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Enhancing Waste-to-Energy and Hydrogen Production through Urban–Industrial Symbiosis: A Multi-Objective Optimisation Model Incorporating a Bayesian Best-Worst Method
Feb 2024
Publication
A surging demand for sustainable energy and the urgency to lower greenhouse gas emissions is driving industrial systems towards more eco-friendly and cost-effective models. Biogas from agricultural and municipal organic waste is gaining momentum as a renewable energy source. Concurrently the European Hydrogen Strategy focuses on green hydrogen for decarbonising the industrial and transportation sectors. This paper presents a multi-objective network design model for urban–industrial symbiosis incorporating anaerobic digestion cogeneration photovoltaic and hydrogen production technologies. Additionally a Bayesian best-worst method is used to evaluate the weights of the sustainability aspects by decision-makers integrating these into the mathematical model. The model optimises industrial plant locations considering economic environmental and social parameters including the net present value energy consumption and carbon footprint. The model’s functionalities are demonstrated through a real-world case study based in Emilia Romagna Italy. It is subject to sensitivity analysis to evaluate how changes in the inputs affect the outcomes and highlights feasible trade-offs through the exploration of the ϵ-constraint. The findings demonstrate that the model substantially boosts energy and hydrogen production. It is not only economically viable but also reduces the carbon footprint associated with fossil fuels and landfilling. Additionally it contributes to job creation. This research has significant implications with potential future studies intended to focus on system resilience plant location optimisation and sustainability assessment.
Liquid Hydrogen Pool Evaporation Above Four Different Substrates
Sep 2023
Publication
In the frame of the EC-funded project PRESLHY ten experiments on LH2-pool evaporation above four different substrates have been performed with the POOL-facility on a free field test site. Substrates to be investigated comprised concrete sand water and gravel. Four of the experiments were made with artificial side wind of known direction and known velocity to investigate the influence of side wind on hydrogen evaporation and cloud formation above the LH2-pool. The POOL-facility mainly consists of an insulated stainless-steel box with the dimensions 0.5 x 0.5 x 0.2 m³ that is filled up to half the height (0.1 m) with the respective substrate and LH2. The height of the LH2-pool that forms above the substrate can be determined using the weight of the complete facility which is positioned on a scale. Additionally six thermocouples are located in different heights above the substrate surface to indicate the LH2-level as soon as they are covered with LH2. Further measurement equipment used in the tests comprises temperature measurements inside the substrate and several thermocouples in the unconfined space above the pool where also H2-concentration measurements were performed. Using the sensor information pool evaporation rates for the different substrates were determined. The temperature and concentration measurements above the pool were mainly used to define promising ignition positions for subsequent combustion experiments in which the LH2-spills above the different substrates were ignited.
Look-ahead Scheduling of Energy-Water Nexus Integrated with Power2X Conversion Technologies under Multiple Uncertainties
Aug 2023
Publication
Co-optimizing energy and water resources in a microgrid can increase efficiency and improve economic performance. Energy-water storage (EWS) devices are crucial components of a high-efficient energy-water microgrid (EWMG). The state of charge (SoC) at the end of the first day of operation is one of the most significant variables in EWS devices since it is used as a parameter to indicate the starting SoC for the second day which influences the operating cost for the second day. Hence this paper examines the benefits and applicability of a lookahead optimization strategy for an EWMG integrated with multi-type energy conversion technologies and multienergy demand response to supply various energy-water demands related to electric/hydrogen vehicles and commercial/residential buildings with the lowest cost for two consecutive days. In addition a hybrid info-gap/robust optimization technique is applied to cover uncertainties in photovoltaic power and electricity prices as a tri-level optimization framework without generating scenarios and using the probability distribution functions. Duality theory is also used to convert the problem into a single-level MILP so that it can be solved by CPLEX. According to the findings the implemented energy-water storage systems and look-ahead strategy accounted for respectively 4.03% and 0.43% reduction in the total cost.
Multi-Objective Robust Optimization of Integrated Energy System with Hydrogen Energy Storage
Feb 2024
Publication
A novel multi-objective robust optimization model of an integrated energy system with hydrogen storage (HIES) considering source–load uncertainty is proposed to promote the low-carbon economy operation of the integrated energy system of a park. Firstly the lowest total system cost and carbon emissions are selected as the multi-objective optimization functions. The Pareto front solution set of the objective function is applied by compromise planning and the optimal solution among them is obtained by the maximum–minimum fuzzy method. Furthermore the robust optimization (RO) approach is introduced to cope with the source–load uncertainty effectively. Finally it is demonstrated that the illustrated HIES can significantly reduce the total system cost carbon emissions and abandoned wind and solar power. Meanwhile the effectiveness of the proposed model and solution method is verified by analyzing the influence of multi-objective solutions and a robust coefficient on the Chongli Demonstration Project in Hebei Province.
Deep Learning for Wind and Solar Energy Forecasting in Hydrogen Production
Feb 2024
Publication
This research delineates a pivotal advancement in the domain of sustainable energy systems with a focused emphasis on the integration of renewable energy sources—predominantly wind and solar power—into the hydrogen production paradigm. At the core of this scientific endeavor is the formulation and implementation of a deep-learning-based framework for short-term localized weather forecasting specifically designed to enhance the efficiency of hydrogen production derived from renewable energy sources. The study presents a comprehensive evaluation of the efficacy of fully connected neural networks (FCNs) and convolutional neural networks (CNNs) within the realm of deep learning aimed at refining the accuracy of renewable energy forecasts. These methodologies have demonstrated remarkable proficiency in navigating the inherent complexities and variabilities associated with renewable energy systems thereby significantly improving the reliability and precision of predictions pertaining to energy output. The cornerstone of this investigation is the deployment of an artificial intelligence (AI)-driven weather forecasting system which meticulously analyzes data procured from 25 distinct weather monitoring stations across Latvia. This system is specifically tailored to deliver short-term (1 h ahead) forecasts employing a comprehensive sensor fusion approach to accurately predicting wind and solar power outputs. A major finding of this research is the achievement of a mean squared error (MSE) of 1.36 in the forecasting model underscoring the potential of this approach in optimizing renewable energy utilization for hydrogen production. Furthermore the paper elucidates the construction of the forecasting model revealing that the integration of sensor fusion significantly enhances the model’s predictive capabilities by leveraging data from multiple sources to generate a more accurate and robust forecast. The entire codebase developed during this research endeavor has been made available on an open access GIT server.
A Review of Gas Phase Inhibition of Gaseous Hydrogen Embrittlement in Pipeline Steels
Feb 2024
Publication
The addition of small amounts of certain gases such as O2 CO and SO2 may mitigate hydrogen embrittlement in high-pressure gas transmission pipelines that transport hydrogen. To practically implement such inhibition in gas transmission pipelines a comprehensive understanding and quantification of this effect are essential. This review examines the impact of various added gases to hydrogen including typical odorants on gaseous hydrogen embrittlement of steels and evaluates their inhibition effectiveness. O2 CO and SO2 were found to be effective inhibitors of hydrogen embrittlement. Yet the results in the literature have not always been consistent partly because of the diverse range of mechanical tests and their parameters. The absence of systematic studies hinders the evaluation of the feasibility of using gas phase inhibitors for controlling gaseous hydrogen embrittlement. A method to quantify the effectiveness of gas phase inhibition is proposed using gas phase permeation studies.
