the current trends of wind energy already playing a major part in the Scottish energy supply the capacity of wind farms is predicted to grow exponentially and reach further depths offshore. However a key challenge that presents itself is the integration of large producing assets into the current UK grid. One potential solution to this is green hydrogen production which is being heavily researched in industry with many concepts being investigated for large-scale purposes. However the operations and maintenance (O&M) costs and availability of green hydrogen systems need to be quantified to ensure economical and technical viability which is sparse in the available literature. The study presented in this paper investigated the availability and O&M costs of coupled wind–hydrogen systems by attempting to quantify the failure rates repair times repair costs and number of technicians required for key green hydrogen components. This study also utilised an O&M model created by the University of Strathclyde which uses Monte Carlo Markov chain simulations to produce the O&M outputs. A number of assumptions were made throughout the study in relation to the O&M model inputs and the baseline availability for the coupled wind–hydrogen system was 85.24%. Whilst the wind turbine still contributed a major part to the downtime seen in the simulations the combined hydrogen system also contributed a significant amount a total of 37% which could have been due to the technology readiness levels of some the components included in the hydrogen system.
Hierarchical Model Predictive Control for Islanded and Grid-connected Microgrids with Wind Generation and Hydrogen Energy Storage Systems
Aug 2023
Publication
This paper presents a novel energy management strategy (EMS) to control a wind-hydrogen microgrid which includes a wind turbine paired with a hydrogen-based energy storage system (HESS) i.e. hydrogen production storage and re-electrification facilities and a local load. This complies with the mini-grid use case as per the IEA-HIA Task 24 Final Report where three different use cases and configurations of wind farms paired with HESS are proposed in order to promote the integration of wind energy into the grid. Hydrogen production surpluses by wind generation are stored and used to provide a demand-side management solution for energy supply to the local and contractual loads both in the grid-islanded and connected modes with corresponding different control objectives. The EMS is based on a hierarchical model predictive control (MPC) in which long-term and short-term operations are addressed. The long-term operations are managed by a high-level MPC in which power production by wind generation and load demand forecasts are considered in combination with day-ahead market participation. Accordingly the hydrogen production and re-electrification are scheduled so as to jointly track the load demand maximize the revenue through electricity market participation and minimize the HESS operating costs. Instead the management of the short-term operations is entrusted to a low-level MPC which compensates for any deviations of the actual conditions from the forecasts and refines the power production so as to address the real-time market participation and the short time-scale equipment dynamics and constraints. Both levels also take into account operation requirements and devices’ operating ranges through appropriate constraints. The mathematical modeling relies on the mixed-logic dynamic (MLD) framework so that the various logic states and corresponding continuous dynamics of the HESS are considered. This results in a mixed-integer linear program which is solved numerically. The effectiveness of the controller is analyzed by simulations which are carried out using wind forecasts and spot prices of a wind farm in center-south of Italy.
Design of Hydrogen Production Systems Powered by Solar and Wind Energy: An Insight into the Optimal Size Ratios
Jun 2024
Publication
Green hydrogen is expected to play a crucial role in the future energy landscape particularly in the pursuit of deep decarbonisation strategies within hard-to-abate sectors such as the chemical and steel industries and heavy-duty transport. However competitive production costs are vital to unlock the full potential of green hydrogen. In the case of green hydrogen produced via water electrolysis powered by fluctuating renewable energy sources the design of the plant plays a pivotal role in achieving market-competitive production costs. The present work investigates the optimal design of power-to-hydrogen systems powered by renewable sources (solar and wind energy). A detailed model of a power-to-hydrogen system is developed: an energy simulation framework coupled with an economic assessment provides the hydrogen production cost as a function of the component sizes. By spanning a wide range of size ratios namely the ratio between the size of the renewable generator and the size of the electrolyser the cost-optimal design point (minimum hydrogen production cost) is identified. This investigation is carried out for three plant configurations: solar-only wind-only and hybrid. The objective is to extend beyond the analysis of a specific case study and provide broadly applicable considerations for the optimal design of green hydrogen production systems. In particular the rationale behind the cost-optimal size ratio is unveiled and discussed through energy (utilisation factors) and economic (hydrogen production cost) indicators. A sensitivity analysis on investment costs for the power-to-hydrogen technologies is also conducted to explore various technological learning paths from today to 2050. The optimal size ratio is found to be a trade-off between the utilisation factors of the electrolyser and the renewable generator which exhibit opposite trends. Moreover the costs of the power-to-hydrogen technologies are a key factor in determining the optimal size ratio: depending on these costs the optimal solution tends to improve one of the two utilization factors at the expense of the other. Finally the optimal size ratio is foreseen to decrease in the upcoming years primarily due to the reduction in the investment cost of the electrolyser.
Mapping Hydrogen Initiatives in Italy: An Overview of Funding and Projects
May 2024
Publication
The global momentum towards hydrogen has led to various initiatives aimed at harnessing hydrogen’s potential. In particular low-carbon hydrogen is recognized for its crucial role in reducing greenhouse gas emissions across hard-to-abate sectors such as steel cement and heavy-duty transport. This study focuses on the presentation of all hydrogen-related financing initiatives in Italy providing a comprehensive overview of the various activities and their geographical locations. The examined funding comes from the National Recovery and Resilience Plan (PNRR) from projects directly funded through the Important Projects of Common European Interest (IPCEI) and from several initiatives supported by private companies or other funding sources (hydrogen valleys). Specific calls for proposals within the PNRR initiative outline the allocation of funds focusing on hydrogen production in brownfield areas (52 expected hydrogen production plants by 2026) hydrogen use in hard-to-abate sectors and the establishment of hydrogen refuelling stations for both road (48 refuelling stations by 2026) and railway transport (10 hydrogen-based railway lines). A detailed description of the funded initiatives (150 in total) is presented encompassing their geographical location typology and size (when available) as well as the funding they have received. This overview sheds light on regions prioritising decarbonisation efforts in heavy-duty transport especially along cross-border commercial routes as evident in northern Italy. Conversely some regions concentrate more on local transport typically buses or on the industrial sector primarily steel and chemical industries. Additionally the study presents initiatives aimed at strengthening the national manufacturing capacity for hydrogenrelated technologies alongside new regulatory and incentive schemes for hydrogen. The ultimate goal of this analysis is to foster connections among existing and planned projects stimulate new initiatives along the entire hydrogen value chain raise an awareness of hydrogen among stakeholders and promote cooperation and international competitiveness.
A Simulation Study on Evaluating the Influence of Impurities on Hydrogen Production in Geological Carbon Dioxide Storage
Sep 2023
Publication
In this study we examined the effect of CO2 injection into deep saline aquifers considering impurities present in blue hydrogen production. A fluid model was designed for reservoir conditions with impurity concentrations of 3.5 and 20%. The results showed that methane caused density decreases of 95.16 and 76.16% at 3.5 and 20% respectively whereas H2S caused decreases of 99.56 and 98.77% respectively. Viscosity decreased from 0.045 to 0.037 cp with increasing methane content up to 20%; however H2S did not affect the viscosity. Notably CO2 with H2S impacted these properties less than methane. Our simulation model was based on the Gorae-V properties and simulated injections for 10 years followed by 100 years of monitoring. Compared with the pure CO2 injection methane reached its maximum pressure after eight years and eleven months at 3.5% and eight years at 20% whereas H2S reached maximum pressure after nine years and two months and nine years and six months respectively. These timings affected the amount of CO2 injected. With methane as an impurity injection efficiency decreased up to 73.16% whereas with H2S it decreased up to 81.99% with increasing impurity concentration. The efficiency of CO2 storage in the dissolution and residual traps was analyzed to examine the impact of impurities. The residual trap efficiency consistently decreased with methane but increased with H2S. At 20% concentration the methane trap exhibited higher efficiency at the end of injection; however H2S had a higher efficiency at the monitoring endpoint. In carbon capture and storage projects methane impurities require removal whereas H2S may not necessitate desulfurization due to its minimal impact on CO2 storage efficiency. Thus the application of carbon capture and storage (CCS) to CO2 emissions containing H2S as an impurity may enable economically viable operations by reducing additional costs.
The Role of Hydrogen in a Decarbonised Future Transport Sector: A Case Study of Mexico
Sep 2023
Publication
In recent years several approaches and pathways have been discussed to decarbonise the transport sector; however any effort to reduce emissions might be complex due to specific socio-economic and technical characteristics of different regions. In Mexico the transport sector is the highest energy consumer representing 38.9% of the national final energy demand with gasoline and diesel representing 90% of the sector´s total fuel consumption. Energy systems models are powerful tools to obtain insights into decarbonisation pathways to understand costs emissions and rate of deployment that could serve for energy policy development. This paper focuses on the modelling of the current Mexican transport system using the MUSE-MX multi-regional model with the aim to project a decarbonisation pathway through two different scenarios. The first approach being business as usual (BAU) which aims to analyse current policies implementation and the second being a goal of net zero carbon emissions by 2050. Under the considered net zero scenario results show potential deployment of hydrogen-based transport technologies especially for subsectors such as lorries (100% H2 by 2050) and freight train (25% H2 by 2050) while cars and buses tend to full electrification by 2050.
Synergistic Integration of Hydrogen Energy Economy with UK’s Sustainable Development Goals: A Holistic Approach to Enhancing Safety and Risk Mitigation
Oct 2023
Publication
Hydrogen is gaining prominence as a sustainable energy source in the UK aligning with the country’s commitment to advancing sustainable development across diverse sectors. However a rigorous examination of the interplay between the hydrogen economy and the Sustainable Development Goals (SDGs) is imperative. This study addresses this imperative by comprehensively assessing the risks associated with hydrogen production storage transportation and utilization. The overarching aim is to establish a robust framework that ensures the secure deployment and operation of hydrogen-based technologies within the UK’s sustainable development trajectory. Considering the unique characteristics of the UK’s energy landscape infrastructure and policy framework this paper presents practical and viable recommendations to facilitate the safe and effective integration of hydrogen energy into the UK’s SDGs. To facilitate sophisticated decision making it proposes using an advanced Decision-Making Trial and Evaluation Laboratory (DEMATEL) tool incorporating regret theory and a 2-tuple spherical linguistic environment. This tool enables a nuanced decision-making process yielding actionable insights. The analysis reveals that Incident Reporting and Learning Robust Regulatory Framework Safety Standards and Codes are pivotal safety factors. At the same time Clean Energy Access Climate Action and Industry Innovation and Infrastructure are identified as the most influential SDGs. This information provides valuable guidance for policymakers industry stakeholders and regulators. It empowers them to make well-informed strategic decisions and prioritize actions that bolster safety and sustainable development as the UK transitions towards a hydrogen-based energy system. Moreover the findings underscore the varying degrees of prominence among different SDGs. Notably SDG 13 (Climate Action) exhibits relatively lower overall distinction at 0.0066 and a Relation value of 0.0512 albeit with a substantial impact. In contrast SDG 7 (Clean Energy Access) and SDG 9 (Industry Innovation and Infrastructure) demonstrate moderate prominence levels (0.0559 and 0.0498 respectively) each with its unique influence emphasizing their critical roles in the UK’s pursuit of a sustainable hydrogen-based energy future.
Hydrogen Energy Storage: New Techno-economic Emergence Solution Analysis
Aug 2015
Publication
The integration of various renewable energy sources as well as the liberalization of electricity markets are established facts in modern electrical power systems. The increased share of renewable sources within power systems intensifies the supply variability and intermittency. Therefore energy storage is deemed as one of the solutions for stabilizing the supply of electricity to maintain generation-demand balance and to guarantee uninterrupted supply of energy to users. In the context of sustainable development and energy resources depletion the question of the growth of renewable energy electricity production is highly linked to the ability to propose new and adapted energy storage solutions. The purpose of this multidisciplinary paper is to highlight the new hydrogen production and storage technology its efficiency and the impact of the policy context on its development. A comprehensive techno/socio/economic study of long term hydrogen based storage systems in electrical networks is addressed. The European policy concerning the different energy storage systems and hydrogen production is explicitly discussed. The state of the art of the techno-economic features of the hydrogen production and storage is introduced. Using Matlab-Simulink for a power system of rated 70 kW generator the excess produced hydrogen during high generation periods or low demand can be sold either directly to the grid owners or as filled hydrogen bottles. The affordable use of Hydrogen-based technologies for long term electricity storage is verified.
Techno-Economic Analysis of Hydrogen–Natural Gas Blended Fuels for 400 MW Combined Cycle Power Plants (CCPPs)
Sep 2023
Publication
Various research and development activities are being conducted to use hydrogen an environmentally friendly fuel to achieve carbon neutrality. Using natural gas–hydrogen blends has advantages such as the usage of traditional combined cycle power plant (CCPP) technology and existing natural gas piping infrastructure. Therefore we conducted CCPP process modeling and economic analysis based on natural gas–hydrogen blends. For process analysis we developed a process model for a 400 MW natural gas CCPP using ASPEN HYSYS and confirmed an error within the 1% range through operation data validation. For economic analysis we comparatively reviewed the levelized cost of electricity (LCOE) of CCPPs using hydrogen blended up to 0.5 mole fraction. For LCOE sensitivity analysis we used fuel cost capital expenditures capacity factor and power generation as variables. LCOE is 109.15 KRW/kWh when the hydrogen fuel price is 2000 KRW/kg and the hydrogen mole fraction is increased to 0.5 a 5% increase from the 103.9 KRW/kWh of CCPPs that use only natural gas. Economic feasibility at the level of 100% natural gas CCPPs is possible by reducing capital expenditures (CAPEX) by at least 20% but net output should be increased by at least 5% (20.47 MW) when considering only performance improvement.
