France
Turbulent Flame Propagation in Large Unconfined H2/O2/N2 Clouds
Oct 2015
Publication
Turbulence is a key aspect in hydrogen explosions. Unfortunately only limited experimental data is available and the current understanding of flame turbulence interactions is too limited to permit safe predictions. New experimental data are presented in which the flame trajectory and pressure history are interpreted for unconfined explosions of H2/O2/N2 clouds of 7 m3. The intensity of the turbulence is varied between 0 and 5 m/s and the integral s Read More
Hydrogen Ironmaking: How It Works
Jul 2020
Publication
A new route for making steel from iron ore based on the use of hydrogen to reduce iron oxides is presented detailed and analyzed. The main advantage of this steelmaking route is the dramatic reduction (90% off) in CO2 emissions compared to those of the current standard blast-furnace route. The first process of the route is the production of hydrogen by water electrolysis using CO2-lean electricity. The challenge is to achieve massive production of H2 in Read More
Cell Failure Mechanisms in PEM Water Electrolyzers
Sep 2011
Publication
PEM water electrolysis offers an efficient and flexible way to produce “green-hydrogen” from renewable (intermittent) energy sources. Most research papers published in the open literature on the subject are addressing performances issues and to date very few information is available concerning the mechanisms of performance degradation and the associated consequences. Results reported in this communication have been used to analyze the failure mec Read More
Experimental Study of the Effects of Vent Geometry on the Dispersion of a Buoyant Gas in a Small Enclosure
Sep 2011
Publication
We present an experimental study on the dispersion of helium in an enclosure of 1 m3 with natural ventilation through one vent. Three vent geometries have been studied. Injection parameters have been varied so that the injection Richardson number ranges from 2·10−6 to 9 and the volume Richardson number which gives the ability of the release to mix the enclosure content ranges from 8·10−4 to 900. It has been found that the vertical distribution of he Read More
An Experimental Study Dedicated to Wind Influence on Helium Build-up and Concentration Distribution Inside a 1 m 3 Semi-confined Enclosure Considering Hydrogen Energy Applications Conditions of Use
Oct 2015
Publication
Hydrogen energy applications can be used outdoor and thus exposed to environmental varying conditions like wind. In several applications natural ventilation is the first mitigation means studied to limit hydrogen build-up inside a confined area. This study aims at observing and understanding the influence of wind on light gas build-up in addition. Experiments were performed with helium as releasing gas in a 1-m 3 enclosure equipped with ventilation opening Read More
Isotopic Tracing of Hydrogen Transport and Trapping in Nuclear Materials
Jun 2017
Publication
Some illustrations of the use of deuterium or tritium for isotopic tracing of hydrogen absorption transport and trapping in nuclear materials are presented. Isotopic tracing of hydrogen has been shown to be successful for the determination of the boundaries conditions for hydrogen desorption or absorption in a material exposed to a hydrogen source. Also the unique capabilities of isotopic tracing and related techniques to characterize H interactions with Read More
Hydrogen Storage: Recent Improvements and Industrial Perspectives
Sep 2019
Publication
Efficient storage of hydrogen is crucial for the success of hydrogen energy markets (early markets as well as transportation market). Hydrogen can be stored either as a compressed gas a refrigerated liquefied gas a cryo-compressed gas or in hydrides. This paper gives an overview of hydrogen storage technologies and details the specific issues and constraints related to the materials behaviour in hydrogen and conditions representative of hydro Read More
Status of the Pre-normative Research Project PRESLHY for the Safe Use of LH2
Sep 2019
Publication
Liquid hydrogen (LH2) compared to compressed gaseous hydrogen offers advantages for large scale transport and storage of hydrogen with higher densities and potentially better safety performance. Although the gas industry has good experience with LH2 only little experience is available for the new applications of LH2 as an energy carrier. Therefore the European FCH JU funded project PRESLHY conducts pre-normative research for the safe use of cryoge Read More
Fire Tests Carried Out in FCH JU FIRECOMP Project, Recommendations and Application to Safety of Gas Storage Systems
Sep 2017
Publication
In the event of a fire composite pressure vessels behave very differently from metallic ones: the material is degraded potentially leading to a burst without significant pressure increase. Hence such objects are when necessary protected from fire by using thermally-activated devices (TPRD) and standards require testing cylinder and TPRD together. The pre-normative research project FireComp aimed at understanding better the conditions which may lead t Read More
Highly Resolve Large Eddy Simulations of a Transitional Air-helium Buoyant Jet in a Two Vented Enclosure: Validation Against Particle Image Velocimetry Experiments
Sep 2017
Publication
The article deals with LES simulations of an air-helium buoyant jet in a two vented enclosure and their validation against particle image velocimetry experiments. The main objective is to test the ability of LES models to simulate such scenarios. These types of scenarios are of first interest considering safety studies for new hydrogen systems. Three main challenges are identified. The two first are the ability of the LES model to account for a rapi Read More