Real-Time Energy Management Strategy of Hydrogen Fuel Cell Hybrid Electric Vehicles Based on Power Following Strategy–Fuzzy Logic Control Strategy Hybrid Control
Nov 2023
Publication
Fuel cell hybrid electric vehicles have the advantages of zero emission high efficiency and fast refuelling etc. and are one of the key directions for vehicle development. The energy management problem of fuel cell hybrid electric vehicles is the key technology for power distribution. The traditional power following strategy has the advantage of a real-time operation but the power correction is usually based only on the state of charge of a lithium battery which causes the operating point of the fuel cell to be in the region of a low efficiency. To solve this problem this paper proposes a hybrid power-following-fuzzy control strategy where a fuzzy logic control strategy is used to optimise the correction module based on the power following strategy which regulates the state of charge while correcting the output power of the fuel cell towards the efficient operating point. The results of the joint simulation with Matlab + Advisor under the Globally Harmonised Light Vehicle Test Cycle Conditions show that the proposed strategy still ensures the advantages of real-time energy management and for the hydrogen fuel cell the hydrogen consumption is reduced by 13.5% and 4.1% compared with the power following strategy and the fuzzy logic control strategy and the average output power variability is reduced by 14.6% and 5.1% respectively which is important for improving the economy of the whole vehicle and prolonging the lifetime of fuel cell.
Calculating the Fundamental Parameters to Assess the Explosion Risk Due to Crossover in Electrolysers
Sep 2023
Publication
With the predicted high demand of hydrogen projected to support the neutral carbon society transition in the coming years the production of hydrogen is set to increase alongside the demand. As electrolysis is set to be amongst the main solutions for green hydrogen production ensuring the safety of electrolysers during operation will become a central concern. This is mainly due to the crossover risk (hydrogen into oxygen or the other way around) in the separators as throughout the years several cases of incidents have been reported. This study aims to evaluate the methodologies for calculating H2/O2 detonation cell size and laminar flame velocity using detailed kinetic mechanisms at the operating conditions of electrolysers (up to 35 bar and 360 K). Therefore the modeling of H2/O2 and H2/Air shock tube delay times and laminar flame speeds at initial different pressures and temperature based on the GRI mech 3.0 [1] Mevel et al.[2] Li et al.[3] Lutz et al. [4] and Burke et al. [5] kinetic mechanisms were performed and compared with the available experimental data in the literature. In each case a best candidate mechanism was then chosen to build a database for the detonation cell size then for the laminar flame speeds up to the operating conditions of electrolysers (293-360K and 1-35 bar).
A Review on the Research Progress and Application of Compressed Hydrogen in the Marine Hydrogen Fuel Cell Power System
Jan 2024
Publication
The urgency to mitigate greenhouse gas emissions from maritime vessels has intensified due to the increasingly stringent directives set forth by the International Maritime Organization (IMO). These directives specifically address energy efficiency enhancements and emissions reduction within the shipping industry. In this context hydrogen is the much sought after fuel for all the global economies and its applications for transportation and propulsion in particular is crucial for cutting down carbon emissions. Nevertheless the realization of hydrogen-powered vessels is confronted by substantial technical hurdles that necessitate thorough examination. This study undertakes a comprehensive analysis encompassing diverse facets including distinct variations of hydrogen fuel cells hydrogen internal combustion engines safety protocols associated with energy storage as well as the array of policies and commercialization endeavors undertaken globally for the advancement of hydrogen-propelled ships. By amalgamating insights from these multifaceted dimensions this paper adeptly encapsulates the myriad challenges intrinsic to the evolution of hydrogen-fueled maritime vessels while concurrently casting a forward-looking gaze on their prospective trajectory.
Modelling of Hydrogen Dispersion with Effects
Sep 2023
Publication
The paper shows the latest developments of Gexcon’s consequence modelling software EFFECTS with validation based on hydrogen experimental data for different storage conditions and scenarios including liquid hydrogen two-phase jet releases. The effect of atmospheric turbulence on the dispersion and potential worst-case scenarios of hydrogen which are very different from heavy gas releases are discussed. Beside validation for gaseous hydrogen releases a validation study for pressurised liquid hydrogen jet releases including a sensitivity analysis is performed and the results are compared with experimental data.
Comparative Life Cycle Greenhouse Gas Analysis of Clean Hydrogen Pathways: Assessing Domestic Production and Overseas Import in South Korea
Sep 2023
Publication
The development of a Clean Hydrogen Standard based on life-cycle greenhouse gas (GHG) emissions is gaining prominence on the international agenda. Thus a framework for assessing life-cycle GHG emissions for clean hydrogen pathways is necessary. In this study the comprehensive datasets and effects of various scenarios encompassing hydrogen production carriers (liquid hydrogen ammonia methylcyclohexane) carbon capture and storage (CCS) target analysis year (2021 2030) to reflect trends of greening grid electricity and potential import countries on aggregated life-cycle GHG emissions were presented. South Korea was chosen as a case study region and the low-carbon alternatives were suggested for reducing aggregated emissions to meet the Korean standard (5 kgCO2e/kgH2). First capturing and storing nearly entire (>90%) CO2 from fossil- and waste-based production pathways is deemed essential. Second when repurposing the use of hydrogen that was otherwise used internally applying a penalty for substitution is appropriate leading to results notably exceeding the standard. Third for electrolysis-based hydrogen using renewable or nuclear electricity is essential. Lastly when hydrogen is imported in a well-to-point-of-delivery (WtP) perspective using renewable electricity during hydrogen conversion into a carrier and reusing the produced hydrogen for endothermic reconversion reaction are recommended. By implementing the developed calculation framework to other countries' cases it was observed that importing hydrogen to regions having scope of WtP or above (e.g. well-to-wheel) might not meet the threshold due to additional emissions from importation processes. Additionally for hydrogen carriers undergoing the endothermic reconversion the approach to reduce WtP emissions (reusing produced hydrogen) may conflict with the approach to reduce well-to-gate (WtG) emission (using external fossilbased fuel). The discrepancy highlights the need to set a broader scope of emissions assessment to effectively promote the life-cycle emission reduction efforts of hydrogen importers. This study contributes to the field of clean hydrogen GHG emission assessment offering a robust database and calculation framework while addressing the effects of greening grid electricity and CCS implementation proposing low-carbon alternatives and GHG assessment scope to achieve global GHG reduction.
Green Hydrogen Credit Subsidized Renewable Energy-hydrogen Business Models for Achieving the Carbon Netural Future
Feb 2024
Publication
The global resurgence of hydrogen as a clean energy source particularly green hydrogen derived from renewable energy is pivotal for achieving a carbon-neutral future. However scalability poses a significant challenge. This research proposes innovative business models leveraging the low-emission property of green hydrogen to reduce its financial costs thereby fostering its widespread adoption. Key components of the business workflow are elaborated mathematical formulations of market parameters are derived and case studies are presented to demonstrate the feasibility and efficiency of these models. Results demonstrate that the substantial costs associated with the current hydrogen industry can be effectively subsidized via the implementation of proposed business models. When the carbon emission price falls within the range of approximately 86–105 USD/ton free access to hydrogen becomes a viable option for end-users. This highlights the significance and promising potential of the proposed business models within the green hydrogen credit framework.
