Applications & Pathways
Economic Evaluation of Low-carbon Steelmaking via Coupling of Electrolysis and Direct Reduction
Oct 2021
Publication
The transition from fossil-based primary steel production to a low-emission alternative has gained increasing attention in recent years. Various schemes including Carbon Capture and Utilization (CCU) and Carbon Direct Avoidance (CDA) via hydrogen-based as well as electrochemical routes have been proposed. With multiple technical analyses being available and technical feasibility being proven by first pilot plants pathways towards commercial market entry are of increasing interest. While multiple publications on the economic feasibility of CCU are available data on CDA approaches is scarce. In this work an economic model for the quantification of production cost as well as CO2 emission mitigation cost is presented. The approach is characterized by a seamless integration with a flowsheet-based process model of a direct reduction-based crude steel production plant detailed in a previous work and allows for the investigation of multiple economic aspects. Firstly the gradual transition from the natural gas-based state-of-the-art direct reduction towards a fossil-free hydrogen-based reduction is analyzed. Furthermore a comparison between the more mature technology of low-temperature electrolysis and a potentially more efficient solid oxide electrolysis (SOEL) is given highlighting the potential of SOEL technology. The conducted forecast to 2050 shows that SOEL-based CDA offers lower production cost when technological maturity is reached. Based on the results of the economic assessment possible legislative support mechanisms are studied showing that legislative actions are necessary to allow for market entry as well as for sustainable and economically feasible operation of fossil-free direct reduction plants.
Enhancing Energy Transition through Sector Coupling: A Review of Technologies and Models
Jul 2023
Publication
In order to effectively combat the effects of global warming all sectors must actively reduce greenhouse gas emissions in a sustainable and substantial manner. Sector coupling has emerged as a critical technology that can integrate energy systems and address the temporal imbalances created by intermittent renewable energy sources. Despite its potential current sector coupling capabilities remain underutilized and energy modeling approaches face challenges in understanding the intricacies of sector coupling and in selecting appropriate modeling tools. This paper presents a comprehensive review of sector coupling technologies and their role in the energy transition with a specific focus on the integration of electricity heat/cooling and transportation as well as the importance of hydrogen in sector coupling. Additionally we conducted an analysis of 27 sector coupling models based on renewable energy sources with the goal of aiding deciders in identifying the most appropriate model for their specific modeling needs. Finally the paper highlights the importance of sector coupling in achieving climate protection goals while emphasizing the need for technological openness and market-driven conditions to ensure economically efficient implementation.
Green Hydrogen Value Chain: Modelling of a PV Power Plant Integrated with H2 Production for Industry Application
Mar 2024
Publication
Based on the Sustainable Development Goals outlined in the 2030 agenda of the United Nations affordable and clean energy is one of the most relevant goals to achieve the decarbonization targets and break down the global climate change effects. The use of renewable energy sources namely solar energy is gaining attention and market share due to reductions in investment costs. Nevertheless it is important to overcome the energy storage problems mostly in industrial applications. The integration of photovoltaic power plants with hydrogen production and its storage for further conversion to usable electricity are an interesting option from both the technical and economic points of view. The main objective of this study is to analyse the potential for green hydrogen production and storage through PV production based on technical data and operational considerations. We also present a conceptual model and the configuration of a PV power plant integrated with hydrogen production for industry supply. The proposed power plant configuration identifies different pathways to improve energy use: supply an industrial facility supply the hydrogen production and storage unit sell the energy surplus to the electrical grid and provide energy to a backup battery. One of the greatest challenges for the proposed model is the component sizing and water electrolysis process for hydrogen production due to the operational requirements and the technology costs.
Evaluating Fuel Cell vs. Battery Electric Trucks: Economic Perspectives in Alignment with China’s Carbon Neutrality Target
Mar 2024
Publication
The electrification of heavy-duty trucks stands as a critical and challenging cornerstone in the low-carbon transition of the transportation sector. This paper employs the total cost of ownership (TCO) as the economic evaluation metric framed within the context of China’s ambitious goals for heavy truck electrification by 2035. A detailed TCO model is developed encompassing not only the vehicles but also their related energy replenishing infrastructures. This comprehensive approach enables a sophisticated examination of the economic feasibility for different deployment contexts of both fuel cell and battery electric heavy-duty trucks emphasizing renewable energy utilization. This study demonstrates that in the context where both fuel cell components and hydrogen energy are costly fuel cell trucks (FCTs) exhibit a significantly higher TCO compared to battery electric trucks (BETs). Specifically for a 16 ton truck with a 500 km range the TCO for the FCT is 0.034 USD/tkm representing a 122% increase over its BET counterpart. In the case of a 49 ton truck designed for a 1000 km range the TCO for the FCT is 0.024 USD/tkm marking a 36% premium compared to the BET model. The technological roadmap suggests a narrowing cost disparity between FCTs and BETs by 2035. For the aforementioned 16 ton truck model the projected TCO for the FCT is expected to be 0.016 USD/tkm which is 58% above the BET and for the 49 ton variant it is anticipated at 0.012 USD per ton-kilometer narrowing the difference to just 4.5% relative to BET. Further analysis within this study on the influences of renewable energy pricing and operational range on FCT and BET costs highlights a pivotal finding: for the 49 ton truck achieving TCO parity between FCTs and BETs is feasible when renewable energy electricity prices fall to 0.022 USD/kWh or when the operational range extends to 1890 km. This underscores the critical role of energy costs and efficiency in bridging the cost gap between FCTs and BETs.
