Safety
Numerical Study of Spontaneous Ignition in Pressurized Hydrogen Release Through a Length of Tube with Local Contraction
Sep 2011
Publication
Numerical investigations have been conducted on the effect of the internal geometry of a local contraction on the spontaneous ignition of pressurized hydrogen release through a length of tube using a 5th-order WENO scheme. A mixture-averaged multi-component approach was used for accurate calculation of molecular transport. The auto-ignition and combustion chemistry were accounted for using a 21-step kinetic scheme. It is found that Read More
Numerical Study on Spontaneous Ignition of Pressurized Hydrogen Release Through a Length of Tube
Sep 2009
Publication
The issue of spontaneous ignition of highly pressurized hydrogen release is of important safety concern e.g. in the assessment of risk and design of safety measures. This paper reports on recent numerical investigation of this phenomenon through releases via a length of tube. This mimics a potential accidental scenario involving release through instrument line. The implicit large eddy simulation (ILES) approach was used with the 5th-order weighted essen Read More
Regulations and Research on RC&S for Hydrogen Storage Relevant To Transport and Vehicle Issues with Special Focus on Composite Containments
Sep 2011
Publication
Developers interested in high pressure storage of hydrogen for mobile use increasingly rely on composite cylinders for onboard storage or transport of dangerous goods. Thus composite materials and systems deserve special consideration. History gives interesting background information important to the understanding of the current situation as to regulations codes and standards.Based on this review origins of different regulations for the storage o Read More
Spontaneous Ignition Processes Due To High-Pressure Hydrogen Release in Air
Sep 2011
Publication
Spontaneous ignition processes due to the high-pressure hydrogen releases into air were investigated both experimentally and theoretically. Such processes reproduce accident scenarios of sudden expansion of pressurized hydrogen into the ambient atmosphere in cases of tube or valve rupture. High-pressure hydrogen releases in the range of initial pressures from 20 to 275 bar and with nozzle diameters of 0.5 – 4 mm have been investigated. Glass tube Read More
Pressure Cycling Of Type 1 Pressure Vessels with Gaseous Hydrogen
Sep 2011
Publication
Type 1 steel pressure vessels are commonly used for the transport of pressurized gases including gaseous hydrogen. In the majority of cases these cylinders experience relatively few pressure cycles over their lifetime perhaps in the hundreds. In emerging markets such as hydrogen-powered industrial trucks hydrogen fuel systems are expected to experience thousands of cycles over just a few year period. This study investigates the fatigue life of Type Read More
Flammability Limits and Laminar Flame Speed of Hydrogen–air Mixtures at Sub-atmospheric Pressures
Sep 2011
Publication
Hydrogen behavior at elevated pressures and temperatures was intensively studied by numerous investigators. Nevertheless there is a lack of experimental data on hydrogen ignition and combustion at reduced sub-atmospheric pressures. Such conditions are related to the facilities operating under vacuum or sub-atmospheric conditions for instance like ITER vacuum vessel. Main goal of current work was an experimental evaluation of such fundamental Read More
Numerical Study on Fast Filling of 70 MPA Hydrogen Vehicle Cylinder
Sep 2011
Publication
There will be significant temperature rise within hydrogen vehicle cylinder during the fast filling process. The temperature rise should be controlled under the temperature limit (85 °C) of the structure material (set by ISO/TS 15869) because it may lead to the failure of the structure. In this paper a 2-dimensional axisymmetric computational fluid dynamics (CFD) model for fast filling of 70 MPa hydrogen vehicle cylinder is presented. The numerical simulation Read More
Hydrogen Onboard Storage: An Insertion of the Probabilistic Approach Into Standards & Regulations?
