United Kingdom
Life Cycle Assessment of an Autonomous Underwater Vehicle that Employs Hydrogen Fuel Cell
Aug 2023
Publication
In recent years there has been a significant increase in the adoption of autonomous vehicles for marine and submarine missions. The advancement of emerging imaging navigation and communication technologies has greatly expanded the range of operational capabilities and opportunities available. The ENDURUNS project is a European research endeavor focused on identifying strategies for achieving minimal environmental impact. To measure these facts this article evaluates the product impacts employing the Life Cycle Assessment methodology for the first time following the ISO 14040 standard. In this analysis the quantitative values of Damage and Environmental Impact using the Eco-Indicator 99 methodology in SimaPro software are presented. The results report that the main contributors in environmental impact terms have been placed during the manufacturing phase. Thus one of the challenges is accomplished avoiding the use phase emissions that are the focus to reduce nowadays in the marine industry.
Above-ground Hydrogen Storage: A State-of-the-art Review
Nov 2024
Publication
Hydrogen is increasingly recognized as a clean energy alternative offering effective storage solutions for widespread adoption. Advancements in storage electrolysis and fuel cell technologies position hydrogen as a pathway toward cleaner more efficient and resilient energy solutions across various sectors. However challenges like infrastructure development cost-effectiveness and system integration must be addressed. This review comprehensively examines above-ground hydrogen storage technologies and their applications. It highlights the importance of established hydrogen fuel cell infrastructure particularly in gaseous and LH2 systems. The review favors material-based storage for medium- and long-term needs addressing challenges like adverse thermodynamics and kinetics for metal hydrides. It explores hydrogen storage applications in mobile and stationary sectors including fuel-cell electric vehicles aviation maritime power generation systems off-grid stations power backups and combined renewable energy systems. The paper underscores hydrogen’s potential to revolutionize stationary applications and co-generation systems highlighting its significant role in future energy landscapes.
Net Zero Fuel (Mixed Hydrogen and Biofuels) Cement Clinker: Characterisation, Microstructure, and Performance
Oct 2024
Publication
Over 35% of the CO2 associated with cement production comes from operational energy. The cement industry needs alternative fuels to meet its net zero emissions target. This study investigated the influence of hydrogen mixed with biofuels herein designated net zero fuel as an alternative to coal on the clinker quality and performance of cement produced in an industrial cement plant. Scanning electron microscopy X-ray diffraction and nuclear magnetic resonance were coupled to study the clinker mineralogy and polymorphs. Hydration and microstructure development in plain and slag blended cements based on the clinker were compared to commercial cement equivalent. The results revealed a lower alite/belite ratio but a significant proportion of the belite was of the α’H-C2S polymorph. These reacted faster and compensated for the alite/belite ratio. Gel and micro-capillary pores were densified which reduced total porosity and attained comparable strength to the reference plain and blended cement. This study demonstrates that the investigated net zero fuel-produced clinker meets compositional and strength requirements for plain and blended cement providing a feasible pathway for the cement industry to lower its operational carbon significantly.
Whole System Impacts of Decarbonising Transport with Hydrogen: A Swedish Case Study
Oct 2024
Publication
This study aims to carry out a techno-economic analysis of different hydrogen supply chain designs coupled with the Swedish electricity system to study the inter-dependencies between them. Both the hydrogen supply chain designs and the electricity system were parameterized with data for 2030. The supply chain designs comprehend centralised production decentralised production a combination of both and with/without seasonal variation in hydrogen demand. The supply chain design is modelled to minimize the overall cost while meeting the hydrogen demands. The outputs of the supply chain model include the hydrogen refuelling stations’ locations the electrolyser’s locations and their respective sizes as well as the operational schedule. The electricity system model shows that the average electricity prices in Sweden for zones SE1 SE2 SE3 and SE4 will be 4.28 1.88 8.21 and 8.19 €/MWh respectively. The electricity is mainly generated from wind and hydropower (around 42% each) followed by nuclear (14%) solar (2%) and then bio-energy (0.3%). In addition the hydrogen supply chain design that leads to a lower overall cost is the decentralised design with a cost of 1.48 and 1.68 €/kgH2 in scenarios without and with seasonal variation respectively. The seasonal variation in hydrogen demand increases the cost of hydrogen regardless of the supply chain design.
Design Considerations and Preliminary Hydrodynamic Analysis of an Offshore Decentralised Floating Wind-hydrogen System
Sep 2024
Publication
Despite the number of works on the techno-economics of offshore green hydrogen production there is a lack of research on the design of floating platforms to concomitantly support hydrogen production facilities and wind power generation equipment. Indeed previous studies on offshore decentralised configuration for hydrogen production implicitly assume that a floating platform designed for wind power generation (FOWT) can be also suitable as a floating wind hydrogen system (FWHS). This work proposes a novel design for an offshore decentralised FWHS and analyses the effects of the integration of the hydrogen facilities on the platform’s dynamics and how this in turn affects the performances of the wind turbine and the hydrogen equipment. Our findings indicate that despite the reduction in platform’s stability the performance of the wind turbine is barely affected. Regarding the hydrogen system our results aim at contributing to further assessment and design of this equipment for offshore conditions.
Hydrogen UK Manifesto
Jul 2024
Publication
Hydrogen presents the UK with a substantial opportunity to drive economic growth and secure skilled jobs by leveraging our natural geological and geographical advantages robust supply chain and existing energy expertise. Hydrogen UK’s most recent Economic Impact Assessment estimates that the hydrogen sector in the UK could support approximately 30000 direct jobs and contribute more than £7 billion gross value added annually by 2030. On a global scale the hydrogen market is projected to be worth $2.5 trillion by 2050.
With international competition increasing the UK must act now to capitalise on this potential. These projections are supported by a recognition that hydrogen is one of the key solutions to decarbonising the UK economy complementing other low-carbon solutions such as electrification carbon capture biofuels and energy efficiency. Additionally hydrogen will play a vital role in enhancing the UK’s energy security by storing domestically produced energy to balance intermittent renewable sources like wind and solar. As a critical component of the clean energy transition hydrogen is indispensable to achieving net zero.
As it stands the UK is well placed to capitalise on the hydrogen opportunity and emerge as a global leader. We have made early strides in establishing a framework for hydrogen development with various pilot projects and strategic investments already underway. However the next five years will be critical for the sector as we move from strategy and planning to development and delivery. It is imperative to get the first lowcarbon production projects over the line and into construction as a matter of urgency and then deliver substantial infrastructure development regulatory clarity and sustained financial support to scale-up production and distribution. A new Government presents an opportunity for policymakers to solidify commitments and accelerate the deployment of hydrogen technology ensuring the UK remains competitive in the global race.
Our manifesto outlines policy recommendations for the new UK Government to take across production distribution and storage infrastructure end use applications trade and beyond which will support a thriving British industrial base that creates jobs and growth for British people. To achieve this the UK hydrogen industry calls on policymakers to speed up the deployment of hydrogen through the recommendations set out in this Manifesto.
This report can be found on Hydrogen UK's website.
With international competition increasing the UK must act now to capitalise on this potential. These projections are supported by a recognition that hydrogen is one of the key solutions to decarbonising the UK economy complementing other low-carbon solutions such as electrification carbon capture biofuels and energy efficiency. Additionally hydrogen will play a vital role in enhancing the UK’s energy security by storing domestically produced energy to balance intermittent renewable sources like wind and solar. As a critical component of the clean energy transition hydrogen is indispensable to achieving net zero.
As it stands the UK is well placed to capitalise on the hydrogen opportunity and emerge as a global leader. We have made early strides in establishing a framework for hydrogen development with various pilot projects and strategic investments already underway. However the next five years will be critical for the sector as we move from strategy and planning to development and delivery. It is imperative to get the first lowcarbon production projects over the line and into construction as a matter of urgency and then deliver substantial infrastructure development regulatory clarity and sustained financial support to scale-up production and distribution. A new Government presents an opportunity for policymakers to solidify commitments and accelerate the deployment of hydrogen technology ensuring the UK remains competitive in the global race.
Our manifesto outlines policy recommendations for the new UK Government to take across production distribution and storage infrastructure end use applications trade and beyond which will support a thriving British industrial base that creates jobs and growth for British people. To achieve this the UK hydrogen industry calls on policymakers to speed up the deployment of hydrogen through the recommendations set out in this Manifesto.
This report can be found on Hydrogen UK's website.