Hydrogen Fuel Cells for Sustainable Energy: Development and Progress in Selected Developed Countries
Jan 2021
Publication
The sustainable development goals concept towards zero carbon emission set forth by the Paris Agreement is the foundation of decarbonisation implemented in most developed countries worldwide. One of the efforts in the decarbonisation of the environment is through hydrogen fuel cell technology. A fuel cell is an energy converter device that produces electricity via the electrochemical reaction with water as the by-product. The application of fuel cells is strongly related to the economic aspect including local and infrastructure costs making it more relevant to be implemented in a developed country. This work presents a short review of the development and progress of hydrogen fuel cells in a developed country such as Japan Germany USA Denmark and China (in transition between developing to developed status); which championed hydrogen fuel cell technology in their region.
Techno-Economic Analysis of Solid Oxide Fuel Cell-Gas Turbine Hybrid Systems for Stationary Power Applications Using Renewable Hydrogen
Jun 2023
Publication
Solid oxide fuel cell (SOFC)–gas turbine (GT) hybrid systems can produce power at high electrical efficiencies while emitting virtually zero criteria pollutants (e.g. ozone carbon monoxide oxides of nitrogen and sulfur and particulate matters). This study presents new insights into renewable hydrogen (RH2 )-powered SOFC–GT hybrid systems with respect to their system configuration and techno-economic analysis motivated by the need for clean on-demand power. First three system configurations are thermodynamically assessed: (I) a reference case with no SOFC off-gas recirculation (II) a case with cathode off-gas recirculation and (III) a case with anode off-gas recirculation. While these configurations have been studied in isolation here we provide a detailed performance comparison. Moreover a techno-economic analysis is conducted to study the economic competitiveness of RH2 -fueled hybrid systems and the economies of scale by offering a comparison to natural gas (NG)-fueled systems. Results show that the case with anode off-gas recirculation with 68.50%-lower heating value (LHV) at a 10 MW scale has the highest efficiency among the studied scenarios. When moving from 10 MW to 50 MW the efficiency increases to 70.22%-LHV. These high efficiency values make SOFC–GT hybrid systems highly attractive in the context of a circular economy as they outcompete most other power generation technologies. The cost-of-electricity (COE) is reduced by about 10% when moving from 10 MW to 50 MW from USD 1976/kW to USD 1668/kW respectively. Renewable H2 is expected to be economically competitive with NG by 2030 when the U.S. Department of Energy’s target of USD 1/kg RH2 is reached.
Predicting Power and Hydrogen Generation of a Renewable Energy Converter Utilizing Data-Driven Methods: A Sustainable Smart Grid Case Study
Jan 2023
Publication
This study proposes a data-driven methodology for modeling power and hydrogen generation of a sustainable energy converter. The wave and hydrogen production at different wave heights and wind speeds are predicted. Furthermore this research emphasizes and encourages the possibility of extracting hydrogen from ocean waves. By using the extracted data from the FLOW-3D software simulation and the experimental data from the special test in the ocean the comparison analysis of two data-driven learning methods is conducted. The results show that the amount of hydrogen production is proportional to the amount of generated electrical power. The reliability of the proposed renewable energy converter is further discussed as a sustainable smart grid application.