Modelling the Non-adiabatic Blowdown of Pressurised Cryogenic Hydrogen Storage Tank
Sep 2023
Publication
This paper describes a model of hydrogen blowdown dynamics for storage tanks needed for hydrogen safety engineering to accurately represent incident scenarios. Heat transfer through a tank wall affects the temperature and pressure dynamics inside the storage vessel and therefore the characteristics of the resulting hydrogen jet in case of loss of containment. Available non-adiabatic blowdown models are validated only against experiments on hydrogen storages at ambient temperature. Effect of heat transfer for cryo-compressed hydrogen can be more significant due to a larger temperature difference between the stored hydrogen and surrounding atmosphere especially in case of failure of equipment insulation. Previous work by the authors demonstrated that the heat transfer through a discharge pipe wall can significantly affect the mass flow rate of cryogenic hydrogen releases. To the authors’ knowledge thoroughly validated models of non-adiabatic blowdown dynamics for cryo-compressed hydrogen are currently missing. The present work further develops the non-adiabatic blowdown model at ambient temperature using the under-expanded jet theory developed at Ulster University to expand it to cryo-compressed hydrogen storages. The non-ideal behaviour of cryo-compressed hydrogen is accounted through the high-accuracy Helmholtz energy formulations. The developed model includes effect of heat transfer at both the tank and discharge pipe wall. The model is thoroughly validated against sixteen tests performed by Pro-Science on blowdown of hydrogen storage tanks with initial pressure 0.5-20 MPa and temperature 80-310 K through release nozzle of diameter 0.5-4.0 mm. The model well reproduces the experimental pressure and temperature dynamics during the entire blowdown duration.
Energy Sustainability: A Pragmatic Approach and Illustrations
Mar 2009
Publication
Many factors to be appropriately addressed in moving towards energy sustainability are examined. These include harnessing sustainable energy sources utilizing sustainable energy carriers increasing efficiency reducing environmental impact and improving socioeconomic acceptability. The latter factor includes community involvement and social acceptability economic affordability and equity lifestyles land use and aesthetics. Numerous illustrations demonstrate measures consistent with the approach put forward and options for energy sustainability and the broader objective of sustainability. Energy sustainability is of great importance to overall sustainability given the pervasiveness of energy use its importance in economic development and living standards and its impact on the environment.
Overview of International Activities in Hydrogen System Safety in IEA Hydrogen TCP Task 43
Sep 2023
Publication
Safety and reliability have long been recognized as key issues for the development commercialization and implementation of new technologies and infrastructure and hydrogen systems are no exception to this rule. Reliability engineering quantitative risk assessment (QRA) and knowledge exchange each play a key role in proactive addressing safety – before problems happen – and help us learn from problems if they happen. Many international research activities are focusing on both reliability and risk assessment for hydrogen systems. However the element of knowledge exchange is sometimes less visible. To support international collaboration and knowledge exchange the International Energy Agency (IEA) convened a new Technology Collaboration Program “Task 43: Safety and Regulatory Aspects of Emerging Large Scale Hydrogen Energy Applications” started in June 2022. Within Task 43 Subtask E focuses on Hydrogen Systems Safety. This paper discusses the structure of the Hydrogen Systems Safety subtask and the aligned activities and introduces opportunities for future work.
IEA TCP Task 43 - Subtask Safety Distances: State of the Art
Sep 2023
Publication
The large deployment of hydrogen technologies for new applications such as heat power mobility and other emerging industrial utilizations is essential to meet targets for CO2 reduction. This will lead to an increase in the number of hydrogen installations nearby local populations that will handle hydrogen technologies. Local regulations differ and provide different safety and/or separation distances in different geographies. The purpose of this work is to give an insight on different methodologies and recommendations developed for hydrogen (mainly) risk management and consequences assessment of accidental scenarios. The first objective is to review available methodologies and to identify the divergent points on the methodology. For this purpose a survey has been launched to obtain the needed inputs from the subtask participants. The current work presents the outcomes of this survey highlighting the gaps and suggesting the prioritization of the actions to take to bridge these gaps.
QRA of Hydrogen Vehicles in a Road Tunnel
Sep 2023
Publication
Hydrogen energy is recognized by many European governments as an important part of the development to achieve a more sustainable energy infrastructure. Great efforts are spent to build up a hydrogen supply chain to support the increasing number of hydrogen-powered vehicles. Naturally these vehicles will use the common traffic infrastructure. Thus it has to be ensured these infrastructures are capable to withstand the hazards and associated risks that may arise from these new technologies. In order to have an appropriate assessment tool for hydrogen vehicles transport through tunnels a new QRA methodology is developed and presented here. In Europe the PIARC is a very common approach. It is therefore chosen as a starting point for the new methodology. It provides data on traffic statistics accident frequencies tunnel geometries including certain prevention and protection measures. This approach is enhanced by allowing better identification of hazards and their respective sources for hydrogen vehicles. A detailed analysis of the accident scenarios that are unique for hydrogen vehicles hereunder the initiating events severity of collision types that may result in a release of hydrogen gas in a tunnel and the location of such an accident are included. QRA enables the assessment and evaluation of scenarios involving external fires or vehicles that burst into fire because of an accident or other fire sources. Event Tree Analysis is the technique used to estimate the event frequencies. The consequence analysis includes the hazards from blast waves hydrogen jet fires DDT.
An Overview of Hydrogen Valleys: Current Status, Challenges and their Role in Increased Renewable Energy Penetration
Sep 2024
Publication
Renewable hydrogen is a flexible and versatile energy vector that can facilitate the decarbonization of several sectors and simultaneously ease the stress on the electricity grids that are currently being saturated with intermittent renewable power. But hydrogen technologies are currently facing limitations related to existing infrastructure limitations available markets as well as production storage and distribution costs. These challenges will be gradually addressed through the establishment operation and scaling-up of hydrogen valleys. Hydrogen valleys are an important stepping stone towards the full-scale implementation of the hydrogen economy with the target to foster sustainability lower carbon emissions and derisk the associated hydrogen technologies. These hydrogen ecosystems integrate renewable energy sources efficient hydrogen production storage transportation technologies as well as diverse end-users within a defined geographical region. This study offers an overview of the hydrogen valleys concept analyzing the critical aspects of their design and the key segments that constitute the framework of a hydrogen valley. А holistic overview of the key characteristics of a hydrogen valley is provided whereas an overview of key on-going hydrogen valley projects is presented. This work underscores the importance of addressing challenges related to the integration of renewable energy sources into electricity grids as well as scale-up challenges associated with economic and market conditions society awareness and political decision-making.
GT Enclosure Dispersion Analysis with Different CFD Tools
Sep 2023
Publication
A gas turbine is usually installed inside an acoustic enclosure where the fuel gas supply system is also placed. It is common practice using CFD analysis to simulate the accidental fuel gas release inside the enclosure and the consequent dispersion. These numerical studies are used to properly design the gas detection system according to specific safety criteria which are well defined when the fuel gas is a conventional natural gas. Package design is done to prevent that any sparking items and hot surfaces higher than auto-ignition temperature could be a source of ignition in case of leak. Nevertheless it is not possible to exclude that a leakage from a theoretical point of view could be ignited and for this reason a robust design requires that the enclosure structure is able to withstand the overpressure generated by a gas cloud ignition. Moving to hydrogen as fuel gas makes this design constraint much more relevant for its known characteristics of reactiveness large range of flammability maximum burning velocity etc. In such context gas leak and dispersion analysis become even more crucial because a correct prediction of these scenarios can guide the design to a safe configuration. The present work shows a comparison of the dispersion of different leakages inside a gas turbine enclosure carried out with two different CFD tools Ansys CFX and FLACS. This verification is considered essential since dispersion analysis results are used as initial conditions for gas cloud ignition simulations strictly necessary to predict the consequence in term of overpressure without doing experimental tests.
