Finland

Power-to-Gas technologies offer a promising approach for converting renewable electricity into a molecular form (fuel) to serve the energy demands of non-electric energy applications in all end-use sectors. The technologies have been broadly developed and are at the edge of a mass roll-out. The barriers that Power-to-Gas faces are no longer technical but are foremost regulatory and economic. This study focuses on a Power-to-Gas pathway where electricity is first converted in a water electrolyzer into hydrogen which is then synthetized with carbon dioxide to produce synthetic natural gas. A key aspect of this pathway is that an intermittent electricity supply could be used which could reduce the amount of electricity curtailment from renewable energy generation. Interim storages would then be necessary to decouple the synthesized part from hydrogen production to enable (I) longer continuous operation cycles for the methanation reactor and (II) increased annual full-load hours leading to an overall reduction in gas production costs. This work optimizes a Power-to-Gas plant configuration with respect to the cost benefits using a Monte Carlo-based simulation tool. The results indicate potential cost reductions of up to 17% in synthetic natural gas production by implementing well-balanced components and interim storages. This study also evaluates three different power sources which differ greatly in their optimal system configuration. Results from time-resolved simulations and sensitivity analyses for different plant designs and electricity sources are discussed with respect to technical and economic implications so as to facilitate a plant design process for decision makers.

The 2018 IPCC (The Intergovernmental Panel on Climate Change’s) report defined the goal to limit global warming to 1.5 ◦C by 2050. This will require “rapid and far-reaching transitions in land energy industry buildings transport and cities”. The challenge falls on all sectors especially energy production and industry. In this regard the recent progress and future challenges of greenhouse gas emissions and energy supply are first briefly introduced. Then the current situation of the steel industry is presented. Steel production is predicted to grow by 25–30% by 2050. The dominant iron-making route blast furnace (BF) especially is an energy-intensive process based on fossil fuel consumption; the steel sector is thus responsible for about 7% of all anthropogenic CO2 emissions. In order to take up the 2050 challenge emissions should see significant cuts. Correspondingly specific emissions (t CO2/t steel) should be radically decreased. Several large research programs in big steelmaking countries and the EU have been carried out over the last 10–15 years or are ongoing. All plausible measures to decrease CO2 emissions were explored here based on the published literature. The essential results are discussed and concluded. The specific emissions of “world steel” are currently at 1.8 t CO2/t steel. Improved energy efficiency by modernizing plants and adopting best available technologies in all process stages could decrease the emissions by 15–20%. Further reductions towards 1.0 t CO2/t steel level are achievable via novel technologies like top gas recycling in BF oxygen BF and maximal replacement of coke by biomass. These processes are however waiting for substantive industrialization. Generally substituting hydrogen for carbon in reductants and fuels like natural gas and coke gas can decrease CO2 emissions remarkably. The same holds for direct reduction processes (DR) which have spread recently exceeding 100 Mt annual capacity. More radical cut is possible via CO2 capture and storage (CCS). The technology is well-known in the oil industry; and potential applications in other sectors including the steel industry are being explored. While this might be a real solution in propitious circumstances it is hardly universally applicable in the long run. More auspicious is the concept that aims at utilizing captured carbon in the production of chemicals food or fuels e.g. methanol (CCU CCUS). The basic idea is smart but in the early phase of its application the high energy-consumption and costs are disincentives. The potential of hydrogen as a fuel and reductant is well-known but it has a supporting role in iron metallurgy. In the current fight against climate warming H2 has come into the “limelight” as a reductant fuel and energy storage. The hydrogen economy concept contains both production storage distribution and uses. In ironmaking several research programs have been launched for hydrogen production and reduction of iron oxides. Another global trend is the transfer from fossil fuel to electricity. “Green” electricity generation and hydrogen will be firmly linked together. The electrification of steel production is emphasized upon in this paper as the recycled scrap is estimated to grow from the 30% level to 50% by 2050. Finally in this review all means to reduce specific CO2 emissions have been summarized. By thorough modernization of production facilities and energy systems and by adopting new pioneering methods “world steel” could reach the level of 0.4–0.5 t CO2/t steel and thus reduce two-thirds of current annual emissions.

