Spain
Prospective Life Cycle Assessment of Hydrogen Production by Waste Photoreforming
Jan 2022
Publication
Identifying sustainable energy vectors is perhaps one of the most critical issues that needs addressing to achieve a climate-neutral society by 2050. In this context the hydrogen economy has been proposed as a solution to mitigate our current fossil-based energy system while the concept of the circular economy aims to boost the efficient use of resources. Photoreforming offers a promising opportunity for recycling and transforming widely availa Read More
Potential for Hydrogen Production from Biomass Residues in the Valencian Community
Sep 2007
Publication
The production of hydrogen from renewable sources is essential to develop the future hydrogen economy. Biomass is an abundant clean and renewable energy source and it can be important in the production of hydrogen. The Valencian Community due to its great agricultural and forestry activities generates an important quantity of biomass residues that can be used for energy generation approximately 778 kt of wet biomass residues per year. This gr Read More
Flame Propagation Near the Limiting Conditions in a Thin Layer Geometry
Sep 2019
Publication
A series of experiments on hydrogen flame propagation in a thin layer geometry is presented. Premixed hydrogen-air compositions in the range from 6 to 15%(vol.) H2 are tested. Semi-open vertical combustion chamber consists of two transparent Plexiglas side walls with main dimensions of 90x20 cm with a gap from 1 to 10 mm in between. Test mixtures are ignited at the open end of the chamber so that the flame propagates towards the closed end. Read More
Integration of Experimental Facilities: A Joint Effort for Establishing a Common Knowledge Base in Experimental Work on Hydrogen Safety
Sep 2009
Publication
With regard to the goals of the European HySafe Network research facilities are essential for the experimental investigation of relevant phenomena for testing devices and safety concepts as well as for the generation of validation data for the various numerical codes and models. The integrating activity ‘Integration of Experimental Facilities (IEF)’ has provided basic support for jointly performed experimental work within HySafe. Even beyond the fu Read More
Hydrogen vs. Battery-Based Propulsion Systems in Unipersonal Vehicles—Developing Solutions to Improve the Sustainability of Urban Mobility
May 2021
Publication
The percentage of the population in urban areas has increased by ten points from 2000 (46%) to 2020 (56%); it is expected to reach up to 70% by 2050. This undoubtedly will encourage society to use alternative transports. On the other hand the widespread fear of pandemics seems to be here to stay and it is causing most people to leave public transport to use private cars and a few have chosen unipersonal electric vehicles. As a consequence the decis Read More
The Potential of Gas Switching Partial Oxidation Using Advanced Oxygen Carriers for Efficient H2 Production with Inherent CO2 Capture
May 2021
Publication
The hydrogen economy has received resurging interest in recent years as more countries commit to net-zero CO2 emissions around the mid-century. “Blue” hydrogen from natural gas with CO2 capture and storage (CCS) is one promising sustainable hydrogen supply option. Although conventional CO2 capture imposes a large energy penalty advanced process concepts using the chemical looping principle can produce blue hydrogen at efficiencies even e Read More
Transportation in a 100% Renewable Energy System
Jan 2018
Publication
A 100% renewable economy would give a lasting solution to the challenges raised by climate change energy security sustainability and pollution. The conversion of the present transport system appears to be one of the most difficult aspects of such renewable transition. This study reviews the technologies and systems that are being proposed or proven as alternative to fossil-fuel based transportation and their prospects for their entry into the post-c Read More
Absence of Spillover of Hydrogen Adsorbed on Small Palladium Clusters Anchored to Graphene Vacancies
May 2021
Publication