Hydrogen Jet Flame Simulation and Thermal Radiation Damage Estimation for Leakage Accidents in a Hydrogen Refueling Station
Jun 2024
Publication
With the rapid development of hydrogen energy worldwide the number of hydrogen energy facilities such as hydrogen refueling stations has grown rapidly in recent years. However hydrogen is prone to leakage accidents during use which could lead to hazards such as fires and explosions. Therefore research on the safety of hydrogen energy facilities is crucial. In this paper a study of high-pressure hydrogen jet flame accidents is conducted for a proposed integrated hydrogen production and refueling station in China. The effects of leakage direction and leakage port diameter on the jet flame characteristics are analyzed and a risk assessment of the flame accident is conducted. The results showed that the death range perpendicular to the flame direction increased from 2.23 m to 5.5 m when the diameter of the leakage port increased from 4 mm to 10 mm. When the diameter of the leakage port is larger than 8 mm the equipment on the scene will be within the boundaries of the damage. The consequences of fire can be effectively mitigated by a reasonable firewall setup to ensure the overall safety of the integrated station.
It Is Not the Same Green: A Comparative LCA Study of Green Hydrogen Supply Network Pathways
Jul 2024
Publication
Green hydrogen (H2 ) a promising clean energy source garnering increasing attention worldwide can be derived through various pathways resulting in differing levels of greenhouse gas emissions. Notably Green H2 production can utilize different methods such as integrating standard photovoltaic panels thermal photovoltaic or concentrated photovoltaic thermal collectors with electrolyzers. Furthermore it can be conditioned to different states or carriers including liquefied H2 compressed H2 ammonia and methanol and stored and transported using various methods. This paper employs the Life Cycle Assessment methodology to compare 18 different green hydrogen pathways and provide recommendations for greening the hydrogen supply chain. The findings indicate that the production pathway utilizing concentrated photovoltaic thermal panels for electricity generation and hydrogen compression in the conditioning and transportation stages exhibits the lowest environmental impact emitting only 2.67 kg of CO2 per kg of H2 .
Review on Bubble Dynamics in Proton Exchange Membrane Water Electrolysis: Towards Optimal Green Hydrogen Yield
Dec 2023
Publication
Water electrolysis using a proton exchange membrane (PEM) holds substantial promise to produce green hydrogen with zero carbon discharge. Although various techniques are available to produce hydrogen gas the water electrolysis process tends to be more cost-effective with greater advantages for energy storage devices. However one of the challenges associated with PEM water electrolysis is the accumulation of gas bubbles which can impair cell performance and result in lower hydrogen output. Achieving an in-depth knowledge of bubble dynamics during electrolysis is essential for optimal cell performance. This review paper discusses bubble behaviors measuring techniques and other aspects of bubble dynamics in PEM water electrolysis. It also examines bubble behavior under different operating conditions as well as the system geometry. The current review paper will further improve the understanding of bubble dynamics in PEM water electrolysis facilitating more competent inexpensive and feasible green hydrogen production.
Hydrogen Production, Transporting and Storage Processes—A Brief Review
Sep 2024
Publication
This review aims to enhance the understanding of the fundamentals applications and future directions in hydrogen production techniques. It highlights that the hydrogen economy depends on abundant non-dispatchable renewable energy from wind and solar to produce green hydrogen using excess electricity. The approach is not limited solely to existing methodologies but also explores the latest innovations in this dynamic field. It explores parameters that influence hydrogen production highlighting the importance of adequately controlling the temperature and concentration of the electrolytic medium to optimize the chemical reactions involved and ensure more efficient production. Additionally a synthesis of the means of transport and materials used for the efficient storage of hydrogen is conducted. These factors are essential for the practical feasibility and successful deployment of technologies utilizing this energy resource. Finally the technological innovations that are shaping the future of sustainable use of this energy resource are emphasized presenting a more efficient alternative compared to the fossil fuels currently used by society. In this context concrete examples that illustrate the application of hydrogen in emerging technologies are highlighted encompassing sectors such as transportation and the harnessing of renewable energy for green hydrogen production.
Strategic Analysis of Hydrogen Market Dynamics Across Collaboration Models
Oct 2024
Publication
The global energy landscape is experiencing a transformative shift with an increasing emphasis on sustainable and clean energy sources. Hydrogen remains a promising candidate for decarbonization energy storage and as an alternative fuel. This study explores the landscape of hydrogen pricing and demand dynamics by evaluating three collaboration scenarios: market-based pricing cooperative integration and coordinated decision-making. It incorporates price-sensitive demand environmentally friendly production methods and market penetration effects to provide insights into maximizing market share profitability and sustainability within the hydrogen industry. This study contributes to understanding the complexities of collaboration by analyzing those structures and their role in a fast transition to clean hydrogen production by balancing economic viability and environmental goals. The findings reveal that the cooperative integration strategy is the most effective for sustainable growth increasing green hydrogen’s market share to 19.06 % and highlighting the potential for environmentally conscious hydrogen production. They also suggest that the coordinated decision-making approach enhances profitability through collaborative tariff contracts while balancing economic viability and environmental goals. This study also underscores the importance of strategic pricing mechanisms policy alignment and the role of hydrogen hubs in achieving sustainable growth in the hydrogen sector. By highlighting the uncertainties and potential barriers this research offers actionable guidance for policymakers and industry players in shaping a competitive and sustainable energy marketplace.
Component and System Levels Limitations in Power-Hydrogen Systems: Analytical Review
Jun 2024
Publication
This study identifies limitations and research and development (R&D) gaps at both the component and system levels for hydrogen energy systems (HESs) and specifies how these limitations impact HES adoption within the electric power system (EPS) decarbonization roadmap. To trace these limitations and potential solutions an analytical review is conducted in electrification and integration of HESs renewable energy sources (RESs) and multi-carrier energy systems (MCESs) in sequence. The study also innovatively categorizes HES integration challenges into component and system levels. At the component level technological aspects of hydrogen generation storage transportation and refueling are explored. At the system level HES coordination hydrogen market frameworks and adoption challenges are evaluated. Findings highlight R&D gaps including misalignment between HES operational targets and techno-economic development integration insufficiency model deficiencies and challenges in operational complexity. This study provides insights for sustainable energy integration by supporting the transition to a decarbonized energy system.
A Systematic Study on Techno-Economic Evaluation of Hydrogen Production
Sep 2023
Publication
This paper aims to perform a systematic review with a bibliometric approach of the technoeconomic evaluation studies of hydrogen production. To achieve this objective a comprehensive outline of hydrogen production processes from fossil and renewable sources is presented. The results reveal that electrolysis classified as water splitting is the most investigated process in the literature since it contributes to a reduction in greenhouse gas emissions and presents other advantages such as maturity and applicability energy efficiency flexibility and energy storage potential. In addition the processes of gasification classified as thermochemical and steam reforming classified as catalytic reforming are worth mentioning. Regarding the biological category there is a balance between research on photo fermentation and dark fermentation. The literature on the techno-economic evaluation of hydrogen production highlights significant gaps including a scarcity of comprehensive studies a lack of emphasis on commercial viability an absence of sensitivity analysis and the need for comparative analyses between production technologies.