ISO 19880-1, Hydrogen Fueling Station and Vehicle Interface Safety Technical Report
Oct 2015
Publication
Hydrogen Infrastructures are currently being built up to support the initial commercialization of the fuel cell vehicle by multiple automakers. Three primary markets are presently coordinating a large build up of hydrogen stations: Japan; USA; and Europe to support this. Hydrogen Fuelling Station General Safety and Performance Considerations are important to establish before a wide scale infrastructure is established.This document introduces the ISO Tec Read More
Material Testing and Design Recommendations for Components Exposed to Hydrogen Enhanced Fatigue – the Mathryce Project
Sep 2013
Publication
The three years European MATHRYCE project dedicated to material testing and design recommendations for components exposed to hydrogen enhanced fatigue started in October 2012. Its main goal is to provide an “easy” to implement methodology based on lab-scale experimental tests under hydrogen gas to assess the service life of a real scale component taking into account fatigue loading under hydrogen gas. Dedicated experimental tests will be d Read More
Cylinders and Tubes Used as Buffers in Filling Stations
Oct 2015
Publication
Buffers are key components for hydrogen filling stations that are currently being developed. Type 1 or composite cylinders are used for this application. The type used depends on many parameters including pressure level cost and space available for the filling station. No international standards exist for such high pressure vessels whereas many standards exist covering Types 123 and 4 used for transport of gas or on-board fuel tanks. It is suggested to use t Read More
The CALIF3S-P2remics Software – An Application to Underexpanded Hydrogen Jet Deflagration
Sep 2019
Publication
To assess explosion hazard the French Institut de Radioprotection et de Sûreté Nucléaire (IRSN) is developing the P2REMICS software (for Partially PREMIxed Combustion Solver) on the basis of the generic CFD solver library CALIF3S (for Components Adaptive Library for Fluid Flow Simulation). Both P2REMICS and CALIF3S are in-house IRSN softwares released under an open-source license. CALIF3S-P2REMICS is dedicated to the simulation of explosion scena Read More
Mixed E-learning and Virtual Reality Pedagogical Approach for Innovative Hydrogen Safety Training for First Responders
Oct 2015
Publication
Within the scope of the HyResponse project the development of a specialised training programme is currently underway. Utilizing an andragogy approach to teaching distance learning is mixed with classroom instructors-led activities while hands-on training on a full-scale simulator is coupled with an innovative virtual reality based experience. Although the course is dedicated mainly to first responders provision has been made to incorporate not only simp Read More
Modelling Of Hydrogen Explosion on a Pressure Swing Adsorption Facility
Sep 2011
Publication
Computational fluid dynamic simulations have been performed in order to study the consequences of a hydrogen release from a pressure swing adsorption installation operating at 30 barg. The simulations were performed using FLACS-Hydrogen software from GexCon. The impact of obstruction partial confinement leak orientation and wind on the explosive cloud formation (size and explosive mass) and on explosion consequences is investigated. Read More
Comparative Study of Regulations, Codes and Standards and Practices on Hydrogen Fuelling Stations
Oct 2015
Publication
This work deals with a comparative study of regulations codes and standards for hydrogen fuelling station dedicated for light duty land vehicles in the following countries: United States (California) United Kingdom Italy Germany Canada Sweden Norway Denmark and Spain.The following technical components of a hydrogen fuelling station are included in the scope of the study: the hydrogen storage systems (cryogenic or compressed gases) Read More
Explosion and Fire Risk Analyses of Maritime Fuel Cell Rooms with Hydrogen
Sep 2017
Publication
A methodology for explosion and fire risk analyses in enclosed rooms is presented. The objectives of this analysis are to accurately predict the risks associated with hydrogen leaks in maritime applications and to use the approach to provide decision support regarding design and risk-prevention and risk mitigating measures. The methodology uses CFD tools and simpler consequence models for ventilation dispersion and explosion scenarios as well Read More
Fire Risk on High-pressure Full Composite Cylinders for Automotive Applications
Sep 2011
Publication
In the event of a fire the TPRD (Thermally activated Pressure Relief Device) prevents the high-pressure full composite cylinder from bursting by detecting high temperatures and releasing the pressurized gas. The current safety performance of both the vessel and the TPRD is demonstrated by an engulfing bonfire test. However there is no requirement concerning the effect of the TPRD release which may produce a hazardous hydrogen flame due to t Read More
Determination of Characteristic Parameters for the Thermal Decomposition of Epoxy Resin/carbon Fibre Composites in Cone Calorimeter
Sep 2011
Publication
The thermal degradation of two epoxy resin/carbon fiber composites which differ by their volume fractions in carbon fiber (56 and 59 vol%.) was investigated in cone calorimeter under air atmosphere with a piloted ignition. The external heat flux of cone calorimeter was varied up to 75 kW.m-2 to study the influence of the carbon fiber amount on the thermal decomposition of those composites. Thus main parameters of the thermal decomposition of t Read More
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