Hydrogen UK Supply Chains Report Executive Summary 2023
Dec 2023
Publication
The strategic importance of hydrogen has gained significant recognition as nations across the world have committed to achieving net zero. Here in the UK there’s a widespread consensus that hydrogen is critical to achieving our net zero target. This commitment culminated in the launch of the UK’s first Hydrogen Strategy and has been reaffirmed by Chris Skidmore’s Independent Review of Net Zero. Both these documents highlight hydrogen’s importance not only to net zero but growing the UK industrial base1 . Analysis by Hydrogen UK estimates up to 20000 jobs could be created by 2030 contributing £26bn in cumulative GVA2. These economic benefits flow from all areas of the value chain ranging from production storage network development and off-taker markets. However with large scale projects still to take final investment decisions current volumes of low-carbon hydrogen produced and consumed fall well below the government’s 2030 ambitions. Encouragingly the UK has a positive track record of deploying low carbon technologies. The combination of the UK’s world leading policies and incentive schemes alongside our vibrant RD&I and engineering environment has enabled rapid deployment of technologies like offshore wind and electric vehicles. Yet despite being world leaders in deployment early opportunities for regional supply chain growth and job creation were not fully realised and taken advantage of from inception. The hydrogen sector is therefore at a tipping point. To capitalise on the economic opportunity hydrogen offers the UK must learn from prior technology deployments and build a strong domestic hydrogen supply chain in parallel to championing deployment. This report delivers on a recommendation from the Hydrogen Champion Report which encouraged industry to create an industry led supply chain strategy3 . With Hydrogen UK steering the work on behalf of the UK hydrogen industry this study focusses on identifying the actions needed to mature a local supply chain that can support the initial deployment of hydrogen technologies across the value chain. The report is segmented into two sections. The first section outlines a voluntary ambition for local content from industry alongside the potential intervention mechanisms needed to achieve the ambition. The second section exploresthe challenges companies across the hydrogen value chain face in maximising UK supply chain opportunities.
This report can be found on Hydrogen UK's website.
This report can be found on Hydrogen UK's website.
Computational Predictions of Hydrogen-assisted Fatigue Crack Growth
May 2024
Publication
A new model is presented to predict hydrogen-assisted fatigue. The model combines a phase field description of fracture and fatigue stress-assisted hydrogen diffusion and a toughness degradation formulation with cyclic and hydrogen contributions. Hydrogen-assisted fatigue crack growth predictions exhibit an excellent agreement with experiments over all the scenarios considered spanning multiple load ratios H2 pressures and loading frequencies. These are obtained without any calibration with hydrogen-assisted fatigue data taking as input only mechanical and hydrogen transport material properties the material’s fatigue characteristics (from a single test in air) and the sensitivity of fracture toughness to hydrogen content. Furthermore the model is used to determine: (i) what are suitable test loading frequencies to obtain conservative data and (ii) the underestimation made when not pre-charging samples. The model can handle both laboratory specimens and large-scale engineering components enabling the Virtual Testing paradigm in infrastructure exposed to hydrogen environments and cyclic loading.
Exploiting the Ocean Thermal Energy Conversion (OTEC) Technology for Green Hydrogen Production and Storage: Exergo-economic Analysis
Nov 2024
Publication
This study presents and analyses three plant configurations of the Ocean Thermal Energy Conversion (OTEC) technology. All the solutions are based on using the OTEC system to obtain hydrogen through an electrolyzer. The hydrogen is then compressed and stored. In the first and second layouts a Rankine cycle with ammonia and a mixture of water and ethanol is utilised respectively; in the third layout a Kalina cycle is considered. In each configuration the OTEC cycle is coupled with a polymer electrolyte membrane (PEM) electrolyzer and the compression and storage system. The water entering the electrolyzer is pre-heated to 80 ◦C by a solar collector. Energy exergy and exergo-economic studies were conducted to evaluate the cost of producing compressing and storing hydrogen. A parametric analysis examining the main design constraints was performed based on the temperature range of the condenser the mass flow ratio of hot and cold resource flows and the mass fraction. The maximum value of the overall exergy efficiency calculated is equal to 93.5% for the Kalina cycle and 0.524 €/kWh is the minimum cost of hydrogen production achieved. The results were compared with typical data from other hydrogen production systems.
The Latest Voyage of Discovery - Quantifying the Consequences of LH2 Releases for the Marine Industry
Sep 2023
Publication
Following a desktop study undertaken in 2021 to identify hazard scenarios associated with the use of liquid and compressed hydrogen on commercial shipping Shell has started a programme of large-scale experiments on the consequences of a release of liquid hydrogen. This work will compliment on-going research Shell has sponsored within several joint industry projects but will also address immediate concerns that the maritime industry has for the transportation of liquid hydrogen (LH2). This paper will describe the first phase of experiments involving the release of LH2 onto various substrates as well as dispersion across an instrumented test pad. These results will be used to address the following uncertainties in risk assessments within the hydrogen economy such as (1) Quantify the impact of low wind speed and high humidity on the buoyancy of both a passive and momentum jet dispersion cloud (2) Gather additional data on liquid hydrogen jet fires (3) Understand the likelihood for the formation of a sustained pool of hydrogen (4) Characterise materials especially passive fire protective coatings that are exposed to LH2. Not only will these experiments generate validation data to provide confidence in the Shell consequence tool FRED but they will also be used by Shell to support updates and new regulations developed by the International Maritime Organisation as it seeks to reduce CO2 intensity in the maritime industry.
The Economical Repurposing Pipeliness to Hydrogen - Why Performance Testing of Representative Line Pipes is Key?
Sep 2023
Publication
The introduction of hydrogen in natural gas pipeline systems introduces integrity challenges due to the nature of interactions between hydrogen and line pipe steel materials. However not every natural gas pipeline is equal in regards to the challenges potentially posed by the repurposing to hydrogen. Existing codes and practices penalise high-grade materials on the basis of a perceived higher susceptibility to hydrogen embrittlement in regards to their increased strength. This philosophy challenges the realisation of a hydrogen economy because it puts at economical and technical risk the conversion of almost half of the natural gas transmission systems in western countries.
The paper addresses the question whether pipe grade is actually a good proxy to strength and predictor to assess the performance of steel line pipes in hydrogen. Drivers that could affect the suitability of pipeline conversion in hydrogen from an integrity management perspective and industry experience of other hydrogen-charging applications are reviewed. In doing so the paper challenges the basis of the assumption that low-grade steels (up to X52 / L360) are automatically safer for hydrogen repurposing while at the other end of the spectrum higher-grade materials (>X52 / L360) are inevitably less suitable for hydrogen service.
Ultimately the paper discusses that materials sampling and testing of representative line pipes populations should be placed at the core of hydrogen repurposing strategies in order to safely address conversion and to maximize the hydrogen chain value. The paper addresses alternatives to make the sampling smart and cost-effective.
The paper addresses the question whether pipe grade is actually a good proxy to strength and predictor to assess the performance of steel line pipes in hydrogen. Drivers that could affect the suitability of pipeline conversion in hydrogen from an integrity management perspective and industry experience of other hydrogen-charging applications are reviewed. In doing so the paper challenges the basis of the assumption that low-grade steels (up to X52 / L360) are automatically safer for hydrogen repurposing while at the other end of the spectrum higher-grade materials (>X52 / L360) are inevitably less suitable for hydrogen service.
Ultimately the paper discusses that materials sampling and testing of representative line pipes populations should be placed at the core of hydrogen repurposing strategies in order to safely address conversion and to maximize the hydrogen chain value. The paper addresses alternatives to make the sampling smart and cost-effective.
Advancing Hydrogen: A Closer Look at Implementation Factors, Current Status and Future Potential
Dec 2023
Publication
This review article provides a comprehensive analysis of the hydrogen landscape outlining the imperative for enhanced hydrogen production implementation and utilisation. It places the question of how to accelerate hydrogen adoption within the broader context of sustainable energy transitions and international commitments to reduce carbon emissions. It discusses influencing factors and policies for best practices in hydrogen energy application. Through an in-depth exploration of key factors affecting hydrogen implementation this study provides insights into the complex interplay of both technical and logistical factors. It also discusses the challenges of planning constructing infrastructure and overcoming geographical constraints in the transition to hydrogen-based energy systems. The drive to achieve net-zero carbon emissions is contingent on accelerating clean hydrogen development with blue and green hydrogen poised to complement traditional fuels. Public–private partnerships are emerging as catalysts for the commercialisation of hydrogen and fuel-cell technologies fostering hydrogen demonstration projects worldwide. The anticipated integration of clean hydrogen into various sectors in the coming years signifies its importance as a complementary energy source although specific applications across industries remain undefined. The paper provides a good reference on the gradual integration of hydrogen into the energy landscape marking a significant step forward toward a cleaner greener future.