A Review on Liquid Hydrogen Fuel Systems in Aircraft Applications for Gas Turbine Engines
Oct 2024
Publication
The transition from traditional aviation fuels to low-emission alternatives such as hydrogen is a crucial step towards a sustainable future for aviation. Conventional jet fuels substantially contribute to greenhouse gas emissions and climate change. Hydrogen fuel especially "green" hydrogen offers great potential for achieving full sustainability in aviation. Hybrid/electric/fuel cell technologies may be used for shorter flights while longrange aircraft are more likely to combust hydrogen in gas turbines. Liquid hydrogen is necessary to minimize storage tank weight but the required fuel systems are at a low technology readiness level and differ significantly from Jet A-1 systems in architecture operation and performance. This paper provides an in-depth review covering the development of liquid hydrogen fuel system design concepts for gas turbines since the 1950s compares insights from key projects such as NASA studies and ENABLEH2 alongside an analysis of recent publications and patent applications and identifies the technological advancements required for achieving zeroemission targets through hydrogen-fuelled propulsion.
Optimization Strategy for Low-Carbon Economy of Integrated Energy System Considering Carbon Capture-Two Stage Power-to-Gas Hydrogen Coupling
Jun 2024
Publication
To further optimize the low-carbon economy of the integrated energy system (IES) this paper establishes a two-stage P2G hydrogen-coupled electricity–heat–hydrogen–gas IES with carbon capture (CCS). First this paper refines the two stages of P2G and introduces a hydrogen fuel cell (HFC) with a hydrogen storage device to fully utilize the hydrogen energy in the first stage of power-to-gas (P2G). Then the ladder carbon trading mechanism is considered and CCS is introduced to further reduce the system’s carbon emissions while coupling with P2G. Finally the adjustable thermoelectric ratio characteristics of the combined heat and power unit (CHP) and HFC are considered to improve the energy utilization efficiency of the system and to reduce the system operating costs. This paper set up arithmetic examples to analyze from several perspectives and the results show that the introduction of CCS can reduce carbon emissions by 41.83%. In the CCS-containing case refining the P2G two-stage and coupling it with HFC and hydrogen storage can lead to a 30% reduction in carbon emissions and a 61% reduction in wind abandonment costs; consideration of CHP and HFC adjustable thermoelectric ratios can result in a 16% reduction in purchased energy costs.
Towards the Design of a Hydrogen-powered Ferry for Cleaner Passenger Transport
Aug 2024
Publication
The maritime transportation sector is a large and growing contributor of greenhouse gas and other emissions. Therefore stringent measures have been taken by the International Maritime Organization to mitigate the environmental impact of the international shipping. These lead to the adoption of new technical solutions involving clean fuels such as hydrogen and high efficiency propulsion technologies that is fuel cells. In this framework this paper proposes a methodological approach aimed at supporting the retrofit design process of a car-passenger ferry operating in the Greece’s western maritime zone whose conventional powertrain is replaced with a fuel cell hybrid system. To this aim first the energy/power requirements and the expected hydrogen consumption of the vessel are determined basing on a typical operational profile retrieved from data provided by the shipping company. Three hybrid powertrain configurations are then proposed where fuel cell and batteries are balanced out according to different design criteria. Hence a new vessel layout is defined for each of the considered options by taking into account on-board weight and space constraints to allocate the components of the new hydrogen-based propulsion systems. Finally the developed vessel configurations are simulated in a virtual towing tank environment in order to assess their hydrodynamic response and compare them with the original one thus providing crucial insights for the design process of new hydrogen-fueled vessel solutions. Findings from this study reveal that the hydrogen-based configurations of the vessel are all characterized by a slight reduction of the payload mainly due to the space required to allocate the hydrogen storage system; instead the hydrodynamic behavior of the H2 powered vessels is found to be similar to the one of the original Diesel configuration; also from a hydrodynamic point of view the results show that mid load operating conditions get relevance for the design process of the hybrid vessels.
Techno‐Economic Analysis of Hydrogen as a Storage Solution in an Integrated Energy System for an Industrial Area in China
Jun 2024
Publication
This study proposes four kinds of hybrid source–grid–storage systems consisting of pho‐ tovoltaic and wind energy and a power grid including different batteries and hydrogen storage systems for Sanjiao town. HOMER‐PRO was applied for the optimal design and techno‐economic analysis of each case aiming to explore reproducible energy supply solutions for China’s industrial clusters. The results show that the proposed system is a fully feasible and reliable solution for in‐ dustry‐based towns like Sanjiao in their pursuit of carbon neutrality. In addition the source‐side price sensitivity analysis found that the hydrogen storage solution was cost‐competitive only when the capital costs on the storage and source sides were reduced by about 70%. However the hydro‐ gen storage system had the lowest carbon emissions about 14% lower than the battery ones. It was also found that power generation cost reduction had a more prominent effect on the whole system’s NPC and LCOE reduction. This suggests that policy support needs to continue to push for genera‐ tion‐side innovation and scaling up while research on different energy storage types should be en‐ couraged to serve the needs of different source–grid–load–storage systems.
An Economic Performance Improving and Analysis for Offshore Wind Farm-Based Islanded Green Hydrogen System
Jul 2024
Publication
When offshore wind farms are connected to a hydrogen plant with dedicated transmission lines for example high-voltage direct current the fluctuation of wind speed will influence the efficiency of the alkaline electrolyzer and deteriorate the techno-economic performance. To overcome this issue firstly an additional heating process is adopted to achieve insulation for the alkaline solution when power generated by wind farms is below the alkaline electrolyzer minimum power threshold while the alkaline electrolyzer overload feature is used to generate hydrogen when wind power is at its peak. Then a simplified piecewise model-based alkaline electrolyzer techno-economic analysis model is proposed. The improved economic performance of the islanded green hydrogen system with the proposed operation strategy is verified based on the wind speed data set simulation generated by the Weibull distribution. Lastly the sensitivity of the total return on investment to wind speed parameters was investigated and an islanded green hydrogen system capacity allocation based on the proposed analysis model was conducted. The simulation result shows the total energy utilization increased from 62.0768% to 72.5419% and the return on investment increased from 5.1303%/month to 5.9581%/month when the proposed control strategy is adopted.
A Novel Sustainable Approach for Site Selection of Underground Hydrogen Storage in Poland Using Deep Learning
Jul 2024
Publication
This research investigates the potential of using bedded salt formations for underground hydrogen storage. We present a novel artificial intelligence framework that employs spatial data analysis and multi-criteria decision-making to pinpoint the most appropriate sites for hydrogen storage in salt caverns. This methodology incorporates a comprehensive platform enhanced by a deep learning algorithm specifically a convolutional neural network (CNN) to generate suitability maps for rock salt deposits for hydrogen storage. The efficacy of the CNN algorithm was assessed using metrics such as Mean Absolute Error (MAE) Mean Squared Error (MSE) Root Mean Square Error (RMSE) and the Correlation Coefficient (R2 ) with comparisons made to a real-world dataset. The CNN model showed outstanding performance with an R2 of 0.96 MSE of 1.97 MAE of 1.003 and RMSE of 1.4. This novel approach leverages advanced deep learning techniques to offer a unique framework for assessing the viability of underground hydrogen storage. It presents a significant advancement in the field offering valuable insights for a wide range of stakeholders and facilitating the identification of ideal sites for hydrogen storage facilities thereby supporting informed decisionmaking and sustainable energy infrastructure development.
Comparative Analysis of Solar Cells and Hydrogen Fuels: A Mini Review
Jul 2024
Publication
The aim of this mini-review is to compare the effectiveness and potential of solar cells and hydrogen fuel technologies in clean energy generation. Key aspects such as efficiency scalability environmental footprint and technological maturity are examined. Solar cells are analyzed for their ability to convert sunlight into electricity efficiently and their potential for widespread deployment with minimal environmental impact. Hydrogen fuel technologies are assessed based on their efficiency in hydrogen production scalability and overall environmental footprint from production to end use. The review identifies significant challenges including high costs infrastructure needs and policy requirements as well as opportunities for innovation and market growth. The findings provide insights to guide decision-making towards a sustainable energy future.