A Review of Ni Based Powder Catalyst for Urea Oxidation in Assisting Water Splitting Reaction
Jan 2022
Publication
Water splitting has been regarded as a sustainable and environmentally-friendly technique to realize green hydrogen generation while more energy is consumed due to the high overpotentials required for the anode oxygen evolution reaction. Urea electrooxidation an ideal substitute is thus received increasing attention in assisting water-splitting reactions. Note that highly efficient catalysts are still required to drive urea oxidation and the facile generation of high valence state species is significant in the reaction based on the electrochemical-chemical mechanisms. The high cost and rareness make the noble metal catalysts impossible for further consideration in large-scale application. Ni-based catalysts are very promising due to their cheap price facile structure tuning good compatibility and easy active phase formation. In the light of the significant advances made recently herein we reviewed the recent advances of Ni-based powder catalysts for urea oxidation in assisting water-splitting reaction. The fundamental of urea oxidation is firstly presented to clarify the mechanism of urea-assisted water splitting and then the prevailing evaluation indicators are briefly expressed based on the electrochemical measurements. The catalyst design principle including synergistic effect electronic effect defect construction and surface reconstruction as well as the main fabrication approaches are presented and the advances of various Ni-based powder catalysts for urea assisted water splitting are summarized and discussed. The problems and challenges are also concluded for the Ni-based powder catalysts fabrication the performance evaluation and their application. Considering the key influence factors for catalytic process and their application attention should be given to structure-property relationship deciphering novel Ni-based powder catalysts development and their construction in the real device; specifically the effort should be directed to the Ni-based powder catalyst with multi-functions to simultaneously promote the fundamental steps and high anti-corrosion ability by revealing the local structure reconstruction as well as the integration in the practical application. We believe the current summarization will be instructive and helpful for the Ni-based powder catalysts development and understanding their catalytic action for urea-assisted hydrogen generation via water splitting technique.
Strategies for the Adoption of Hydrogen-Based Energy Storage Systems: An Exploratory Study in Australia
Aug 2022
Publication
A significant contribution to the reduction of carbon emissions will be enabled through the transition from a centralised fossil fuel system to a decentralised renewable electricity system. However due to the intermittent nature of renewable energy storage is required to provide a suitable response to dynamic loads and manage the excess generated electricity with utilisation during periods of low generation. This paper investigates the use of stationary hydrogen-based energy storage systems for microgrids and distributed energy resource systems. An exploratory study was conducted in Australia based on a mixed methodology. Ten Australian industry experts were interviewed to determine use cases for hydrogen-based energy storage systems’ requirements barriers methods and recommendations. This study suggests that the current cost of the electrolyser fuel cell and storage medium and the current low round-trip efficiency are the main elements inhibiting hydrogen-based energy storage systems. Limited industry and practical experience are barriers to the implementation of hydrogen storage systems. Government support could help scale hydrogen-based energy storage systems among early adopters and enablers. Furthermore collaboration and knowledge sharing could reduce risks allowing the involvement of more stakeholders. Competition and innovation could ultimately reduce the costs increasing the uptake of hydrogen storage systems.
The Role of Hydrogen in the Corrosion and Cracking of Steels - A Review
Oct 2021
Publication
In many processes of steel industrial including steel manufacture storage and service hydrogen could be absorbed into metallic materials and the absorbed hydrogen seriously impaired its corrosion resistance. This paper provides a comprehensive review on the effects of hydrogen on passive film anodic dissolution pitting corrosion and stress corrosion cracking and based on the review the mechanism by which hydrogen promotes corrosion of steel and subsequently leads to cracking has been discussed. It is envisaged that hydrogen harms the stability of the passive film and as a result escalates anode’s activation of steel eventually leading to pitting and stress corrosion cracking.
Building Efficiency- Reducing Energy Demand in the Commercial Sector
Dec 2013
Publication
The report was formally launched on 2nd December in Parliament at a panel debate chaired by Lord Whitty and Oliver Colvile and featured representatives from Government and Industry. The report outlines the case for investment by businesses in the energy efficiency of their buildings and operations and highlights how this could help neutralise the threat to profitability posed by increasing energy bills energy price volatility and an increasing reliance on electricity in the commercial sector. The report highlights that business in the UK have the opportunity to not only reduce energy bills but increase their competitiveness and improve worker productivity through better designed buildings.
Investigation of Hydrogen Leaks from Double Ferrule Fittings
Sep 2021
Publication
The use of hydrogen is expected to increase rapidly in the future. Leakage of hydrogen pipework are the main forms of safety problems in hydrogen utilization. In this paper a numerical model of hydrogen leakage and diffusion in pipe joints was established. The Schlieren + high-speed camera is used in experiments to observe the leakage of hydrogen in the pipe joints. In addition the shape and size of the scratches in the tube were statistically analyzed. Finally the leakage characteristics of double ferrule joints with scratches are experimentally analyzed. For the two scratch sizes the critical pressure values for the vortex transition are 0.2 MPa and 0.03 MPa. Through our experimental process some practical experience and suggestions are given.
Hybrid Energy System Model in Matlab/Simulink Based on Solar Energy, Lithium‐Ion Battery and Hydrogen
Mar 2022
Publication
In this work a model of an energy system based on photovoltaics as the main energy source and a hybrid energy storage consisting of a short‐term lithium‐ion battery and hydrogen as the long‐term storage facility is presented. The electrical and the heat energy circuits and resulting flows have been modelled. Therefore the waste heat produced by the electrolyser and the fuel cell have been considered and a heat pump was considered to cover the residual heat demand. The model is designed for the analysis of a whole year energy flow by using a time series of loads weather and heat profile as input. This paper provides the main set of equations to derive the component properties and describes the implementation into MATLAB/Simulink. The novel model was created for an energy flow simulation over one year. The results of the simulation have been verified by comparing them with well‐established simulation results from HOMER Energy. It turns out that the novel model is well suited for the analysis of the dynamic system behaviour. Moreover different characteristics to achieve an energy balance an ideal dimensioning for the particular use case and further research possibilities of hydrogen use in the residential sector are covered by the novel model.
A Review of the Status of Fossil and Renewable Energies in Southeast Asia and Its Implications on the Decarbonization of ASEAN
Mar 2022
Publication
The ten nations of Southeast Asia collectively known as ASEAN emitted 1.65 Gtpa CO2 in 2020 and are among the most vulnerable nations to climate change which is partially caused by anthropogenic CO2 emission. This paper analyzes the history of ASEAN energy consumption and CO2 emission from both fossil and renewable energies in the last two decades. The results show that ASEAN’s renewable energies resources range from low to moderate are unevenly distributed geographically and contributed to only 20% of total primary energy consumption (TPEC) in 2015. The dominant forms of renewable energies are hydropower solar photovoltaic and bioenergy. However both hydropower and bioenergy have substantial sustainability issues. Fossil energies depend heavily on coal and oil and contribute to 80% of TPEC. More importantly renewable energies’ contribution to TPEC has been decreasing in the last two decades despite the increasing installation capacity. This suggests that the current rate of the addition of renewable energy capacity is inadequate to allow ASEAN to reach net-zero by 2050. Therefore fossil energies will continue to be an important part of ASEAN’s energy mix. More tools such as carbon capture and storage (CCS) and hydrogen will be needed for decarbonization. CCS will be needed to decarbonize ASEAN’s fossil power and industrial plants while blue hydrogen will be needed to decarbonize hard-to-decarbonize industrial plants. Based on recent research into regional CO2 source-sink mapping this paper proposes six large-scale CCS projects in four countries which can mitigate up to 300 Mtpa CO2 . Furthermore this paper identifies common pathways for ASEAN decarbonization and their policy implications.
Hydrogen Production Technologies Overview
Jan 2019
Publication
Hydrogen energy became the most significant energy as the current demand gradually starts to increase. Hydrogen energy is an important key solution to tackle the global temperature rise. The key important factor of hydrogen production is the hydrogen economy. Hydrogen production technologies are commercially available while some of these technologies are still under development. This paper reviews the hydrogen production technologies from both fossil and non-fossil fuels such as (steam reforming partial oxidation auto thermal pyrolysis and plasma technology). Additionally water electrolysis technology was reviewed. Water electrolysis can be combined with the renewable energy to get eco-friendly technology. Currently the maximum hydrogen fuel productions were registered from the steam reforming gasification and partial oxidation technologies using fossil fuels. These technologies have different challenges such as the total energy consumption and carbon emissions to the environment are still too high. A novel non-fossil fuel method [ammonia NH3] for hydrogen production using plasma technology was reviewed. Ammonia decomposition using plasma technology without and with a catalyst to produce pure hydrogen was considered as compared case studies. It was showed that the efficiency of ammonia decomposition using the catalyst was higher than ammonia decomposition without the catalyst. The maximum hydrogen energy efficiency obtained from the developed ammonia decomposition system was 28.3% with a hydrogen purity of 99.99%. The development of ammonia decomposition processes is continues for hydrogen production and it will likely become commercial and be used as a pure hydrogen energy source.
A Brief Review of Hydrogen Production Methods and Their Challenges
Jan 2023
Publication
Hydrogen is emerging as a new energy vector outside of its traditional role and gaining more recognition internationally as a viable fuel route. This review paper offers a crisp analysis of the most recent developments in hydrogen production techniques using conventional and renewable energy sources in addition to key challenges in the production of Hydrogen. Among the most potential renewable energy sources for hydrogen production are solar and wind. The production of H2 from renewable sources derived from agricultural or other waste streams increases the flexibility and improves the economics of distributed and semi-centralized reforming with little or no net greenhouse gas emissions. Water electrolysis equipment driven by off-grid solar or wind energy can also be employed in remote areas that are away from the grid. Each H2 manufacturing technique has technological challenges. These challenges include feedstock type conversion efficiency and the need for the safe integration of H2 production systems with H2 purification and storage technologies.
Integrated Power and Propulsion System Optimization for a Planetary-Hopping Robot
Aug 2022
Publication
Missions targeting the extreme and rugged environments on the moon and Mars have rich potential for a high science return although several risks exist in performing these exploration missions. The current generation of robots is unable to access these high-priority targets. We propose using teams of small hopping and rolling robots called SphereX that are several kilograms in mass and can be carried by a large rover or lander and tactically deployed for exploring these extreme environments. Considering that the importance of minimizing the mass and volume of these robot platforms translates into significant mission-cost savings we focus on the optimization of an integrated power and propulsion system for SphereX. Hydrogen is used as fuel for its high energy and it is stored in the form of lithium hydride and oxygen in the form of lithium perchlorate. The system design undergoes optimization using Genetic Algorithms integrated with gradient-based search techniques to find optimal solutions for a mission. Our power and propulsion system as we show in this paper is enabling because the robots can travel long distances to perform science exploration by accessing targets not possible with conventional systems. Our work includes finding the optimal mass and volume of SphereX such that it can meet end-to-end mission requirements.
Effect of Hydrogen Blending on the Energy Capacity of Natural Gas Transmission Networks
Dec 2022
Publication
In this paper the effects of hydrogen on the transport of natural gas-hydrogen mixture in a high-pressure natural gas transmission system are investigated in detail. Our research focuses on the decrease in transferable energy content under identical operating conditions as hydrogen is blended in the gas transmission network. Based on the extensive literature review the outstanding challenges and key questions of using hydrogen in the natural gas system are introduced. In our research the transmissible energy factor - TEF - is defined that quantifies the relative energy capacity of the pipeline caused by hydrogen blending. A new equation is proposed in this paper to find the value of TEF at specific pressure and temperature conditions for different hydrogen concentrations. This practical equation helps the natural gas system operators in the decision-making process when hydrogen emerges in the gas transmission system. In this paper the change of the compression power requirement which increases significantly with hydrogen blending is investigated in detail.
Investigation on the Changes of Pressure and Temperature in High Pressure Filling of Hydrogen Storage Tank
May 2022
Publication
Hydrogen as fuel has been considered as a feasible energy carry and which offers a clean and efficient alternative for transportation. During the high pressure filling the temperature in the hydrogen storage tank (HST) may rise rapidly due to the hydrogen compression. The high temperature may lead to safety problem. Thus for fast and safely refueling the hydrogen several key factors need to be considered. In the present study by the thermodynamics theories a mathematical model is established to simulate and analyze the high pressure filling process of the storage tank for the hydrogen station. In the analysis the physical parameters of normal hydrogen are introduced to make the simulation close to the actual process. By the numerical simulation for 50 MPa compressed hydrogen tank the temperature and pressure trends during filling are obtained. The simulation results for non-adiabatic filling were compared with the theoretically calculated ones for adiabatic conditions and the simulation results for non-adiabatic filling were compared with the simulation ones for adiabatic conditions. Then the influence of working pressure initial temperature mass flow rate initial pressure and inlet temperature on the temperature rise were analyzed. This study provides a theoretical research basis for high pressure hydrogen energy storage and hydrogenation technology.
