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Hydrogen Infrastructure Project Risks in The Netherlands
Sep 2021
Publication
This study aims to assess the potential risks of setting up a hydrogen infrastructure in the Netherlands. An integrated risk assessment framework capable of analyzing projects identifying risks and comparing projects is used to identify and analyze the main risks in the upcoming Dutch hydrogen infrastructure project. A time multiplier is added to the framework to develop parameters. The impact of the different risk categories provided by the integrated framework is calculated using the discounted cash flow (DCF) model. Despite resource risks having the highest impact scope risks are shown to be the most prominent in the hydrogen infrastructure project. To present the DCF model results a risk assessment matrix is constructed. Compared to the conventional Risk Assessment Matrix (RAM) used to present project risks this matrix presents additional information in terms of the internal rate of return and risk specifics.
Characterization of the Inducible and Slow-Releasing Hydrogen Sulfide and Persulfide Donor P*: Insights into Hydrogen Sulfide Signaling
Jun 2021
Publication
Hydrogen sulfide (H2S) is an important mediator of inflammatory processes. However controversial findings also exist and its underlying molecular mechanisms are largely unknown. Recently the byproducts of H2S per-/polysulfides emerged as biological mediators themselves highlighting the complex chemistry of H2S. In this study we characterized the biological effects of P* a slow-releasing H2S and persulfide donor. To differentiate between H2S and polysulfide-derived effects we decomposed P* into polysulfides. P* was further compared to the commonly used fast-releasing H2S donor sodium hydrogen sulfide (NaHS). The effects on oxidative stress and interleukin-6 (IL-6) expression were assessed in ATDC5 cells using superoxide measurement qPCR ELISA and Western blotting. The findings on IL-6 expression were corroborated in primary chondrocytes from osteoarthritis patients. In ATDC5 cells P* not only induced the expression of the antioxidant enzyme heme oxygenase-1 via per-/polysulfides but also induced activation of Akt and p38 MAPK. NaHS and P* significantly impaired menadione-induced superoxide production. P* reduced IL-6 levels in both ATDC5 cells and primary chondrocytes dependent on H2Srelease. Taken together P* provides a valuable research tool for the investigation of H2S and per-/polysulfide signalling. These data demonstrate the importance of not only H2S but also per-/polysulfides as bioactive signaling molecules with potent anti-inflammatory and in particular antioxidant properties.
Fuel Cell Power Systems for Maritime Applications: Progress and Perspectives
Jan 2021
Publication
Fuel cells as clean power sources are very attractive for the maritime sector which is committed to sustainability and reducing greenhouse gas and atmospheric pollutant emissions from ships. This paper presents a technological review on fuel cell power systems for maritime applications from the past two decades. The available fuels including hydrogen ammonia renewable methane and methanol for fuel cells under the context of sustainable maritime transportation and their pre-processing technologies are analyzed. Proton exchange membrane molten carbonate and solid oxide fuel cells are found to be the most promising options for maritime applications once energy efficiency power capacity and sensitivity to fuel impurities are considered. The types layouts and characteristics of fuel cell modules are summarized based on the existing applications in particular industrial or residential sectors. The various research and demonstration projects of fuel cell power systems in the maritime industry are reviewed and the challenges with regard to power capacity safety reliability durability operability and costs are analyzed. Currently power capacity costs and lifetime of the fuel cell stack are the primary barriers. Coupling with batteries modularization mass production and optimized operating and control strategies are all important pathways to improve the performance of fuel cell power systems.
Review of the Durability of Polymer Electrolyte Membrane Fuel Cell in Long-Term Operation: Main Influencing Parameters and Testing Protocols
Jul 2021
Publication
Durability is the most pressing issue preventing the efficient commercialization of polymer electrolyte membrane fuel cell (PEMFC) stationary and transportation applications. A big barrier to overcoming the durability limitations is gaining a better understanding of failure modes for user profiles. In addition durability test protocols for determining the lifetime of PEMFCs are important factors in the development of the technology. These methods are designed to gather enough data about the cell/stack to understand its efficiency and durability without causing it to fail. They also provide some indication of the cell/stack’s age in terms of changes in performance over time. Based on a study of the literature the fundamental factors influencing PEMFC long-term durability and the durability test protocols for both PEMFC stationary and transportation applications were discussed and outlined in depth in this review. This brief analysis should provide engineers and researchers with a fast overview as well as a useful toolbox for investigating PEMFC durability issues.