Fuzzy Logic-Based Energy Management Strategy for Hybrid Fuel Cell Electric Ship Power and Propulsion System
Oct 2024
Publication
The growing use of proton-exchange membrane fuel cells (PEMFCs) in hybrid propulsion systems is aimed at replacing traditional internal combustion engines and reducing greenhouse gas emissions. Effective power distribution between the fuel cell and the energy storage system (ESS) is crucial and has led to a growing emphasis on developing energy management systems (EMSs) to efficiently implement this integration. To address this goal this study examines the performance of a fuzzy logic rule-based strategy for a hybrid fuel cell propulsion system in a small hydrogenpowered passenger vessel. The primary objective is to optimize fuel efficiency with particular attention on reducing hydrogen consumption. The analysis is carried out under typical operating conditions encountered during a river trip. Comparisons between the proposed strategy with other approaches—control based optimization based and deterministic rule based—are conducted to verify the effectiveness of the proposed strategy. Simulation results indicated that the EMS based on fuzzy logic mechanisms was the most successful in reducing fuel consumption. The superior performance of this method stems from its ability to adaptively manage power distribution between the fuel cell and energy storage systems.
Hydrogen Revolution in Europe: Bibliometric Review of Industrial Hydrogen Applications for a Sustainable Future
Jul 2024
Publication
Industrial applications of hydrogen are key to the transition towards a sustainable lowcarbon economy. Hydrogen has the potential to decarbonize industrial sectors that currently rely heavily on fossil fuels. Hydrogen with its unique and versatile properties has several in-industrial applications that are fundamental for sustainability and energy efficiency such as the following: (i) chemical industry; (ii) metallurgical sector; (iii) transport; (iv) energy sector; and (v) agrifood sector. The development of a bibliometric analysis of industrial hydrogen applications in Europe is crucial to understand and guide developments in this emerging field. Such an analysis can identify research trends collaborations between institutions and countries and the areas of greatest impact and growth. By examining the scientific literature and comparing it with final hydrogen consumption in different regions of Europe the main actors and technologies that are driving innovation in industrial hydrogen use on the continent can be identified. The results obtained allow for an assessment of the knowledge gaps and technological challenges that need to be addressed to accelerate the uptake of hydrogen in various industrial sectors. This is essential to guide future investments and public policies towards strategic areas that maximize the economic and environmental impact of industrial hydrogen applications in Europe.
National Gas FutureGrid Phase 1 Closure Report
Jul 2024
Publication
This project an essential part of the National Gas HyNTS programme endeavours to align the NTS with GB’s net zero ambitions by demonstrating the operational viability of the system with varying hydrogen blends using decommissioned assets typical of the natural gas network today ultimately aiming for 100% hydrogen conveyance. Several desktop studies were undertaken within the HyNTS programme to confirm the theoretical potential of the NTS to transport hydrogen safely and reliably. Further to these studies practical demonstration was deemed necessary to bridge the knowledge gaps and ensure the system’s transition maintains the utmost safety and reliability standards. A range of tests on decommissioned assets were conducted offline in a controlled environment to ensure robust outcomes that will ultimately start to build the safety case for a hydrogen network. The key deliverables and testing achievements of FutureGrid included: • Operational testing with natural gas and 2% 5% 20% and 100% hydrogen to verify the network’s ability to transport hydrogen and varying blends. • Standalone offline testing modules complementing evidence gathered on the main test facility. These address specific areas of concern including material permeation flange integrity asset leakage and rupture consequence which are essential for risk mitigation and safety assurance. FutureGrid is a global first facility and a critical part of National Gas’ hydrogen programme providing physical evidence of the capability of our network to transport hydrogen. It provides key evidence for hydrogen blending alongside 100% hydrogen pipelines which are planned under Project Union our Hydrogen Backbone across GB. FutureGrid is pivotal in the journey to reaching Net Zero by 2050 and is a fully operational proven technical demonstrator. FutureGrid’s repurposed assets are representative of today’s live high pressure gas network and have been subjected to testing at different blends of natural gas with hydrogen and 100% hydrogen; this was achieved with no major findings in differences in terms of how the assets interact with hydrogen. The overall project completion date was delayed from November 2023 to February 2024 due to technical issues with the newly built hydrogen re‑compressor. There were no changes made to the project costs.
Advances in Hospital Energy Systems: Genetic Algorithm Optimization of a Hybrid Solar and Hydrogen Fuel Cell Combined Heat and Power
Sep 2024
Publication
This paper presents an innovative Fuel Cell Combined Heat and Power (FC–CHP) system designed to enhance energy efficiency in hospital settings. The system primarily utilizes solar energy captured through photovoltaic (PV) panels for electricity generation. Excess electricity is directed to an electrolyzer for water electrolysis producing hydrogen which is stored in high-pressure tanks. This hydrogen serves a dual purpose: it fuels a boiler for heating and hot water needs and powers a fuel cell for additional electricity when solar production is low. The system also features an intelligent energy management system that dynamically allocates electrical energy between immediate consumption hydrogen production and storage while also managing hydrogen release for energy production. This study focuses on optimization using genetic algorithms to optimize key components including the peak power of photovoltaic panels the nominal power of the electrolyzer fuel cell and storage tank sizes. The objective function minimizes the sum of investment and electricity costs from the grid considering a penalty coefficient. This approach ensures optimal use of renewable energy sources contributing to energy efficiency and sustainability in healthcare facilities.
Charting the Course: Navigating Decarbonisation Pathways in Greece, Germany, The Netherlands, and Spain’s Industrial Sectors
Jul 2024
Publication
In the quest for a sustainable future energy-intensive industries (EIIs) stand at the forefront of Europe’s decarbonisation mission. Despite their significant emissions footprint the path to comprehensive decarbonisation remains elusive at EU and national levels. This study scrutinises key sectors such as non-ferrous metals steel cement lime chemicals fertilisers ceramics and glass. It maps out their current environmental impact and potential for mitigation through innovative strategies. The analysis spans across Spain Greece Germany and the Netherlands highlighting sector-specific ecosystems and the technological breakthroughs shaping them. It addresses the urgency for the industry-wide adoption of electrification the utilisation of green hydrogen biomass bio-based or synthetic fuels and the deployment of carbon capture utilisation and storage to ensure a smooth transition. Investment decisions in EIIs will depend on predictable economic and regulatory landscapes. This analysis discusses the risks associated with continued investment in high-emission technologies which may lead to premature decommissioning and significant economic repercussions. It presents a dichotomy: invest in climate-neutral technologies now or face the closure and offshoring of operations later with consequences for employment. This open discussion concludes that while the technology for near-complete climate neutrality in EIIs exists and is rapidly advancing the higher costs compared to conventional methods pose a significant barrier. Without the ability to pass these costs to consumers the adoption of such technologies is stifled. Therefore it calls for decisive political commitment to support the industry’s transition ensuring a greener more resilient future for Europe’s industrial backbone.
