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Techno-economic Analysis for Advanced Methods of Green Hydrogen Production
May 2024
Publication
In the ongoing effort to reduce carbon emissions on a worldwide scale green hydrogen which is generated through environmentally responsible processes has emerged as a significant driving force. As the demand for clean energy continues to rise it is becoming increasingly important to have a solid understanding of the technological and economic elements of modern techniques of producing green hydrogen. In the context of green hydrogen generation understanding green hydrogen production's techno-economic features is necessary to reduce carbon emissions and transition to a low-carbon economy. associated with breakthroughs in technology the present study examines the most fascinating and relevant aspects of techno-economic analysis. Despite challenges green hydrogen can help the world move to a cleaner more sustainable energy future with solid analytical frameworks and legislation.
Economic Analysis of Hydrogen Energy Systems: A Global Perspective
Aug 2024
Publication
In the realm of renewable energy the integration of wind power and hydrogen energy systems represents a promising avenue towards environmental sustainability. However the development of cost-effective hydrogen energy storage solutions is crucial to fully realize the potential of hydrogen as a renewable energy source. By combining wind power generation with hydrogen storage a comprehensive hydrogen energy system can be established. This study aims to devise a physiologically inspired optimization approach for designing a standalone wind power producer that incorporates a hydrogen energy system on a global scale. The optimization process considers both total cost and capacity loss to determine the optimal configuration for the system. The optimal setup for an off-grid solution involves the utilization of eight distinct types of compact horizontal-axis wind turbines. Additionally a sensitivity analysis is conducted by varying component capital costs to assess their impact on overall cost and load loss. Simulation results indicate that at a 15% loss the cost of energy (COE) is $1.3772 while at 0% loss it stands at $1.6908. Capital expenses associated with wind turbines and hydrogen storage systems significantly contribute to the overall cost. Consequently the wind turbine-hydrogen storage system emerges as the most cost-effective and reliable option due to its low cost of energy.
CFD Simulation and ANN Prediction of Hydrogen Leakage and Diffusion Behavior in a Hydrogen Refuelling Station
Sep 2023
Publication
Hydrogen refuelling stations are an important part of the infrastructure for promoting the hydrogen economy. Since hydrogen is a flammable and explosive gas hydrogen released from high-pressure hydrogen storage equipment in hydrogen refuelling stations will likely cause combustion or explosion accidents. Studying high-pressure hydrogen leakage in hydrogen refuelling stations is a prerequisite for promoting hydrogen fuel cell vehicles and hydrogen refuelling stations. In this work an actual-size hydrogen refuelling station model was established on the ANSYS FLUENT software platform. The computational fluid dynamics (CFD) models for hydrogen leakage simulation were validated by comparing the simulation results with experimental data in the literature. The effects of ambient wind speed wind direction leakage rate and leakage direction on the diffusion behaviors of the released hydrogen were investigated. The spreading distances of the flammable hydrogen cloud were predicted using an artificial neural network for horizontal leakage. The results show that the leak direction strongly affected the flammable cloud flow. The ambient wind speed has complicated effects on spreading the flammable cloud. The wind makes the flammable cloud move in certain directions and the higher wind speed accelerates the diffusion of the flammable gas in the air. The results of the study can be used as a reference for the study of high-pressure hydrogen leakage in hydrogen refuelling stations.
Sustainable Fuel Production Using In-situ Hydrogen Supply via Aqueous Phase Reforming: A Techno-economic and Life-cycle Greenhouse Gas Emissions Assessment
Jul 2023
Publication
Sustainable aviation fuel (SAF) production is one of the strategies to guarantee an environmental-friendly development of the aviation sector. This work evaluates the technical economic and environmental feasibility of obtaining SAFs by hydrogenation of vegetable oils thanks to in-situ hydrogen production via aqueous phase reforming (APR) of glycerol by-product. The novel implementation of APR would avoid the environmental burden of conventional fossil-derived hydrogen production as well as intermittency and storage issues related to the use of RES-based (renewable energy sources) electrolysers. The conceptual design of a conventional and advanced (APR-aided) biorefinery was performed considering a standard plant capacity equal to 180 ktonne/y of palm oil. For the advanced scenario the feed underwent hydrolysis into glycerol and fatty acids; hence the former was subjected to APR to provide hydrogen which was further used in the hydrotreatment reactor where the fatty acids were deoxygenated. The techno-economic results showed that APR implementation led to a slight increase of the fixed capital investment by 6.6% compared to the conventional one while direct manufacturing costs decreased by 22%. In order to get a 10% internal rate of return the minimum fuel selling price was found equal to 1.84 $/kg which is 17% lower than the one derived from conventional configurations (2.20 $/kg). The life-cycle GHG emission assessment showed that the carbon footprint of the advanced scenario was equal to ca. 12 g CO2/MJSAF i.e. 54% lower than the conventional one (considering an energy-based allocation). The sensitivity analysis pointed out that the cost of the feedstock SAF yield and the chosen plant size are keys parameters for the marketability of this biorefinery while the energy price has a negligible impact; moreover the source of hydrogen has significant consequences on the environmental footprint of the plant. Finally possible uncertainties for both scenarios were undertaken via Monte Carlo simulations.
Investigating the Future of Freight Transport Low Carbon Technologies Market Acceptance across Different Regions
Oct 2024
Publication
Fighting climate change has become a major task worldwide. One of the key energy sectors to emit greenhouse gases is transportation. Therefore long term strategies all over the world have been set up to reduce on-road combustion emissions. In this context the road freight sector faces significant challenges in decarbonization driven by its limited availability of low-emission fuels and commercialized zero-emission vehicles compared with its high energy demand. In this work we develop the Mobility and Energy Transportation Analysis (META) Model a python-based optimization model to quantify the impact of transportation projected policies on freight transport by projecting conventional and alternative fuel technologies market acceptance as well as greenhouse gas (GHG) emissions. Along with introducing e-fuels as an alternative refueling option for conventional vehicles META investigates the market opportunities of Mobile Carbon Capture (MCC) until 2050. To accurately assess this technology a techno-economic analysis is essential to compare MCC abatement cost to alternative decarbonization technologies such as electric trucks. The novelty of this work comes from the detailed cost categories taken into consideration in the analysis including intangible costs associated with heavy-duty technologies such as recharging/refueling time cargo capacity limitations and consumer acceptance towards emerging technologies across different regions. Based on the study results the competitive total cost of ownership (TCO) and marginal abatement cost (MAC) values of MCC make it an economically promising alternative option to decarbonize the freight transport sector. Both in the KSA and EU MCC options could reach greater than 50% market shares of all ICE vehicle sales equivalent to a combined 35% of all new sales shares by 2035.
Experimental Study of the Mitigation of Hydrogen-Air Explosions by Aqueous Foam
Sep 2023
Publication
The development of hydrogen production technologies as well as new uses represents an opportunity both to accelerate the ecological transition and to create an industrial sector. However the risks associated with the use of hydrogen must not be overlooked. The mitigation of a hydrogen explosion in an enclosure is partly based on prevention strategies such as detection and ventilation but also on protection strategies such as explosion venting. However in several situations such as in highly constrained urban environments the discharge of the explosion through blast walls could generate significant overpressure effects outside the containment which are unacceptable. Thus having alternative mitigation solutions can make the effects of the explosion acceptable by reducing the flame speed and the overpressure loading or suppressing the secondary explosion. The objective of this paper is to present the experimental study of the mitigation of hydrogen-air deflagration in a 4 m3 vented enclosure by injection of aqueous foam. After a description of the experimental set-up the main experimental results are presented showing the influence of aqueous foam on flame propagation (Fig. 1). Different foam expansion ratios were investigated. An interpretation of the mitigating effect of foam on the explosion effects is proposed based on the work of Kichatov [5] and Zamashchikov [2].