Hy4Heat Safety Assessment: Conclusions Report (Incorporating Quantitative Risk Assessment) - Work Package 7
May 2021
Publication
The Hy4Heat Safety Assessment has focused on assessing the safe use of hydrogen gas in certain types of domestic properties and buildings. The summary reports (the Precis and the Safety Assessment Conclusions Report) bring together all the findings of the work and should be looked to for context by all readers. The technical reports should be read in conjunction with the summary reports. While the summary reports are made as accessible as possible for general readers the technical reports may be most accessible for readers with a degree of technical subject matter understanding. All of the safety assessment reports have now been reviewed by the HSE.<br/><br/>A comparative risk assessment of natural gas versus hydrogen gas including a quantitative risk assessment; and identification of control measures to reduce risk and manage hydrogen gas safety for a community demonstration.
Computational Intelligence Approach for Modeling Hydrogen Production: A Review
Mar 2018
Publication
Hydrogen is a clean energy source with a relatively low pollution footprint. However hydrogen does not exist in nature as a separate element but only in compound forms. Hydrogen is produced through a process that dissociates it from its compounds. Several methods are used for hydrogen production which first of all differ in the energy used in this process. Investigating the viability and exact applicability of a method in a specific context requires accurate knowledge of the parameters involved in the method and the interaction between these parameters. This can be done using top-down models relying on complex mathematically driven equations. However with the raise of computational intelligence (CI) and machine learning techniques researchers in hydrology have increasingly been using these methods for this complex task and report promising results. The contribution of this study is to investigate the state of the art CI methods employed in hydrogen production and to identify the CI method(s) that perform better in the prediction assessment and optimization tasks related to different types of Hydrogen production methods. The resulting analysis provides in-depth insight into the different hydrogen production methods modeling technique and the obtained results from various scenarios integrating them within the framework of a common discussion and evaluation paper. The identified methods were benchmarked by a qualitative analysis of the accuracy of CI in modeling hydrogen production providing extensive overview of its usage to empower renewable energy utilization.
Exergetic Sustainability Comparison of Turquoise Hydrogen Conversion to Low-carbon Fuels
Nov 2022
Publication
Turquoise hydrogen is produced from methane cracking a cleaner alternative to steam methane reforming. This study looks at two proposed systems based on solar methane cracking for low-carbon fuel production. The systems utilize different pathways to convert the hydrogen into a suitable form for transportation and utilize the carbon solid by-product. A direct carbon fuel cell is integrated to utilize the carbon and capture the CO2 emissions. The CO2 generated is utilized for fuel production using CO2 hydrogenation or co-electrolysis. An advanced exergetic analysis is conducted on these systems using Aspen plus simulations of the process. The exergetic efficiency waste exergy ratio exergy destruction ratio exergy recoverability ratio environmental effect factor and the exergetic sustainability index were determined for each system and the subsystems. Solar methane cracking was found to have an environmental effect factor of 0.08 and an exergetic sustainability index of 12.27.
Modelling of Boil‐Off and Sloshing Relevant to Future Liquid Hydrogen Carriers
Mar 2022
Publication
This study presents an approach for estimating fuel boil‐off behaviour in cryogenic energy carrier ships such as future liquid hydrogen (LH2) carriers. By relying on thermodynamic model‐ ling and empirical formulas for ship motion and propulsion the approach can be used to investigate boil‐off as a function of tank properties weather conditions and operating velocities during a laden voyage. The model is first calibrated against data from a liquefied natural gas (LNG) carrier and is consequently used to investigate various design configurations of an LH2 ship. Results indicate that an LH2 ship with the same tank volume and glass wool insulation thickness as a conventional LNG carrier stores 40% of the fuel energy and is characterised by a boil‐off rate nine times higher and twice as sensitive to sloshing. Adding a reliquefaction unit can reduce the LH2 fuel depletion rate by at least 38.7% but can increase its variability regarding velocity and weather conditions. In calm weather LH2 boil‐off rates can only meet LNG carrier standards by utilising at least 6.6 times the insulation thickness. By adopting fuel cell propulsion in an LH2 ship a 1.1% increase in fuel delivery is expected. An LH2 ship with fuel cells and reliquefaction is required to be at least 1.7 times larger than an existing LNG carrierto deliverthe same energy. Further comparison of alternative scenarios indicates that LH2 carriers necessitate significant redesigns if LNG carrier standards are desired. The present approach can assist future feasibility studies featuring other vessels and propulsion technologies and can be seen as an extendable framework that can predict boil‐off in real‐time.