Storage Integrity During Underground Hydrogen Storage in Depleted Gas Reservoirs
Nov 2023
Publication
The transition from fossil fuels to renewable energy sources particularly hydrogen has emerged as a central strategy for decarbonization and the pursuit of net-zero carbon emissions. Meeting the demand for large-scale hydrogen storage a crucial component of the hydrogen supply chain has led to the exploration of underground hydrogen storage as an economically viable solution to global energy needs. In contrast to other subsurface storage options such as salt caverns and aquifers which are geographically limited depleted gas reservoirs have garnered increasing attention due to their broader distribution and higher storage capacity. However the safe storage and cycling of hydrogen in depleted gas reservoirs require the preservation of high stability and integrity in the caprock reservoir and wellbore. Nevertheless there exists a significant gap in the current research concerning storage integrity in underground hydrogen storage within depleted gas reservoirs and a systematic approach is lacking. This paper aims to address this gap by reviewing the primary challenges associated with storage integrity including geochemical reactions microbial activities faults and fractures and perspectives on hydrogen cycling. The study comprehensively reviews the processes and impacts such as abiotic and biotic mineral dissolution/precipitation reactivation and propagation of faults and fractures in caprock and host-rock wellbore instability due to cement degradation and casing corrosion and stress changes during hydrogen cycling. To provide a practical solution a technical screening tool has been developed considering controlling variables risks and consequences affecting storage integrity. Finally this paper highlights knowledge gaps and suggests feasible methods and pathways to mitigate these risks facilitating the development of large-scale underground hydrogen storage in depleted gas reservoirs.
Hopes and Fears for a Sustainable Energy Future: Enter the Hydrogen Acceptance Matrix
Feb 2024
Publication
Hydrogen-fuelled technologies for home heating and cooking may provide a low-carbon solution for decarbonising parts of the global housing stock. For the transition to transpire the attitudes and perceptions of consumers must be factored into policy making efforts. However empirical studies are yet to explore potential levels of consumer heterogeneity regarding domestic hydrogen acceptance. In response this study explores a wide spectrum of consumer responses towards the prospect of hydrogen homes. The proposed spectrum is conceptualised in terms of the ‘domestic hydrogen acceptance matrix’ which is examined through a nationally representative online survey conducted in the United Kingdom. The results draw attention to the importance of interest and engagement in environmental issues knowledge and awareness of renewable energy technologies and early adoption potential as key drivers of domestic hydrogen acceptance. Critically strategic measures should be taken to convert hydrogen scepticism and pessimism into hope and optimism by recognising the multidimensional nature of consumer acceptance. To this end resources should be dedicated towards increasing the observability and trialability of hydrogen homes in proximity to industrial clusters and hubs where the stakes for consumer acceptance are highest. Progress towards realising a net-zero society can be supported by early stakeholder engagement with the domestic hydrogen acceptance matrix.
Design of Long-Life Wireless Near-Field Hydrogen Gas Sensor
Sep 2023
Publication
A wireless near-field hydrogen gas sensor is proposed which detects the leaking hydrogen near its source to achieve fast response and high reliability. The proposed sensor can detect leaking hydrogen in 100ms with nearly no delay due to hydrogen diffusion in space. The overall response time is shortened by orders of magnitude compared to conventional sensors according to simulation results. Over 1 year of maintenance interval is empowered by wireless design based on Bluetooth low energy protocol.
Integration of Different Storage Technologies towards Sustainable Development—A Case Study in a Greek Island
Mar 2024
Publication
The necessity for transitioning to renewable energy sources and the intermittent nature of the natural variables lead to the integration of storage units into these projects. In this research paper wind turbines and solar modules are combined with pumped hydro storage batteries and green hydrogen. Energy management strategies are described for five different scenarios of hybrid renewable energy systems based on single or hybrid storage technologies. The motivation is driven by grid stability issues and the limited access to fresh water in the Greek islands. A RES-based desalination unit is introduced into the hybrid system for access to low-cost fresh water. The comparison of single and hybrid storage methods the exploitation of seawater for the simultaneous fulfillment of water for domestic and agricultural purposes and the evaluation of different energy economic and environmental indices are the innovative aspects of this research work. The results show that pumped hydro storage systems can cover the energy and water demand at the minimum possible price 0.215 EUR/kWh and 1.257 EUR/m3 while hybrid storage technologies provide better results in the loss of load probability payback period and CO2 emissions. For the pumped hydro– hydrogen hybrid storage system these values are 21.40% 10.87 years and 2297 tn/year respectively.
CFD Analysis of Hydrogen Leakage from a Small Hole in a Sloping Roof Hydrogen Refueling Station
Sep 2023
Publication
As a key link in the application of hydrogen energy hydrogen refueling stations are significant for their safe operation. This paper established a three-dimensional 1:1 model for a seaport hydrogen refueling station in Ningbo City. In this work the CFD software FLUENT was used to study the influence of leakage angles on the leakage of high-pressure hydrogen through a small hole. Considering the calculation accuracy and efficiency this paper adopted the pseudo-diameter model. When the obstacle was far from the leakage hole it had almost no obstructive effect on the jet's main body. Still it affected the hydrogen whose momentum in the outer layer of the jet has been significantly decayed. In this condition there would be more hydrogen in stagnation. Thus the volume of the flammable hydrogen cloud was hardly affected while there was a significant increase in the volume of the hazardous hydrogen cloud. When the obstacle was close to the leakage hole it directly affected the jet's main body. Therefore the volume of the flammable hydrogen cloud increased. However the air impeded the hydrogen jet relatively less because the hydrogen jet contacted the obstacle more quickly. The hydrogen jet blocked by the obstacle still has some momentum. Therefore there was no more hydrogen in stagnation and no significant increase in the volume of the hazardous hydrogen cloud.
Potential Cost Savings of Large-scale Blue Hydrogen Production via Sorption-enhanced Steam Reforming Process
Jan 2024
Publication
As countries work towards achieving net-zero emissions the need for cleaner fuels has become increasingly urgent. Hydrogen produced from fossil fuels with carbon capture and storage (blue hydrogen) has the potential to play a significant role in the transition to a low-carbon economy. This study examined the technical and economic potential of blue hydrogen produced at 600 MWth(LHV) and scaled up to 1000 MWth(LHV) by benchmarking sorption-enhanced steam reforming process against steam methane reforming (SMR) autothermal gasheated reforming (ATR-GHR) integrated with carbon capture and storage (CCS) and SMR with CCS. Aspen Plus® was used to develop the process model which was validated using literature data. Cost sensitivity analyses were also performed on two key indicators: levelised cost of hydrogen and CO2 avoidance cost by varying natural gas price electricity price CO2 transport and storage cost and carbon price. Results indicate that at a carbon price of 83 £/tCO2e the LCOH for SE-SR of methane is the lowest at 2.85 £/kgH2 which is 12.58% and 22.55% lower than that of ATR-GHR with CCS and SMR plant with CCS respectively. The LCOH of ATR-GHR with CCS and SMR plant with CCS was estimated to be 3.26 and 3.68 £/kgH2 respectively. The CO2 avoidance cost was also observed to be lowest for SE-SR followed by ATR-GHR with CCS then SMR plant with CCS and was observed to reduce as the plant scaled to 1000 MWth(LHV) for these technologies.