Deflagration-to-detonation Transition Due to a Pressurised Release of a Hydrogen Jet. First Results of the Ongoing TAU_NRCN-CEA Project
Sep 2023
Publication
A sudden release of compressed gases and the formation of a jet flow can occur in nature and various engineering applications. In particular high-pressure hydrogen jets can spontaneously ignite when released into an environment that contains oxygen. For some scenarios these high-pressure hydrogen jets can be released into a mixture containing hydrogen and oxygen. This scenario can possibly lead to a wide range of combustion regimes such as jet flames slow or fast deflagrations or even hazardous detonations. Each combustion regime is characterized by typical pressures and temperatures however fast transition between regimes is also possible.<br/>A common project between Tel Aviv University (TAU) Nuclear Research Center Negev (NRCN) and Commissariat à l’Energie Atomique et aux énergies alternatives (CEA) has been recently launched in order to understand these phenomena from experimental modelling and numerical points of view. The main goal is to investigate the dynamics and combustion regimes that arise once a pressurized hydrogen jet is released into a reactive environment that contains inhomogeneous concentrations of hydrogen steam and air.<br/>In this paper we present the first numerical results describing high-pressure hydrogen release obtained using a massively parallel compressible structured-grid flow solver. The experimental arrangements devoted to this phenomenon will also be described.
Green Hydrogen and its Unspoken Challenges for Energy Justice
Oct 2024
Publication
Green hydrogen is often promoted as a key facilitator for the clean energy transition but its implementation raises concerns around energy justice. This paper examines the socio-political and techno-economic challenges that green hydrogen projects may pose to the three tenets of energy justice: distributive procedural and recognition justice. From a socio-political perspective the risk of neocolonial resource extraction uneven distribution of benefits exclusion of local communities from decision-making and disregard for indigenous rights and cultures threaten all three justice tenets. Techno-economic factors such as water scarcity land disputes and resource-related conflicts in potential production hotspots further jeopardise distributive and recognition justice. The analysis framed by an adapted PEST model reveals that while green hydrogen holds promise for sustainable development its implementation must proactively address these justice challenges. Failure to do so could perpetuate injustices exploitation and marginalisation of vulnerable communities undermining the sustainability goals it aims to achieve. The paper highlights the need for inclusive and equitable approaches that respect local sovereignty integrate diverse stakeholders and ensure fair access and benefit-sharing. Only by centring justice considerations can the transition to green hydrogen catalyse positive social change and realise its full potential as a driver of sustainable energy systems.
Examining the Nature of Two-dimensional Transverse Waves in Marginal Hydrogen Detonations using Boundary Layer Loss Modeling with Detailed Chemistry
Sep 2023
Publication
Historically it has been a challenge to simulate the experimentally observed cellular structures and marginal behavior of multidimensional hydrogen-oxygen detonations in the presence of losses even with detailed chemistry models. Very recently a quasi-two-dimensional inviscid approach was pursued where losses due to viscous boundary layers were modeled by the inclusion of an equivalent mass divergence in the lateral direction using Fay’s source term formulation with Mirels’ compressible boundary layer solutions. The same approach was used for this study along with the inclusion of thermally perfect detailed chemistry in order to capture the correct ignition sensitivity of the gas to dynamic changes in the thermodynamic state behind the detonation front. In addition the strength of transverse waves and their impact on the detonation front was investigated. Here the detailed San Diego mechanism was applied and it has been found that the detonation cell sizes can be accurately predicted without the need to prescribe specific parameters for the combustion model. For marginal cases where the detonation waves approach their failure limit quasi-stable mode behavior was observed where the number of transverse waves monotonically decreased to a single strong wave over a long enough distance. The strong transverse waves were also found to be slightly weaker than the detonation front indicating that they are not overdriven in agreement with recent studies.
Analysis of Hydrogen Embrittlement on Aluminum Alloys for Vehicle-Mounted Hydrogen Storage Tanks: A Review
Aug 2021
Publication
High-pressure hydrogen tanks which are composed of an aluminum alloy liner and a carbon fiber wound layer are currently the most popular means to store hydrogen on vehicles. Nevertheless the aluminum alloy is easily affected by high-pressure hydrogen which leads to the appearance of hydrogen embrittlement (HE). Serious HE of hydrogen tank represents a huge dangers to the safety of vehicles and passengers. It is critical and timely to outline the mainstream approach and point out potential avenues for further investigation of HE. An analysis including the mechanism (including hydrogen-enhanced local plasticity model hydrogen-enhanced decohesion mechanism and hydrogen pressure theory) the detection (including slow strain rate test linearly increasing stress test and so on) and methods for the prevention of HE on aluminum alloys of hydrogen vehicles (such as coating) are systematically presented in this work. Moreover the entire experimental detection procedures for HE are expounded. Ultimately the prevention measures are discussed in detail. It is believed that further prevention measures will rely on the integration of multiple prevention methods. Successfully solving this problem is of great significance to reduce the risk of failure of hydrogen storage tanks and improve the reliability of aluminum alloys for engineering applications in various industries including automotive and aerospace.
Renewable Hydrogen Standards, Certifications, and Labels: A State-of-the-art Review from a Sustainability Systems Governance Perspective
Feb 2024
Publication
A range of existing and newly developed hydrogen standards certification and labelling (SCL) schemes aim to promote the role of ‘renewable’ ‘clean’ or ‘green’ hydrogen in decarbonising energy transitions. This paper analyses a sample of these SCLs to assess their role in the scaling up of renewable hydrogen and its derivatives. To analyse these hydrogen SCLs we embellish a novel conceptual framework that brings together Sustainability Systems Thinking and Governance (SSG) literatures. The results reveal noteworthy scheme differences in motivation approach criteria and governance; highlighting the complex interconnected and dynamic reality within which energy systems are embedded. We consider whether the sustainable utilisation of renewable hydrogen is well-served by the proliferation of SCLs and recommend an SSG-informed approach. An SSG approach will better promote collaboration towards an authoritative global multistakeholder compromise on hydrogen certification that balances economic considerations with social and environmental dimensions.
Palladium-alloy Membrane Reactors for Fuel Reforming and Hydrogen Production: Hydrogen Production Modelling
Jul 2023
Publication
Endeavors have recently been concentrated on minimizing the dependency on fossil fuels in order to mitigate the ever-increasing problem of greenhouse gas (GHG) emissions. Hydrogen energy is regarded as an alternative to fossil fuels due to its cleaner emission attributes. Reforming of hydrocarbon fuels is amongst the most popular and widely used methods for hydrogen production. Hydrogen produced from reforming processes requires additional processes to separate from the reformed gases. In some cases further purification of hydrogen has to be carried out to use the hydrogen in power generation applications. Metallic membranes especially palladium (Pd)-based ones have demonstrated sustainable hydrogen separation potential with around 99.99% hydrogen purity. Comprehensive and critical research investigations must be performed to optimize membrane-assisted reforming as well as to maximize the production of hydrogen. The computational fluid dynamic (CFD) can be an excellent tool to analyze and visualize the flow/reaction/permeation mechanisms at a lower cost in contrast with the experiments. In order to provide the necessary background knowledge on membrane reactor modeling this study reviews summarizes and analyses the kinetics of different fuel reforming processes equations to determine hydrogen permeation and lastly various geometry and operating condition adopted in the literature associated with membrane-reactor modeling works. It is indicated that hydrogen permeation through Pd-membranes depends highly on the difference in hydrogen pressure. It is found that hydrogen permeation can be improved by employing different pressure configuration introducing sweep flow on the permeate side of the membrane reducing retentate side flow rate and increasing the temperature.