Preliminary Analysis of Compression System Integrated Heat Management Concepts Using LH2-Based Parametric Gas Turbine Model
Apr 2021
Publication
The investigation of the various heat management concepts using LH2 requires the development of a modeling environment coupling the cryogenic hydrogen fuel system with turbofan performance. This paper presents a numerical framework to model hydrogen-fueled gas turbine engines with a dedicated heat-management system complemented by an introductory analysis of the impact of using LH2 to precool and intercool in the compression system. The propulsion installations comprise Brayton cycle-based turbofans and first assessments are made on how to use the hydrogen as a heat sink integrated into the compression system. Conceptual tubular compact heat exchanger designs are explored to either precool or intercool the compression system and preheat the fuel to improve the installed performance of the propulsion cycles. The precooler and the intercooler show up to 0.3% improved specific fuel consumption for heat exchanger effectiveness in the range 0.5–0.6 but higher effectiveness designs incur disproportionately higher pressure losses that cancel-out the benefits.
Uncertainty of Acceleration of a Premixed Laminar Unstable Hydrogen Flame
Sep 2021
Publication
Unstable hydrogen-air flame behavior randomities are important for industrial safety hydrogen infrastructure safety and nuclear power plant hydrogen safety problems. The paper is devoted to an experimental and theoretical study of the uncertainty in the acceleration of a premixed laminar unstable hydrogen flame. The results of experiments on spherical flame propagation in hydrogen-air mixtures with a hydrogen content of 10 to 60% are presented. The experiments were repeated up to 30 times in the same mixtures. A statistical analysis of the experimental results has been carried out. The scatter of the experimental data depending on the hydrogen content in the mixture was estimated. It was found to be between 8 to 17% for different mixtures with the same flame radius and mixture composition. Similar results were obtained using the numerical integration of the Sivashinsky equation of flame propagation.
Hydrogen Component Leak Rate Quantification for System Risk and Reliability Assessment through QRA and PHM Frameworks
Sep 2021
Publication
The National Renewable Energy Laboratory’s (NREL) Hydrogen Safety Research and Development (HSR&D) program in collaboration with the University of Maryland’s Systems Risk and Reliability Analysis Laboratory (SyRRA) are working to improve reliability and reduce risk in hydrogen systems. This approach strives to use quantitative data on component leaks and failures together with Prognosis and Health Management (PHM) and Quantitative Risk Assessment (QRA) to identify atrisk components reduce component failures and downtime and predict when components require maintenance. Hydrogen component failures increase facility maintenance cost facility downtime and reduce public acceptance of hydrogen technologies ultimately increasing facility size and cost because of conservative design requirements. Leaks are a predominant failure mode for hydrogen components. However uncertainties in the amount of hydrogen emitted from leaking components and the frequency of those failure events limit the understanding of the risks that they present under real-world operational conditions. NREL has deployed a test fixture the Leak Rate Quantification Apparatus (LRQA) to quantify the mass flow rate of leaking gases from medium and high-pressure components that have failed while in service. Quantitative hydrogen leak rate data from this system could ultimately be used to better inform risk assessment and Regulation Codes and Standards (RCS). Parallel activity explores the use of PHM and QRA techniques to assess and reduce risk thereby improving safety and reliability of hydrogen systems. The results of QRAs could further provide a systematic and science-based foundation for the design and implementation of RCS as in the latest versions of the NFPA 2 code for gaseous hydrogen stations. Alternatively data-driven techniques of PHM could provide new damage diagnosis and health-state prognosis tools. This research will help end users station owners and operators and regulatory bodies move towards risk-informed preventative maintenance versus emergency corrective maintenance reducing cost and improving reliability. Predictive modelling of failures could improve safety and affect RCS requirements such as setback distances at liquid hydrogen fueling sites. The combination of leak rate quantification research PHM and QRA can lead to better informed models enabling data-based decision to be made for hydrogen system safety improvements.
French Guide to Conformity Assessment and Certification of Hydrogen Systems
Sep 2021
Publication
Hydrogen as energy carrier is referenced in French and European political strategies to realize the transition to low-carbon energy. In 2020 in France the government was launching a major investment plan amounting to 7.2 billion euros until 2030 to support the deployment of large-scale hydrogen technologies [1]. The implementation of this strategy should lead to the arrival of several new hydrogen systems that will need to be evaluated and certified regarding their compliance with safety requirements before being commercialized. Conformity assessment and certification play an important role to achieve a good safety level on the EU market for the protection of workers and consumers. It is a way for the manufacturer to prove that hazards have been identified and risks are managed and to demonstrate his commitment to safety that are key to access to the EU market. To assist manufacturers in identifying the applicable regulations standards and procedures for putting their product on the market Ineris elaborated a guidebook [2] with financial and technical support by ADEME the French Agency for Ecological Transition and France Hydrogen the French Association for Hydrogen and Fuel Cells. The preparation of this document also led to identifying gaps in the Regulations Codes and Standards (RCS) framework and necessary resources for the implementation of the conformity assessment procedures. This paper first describes the main regulatory procedures applicable for various types of hydrogen systems. Then describes the role of the actors involved in this process with a special focus on the French context. And finally focuses on some of the gaps that were identified and formulates suggestions to address them.