Elevating the Prospects of Green Hydrogen (H2) Production Through Solar-powered Water Splitting Devices: A Systematic Review
May 2024
Publication
As the commercialisation of two contrasting solar-powered water splitting devices with lower TRLs of proton exchange membrane (PEM) electrolyser systems and photoelectrochemical (PEC) systems gains momentum the path towards a sustainable H2 economy is taking shape. Ongoing pilot projects and demonstration plants are proving the feasibility and potential of these technologies in real-world applications. However to ensure their success we must confront the critical challenges of cost reduction and efficiency enhancement making green H2 economically competitive with traditional production methods. To achieve this a collaborative effort among academia industry and policymakers is paramount. This comprehensive review begins by examining traditional water electrolysis methods focusing on the production of green H2 through electrochemical splitting. It delves into crucial components and advancements in the PEM systems addressing challenges related to catalysts membranes gas diffusion layers and bipolar plates. The review also explores solar-driven PEC water splitting emphasizing the significance of efficient photoelectrodes and reactor design. Additionally it discusses the integration of photovoltaic cells with electrochemical or PEC systems for higher H2 yield. Commercialisation is underway and this endeavour necessitates a collaborative approach with active involvement from academia industry and policymakers. This collective effort not only propels us towards greener and more sustainable energy solutions but also represents a transformative step in the global journey towards a sustainable and environmentally conscious economy.
Review on the Thermal Neutrality of Application-orientated Liquid Organic Hydrogen Carrier for Hydrogen Energy Storage and Delivery
Aug 2023
Publication
The depletion and overuse of fossil fuels present formidable challenge to energy supply system and environment. The human society is in great need of clean renewable and sustainable energy which can guarantee the long-term utilization without leading to escalation of greenhouse effect. Hydrogen as an extraordinary secondary energy is capable of realizing the target of environmental protection and transferring the intermittent primary energy to the application terminal while its nature of low volumetric energy density and volatility need suitable storage method and proper carrier. In this context liquid organic hydrogen carrier (LOHC) among a series of storage methods such as compressed and liquefied hydrogen provokes a considerable amount of research interest since it is proven to be a suitable carrier for hydrogen with safety and stability. However the dehydrogenation of hydrogen-rich LOHC materials is an endothermic process and needs large energy consumption which hampers the scale up of the LOHC system. The heat issue is thus essential to be addressed for fulfilling the potential of LOHC. In this work several strategies of heat intensification and management for LOHC system including the microwave irradiation circulation of exhaust heat and direct LOHC fuel cell are summarized and analyzed to provide suggestions and directions for future research.
Thermodynamic Modelling and Optimisation of a Green Hydrogen-blended Syngas-fueled Integrated PV-SOFC System
Sep 2023
Publication
Developing an effective energy transition roadmap is crucial in the face of global commitments to achieve net zero emissions. While renewable power generation systems are expanding challenges such as curtailments and grid constraints can lead to energy loss. To address this surplus electricity can be converted into green hydrogen serving as a key component in the energy transition. This research explores the use of renewable solar energy for powering a proton exchange membrane electrolyser to produce green hydrogen while a downdraft gasifier fed by municipal solid waste generates hydrogen-enriched syngas. The blended fuel is then used to feed a Solid Oxide Fuel Cell (SOFC) system. The study investigates the impact of hydrogen content on the performance of the fuel cell-based power plant from thermodynamics and exergoeconomic perspectives. Multiobjective optimisation using a genetic algorithm identifies optimal operating conditions for the system. Results show that blending hydrogen with syngas increases combined heat and power efficiency by up to 3% but also raises remarkably the unit product cost and reduces carbon dioxide emissions. Therefore the optimal values for hydrogen content current density temperatures and other parameters are determined. These findings contribute to the design and operation of an efficient and sustainable energy generation system.
Optimal Hydrogen Infrastructure Planning for Heat Decarbonisation
Feb 2024
Publication
Energy decarbonisation is essential to achieve Net-Zero emissions goal by 2050. Consequently investments in alternative low-carbon pathways and energy carriers for the heat sector are required. In this study we propose an optimisation framework for the transition of heat sector in Great Britain focusing on hydrogen infrastructure decisions. A spatially-explicit mixed-integer linear programming (MILP) evolution model is developed to minimise the total system’s cost considering investment and operational decisions. The optimisation framework incorporates both long-term planning horizon of 5-year steps from 2035 to 2050 and typical days with hourly resolution. Aiming to alleviate the computational effort of such multiscale model two hierarchical solution approaches are suggested that result in computational time reduction. From the optimisation results it is shown that the installation of gas reforming hydrogen production technologies with CCS and biomass gasification with CCS can provide a cost-effective strategy achieving decarbonisation goal. What-if analysis is conducted to demonstrate further insights for future hydrogen infrastructure investments. Results indicate that as cost is highly dependent on natural gas price Water Electrolysis capacity increases significantly when gas price rises. Moreover the introduction of carbon tax policy can lead to lower CO2 net emissions.
Deep Low-Carbon Economic Optimization Using CCUS and Two-Stage P2G with Multiple Hydrogen Utilizations for an Integrated Energy System with a High Penetration Level of Renewables
Jul 2024
Publication
Integrating carbon capture and storage (CCS) technology into an integrated energy system (IES) can reduce its carbon emissions and enhance its low-carbon performance. However the full CCS of flue gas displays a strong coupling between lean and rich liquor as carbon dioxide liquid absorbents. Its integration into IESs with a high penetration level of renewables results in insufficient flexibility and renewable curtailment. In addition integrating split-flow CCS of flue gas facilitates a short capture time giving priority to renewable energy. To address these limitations this paper develops a carbon capture utilization and storage (CCUS) method into which storage tanks for lean and rich liquor and a two-stage power-to-gas (P2G) system with multiple utilizations of hydrogen including a fuel cell and a hydrogen-blended CHP unit are introduced. The CCUS is integrated into an IES to build an electricity–heat–hydrogen–gas IES. Accordingly a deep low-carbon economic optimization strategy for this IES which considers stepwise carbon trading coal consumption renewable curtailment penalties and gas purchasing costs is proposed. The effects of CCUS the twostage P2G system and stepwise carbon trading on the performance of this IES are analyzed through a case-comparative analysis. The results show that the proposed method allows for a significant reduction in both carbon emissions and total operational costs. It outperforms the IES without CCUS with an 8.8% cost reduction and a 70.11% reduction in carbon emissions. Compared to the IES integrating full CCS the proposed method yields reductions of 6.5% in costs and 24.7% in emissions. Furthermore the addition of a two-stage P2G system with multiple utilizations of hydrogen further amplifies these benefits cutting costs by 13.97% and emissions by 12.32%. In addition integrating CCUS into IESs enables the full consumption of renewables and expands hydrogen utilization and the renewable consumption proportion in IESs can reach 69.23%.
A Bibliometric Study on the Research Trends and Hotspots of Proton Exchange Membrane Electrolyzer
Jan 2024
Publication
The application of hydrogen energy produced by proton exchange membrane electrolyzer (PEMEC) is conducive to the solution of the greenhouse effect and the energy crisis. In order to understand the development trends and research hotspot of PEMEC in recent years a total of 1874 research articles related to this field from 2003 to 2023 were obtained from the Web of Science Core Collection (WoS CC) database. The visualization software VOSviewer is used for bibliometric analysis and the research progress hotspots and trends in the PEMEC field are summarized. It was found that in the past two decades literature in the PEMEC field has shown a trend of stable increase at first and then rapidly increasing. And it is in a stage of rapid growth after 2021.Renewable Energy previously published research articles related to PEMEC with the highest frequency of citations. There are a total of 6128 researchers in this field but core authors only account for 4.5% of the total. Although China entered this field later than the United States and Canada it has the largest number of research articles. The research results provide a comprehensive overview of various aspects in the PEMEC field which is beneficial for researchers to grasp the development hotspots of PEMEC.
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