Modelling Flexibility Requirements in Deep Decarbonisation Scenarios: The Role of Conventional Flexibility and Sector Coupling Options in the European 2050 Energy System
Feb 2024
Publication
Russia’s invasion of Ukraine has reaffirmed the importance of scaling up renewable energy to decarbonise Europe’s economy while rapidly reducing its exposure to foreign fossil fuel suppliers. Therefore the question of sources of flexibility to support a fully decarbonised European energy system is becoming even more critical in light of a renewable-dominated energy system. We developed and used a Pan-European energy system model to systematically assess and quantify sources of flexibility to meet deep decarbonisation targets. The electricity supply sector and electricity-based end-use technologies are crucial in achieving deep decarbonisation. Other low-carbon energy sources like biomethane hydrogen synthetic e-fuels and bioenergy with carbon capture and storage will also play a role. To support a fully decarbonised European energy system by 2050 both temporal and spatial flexibility will be needed. Spatial flexibility achieved through investments in national electricity networks and cross-border interconnections is crucial to support the aggressive roll-out of variable renewable energy sources. Cross-border trade in electricity is expected to increase and in deep decarbonisation scenarios the electricity transmission capacity will be larger than that of natural gas. Hydrogen storage and green hydrogen production will play a key role in providing traditional inter-seasonal flexibility and intraday flexibility will be provided by a combination of electrical energy storage hydrogen-based storage solutions (e.g. liquid H2 and pressurised storage) and hybrid heat pumps. Hydrogen networks and storage will become more critical as we move towards the highest decarbonisation scenario. Still the need for natural gas networks and storage will decrease substantially.
0-D Dynamic Performance Simulation of Hydrogen-Fueled Turboshaft Engine
Oct 2024
Publication
In the last few decades the problem of pollution resulting from human activities has pushed research toward zero or net-zero carbon solutions for transportation. The main objective of this paper is to perform a preliminary performance assessment of the use of hydrogen in conventional turbine engines for aeronautical applications. A 0-D dynamic model of the Allison 250 C-18 turboshaft engine was designed and validated using conventional aviation fuel (kerosene Jet A-1). A dedicated experimental campaign covering the whole engine operating range was conducted to obtain the thermodynamic data for the main engine components: the compressor lateral ducts combustion chamber high- and low-pressure turbines and exhaust nozzle. A theoretical chemical combustion model based on the NASA-CEA database was used to account for the energy conversion process in the combustor and to obtain quantitative feedback from the model in terms of fuel consumption. Once the engine and the turbomachinery of the engine were characterized the work focused on designing a 0-D dynamic engine model based on the engine’s characteristics and the experimental data using the MATLAB/Simulink environment which is capable of replicating the real engine behavior. Then the 0-D dynamic model was validated by the acquired data and used to predict the engine’s performance with a different throttle profile (close to realistic request profiles during flight). Finally the 0-D dynamic engine model was used to predict the performance of the engine using hydrogen as the input of the theoretical combustion model. The outputs of simulations running conventional kerosene Jet A-1 and hydrogen using different throttle profiles were compared showing up to a 64% reduction in fuel mass flow rate and a 3% increase in thermal efficiency using hydrogen in flight-like conditions. The results confirm the potential of hydrogen as a suitable alternative fuel for small turbine engines and aircraft.
Zone Negligible Extent: Example of Specific Detailed Risk Assessment for Low Pressure Equipment in a Hydrogen Refuelling Station
Sep 2023
Publication
The MultHyFuel project aims to develop evidence-based guidelines for the safe implementation of Hydrogen Refueling Stations (HRS) in a multi-fuel context. As a part of the generation of good practice guidelines for HRS Hazardous Area Classification (HAC) methodologies were analyzed and applied to case studies representing example configurations of HRS. It has been anticipated that Negligible Extent (NE) classifications might be applicable for sections of the HRS for instance a hydrogen generator. A NE zone requires that an ignition of a flammable cloud would result in negligible consequences. In addition depending on the pressure of the system IEC 60079-10-1:2020 establishes specific requirements in order to classify the hazardous area as being of NE. One such requirement is that a zone of NE shall not be applied for releases from flammable gas systems at pressures above 2000 kPag (20 barg) unless a specific detailed risk assessment is documented. However there is no definition within the standard as to the requirements of the specific detailed risk assessment. In this work an example for a specific detailed risk assessment for the NE classification is presented:<br/>• Firstly the requirements of cloud volume dilution and background concentration for a zone of NE classification from IEC 60079-10-1:2020 are analyzed for hydrogen releases from equipment placed in a mechanically ventilated enclosure.<br/>• Secondly the consequences arising from the ignition of the localized cloud are estimated and compared to acceptable harm criteria in order to assess if negligible consequences are obtained from the scenario.<br/>• In addition a specific qualitative risk assessment for the ignition of the cloud in the enclosure was considered incorporating the estimated consequences and analyzing the available safeguards in the example system.<br/>Recommendations for the specific detailed risk assessment are proposed for this scenario with the intention to support improved definition of the requirement in future revisions of IEC 60079-10-1.
Integration of Microgrids in Chemical Industries with Hydrogen as a Byproduct: Styrene Production Case Study
Feb 2024
Publication
The chemical industry serves as a global economic backbone and it is an intensive consumer of conventional energy. Due to the depletion of fossil fuels and the emission of greenhouse gases it is necessary to analyze energy supply solutions based on renewable energy sources in this industrial sector. Unlike other sectors such as residential or service industries which have been thoroughly analyzed by the scientific community the use of renewable energies in the chemical industry remains comparatively less examined by the scientific community. This article studies the use of an energy supply system based on photovoltaic technology or a PEM fuel cell for a styrene production industry analyzing the integration of energy storage systems such as batteries as well as different uses for the surplus hydrogen produced by the facility. The most interesting conclusions of the article are: (1) the renewable microgrid considered is viable both technically and economically with a discounted payback period between 5.4 and 6.5 years using batteries as an energy storage system; and (2) the use of hydrogen as energy storage system for a styrene industry is not yet a viable option from an economic point of view.
Review of Next Generation Hydrogen Production from Offshore Wind Using Water Electrolysis
Dec 2023
Publication
Hydrogen produced using renewable energy from offshore wind provides a versatile method of energy storage and power-to-gas concepts. However few dedicated floating offshore electrolyser facilities currently exist and therefore conditions of the offshore environment on hydrogen production cost and efficiency remain uncertain. Therefore this review focuses on the conversion of electrical energy to hydrogen using water electrolysis located in offshore areas. The challenges associated with the remote locations fluctuating power and harsh conditions are highlighted and recommendations for future electrolysis system designs are suggested. The latest research in polymer electrolyte membrane alkaline and membraneless electrolysis are evaluated in order to understand their capital costs efficiency and current research status for achieving scaled manufacturing to the GW scale required in the next three decades. Operating fundamentals that govern the performance of each device are investigated and future recommendations of research specifically for the integration of water electrolysers with offshore wind turbines is presented.
On the Green Transformation of the Iron and Steel Industry: Market and Competition Aspects of Hydrogen Biomass Options
Feb 2024
Publication
The iron and steel industry is a major emitter of carbon dioxide globally. To reduce their carbon footprint the iron and steel industry pursue different decarbonization strategies including deploying bio-based materials and energy carriers for reduction carburisation and/or energy purposes along their value-chains. In this study two potential roles for biomass were analysed: (a) substituting for fossil fuels in iron-ore pellets induration and (b) carburisation of DRI (direct reduced iron) produced via fully hydrogen-based reduction. The purpose of the study was to analyse the regional demand-driven price and allocative effects of biomass assortments under different biomass demand scenarios for the Swedish iron and steel industry. Economic modelling was used in combination with spatial biomass supply assessments to predict the changes on relevant biomass markets. The results showed that the estimated demand increases for forest biomass will have significant regional price effects. Depending on scenario the biomass demand will increase up to 25 percent causing regional prices to more than doubling. In general the magnitude of the price effects was driven by the volumes and types of biomasses needed in the different scenarios with larger price effects for harvesting residues and industrial by-products compared to those of roundwood. A small price effect of roundwood means that the incentives for forest-owners to increase their harvests and thus also the availability of harvest residues are small. Flexibility in the feedstock sourcing (both regarding quality and geographic origin) will thus be important if forest biomass is to satisfy demands in iron and steel industry.
