France
Market Segmentation of Domestic and Commercial Natural Gas Appliances
Jan 2021
Publication
The main goal of the project is to enable the wide adoption of H2NG (hydrogen in natural gas) blends by closing knowledge gaps regarding technical impacts on residential and commercial gas appliances. The project consortium will identify and recommend appropriate codes and standards that should be adapted to answer the needs and develop a strategy for addressing the challenges for new and existing appliances.<br/>This deliverable on market segmentation is part of work package 2 and provides a quantitative segmentation of the gas appliance market in terms of appliance population numbers. It therefore prepares the project partners to perform the subsequent selection of the most representative product types to be tested in the laboratories of the THyGA partners.<br/>The classification is developed to categorise appliances installed in the field based on available statistics calculation methods and estimations. As a result appliance populations are provided for each technology segment that draw a representative picture of the installed end-use appliances within the European Union in 2020.
Effects of Purity and Pressure on the Hydrogen Embrittlement of Steels and Other Metallic Materials
Sep 2009
Publication
A study of open literature was performed to determine the effects of high hydrogen purity and gas pressure (in the range of 700-1000 bar) on the hydrogen embrittlement of several metallic materials. A particular focus was given to carbon low-alloy and stainless steels but information on embrittlement of aluminum and copper was included in the study. Additionally the most common test methods were studied and results from similar tests are presented in a manner so as to simplify comparisons of materials. Finally suggestions are provided for future testing necessary to ensure the safety of hydrogen storage at 700 bar.
On the Use of Spray Systems- An Example of R&D Work in Hydrogen Safety for Nuclear Applications
Sep 2007
Publication
The aim of the present work is to investigate the interaction between a water spray and a laminar hydrogen-air flame in the case of steam inerted mixture. A first work is devoted to study the thermodynamics involved in the phenomena via a lumped parameter code. The flow is two- phase and reactive the gas is multi-component the water spray is polydisperse and the droplet size has certainly an influence on the flame propagation. The energy released by the reaction between hydrogen and oxygen vaporizes suspended droplets. The next step of this study will be to consider a drift-flux model for the droplets and air under hypotheses that the velocity and thermal disequilibria are weak. The multi-component feature of the gas will be further taken into account by studying a gas mixture containing hydrogen air and water vapor. A second study concerns an experimental investigation of the effect of droplets on the flame propagation using a spherical vessel. A Schlieren system is coupled to the spherical vessel in order to record the flame propagation on a digital high speed camera. Both studies will help improve our knowledge of safety relevant phenomena.
Hydrogen Storage: Recent Improvements and Industrial Perspectives
Sep 2019
Publication
Efficient storage of hydrogen is crucial for the success of hydrogen energy markets (early markets as well as transportation market). Hydrogen can be stored either as a compressed gas a refrigerated liquefied gas a cryo-compressed gas or in hydrides. This paper gives an overview of hydrogen storage technologies and details the specific issues and constraints related to the materials behaviour in hydrogen and conditions representative of hydrogen energy uses. It is indeed essential for the development of applications requiring long-term performance to have good understanding of long-term behaviour of the materials of the storage device and its components under operational loads.
Energy integration – The Covid-19 Crisis and Clean Energy Progress – Analysis Report
Jun 2020
Publication
The Covid-19 pandemic has dealt a massive blow to countries around the world choking economies and transforming daily life for billions of people. This extraordinary disruption has significantly impacted the energy sector with worrying implications for clean energy transitions. Some key clean energy technologies have been encouragingly resilient to the effects of the crisis but so far there is little to suggest that the dramatic structural progress needed to achieve long-term climate and energy goals will happen in the current turmoil. Unprecedented action and leadership from governments companies and other real-world decision makers will be required to put the world more firmly on a sustainable long-term pathway. The energy sector must achieve dramatic sustained emissions reductions through policy investment and innovation measures across all energy sectors and technologies.
Building on Tracking Clean Energy Progress 2020 and other COVID-19 analysis this article takes stock of how the crisis has affected energy sectors and technologies thus far and explores the potential implications for clean energy transitions over the medium and longer term.