Ignition and Flow Stopping Considerations for the Transmission of Hydrogen in the Existing Natural Gas Network
Sep 2023
Publication
This work formed part of the H21 programme whose objective is to reach the point whereby it is feasible to convert the existing natural gas (NG) distribution network to 100% hydrogen (H2) and provide a contribution to decarbonising the UK’s heat and power sectors with the focus on decarbonised fuel at point of use. Hydrogen has an ATEX Gas Group of IIC compared to IIA for natural gas which means further precautions are necessary to prevent the ignition of hydrogen during network operations. Both electrostatic and friction ignition risks were considered. Network operations considered include electrostatic precautions for polyethylene (PE) pipe and cutting and drilling of metallic pipes. As a result of the updated basis of safety from ignition considerations existing flow stopping methods were reviewed to see if they were compatible. Commonly used flow stopping methods were tested under laboratory conditions with hydrogen following the methodologies specified in the Gas Industry Standards (GIS). A new basis of safety for flow stopping has been proposed that looks at the flow past the secondary stop as double isolations are recommended for use with hydrogen.
Explaining Varying Speeds of Low-carbon Reorientation in the United Kingdom's Steel, Petrochemical, and Oil Refining Industries: A Multi-dimensional Comparative Analysis and Outlook
Feb 2024
Publication
Accelerated decarbonisation of steelmaking oil refining and petrochemical industries is essential for climate change mitigation. Drawing on three longitudinal case studies of these industries in the UK this synthesis article makes a comparative analysis of their varying low-carbon reorientation speeds. The paper uses the triple embeddedness framework to analyse five factors (policy support international competition financial health technical feasibility corporate strategy and mindset) that explain why UK oil refineries have in recent years been comparatively the fastest in their low-carbon reorientation and UK steelmakers the slowest. We find that policy support has been more beneficial for refining and petrochemicals than for steel although recent government deals with steelmakers addressed this imbalance. International competition has been high for steel and petrochemicals and comparatively lower for refining (meaning that decarbonisation costs are less detrimental for international competitiveness). Financial performance has comparatively been worst for steel and best for oil refining which shapes the economic feasibility of low-carbon options. Hydrogen and carbon-capture-and-storage are technologically feasible for refining and petrochemicals while Electric Arc Furnaces are technically feasible for steelmakers but face wider feasibility problems (with scrap steel supply electricity grids and electricity prices) which is why we question the recent government deals. Corporate strategy and perceptions changed in oil refining with firms seeing economic opportunities in decarbonisation while steelmakers and petrochemical firms still mostly see decarbonisation as a burden and threat. The paper ends with comparative conclusions a discussion of political considerations and future outlooks for the three UK industries policy and research.
Optimizing Underground Hydrogen Storage in Aquifers: The Impact of Cushion Gas Type
Aug 2023
Publication
This study investigated the impact of cushion gas type and presence on the performance of underground hydrogen storage (UHS) in an offshore North Sea aquifer. Using numerical simulation the relationship between cushion gas type and UHS performance was comprehensively evaluated providing valuable insights for designing an efficient UHS project delivery. Results indicated that cushion gas type can significantly impact the process's recovery efficiency and hydrogen purity. CO2 was found to have the highest storage capacity while lighter gases like N2 and CH4 exhibited better recovery efficiency. Utilising CH4 as a cushion gas can lead to a higher recovery efficiency of 80%. It was also determined that utilising either of these cushion gases was always more beneficial than hydrogen storage alone leading to an incremental hydrogen recovery up to 7%. Additionally hydrogen purity degraded as each cycle progressed but improved over time. This study contributes to a better understanding of factors affecting UHS performance and can inform the selection of cushion gas type and optimal operational strategies.
Numerical Simulations of the Critical Diameter and Flame Stability for the Hydrogen Jet Flames
Sep 2023
Publication
This study focuses on development of a CFD model able to simulate the experimentally observed critical nozzle diameter for hydrogen non-premixed flames. The critical diameter represents the minimum nozzle size through which a free jet flame will remain stable at all driving pressures. Hydrogen non-premixed flames will not blow-out at diameters equal to or greater than the critical diameter. Accurate simulation of this parameter is important for assessment of thermally activated pressure relief device (TPRD) performance during hydrogen blowdown from a storage tank. At TPRD diameters below the critical value there is potential for a hydrogen jet flame to blow-out as the storage tank vents potentially leading to hydrogen accumulation in an indoor release scenario. Previous experimental studies have indicated that the critical diameter for hydrogen is approximately 1 mm. In this study flame stability is considered across a range of diameters and overpressures from 0.1 mm to 2 mm and from 0.2 MPa to 20 MPa respectively. The impact of turbulent Schmidt number Sct which is the ratio of momentum diffusivity (kinematic viscosity) and mass diffusivity on the hydrogen concentration profile in the region near the nozzle exit and subsequent influence on critical diameter was investigated and discussed. For lower Sct values the enhanced mass mixing resulted in smaller predicted critical diameters. The use of value Sct=0.61 in the model demonstrated the best agreement with experimental values of the critical diameter. The model reproduced the critical diameter of 1 mm and then was applied to predict flame stability for under-expanded hydrogen jets.
Sudden Releases of Hydrogen into a Tunnel
Sep 2023
Publication
This paper presents work undertaken by the HSE as part of the Hytunnel-CS project a consortium investigating safety considerations for fuel cell hydrogen (FCH) vehicles in tunnels and similar confined spaces. The sudden failure of a pressurised hydrogen vessel was identified as a scenario of concern due to the severity of the consequences associated with such an event. In order to investigate this scenario experimentally HSE designed a bespoke and reusable ‘sudden release’ vessel. This paper presents an overview of the vessel and the results of a series of 13 tests whereby hydrogen was released from the bespoke vessel into a tunnel at pressures up to 65 MPa. The starting pressure and the volume of hydrogen in the vessel were altered throughout the campaign. Four of the tests also included congestion in the tunnel. The tests reliably autoignited. Overpressure measurements and flame arrival times measured with exposed-tip thermocouples enabled analysis of the severity of the events. A high-pressure fast-acting pressure transducer in the body of the vessel showed the pressure decay in the vessel which shows that 90% of the hydrogen was evacuated in between 1.8 and 3.2 ms (depending on the hydrogen inventory). Schlieren flow imagery was also used at the release point of the hydrogen showing the progression of the shock front following initiation of the tests. An assessment of the footage shows an estimated initial velocity of Mach 3.9 at 0.4 m from the release point. Based on this an ignition mechanism is proposed based upon the temperature behind the initial shock front.
Opportunities and Challenges of Hydrogen Ports: An Empirical Study in Australia and Japan
Jul 2024
Publication
This paper investigated the opportunities and challenges of integrating ports into hydrogen (H2 ) supply chains in the context of Australia and Japan because they are leading countries in the field and are potential leaders in the upcoming large-scale H2 trade. Qualitative interviews were conducted in the two countries to identify opportunities for H2 ports necessary infrastructure and facilities key factors for operations and challenges associated with the ports’ development followed by an online survey investigating the readiness levels of H2 export and import ports. The findings reveal that there are significant opportunities for both countries’ H2 ports and their respective regions which encompass business transition processes and decarbonisation. However the ports face challenges in areas including infrastructure training standards and social licence and the sufficiency and readiness levels of port infrastructure and other critical factors are low. Recommendations were proposed to address the challenges and barriers encountered by H2 ports. To optimise logistics operations within H2 ports and facilitate effective integration of H2 applications this paper developed a user-oriented working process framework to provide guidance to ports seeking to engage in the H2 economy. Its findings and recommendations contribute to filling the existing knowledge gap pertaining to H2 ports.
Emission Reduction and Cost-benefit Analysis of the Use of Ammonia and Green Hydrogen as Fuel for Marine Applications
Dec 2023
Publication
Increasingly stringent emission standards have led shippers and port operators to consider alternative energy sources which can reduce emissions while minimizing capital investment. It is essential to understand whether there is a certain economic investment gap for alternative energy. The present work mainly focuses on the simulation study of ships using ammonia and hydrogen fuels arriving at Guangzhou Port to investigate the emission advantages and cost-benefit analysis of ammonia and hydrogen as alternative fuels. By collecting actual data and fuel consumption emissions of ships arriving at Guangzhou Port the present study calculated the pollutant emissions and cost of ammonia and hydrogen fuels substitution. As expected it is shown that with the increase of NH3 in fuel mixed fuels will effectively reduce CO and CO2 emissions. Compared to conventional fuel the injection of NH3 increases the NOx emission. However the cost savings of ammonia fuel for CO2 SOx and PM10 reduction are higher than that for NOx. In terms of pollutants ammonia is less expensive than conventional fuels when applied to the Guangzhou Port. However the cost of fuel supply is still higher than conventional energy as ammonia has not yet formed a complete fuel supply and storage system for ships. On the other hand hydrogen is quite expensive to store and transport resulting in higher overall costs than ammonia and conventional fuels even if no pollutants are produced. At present conventional fuels still have advantage in terms of cost. With the promotion of ammonia fuel technology and application the cost of supply will be reduced. It is predicted that by 2035 ammonia will not only have emission reduction benefits but also will have a lower overall economic cost than conventional fuels. Hydrogen energy will need longer development and technological breakthroughs due to the limitation of storage conditions.