A Preliminary Study on an Alternative Ship Propulsion System Fueled by Ammonia: Environmental and Economic Assessments
Mar 2020
Publication
The shipping industry is becoming increasingly aware of its environmental responsibilities in the long-term. In 2018 the International Maritime Organization (IMO) pledged to reduce greenhouse gas (GHG) emissions by at least 50% by the year 2050 as compared with a baseline value from 2008. Ammonia has been regarded as one of the potential carbon-free fuels for ships based on these environmental issues. In this paper we propose four propulsion systems for a 2500 Twenty-foot Equivalent Unit (TEU) container feeder ship. All of the proposed systems are fueled by ammonia; however different power systems are used: main engine generators polymer electrolyte membrane fuel cell (PEMFC) and solid oxide fuel cell (SOFC). Further these systems are compared to the conventional main engine propulsion system that is fueled by heavy fuel oil with a focus on the economic and environmental perspectives. By comparing the conventional and proposed systems it is shown that ammonia can be a carbon-free fuel for ships. Moreover among the proposed systems the SOFC power system is the most eco-friendly alternative (up to 92.1%) even though it requires a high lifecycle cost than the others. Although this study has some limitations and assumptions the results indicate a meaningful approach toward solving GHG problems in the maritime industry.
Multi-vector Energy Management System including Scheduling Electrolyser, Electric Vehicle Charging Station and Other Assets in a Real Scenario
Oct 2022
Publication
Today in the field of energy the main goal is to reduce emissions with 7 the aim of maintaining a clean environment. To reduce energy consumption 8 from fossil fuels new tools for micro-grids have been proposed. In the context 9 of multi-vector energy management systems the present work proposes an 10 optimal scheduler based on genetic algorithms to manage flexible assets in the 11 energy system such as energy storage and manageable demand. This tool is 12 applied to a case study for a Spanish technology park (360 kW consumption 13 peak) with photovoltaic and wind generation (735 kW generation peak) 14 hydrogen production (15 kW) and electric and fuel cell charging stations. 15 It provides an hourly day-ahead scheduling for the existing flexible assets: 16 the electrolyser the electric vehicle charging station the hydrogen refuelling 17 station and the heating ventilation and air conditioning system in one 18 building of the park. 19 A set of experiments is carried out over a period of 14 days using real 20 data and performing computations in real time in order to test and validate 21 the tool. The analysis of results show that the solution maximises the use of 22 local renewable energy production (demand is shifted to those hours when 23 there is a surplus of generation) which means a reduction in energy costs 24 whereas the computational cost allows the implementation of the tool in real 25 time.
Polymer Electrolyte Membrane Electrolyzer and Fuel Cell System Characterization for Power System Frequency Control
Mar 2022
Publication
This work focuses on tests for control reserve of a novel Power-to-Gas-to-Power platform based on proton exchange membrane technologies and on pure oxygen instead of air in the re-electrification process. The technologies are intended as a further option to stabilize the power system therefore helping integrating renewable energy into the power system. The tests are based on the pre-qualification tests used by Swissgrid but are not identical in order to capture the maximum dynamics by the plants. The main characteristics identified are the ramping capabilities of ±8% per unit per second for the electrolyzer system and ±33% per unit per second for the fuel cell system. The ramping capabilities are mainly limited by the underlying processes of polymer electrolyte membrane technologies. Additionally the current and projected round-trip efficiencies for Power-to-Gas-to-Power of 39% in 2025 and 48% in 2040 are derived. Furthermore during the successful tests the usage of oxygen in the present Power-to-Gas and Gas-to-Power processes and its influence on the dynamics and the round-trip efficiency was assessed. In consequence fundamental data on the efficiency and the dynamics of the Power-to-Gas-to-Power technologies is presented. This data can serve as basis for prospective assessments on the suitability of the technologies investigated for frequency control in power systems.
Methodologies for Representing the Road Transport Sector in Energy System Models
Dec 2013
Publication
Energy system models are often used to assess the potential role of hydrogen and electric powertrains for reducing transport CO2 emissions in the future. In this paper we review how different energy system models have represented both vehicles and fuel infrastructure in the past and we provide guidelines for their representation in the future. In particular we identify three key modelling decisions: the degree of car market segmentation the imposition of market share constraints and the use of lumpy investments to represent infrastructure. We examine each of these decisions in a case study using the UK MARKAL model. While disaggregating the car market principally affects only the transition rate to the optimum mix of technologies market share constraints can greatly change the optimum mix so should be chosen carefully. In contrast modelling infrastructure using lumpy investments has little impact on the model results. We identify the development of new methodologies to represent the impact of behavioural change on transport demand as a key challenge for improving energy system models in the future.