Link to Document on IEA Website
Building on Tracking Clean Energy Progress 2020 and other COVID-19 analysis this article takes stock of how the crisis has affected energy sectors and technologies thus far and explores the potential implications for clean energy transitions over the medium and longer term.
Link to Document on IEA Website
Static and Dynamic Studies of Hydrogen Adsorption on Nanoporous Carbon Gels
Jun 2019
Publication
Although hydrogen is considered to be one of the most promising green fuels its efficient and safe storage and use still raise several technological challenges. Physisorption in porous materials may offer an attractive means of storage but the state-of-the-art capacity of these kinds of systems is still limited. To overcome the present drawbacks a deeper understanding of the adsorption and surface diffusion mechanism is required along with new types of adsorbents developed and/or optimised for this purpose. In the present study we compare the hydrogen adsorption behaviour of three carbon gels exhibiting different porosity and/or surface chemistry. In addition to standard adsorption characterisation techniques neutron spin-echo spectroscopy (NSE) has been also applied to explore the surface mobility of the adsorbed hydrogen. Our results reveal that both the porosity and surface chemistry of the adsorbent play a significant role in the adsorption of in these systems.
CFD Validation Against Large Scale Liquified Helium Release
Sep 2019
Publication
The ADREA-HF CFD code is validated against a large scale liquefied helium release experiment on flat ground performed by INERIS in the past. The predicted release and dispersion behavior is evaluated against the experimental using temperature time histories at sensors deployed at various distances and heights downstream the source. For the selected sensors the temperature predictions are generally in good agreement with the experimental with a tendency to under-predict temperature as the source is approached.
20 Years of Carbon Capture and Storage - Accelerating Future Deployment
Nov 2016
Publication
Carbon capture and storage (CCS) technologies are expected to play a significant part in the global climate response. Following the ratification of the Paris Agreement the ability of CCS to reduce emissions from fossil fuel use in power generation and industrial processes – including from existing facilities – will be crucial to limiting future temperature increases to ""well below 2°C"" as laid out in the Agreement. CCS technology will also be needed to deliver ""negative emissions"" in the second half of the century if these ambitious goals are to be achieved.
CCS technologies are not new. This year is the 20th year of operation of the Sleipner CCS Project in Norway which has captured almost 17 million tonnes of CO2 from an offshore natural gas production facility and permanently stored them in a sandstone formation deep under the seabed. Individual applications of CCS have been used in industrial processes for decades and projects injecting CO2 for enhanced oil recovery (EOR) have been operating in the United States since the early 1970s.
This publication reviews progress with CCS technologies over the past 20 years and examines their role in achieving 2°C and well below 2°C targets. Based on the International Energy Agency’s 2°C scenario it also considers the implications for climate change if CCS was not a part of the response. And it examines opportunities to accelerate future deployment of CCS to meet the climate goals set in the Paris Agreement.
Link to Document on IEA Website
CCS technologies are not new. This year is the 20th year of operation of the Sleipner CCS Project in Norway which has captured almost 17 million tonnes of CO2 from an offshore natural gas production facility and permanently stored them in a sandstone formation deep under the seabed. Individual applications of CCS have been used in industrial processes for decades and projects injecting CO2 for enhanced oil recovery (EOR) have been operating in the United States since the early 1970s.
This publication reviews progress with CCS technologies over the past 20 years and examines their role in achieving 2°C and well below 2°C targets. Based on the International Energy Agency’s 2°C scenario it also considers the implications for climate change if CCS was not a part of the response. And it examines opportunities to accelerate future deployment of CCS to meet the climate goals set in the Paris Agreement.