The Effect of Defueling Rate on the Temperature Evolution of On-board Hydrogen Tanks
Jul 2015
Publication
During the driving of a fuel cell car the expansion of the hydrogen along the emptying of the high pressure storage tank produces a cooling of the gas. The hydrogen vessel can experience a fast depressurization during acceleration or under an emergency release. This can result on the one hand in exceeding the low safety temperature limit of 40 C inside the on-board compressed hydrogen tank and on the other hand in the cooling of its walls. In the present paper defueling experiments of two different types of on-board hydrogen tanks (Type III and Type IV) have been performed in all the range of expected defueling rates. The lowest temperatures have been found on the bottom part of the Type IV tank in very fast defuelings. For average driving conditions in both types of vessels the inside gas temperature gets closer to that of the walls and the tank would arrive to the refuelling station at a temperature significantly lower than the ambient temperature.
Modeling of Tube Deformation and Failure under Conditions of Hydrogen Detonation
Sep 2023
Publication
In case of accidental conditions involving high-speed hydrogen combustion the considerable pressure and thermal loads could result in substantial deformation and/or destruction of the industrial appliances. Accounting of such effects in the safety analysis with CFD tools can provide critical information on the design and construction of the sensitive appliances’ elements. The current paper presents the development and the implementation of a new 3D-technique which makes possible to perform simulations of the gas-dynamic processes simultaneously with adaptation of the geometry of complex configurations. Using the data obtained in the experiments on the flame acceleration and DDT in the tubes of industrial arrangements performed in MPA and KIT the authors performed a series of the combustion simulations corresponding to the experimental conditions. The combustion gas-dynamics was simulated using COM3D code and the tube wall material behavior was modelled using finite-element code ABAQUS - © Dassault Systèmes with real-time data exchange between the codes. Obtained numerical results demonstrated good agreement with the observed experimental data on both pressure dynamics and tube deformation history.
Low Platinum Fuel Cell as Enabler for the Hydrogen Fuel Cell Vehicle
Feb 2024
Publication
In this work the design and modeling of a fuel cell vehicle using low-loading platinum catalysts were investigated. Data from single fuel cells with low Pt-loading cathode catalysts were scaled up to fuel cell stacks and systems implemented in a vehicle and then compared to a commercial fuel cell vehicle. The low-loading Pt systems have shown lower efficiency at high loads compared to the commercial systems suggesting less stable materials. However the analysis showed that the vehicle comprising low-loading Pt catalysts achieves similar or higher efficiency compared to the commercial fuel cell vehicle when being scaled up for the same number of cells. When the systems were scaled up for the same maximum power as the commercial fuel cell vehicle all the low-loading Pt fuel cell systems showed higher efficiencies. In this case more cells are needed but still the amount of Pt is significantly reduced compared to the commercial one. The high-efficiency results can be associated with the vehicle’s power range operation that meets the region where the low-loading Pt fuel cells have high performance. The results suggested a positive direction towards the reduction of Pt in commercial fuel cell vehicles supporting a cost-competitive clean energy transition based on hydrogen.
Probabilistic Analysis of Low-Emission Hydrogen Production from a Photovoltaic Carport
Oct 2024
Publication
This article presents a 3D model of a yellow hydrogen generation system that uses the electricity produced by a photovoltaic carport. The 3D models of all key system components were collected and their characteristics were described. Based on the design of the 3D model of the photovoltaic carport the amount of energy produced monthly was determined. These quantities were then applied to determine the production of low-emission hydrogen. In order to increase the amount of low-emission hydrogen produced the usage of a stationary energy storage facility was proposed. The Metalog family of probability distributions was adopted to develop a strategic model for low-emission hydrogen production. The hydrogen economy of a company that uses small amounts of hydrogen can be based on such a model. The 3D modeling and calculations show that it is possible to design a compact low-emission hydrogen generation system using rapid prototyping tools including the photovoltaic carport with an electrolyzer placed in the container and an energy storage facility. This is an effective solution for the climate and energy transition of companies with low hydrogen demand. In the analytical part the Metalog probability distribution family was employed to determine the amount of monthly energy produced by 6.3 kWp photovoltaic systems located in two European countries: Poland and Italy. Calculating the probability of producing specific amounts of hydrogen in two European countries is an answer to a frequently asked question: In which European countries will the production of low-emission hydrogen from photovoltaic systems be the most profitable? As a result of the calculations for the analyzed year 2023 in Poland and Italy specific answers were obtained regarding the probability of monthly energy generation and monthly hydrogen production. Many companies from Poland and Italy are taking part in the European competition to create hydrogen banks. Only those that offer low-emission hydrogen at the lowest prices will receive EU funding.
Decarbonization with Induced Technical Change: Exploring the Niche Potential of Hydrogen in Heavy Transportation
Jan 2024
Publication
Fuel cells and electric batteries are competing technologies for the energy transition in heavy transportation. We explore the conditions for the survival of a unique technology in the long term. Learning by doing suggests focusing on a single technology while differentiation and decreasing return to scale (cost convexity) favor diversification. Exogenous technical change also plays a role. The interaction between these factors is analyzed in a general model. It is proved that in absence of convexity and exogenous technical change only one technology is used for the whole transition. We then apply this framework to analyze the competition between fuel-cell electric buses (FCEBs) and battery electric buses (BEB) in the European bus sector. There are both learning by doing and exogenous technical change. The model is calibrated and solved. It is shown that the existence of a niche for FCEBs critically depends on the speed at which cost reductions are achieved. The speed depends both on the size of the niche and the rate of learning by doing for FCEBs. Public policies to decentralize the socially optimal trajectory in terms of taxes (carbon) and subsidies (learning by doing) are derived.
Numerical Simulation of Hydrogen–Coal Blending Combustion in a 660 MW Tangential Boiler
Feb 2024
Publication
With the adjustment of energy structure the utilization of hydrogen energy has been widely attended. China’s carbon neutrality targets make it urgent to change traditional coal-fired power generation. The paper investigates the combustion of pulverized coal blended with hydrogen to reduce carbon emissions. In terms of calorific value the pulverized coal combustion with hydrogen at 1% 5% and 10% blending ratios is investigated. The results show that there is a significant reduction in CO2 concentration after hydrogen blending. The CO2 concentration (mole fraction) decreased from 15.6% to 13.6% for the 10% hydrogen blending condition compared to the non-hydrogen blending condition. The rapid combustion of hydrogen produces large amounts of heat in a short period which helps the ignition of pulverized coal. However as the proportion of hydrogen blending increases the production of large amounts of H2O gives an overall lower temperature. On the other hand the temperature distribution is more uniform. The concentrations of O2 and CO in the upper part of the furnace increased. The current air distribution pattern cannot satisfy the adequate combustion of the fuel after hydrogen blending.
Electricity Supply Configurations for Green Hydrogen Hubs: A European Case Study on Decarbonizing Urban Transport
Aug 2024
Publication
In this study a techno-economic analysis tool for conducting detailed feasibility studies on the deployment of green hydrogen hubs for fuel cell bus fleets is developed. The study evaluates and compares five green hydrogen hub configurations’ operational and economic performance under a typical metropolitan bus fleet refuelling schedule. Each configuration differs based on its electricity sourcing characteristics such as the mix of energy sources capacity sizing financial structure and grid interaction. A detailed comparative analysis of distinct green hydrogen hub configurations for decarbonising a fleet of fuel-cell buses is conducted. Among the key findings is that a hybrid renewable electricity source and hydrogen storage are essential for cost-optimal operation across all configurations. Furthermore bi-directional grid-interactive configurations are the most costefficient and can benefit the electricity grid by flattening the duck curve. Lastly the paper highlights the potential for cost reduction when the fleet refuelling schedule is co-optimized with the green hydrogen hub electricity supply configuration.