Resilience Assessment of Offshore Wind-to-Hydrogen Systems
Jul 2024
Publication
Low-cost green hydrogen production will be key in reaching net zero carbon emissions by 2050. Green hydrogen can be produced by electrolysis using renewable energy including wind energy. However the configuration of offshore wind-to-hydrogen systems is not yet standardised. For example electrolysis can take place onshore or offshore. This work presents a framework to assess and quantify which configuration is more resilient so that security of hydrogen supply is incorporated in strategic decisions with the following key findings. First resilience should be assessed according to hydrogen supply rather than hydrogen production. This allows the framework to be applicable for all identified system configurations. Second resilience can be quantified according to the quantity ratio and lost revenue of the unsupplied hydrogen.
Hydrogen UK Supply Chain Strategic Assessment
Sep 2024
Publication
Hydrogen offers the UK a unique opportunity to deliver on our Net Zero ambitions enabling deep decarbonisation of the parts of the energy system that are challenging to electrify balancing the energy system by providing large scale long duration energy storage and reducing pressure on electricity infrastructure. The UK Government in recognition of the centrality of hydrogen to the future energy system has set a 10GW hydrogen production ambition to be achieved by 2030. This ambition and its supporting policies such as the Hydrogen Business Model the Low Carbon Hydrogen Standard and the Hydrogen Transport and Storage Business Models will unlock private sector investment and kick-start the UK’s hydrogen activity. Encouragingly the UK has a positive track record of deploying low carbon technologies. The combination of the UK’s world leading policies and incentive schemes alongside a vibrant Research Development and Innovation (RD&I) and engineering environment has enabled rapid deployment of technologies such as offshore wind and electric vehicles. Yet despite being world leaders in deployment early opportunities for regional supply chain growth and job creation were not fully realised and taken advantage of from inception. The hydrogen sector is therefore at a tipping point. To capitalise on the economic opportunity hydrogen offers the UK must learn from prior technology deployments and build a strong domestic hydrogen supply chain in parallel to championing deployment.
Hydrogen is unique amongst low carbon technologies. It represents a significant economic opportunity with future hydrogen markets estimated by the Hydrogen Innovation Initiative to be worth $8tn and hydrogen technology markets estimated to reach $1tn by 20501 but crucially it is also still a nascent market. Unlike many other low carbon technologies where supply chains are already well established hydrogen supply chains are embryonic meaning that the UK has an opportunity to anchor these supply chains here and establish itself as a global leader.
The UK is well placed to capitalise on this opportunity with favourable geography and geology that enables us to produce and store hydrogen cost effectively coupled with a strong pipeline of hydrogen projects a stable policy environment that is attractive to investors and a wealth of transferable skills and expertise from the oil and gas industry.
We must ensure that alongside our focus on deployment we are also investing in technology and supply chains. Not only will this deliver exponential economic benefits from the projects supported by Government but it will also enable us to tackle increasing global supply chain constraints. Hydrogen UK estimated in its Economic Impact Assessment that hydrogen could deliver 30000 jobs annually and £7bn of GVA by 2030
It is important to be targeted and strategic in our investment and activities and recognise that hydrogen represents a wide range of technologies and the UK should not expect to lead in every area. Hydrogen UK with the support of the Hydrogen Delivery Council has undertaken analysis of the hydrogen value chain building on UK strengths and identifying the high value items that can deliver significant impact and benefit to the UK. We have also conducted widespread engagement with project developers to identify the barriers to utilising UK technology in projects and with technology developers to identify the challenges and barriers to investing and siting development and manufacturing in the UK.
The report can be found on Hydrogen UK's website.
Hydrogen is unique amongst low carbon technologies. It represents a significant economic opportunity with future hydrogen markets estimated by the Hydrogen Innovation Initiative to be worth $8tn and hydrogen technology markets estimated to reach $1tn by 20501 but crucially it is also still a nascent market. Unlike many other low carbon technologies where supply chains are already well established hydrogen supply chains are embryonic meaning that the UK has an opportunity to anchor these supply chains here and establish itself as a global leader.
The UK is well placed to capitalise on this opportunity with favourable geography and geology that enables us to produce and store hydrogen cost effectively coupled with a strong pipeline of hydrogen projects a stable policy environment that is attractive to investors and a wealth of transferable skills and expertise from the oil and gas industry.
We must ensure that alongside our focus on deployment we are also investing in technology and supply chains. Not only will this deliver exponential economic benefits from the projects supported by Government but it will also enable us to tackle increasing global supply chain constraints. Hydrogen UK estimated in its Economic Impact Assessment that hydrogen could deliver 30000 jobs annually and £7bn of GVA by 2030
It is important to be targeted and strategic in our investment and activities and recognise that hydrogen represents a wide range of technologies and the UK should not expect to lead in every area. Hydrogen UK with the support of the Hydrogen Delivery Council has undertaken analysis of the hydrogen value chain building on UK strengths and identifying the high value items that can deliver significant impact and benefit to the UK. We have also conducted widespread engagement with project developers to identify the barriers to utilising UK technology in projects and with technology developers to identify the challenges and barriers to investing and siting development and manufacturing in the UK.
The report can be found on Hydrogen UK's website.
Economic Impact Assessment for the Hydrogen Sector to 2030
Apr 2024
Publication
Hydrogen is one of the key solutions to decarbonising the UK economy along with other carbon abatement solutions such as electrification CCUS biofuels and energy efficiency. It provides a low carbon alternative to fossil fuels that has many of the same desirable features such as burning with a high temperature flame without producing carbon emissions during combustion. Hydrogen will be particularly valuable in hard-to-decarbonise sectors that have few cost-effective alternatives including elements of industry heavy transport and dispatchable power generation. However it’s use could be much more widespread depending on how costs preferences and policy for different low carbon solutions develop. The Government’s Hydrogen Strategy estimates that based on analysis from the Climate Change Committee (CCC) in 2050 between 20% and 35% of the UK’s final energy demand could be met with low carbon hydrogen1 . While hydrogen provides a promising solution to reducing emissions current deployment of low carbon hydrogen is low with almost all hydrogen in the UK produced from unabated fossil fuels resulting in high emissions. In the UK hydrogen production must meet the Low Carbon Hydrogen Standard (LCHS) to access government support. This is currently set at 20g CO2 e/MJ(LHV) and will ensure that future deployment will deliver significant emissions reductions when switching from fossil fuels2. The period to 2030 will be a critical time for the UK to seize the economic opportunity presented by low carbon hydrogen sector. Internationally increasing attention has been placed on hydrogen as a solution to global emissions. In the USA the Inflation Reduction Act (IRA) has provided fixed rate tax credits of up to $3/kg (£2.4/kgII) for clean hydrogen production3. Closer to home the EU is targeting 10 million tonnes of domestic electrolytic production and an additional 10 million tonnes of electrolytic hydrogen imports by 20304. This will be achieved through a variety of policy levers including an auction for fixed price subsidy support for electrolytic production with a ceiling of €4.5/kg5 (£3.84/kgIII). In the UK Government have set an ambitious target of up to 10 GW of low carbon hydrogen production by 2030 with at least half of this from electrolytic sources6. This will be supported by the Hydrogen Production Business Model (HPBM) a two-way variable CfD which could potentially provide hydrogen for a price as low as the natural gas price7 . As global supply chains investment and skills are in international competition the UK must continue its ambitious hydrogen aspirations to ensure the decarbonisation and economic opportunity presented by low carbon hydrogen is captured. This study estimates the economic impact of the low carbon hydrogen sector in the UK by 2030. The impact is assessed by estimating the costs of hydrogen deployment and applying employment and GVA multipliers to these costs based on historic economic activity. These estimates are broken down by different forms of low carbon hydrogen production and end use as well as the enabling infrastructure required to connect production and demand namely hydrogen networks and storage. Both the employment and GVA are estimated for each of these value chain elements for every year between 2024 and 2030. Employment and economic growth from the hydrogen sector will be created across the UK with many benefits arising in regions that have faced historic underinvestment such as the industrial clusters and Scotland. Beyond the high-level economic benefits estimated in this study the hydrogen sector creates an opportunity for the hundreds of thousands oil and gas sector jobs in the UK to transition to a low carbon alternative.
This report can be found on Hydrogen UK's website.
This report can be found on Hydrogen UK's website.