Link to Document on IEA Website
The CALIF3S-P2remics Software – An Application to Underexpanded Hydrogen Jet Deflagration
Sep 2019
Publication
To assess explosion hazard the French Institut de Radioprotection et de Sûreté Nucléaire (IRSN) is developing the P2REMICS software (for Partially PREMIxed Combustion Solver) on the basis of the generic CFD solver library CALIF3S (for Components Adaptive Library for Fluid Flow Simulation). Both P2REMICS and CALIF3S are in-house IRSN softwares released under an open-source license. CALIF3S-P2REMICS is dedicated to the simulation of explosion scenarii (explosive atmosphere formation deflagration or detonation and blast waves propagation) for hydrogen as more generally for any explosive gas or gas/dust mixture. It is based on staggered space discretizations and implements fractional-steps time algorithms well suited for massively parallel computations. A wide range of experiments is used for the software validation. Among them we focus here on a free underexpanded hydrogen jet deflagration performed in two steps: first the hydrogen is released in air up to obtain a steady jet (dispersion phase) then the deflagration is triggered. For the dispersion phase simulation a notional nozzle approach is used to get rid of the description of the shocked zone located near the nozzle. Then a so-called turbulent flame velocity approach is chosen for the deflagration simulation. The computations allow to highlight the complex flow structures induced by the inhomogeneity fuel concentration in the jet. A large dispersion of results is observed depending on the chosen correlation for the turbulent flame speed.
European Hydrogen Safety Training Platform for First Responders- Hyresponse Project
Sep 2013
Publication
The paper presents HyResponse project i.e. a European Hydrogen Safety Training Platform that targets to train First responders to acquire professional knowledge and skills to contribute to FCH permitting process as approving authority. The threefold training program is described: educational training operational-level training on mock-up real scale transport and hydrogen stationary installations and innovative virtual training exercises reproducing entire accident scenarios. The paper highlights how the three pilot sessions for European First Responders in a face to face mode will be organized to get a feedback on the training program. The expected outputs are also presented i.e. the Emergency Response Guide and a public website including teaching material and online interactive virtual training.
Status of the Pre-normative Research Project PRESLHY for the Safe Use of LH2
Sep 2019
Publication
Liquid hydrogen (LH2) compared to compressed gaseous hydrogen offers advantages for large scale transport and storage of hydrogen with higher densities and potentially better safety performance. Although the gas industry has good experience with LH2 only little experience is available for the new applications of LH2 as an energy carrier. Therefore the European FCH JU funded project PRESLHY conducts pre-normative research for the safe use of cryogenic LH2 in non-industrial settings. The work program consists of a preparatory phase where the state of the art before the project has been summarized and where the experimental planning was adjusted to the outcome of a research priorities workshop. The central part of the project consists of 3 phenomena oriented work packages addressing Release Ignition and Combustion with analytical approaches experiments and simulations. The results shall improve the general understanding of the behavior of LH2 in accidents and thereby enhance the state-of-the-art what will be reflected in appropriate recommendations for development or revision of specific international standards. The paper presents the status of the project at the middle of its terms.
Detonation Dynamics in a Curved Chamber for an Argon Diluted Hydrogen-oxygen Mixture
Sep 2019
Publication
The dynamics of detonation transmission from a straight channel into a curved chamber was investigated as a function of initial pressure using a combined experimental and numerical study. Hi-speed Schlieren and *OH chemiluminescense were used for flow visualization; numerical simulations considered the two-dimensional reactive Euler equations with detailed chemistry. Results show the highly transient sequence of events (i.e. detonation diffraction re-initiation attempts and wave reflections) that precede the formation of a steadily rotating Mach detonation along the outer wall of the chamber. An increase in pressure from 15 kPa to 26 kPa expectedly resulted in detonations that are less sensitive to diffraction. Local quenching of the initial detonation occurred for all pressures considered. The location where this decoupling occurred along the inner wall determined the location where transition from regular reflection to a rather complex wave structure occurred along the outer wall. This complex wave structure includes a steadily rotating Mach detonation (stem) an incident decoupled shock-reaction zone region and a transverse detonation that propagates in pre-shocked mixture.
Indoor Use of Hydrogen, Knowledge Gaps and Priorities for the Improvement of Current Standards on Hydrogen, a Presentation of HyIndoor European Project
Sep 2013
Publication
To develop safety strategies for the use of hydrogen indoors the HyIndoor project is studying the behaviour of a hydrogen release deflagration or non-premixed flame in an enclosed space such as a fuel cell or its cabinet a room or a warehouse. The paper proposes a safety approach based on safety objectives that can be used to take various scenarios of hydrogen leaks into account for the safe design of Hydrogen and Fuel Cell (HFC) early market applications. Knowledge gaps on current engineering models and unknown influence of specific parameters were identified and prioritized thereby re-focusing the objectives of the project test campaign and numerical simulations. This approach will enable the improvement of the specification of openings and use of hydrogen sensors for enclosed spaces. The results will be disseminated to all stakeholders including hydrogen industry and RCS bodies.