Experimental evidence exists for the enhancement of the hydrogen storage capacity of porous carbons when these materials are doped with metal nanoparticles. One of the most studied dopants is palladium. Dissociation of the hydrogen molecules and spillover of the H atoms towards the carbon substrate has been advocated as the reason for the enhancement of the storage capacity. We have investigated this mechanism by performing a Read More
Analysis of Stress Corrosion Cracking in X80 Pipeline Steel: An Approach from the Theory of Critical Distances
Dec 2018
Publication
This paper presents an analysis of Stress Corrosion Cracking (SCC) based on the Theory of Critical Distances (TCD). The research is based on an experimental program composed of fracture specimens with notch radius varying from 0 mm (crack-like defect) up to 1 mm and tensile specimens. A pipeline steel was used in this work (X80). It has been analysed in one hydrogen embrittlement situation. The study has been completed with Finite Elements Simulat Read More
Gaseous Fueling of an Adapted Commercial Automotive Spark-ignition Engine: Simplified Thermodynamic Modeling and Experimental Study Running on Hydrogen, Methane, Carbon Monoxide and their Mixtures
Dec 2022
Publication
In the present work methane carbon monoxide hydrogen and the binary mixtures 20 % CH4–80 % H2 80 % CH4–20 % H2 25 % CO–75 % H2 (by volume) were considered as fuels of a naturally aspirated port-fuel injection four-cylinder Volkswagen 1.4 L spark-ignition (SI) engine. The interest in these fuels lies in the fact that they can be obtained from renewable resources such as the fermentation or gasification of residual biomasses as well as the electrol Read More
Direct Route from Ethanol to Pure Hydrogen through Autothermal Reforming in a Membrane Reactor: Experimental Demonstration, Reactor Modelling and Design
Nov 2020
Publication
This work reports the integration of thin (~3e4 mm thick) Pd-based membranes for H2 separation in a fluidized bed catalytic reactor for ethanol auto-thermal reforming. The performance of a fluidized bed membrane reactor has been investigated from an experimental and numerical point of view. The demonstration of the technology has been carried out over 50 h under reactive conditions using 5 thin Pd-based alumina-supported membranes a Read More
Cohesive Zone Modelling of Hydrogen Assisted Fatigue Crack Growth: The Role of Trapping
Apr 2022
Publication
We investigate the influence of microstructural traps in hydrogen-assisted fatigue crack growth. To this end a new formulation combining multi-trap stress-assisted diffusion mechanism-based strain gradient plasticity and a hydrogen- and fatigue-dependent cohesive zone model is presented and numerically implemented. The results show that the ratio of loading frequency to effective diffusivity governs fatigue crack growth behaviour. Increasing the d Read More
Environmentally Assisted Cracking Behavior of S420 and X80 Steels Containing U-notches at Two Different Cathodic Polarization Levels: An Approach from the Theory of Critical Distances
May 2019
Publication
This paper analyzes using the theory of critical distances the environmentally assisted cracking behaviour of two steels (S420 and API X80) subjected to two different aggressive environments. The propagation threshold for environmentally assisted cracking (i.e. the stress intensity factor above which crack propagation initiates) in cracked and notched specimens (KIEAC and KNIEAC) has been experimentally obtained under different environmental co Read More
Hydrogen Induced Damage in Heavily Cold-Drawn Wires of Lean Duplex Stainless Steel
Sep 2017
Publication
The paper addresses the sensitivity to hydrogen embrittlement of heavily cold-drawn wires made of the new generation of lower alloyed duplex stainless steels often referred to as lean duplex grades. It includes comparisons with similar data corresponding to cold-drawn eutectoid and duplex stainless steels. For this purpose fracture tests under constant load were carried out with wires in the as-received condition and fatigue-precracked in air and expo Read More
Magnesium Based Materials for Hydrogen Based Energy Storage: Past, Present and Future
Jan 2019
Publication
Volodymyr A. Yartys,
Mykhaylo V. Lototskyy,
Etsuo Akiba,