CFD Analysis of Delayed Ignition Hydrogen Releases from a Train Inside a Tunnel
Sep 2023
Publication
In the present work we present the results of numerical simulations involving the dispersion and combustion of a hydrogen cloud released in an empty tunnel. The simulations were conducted with the use of ADREA-HF CFD code and the results are compared with measurements from experiments conducted by HSE in a tunnel with the exact same geometry. The length of the tunnel is equal to 70 m and the maximum height from the floor is equal to 3.25 m. Hydrogen release is considered to occur from a train containing pressurized hydrogen stored at 580 bars. The release diameter is equal to 4.7 mm and the release direction is upwards. Initially dispersion simulation was performed in order to define the initial conditions for the deflagration simulations. The effect of the initial wind speed and the effect of the ignition delay time were investigated. An extensive grid sensitivity study was conducted in order to achieve grid independent results. The CFD model takes into account the flame instabilities that are developed as the flame propagates inside the tunnel and turbulence that exists in front of the flame front. Pressure predictions are compared against experimental measurements revealing a very good performance of the CFD model.
The Regulatory Framework of Geological Storage of Hydrogen in Salt Caverns
Sep 2023
Publication
A growing share of renewable energy production in the energy supply systems is key to reaching the European political goal of zero CO2 emission in 2050 highlighted in the green deal. Linked to the irregular production of solar and wind energies which have the highest potential for development in Europe massive energy storage solutions are needed as energy buffers. The European project HyPSTER [1] (Hydrogen Pilot STorage for large Ecosystem Replication) granted by the Clean Hydrogen Partnership addresses this topic by demonstrating a cyclic test in an experimental salt cavern filled with hydrogen up to 3 tons using hydrogen that is produced onsite by a 1 MW electrolyser. One specific objective of the project is the assessment of the risks and environmental impacts of cyclic hydrogen storage in salt caverns and providing guidelines for safety regulations and standards. This paper highlights the first outcome of the task WP5.5 of the HyPSTER project addressing the regulatory and normative frameworks for the safety of hydrogen storage in salt caverns from some selected European Countries which is dedicated to defining recommendations for promoting the safe development of this industry within Europe.
A Review of Control Strategies for Proton Exchange Membrane (PEM) Fuel Cells and Water Electrolysers: From Automation to Autonomy
Jul 2024
Publication
Proton exchange membrane (PEM) based electrochemical systems have the capability to operate in fuel cell (PEMFC) and water electrolyser (PEMWE) modes enabling efficient hydrogen energy utilisation and green hydrogen production. In addition to the essential cell stacks the system of PEMFC or PEMWE consists of four sub-systems for managing gas supply power thermal and water respectively. Due to the system’s complexity even a small fluctuation in a certain sub-system can result in an unexpected response leading to a reduced performance and stability. To improve the system’s robustness and responsiveness considerable efforts have been dedicated to developing advanced control strategies. This paper comprehensively reviews various control strategies proposed in literature revealing that traditional control methods are widely employed in PEMFC and PEMWE due to their simplicity yet they suffer from limitations in accuracy. Conversely advanced control methods offer high accuracy but are hindered by poor dynamic performance. This paper highlights the recent advancements in control strategies incorporating machine learning algorithms. Additionally the paper provides a perspective on the future development of control strategies suggesting that hybrid control methods should be used for future research to leverage the strength of both sides. Notably it emphasises the role of artificial intelligence (AI) in advancing control strategies demonstrating its significant potential in facilitating the transition from automation to autonomy.
Comparative Analysis of Marine Alternative Fuels for Offshore Supply Vessels
Nov 2024
Publication
This paper provides an in-depth analysis of alternative fuels including liquefied natural gas (LNG) hydrogen ammonia and biofuels assessing their feasibility based on operational requirements availability safety concerns and the infrastructure needed for large-scale adoption. Moreover it examines hybrid and fully electric propulsion systems considering advancements in battery technology and the integration of renewable energy sources such as wind and solar power to further reduce SOV emissions. Key findings from this research indicate that LNG serves as a viable short- to medium-term solution for reducing GHG emissions in the SOV sector due to its relatively lower carbon content compared to MDO and HFO. This paper finally insists that while LNG presents an immediate opportunity for emission reduction in the SOV sector a combination of hydrogen ammonia and hybrid propulsion systems will be necessary to meet long-term decarbonisation goals. The findings underscore the importance of coordinated industry efforts technological innovation and supportive regulatory frameworks to overcome the technical economic and infrastructural challenges associated with decarbonising the maritime industry.
"Green" Ammonia: Impact of Renewable Energy Intermittency on Plant Sizing and Levelized Cost of Ammonia
Oct 2018
Publication
Ammonia production currently contributesalmost 11% of global industrial carbon dioxide emissions or1.3% of global emissions. In the context of global emissiontargets and growing demand decarbonization of this processis highly desirable. We present a method to calculate a firstestimate for the optimum size of an ammonia productionplant (at the process level) the required renewable energy(RE) supply and the levelized cost of ammonia (LCOA) forislanded operation with a hydrogen buffer. A model wasdeveloped to quantitatively identify the key variables thatimpact the LCOA (relative to a ±10 GBP/tonne change inLCOA): levelized cost of electricity (±0.89 GBP/MWh) electrolyzer capital expenditure (±65 GBP/kW) minimum Haber−Bosch (HB) load (±12% of rated power) maximum rate of HB load ramping and RE supply mix. Using 2025/2030 estimatesresults in a LCOA of 588 GBP/tonne for Lerwick Scotland. The application of the model will facilitate and improve theproduction of carbon-free ammonia in the future.
Impact of Impurities on Water Electrolysis: A Review
Feb 2023
Publication
Low temperature water electrolysers such as Proton Exchange Membrane Water Electrolysers (PEMWEs) Alkaline Water Electrolysers (AWEs) and Anion Exchange Membrane Water Electrolysers (AEMWEs) are known to be sensitive to water quality with a range of common impurities impacting performance hydrogen quality and device lifetime. Purification of feed water adds to cost operational complexity and design limitations while failure of purification equipment can lead to degradation of electrolyser materials and components. Increased robustness to impurities will offer a route to longer device lifetimes and reduced operating costs but understanding of the impact of impurities and associated degradation mechanisms is currently limited. This critical review offers for the first time a comprehensive overview of relevant impurities in operating electrolysers and their impact. Impurity sources degradation mechanisms characterisation techniques water purification technologies and mitigation strategies are identified and discussed. The review generalises already reported mechanisms proposes new mechanisms and provides a framework for consideration of operational implications.
Erosive Effects of Hydrogen Jet Fires on Tunnel Structural Materials
Sep 2023
Publication
This paper presents work undertaken as part of the Hytunnel-CS project a consortium investigating safety considerations for fuel cell hydrogen (FCH) vehicles in tunnels and similar confined spaces. This test programme investigated erosive effects of an ignited high pressure hydrogen jet impinging onto tunnel structural materials specifically concrete as used for tunnel linings and asphalt road surfacing for the road itself. The chosen test conditions mimicked a high-pressure release (700 bar) from an FCH car as a result of activation of the thermal pressure relief device (TPRD) on the fuel tank. These devices typically have a release opening of 2 mm and thus a nozzle diameter of approximately 2 mm was used. The resultant releases were ignited using a propane pilot light and test samples were placed in the jet path at varying standoff distances from the release nozzle.<br/>An initial characterization test of a free unimpeded ignited jet demonstrated a rapid and intense temperature increase up to 1650 °C lasting in the order of 3 - 5 minutes for that fuel inventory (4 kg hydrogen). Five tests were carried out where the ignited jet was impinged onto five structural samples. It was found that erosion occurred in the concrete samples where no fire mitigation namely addition of polypropylene fibres was applied. The road-surface sample was found to become molten but did not progress to combustion.<br/>Post-test material analysis including compressive strength and thermal conductivity measurements was carried out on some of the concrete samples to investigate whether structural deformities had occurred within the sample microstructure. The results suggested that the erosive damage caused by the hydrogen jet was mostly superficial and as such did not present an increased fire risk to the structural integrity to that of conventional hydrocarbon fires i.e. those that would result from petrol or diesel fuel tank releases. In terms of fire resistance standards it is suggested that current fire mitigation strategies and structural testing standards would be adequate for hydrogen vehicles on the road network.
An Assessment of Current Hydrogen Supply Chains in the Gulf Cooperation Council (GCC)
May 2024
Publication
The Gulf Cooperation Council (GCC) comprising: Saudi Arabia United Arab Emirates Kuwait Qatar Oman and Bahrain is home to an abundant number of resources including natural gas and solar and wind energy (renewables). Because of this the region is favourably positioned to become a significant player in both blue and green hydrogen production and their export. Current dependence on fossil fuels and ambitious national targets for decarbonisation have led the region and world to research the feasibility of switching to a hydrogen economy. This literature review critically examines the current advantages and strategies adopted by the GCC to expedite the implementation of hydrogen supply chains as well as investigation into the methodologies employed in current research for the modelling and optimisation of hydrogen supply chains. Insight into these endeavours is critical for stakeholders to assess the inherent challenges and opportunities in establishing a sustainable hydrogen economy. Despite a substantial global effort establishing a solid hydrogen supply chain presently faces various obstacles including the costs of clean hydrogen production. Scaling-up storage and transport methods is an issue that affects all types of hydrogen including carbon-intensive (grey) hydrogen. However the current costs of green hydrogen production mostly via the process of electrolysis is a major obstacle hindering the widescale deployment of clean hydrogen. Research in this literature review found that compressed gas and cryogenic liquid options have the highest storage capacities for hydrogen of 39.2 and 70.9 kg/m3 respectively. Meanwhile for hydrogen transportation pipelines and cryogenic tankers are the most conventional and efficient options with an efficiency of over 99 %. Cryogenic ships to carry liquid hydrogen also show potential due to their large storage capacities of 10000 tonnes per shipment However costs per vessel are currently still very expensive ranging between $ 465 and $620 million.