Magnesium Based Materials for Hydrogen Based Energy Storage: Past, Present and Future
Jan 2019
Publication
Volodymyr A. Yartys,
Mykhaylo V. Lototskyy,
Etsuo Akiba,
Rene Albert,
V. E. Antonov,
Jose-Ramón Ares,
Marcello Baricco,
Natacha Bourgeois,
Craig Buckley,
José Bellosta von Colbe,
Jean-Claude Crivello,
Fermin Cuevas,
Roman V. Denys,
Martin Dornheim,
Michael Felderhoff,
David M. Grant,
Bjørn Christian Hauback,
Terry D. Humphries,
Isaac Jacob,
Petra E. de Jongh,
Jean-Marc Joubert,
Mikhail A. Kuzovnikov,
Michel Latroche,
Mark Paskevicius,
Luca Pasquini,
L. Popilevsky,
Vladimir M. Skripnyuk,
Eugene I. Rabkin,
M. Veronica Sofianos,
Alastair D. Stuart,
Gavin Walker,
Hui Wang,
Colin Webb,
Min Zhu and
Torben R. Jensen
Magnesium hydride owns the largest share of publications on solid materials for hydrogen storage. The “Magnesium group” of international experts contributing to IEA Task 32 “Hydrogen Based Energy Storage” recently published two review papers presenting the activities of the group focused on magnesium hydride based materials and on Mg based compounds for hydrogen and energy storage. This review article not only overviews the latest activities on both fundamental aspects of Mg-based hydrides and their applications but also presents a historic overview on the topic and outlines projected future developments. Particular attention is paid to the theoretical and experimental studies of Mg-H system at extreme pressures kinetics and thermodynamics of the systems based on MgH2 nanostructuring new Mg-based compounds and novel composites and catalysis in the Mg based H storage systems. Finally thermal energy storage and upscaled H storage systems accommodating MgH2 are presented.
1D Phenomenological Model Estimating the Overpressure which could be Generated by Gas Explosion in a Congested Space
Sep 2005
Publication
A phenomenological approach is developed to calculate the velocity of flame propagation and to estimate the value of pressure peak when igniting gaseous combustible mixtures in a congested space. The basic idea of this model is afterburning of the remanent fuel in pockets of congested space behind the flame front. The estimation of probable overpressure peak is based on solution of one-dimensional problem of the piston (having corresponding symmetry) moving with given velocity in polytropic gas. Submitted work is the first representation of such phenomenological approach and is realized for the simplest situation close to one-dimensional.
Hydrogen Refueling Stations: Safe Filling Procedures
Sep 2005
Publication
Safety is a high priority for a hydrogen refueling station. Here we propose a method to safely refuel a vehicle at optimised speed of filling with minimum information about it. Actually we identify two major risks during a vehicle refuelling: over filling and overheating. These two risks depend on the temperature increase in the tank during refuelling. But the inside temperature is a difficult information to get from the station point of view. It assumes a temperature sensor in a representative place of the tank and an additional connection between the vehicle and the station for data exchange. The refuelling control may not depend on this parameter only. Therefore out objective was to effectively control the filling particularly to avoid the two identified risks independently of optional and safety redundant information from the vehicle. For that purpose we defined a maximum filling pressure which corresponds to the most severe following conditions: if the maximum temperature is reached in the tank or if the maximum capacity is reached in the tank. This maximum pressure depends on a few filling parameters which are easily available. The method and its practical applications are depicted.
