France
Hydrogen Fuel Cell Road Vehicles: State of the Art and Perspectives
Nov 2020
Publication
Driven by a small number of niche markets and several decades of application research fuel cell systems (FCS) are gradually reaching maturity to the point where many players are questioning the interest and intensity of its deployment in the transport sector in general. This article aims to shed light on this debate from the road transport perspective. It focuses on the description of the fuel cell vehicle (FCV) in order to understand its assets limitations Read More
Water Photo-Electrooxidation Using Mats of TiO2 Nanorods, Surface Sensitized by a Metal–Organic Framework of Nickel and 1,2-Benzene Dicarboxylic Acid
Apr 2021
Publication
Photoanodes comprising a transparent glass substrate coated with a thin conductive film of fluorine-doped tin oxide (FTO) and a thin layer of a photoactive phase have been fabricated and tested with regard to the photo-electro-oxidation of water into molecular oxygen. The photoactive layer was made of a mat of TiO2 nanorods (TDNRs) of micrometric thickness. Individual nanorods were successfully photosensitized with nanoparticles of a metal–organic f Read More
CFD Simulations of Large Scale LH2 Dispersion in Open Environment
Sep 2021
Publication
An inter-comparison among partners’ CFD simulations has been carried out within the EU-funded project PRESLHY to investigate the dispersion of the mixture cloud formed from large scale liquid hydrogen release. Rainout experiments performed by Health and Safety Executive (HSE) have been chosen for the work. From the HSE experimental series trial-11 was selected forsimulation due to its conditions where only liquid flow at the nozzle was a Read More
Energy Transition in France
May 2022
Publication
To address the climate emergency France is committed to achieving carbon neutrality by 2050. It plans to significantly increase the contribution of renewable energy in its energy mix. The share of renewable energy in its electricity production which amounts to 25.5% in 2020 should reach at least 40% in 2030. This growth poses several new challenges that require policy makers and regulators to act on the technological changes and expanding need for flexibi Read More
Spin Pinning Effect to Reconstructed Oxyhydroxide Layer on Ferromagnetic Oxides for Enhanced Water Oxidation
Jun 2021
Publication
Producing hydrogen by water electrolysis suffers from the kinetic barriers in the oxygen evolution reaction (OER) that limits the overall efficiency. With spin-dependent kinetics in OER to manipulate the spin ordering of ferromagnetic OER catalysts (e.g. by magnetization) can reduce the kinetic barrier. However most active OER catalysts are not ferromagnetic which makes the spin manipulation challenging. In this work we report a strategy with spin pinnin Read More
Towards Ecological Alternatives in Bearing Lubrication
Jun 2021
Publication
Hydrogen is the cleanest fuel available because its combustion product is water. The internal combustion engine can in principle and without significant modifications run on hydrogen to produce mechanical energy. Regarding the technological solution leading to compact engines a question to ask is the following: Can combustion engine systems be lubricated with hydrogen? In general since many applications such as in turbomachines is it possible Read More
Preliminary Risk Assessment (PRA) for Tests Planned in a Pilot Salt Cavern Hydrogen Storage in the Frame of the French Project STOPIL-H2
Sep 2021
Publication
The STOPIL-H2 project supported by the French Geodenergies research consortium aims to design a demonstrator for underground hydrogen storage in cavern EZ53 of the Etrez gas storage (France) operated by Storengy. Two types of tests are planned in this cavern: a tightness test with nitrogen and hydrogen then a cycling test during which the upper part of the cavern (approximately 200 m3) will be filled with hydrogen during 6 to 9 months. I Read More
Interaction of Hydrogen with the Bulk, Surface and Subsurface of Crystalline RuO2 from First Principles
Feb 2021
Publication
Hydrogen and its interaction with metal oxide surfaces is of major importance for a wide range of research and applied fields spanning from catalysis energy storage microelectronics to metallurgy. This paper reviews state of the art of first principles calculations on the well-known ruthenium oxide (RuO2) surface in its (110) orientation and its interaction with hydrogen. In addition to it the paper also fills gaps in knowledge with new calculations and results on th Read More
Validation of Selected Optical Methods for Assessing Polyethylene (PE) Liners Used in High Pressure Vessels for Hydrogen Storage
Jun 2021
Publication
A polyethylene (PE) liner is the basic element in high-pressure type 4 composite vessels designed for hydrogen or compressed natural gas (CNG) storage systems. Liner defects may result in the elimination of the whole vessel from use which is very expensive both at the manufacturing and exploitation stage. The goal is therefore the development of efficient non-destructive testing (NDT) methods to test a liner immediately after its manufacturing befor Read More
The Challenges of Hydrogen Storage on a Large Scale
Sep 2021
Publication
With the growing success of green hydrogen the general trend is for increased hydrogen production and large quantities of storage. Engie’s projects have grown from a few kilos of hydrogen to the quest for large scale production and associated storage – e.g. several tons or tens of tons. Although a positive sign for Engie’s projects it does inevitably result in challenges in new storage methods and in risks management related to such facilities; particularly w Read More
Hydrogen-air Vented Explosions- New Experimental Data
Sep 2013
Publication