Detailed Assessment of Dispersion for High-pressure H2 in Multi-fuel Environment
Sep 2023
Publication
The MultHyFuel project notably aims to produce the data missing for usable risk analysis and mitigation activity for Hydrogen Refuelling Stations (HRS) in a multi-fuel context. In this framework realistic releases of hydrogen that could occur in representative multi-fuel forecourts were studied. These releases can occur inside or outside fuel dispensers and they can interact with a complex environment notably made of parked cars and trucks. This paper is focused on the most critical scenarios that were addressed by a sub-group through the use of Computational Fluid Dynamics (CFD) modelling. Once the corresponding source terms for hydrogen releases were known two stages are followed:<br/>♦ Model Validation – to evaluate the CFD models selected by the task partners and to evaluate their performance through comparison to experimental data.<br/>♦ Realistic Release Modelling – to perform demonstration simulations of a range of critical scenarios.<br/>The CFD models selected for the Model Validation have been tested against measured data for a set of experiments involving hydrogen releases. Each experiment accounts for physical features that are encountered in the realistic cases. The selected experiments include an under-expanded hydrogen jet discharging into the open atmosphere with no obstacles or through an array of obstacles. Additionally a very different set-up was studied with buoyancy-driven releases inside a naturally ventilated enclosure. The results of the Model Validation exercise show that the models produce acceptable solutions when compared to measured data and give confidence in the ability of the models and the modellers to capture the behaviour of the realistic releases adequately. The Realistic Release Modelling phase will provide estimation of the flammable gas cloud volume for a set of critical scenarios and will be described at the second stage.
Multiphysics Performance Assessment of Hydrogen Fuelled Engines
Sep 2023
Publication
In the quest for decarbonisation alternative clean fuels for propulsion systems are sought. There is definite advantage in retaining the well-established principles of operation of combustion engines at the core of future developments with hydrogen as a fuel. Hydrogen is envisaged as a clean source of energy for propulsion of heavy and off-road vehicles as well as in marine and construction sectors. A source of concern is the unexplored effect of hydrogen combustion on dilution and degradation of engine lubricants and their additives and consequently upon tribology of engine contact conjunctions. These potential problems can adversely affect engine efficiency durability and operational integrity. Use of different fuels and their method of delivery produces distinctive combustion characteristics that can affect the energy losses associated with in-cylinder components and their durability. Therefore detailed predictive analysis should support the developments of such new generation of eco-friendly engines. Different fundamental physics underpin the various aspects of a pertinent detailed analysis. These include thermodynamics of combustion in-cylinder tribological interactions of contacting surfaces and blowby of generated gasses. This paper presents such an integrated multi-physics analysis of internal combustion engines with focus on hydrogen as the fuel. Such an in-depth and computationally efficient analysis has not hitherto been reported in the literature. The results show implications for lubricant degradation due to the use of hydrogen in the performance of in-cylinder components and the underlying physical principles.
Conceptual Design-optimisation of a Subsonic Hydrogen-powered Long-range Blended-wing-body Aircraft
Nov 2024
Publication
The adoption of liquid hydrogen (LH2) holds promise for decarbonising long-range aviation. LH2 aircraft could weigh less than Jet-A aircraft thereby reducing the thrust requirement. However the lower volumetric energy density of LH2 can adversely impact the aerodynamic performance and energy consumption of tube-wing aircraft. In a first this work conducts an energy performance modelling of a futuristic (2030+) LH2 blendedwing-body (BWB) aircraft (301 passengers and 13890 km) using conceptual aircraft design-optimisation approach employing weight-sizing methods while considering the realistic gravimetric and volumetric energy density effects of LH2 on aircraft design and the resulting reduction in aircraft thrust requirement. This study shows that at the design point the futuristic LH2 BWB aircraft reduces the specific energy consumption (SEC MJ/ tonne-km) by 51.7–53.5% and 7.3–10.8% compared to (Jet-A) Boeing 777-200LR and Jet-A BWB respectively. At the off-design points this study shows that by increasing the load factor for a given range and/or increasing range for all load factor cases the SEC (or energy efficiency) of this LH2 BWB concept improves. The results of this work will inform future studies on use-phase emissions and contrails modelling LH2 aircraft operations for contrail reduction estimation of operating costs and lifecycle climate impacts.
Hydrogen Production from Municipal Waste and Low Grade Lignite Blend
Nov 2024
Publication
The updraft rotating bed gasifier (URBG) offers a sustainable solution for waste-to-energy conversion utilizing low-grade lignite and municipal solid waste (MSW) from metropolitan dumping sites. This study investigates the co-gasification of lignite with various MSW components demonstrating a significant enhancement in gasification efficiency due to the synergistic effects arising from their higher hydrogen-to-carbon (H/C) ratios. We find feedstock blending is key to maximizing gasification efficiency from 11% to 52% while reducing SO emissions from 739 mg/kg to 155 mg/kg. Increasing the combustion zone temperature to 1100 K resulted in a peak hydrogen yield which was 19% higher than at 800 K. However steam management is complicated as increasing it improves hydrogen fraction in produced gas but gasification efficiency is compromised. These findingsshowcase the URBG’s potential to address both energy production and waste management challenges guiding fossil-reliant regions toward a more sustainable energy future.
Multilateral Governance in a Global Hydrogen Economy: An Overview of Main Actors and Institutions, Key Challenges and Future Pathways
Nov 2024
Publication
This paper explores the current scope and direction of the emerging global governance of hydrogen within the broader context of the energy transition where technological innovation and institutional change intersect. Hydrogen as a critical yet complex energy vector requires coordinated governance efforts to navigate its development effectively. To this end we critically engage with key challenges facing the hydrogen sector and examine how institutional frameworks are addressing these issues. Departing from the broader scholarship on global energy governance we conceptually leverage the socio-technical transition and innovation system liter ature to understand the complexities underpinning the development of the global hydrogen economy. We identify three overarching issue areas pertaining to the nature and role of hydrogen in the global energy system: end-use sector development infrastructure and trade and environmental and socio-economic sustainability. Each of these areas presents distinct challenges to hydrogen’s global governance from stimulating supply and demand to managing geo-economic challenges and establishing comprehensive certification and standards. Through mapping multilateral institutions at the global and regional levels and their main objectives we offer insights into the emerging institutional architecture related to hydrogen and identify potential gaps in current governance. Our findings suggest that while newer hydrogen-specific institutions complement the broader agenda of the main established international organizations the overall global hydrogen structure remains a patchwork of diverse actors and frameworks each addressing hydrogen-related challenges to varying degrees. Our research contributes to a nuanced understanding of global governance in the hydrogen sector and advances scholarly discussions on how institutional and actor dynamics shape the emergence and development of new technologies.
Decision Support System for Sustainable Hydrogen Production: Case Study of Saudi Arabia
Nov 2024
Publication
The global energy sector is undergoing a transition towards sustainable sources with hydrogen emerging as a promising alternative due to its high energy content and clean-burning properties. The integration of hydrogen into the energy landscape represents a significant advancement towards a cleaner greener future. This paper introduces an innovative decision support system (DSS) that combines multi-criteria decision-making (MCDM) and decision tree methodologies to optimize hydrogen production decisions in emerging economies using Saudi Arabia as a case study. The proposed DSS developed using MATLAB Web App Designer tools evaluates various scenarios related to demand and supply cost and profit margins policy implications and environmental impacts with the goal of balancing economic viability and ecological responsibility. The study's findings highlight the potential of this DSS to guide policymakers and industry stakeholders in making informed scalable and flexible hydrogen production decisions that align with sustainable development goals. The novel DSS framework integrates two key influencing factors technical and logistical by considering components such as data management modeling analysis and decision-making. The analysis component employs statistical and economic methods to model and assess the costs and benefits of eleven strategic scenarios while the decision-making component uses these results to determine the most effective strategies for implementing hydrogen production to minimize risks and uncertainties.