Green hydrogen is identified as one of the prime clean energy carriers due to its high energy density and a zero emission of CO2. A possible solution for the transport of H2 in a safe and low-cost way is in the form of liquid organic hydrogen carriers (LOHCs). As an alternative to loading LOHC with H2 via a two-step procedure involving preliminary electrolytic production of H2 and subsequent chemical hydrogenation of the LOHC we explore here the possibility of electrochemical hydrogen storage (EHS) via conversion of proton of a proton donor into a hydrogen atom involved in covalent bonds with the LOHC (R) via a proton-coupled electron transfer (PCET) reaction: . 2 + +2 ― + ox↔ 0 2red We chose 9-fluorenone/fluorenol (Fnone/Fnol) conversion as such a model PCET reaction. The electrochemical activation of Fnone via two sequential electron transfers was monitored with in-situ and operando spectroscopies in absence and in presence of different alcohols as proton donors of different reactivity which enabled us to both quantify and get the mechanistic insight on PCET. The possibility of hydrogen extraction from the loaded carrier molecule was illustrated by chemical activation.

This study sheds light on the Hydrogen technology in transportation for reaching the sustainability goals of societies illustrated by the case of Mexico. In terms of the affected supply chains the study explores how the packaging and distribution of a fuel-saving tool that allows the adoption of hydrogen as complementary energy for maritime transportation to improve economic and environmental performance in Mexico. This exploratory study performs interviews observations simulations and tests involving producers suppliers and users at 26 ports in Mexico. The study shows that environmental and economic performance are related to key processes in Supply Chain Management (SCM) in which packaging and distribution are critical for achieving logistics and transportation sustainability goals. Reusable packaging and the distribution of a fuel-saving tool can help decrease costs - of transport and downstream/upstream processes in SCM while at the same time increasing the environmental performance.

The competitiveness of biofuels may be increased by integrating biomass gasification plants with electrolysis units which generate hydrogen to be combined with carbon-rich syngas. This option allows increasing the yield of the final product by retaining a higher amount of biogenic carbon and improving the resilience of the energy sector by favoring electric grid services and sector coupling. This article illustrates a techno-economic comparative analysis of three flexible power and biomass to methanol plants based on different gasification technologies: direct gasification indirect gasification and sorptionenhanced gasification. The design and operational criteria of each plant are conceived to operate both without green hydrogen addition (baseline mode) and with hydrogen addition (enhanced mode) following an intermittent use of the electrolysis system which is turned on when the electricity price allows an economically viable hydrogen production. The methanol production plants include a gasification section syngas cleaning conditioning and compression section methanol synthesis and purification and heat recovery steam cycle to be flexibly operated. Due to the high oxygen demand in the gasifier the direct gasification-based plant obtains a great advantage to be operated between a minimum load to satisfy the oxygen demand at high electricity prices and a maximum load to maximize methanol production at low electricity prices. This allows avoiding large oxygen storages with significant benefits for Capex and safety issues. The analysis reports specific fixed-capital investments between 1823 and 2048 €/kW of methanol output in the enhanced operation and LCOFs between 29.7 and 31.7 €/GJLHV. Economic advantages may be derived from a decrease in the electrolysis capital investment especially for the direct gasification-based plants which employ the greatest sized electrolyzer. Methanol breakeven selling prices range between 545 and 582 €/t with the 2019 reference Denmark electricity price curve and between 484 and 535 €/t with an assumed modified electricity price curve of a future energy mix with increased penetration of intermittent renewables.

In FY-20 India’s steel production was 109 MT and it is the second-largest steel producer on the planet after China. India’s per capita consumption of steel was around 75 kg which has risen from 59 kg in FY-14. Despite the increase in consumption it is much lower than the average global consumption of 230 kg. The per capita consumption of steel is one of the strongest indicators of economic development across the nation. Thus India has an ambitious plan of increasing steel production to around 250 MT and per capita consumption to around 160 kg by the year 2030. Steel manufacturers in India can be classified based on production routes as (a) oxygen route (BF/BOF route) and (b) electric route (electric arc furnace and induction furnace). One of the major issues for manufacturers of both routes is the availability of raw materials such as iron ore direct reduced iron (DRI) and scrap. To achieve the level of 250 MT steel manufacturers have to focus on improving the current process and product scenario as well as on research and development activities. The challenge to stop global warming has forced the global steel industry to strongly cut its CO2 emissions. In the case of India this target will be extremely difficult by ruling in the production duplication planned by the year 2030. This work focuses on the recent developments of various processes and challenges associated with them. Possibilities and opportunities for improving the current processes such as top gas recycling increasing pulverized coal injection and hydrogenation as well as the implementation of new processes such as HIsarna and other CO2 -lean iron production technologies are discussed. In addition the eventual transition to hydrogen ironmaking and “green” electricity in smelting are considered. By fast-acting improvements in current facilities and brave investments in new carbon-lean technologies the CO2 emissions of the Indian steel industry can peak and turn downward toward carbon-neutral production.