Effect of a Ripple Current on the Efficiency of a PEM Electrolyser
Mar 2021
Publication
The aim of this study was to determine how the efficiency of a proton exchange membrane (PEM) electrolyser is affected by an electric ripple current and the different characteristics of the ripple current (frequency amplitude and waveform). This paper presents the experimental method and measured results used to analyse the effect of ripple currents at various frequencies ripple factors and waveforms on the hydrogen production power consumption and efficiency of a PEM electrolyser. An active laboratory-size PEM electrolysis system was used to investigate the impact of various ripple currents on the efficiency of the system. The results revealed that the average power consumption increases as the ripple factor increases and decreases as the frequency of the ripple increases while the waveform of the applied current has no effect. Furthermore the average hydrogen flow rate is unaffected by the ripple factor frequency or waveform of the applied ripple current.
Future Heat Series Part 1 - Pathways for Heat
Nov 2014
Publication
Together the pathways examined in the report paint a picture of the nationwide transformation getting underway in how we heat our homes and buildings. The report identifies that by 2050 gas used to heat buildings could fall by 75-95% electricity increase from a 10% share today to 30-80% and district heat increase from less than 2% to up to a 40% share. At the same time energy efficiency could help to lower bills and offset the expected growth in our heating needs from an expanding population and building stock. Across most pathways examined in the report mass deployment of low carbon heat solutions ramps up in the lead-in to 2030. Carbon Connect’s overarching recommendation is that the next decade should be spent preparing by developing a robust strategy for decarbonising heat in buildings whilst testing and scaling up delivery models. The report calls for the next Government to prioritise these preparations in the same way that preparing for power sector decarbonisation has been the overriding focus of energy policy in the past decade. The Future Heat Series brings together politicians policy and academic experts and industry leaders. Together this coalition of key figures is taking stock of evidence progressing the policy debate in an open and constructive forum and building consensus for prioritising and transforming heat. Pathways for Heat is the first part of the Future Heat Series and presents six recommendations and over twenty findings.
Life Cycle Assessments on Battery Electric Vehicles and Electrolytic Hydrogen: The Need for Calculation Rules and Better Databases on Electricity
May 2021
Publication
LCAs of electric cars and electrolytic hydrogen production are governed by the consumption of electricity. Therefore LCA benchmarking is prone to choices on electricity data. There are four issues: (1) leading Life Cycle Impact (LCI) databases suffer from inconvenient uncertainties and inaccuracies (2) electricity mix in countries is rapidly changing year after year (3) the electricity mix is strongly fluctuating on an hourly and daily basis which requires time-based allocation approaches and (4) how to deal with nuclear power in benchmarking. This analysis shows that: (a) the differences of the GHG emissions of the country production mix in leading databases are rather high (30%) (b) in LCA a distinction must be made between bundled and unbundled registered electricity certificates (RECs) and guarantees of origin (GOs); the residual mix should not be applied in LCA because of its huge inaccuracy (c) time-based allocation rules for renewables are required to cope with periods of overproduction (d) benchmarking of electricity is highly affected by the choice of midpoints and/or endpoint systems and (e) there is an urgent need for a new LCI database based on measured emission data continuously kept up-to-date transparent and open access.
On Board 70 MPA Hydrogen Composite Pressure Vessel Safety Factor
Sep 2021
Publication
The safety factor of a composite structure in relation to its mechanical rupture is an important criterion for the safety of a 70 MPa composite pressure vessel for hydrogen storage particularly for on-board applications (car bus truck train…). After an introduction of Type IV technology the contribution of carbon fibre composite material structure manufacturing process of pressure vessels and environmental effects on the safety factor are commented. Thanks to an experimental-based evaluation on composite material and H2 composite pressure vessel the safety margins are addressed.
Research on the Sealing Mechanism of Split-Liner High-Pressure Hydrogen Storage Cylinders
Mar 2024
Publication
Hydrogen storage is a crucial factor that limits the development of hydrogen energy. This paper proposes using a split liner for the inner structure of a hydrogen storage cylinder. A self-tightening seal is employed to address the sealing problem between the head and the barrel. The feasibility of this structure is demonstrated through hydraulic pressure experiments. The influence laws of the O-ring compression rate the distance from the straight edge section of the head to the sealing groove and the thickness of the head on the sealing performance of gas cylinders in this sealing structure are revealed using finite elements analysis. The results show that when the gas cylinder is subjected to medium internal pressure the maximum contact stress on the O-ring extrusion deformation sealing surface is greater than the medium pressure. There is sufficient contact width that is the arc length of the part where the stress on the O-ring contact surface is greater than the medium pressure so that it can form a good sealing condition. At the same time increasing the compression ratio of the O-ring and the head’s thickness will help improve the sealing performance and reducing the distance from the straight edge section of the head to the sealing groove will also improve the sealing performance.
A Geospatial Method for Estimating the Levelised Cost of Hydrogen Production from Offshore Wind
Jan 2023
Publication
This paper describes the development of a general-purpose geospatial model for assessing the economic viability of hydrogen production from offshore wind power. A key feature of the model is that it uses the offshore project's location characteristics (distance to port water depth distance to gas grid injection point). Learning rates are used to predict the cost of the wind farm's components and electrolyser stack replacement. The notional wind farm used in the paper has a capacity of 510 MW. The model is implemented in a geographic information system which is used to create maps of levelised cost of hydrogen from offshore wind in Irish waters. LCOH values in 2030 spatially vary by over 50% depending on location. The geographically distributed LCOH results are summarised in a multivariate production function which is a simple and rapid tool for generating preliminary LCOH estimates based on simple site input variables.
The Hydrogen Economy - Where is the Water?
Jul 2022
Publication
"Green hydrogen” i.e. hydrogen produced by splitting water with a carbon “free” source of electricity via electrolysis is set to become the energy vector enabling a deep decarbonisation of society and a virtuous water based energy cycle. If to date water electrolysis is considered to be a scalable technology the source of water to enable a “green hydrogen” economy at scale is questionable. Countries with the highest renewable energy potential like Australia are also among the driest places on earth. Globally 380000 GL/year of wastewater is available and this is much more than the 34500 GL/year of water required to produce the projected 2.3 Gt of hydrogen of a mature hydrogen economy. Hence the need to assess both technically and economically whether some wastewater treatment effluent are a better source for green hydrogen. Analysis of Sydney Water’s wastewater treatment plants alone shows that these plants have 37.6 ML/day of unused tertiary effluents which if electrolysed would generate 420000 t H2/day or 0.88 Mt H2/year and cover ∼100% of Australia’s estimated production by 2030. Furthermore the production of oxygen as a by-product of the electrolysis process could lead to significant benefits to the water industry not only in reducing the cost of the hydrogen produced for $3/kg (assuming a price of oxygen of $3–4 per kg) but also in improving the environmental footprint of wastewater treatment plants by enabling the onsite re-use of oxygen for the treatment of the wastewater. Compared to desalinated water that requires large investments or stormwater that is unpredictable it is apparent that the water utilities have a critical role to play in managing water assets that are “climate independent” as the next “golden oil” opportunity and in enabling a “responsible” hydrogen industry that sensibly manages its water demands and does not compete with existing water potable water demand.
Molten Carbonate Fuel Cells for Simultaneous CO2 Capture, Power Generation, and H2 Generation
Mar 2022
Publication
This article presents a new technology for the generation of power and steam or other process heat with very low CO2 emissions. It is well known that cogeneration of electricity and steam is highly efficient and that amine units can be used to remove CO2 from combustion flue gas but that the amine unit consumes a significant amount of steam and power reducing the overall system efficiency. In this report the use of molten carbonate fuel cells (MCFCs) to capture CO2 from cogen units is investigated and shown to be highly efficient due to the additional power that they produce while capturing the CO2. Furthermore the MCFCs are capable of reforming methane to hydrogen simultaneous to the power production and CO2 capture. This hydrogen can either be recycled as fuel for consumption by the cogen or MCFCs or exported to an independent combustion unit as low carbon fuel thereby decarbonizing that unit as well. The efficiency of MCFCs for CO2 capture is higher than use of amines in all cases studied often by a substantial margin while at the same time the MCFCs avoid more CO2 than the amine technology. As one example the use of amines on a cogeneration unit can avoid 87.6% of CO2 but requires 4.91 MJ/kg of additional primary energy to do so. In contrast the MCFCs avoid 89.4% of CO2 but require only 1.37 MJ/kg of additional primary energy. The high thermal efficiency and hydrogen export option demonstrate the potential of this technology for widespread deployment in a low carbon energy economy.
Review and Perspectives of Key Decarbonization Drivers to 2030
Jan 2023
Publication
Global climate policy commitments are encouraging the development of EU energy policies aimed at paving the way for cleaner energy systems. This article reviews key decarbonization drivers for Italy considering higher environmental targets from recent European Union climate policies. Energy efficiency the electrification of final consumption the development of green fuels increasing the share of renewable energy sources in the electric system and carbon capture and storage are reviewed. A 2030 scenario is designed to forecast the role of decarbonization drivers in future energy systems and to compare their implementation with that in the current situation. Energy efficiency measures will reduce final energy consumption by 15.6% as primary energy consumption will decrease by 19.8%. The electrification of final consumption is expected to increase by 6.08%. The use of green fuels is estimated to triple as innovative fuels may go to market at scale to uphold the ambitious decarbonization targets set in the transportation sector. The growing trajectory of renewable sources in the energy mix is confirmed as while power generation is projected to increase by 10% the share of renewables in that generation is expected to increase from 39.08% to 78.16%. Capture and storage technologies are also expected to play an increasingly important role. This article has policy implications and serves as a regulatory reference in the promotion of decarbonization investments.
Renewable Energy, Carbon Capture & Sequestration and Hydrogen Solutions as Enabling Technologies for Reduced CO2 Energy Transition at a National Level: An Application to the 2030 Italian National Energy Scenarios
Dec 2022
Publication
Globally climate change fossil fuel depletion and greenhouse emissions are fundamental problems requiring massive effort from the international scientific community to be addressed and solved. Following the Clean Energy for all Europeans Package (CEP) guidelines the Italian Government has established challenging and tight objectives both on energy and climate matter to be targeted by 2030. Accordingly research activities on different topics are carried out in Italy looking at the installation of intermittent renewable energy systems (IRES) implementation of carbon capture and sequestration (CCS) on existing power plants and hydrogen technology and infrastructure penetration for accomplishing the end-users demands. The optimal integration of the above-mentioned technologies is one of the most effective weapons to address these objectives. The paper investigates different energy scenarios for meeting the Italian National Energy and Climate Plan (NECP) 2030 targets showing how the combined implementation of around +12 GW of IRES and +6 GW of electrolyzers compared to the national estimates simultaneously with the CCS of around 10 Mt of CO2 per year can reduce the CO2 emissions up to about 247 Mt/year. Thanks to the adoption of the well-established software platform EnergyPlan the integration of IRES plants CCS and hydrogen-based technologies have been explored and the most successful results for concurrently reducing the impact of industrial transport residential and energy sectors and mitigating the greenhouse emissions substantially relies on the diversifications. Results show both the technical and economic convenience of a 2030 energy scenario which implements properly hydrogen IRES and CCS penetration in the energy system meeting the NECP 2030 targets and maintaining both the over-generation of the power plants below 5 TWh and the initial capital expenditure to be sustained for this scenario to occur below +80% compared to the 2019 energy scenario.
A Review of Factors Affecting SCC Initiation and Propagation in Pipeline Carbon Steels
Aug 2022
Publication
Pipelines have been installed and operated around the globe to transport oil and gas for decades. They are considered to be an effective economic and safe means of transportation. The major concern in their operation is corrosion. Among the different forms of corrosion stress corrosion cracking (SCC) which is caused by stresses induced by internal fluid flow or other external forces during the pipeline’s operation in combined action with the presence of a corrosive medium can lead to pipeline failure. In this paper an extensive review of different factors affecting SCC of pipeline steels in various environmental conditions is carried out to understand their impact. Several factors such as temperature presence of oxidizers (O2 CO2 H2S etc.) composition and concentration of medium pH applied stress and microstructure of the metal/alloy have been established to affect the SCC of pipeline steels. SCC susceptibility of a steel at a particular temperature strongly depends on the type and composition of the corrosive medium and microstructure. It was observed that pipeline steels with water quenched and quenched and tempered heat treatments such as those that consist of acicular ferrite or bainitic ferrite grains are more susceptible to SCC irrespective of solution type and composition. Applied stress stress concentration and fluctuating stress facilitates SCC initiation and propagation. In general the mechanisms for crack initiation and propagation in near-neutral solutions are anodic dissolution and hydrogen embrittlement.