The Impact of Hydrogen on Decarbonisation and Resilience in Integrated Energy Systems
Nov 2024
Publication
The lack of clarity and uncertainty about hydrogen’s role demand applications and economics has been a barrier to the development of the hydrogen economy. In this paper an optimisation model for the integrated planning and operation of hydrogen and electricity systems is presented to identify the role of hydrogen technologies and linepack in decarbonising energy systems improving system flexibility and enhancing energy system security and resilience against extreme weather events. The studies are conducted on Great Britain’s (GB) 2050 net-zero electricity and gas transmission systems to analyse the hydrogen transport and capacity requirements within the existing infrastructure under different scenarios. This includes sensitivities on the level of flexibility high gas prices hydrogen production mixes enabled reversibility of electrolysers electricity generation cost and hydrogen storage facilities. In all sensitivity scenarios efficient hydrogen transport within the existing infrastructure is enabled by the optimal allocation of green and blue hydrogen sources distributed storage facilities and the intra-day flexibility provided by linepack. The findings highlight that increased renewable deployment transfers intermittency to the hydrogen network requiring greater linepack flexibility compared to the current paradigm (up to 83%). Furthermore the necessity of synergy between different gas and electricity systems components in providing flexibility security and resilience is quantified.
Safety Assessment of Hydrogen Production Using Alkaline Water Electrolysis
Aug 2024
Publication
This paper presents a comprehensive safety assessment of hydrogen production using Alkaline Water Electrolysis (AWE). The study utilizes various risk assessment methodologies including Hazard Identification (HAZID) What-If analysis Fault Tree Analysis (FTA) Event Tree Analysis (ETA) and Bow Tie analysis to systematically identify and evaluate potential hazards associated with the AWE process. Key findings include the identification of critical hazards such as hydrogen leaks oxygen-related risks and maintenance challenges. The assessment emphasizes the importance of robust safety measures including preventive and mitigative strategies to manage these risks effectively. Consequence modeling highlights significant threat zones for thermal radiation and explosion risks underscoring the need for comprehensive safety protocols and emergency response plans. This work contributes valuable insights into hydrogen safety providing a framework for risk assessment and mitigation in hydrogen production facilities crucial for the safe and sustainable development of hydrogen infrastructure in the global energy transition.
Bio-Hydrogen Production from Wastewater: A Comparative Study of Low Energy Intensive Production Processes
Feb 2021
Publication
Billions of litres of wastewater are produced daily from domestic and industrial areas and whilst wastewater is often perceived as a problem it has the potential to be viewed as a rich source for resources and energy. Wastewater contains between four and five times more energy than is required to treat it and is a potential source of bio-hydrogen—a clean energy vector a feedstock chemical and a fuel widely recognised to have a role in the decarbonisation of the future energy system. This paper investigates sustainable low-energy intensive routes for hydrogen production from wastewater critically analysing five technologies namely photo-fermentation dark fermentation photocatalysis microbial photo electrochemical processes and microbial electrolysis cells (MECs). The paper compares key parameters influencing H2 production yield such as pH temperature and reactor design summarises the state of the art in each area and highlights the scale-up technical challenges. In addition to H2 production these processes can be used for partial wastewater remediation providing at least 45% reduction in chemical oxygen demand (COD) and are suitable for integration into existing wastewater treatment plants. Key advancements in lab-based research are included highlighting the potential for each technology to contribute to the development of clean energy. Whilst there have been efforts to scale dark fermentation electro and photo chemical technologies are still at the early stages of development (Technology Readiness Levels below 4); therefore pilot plants and demonstrators sited at wastewater treatment facilities are needed to assess commercial viability. As such a multidisciplinary approach is needed to overcome the current barriers to implementation integrating expertise in engineering chemistry and microbiology with the commercial experience of both water and energy sectors. The review concludes by highlighting MECs as a promising technology due to excellent system modularity good hydrogen yield (3.6–7.9 L/L/d from synthetic wastewater) and the potential to remove up to 80% COD from influent streams.
Design Trends and Challenges in Hydrogen Direct Injection (H2DI) Internal Combustion Engines - A Review
Sep 2024
Publication
The hydrogen internal combustion engine (H2-ICE) is proposed as a robust and viable solution to decarbonise the heavy-duty on- and off-road as well as the light-duty automotive sectors of the transportation markets and is therefore the subject of rapidly growing research interest. With the potential for engine performance improvement by controlling the internal mixture formation and avoiding combustion anomalies hydrogen direct injection (H2DI) is a promising combustion mode. Furthermore the H2-ICE poses an attractive proposition for original equipment manufacturers (OEMs) and their suppliers since the fundamental base engine design components and manufacturing processes are largely unchanged. Nevertheless to deliver the highest thermal efficiency and zero-harm levels of tailpipe emissions moderate adaptations are needed to the engine control air path fuel injection and ignition systems. Therefore in this article critical design features fuel-air mixing combustion regimes and exhaust after-treatment systems (EATS) for H2DI engines are carefully assessed.
Machine Learning-powered Performance Monitoring of Proton Exchange Membrane Water Electrolyzers for Enhancing Green Hydrogen Production as a Sustainable Fuel for Aviation Industry
Aug 2024
Publication
Aviation is a major contributor to transportation carbon emissions but aims to reduce its carbon footprint. Sustainable and environmentally friendly green hydrogen fuel is essential for decarbonization of this industry. Using the extremely low temperature of liquid hydrogen in aviation sector unlocks the opportunity for cryoelectric aircraft concept which exploits the advantageous properties of superconductors onboard. A significant barrier for green hydrogen adoption relates to its high cost and the immediate need for large-scale production which Proton Exchange Membrane Water Electrolyzers (PEMWE) can address through optimal dynamic performance high lifetimes good efficiencies and importantly scalability. In PEMWE the cell is a crucial component that facilitates the electrolysis process and consists of a polymer membrane and electrodes. To control the required production rate of hydrogen the output power of cell should be monitored which usually is done by measuring the cell’s potential and current density. In this paper five different machine learning (ML) models based on different algorithms have been developed to predict this parameter. Findings of the work highlight that the model based on Cascade-Forward Neural Network (CFNN) is investigated to accurately predict the cell potential of PEMWE under different anodic material and working conditions with an accuracy of 99.998 % and 0.001884 in terms of R2 and root mean square error respectively. It can predict the cell potential with a relative error of less than 0.65 % and an absolute error of below 0.01 V. The Standard deviation of 0.000061 for 50 iterations of stability analysis indicated that this model has less sensitivity to the random selection of training data. By accurately estimating different cell’s output with one model and considering its ultra-fast response CFNN model has the potential to be used for both monitoring and the designing purposes of green hydrogen production.
Hydrogen Liquefaction and Storage: Recent Progress and Perspectives
Feb 2023
Publication
The global energy sector accounts for ~75% of total greenhouse gas (GHG) emissions. Low-carbon energy carriers such as hydrogen are seen as necessary to enable an energy transition away from the current fossilderived energy paradigm. Thus the hydrogen economy concept is a key part of decarbonizing the global en ergy system. Hydrogen storage and transport are two of key elements of hydrogen economy. Hydrogen can be stored in various forms including its gaseous liquid and solid states as well as derived chemical molecules. Among these liquid hydrogen due to its high energy density ambient storage pressure high hydrogen purity (no contamination risks) and mature technology (stationary liquid hydrogen storage) is suitable for the transport of large-volumes of hydrogen over long distances and has gained increased attention in recent years. However there are critical obstacles to the development of liquid hydrogen systems namely an energy intensive liquefaction process (~13.8 kWh/kgLH2) and high hydrogen boil-off losses (liquid hydrogen evaporation during storage 1–5% per day). This review focuses on the current state of technology development related to the liquid hydrogen supply chain. Hydrogen liquefaction cryogenic storage technologies liquid hydrogen transmission methods and liquid hydrogen regasification processes are discussed in terms of current industrial applications and underlying technologies to understand the drivers and barriers for liquid hydrogen to become a commer cially viable part of the emerging global hydrogen economy. A key finding of this technical review is that liquid hydrogen can play an important role in the hydrogen economy - as long as necessary technological transport and storage innovations are achieved in parallel to technology demonstrations and market development efforts by countries committed liquid hydrogen as part of their hydrogen strategies.