The use of hydrogen as an energy carrier is a real perspective in Europe since a number of breakthroughs obtained in the last decades open the possibility to envision a deployment at the industrial scale if safety issues are duly accounted. However on this particular aspects experimental data are still lacking especially about the explosion dynamics in realistic dimensions. The purpose of this paper is to provide a set of totally new and well instrumented Read More
On the Use of Hydrogen in Confined Spaces: Results from the Internal Project InsHyde
Sep 2009
Publication
Alexandros G. Venetsanos,
Paul Adams,
Inaki Azkarate,
A. Bengaouer,
Marco Carcassi,
Angunn Engebø,
E. Gallego,
Olav Roald Hansen,
Stuart J. Hawksworth,
Thomas Jordan,
Armin Keßler,
Sanjay Kumar,
Vladimir V. Molkov,
Sandra Nilsen,
Ernst Arndt Reinecke,
M. Stöcklin,
Ulrich Schmidtchen,
Andrzej Teodorczyk,
D. Tigreat,
N. H. A. Versloot and
L. Boon-Brett
The paper presents an overview of the main achievements of the internal project InsHyde of the HySafe NoE. The scope of InsHyde was to investigate realistic small-medium indoor hydrogen leaks and provide recommendations for the safe use/storage of indoor hydrogen systems. Additionally InsHyde served to integrate proposals from HySafe work packages and existing external research projects towards a common effort. Following a state of t Read More
Feasibility of Hydrogen Detection by the Use of Uncoated Silicon Microcantilever-based Sensors
Sep 2013
Publication
Hydrogen is a key parameter to monitor radioactive disposal facility such as the envisioned French geological repository for nuclear wastes. The use of microcantilevers as chemical sensors usually involves a sensitive layer whose purpose is to selectively sorb the analyte of interest. The sorbed substance can then be detected by monitoring either the resonant frequency shift (dynamic mode) or the quasi-static deflection (static mode). The objective of t Read More
An Inter-comparison Exercise on Engineering Models Capabilities to Simulate Hydrogen Vented Explosions
Sep 2013
Publication
A benchmark exercise on vented explosion engineering model was carried out against the maximum overpressures (one or two peaks) of published experiments. The models evaluated are Bauwens et al. (2012-1 and 2012-2) [4 7] models Molkov Vent Sizing Technology 1999 2001 and 2008 models [12 13 6]. The experiments in consideration are Pasman et al. experiments (1974) (30% H2 - 1m3) [1] Bauwens et al. (2012) experiments (64m3) [4] Dau Read More
Experimental Determination of Minimum Ignition Current (MIC) for Hydrogen & Methane Mixtures for the Determination of the Explosion Group Corresponding to IEC 60079-20-1
Sep 2017
Publication
Power to gas could get an important issue in future permitting the valorisation of green electric excess energy by producing hydrogen mixing it with natural gas (NG) and use the NG grid as temporary storage. NG grid stakeholders expect that blends up to 20% seem to be a realistic scenario. The knowledge of the explosion group for these hydrogen/NG (H2NG) mixtures is a necessary information for the choice of equipment and protective systems intended f Read More
European Hydrogen Safety Training Programme for First Responders: Hyresponse Outcomes and Perspectives
Sep 2017
Publication
The paper presents the outcomes of the HyResponse project i.e. the European Hydrogen Safety Training Programme for first responders. The threefold training is described: the content of the educational training is presented the operational training platform and its mock-up real scale transport and hydrogen stationary installations are detailed and the innovative virtual tools and training exercises are highlighted. The paper underlines the outcomes the Read More
Effects of Oxidants on Hydrogen Spontaneous Ignition: Experiments and Modelling
Sep 2017
Publication
Experiments were performed on the influence of oxidants (air pure oxygen O2 and pure nitrous oxide N2O at atmospheric pressure) in the straight expansion tube after the burst disk on the hydrogen spontaneous ignition. The lowest pressure at which the spontaneous ignition is observed has been researched for a 4 mm diameter tube with a length of 10 cm for the two oxidant gases. The ignition phenomenon is observed with a high speed camera and the ex Read More
Combustion Modeling in Large Scale Volumes
Sep 2013
Publication
This paper is devoted to a benchmarking exercise of the EUROPLEXUS code against several large scale deflagration and detonation experimental data sets in order to improve its hydrogen combustion modeling capabilities in industrial settings. The code employs an algorithm for the propagation of reactive interfaces RDEM which includes a combustion wave as an integrable part of the Reactive Riemann problem propagating with a fundamental flame Read More
Identification and Monitoring of a PEM Electrolyser Based on Dynamical Modelling
Sep 2007
Publication
Hydrogen from water electrolysis associated with renewable energies is one of the most attractive solutions for the green energy storage. To improve the efficiency and the safety of such stations some technological studies are still under investigation both on methods and materials. As methods control monitoring and diagnosis algorithms are relevant tools. These methods are efficient when they use an accurate mathematical model representing Read More
Helium Release in A Closed Enclosure- Comparisons Between Simple Models, CFD Calculations And Experimental Results
Sep 2011
Publication
In the prospect of a safe use of hydrogen in our society one important task is to evaluate under which conditions the storage of hydrogen systems can reach a sufficient level of safety. One of the most important issues is the use of such system in closed area for example a private garage or an industrial facility. In the scope of this paper we are mainly interested in the following scenario: a relatively slow release of hydrogen (around 5Nl/min) in a closed and a Read More
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