A Novel Approach for Quantifying Hydrogen Embrittlement Using Side-grooved CT Samples
Feb 2022
Publication
Aerospace parts made of high strength steels such as landing gears and helicopter transmissions are often electroplated to satisfy various engineering specifications. However plated parts are occasionnaly rejected because of hydrogen embrittlement and the industry has few means of evaluating quantitatively the actual damage caused by hydrogen. In the present article we developed a novel method to measure the stress intensity threshold for hydrogen embrittlement (Kth) in industrial plating conditions. The method consists in plating side-grooved CT samples in industrial plating baths and measuring Kth with an incremental step loading methodology. We validated the method with a benchmark case known to produce embrittlement (omitted post-plating bake) and we used the method on a test case for which the level of embrittlement was unknown (delayed bake). For the benchmark case we measured a Kth of 49.0 MPa m0.5 for non-baked samples. This value is significantly lower than the fracture toughness of the unplated material which is 63.8 MPa m0.5 . We conclude that this novel combination of geometry and test method is efficient in quantifying hydrogen embrittlement of samples plated in industrial conditions. For the test case the Kth are respectively 57.9 MPa m0.5 and 58.8 MPa m0.5 for samples baked 100 h and 4 h after plating. We conclude that delaying the post-plating bake does not cause hydrogen embrittlement in the studied conditions. Using a finite element hydrogen diffusion analysis we argue that the side grooves on CT samples increase the sensitivity to hydrogen embrittlement in comparison to smooth samples. In smooth samples a zone of plane stress at the surface of the specimen shields hydrogen from penetrating to the center of the specimen a phenomenon which is alleviated with machining side grooves.
Techno-economic Assessment of a Hybrid Off-grid DC System for Combined Heat and Power Generation in Remote Islands
Mar 2019
Publication
Hybrid renewable energy systems that combine heat and electricity generation is an achievable option for remote areas where grid is uneconomical to extend. In this study a renewable-based system was designed to satisfy the electrical and thermal demands of a remote household in an off-grid Greek island. A hybrid DC system consisted of a combination of photovoltaic modules wind turbine electrolyzer-hydrogen tank fuel cell and batteries were analysed using HOMER Pro software. Based on the optimal obtained system it is found that such a system can satisfy both electrical and thermal load demand throughout the year in a reliable manner.
First Solar Hydrogen Storage in a Private Building in Western Switzerland: Building energy Analysis and Schematic Design
Sep 2019
Publication
Self-sufficiency of buildings with carbon emission reduction can be obtained thanks to the introduction of Photovoltaics systems coupled with Hydrogen seasonal storage. To be self-sufficient over the year the electricity converted to hydrogen by electrolysis during the sunny season can be re-used with the help of fuel cells during the winter season. This article is dealing with the dimensioning methodology of a solar PV hydrogen-electrochemical system for self-sufficient buildings. We introduce the case study of the first private building in western Switzerland that will be equipped with solar hydrogen storage. Calculation results of the dimensioning of the PV system with storage will be presented. The life cycle assessment and the calculations of the environmental indicators GWP and CED will be introduced.
Numerical Modelling of H2 Storage with Cushion Gas of CO2 in Subsurface Porous Media: Filter Effects of CO2 Solubility
Jun 2022
Publication
The central objective of this study is to improve the understanding of flow behaviour during hydrogen (H2) storage in subsurface porous media with a cushion gas of carbon dioxide (CO2). In this study we investigate the interactions between various factors driving the flow behaviour including the underlying permeability heterogeneity viscous instability and the balance between the viscous and gravity forces. In particular we study the impact of CO2 solubility in water on the level of H2 purity. This effect is demonstrated for the first time in the context of H2 storage. We have performed a range of 2D vertical cross-sectional simulations at the decametre scale with a very fine cell size (0.1 m) to capture the flow behaviour in detail. This is done since it is at this scale that much of the mixing between injected and native fluids occurs in physical porous media. It is found that CO2 solubility may have different (positive and negative) impacts on the H2 recovery performance (i.e. on the purity of the produced H2) depending on the flow regimes in the system. In the viscous dominated regime the less viscous H2 may infiltrate and bypass the cushion gas of CO2 during the period of H2 injection. This leads to a quick and dramatic reduction in the H2 purity when back producing H2 due to the co-production of the previously bypassed CO2. Interestingly the impurity levels in the H2 are much less severe in the case when CO2 solubility in water is considered. This is because the bypassed CO2 will redissolve into the water surrounding the bypassed zones which greatly retards the movement of CO2 towards the producer. In the gravity dominated scenario H2 accumulates at the top of the model and displaces the underlying cushion gas in an almost piston-like fashion. Approximately 58% of H2 can be recovered at a purity level above 98% (combustion requirements by ISO) in this gravity-dominated case. However when CO2 solubility is considered the H2 recovery performance is slightly degraded. This is because the dissolved CO2 is also gradually vaporised during H2 injection which leads to an expansion of mixing zone of CO2 and H2. This in turn reduces the period of high H2 purity level (>98%) during back-production.
Exergy Estimate of a Novel Hybrid Solar-gas Power and Organic Rankine Cycle-based Hydrogen-production System
Mar 2022
Publication
This study proposes a novel hybrid solar-gas power and hydrogen-production system which is comprised by the solar tower thermal system gas-steam turbine combined cycle and organic Rankine cycle-based hydrogen-production system. Based on the Ebsilon code the operation processes of the hybrid system are simulated. The results show that the output power and electric efficiency of the hybrid system are 103.9 MW and 41.3% and the daily hydrogen output is 62.2 kg. The operation simulation results of the hybrid system reveal that the gas-steam combined cycle and solar island can both achieve stable operations and the power generation section and hydrogen-production device can both work effectively which means the hybrid system is technically feasible. The exergy estimate results of the hybrid system show that the combustion chamber and solar receiver have the two largest exergy destructions which are 56.5 MW and 45.3 MW. That means the performances of the two components can be further improved. For the hydrogen-production system the exergy destructions of the proton exchange membrane electrolyzer turbine condenser and evaporator of the organic Rankine cycle are 0.156 MW 0.111 MW 2.338 MW and 1.891 MW and the corresponding exergy efficiencies are 51.2% 92.6% 80.7% and 79.5% respectively.
Optimal Allocation of Energy Sources in Hydrogen Production for Sustainable Deployment of Electric Vehicles
Jan 2023
Publication
We analyze the use of hydrogen as a fuel for the automotive industry with the aim of decarbonizing the economy. Hydrogen is a suitable option for avoiding pollutant gas emissions developing environmentally friendly technologies replacing fossil fuels with clean renewable energies and complying with the Paris Agreement and Glasgow resolutions. In this sense renewable energies such as wind solar photovoltaic geothermal biomass etc. can be used to produce the necessary hydrogen to power vehicles. In this way the entire process from hydrogen production to its consumption as fuel will be 100% clean. If we are to meet future energy demands it is necessary to forecast the amount of hydrogen needed taking into account the facilities currently available and new ones that will be required for its generation storage and distribution. This paper presents a process for optimizing hydrogen production for the automotive industry that considers the amount of hydrogen needed the type of facilities from which it will be produced how the different sources of production are to be combined to achieve a competitive product and the potential environmental impacts of each energy source. It can serve as a frame of reference for the various actors in the hydropower and automotive industries so that more efficient designs can be planned for the gradual introduction of hydrogen fuel cell vehicles (HFCVs). The methodology implemented in this paper sets an optimization problem for minimizing energy production costs and reducing environmental impacts according to the source of energy production. The EU framework with respect to the decarbonization of the economy the percentages of the different types of energy sources used and the non-polluting vehicle fleet in the automotive sector will be considered.
Optimal Integration of Hydrogen-Based Energy Storage Systems in Photovoltaic Microgrids: A Techno-Economic Assessment
Aug 2020
Publication
The feasibility and cost-effectiveness of hydrogen-based microgrids in facilities such as public buildings and small- and medium-sized enterprises provided by photovoltaic (PV) plants and characterized by low electric demand during weekends were investigated in this paper. Starting from the experience of the microgrid being built at the Renewable Energy Facility of Sardegna Ricerche (Italy) which among various energy production and storage systems includes a hydrogen storage system a modeling of the hydrogen-based microgrid was developed. The model was used to analyze the expected performance of the microgrid considering different load profiles and equipment sizes. Finally the microgrid cost-effectiveness was evaluated using a preliminary economic analysis. The results demonstrate that an effective design can be achieved with a PV system sized for an annual energy production 20% higher than the annual energy requested by the user and a hydrogen generator size 60% of the PV nominal power size. This configuration leads to a self-sufficiency rate of about 80% and without public grants a levelized cost of energy comparable with the cost of electricity in Italy can be achieved with a reduction of at least 25–40% of the current initial costs charged for the whole plant depending on the load profile shape.
A Review of Hydrogen Production and Supply Chain Modeling and Optmization
Jan 2023
Publication
This paper reviews recent optimization models for hydrogen supply chains and production. Optimization is a central component of systematic methodologies to support hydrogen expansion. Hydrogen production is expected to evolve in the coming years to help replace fossil fuels; these high expectations arise from the potential to produce low-carbon hydrogen via electrolysis using electricity generated by renewable sources. However hydrogen is currently mainly used in refinery and industrial operations; therefore physical infrastructures for transmission distribution integration with other energy systems and efficient hydrogen production processes are lacking. Given the potential of hydrogen the greenfield state of infrastructures and the variability of renewable sources systematic methodologies are needed to reach competitive hydrogen prices and design hydrogen supply chains. Future research topics are identified: 1) improved hydrogen demand projections 2) integrated sector modeling 3) improving temporal and spatial resolutions 4) accounting for climate change 5) new methods to address sophisticated models.
Experimental Study on the Self-ignition of Pressurized Hydrogen Released into Three-way Tubes
Sep 2021
Publication
To explore the effect of bifurcation structures on the spontaneous ignition and shock wave result from the sudden release of pressurized hydrogen. Three-way tubes with different bifurcation angles (90° 120° 150°) were used in the experiments. They are two Y-shape tubes and one T-shape tube. The photoelectric and pressure signals in the tube were recorded by the sensor. The results show that the reflected shock wave will be formed at the bifurcation. In addition the intensity and velocity of the leading shock wave will attenuate sharply when it passes through the bifurcation.The smaller bifurcation angle of tubethe smaller overpressure decay rate of shock wave at bifurcation position.The smaller the bifurcation angle of tubes the weaker the reflected shock wave transmitted downstream and the greater attenuation of shock wave intensity. Experimental results have reference value for the safety of hydrogen storage at high-pressure and are helpful to understand the influence of different tube structures on spontaneous ignition when hydrogen is transported at high pressure.
Hydrogen Permeation Behavior of QP1180 High Strength Steel in Simulated Coastal Atmosphere
Mar 2022
Publication
The hydrogen permeation behavior of QP1180 high strength steel for automobile was studied in simulate coastal atmosphere environment by using Devanathan-Stachurski dual electrolytic cell the cyclic corrosion test (CCT) thermal desorption spectrometry (TDS) and electrochemical measurement methods. The current density of hydrogen permeation generally increases with reducing the relative humidity from 95% to 50% and periodically changes in the CCT process. These mainly result from the evolution of corrosion and rust layer on the specimen surface with the atmospheric humidity and intermittent salt spraying. The contents of diffusible hydrogen and non-diffusible hydrogen in the steel enlarge slightly in the CCT process. The plastic deformation about 11.3% results in much higher diffusible hydrogen content in steel but noticeably reduces the hydrogen permeation current and almost has no influence on the non-diffusible hydrogen content. The combination of double electrolytic cell and standard cyclic corrosion test can effectively characterize the hydrogen permeation of high strength steel in atmospheric service environments.
Future Electricity Series Part 2 - Power from Renewables
Sep 2013
Publication
The independent cross-party report highlights a ‘sensible middle ground’ in the renewables debate and calls for more effort in building cross-party consensus. It finds that the UK has only just begun to harness low carbon renewable resources bigger than North Sea oil and gas and argues that the Government could do more to narrow the scope of debate about the technology mix beyond 2020. It argues that it should work with industry and academia first to establish ‘low regrets’ levels of technology deployment and second to ensure that policies are in place to incentivise investments such as supply chain investment needed to deliver these low regrets actions.
This approach would help provide the longer term clarity that could secure supply chain investments giving the UK a head-start in the global race. The report finds that these investments could be missed delayed or more expensive if there is insufficient confidence about long term demand for key technologies such as offshore wind. Work by Government to help incentivise these investments would increase the likelihood that technology cost reductions are achieved and help mitigate against high costs if new nuclear or carbon capture and storage development fail or are delayed.
On affordability the report finds that there are ‘hidden’ benefits that the UK could see from investing more in renewables through electricity bills between now and 2020. These include: avoiding bill increases driven by fossil fuels; making electricity bills more predictable; and providing an economic boost. The extra money paid to support renewables and other low carbon generation such as nuclear power could be more than offset by energy efficiency savings although Government needs to do more to show how these savings will arise.