Reducing the Environmental Impact of International Aviationg through Sustainable Aviation Fuel with Integrated Carbon Capture and Storage
Feb 2024
Publication
Sustainable aviation fuels (SAFs) represent the short-term solution to reduce fossil carbon emissions from aviation. The Carbon Offsetting and Reduction Scheme for International Aviation (CORSIA) was globally adopted to foster and make SAFs production economically competitive. Fischer-Tropsch synthetic paraffinic kerosene (FTSPK) produced from forest residue is a promising CORSIA-eligible fuel. FT conversion pathway permits the integration of carbon capture and storage (CCS) technology which provides additional carbon offsetting ca pacities. The FT-SPK with CCS process was modelled to conduct a comprehensive analysis of the conversion pathway. Life-cycle assessment (LCA) with a well-to-wake approach was performed to quantify the SAF’s carbon footprint considering both biogenic and fossil carbon dynamics. Results showed that 0.09 kg FT-SPK per kg of dry biomass could be produced together with other hydrocarbon products. Well-to-wake fossil emissions scored 21.6 gCO2e per MJ of FT-SPK utilised. When considering fossil and biogenic carbon dynamics a negative carbon flux (-20.0 gCO2eMJ− 1 ) from the atmosphere to permanent storage was generated. However FT-SPK is limited to a 50 %mass blend with conventional Jet A/A1 fuel. Using the certified blend reduced Jet A/A1 fossil emissions in a 37 % and the net carbon flux resulted positive (30.9 gCO2eMJ− 1 ). Sensitivity to variations in process as sumptions was investigated. The lifecycle fossil-emissions reported in this study resulted 49 % higher than the CORSIA default value for FT-SPK. In a UK framework only 0.7 % of aviation fuel demand could be covered using national resources but the emission reduction goal in aviation targeted for 2037 could be satisfied when considering CCS.
HyDeploy2 - Gas Network Innovation Competition: Cadent 5th Project Progress Report
Jan 2024
Publication
The HyDeploy2 project seeks to address a key issue for UK energy customers: how to reduce the carbon they emit in heating their homes. The UK has a world class gas grid delivering heat conveniently and safely to more than 83% of homes. Emissions can be reduced by lowering the carbon content of gas through blending with hydrogen. This delivers carbon savings without customers requiring disruptive and expensive changes in their homes. It also provides the platform for deeper carbon savings by enabling wider adoption of hydrogen across the energy system.
Energy-exergy Evaluation of Liquefied Hydrogen Production System Based on Steam Methane Reforming and LNG Revaporization
Jul 2023
Publication
The research motivation of this paper is to utilize the large amount of energy wasted during the LNG (liquefied natural gas) gasification process and proposes a synergistic liquefied hydrogen (LH2) production and storage process scheme for LNG receiving station and methane reforming hydrogen production process - SMR-LNG combined liquefied hydrogen production system which uses the cold energy from LNG to pre-cool the hydrogen and subsequently uses an expander to complete the liquefaction of hydrogen. The proposed process is modeled and simulated by Aspen HYSYS software and its efficiency is evaluated and sensitivity analysis is carried out. The simulation results show that the system can produce liquefied hydrogen with a flow rate of 5.89t/h with 99.99% purity when the LNG supply rate is 50t/h. The power consumption of liquefied hydrogen is 46.6kWh/kg LH2; meanwhile the energy consumption of the HL subsystem is 15.9kWh/kg LH2 lower than traditional value of 17~19kWh/kg LH2. The efficiency of the hydrogen production subsystem was 16.9%; the efficiency of the hydrogen liquefaction (HL) subsystem was 29.61% which was significantly higher than the conventional industrial value of 21%; the overall energy efficiency (EE1) of the system was 56.52% with the exergy efficiency (EE2) of 22.2% reflecting a relatively good thermodynamic perfection. The energy consumption of liquefied hydrogen per unit product is 98.71 GJ/kg LH2.
Exergy Analysis in Intensification of Sorption-enhanced Steam Methane Reforming for Clean Hydrogen Production: Comparative Study and Efficiency Optimisation
Feb 2024
Publication
Hydrogen has a key role to play in decarbonising industry and other sectors of society. It is important to develop low-carbon hydrogen production technologies that are cost-effective and energy-efficient. Sorption-enhanced steam methane reforming (SE-SMR) is a developing low-carbon (blue) hydrogen production process which enables combined hydrogen production and carbon capture. Despite a number of key benefits the process is yet to be fully realised in terms of efficiency. In this work a sorption-enhanced steam methane reforming process has been intensified via exergy analysis. Assessing the exergy efficiency of these processes is key to ensuring the effective deployment of low-carbon hydrogen production technologies. An exergy analysis was performed on an SE-SMR process and was then subsequently used to incorporate process improvements developing a process that has theoretically an extremely high CO2 capture rate of nearly 100 % whilst simultaneously demonstrating a high exergy efficiency (77.58 %) showcasing the potential of blue hydrogen as an effective tool to ensure decarbonisation in an energy-efficient manner.
Great Britain's Hydrogen Infrastructure Development - Investment Priorities and Locational Flexibility
Aug 2024
Publication
Future pathways for Great Britain’s energy system decarbonization have highlighted the importance of lowcarbon hydrogen as an energy carrier and demand flexibility support. However the potential application within various sectors (heating industry transport) and production capacity through different technologies (methane reformation with carbon capture biomass gasification electrolysis) is highly varying introducing substantial uncertainties for hydrogen infrastructure development. This study sets out infrastructure priorities and identifies locational flexibility for hydrogen supply and demand options. Advances on limitations of previous research are made by developing an open-source model of the hydrogen system of Great Britain based on three Net Zero scenarios set out by National Grid in their Future Energy Scenarios in high temporal and spatial resolution. The model comprehensively covers demand sectors and supply options in addition to extending the locational considerations of the Future Energy Scenarios. This study recommends prioritizing the establishment of green hydrogen hubs in the near-term aligning with demands for synthetic fuels production industry and power which can facilitate the subsequent roll out of up to 10GW of hydrogen production capacity by 2050. The analysis quantifies a high proportion of hydrogen supply and demand which can be located flexibly.
Green Hydrogen Energy Production: Current Status and Potential
Jan 2024
Publication
The technique of producing hydrogen by utilizing green and renewable energy sources is called green hydrogen production. Therefore by implementing this technique hydrogen will become a sustainable and clean energy source by lowering greenhouse gas emissions and reducing our reliance on fossil fuels. The key beneft of producing green hydrogen by utilizing green energy is that no harmful pollutants or greenhouse gases are directly released throughout the process. Hence to guarantee all of the environmental advantages it is crucial to consider the entire hydrogen supply chain involving storage transportation and end users. Hydrogen is a promising clean energy source and targets plan pathways towards decarbonization and net-zero emissions by 2050. This paper has highlighted the techniques for generating green hydrogen that are needed for a clean environment and sustainable energy solutions. Moreover it summarizes an overview outlook and energy transient of green hydrogen production. Consequently its perspective provides new insights and research directions in order to accelerate the development and identify the potential of green hydrogen production.
A Comparative Total Cost of Ownership Analysis of Heavy Duty On-road and Off-road Vehicles Powered by Hydrogen, Electricity, and Diesel
Dec 2022
Publication
This study investigated the cost competitiveness using total cost of ownership (TCO) analysis of hydrogen fuel cell electric vehicles (FCEVs) in heavy duty on and off-road fleet applications as a key enabler in the decarbonisation of the transport sector and compares results to battery electric vehicles (BEVs) and diesel internal combustion engine vehicles (ICEVs). Assessments were carried out for a present day (2021) scenario and a sensitivity analysis assesses the impact of changing input parameters on FCEV TCO. This identified conditions under which FCEVs become competitive. A future outlook is also carried out examining the impact of time-sensitive parameters on TCO when net zero targets are to be reached in the UK and EU. Several FCEVs are cost competitive with ICEVs in 2021 but not BEVs under base case conditions. However FCEVs do have potential to become competitive with BEVs under specific conditions favouring hydrogen including the application of purchase grants and a reduced hydrogen price. By 2050 a number of FCEVs running on several hydrogen scenarios show a TCO lower than ICEVs and BEVs using rapid chargers but for the majority of vehicles considered BEVs remain the lowest in cost unless specific FCEV incentives are implemented. This paper has identified key factors hindering the deployment of hydrogen and conducted comprehensive TCO analysis in heavy duty on and off-road fleet applications. The output has direct contribution to the decarbonisation of the transport sector.
Cost and Competitiveness of Green Hydrogen and the Effects of the European Union Regulatory Framework
May 2024
Publication
By passing the delegated acts supplementing the revised Renewable Energy Directive the European Commission has recently set a regulatory benchmark for the classifcation of green hydrogen in the European Union. Controversial reactions to the restricted power purchase for electrolyser operation refect the need for more clarity about the efects of the delegated acts on the cost and the renewable characteristics of green hydrogen. To resolve this controversy we compare diferent power purchase scenarios considering major uncertainty factors such as electricity prices and the availability of renewables in various European locations. We show that the permission for unrestricted electricity mix usage does not necessarily lead to an emission intensity increase partially debilitating concerns by the European Commission and could notably decrease green hydrogen production cost. Furthermore our results indicate that the transitional regulations adopted to support a green hydrogen production ramp-up can result in similar cost reductions and ensure high renewable electricity usage.
No more items...