Rene Albert,
V. E. Antonov,
Jose-Ramón Ares,
Marcello Baricco,
Natacha Bourgeois,
Craig Buckley,
José Bellosta von Colbe,
Jean-Claude Crivello,
Fermin Cuevas,
Roman V. Denys,
Martin Dornheim,
Michael Felderhoff,
David M. Grant,
Bjørn Christian Hauback,
Terry D. Humphries,
Isaac Jacob,
Petra E. de Jongh,
Jean-Marc Joubert,
Mikhail A. Kuzovnikov,
Michel Latroche,
Mark Paskevicius,
Luca Pasquini,
L. Popilevsky,
Vladimir M. Skripnyuk,
Eugene I. Rabkin,
M. Veronica Sofianos,
Alastair D. Stuart,
Gavin Walker,
Hui Wang,
Colin Webb,
Min Zhu and
Torben R. Jensen
Magnesium hydride owns the largest share of publications on solid materials for hydrogen storage. The “Magnesium group” of international experts contributing to IEA Task 32 “Hydrogen Based Energy Storage” recently published two review papers presenting the activities of the group focused on magnesium hydride based materials and on Mg based compounds for hydrogen and energy storage. This review article not only overviews the lat Read More
Hydrogen Assisted Macrodelamination in Gas Lateral Pipe
Jul 2016
Publication
Hydrogen assisted macrodelamination in the pipe elbows of 40-year exploited lateral pipelines located behind the compressor station was studied. The crack on the external surface of the pipe elbow was revealed. Macrodelamination was occurred in the steel being influenced by the joined action of working loads and hydrogen absorbed by metal during long-term operation. The causes of the material degradation were investigated by non-destructive testin Read More
Novel Safe Method Of Manufacturing Hydrogen Metallic Hydrides
Sep 2005
Publication
The present work proposes a novel safe method for obtaining metallic hydrides. The method is called SHS (Self-Propagating High temperature synthesis). A novel high pressure gas reactor governed by an electromechanical control device has been designed and built up in order to synthesise metallic hydrides. This system is provided with a control system that allows calculating the amount of gas coming into the reaction vessel at every stage of the proc Read More
An Inter-Comparison Exercise on the Capabilities of CFD Models to Predict the Short and Long Term Distribution and Mixing of Hydrogen in a Garage
Sep 2007
Publication
Alexandros G. Venetsanos,
E. Papanikolaou,
J. García,
Olav Roald Hansen,
Matthias Heitsch,
Asmund Huser,
Wilfried Jahn,
Jean-Marc Lacome,
Thomas Jordan,
H. S. Ledin,
Dmitry Makarov,
Prankul Middha,
Etienne Studer,
Andrei V. Tchouvelev,
Franck Verbecke,
M. M. Voort,
Andrzej Teodorczyk and
M. A. Delichatsios
The paper presents the results of the CFD inter-comparison exercise SBEP-V3 performed within the activity InsHyde internal project of the HYSAFE network of excellence in the framework of evaluating the capability of various CFD tools and modelling approaches in predicting the physical phenomena associated to the short and long term mixing and distribution of hydrogen releases in confined spaces. The experiment simulated was INERIS-TEST-6C performe Read More
An Intercomparison Exercise on the Capabilities of CFD Models to Predict Distribution and Mixing of H2 in a Closed Vessel.
Sep 2005
Publication
This paper presents a compilation and discussion of the results supplied by HySafe partners participating in the Standard Benchmark Exercise Problem (SBEP) V1 which is based on an experiment on hydrogen release mixing and distribution inside a vessel. Each partner has his own point of view of the problem and uses a different approach to the solution. The main characteristics of the models employed for the calculations are compared. The comparison be Read More
Determination Of Hazardous Zones For A Generic Hydrogen Station – A Case Study
Sep 2007
Publication
A method for determination of hazardous zones for hydrogen installations has been studied. This work has been carried out within the NoE HySafe. The method is based on the Italian Method outlined in Guide 31-30(2004) Guide 31–35(2001) Guide 31-35/A(2001) and Guide 31-35/A; V1(2003). Hazardous zones for a “generic hydrogen refuelling station”(HRS) are assessed based on this method. The method is consistent with the EU directive 1999/92/EC “S Read More
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