On sustainability the report tackles myths about the carbon emitted in manufacturing renewable technologies or in backing up varying technologies such as wind solar wave and tidal. It finds that even when considering these factors renewables are still amongst the most low carbon options. The report also looks at the sustainability of electricity from biomass. Bioenergy overall could provide up to ten per cent of energy and reduce the cost of cutting carbon by £44 billion per year in 2050. The Government’s new biomass policies are a pragmatic response to concerns about the sustainability of biomass power which balances protecting the environment building public confidence and enabling the sector to grow.
On security of supply the inquiry argues that debate should focus on the whole electricity system and that individual technologies should be considered in the context of how they add to or reduce system risks. Considered like this renewables reduce some risks such as fuel supply risks which caused concern last winter and add to others such as system balancing risks. System balancing risks from varying renewables (wind solar wave and tidal technologies) are manageable using a number of existing and developing technologies.
The independent report chaired by former Energy Minister Charles Hendry MP and Shadow Energy Minister Baroness Worthington was compiled between May and September 2013 and was sponsored by Siemens and DONG Energy. It is part of a year-long independent and cross party inquiry into the UK power sector the Future Electricity Series sponsored by the Institution of Gas Engineers and Managers.
Link to Launch Video
This approach would help provide the longer term clarity that could secure supply chain investments giving the UK a head-start in the global race. The report finds that these investments could be missed delayed or more expensive if there is insufficient confidence about long term demand for key technologies such as offshore wind. Work by Government to help incentivise these investments would increase the likelihood that technology cost reductions are achieved and help mitigate against high costs if new nuclear or carbon capture and storage development fail or are delayed.
On affordability the report finds that there are ‘hidden’ benefits that the UK could see from investing more in renewables through electricity bills between now and 2020. These include: avoiding bill increases driven by fossil fuels; making electricity bills more predictable; and providing an economic boost. The extra money paid to support renewables and other low carbon generation such as nuclear power could be more than offset by energy efficiency savings although Government needs to do more to show how these savings will arise.
On sustainability the report tackles myths about the carbon emitted in manufacturing renewable technologies or in backing up varying technologies such as wind solar wave and tidal. It finds that even when considering these factors renewables are still amongst the most low carbon options. The report also looks at the sustainability of electricity from biomass. Bioenergy overall could provide up to ten per cent of energy and reduce the cost of cutting carbon by £44 billion per year in 2050. The Government’s new biomass policies are a pragmatic response to concerns about the sustainability of biomass power which balances protecting the environment building public confidence and enabling the sector to grow.
On security of supply the inquiry argues that debate should focus on the whole electricity system and that individual technologies should be considered in the context of how they add to or reduce system risks. Considered like this renewables reduce some risks such as fuel supply risks which caused concern last winter and add to others such as system balancing risks. System balancing risks from varying renewables (wind solar wave and tidal technologies) are manageable using a number of existing and developing technologies.
The independent report chaired by former Energy Minister Charles Hendry MP and Shadow Energy Minister Baroness Worthington was compiled between May and September 2013 and was sponsored by Siemens and DONG Energy. It is part of a year-long independent and cross party inquiry into the UK power sector the Future Electricity Series sponsored by the Institution of Gas Engineers and Managers.
Link to Launch Video
Effects of Renewable Energy Unstable Source to Hydrogen Production: Safety Considerations
Sep 2021
Publication
Hydrogen is considered a promising energy carrier for a sustainable future when it is produced by utilizing renewable energy. Nowadays less than 4% of hydrogen production is based on electrolysis processes. Each component of a hydrogen energy system needs to be optimized to increase the operation time and system efficiency. Only in this way hydrogen produced by electrolysis processes can be competitive with the conventional fossil energy sources. As conventional electrolysers are designed for operation at fixed process conditions the implementation of fluctuating and highly intermittent renewable energy is challenging. Alkaline water electrolysis is a key technology for large-scale hydrogen production powered by renewable energy. At low power availability conventional alkaline water electrolysers show a limited part-load range due to an increased gas impurity. Explosive mixtures of hydrogen and oxygen must be prevented; thus a safety shutdown is performed when reaching specific gas contamination. The University of Pisa is setting up a dedicated laboratory including a 40-kW commercial alkaline electrolyser: the focus of the study is to analyze the safety of the electrolyser together with its performance and the real energy efficiency analyzing its operational data collected under different operating conditions affected by the unstable energy supply.
HyDeploy2 Technical Services Report: Downstream Gas Standards Review
Jan 2021
Publication
The application of appropriate procedures in the downstream gas industry (defined as any works downstream of the emergency control value) is critical in protecting consumers of gas both domestic and commercial. The two primary standard setting bodies for the downstream gas industry are the British Standard Institution (BSI) and the Institution of Gas Engineers and Managers (IGEM). To ensure only competent engineers carry out works on a gas installation all gas businesses or selfemployed persons must become a member of Gas Safe Register as stipulated by the Gas Safety (Installation and Use) Regulations 1998 1 and each gas operative shall be included on the register and hold a valid license card that covers the areas of gas work they undertake. Membership of the Gas Safe Register is contingent upon demonstration of competency the recognised competency assessments are based on the relevant BSI and IGEM standards. Therefore the primary source of a gas operative’s competency to work on natural gas installations are the associated BSI and IGEM natural gas downstream standards.<br/>Investigation was undertaken to understand the potential implications of introducing 20 mol% hydrogen (H2) within natural gas supplies on the ability of gas operatives to competently carry out works. This investigation took the form of identifying all BSI and IGEM standards that could be applied on natural gas installations and reviewing them within the context of the known effects of introducing a 20 mol% H2 blend. Following review a series of technical questions were generated and responded to by the Health and Safety Executive Science Division. The responses provided were then reviewed and if considered necessary challenged to provide further information. The procedural review was led by Blue Flame Associates a body deemed sufficiently competent in downstream standards training certification and investigation. The report was subsequently reviewed by industry and feedback received. The industry comments were reviewed by the Project Team and where considered necessary the report was updated.
Overview of the Hydrogen Production by Plasma-Driven Solution Electrolysis
Oct 2022
Publication
This paper reviews the progress in applying the plasma-driven solution electrolysis (PDSE) which is also referred to as the contact glow-discharge electrolysis (CGDE) or plasma electrolysis for hydrogen production. The physicochemical processes responsible for the formation of PDSE and effects occurring at the discharge electrode in the cathodic and anodic regimes of the PDSE operation are described. The influence of the PDSE process parameters especially the discharge polarity magnitude of the applied voltage type and concentration of the typical electrolytic solutions (K2CO3 Na2CO3 KOH NaOH H2SO4 ) presence of organic additives (CH3OH C2H5OH CH3COOH) temperature of the electrolytic solution the active length and immersion depth of the discharge electrode into the electrolytic solution on the energy efficiency (%) energy yield (g(H2 )/kWh) and hydrogen production rate (g(H2 )/h) is presented and discussed. This analysis showed that in the cathodic regime of PDSE the hydrogen production rate is 33.3 times higher than that in the anodic regime of PDSE whereas the Faradaic and energy efficiencies are 11 and 12.5 times greater respectively than that in the anodic one. It also revealed the energy yield of hydrogen production in the cathodic regime of PDSE in the methanol–water mixture as the electrolytic solution is 3.9 times greater compared to that of the alkaline electrolysis 4.1 times greater compared to the polymer electrolyte membrane electrolysis 2.8 times greater compared to the solid oxide electrolysis 1.75 times greater than that obtained in the microwave (2.45 GHz) plasma and 5.8% greater compared to natural gas steam reforming.
Thermodynamic and Ecological Preselection of Synthetic Fuel Intermediates from Biogas at Farm Sites
Jan 2020
Publication
Background: Synthetic fuels based on renewable hydrogen and CO2 are a currently highly discussed piece of the puzzle to defossilize the transport sector. In this regard CO2 can play a positive role in shaping a sustainable future. Large potentials are available as a product of biogas production however occurring in small scales and in thin spatial distributions. This work aims to evaluate suitable synthetic fuel products to be produced at farm sites.<br/>Methods: A thermodynamic analysis to assess the energetic efficiency of synthesis pathways and a qualitative assessment of product handling issues is carried out.<br/>Results: Regarding the technical and safety-related advantages in storage liquid products are the superior option for fuel production at decentralized sites. Due to the economy of scale multi-stage synthesis processes lose economic performance with rising complexity. A method was shown which covers a principle sketch of all necessary reaction separation steps and all compression and heat exchanger units. The figures showed that methanol and butanol are the most suitable candidates in contrast to OME3-5 for implementation in existing transportation and fuel systems. These results were underpin by a Gibbs energy analysis.<br/>Conclusions: As long as safety regulations are met and the farm can guarantee safe storage and transport farm-site production for all intermediates can be realized technically. Ultimately this work points out that the process must be kept as simple as possible favoring methanol production at farm site and its further processing to more complicated fuels in large units for several fuel pathways.
Incentive Structures for Power-to-X and E-fuel Pathways for Transport in EU and Member States
Jun 2022
Publication
Though Power-to-X pathways primarily Power-to-Liquids attract interest as solutions for decarbonising parts of the transport sector that are not suitable for electrification the regulatory framework until recently slowed down their implementation. This paper examines the updates in the main aspects of the legal framework in the European Union from 2019 to the beginning of 2022 related to Power-to-X: support schemes specific targets and potential barriers. The results show increasing interest and market entrance of electrolysis and push from the different actors and regulatory parties to establish solutions that will enable faster upscaling. However it is visible from the National Energy and Climate Plans and hydrogen strategies that the most emphasis is still on hydrogen as an end fuel for personal vehicles or power-to-gas. On the other hand few countries have implemented legal frameworks facilitating diverse PtX pathways without focusing solely on hydrogen. Nevertheless revisions of RED II have finally set up specific targets for electrofuels and Fit for 55 has introduced new actions supporting electrofuels in aviation and marine transport.
Main Trends and Research Directions in Hydrogen Generation Using Low Temperature Electrolysis: A Systematic Literature Review
Aug 2022
Publication
Hydrogen (H2 ) is the most abundant element in the universe and it is also a neutral energy carrier meaning the environmental effects of using it are strictly related to the effects of creating the means of producing of that amount of Hydrogen. So far the H2 generation by water electrolysis research field did not manage to break the efficiency barrier in order to consider H2 production as a technology that sustains financially its self-development. However given the complexity of this technology and the overall environmental impacts an up-to-date research and development status review is critical. Thus this study aims to identify the main trends achievements and research directions of the H2 generation using pure and alkaline water electrolysis providing a review of the state of the art in the specific literature. Methods: In order to deliver this a Systematic Literature Review was carried out using PRISMA methodology highlighting the research trends and results in peer review publish articles over more than two years (2020–2022). Findings: This review identifies niches and actual status of the H2 generation by water and alkaline water electrolysis and points out in numbers the boundaries of the 2020–2022 timeline research.
Fuel-scale Tunnel Experiments for Fuel Cell Hydrogen Vehicles: Gas Dispersion
Sep 2021
Publication
In the framework of the HYTUNNEL-CS European project sponsored by FCH-JU a set of preliminary tests were conducted in a real tunnel in France. These tests are devoted to safety of hydrogen-fueled vehicles having a compressed gas storage and Temperature Pressure Release Device (TPRD). The goal of the study is to develop recommendations for Regulations Codes and Standards (RCS) for inherently safer use of hydrogen vehicles in enclosed transportation systems. In these preliminary tests the helium gas has been employed instead of hydrogen. Upward and downward gas releases following by TPRD activation has been considered. The experimental data describing local behavior (close to jet or below the chassis) as well as global behavior at the tunnel scale are obtained. These experimental data are systematically compared to existing engineering correlations. The results will be used for benchmarking studies using CFD codes. The hydrogen pressure range in these preliminary tests has been lowered down to 20MPa in order to verify the capability of various large-scale measurement techniques before scaling up to 70MPa the subject of the second campaign.
Use of Hydrogen in Off-Grid Locations, a Techno-Economic Assessment
Nov 2018
Publication
Diesel generators are currently used as an off-grid solution for backup power but this causes CO2 and GHG emissions noise emissions and the negative effects of the volatile diesel market influencing operating costs. Green hydrogen production by means of water electrolysis has been proposed as a feasible solution to fill the gaps between demand and production the main handicaps of using exclusively renewable energy in isolated applications. This manuscript presents a business case of an off-grid hydrogen production by electrolysis applied to the electrification of isolated sites. This study is part of the European Ely4off project (n◦ 700359). Under certain techno-economic hypothesis four different system configurations supplied exclusively by photovoltaic are compared to find the optimal Levelized Cost of Electricity (LCoE): photovoltaic-batteries photovoltaic-hydrogen-batteries photovoltaic-diesel generator and diesel generator; the influence of the location and the impact of different consumptions profiles is explored. Several simulations developed through specific modeling software are carried out and discussed. The main finding is that diesel-based systems still allow lower costs than any other solution although hydrogen-based solutions can compete with other technologies under certain conditions.