An Experimental Investigation of Hydrogen Production through Biomass Electrolysis
Jan 2024
Publication
This work investigated hydrogen production from biomass feedstocks (i.e. glucose starch lignin and cellulose) using a 100 mL h-type proton exchange membrane electrolysis cell. Biomass electrolysis is a promising process for hydrogen production although low in technology readiness level but with a series of recognised advantages: (i) lower-temperature conditions (compared to thermochemical processes) (ii) minimal energy consumption and low-cost post-production (iii) potential to synthesise high-volume H2 and (iv) smaller carbon footprint compared to thermochemical processes. A Lewis acid (FeCl3 ) was employed as a charge carrier and redox medium to aid in the depolymerisation/oxidation of biomass components. A comprehensive analysis was conducted measuring the H2 and CO2 emission volume and performing electrochemical analysis (i.e. linear sweep voltammetry and chronoamperometry) to better understand the process. For the first time the influence of temperature on current density and H2 evolution was studied at temperatures ranging from ambient temperature (i.e. 19 ◦C) to 80 ◦C. The highest H2 volume was 12.1 mL which was produced by FeCl3 -mediated electrolysis of glucose at ambient temperature which was up to two times higher than starch lignin and cellulose at 1.20 V. Of the substrates examined glucose also showed a maximum power-to-H2 -yield ratio of 30.99 kWh/kg. The results showed that hydrogen can be produced from biomass feedstock at ambient temperature when a Lewis acid (FeCl3 ) is employed and with a higher yield rate and a lower electricity consumption compared to water electrolysis.
A Review on the Environmental Performance of Various Hydrogen Production Technologies: An Approach Towards Hydrogen Economy
Nov 2023
Publication
Demand for hydrogen has grown and continues to rise as a versatile energy carrier. Hydrogen can be produced from renewable and non-renewable energy sources. A wide range of technologies to produce hydrogen in an environmentally friendly way have been developed. As the life cycle assessment (LCA) approach has become popular recently including in the hydrogen energy system this paper comprehensively reviews the LCA of hydrogen production technology. A subdivision based on the trends in the LCA studies hydrogen production technology goal and scope definition system boundary and environmental performance of hydrogen production is discussed in this review. Thermochemical hydrogen production is the most studied technology in LCA. However utilizing natural resources especially wind power in the electrolysis process stands out as an environmentally preferable solution when compared to alternative production processes. It is crucial to rethink reactors and other production-related equipment to improve environmental performance and increase hydrogen production efficiency. Since most of the previous LCA studies were conducted in developed countries and only a few were from developing countries a way forward for LCA application on hydrogen in developing countries was also highlighted and discussed. This review provides a comprehensive insight for further research on hydrogen production technology from an LCA perspective.
Techno-economic Viability of Decentralised Solar Photovoltaic-based Green Hydrogen Production for Sustainable Energy Transition in Ghana
Feb 2024
Publication
Transition to a sustainable energy supply is essential for addressing the challenges of climate change and achieving a low-carbon future. Green hydrogen produced from solar photovoltaic (PV) systems presents a promising solution in Ghana where energy demands are increasing rapidly. The levelized cost of hydrogen (LCOH) is considered a critical metric to evaluate hydrogen production techniques cost competitiveness and economic viability. This study presents a comprehensive analysis of LCOH from solar PV systems. The study considered a 5 MW green hydrogen production plant in Ghana’s capital Accra as a proposed system. The results indicate that the LCOH is about $9.49/kg which is comparable to other findings obtained within the SubSaharan Africa region. The study also forecasted that the LCOH for solar PV-based hydrogen produced will decrease to $5–6.5/kg by 2030 and $2–2.5/kg by 2050 or lower making it competitive with fossil fuel-based hydrogen. The findings of this study highlight the potential of green hydrogen as a sustainable energy solution and its role in driving the country’s net-zero emissions agenda in relation to its energy transition targets. The study’s outcomes are relevant to policymakers researchers investors and energy stakeholders in making informed decisions regarding deploying decentralised green hydrogen technologies in Ghana and similar contexts worldwide.
Analysis of the Combustion Speed in a Spark Ignition Engine Fuelled with Hydrogen and Gasoline Blends at Different Air Fuel Ratios
Nov 2024
Publication
The use of hydrogen in internal combustion engines is a promising solution for the decarbonisation of the transport sector. The current transition scenario is marked by the unavailability and storage challenges of hydrogen. Dual fuel combustion of hydrogen and gasoline in current spark ignition engines is a feasible solution in the short and medium term as it can improve engine efficiency reduce pollutant emissions and contribute significantly in tank to wheel decarbonisation without major engine modification. However new research is needed to understand how the incorporation of hydrogen affects existing engines to effectively implement gasoline-hydrogen dual fuel option. Understanding the impact of hydrogen on the combustion process (e.g. combustion speed) will guide and optimize the operation of engines under dual fuel combustion conditions. In this work a commercial gasoline direct injection engine has been modified to operate with gasolinehydrogen fuels. The experiments have been carried out at various air–fuel ratios ranging from stoichiometric to lean combustion conditions at constant engine speed and torque. At each one of the 14 experimental points 200-cycle in-cylinder pressure traces were recorded and processed with a quasi-dimensional diagnostic model and a combustion speed analysis was then carried out. It has been understood that hydrogen mainly reduces the duration of the first combustion phase. Hydrogen also enables to increase air excess ratios (lean in fuel combustion) without significantly increasing combustion duration. Furthermore a correlation is proposed to predict combustion speed as a function of the fuel and air mixture properties. This correlation can be incorporated to calculate combustion duration in predictive models of engines operating under different fuel mixtures and different geometries of the combustion chamber with pent-roof cylinder head and flat piston head.
Hydrogen Production from Wastewater: A Comprehensive Review of Conventional and Solar Powered Technologies
Mar 2024
Publication
The need to reduce the carbon footprint of conventional energy sources has made green hydrogen a promising solution for the energy transition. The most environmentally friendly way to produce hydrogen is through water-based production using renewable energy. However the availability of fresh water is limited so switching to wastewater instead of fresh water is the key solution to this problem. In response to this issue the present review reports the main findings of the research studies dealing with the feasibility of hydrogen production from wastewater using various technologies including biological electrochemical and advanced oxidation routes. These methods have been studied in a large number of experiments with the aim of investigating and improving the potential of each method. On the other hand the maturity of solar energy technologies has led researchers to focus on the possibility of harnessing this source and combining it with wastewater treatment techniques for the production of green hydrogen. Therefore the present review pays special attention to solar driven hydrogen production from wastewater by highlighting the potential of several technologies for simultaneous water treatment and green hydrogen production from wastewater. Recent results limitations challenges possible improvements and techno-economic assessments reported by several authors as well as future directions of research and industrial implementation in this field are reported.
Hydrogen Impact: A Review on Diffusibility, Embrittlement Mechanisms, and Characterization
Feb 2024
Publication
Hydrogen embrittlement (HE) is a broadly recognized phenomenon in metallic materials. If not well understood and managed HE may lead to catastrophic environmental failures in vessels containing hydrogen such as pipelines and storage tanks. HE can affect the mechanical properties of materials such as ductility toughness and strength mainly through the interaction between metal defects and hydrogen. Various phenomena such as hydrogen adsorption hydrogen diffusion and hydrogen interactions with intrinsic trapping sites like dislocations voids grain boundaries and oxide/matrix interfaces are involved in this process. It is important to understand HE mechanisms to develop effective hydrogen resistant strategies. Tensile double cantilever beam bent beam and fatigue tests are among the most common techniques employed to study HE. This article reviews hydrogen diffusion behavior mechanisms and characterization techniques.