Climate Change Committee: Progress in Reducing Emissions, 2022 Report to Parliament
Jun 2022
Publication
This statutory report provides a comprehensive overview of the UK Government’s progress to date in reducing emissions. It is accompanied by a new Monitoring Framework which details the CCC’s updated approach to tracking real-world progress through a host of new indicators.<br/>This is a pivotal point in the UK’s journey to Net Zero. The UK is one of the few countries with emissions targets in line with the long-term temperature goal of the Paris Agreement. Policy ambition has moved substantially with the publication of the UK’s Net Zero Strategy. Now is the time to deliver the promised action.
Decarbonizing Primary Steel Production : Techno-economic Assessment of a Hydrogen Based Green Steel Production Plant in Norway
Mar 2022
Publication
High electricity cost is the biggest challenge faced by the steel industry in transitioning to hydrogen based steelmaking. A steel plant in Norway could have access to cheap emission free electricity high-quality iron ore skilled manpower and the European market. An open-source model for conducting techno-economic assessment of a hydrogen based steel manufacturing plant operating in Norway has been developed in this work. Levelized cost of production (LCOP) for two plant configurations; one procuring electricity at a fixed price and the other procuring electricity from the day-ahead electricity markets with different electrolyzer capacity were analyzed. LCOP varied from $622/tls to $722/tls for the different plant configurations. Procuring electricity from the day-ahead electricity markets could reduce the LCOP by 15%. Increasing the electrolyzer capacity reduced the operational costs but increased the capital investments reducing the overall advantage. Sensitivity analysis revealed that electricity price and iron ore price are the major contributors to uncertainty for configurations with fixed electricity prices. For configurations with higher electrolyzer capacity changes in the iron ore price and parameters related to capital investment were found to affect the LCOP significantly.
Conversion of the UK Gas System to Transport Hydrogen
May 2013
Publication
One option to decarbonise residential heat in the UK is to convert the existing natural gas networks to deliver hydrogen. We review the technical feasibility of this option using semistructured interviews underpinned by a literature review and we assess the potential economic benefits using the UK MARKAL energy systems model. We conclude that hydrogen can be transported safely in the low-pressure pipes but we identify concerns over the reduced capacity of the system and the much lower linepack storage compared to natural gas. New hydrogen meters and sensors would have to be fitted to every building in a hydrogen conversion program and appliances would have to be converted unless the government was to legislate to make them hydrogen-ready in advance. Converting the gas networks to hydrogen is a lower-cost residential decarbonisation pathway for the UK than those identified previously. The cost-optimal share of hydrogen is sensitive to the conversion cost and to variations in the capital costs of heat pumps and micro-CHP fuel cells. With such small cost differentials between technologies the decision to convert the networks will also depend on non-economic factors including the relative performance of technologies and the willingness of the government to organise a conversion program.
Thermodynamic and Technical Issues of Hydrogen and Methane-Hydrogen Mixtures Pipeline Transmission
Feb 2019
Publication
The use of hydrogen as a non-emission energy carrier is important for the innovative development of the power-generation industry. Transmission pipelines are the most efficient and economic method of transporting large quantities of hydrogen in a number of variants. A comprehensive hydraulic analysis of hydrogen transmission at a mass flow rate of 0.3 to 3.0 kg/s (volume flow rates from 12000 Nm3/h to 120000 Nm3/h) was performed. The methodology was based on flow simulation in a pipeline for assumed boundary conditions as well as modeling of fluid thermodynamic parameters for pure hydrogen and its mixtures with methane. The assumed outlet pressure was 24 bar (g). The pipeline diameter and required inlet pressure were calculated for these parameters. The change in temperature was analyzed as a function of the pipeline length for a given real heat transfer model; the assumed temperatures were 5 and 25 ◦C. The impact of hydrogen on natural gas transmission is another important issue. The performed analysis revealed that the maximum participation of hydrogen in natural gas should not exceed 15%–20% or it has a negative impact on natural gas quality. In the case of a mixture of 85% methane and 15% hydrogen the required outlet pressure is 10% lower than for pure methane. The obtained results present various possibilities of pipeline transmission of hydrogen at large distances. Moreover the changes in basic thermodynamic parameters have been presented as a function of pipeline length for the adopted assumptions.
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