Electric Load Influence on Performances of a Composite Plant for Hydrogen Production from RES and its Conversion in Electricity
Nov 2019
Publication
The analysis here presented investigates the influence of electrical load on the operational performances of a plant for hydrogen production from solar energy and its conversion in electricity via a fuel cell. The plant is an actual one currently under construction in Reggio Calabria (Italy) at the site of the Mediterranean university campus; it is composed of a Renewable Energy Source (RES) section (photovoltaic panels) a hydrogen production section and a fuel cell power section feeding the electrical energy demand of the load. Two different load configurations have been analysed and simulations have been carried out through HomerTM simulation code. Results allow interesting conclusions regarding the plant operation to be drawn. The study could have a remarkable role in supporting further research activities aimed at the assessment of the optimal configuration of this type of pioneering plants designed for feeding electrical loads possibly in a self-sufficient way.
Hydrogen Safety Strategies and Risk Management in Equinor
Sep 2021
Publication
Equinor has in recent years focused on low carbon technologies in addition to conventional oil & gas technologies. Clear strategic directions have been set to demonstrate Equinor’s commitment to longterm value creation that supports the Paris Agreement. This includes acceleration of decarbonization by establishing a well-functioning market for carbon capture transport and storage (CCS) as well as development of competitive hydrogen-based value chains and solutions. The specific properties of hydrogen must be taken into account in order to ensure safe design and operation of hydrogen systems as these properties differ substantially from those of natural gas and other conventional oil & gas products. Development projects need to consider and mitigate the increased possibility of high explosion pressures or detonation if hydrogen releases accumulate in enclosed or congested areas. On the other hand hydrogen’s buoyant properties can be exploited by locating potential leak points in the open to avoid gas accumulation thereby reducing the explosion risk. The purpose of this paper is to introduce Equinor’s hydrogen-based value chain projects and present our approach to ensure safe and effective designs. Safety strategies constitute the basis for Equinor’s safety and risk management. The safety strategies describe the connection between the hazards and risk profiles on one hand and the safety barrier elements and their needed performance on the other as input to safe design. The safety strategies also form the basis for safe operation. Measures to control the risk through practical designs follow from these strategies.
Model Supported Business Case Scenario Analysis for Decentral Hydrogen Conversion, Storage and Consumption within Energy Hubs
Mar 2022
Publication
Recently smart energy hubs with hydrogen conversion and storage have received increased attention in the Netherlands. The hydrogen is to be used for vehicle filling stations industrial processes and heating. The scientific problem addressed in this paper is the proper sizing of capacities for renewable energy generation hydrogen conversion and storage in relation to a feasible business case for the energy hub while achieving security of supply. Scenario analysis is often used during the early stages of the energy planning process and for this an easy-to-use analysis model is required. This paper investigates available modelling approaches and develops an algorithmic modelling method which is worked out in Microsoft Excel and offers ease of use for scenario analysis purposes. The model is applied to case study which leads to important insights such as the expected price of hydrogen and the proper sizing of electrolyser and hydrogen storage for that case. The model is made available open-source. Future work is proposed in the direction of application of the model for other project cases and comparison of results with other available modelling tools.
Optimized Design of a H2-Powered Moped for Urban Mobility
Mar 2024
Publication
Micro-mobility plays an increasingly important role in the current energy transition thanks to its low energy consumption and reduced contribution to urban congestion. In this scenario fuel cell hybrid electric vehicles have several advantages over state-of-the-art battery electric vehicles such as increased driving ranges and reduced recharge times. In this paper we study the conversion of a commercial electric moped (Askoll eS3 ®) into a fuel cell hybrid electric vehicle by finding the optimal design of the components through an optimization methodology based on backward dynamic programming. This optimal design and operation strategy can also be implemented with a rulesbased approach. The results show that a system composed of a 1 kW proton exchange membrane fuel cell a 2000 Sl metal hydride hydrogen tank and a 240 Wh buffer battery can cover the same driving range as the batteries in an electric moped (119 km). Such a hybrid system occupies considerably less volume (almost 40 L) and has a negligibly higher mass. The free volume can be used to extend the driving range up to almost three times the nominal value. Moreover by using a high-pressure composite tank it is possible to increase the mass energy density of the onboard energy storage (although compression can require up to 10% of the hydrogen’s chemical energy). The fuel cell hybrid electric vehicle can be recharged with green hydrogen that is locally produced. In detail we analyze a residential scenario and a shared mobility scenario in the small Italian city of Viterbo.
The Role of Clean Hydrogen Value Chain in a Successful Energy Transition of Japan
Aug 2022
Publication
The clean hydrogen in the prioritized value chain platform could provide energy incentives and reduce environmental impacts. In the current study strengths weaknesses opportunities and threats (SWOT) analysis has been successfully applied to the clean hydrogen value chain in different sectors to determine Japan’s clean hydrogen value chain’s strengths weaknesses opportunities and threats as a case study. Japan was chosen as a case study since we believe that it is the only pioneer country in that chain with a national strategy investments and current projects which make it unique in this way. The analyses include evaluations of clean energy development power supply chains regional energy planning and renewable energy development including the internal and external elements that may influence the growth of the hydrogen economy in Japan. The ability of Japan to produce and use large quantities of clean hydrogen at a price that is competitive with fossil fuels is critical to the country’s future success. The implementation of an efficient carbon tax and carbon pricing is also necessary for cost parity. There will be an increasing demand for global policy coordination and inter-industry cooperation. The results obtained from this research will be a suitable model for other countries to be aware of the strengths weaknesses opportunities and threats in this field in order to make proper decisions according to their infrastructures potentials economies and socio-political states in that field.
Optimized Configuration of Diesel Engine-Fuel Cell-Battery Hybrid Power Systems in a Platform Supply Vessel to Reduce CO2 Emissions
Mar 2022
Publication
The main objective of this paper is to select the optimal configuration of a ship’s power system considering the use of fuel cells and batteries that would achieve the lowest CO2 emissions also taking into consideration the number of battery cycles. The ship analyzed in this work is a Platform Supply Vessel (PSV) used to support oil and gas offshore platforms transporting goods equipment and personnel. The proposed scheme considers the ship’s retrofitting. The ship’s original main generators are maintained and the fuel cell and batteries are installed as complementary sources. Moreover a sensitivity analysis is pursued on the ship’s demand curve. The simulations used to calculate the CO2 emissions for each of the new hybrid configurations were developed using HOMER software. The proposed solutions are auxiliary generators three types of batteries and a protonexchange membrane fuel cell (PEMFC) with different sizes of hydrogen tanks. The PEMFC and batteries were sized as containerized solutions and the sizing of the auxiliary engines was based on previous works. Each configuration consists of a combination of these solutions. The selection of the best configuration is one contribution of this paper. The new configurations are classified according to the reduction of CO2 emitted in comparison to the original system. For different demand levels the results indicate that the configuration classification may vary. Another valuable contribution of this work is the sizing of the battery and hydrogen storage systems. They were installed in 20 ft containers since the installation of batteries fuel cells and hydrogen tanks in containers is widely used for ship retrofit. As a result the most significant reduction of CO2 emissions is 10.69%. This is achieved when the configuration includes main generators auxiliary generators a 3119 kW lithium nickel manganese cobalt (LNMC) battery a 250 kW PEMFC and 581 kg of stored hydrogen.
Minimum Fire Size for Hydrogen Storage Tank Fire Test Protocol for Hydrogen-powered Electric City Bus Determine Via Risk-based Approach
Sep 2021
Publication
As part of the United Nations Global Technical Regulation No. 13 (UN GTR #13 [1]) vehicle fire safety is validated using a localized and engulfing fire test methodology and currently updates are being considered in the on-going Phase 2 development stage. The GTR#13 fire test is designed to verify the performance of a hydrogen storage system of preventing rupture when exposed to service-terminating condition of fire situation. The test is conducted in two stages – localized flame exposure at a location most challenging for thermally-activated pressure relief device(s) (TPRDs) to respond for 10 min. followed by engulfing fire exposure until the system vents and the pressure falls to less than 1 MPa or until “time out” (30min. for light-duty vehicle containers and 60 min. for heavy-duty vehicle containers). The rationale behind this two-stage fire test is to ensure that even when fire sizes are small and TPRDs are not responding the containers have fire resistance to withstand or fire sensitivity to respond to a localized fire to avoid system rupture. In this study appropriate fire sizes for localized and engulfing fire tests in GTR#13 are evaluated by considering actual fire conditions in a hydrogen-powered electric city bus. Quantitative risk analysis is conducted to develop various fire accident scenarios including regular bus fire battery fire and hydrogen leak fire. Frequency and severity analyses are performed to determine the minimum fire size required in GTR#13 fire test to ensure hydrogen storage tank safety in hydrogen-powered electric city buses.
Design of Fuel Cell Systems for Aviation: Representative Mission Profiles and Sensitivity Analyses
Apr 2019
Publication
The global transition to a clean and sustainable energy infrastructure does not stop at aviation. The European Commission defined a set of environmental goals for the “Flight Path 2050”: 75% CO2 reduction 90% NOx reduction and 65% perceived noise reduction. Hydrogen as an energy carrier fulfills these needs while it would also offer a tenable and flexible solution for intermittent large-scale energy storage for renewable energy networks. If hydrogen is used as an energy carrier there is no better device than a fuel cell to convert its stored chemical energy. In order to design fuel cell systems for passenger aircraft it is necessary to specify the requirements that the system has to fulfill. In this paper a statistical approach to analyze these requirements is presented which accounts for variations in the flight mission profile. Starting from a subset of flight data within the desired class (e.g. mid-range inter-European flights) a stochastic model of the random mission profile is inferred. This model allows for subsequent predictions under uncertainty as part of the aircraft design process. By using Monte Carlo-based sampling of flight mission profiles the range of necessary component sizes as well as optimal degrees of hybridization with a battery is explored and design options are evaluated. Furthermore Monte Carlo-based sensitivity analysis of performance parameters explores the potential of future technological developments. Results suggest that the improvement of the specific power of the fuel cell is the deciding factor for lowering the energy system mass. The specific energy of the battery has a low influence but acts in conjunction with the specific power of the fuel cell.
Underground Storage of Green Hydrogen—Boundary Conditions for Compressor Systems
Aug 2022
Publication
The large-scale storage of hydrogen in salt caverns modelled on today’s natural gas storage is a promising approach to storing renewable energy over a large power range and for the required time period. An essential subsystem of the overall gas storage is the surface facility and in particular the compressor system. The future design of compressor systems for hydrogen storage strongly depends on the respective boundary conditions. Therefore this work analyses the requirements of compressor systems for cavern storage facilities for the storage of green hydrogen i.e. hydrogen produced from renewable energy sources using the example of Lower Saxony in Germany. In this course a hydrogen storage demand profile of one year is developed in hourly resolution from feed-in time series of renewable energy sources. The injection profile relevant for compressor operation is compared with current natural gas injection operation modes
Transient Modeling and Performance Analysis of Hydrogen-Fueled Aero Engines
Jan 2023
Publication
With the combustor burning hydrogen as well as the strongly coupled fuel and cooling system the configuration of a hydrogen-fueled aero engine is more complex than that of a conventional aero engine. The performance and especially the dynamic behavior of a hydrogen-fueled aero engine need to be fully understood for engine system design and optimization. In this paper both the transient modeling and performance analysis of hydrogen-fueled engines are presented. Firstly the models specific to the hydrogen-fueled engine components and systems including the hydrogen-fueled combustor the steam injection system a simplified model for a quick NOx emission assessment and the heat exchangers are developed and then integrated to a conventional engine models. The simulations with both Simulink and Speedgoat-based hardware in the loop system are carried out. Secondly the performance analysis is performed for a typical turbofan engine configuration CF6 and for the two hydrogen-fueled engine configurations ENABLEH2 and HySIITE which are currently under research and development by the European Union and Pratt & Whitney respectively. At last the simulation results demonstrate that the developed transient models can effectively reflect the characteristics of hydrogen burning heat exchanging and NOx emission for hydrogen-fueled engines. In most cases the hydrogen-fueled engines show lower specific fuel consumption lower turbine entry temperature and less NOx emissions compared with conventional engines. For example at max thrust state the advanced hydrogen-fueled engine can reduce the parameters mentioned above by about 68.5% 3.7% and 12.7% respectively (a mean value of two configurations).