Integration of Air-cooled Multi-stack Polymer Electrolyte Fuel Cell Systems into Renewable Microgrids
May 2022
Publication
Currently there is a growing interest in increasing the power range of air-cooled fuel cells (ACFCs) as they are cheaper easier to use and maintain than water-cooled fuel cells (WCFCs). However air-cooled stacks are only available up to medium power (<10 kW). Therefore a good solution may be the development of ACFCs consisting of several stacks until the required power output is reached. This is the concept of air-cooled multi-stack fuel cell (AC-MSFC). The objective of this work is to develop a turnkey solution for the integration of AC-MSFCs in renewable microgrids specifically those with high-voltage DC (HVDC) bus. This is challenging because the AC-MSFCs must operate in the microgrid as a single ACFC with adjustable power depending on the number of stacks in operation. To achieve this the necessary power converter (ACFCs operate at low voltages so high conversion rates are required) and control loops must be developed. Unlike most designs in the literature the proposed solution is compact forming a system (AC-MSFCS) with a single input (hydrogen) and a single output (high voltage regulated power or voltage) that can be easily integrated into any microgrid and easily scalable depending on the power required. The developed AC-MSFCS integrates stacks balance of plant data acquisition and instrumentation power converters and local controllers. In addition a virtual instrument (VI)has been developed which connected to the energy management system (EMS) of the microgrid allows monitoring of the entire AC-MSFCS (operating temperature purging cell voltage monitoring for degradation evaluation stacks operating point control and alarm and event management) as well as serving as a user interface. This allows the EMS to know the degradation of each stack and to carry out energy distribution strategies or specific maintenance actions which improves efficiency lifespan and of course saves costs. The experimental results have been excellent in terms of the correct operation of the developed AC-MSFCS. Likewise the accumulated degradation of the stacks was quantified showing cells with a degradation of >80%. The excellent electrical and thermal performance of the developed power converter was also validated which allowed the correct and efficient supply of regulated power (average efficiency above 90%) to the HVDC bus according to the power setpoint defined by the EMS of the microgrid.
Hydrogen–Natural Gas Mix—A Viable Perspective for Environment and Society
Aug 2023
Publication
The increase in demand and thus the need to lower its price has kept C-based fuels as the main source. In this context the use of oil and gas has led to increased climate change resulting in greenhouse gases. The high percentage of emissions over 40% is due to the production of electricity heat or/and energy transport. This is the main reason for global warming and the extreme and increasingly common climate change occurrences with all of nature being affected. Due to this reason in more and more countries there is an increased interest in renewable energies from sustainable sources with a particular emphasis on decarbonisation. One of the energies analysed for decarbonisation that will play a role in future energy systems is hydrogen. The development of hydrogen–natural gas mixtures is a major challenge in the field of energy and fuel technology. This article aims to highlight the major challenges associated with researching hydrogen–natural gas blends. Meeting this challenge requires a comprehensive research and development effort including exploring appropriate blending techniques optimising performance addressing infrastructure requirements and considering regulatory considerations. Overcoming this challenge will enable the full potential of hydrogen–natural gas blends to be realised as a clean and sustainable energy source. This will contribute to the global transition to a greener and more sustainable future. Several international European and Romanian studies projects and legislative problems are being analysed. The mix between H2 and natural gas decreases fugitive emissions. In contrast using hydrogen increases the risk of fire more than using natural gas because hydrogen is a light gas that easily escapes and ignites at almost any concentration in the air.
Life Cycle Assessments Use in Hydrogen-related Policies: The Case for a Harmonized Methodology Addressing Multifunctionality
May 2024
Publication
Legislation regulating the sustainability requirements for hydrogen technologies relies more and more on life cycle assessments (LCAs). Due to different scopes and development processes different pieces of EU legislation refer to different LCA methodologies with differences in the way multifunctional processes (i.e. co-productions recycling and energy recovery) are treated. These inconsistencies arise because incentive mechanisms are not standardized across sectors even though the end product hydrogen remains the same. The goal of this paper is to compare the life-cycle greenhouse gas (GHG) emissions of hydrogen from four production pathways depending on the multifunctional approach prescribed by the different EU policies (e.g. using substitution or allocation). The study reveals a large variation in the LCA results. For instance the life-cycle GHG emissions of hydrogen co-produced with methanol is found to vary from 1 kg CO2-equivalent/kg H2 (when mass allocation is considered) to 11 kg CO2-equivalent/kg H2 (when economic allocation is used). These inconsistencies could affect the market (e.g. hydrogen from a certain pathway could be considered sustainable or unsustainable depending on the approach) and the environment (e.g. pathways that do not lead to a global emission reduction could be promoted). To mitigate these potential negative effects we urge for harmonized and strict guidelines to assess the life-cycle GHG emissions of hydrogen technologies in an EU policy context. Harmonization should cover international policies too to avoid the same risks when hydrogen will be traded based on its GHG emissions. The appropriate methodological approach for each production pathway should be chosen by policymakers in collaboration with the LCA community and stakeholders from the industry based on the potential market and environmental consequences of such choice.
Development of a Fuel Cell-based System for Refrigerated Transport
Nov 2012
Publication
Benchmark refrigerated systems in the road transportation sector are powered by diesel having operation costs of up to 6000 €/y. This paper presents the development of an alternative refrigeration system based on fuel cells with higher efficiency reduced costs and independent of diesel price fluctuations. Energy load profiles have been analyzed and the fuel cell stack and auxiliaries are being modeled in order to dimension and design a balance of plant and control algorithms that ensure a safe and easy utilization. Additionally a prototype shall be tested under different load profiles to validate the control strategies and to characterize the performance of the system.
Risky Business? Evaluating Hydrogen Partnerships Established by Germany, The Netherlands, and Belgium
Dec 2023
Publication
Following the introduction of the EU’s Hydrogen Strategy in 2020 as part of the European Green Deal some EU member states have deployed a very active hydrogen diplomacy. Germany The Netherlands and Belgium have been the most active ones establishing no less than 40 bilateral hydrogen trade partnerships with 30 potential export countries in the last three years. However concerns have been voiced about whether such hydrogen trade relationships can be economically feasible geopolitically wise environmentally sustainable and socially just. This article therefore evaluates these partnerships considering three risk dimensions: economic political and sustainability (covering both environmental and justice) risks. The analysis reveals that the selection of partner countries entails significant trade-offs. Four groups of partner countries can be identified based on their respective risk profile: “Last Resorts” “Volatile Ventures” “Strategic Gambits” and “Trusted Friends”. Strikingly less than one-third of the agreements are concluded with countries that fall within the “Trusted Friends” category which have the lowest overall risk profile. These findings show the need for policy makers to think much more strategically about which partnerships to pursue and to confront tough choices about which risks and trade-offs they are willing to accept.
Optimal Capacity Configuration of Wind–Solar Hydrogen Storage Microgrid Based on IDW-PSO
Aug 2023
Publication
Because the new energy is intermittent and uncertain it has an influence on the system’s output power stability. A hydrogen energy storage system is added to the system to create a wind light and hydrogen integrated energy system which increases the utilization rate of renewable energy while encouraging the consumption of renewable energy and lowering the rate of abandoning wind and light. Considering the system’s comprehensive operation cost economy power fluctuation and power shortage as the goal considering the relationship between power generation and load assigning charging and discharging commands to storage batteries and hydrogen energy storage and constructing a model for optimal capacity allocation of wind–hydrogen microgrid system. The optimal configuration model of the wind solar and hydrogen microgrid system capacity is constructed. A particle swarm optimization with dynamic adjustment of inertial weight (IDW-PSO) is proposed to solve the optimal allocation scheme of the model in order to achieve the optimal allocation of energy storage capacity in a wind–hydrogen storage microgrid. Finally a microgrid system in Beijing is taken as an example for simulation and solution and the results demonstrate that the proposed approach has the characteristics to optimize the economy and improve the capacity of renewable energy consumption realize the inhibition of the fluctuations of power reduce system power shortage and accelerate the convergence speed.