Sep 2005
Publication
The growing attention being paid by car manufacturers and the general public to hydrogen as a middle and long term energy carrier for automotive purpose is giving rise to lively discussions on the advantages and disadvantages of this technology – also with respect to safety. In this connection the focus is increasingly and justifiably so on the possibilities offered by a probabilistic approach to loads and component characteristics: a lower weight oblige Read More
Requirements for the Safety Assessment for the Approval of a Hydrogen Refueling Station
Sep 2007
Publication
The EC 6th framework research project HyApproval will draft a Handbook which will describe all relevant issues to get approval to construct and operate a Hydrogen Refuelling Station (HRS) for hydrogen vehicles. In WP3 of the HyApproval project it is under investigation which safety information competent authorities require to give a licence to construct an operate an HRS. The paper describes the applied methodology to collect the information from Read More
Safety Demands for Automotive Hydrogen Storage Systems
Sep 2005
Publication
Fuel storage systems for vehicles require a fail-safe design strategy. In case of system failures or accidents the control electronics have to switch the system into a safe operation mode. Failure Mode and Effect Analysis (FMEA) or Failure Tree Analysis (FTA) are performed already in the early design phase in order to minimize the risk of design failures in the fuel storage system. Currently the specifications of requirements for pressurized and liquid hydrogen fue Read More
Development of High-pressure Hydrogen Gas Barrier Materials
Oct 2015
Publication
We prepared several gas barrier resins based on amorphous PVA derivative that has the T1C (13C spin-lattice relaxation time) of a long time component in amorphous phase. We confirmed it was important to control state in amorphous phase of gas barrier resin in order to achieve both moldability and good gas barrier property. Polymer alloy was designed to improve flexibility. Polymer alloy made of amorphous PVA and elastomer resin showed good hydro Read More
Determination of Clearance Distances for Venting of Hydrogen Storage
Sep 2005
Publication
This paper discusses the results of computational fluid dynamics (CFD) modelling of hydrogen releases and dispersion outdoors during venting of hydrogen storage in real environment and geometry of a hydrogen refuelling or energy station for a given flow rate and dimensions of vent stack. The PHOENICS CFD software package was used to solve the continuity momentum and concentration equations with the appropriate boundary conditions buoyancy Read More
Massive H2 Production With Nuclear Heating, Safety Approach For Coupling A VHTR With An Iodine Sulfur Process Cycle
Sep 2005
Publication
In the frame of a sustainable development investigations dealing with massive Hydrogen production by means of nuclear heating are carried out at CEA. For nuclear safety thermodynamic efficiency and waste minimization purposes the technological solution privileged is the coupling of a gas cooled Very High Temperature Reactor (VHTR) with a plant producing Hydrogen from an Iodine/Sulfur (I/S) thermochemical cycle. Each of the aforementioned facili Read More
Dispersion Tests on Concentration and its Fluctuations for 40MPa Pressurized Hydrogen
Sep 2007
Publication
Hydrogen is one of the important alternative fuels for future transportation. At the present stage research into hydrogen safety and designing risk mitigation measures are significant task. For compact storage of hydrogen in fuel cell vehicles storage of hydrogen under high pressure up to 40 MPa at refuelling stations is planned and safety in handling such high-pressure hydrogen is essential. This paper describes our experimental investigation into disper Read More
Experimental Releases of Liquid Hydrogen
Sep 2011
Publication
If the hydrogen economy is to progress more hydrogen refuelling stations are required. In the short term in the absence of a hydrogen distribution network the most likely means of supplying the refuelling stations will be by liquid hydrogen road tanker. This development will clearly increase the number of tanker offloading operations significantly and these may need to be performed in more challenging environments with close proximity to the general publ Read More
Fundamental Safety Testing and Analysis of Solid State Hydrogen Storage Materials and Systems
Sep 2007
Publication
Hydrogen is seen as the future automobile energy storage media due to its inherent cleanliness upon oxidation and its ready utilization in fuel cell applications. Its physical storage in light weight low volume systems is a key technical requirement. In searching for ever higher gravimetric and volumetric density hydrogen storage materials and systems it is inevitable that higher energy density materials will be studied and used. To make safe and co Read More
Numerical Analysis for Hydrogen Flame Acceleration during a Severe Accident Initiated by SBLOCA in the APR1400 Containment
Jan 2022
Publication
We performed a hydrogen combustion analysis in the Advanced Power Reactor 1400 MWe (APR1400) containment during a severe accident initiated by a small break loss of coolant accident (SBLOCA) which occurred at a lower part of the cold leg using a multi-dimensional hydrogen analysis system (MHAS) to confirm the integrity of the APR1400 containment. The MHAS was developed by combining MAAP GASFLOW and COM3D to simulate hydrogen rele Read More
Compatibility of Metallic Materials with Hydrogen Review of the Present Knowledge
Sep 2007
Publication
In this document after a review of the accidents/incidents are described the different interactions between hydrogen gas and the most commonly used materials including the influence of "internal" and "external" hydrogen the phenomena occurring in all ranges of temperatures and pressures and Hydrogen Embrittlement (HE) created by gaseous hydrogen. The principle of all the test methods used to investigate this phenomenon are presented and di Read More
CFD Modelling of Accidental Hydrogen Release from Pipelines
Sep 2005
Publication
Although today hydrogen is distributed mainly by trailers in the long terms pipeline distribution will be more suitable if large amounts of hydrogen are produced on industrial scale. Therefore from the safety point of view it is essential to compare hydrogen pipelines to natural gas pipelines which are well established today. Within the paper we compare safety implications in accidental situations. We do not look into technological aspects such as com Read More
The Safe Use of the Existing Natural Gas System for Hydrogen (Overview of the NATURALHY-Project)
Sep 2005
Publication
The transition period towards the situation in which hydrogen will become an important energy carrier will be lengthy (decades) costly and needs a significant R&D effort. It’s clear therefore that the development of a hydrogen system requires a practical strategy within the context of the existing assets. Examining the potential of the existing extensive natural gas chain (transmission - distribution - end user infrastructures and appliances) is a logical first step Read More
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