Determination Of Hazardous Zones For A Generic Hydrogen Station – A Case Study
Sep 2007
Publication
A method for determination of hazardous zones for hydrogen installations has been studied. This work has been carried out within the NoE HySafe. The method is based on the Italian Method outlined in Guide 31-30(2004) Guide 31–35(2001) Guide 31-35/A(2001) and Guide 31-35/A; V1(2003). Hazardous zones for a “generic hydrogen refuelling station”(HRS) are assessed based on this method. The method is consistent with the EU directive 1999/92/EC “Safety and Health Protection of Workers potentially at risk from explosive atmospheres” which is the basis for determination of hazardous zones in Europe. This regulation is focused on protection of workers and is relevant for hydrogen installations such as hydrogen refuelling stations repair shops and other stationary installations where some type of work operations will be involved. The method is also based on the IEC standard and European norm IEC/EN60079-10 “Electrical apparatus for explosive gas atmospheres. Part 10 Classification of hazardous areas”. This is a widely acknowledged international standard/norm and it is accepted/approved by Fire and Safety Authorities in Europe and also internationally. Results from the HySafe work and other studies relevant for hydrogen and hydrogen installations have been included in the case study. Sensitivity studies have been carried out to examine the effect of varying equipment failure frequencies and leak sizes as well as environmental condition (ventilation obstacles etc.). The discharge and gas dispersion calculations in the Italian Method are based on simple mathematical formulas. However in this work also CFD (Computational Fluid Dynamics) and other simpler numerical tools have been used to quantitatively estimate the effect of ventilation and of different release locations on the size of the flammable gas cloud. Concentration limits for hydrogen to be used as basis for the extent of the hazardous zones in different situations are discussed.
Gaseous Hydrogen Refueling Stations: Selection Of Materials For High Pressure Hydrogen Fueling Connectors
Sep 2005
Publication
Design of hydrogen fueling components is critical for safety and reliability. Intensive usage of such components in urban public environment is expected in the near future. Any leakage of gas or failure of equipment will create potential hazards. Materials for such category of equipment must have specific mechanical characteristics including hardness (influence on the durability of the equipment and on the resistance to hydrogen) and be easy to machine. Air Liquide has developed a test program for qualifying equipment representing the present state of the art. Studies on the susceptibility of various steels to hydrogen embrittlement have been done. Test specimens were exposed to static and cyclic loads with hydrogen and an inert gas the inert gas representing a reference. Various tests are described here. As a result the importance of further development in the design and selection of appropriate materials for critical hydrogen components is required. Various options are presented and discussed.
Determination of Characteristic Parameters for the Thermal Decomposition of Epoxy Resin/carbon Fibre Composites in Cone Calorimeter
Sep 2011
Publication
The thermal degradation of two epoxy resin/carbon fiber composites which differ by their volume fractions in carbon fiber (56 and 59 vol%.) was investigated in cone calorimeter under air atmosphere with a piloted ignition. The external heat flux of cone calorimeter was varied up to 75 kW.m-2 to study the influence of the carbon fiber amount on the thermal decomposition of those composites. Thus main parameters of the thermal decomposition of two different composites were determined such as: mass loss mass loss rate ignition time thermal response parameter ignition temperature critical heat flux thermal inertia and heat of gasification. As a result all the parameters that characterize the thermal resistance of composites are decreased when the carbon fiber volume fraction is increased.
Data for the Evaluation of Hydrogen Risks Onboard Vehicles: Outcomes from the French Project Drive
Sep 2011
Publication
From 2006 to 2009 INERIS alongside with CEA PSA PEUGEOT CITROËN and IRPHE were involved in a project called DRIVE. Its objective was to provide data on the whole reaction chain leading to a hydrogen hazard onboard a vehicle. Out of the three types of leakage identified by the consortium (permeation chronic and accidental) the chronic leakage taking place within the engine was judged to be more problematic since it can feature a high probability of occurrence and a significant release flow rate (up to 100 NL/min). Ignition tests carried out within a real and dummy engine compartment showed that pressure effects due to an explosion will be relatively modest provided that the averaged hydrogen concentration in this area is limited to 10% vol/vol which would correspond to a maximum release flow of 10 NL/min. This maximum concentration could be used as a threshold value for detection or as a target while designing the vehicle. Jet fire experiments were also conducted in the frame of the DRIVE project. It was found that pressure-relief devices (PRDs) might be unsuited to protect humans from the explosion of a tank caused by a bonfire. Other solutions are proposed in this paper.
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