Analysis of Hydrogen-powered Propulsion System Alternatives for Diesel-electric Regional Trains
Aug 2022
Publication
Non-electrified regional railway lines with typically employed diesel-electric multiple units require alternative propulsion systems to meet increasingly strict emissions regulations. With the aim to identify an optimal alternative to conventional diesel traction this paper presents a model-based assessment of hydrogen-powered propulsion systems with an internal combustion engine or fuel cells as the prime mover combined with different energy storage system configurations based on lithium-ion batteries and/or double-layer capacitors. The analysis encompasses technology identification design modelling and assessment of alternative powertrains explicitly considering case-related constraints imposed by the infrastructure technical and operational requirements. Using a regional railway network in the Netherlands as a case we investigate the possibilities in converting a conventional benchmark vehicle and provide the railway undertaking and decision-makers with valuable input for planning of future rolling stock investments. The results indicate the highest fuel-saving potential for fuel cell-based hybrid propulsion systems with lithium-ion battery or a hybrid energy storage system that combines both energy storage system technologies. The two configurations also demonstrate the highest reduction of greenhouse gas emissions compared to the benchmark diesel-driven vehicle by about 25% for hydrogen produced by steam methane reforming and about 19% for hydrogen obtained from electrolysis of water with grey electricity.
Investigation of Mixing Behavior of Hydrogen Blended to Natural Gas in Gas Network
Apr 2021
Publication
Hydrogen is of great significance for replacing fossil fuels and reducing carbon dioxide emissions. The application of hydrogen mixing with natural gas in gas network transportation not only improves the utilization rate of hydrogen energy but also reduces the cost of large-scale updating household or commercial appliance. This paper investigates the necessity of a gas mixing device for adding hydrogen to existing natural gas pipelines in the industrial gas network. A three-dimensional helical static mixer model is developed to simulate the mixing behavior of the gas mixture. In addition the model is validated with experimental results. Parametric studies are performed to investigate the effect of mixer on the mixing performance including the coefficient of variation (COV) and pressure loss. The research results show that based on the the optimum number of mixing units is three. The arrangement of the torsion angle of the mixing unit has a greater impact on the COV. When the torsion angle θ = 120◦ the COV has a minimum value of 0.66% and when the torsion angle θ = 60◦ the COV has a maximum value of 8.54%. The distance of the mixing unit has little effect on the pressure loss of the mixed gas but has a greater impact on the COV. Consecutive arrangement of the mixing units (Case A) is the best solution. Increasing the distance of the mixing unit is not effective for the gas mixing effect. Last but not least the gas mixer is optimized to improve the mixing performance.
Combustion of Hydrogen Enriched Methane and Biogases Containing Hydrogen in a Controlled Auto-Ignition Engine
Dec 2018
Publication
The paper describes a numerical study of the combustion of hydrogen enriched methane and biogases containing hydrogen in a Controlled Auto Ignition engine (CAI). A single cylinder CAI engine is modelled with Chemkin to predict engine performance comparing the fuels in terms of indicated mean effective pressure engine efficiency and pollutant emissions. The effects of hydrogen and carbon dioxide on the combustion process are evaluated using the GRI-Mech 3.0 detailed radical chain reactions mechanism. A parametric study performed by varying the temperature at the start of compression and the equivalence ratio allows evaluating the temperature requirements for all fuels; moreover the effect of hydrogen enrichment on the auto-ignition process is investigated. The results show that at constant initial temperature hydrogen promotes the ignition which then occurs earlier as a consequence of higher chemical reactivity. At a fixed indicated mean effective pressure hydrogen presence shifts the operating range towards lower initial gas temperature and lower equivalence ratio and reduces NOx emissions. Such reduction somewhat counter-intuitive if compared with similar studies on spark-ignition engines is the result of operating the engine at lower initial gas temperatures.
Accurate Predictions of the Effect of Hydrogen Composition on the Thermodynamics and Transport Properties of Natural Gas
Mar 2024
Publication
This work demonstrates the need for accurate thermodynamic models to reliably quantify changes in the thermophysical properties of natural gas when blended with hydrogen. For this purpose a systematic evaluation was carried out on the predictive accuracy of three well-known models the Peng−Robinson equation of state (EoS) the multiparameter empirical GERG-2008 model and the molecular-based polar softSAFT EoS in describing the thermodynamic behavior of mixtures of hydrogen with commonly found components in natural gas. Deviations between the calculated properties and experimental data for phase equilibria critical loci second-order derivative properties and viscosities are used to determine the accuracy of the models with polar soft-SAFT performing either equally or better than the other two examined models. The evaluation for the effect of H2 content on the properties of methane simulated as natural gas at conditions for transportation reveals higher changes in blend density and speed of sound with increasing H2 content within 5% change per 5 mol % H2 added while viscosity is the least affected property changing by 0.4% for every 5 mol % H2.
Energy Management Control Strategy for Saving Trip Costs of Fuel Cell/Battery Electric Vehicles
Mar 2022
Publication
Fuel cell vehicles (FCVs) should control the energy management between two energy sources for fuel economy using the stored energy in a battery or generation of energy through a fuel cell system. The fuel economy for an FCV includes trip costs for hydrogen consumption and the lifetime of two energy sources. This paper proposes an implementable energy management control strategy for an FCV to reduce trip costs. The concept of the proposed control strategy is first to analyze the allowable current of a fuel cell system from the optimal strategies for various initial battery state of charge (SOC) conditions using dynamic programming (DP) and second to find a modulation ratio determining the current of a fuel cell system for driving a vehicle using the particle swarm optimization method. The control strategy presents the on/off moment of a fuel cell system and the proper modulation ratio of the turned-on fuel cell system with respect to the battery SOC and the power demand. The proposed strategy reduces trip costs in real-time similar to the DP-based optimal strategy and more than the simple energy control strategy of switching a fuel cell system on/off at the battery SOC boundary conditions even for long-term driving cycles.
Regional Uptake of Direct Reduction Iron Production Using Hydrogen Under Climate Policy
Nov 2022
Publication
The need to reduce CO2 emissions to zero by 2050 has meant an increasing focus on high emitting industrial sectors such as steel. However significant uncertainties remain as to the rate of technology diffusion across steel production pathways in different regions and how this might impact on climate ambition. Informed by empirical analysis of historical transitions this paper presents modelling on the regional deployment of Direction Reduction Iron using hydrogen (DRI-H2). We find that DRI-H2 can play a leading role in the decarbonisation of the sector leading to near-zero emissions by 2070. Regional spillovers from early to late adopting regions can speed up the rate of deployment of DRI-H2 leading to lower cumulative emissions and system costs. Without such effects cumulative emissions are 13% higher than if spillovers are assumed and approximately 15% and 20% higher in China and India respectively. Given the estimates of DRI-H2 cost-effectiveness relative to other primary production technologies we also find that costs increase in the absence of regional spillovers. However other factors can also have impacts on deployment emission reductions and costs including the composition of the early adopter group material efficiency improvements and scrap recycling rates. For the sector to achieve decarbonisation key regions will need to continue to invest in low carbon steel projects recognising their broader global benefit and look to develop and strengthen policy coordination on technologies such as DRI-H2.
Efficient Plasma Technology for the Production of Green Hydrogen from Ethanol and Water
Apr 2022
Publication
This study concerns the production of hydrogen from a mixture of ethanol and water. The process was conducted in plasma generated by a spark discharge. The substrates were introduced in the liquid phase into the reactor. The gaseous products formed in the spark reactor were hydrogen carbon monoxide carbon dioxide methane acetylene and ethylene. Coke was also produced. The energy efficiency of hydrogen production was 27 mol(H2 )/kWh and it was 36% of the theoretical energy efficiency. The high value of the energy efficiency of hydrogen production was obtained with relatively high ethanol conversion (63%). In the spark discharge it was possible to conduct the process under conditions in which the ethanol conversion reached 95%. However this entailed higher energy consumption and reduced the energy efficiency of hydrogen production to 8.8 mol(H2 )/kWh. Hydrogen production increased with increasing discharge power and feed stream. However the hydrogen concentration was very high under all tested conditions and ranged from 57.5 to 61.5%. This means that the spark reactor is a device that can feed fuel cells the power load of which can fluctuate.
Hydrogen Storage in Geological Formations—The Potential of Salt Caverns
Jul 2022
Publication
Hydrogen-based technologies are among the most promising solutions to fulfill the zero-emission scenario and ensure the energy independence of many countries. Hydrogen is considered a green energy carrier which can be utilized in the energy transport and chemical sectors. However efficient and safe large-scale hydrogen storage is still challenging. The most frequently used hydrogen storage solutions in industry i.e. compression and liquefaction are highly energy-consuming. Underground hydrogen storage is considered the most economical and safe option for large-scale utilization at various time scales. Among underground geological formations salt caverns are the most promising for hydrogen storage due to their suitable physicochemical and mechanical properties that ensure safe and efficient storage even at high pressures. In this paper recent advances in underground storage with a particular emphasis on salt cavern utilization in Europe are presented. The initial experience in hydrogen storage in underground reservoirs was discussed and the potential for worldwide commercialization of this technology was analyzed. In Poland salt deposits from the north-west and central regions (e.g. Rogóźno Damasławek Łeba) are considered possible formations for hydrogen storage. The Gubin area is also promising where 25 salt caverns with a total capacity of 1600 million Nm3 can be constructed.
Injection of Gaseous Hydrogen into a Natural Gas Pipeline
May 2022
Publication
The injection of pure hydrogen at a T-junction into a horizontal pipe carrying natural gas is analysed computationally to understand the influence of blending and pipe geometry (diameter ratio various 90 orientations) on mixing for a target of 4.8e20% volume fraction hydrogen blend. The strongly inhomogeneous distribution of hydrogen within the pipe flow and on the pipe walls could indicate the location of potential pipe material degradation including embrittlement effects. The low molecular mass of hydrogen reduces the penetration of a side-branch flow and increases the buoyancy forces leading to stratification with high hydrogen concentrations on the upper pipe surface downstream of the branch. Top-side injection leads to the hydrogen concentration remaining >40% for up to 8 pipe diameters from the injection point for volumetric dilutions ( D) less than 30%. Under-side injection promotes mixing within the flow interior and reduces wall concentration at the lower surface compared to top-side injection. The practical implications for these results in terms of mixing requirements and the contrasting constraint of codes of practice and energy demands are discussed.
Numerical Simulation on Heating Effects during Hydrogen Absorption in Metal Hydride Systems for Hydrogen Storage
Apr 2022
Publication
A 2-D numerical simulation model was established based on a small-sized metal hydride storage tank and the model was validated by the existing experiments. An external cooling bath was equipped to simulate the heating effects of hydrogen absorption reactions. Furthermore both the type and the flow rate of the cooling fluids in the cooling bath were altered so that changes in temperature and hydrogen storage capacity in the hydrogen storage model could be analyzed. It is demonstrated that the reaction rate in the center of the hydrogen storage tank gradually becomes lower than that at the wall surface. When the flow rate of the fluid is small significant differences can be found in the cooling liquid temperature at the inlet and the outlet cooling bath. In areas adjacent to its inlet the reaction rate is higher than that at the outlet and a better cooling effect is produced by water. As the flow rate increases the total time consumed by hydrogen adsorption reaction is gradually reduced to a constant value. At the same flow rate the wall surface of the tank shows a reaction rate insignificantly different from that in its center provided that cooling water or oil coolant is replaced with air.
Developing Networks for the Future: Long-Term Development Plan 2019
Oct 2019
Publication
This report provides you with the information you need if you have plans to interact with or connect to our gas networks. Our vision is to set the standards that all of our customers love and others aspire to. This means that our long-term plans are shaped by our customers and stakeholders. This annual publication is an important opportunity to share our latest long-term plan and our strategic thinking and seek feedback so we can continue to adapt our activities going forward. We want to make it as easy and efficient as possible for you to interact with us.
Cadent Long Term Development Plan 2019
Cadent Long Term Development Plan 2019
Repurposing Fischer-Tropsch and Natural Gas as Bridging Technologies for the Energy Revolution
Jun 2022
Publication
Immediate and widespread changes in energy generation and use are critical to safeguard our future on this planet. However while the necessity of renewable electricity generation is clear the aviation transport and mobility chemical and material sectors are challenging to fully electrify. The age-old Fischer-Tropsch process and natural gas industry could be the bridging solution needed to accelerate the energy revolution in these sectors – temporarily powering obsolete vehicles acting as renewable energy’s battery supporting expansion of hydrogen fuel cell technologies and the agricultural and waste sectors as they struggle to keep up with a full switch to biofuels. Natural gas can be converted into hydrogen synthetic natural gas or heat during periods of low electricity demand and converted back to electricity again when needed. Moving methane through existing networks and converting it to hydrogen on-site at tanking stations also overcomes hydrogen distribution storage problems and infrastructure deficiencies. Useful co-products include carbon nanotubes a valuable engineering material that offset emissions in the carbon nanotube and black industries. Finally excess carbon can be converted back into syngas if desired. This flexibility and the compatibility of natural gas with both existing and future technologies provides a unique opportunity to rapidly decarbonise sectors struggling with complex requirements.