Effects of Surface Modification on a Proton Exchange Membrane for Improvements in Green Hydrogen Production
Oct 2023
Publication
Proton Exchange Membrane (PEM) electrolysis an advanced technique for producing hydrogen with efficiency and environmental friendliness signifies the forefront of progress in this domain. Compared to alkaline cells these electrolytic cells offer numerous advantages such as lower operating temperatures enhanced hydrogen production efficiency and eliminating the need for an aqueous solution. However PEM electrolysis still faces limitations due to the high cost of materials used for the membrane and catalysts resulting in elevated expenses for implementing large-scale systems. The pivotal factor in improving PEM electrolysis lies in the Platinum catalyst present on the membrane surface. Enhancing catalytic efficiency through various methods and advancements holds immense significance for the progress of this technology. This study investigates the use of patterned membranes to improve the performance of PEM electrolytic cells toward green hydrogen production. By increasing the Platinum loading across the membrane surface and enhancing catalytic performance these patterned membranes overcome challenges faced by conventionally fabricated counterparts. The findings of this research indicate that membranes with modified surfaces not only exhibit higher current draw but also achieve elevated rates of hydrogen production.
Multi-criteria Site Selection Workflow for Geological Storage of Hydrogen in Depleted Gas Fields: A Case for the UK
Oct 2023
Publication
Underground hydrogen storage (UHS) plays a critical role in ensuring the stability and security of the future clean energy supply. However the efficiency and reliability of UHS technology depend heavily on the careful and criteria-driven selection of suitable storage sites. This study presents a hybrid multi-criteria decision-making framework integrating the Analytical Hierarchy Process (AHP) and Preference Ranking Organisation Method for Enrichment of Evaluations (PROMETHEE) to identify and select the best hydrogen storage sites among depleted gas reservoirs in the UK. To achieve this a new set of site selection criteria is proposed in light of the technical and economic aspects of UHS including location reservoir rock quality and tectonic characteristics maximum achievable hydrogen well deliverability rate working gas capacity cushion gas volume requirement distance to future potential hydrogen clusters and access to intermittent renewable energy sources (RESs). The framework is implemented to rank 71 reservoirs based on their potential and suitability for UHS. Firstly the reservoirs are thoroughly evaluated for each proposed criterion and then the AHP-PROMETHEE technique is employed to prioritise the criteria and rank the storage sites. The study reveals that the total calculated working gas capacity based on single-well plateau withdrawal rates is around 881 TWh across all evaluated reservoirs. The maximum well deliverability rates for hydrogen withdrawal are found to vary considerably among the sites; however 22 % are estimated to have deliverability rates exceeding 100 sm3 /d and 63 % are located within a distance of 100 km from a major hydrogen cluster. Moreover 70 % have access to nearby RESs developments with an estimated cumulative RESs capacity of approximately 181 GW. The results highlight the efficacy of the proposed multicriteria site selection framework. The top five highest-ranked sites for UHS based on the evaluated criteria are the Cygnus Hamilton Saltfleetby Corvette and Hatfield Moors gas fields. The insights provided by this study can contribute to informed decision-making sustainable development and the overall progress of future UHS projects within the UK and globally.
Comprehensive Review of Geomechanics of Underground Hydrogen Storage in Depleted Reservoirs and Salt Caverns
Sep 2023
Publication
Hydrogen is a promising energy carrier for a low-carbon future energy system as it can be stored on a megaton scale (equivalent to TWh of energy) in subsurface reservoirs. However safe and efficient underground hydrogen storage requires a thorough understanding of the geomechanics of the host rock under fluid pressure fluctuations. In this context we summarize the current state of knowledge regarding geomechanics relevant to carbon dioxide and natural gas storage in salt caverns and depleted reservoirs. We further elaborate on how this knowledge can be applied to underground hydrogen storage. The primary focus lies on the mechanical response of rocks under cyclic hydrogen injection and production fault reactivation the impact of hydrogen on rock properties and other associated risks and challenges. In addition we discuss wellbore integrity from the perspective of underground hydrogen storage. The paper provides insights into the history of energy storage laboratory scale experiments and analytical and simulation studies at the field scale. We also emphasize the current knowledge gaps and the necessity to enhance our understanding of the geomechanical aspects of hydrogen storage. This involves developing predictive models coupled with laboratory scale and field-scale testing along with benchmarking methodologies.
Underground Storage of Hydrogen and Hydrogen/methane Mixtures in Porous Reservoirs: Influence of Reservoir Factors and Engineering Choices on Deliverability and Storage Operations
Jul 2023
Publication
Seasonal storage of natural gas (NG) which primarily consists of methane (CH4) has been practiced for more than a hundred years at underground gas storage (UGS) facilities that use depleted hydrocarbon reservoirs saline aquifers and salt caverns. To support a transition to a hydrogen (H2) economy similar facilities are envisioned for long-duration underground H2 storage (UHS) of either H2 or H2/CH4 mixtures. Experience with UGS can be used to guide the deployment of UHS so we identify and quantify factors (formation/fluid properties and engineering choices) that influence reservoir behavior (e.g. viscous fingering and gravity override) the required number of injection/withdrawal wells and required storage volume contrasting the differences between the storage of CH4 H2 and H2/CH4 mixtures. The most important engineering choices are found to be the H2 fraction in H2/CH4 mixtures storage depth and injection rate. Storage at greater depths (higher pressure) but with relatively lower temperature is more favorable because it maximizes volumetric energy-storage density while minimizing viscous fingering and gravity override due to buoyancy. To store an equivalent amount of energy storing H2/CH4 mixtures in UHS facilities will require more wells and greater reservoir volume than corresponding UGS facilities. We use our findings to make recommendations about further research needed to guide deployment of UHS in porous reservoirs.
Plastic and Waste Tire Pyrolysis Focused on Hydrogen Production—A Review
Dec 2022
Publication
In this review we compare hydrogen production from waste by pyrolysis and bioprocesses. In contrast the pyrolysis feed was limited to plastic and tire waste unlikely to be utilized by biological decomposition methods. Recent risks of pyrolysis such as pollutant emissions during the heat decomposition of polymers and high energy demands were described and compared to thresholds of bioprocesses such as dark fermentation. Many pyrolysis reactors have been adapted for plastic pyrolysis after successful investigation experiences involving waste tires. Pyrolysis can transform these wastes into other petroleum products for reuse or for energy carriers such as hydrogen. Plastic and tire pyrolysis is part of an alternative synthesis method for smart polymers including semi-conductive polymers. Pyrolysis is less expensive than gasification and requires a lower energy demand with lower emissions of hazardous pollutants. Short-time utilization of these wastes without the emission of metals into the environment can be solved using pyrolysis. Plastic wastes after pyrolysis produce up to 20 times more hydrogen than dark fermentation from 1 kg of waste. The research summarizes recent achievements in plastic and tire waste pyrolysis development.
CFD Modeling and Experimental Validation of an Alkaline Water Electrolysis Cell for Hydrogen Production
Dec 2020
Publication
Although alkaline water electrolysis (AWE) is the most widespread technology for hydrogen production by electrolysis its electrochemical and fluid dynamic optimization has rarely been addressed simultaneously using Computational Fluid Dynamics (CFD) simulation. In this regard a two-dimensional (2D) CFD model of an AWE cell has been developed using COMSOL® software and then experimentally validated. The model involves transport equations for both liquid and gas phases as well as equations for the electric current conservation. This multiphysics approach allows the model to simultaneously analyze the fluid dynamic and electrochemical phenomena involved in an electrolysis cell. The electrical response was evaluated in terms of polarization curve (voltage vs. current density) at different operating conditions: temperature electrolyte conductivity and electrode-diaphragm distance. For all cases the model fits very well with the experimental data with an error of less than 1% for the polarization curves. Moreover the model successfully simulates the changes on gas profiles along the cell according to current density electrolyte flow rate and electrode-diaphragm distance. The combination of electrochemical and fluid dynamics studies provides comprehensive information and makes the model a promising tool for electrolysis cell design.