The depletion of fossil fuels and onset of global warming dictate the achievement of efficient technologies for clean and renewable energy sources. The conversion of solar energy into chemical energy plays a vital role both in energy production and environmental protection. A photocatalytic approach for H2 production and CO2 reduction has been identified as a promising alternative for clean energy production and CO2 conversion. In this process the most critical parameter that controls efficiency is the development of a photocatalyst. Two-dimensional nanomaterials have gained considerable attention due to the unique properties that arise from their morphology. In this paper examples on the development of different 2D structures as photocatalysts in H2 production and CO2 reduction are discussed and a perspective on the challenges and required improvements is given.

Seasonal underground hydrogen storage (UHS) in porous media provides an as yet untested method for storing surplus renewable energy and balancing our energy demands. This study investigates the technical suitability for UHS in depleted hydrocarbon fields and one deep aquifer site in Taranaki Basin Aotearoa New Zealand. Prospective sites are assessed using a decision tree approach providing a “fast-track” method for identifying potential sites and a decision matrix approach for ranking optimal sites. Based on expert elicitation the most important factors to consider are storage capacity reservoir depth and parameters that affect hydrogen injectivity/withdrawal and containment. Results from both approaches suggest that Paleogene reservoirs from gas (or gas cap) fields provide the best option for demonstrating UHS in Aotearoa New Zealand and that the country’s projected 2050 hydrogen storage demand could be exceeded by developing one or two high ranking sites. Lower priority is assigned to heterolithic and typically finer grained labile and clay-rich Miocene oil reservoirs and to deep aquifers that have no proven hydrocarbon containment.

Clean energy technological innovations are widely acknowledged as a prerequisite to achieving ambitious longterm energy and climate targets. However the optimal speed of their adoption has been parsimoniously studied in the literature. This study seeks to identify the optimal intensity of moving to a green hydrogen electricity sector in Greece using the OSeMOSYS energy modeling framework. Green hydrogen policies are evaluated first on the basis of their robustness against uncertainty and afterwards against conflicting performance criteria and for different decision-making profiles towards risk by applying the VIKOR and TOPSIS multi-criteria decision aid methods. Although our analysis focuses exclusively on the power sector and compares different rates of hydrogen penetration compared to a business-as-usual case without considering other game-changing innovations (such as other types of storage or carbon capture and storage) we find that a national transition to a green hydrogen economy can support Greece in potentially cutting at least 16 MtCO2 while stimulating investments of EUR 10–13 bn. over 2030–2050.

As the European Union intensifies its response to the climate emergency increased focus has been placed on the hard-to-abate energy-intensive industries. Primary among these is the steel industry a cornerstone of the European economy and industry. With the emergence of new hydrogen-based steelmaking options particularly through hydrogen direct reduction the structure of global steel production and supply chains will transition from being based on low-cost coal resources to that based on low-cost electricity and therefore hydrogen production. This study examines the techno-economic options for three European countries of Germany Spain and Finland under five different steel supply chain configurations compared to local production. Results suggest that the high costs of hydrogen transportation make a European steelmaking supply chain cost competitive to steel produced with imported hydrogen with local production costs ranging from 465-545 €/t of crude steel (CS) and 380-494 €/tCS for 2030 and 2040 respectively. Conversely imports of hot briquetted iron and crude steel from Morocco become economically competitive with European supply chains. Given the capital and energy intensive nature of the steel industry critical investment decisions are required in this decade and this research serves to provide a deeper understanding of supply chain options for Europe.