Numerical Study on Protective Measures for a Skid-Mounted Hydrogen Refueling Station
Jan 2023
Publication
Hydrogen refueling stations are one of the key infrastructure components for the hydrogen-fueled economy. Skid-mounted hydrogen refueling stations (SHRSs) can be more easily commercialized due to their smaller footprints and lower costs compared to stationary hydrogen refueling stations. The present work modeled hydrogen explosions in a skid-mounted hydrogen refueling station to predict the overpressures for hydrogen-air mixtures and investigate the protective effects for different explosion vent layouts and protective wall distances. The results show that the explosive vents with the same vent area have similar overpressure reduction effects. The layout of the explosion vent affects the flame shape. Explosion venting can effectively reduce the inside maximum overpressure by 61.8%. The protective walls can reduce the overpressures but the protective walls should not be too close to the SHRS because high overpressures are generated inside the walls due to the confined shock waves. The protective wall with a distance of 6 m can effectively protect the surrounding people and avoid the secondary overpressure damage to the container.
Fugitive Hydrogen Emissions in a Future Hydrogen Economy
Apr 2022
Publication
There is an increasing body of evidence that leakage of hydrogen to the atmosphere will have an indirect warming effect on the climate and so should be minimised.<br/>This study investigates and quantifies the current understanding of potential hydrogen emissions in the different sectors across a future hydrogen value-chain. It shows that there are some key areas in production distribution and end-use where there could potentially be significant leaks of hydrogen to the atmosphere. In some of these areas there are clear mitigation options while with others the options are less clear due to uncertainty in either data or future technology development.<br/>The report recommends further research and development to reduce the main leak pathways and additional evidence gathering in key areas where there is currently inadequate data to make accurate predictions.<br/>The study was commissioned by BEIS and conducted by the Frazer-Nash consultancy.
Sector Coupling and Business Models Towards Sustainability: The Case of the Hydrogen Vehicle Industry
Mar 2022
Publication
The concept of sector coupling has been gaining increased momentum in political discourses during 18 the past few years but it has only recently received the attention of international academics. The 19 private sector is particularly relevant to foster sector coupling through entrepreneurial action – 20 specifically innovative business models for more sustainable technologies are needed to promote a 21 transition towards more sustainability. So far however the literature on business models from a 22 sector coupling perspective is scarce yet strongly emerging. To address the identified research gaps 23 and enhance the current knowledge on the emerging hydrogen vehicle industry and sector coupling 24 this study adopts a qualitative and exploratory research approach and builds on information gained 25 in 103 semi-structured interviews to discuss emerging business models in Germany. In particular 33 26 business cases have been analyzed. Anchoring business model theory to the concept of sector 27 coupling this study identifies 12 business model archetypes in the emerging hydrogen vehicle 28 industry and its value chain. It can be shown that while the market is still emerging and the market 29 players are not defined and are evolving companies are currently engaged in finding their position 30 along the value chain fostering vertical integration and promoting cooperation between the 31 different sectors. While this study is relevant for both the academia and the industry it is particularly 2 32 interesting for policy makers shaping the future of sustainable development specifically considering 33 integrated energy systems.
Simulation of Possible Fire and Explosion Hazards of Clean Fuel Vehicles in Garages
Nov 2021
Publication
Clean fuel is advocated to be used for sustainability. The number of liquefied petroleum gas (LPG) and hydrogen vehicles is increasing globally. Explosion hazard is a threat. On the other hand the use of hydrogen is under consideration in Hong Kong. Explosion hazards of these clean fuel (LPG and hydrogen) vehicles were studied and are compared in this paper. The computational fluid dynamics (CFD) software Flame Acceleration Simulator (FLACS) was used. A car garage with a rolling shutter as its entrance was selected for study. Dispersion of LPG from the leakage source with ignition at a higher position was studied. The same garage was used with a typical hydrogen vehicle leaking 3.4 pounds (1.5 kg) of hydrogen in 100 s the mass flow rate being equal to 0.015 kgs−1 . The hydrogen vehicle used in the simulation has two hydrogen tanks with a combined capacity of 5 kg. The entire tank would be completely vented out in about 333 s. Two scenarios of CFD simulation were carried out. In the first scenario the rolling shutter was completely closed and the leaked LPG or hydrogen was ignited at 300 s after leakage. The second scenario was conducted with a gap height of 0.3 m under the rolling shutter. Predicted results of explosion pressure and temperature show that appropriate active fire engineering systems are required when servicing these clean fuel vehicles in garages. An appropriate vent in an enclosed space such as the garage is important in reducing explosion hazards.
Modular Modeling Method and Power Supply Capability Evaluation for Integrated Hydrogen Production Stations of DC Systems
Mar 2022
Publication
Low-voltage DC distribution system has many advantages such as facilitating the access of DC loads and distributed energies and improving the network’s stability. It has become a new idea for integrated hydrogen production stations. Power supply capacity and small-signal stability are important indexes to evaluate a low-voltage DC integrated system. Based on the master–slave control mode this paper selects the typical star structure as the research object constructs the system transfer function through the scalable modular modeling method and further evaluates the impact of the high-order DC hydrogen production station integrated system on the hydrogen production capacity under the changes of the line length and master station position. The results show that the hydrogen production capacity of the system decreases gradually with the main station moving from side to inside. Finally a practical example is analyzed by MATLAB/Simulink simulation to verify the accuracy of the theory. This study can provide an effective theoretical method for the structure optimization and integrated parameter design of low-voltage DC system
Residual Tensile Properties of Carbon Fiber Reinforced Epoxy Resin Composites at Elevated Temperatures
Sep 2021
Publication
Carbon fiber reinforced epoxy resin composites have attracted great attention in high pressure hydrogen storage for its light weight and excellent mechanical properties. The degradation of residual mechanical properties at elevated temperature from 20 °C to 450 °C were studied experimentally. The effects of temperature on the tensile strength and failure mode of the composite specimens with stacking sequences of 0° 90° and ±45° (labeled as CF0 CF90 and CF 45) were systematically analyzed followed by the fracture surfaces examination. Results show that the tensile strength residual ratios of the three kinds of specimens decrease significantly with heating temperature increasing. In particular the decomposing temperature of the resin matrix exerts the largest effects on the degradation of tensile strength of CF0 specimen within 450 °C. While the loss of tensile strength of CF90 and CF45 specimens is dependent on the thermal softening of epoxy resin which has closely related to the glass transition temperature. Furthermore the debonding and fiber softening appeared in the CF0 specimens when the temperature reached 450 °C. For CF90 specimens the degradation of bonding strength of epoxy could be found at 150 °C and regarding CF45 specimens delamination cracking between plies occurred extensively when the temperature above 125 °C.
Full-scale Tunnel Experiments for Fuel Cell Hydrogen Vehicles: Jat Fire and Explosions
Sep 2021
Publication
In the framework of the HYTUNNEL-CS European project sponsored by FCH-JU a set of preliminary tests were conducted in a real tunnel in France. These tests are devoted to safety of hydrogen-fueled vehicles having a compressed gas storage and Temperature Pressure Release Device (TPRD). The goal of the study is to develop recommendations for Regulations Codes and Standards (RCS) for inherently safer use of hydrogen vehicles in enclosed transportation systems. Two scenarios were investigated (a) jet fire evolution following the activation of TPRD due to conventional fuel car fire and (b) explosion of compressed hydrogen tank. The obtained experimental data are systematically compared to existing engineering correlations. The results will be used for benchmarking studies using CFD codes. The hydrogen pressure range in these preliminary tests has been lowered down to 20MPa in order to verify the capability of various large-scale measurement techniques before scaling up to 70 MPa the subject of the second experimental campaign.
Are Sustainable Aviation Fuels a Viable Option for Decarbonizing Air Transport in Europe? An Environmental and Economic Sustainability Assessment
Jan 2022
Publication
The use of drop-in capable alternative fuels in aircraft can support the European aviation sector to achieve its goals for sustainable development. They can be a transitional solution in the short and medium term as their use does not require any structural changes to the aircraft powertrain. However the production of alternative fuels is often energy-intensive and some feedstocks are associated with harmful effects on the environment. In addition alternative fuels are often more expensive to produce than fossil kerosene which can make their use unattractive. Therefore this paper analyzes the environmental and economic impacts of four types of alternative fuels compared to fossil kerosene in a well-to-wake perspective. The fuels investigated are sustainable aviation fuels produced by power-to-liquid and biomass-to-liquid pathways. Life cycle assessment and life cycle costing are used as environmental and economic assessment methods. The results of this well-towake analysis reveal that the use of sustainable aviation fuels can reduce the environmental impacts of aircraft operations. However an electricity mix based on renewable energies is needed to achieve significant reductions. In addition from an economic perspective the use of fossil kerosene ranks best among the alternatives. A scenario analysis confirms this result and shows that the production of sustainable aviation fuels using an electricity mix based solely on renewable energy can lead to significant reductions in environmental impact but economic competitiveness remains problematic.
Complex Hydrides for Hydrogen Storage – New Perspectives
Apr 2014
Publication
Since the 1970s hydrogen has been considered as a possible energy carrier for the storage of renewable energy. The main focus has been on addressing the ultimate challenge: developing an environmentally friendly successor for gasoline. This very ambitious goal has not yet been fully reached as discussed in this review but a range of new lightweight hydrogen-containing materials has been discovered with fascinating properties. State-of-the-art and future perspectives for hydrogen-containing solids will be discussed with a focus on metal borohydrides which reveal significant structural flexibility and may have a range of new interesting properties combined with very high hydrogen densities.
Future Heat Series Part 2 - Policy for Heat
Oct 2015
Publication
Policy for Heat: Transforming the System urges Government to implement an ambitious long-term decarbonisation strategy for the heat sector before it’s too late in new inquiry report. The report builds on the work of Part 1 in the Future Heat Series which compared recent decarbonisation pathways and analyses to identify and highlight key policy mechanisms and transitions that are needed in order to decarbonise heat for buildings by 2050. Chaired by Shadow Energy Minister Jonathan Reynolds MP and Conservative MP Rebecca Pow (and also previous MP and member of the Energy and Climate Change Select Committee Dan Byles MP until he stood down at the General Election) the report is written by cross-party think tank group Carbon Connect. The report was published in Parliament at a cross-party debate on Wednesday 14th October. Sponsored by Energy & Utilities Alliance (EUA) and the Institution of Gas Engineers and Managers (IGEM) the report is the second in a cross-party and independent inquiry series.
Prospects of Integrated Photovoltaic‐Fuel Cell Systems in a Hydrogen Economy: A Comprehensive Review
Oct 2021
Publication
Integrated photovoltaic‐fuel cell (IPVFC) systems amongst other integrated energy generation methodologies are renewable and clean energy technologies that have received diverse re‐ search and development attentions over the last few decades due to their potential applications in a hydrogen economy. This article systematically updates the state‐of‐the‐art of IPVFC systems and provides critical insights into the research and development gaps needed to be filled/addressed to advance these systems towards full commercialization. Design methodologies renewable energy‐ based microgrid and off‐grid applications energy management strategies optimizations and the prospects as self‐sustaining power sources were covered. IPVFC systems could play an important role in the upcoming hydrogen economy since they depend on solar hydrogen which has almost zero emissions during operation. Highlighted herein are the advances as well as the technical challenges to be surmounted to realize numerous potential applications of IPVFC systems in unmanned aerial vehicles hybrid electric vehicles agricultural applications telecommunications desalination synthesis of ammonia boats buildings and distributed microgrid applications.
Notes on the Development of the Hydrogen Supplement to IGEM/TD13 > 7 bar
Nov 2021
Publication
IGEM/TD/13 Standard applies to the safe design construction inspection testing operation and maintenance of pressure regulating installations (PRIs) in accordance with current knowledge and operational experience.
This Supplement provides additional requirements for new PRIs to be used for the transmission of Hydrogen including Natural Gas/Hydrogen blended mixtures (subsequently referred to as NG/H blends) and for the repurposing of Natural Gas (NG) PRIs for Hydrogen service.
NG/H blends are considered to be equivalent to 100 mol % Hydrogen with respect to limits on design stresses the potential effect on the material properties and damage and defect categories and acceptance levels unless an additional technical evaluation is carried out to qualify the materials.
NG/H blends containing in excess of 10 mol % Hydrogen are considered to be equivalent to 100 mol.% Hydrogen with respect to all other requirements except for hazardous areas.
This Supplement gives additional recommendations for PRIs and installations:
This Supplement provides additional requirements for new PRIs to be used for the transmission of Hydrogen including Natural Gas/Hydrogen blended mixtures (subsequently referred to as NG/H blends) and for the repurposing of Natural Gas (NG) PRIs for Hydrogen service.
NG/H blends are considered to be equivalent to 100 mol % Hydrogen with respect to limits on design stresses the potential effect on the material properties and damage and defect categories and acceptance levels unless an additional technical evaluation is carried out to qualify the materials.
NG/H blends containing in excess of 10 mol % Hydrogen are considered to be equivalent to 100 mol.% Hydrogen with respect to all other requirements except for hazardous areas.
This Supplement gives additional recommendations for PRIs and installations:
- with an upstream maximum operating pressure (MOP) not greater than 100 bar
- with an outlet pressure greater than or equal to 7 bar
- for use with Hydrogen or NG/H blends with a Hydrogen content greater than 10 %
- operating with a temperature range between -20°C and 120°C.
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