Towards Energy Freedom: Exploring Sustainable Solutions for Energy Independence and Self-sufficiency using Integrated Renewable Energy-driven Hydrogen System
Jan 2024
Publication
n the pursuit of sustainable energy solutions the integration of renewable energy sources and hydrogen technologies has emerged as a promising avenue. This paper introduces the Integrated Renewable Energy-Driven Hydrogen System as a holistic approach to achieve energy independence and self-sufficiency. Seamlessly integrating renewable energy sources hydrogen production storage and utilization this system enables diverse applications across various sectors. By harnessing solar and/or wind energy the Integrated Renewable EnergyDriven Hydrogen System optimizes energy generation distribution and storage. Employing a systematic methodology the paper thoroughly examines the advantages of this integrated system over other alternatives emphasizing its zero greenhouse gas emissions versatility energy resilience and potential for large-scale hydrogen production. Thus the proposed system sets our study apart offering a distinct and efficient alternative compared to conventional approaches. Recent advancements and challenges in hydrogen energy are also discussed highlighting increasing public awareness and technological progress. Findings reveal a payback period ranging from 2.8 to 6.7 years depending on the renewable energy configuration emphasizing the economic attractiveness and potential return on investment. This research significantly contributes to the ongoing discourse on renewable energy integration and underscores the viability of the Integrated Renewable EnergyDriven Hydrogen System as a transformative solution for achieving energy independence. The employed model is innovative and transferable to other contexts.
Lessons Learned and Recommendations from Analysis of Hydrogen Incidents and Accidents to Support Risk Assessment for the Hydrogen Economy
Feb 2024
Publication
This study addresses challenges associated with hydrogen’s physio-chemical characteristics and the need for safety and public acceptance as a precursor to the emerging hydrogen economy. It highlights the gap in existing literature regarding lessons learned from events in the green hydrogen production value chain. The study aims to use the documented lessons learned from previous hydrogen-related events to assist in enhancing safety measures and to guide stakeholders on how to avoid and mitigate future hydrogen-related events. Given the potential catastrophic consequences robust safety systems are essential for hydrogen economy development. The work underscores the importance of human and operational factors as root causes of these events. The paper recommends establishing a specialized hydrogen-related event database to support risk assessment and risk mitigation thus catering to the growing hydrogen industry’s needs and facilitating quick access to critical information for stakeholders in the private and public sectors.
Industrial Development Status and Prospects of the Marine Fuel Cell: A Review
Jan 2023
Publication
In the context of the increasingly strict pollutant emission regulations and carbon emission reduction targets proposed by the International Maritime Organization the shipping industry is seeking new types of marine power plants with the advantages of high efficiency and low emissions. Among the possible alternatives the fuel cell is considered to be the most practical technology as it provides an efficient means to generate electricity with low pollutant emissions and carbon emissions. Very few comprehensive reviews focus on the maritime applications of the fuel cell. Thus news reports and literature on the maritime applications of the fuel cell in the past sixty years were collected and the industrial development status and prospects of the marine fuel cell were summarized as follows. Some countries in Europe North America and Asia have invested heavily in researching and developing the marine fuel cell and a series of research projects have achieved concrete results such as the industrialized marine fuel cell system or practical demonstration applications. At present the worldwide research of the marine fuel cell focuses more on the proton exchange membrane fuel cell (PEMFC). However the power demand of the marine fuel cell in the future will show steady growth and thus the solid oxide fuel cell (SOFC) with the advantages of higher power and fuel diversity will be the mainstream in the next research stage. Although some challenges exist the SOFC can certainly lead the upgrading and updating of the marine power system with the cooperative efforts of the whole world.
Roles of Bioenergy and Green Hydrogen in Large Scale Energy Storage for Carbon Neutrality
Aug 2023
Publication
A new technical route to incorporate excess electricity (via green hydrogen generation by electrolysis) into a biorefinery to produce modern bioenergy (advanced biofuels) is proposed as a promising alternative. This new route involves storing hydrogen for mobile and stationary applications and can be a three-bird-one-stone solution for the storage of excess electrical energy storage of green hydrogen and high-value utilization of biomass.
Multiperiod Modeling and Optimization of Hydrogen-Based Dense Energy Carrier Supply Chains
Feb 2024
Publication
The production of hydrogen-based dense energy carriers (DECs) has been proposed as a combined solution for the storage and dispatch of power generated through intermittent renewables. Frameworks that model and optimize the production storage and dispatch of generated energy are important for data-driven decision making in the energy systems space. The proposed multiperiod framework considers the evolution of technology costs under different levels of promotion through research and targeted policies using the year 2021 as a baseline. Furthermore carbon credits are included as proposed by the 45Q tax amendment for the capture sequestration and utilization of carbon. The implementation of the mixed-integer linear programming (MILP) framework is illustrated through computational case studies to meet set hydrogen demands. The trade-offs between different technology pathways and contributions to system expenditure are elucidated and promising configurations and technology niches are identified. It is found that while carbon credits can subsidize carbon capture utilization and sequestration (CCUS) pathways substantial reductions in the cost of novel processes are needed to compete with extant technology pathways. Further research and policy push can reduce the levelized cost of hydrogen (LCOH) by upwards of 2 USD/kg.
Experimental Investigation of Fluid-structure Interaction in the Case of Hydrogen/Air Detonation Impacting a Thin Plate
Sep 2023
Publication
In recent years the use and development of hydrogen as a carbon-free energy carrier have grown. However as hydrogen is flammable with air safety issues are raised. In the case of ignition especially in confined space the flame can accelerate and reach the detonation regime causing severe structural damage [1].<br/>To assess these safety issues it is required to understand the fluid-structure interaction in the case of a detonation impacting a deformable structure and to quantify and model this interaction [2]. At the CEA (Commissariat à l’énergie atomique et aux energies alternatives) a combustion tube experimental facility [3] for studying the fluid-structure interaction in the case of hydrogen combustion has been developed. Several Photomultipliers and Pressure sensors are placed along the tube to monitor the flame acceleration and the detonation location. A fluid-structure interaction (FSI) module or a non-deformable flange can be placed at the end of the tube. Post-processing of the sensor’s signal will provide insight into the occurring phenomena inside the tube.<br/>Several experimental campaigns have been conducted with various initial conditions and configurations at the end of the tube. In this contribution the experiments resulting in a detonation are presented. First the recorded pressure and velocities will be compared to theoretical values coming from combustion models [4] [5]. Secondly the impulse before and after reflection for thin plate and non-deformable flange will be compared to quantify the energy transmitted to the plate and the influence of the fluid-structure interaction on the reflected shock.
Renewable Energy Sources for Green Hydrogen Generation in Colombia and Applicable Case of Studies
Nov 2023
Publication
Electrification using renewable energy sources represents a clear path toward solving the current global energy crisis. In Colombia this challenge also involves the diversification of the electrical energy sources to overcome the historical dependence on hydropower. In this context green hydrogen represents a key energy carrier enabling the storage of renewable energy as well as directly powering industrial and transportation sectors. This work explores the realistic potential of the main renewable energy sources including solar photovoltaics (8172 GW) hydropower (56 GW) wind (68 GW) and biomass (14 GW). In addition a case study from abroad is presented demonstrating the feasibility of using each type of renewable energy to generate green hydrogen in the country. At the end an analysis of the most likely regions in the country and paths to deploy green hydrogen projects are presented favoring hydropower in the short term and solar in the long run. By 2050 this energy potential will enable reaching a levelized cost of hydrogen (LCOH) of 1.7 1.5 3.1 and 1.4 USD/kg-H2 for solar photovoltaic wind hydropower and biomass respectively.
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