Proposal of Zero-Emission Tug in South Korea Using Fuel Cell/Energy Storage System: Economic and Environmental Long-Term Impacts
Mar 2023
Publication
This study presents the results of economic and environmental analysis for two types of zero-emission ships (ZESs) that are receiving more attention to meet strengthened environmental regulations. One of the two types of ZES is the ZES using only the energy storage system (All-ESS) and the other is the ZES with fuel cell and ESS hybrid system (FC–ESS). The target ship is a tug operating in South Korea and the main parameters are based on the specific circumstances of South Korea. The optimal capacity of the ESS for each proposed system is determined using an optimization tool. The total cost for a ship’s lifetime is calculated using economic analysis. The greenhouse gas (GHG) emission for the fuel’s lifecycle (well-to-wake) is calculated using environmental analysis. The results reveal that the proposed ZESs are 1.7–3.4 times more expensive than the conventional marine gas oil (MGO)-fueled ship; however it could be reduced by 1.3–2.4 times if the carbon price is considered. The proposed ZESs have 58.7–74.3% lower lifecycle GHG emissions than the one from the conventional ship. The results also highlight that the electricity- or hydrogen-based ZESs should reduce GHG emissions from the upstream phase (well-to-tank) to realize genuine ZESs.
Well-To-Wheels Analysis of Future Automotive Fuels and Powertrains in the European Context
Jun 2014
Publication
The Well-to-Tank study describes the process of producing transporting manufacturing and distributing a number of fuels suitable for road transport powertrains. It covers all steps from extracting capturing or growing the primary energy carrier to refuelling the vehicles with the finished fuel.
Probabilistic Modelling of Seasonal Energy Demand Patterns in the Transition from Natural Gas to Hydrogen for an Urban Energy District
May 2023
Publication
The transition to a low-carbon energy system can be depicted as a “great reconfiguration” from a socio-technical perspective that carries the risk of impact shifts. Electrification with the objective of achieving rapidly deep decarbonisation must be accompanied by effective efficiency and flexibility measures. Hydrogen can be a preferred option in the decarbonisation process where electrification of end-uses is difficult or impractical as well as for long-term storage in energy infrastructure characterised by a large penetration of renewable energy sources. Notwithstanding the current uncertainties regarding costs environmental impact and the inherent difficulties of increasing rapidly supply capacity hydrogen can represent a solution to be used in multi-energy systems with combined heat and power (CHP) in particular in urban energy districts. In fact while achieving carbon savings with natural gas fuelled CHP is not possible when low grid carbon intensity factors are present it may still be possible to use it to provide flexibility services and to reduce emissions further with switch from natural gas to hydrogen. In this paper a commercially established urban district energy scheme located in Southampton (United Kingdom) is analysed with the goal of exploring potential variations in its energy demand. The study proposes the use of scalable data-driven methods and probabilistic simulation to generate seasonal energy demand patterns representing the potential short-term and long-term evolution of the energy district.
Hydrogen Fuel Cell Integration and Testing in a Hybrid-electric Propulsion Rig
Jun 2023
Publication
On the road towards greener aviation hybrid-electric propulsion systems have emerged as a viable solution. In this paper a system based on hydrogen fuel cells is proposed and evaluated in a laboratory setting with its future integration in a propulsive system in mind and main focus on the ability to lessen the power demand on the opposing side of the bench. The setup consists in a parallel architecture with two power sources: a hydrogen fuel cell and a battery. First the performance of the fuel cell and its capability to provide power to one of the motors are analyzed. Then the entire parallel hybrid system is evaluated. Although the experimental setup was shown to be sub-optimal the results demonstrated the ability of this greener alternative to reduce power demand on the opposing side of the parallel configuration with a reduction of up to 40.3% in the highest load scenario and maximum power output on the fuel cell of 257.8 W. The stack performance was also concluded to be very dependent on the operating temperature.
Current State of Technology of Fuel Cell Power Systems for Autonomous Underwater Vehicles
Jul 2014
Publication
Autonomous Underwater Vehicles (AUVs) are vehicles that are primarily used to accomplish oceanographic research data collection and auxiliary offshore tasks. At the present time they are usually powered by lithium-ion secondary batteries which have insufficient specific energies. In order for this technology to achieve a mature state increased endurance is required. Fuel cell power systems have been identified as an effective means to achieve this endurance but no implementation in a commercial device has yet been realized. This paper summarizes the current state of development of the technology in this field of research. First the most adequate type of fuel cell for this application is discussed. The prototypes and design concepts of AUVs powered by fuel cells which have been developed in the last few years are described. Possible commercial and experimental fuel cell stack options are analyzed examining solutions adopted in the analogous aerial vehicle applications as well as the underwater ones to see if integration in an AUV is feasible. Current solutions in oxygen and hydrogen storage systems are overviewed and energy density is objectively compared between battery power systems and fuel cell power systems for AUVs. A couple of system configuration solutions are described including the necessary lithium-ion battery hybrid system. Finally some closing remarks on the future of this technology are given.
A Novel Scheme to Allocate the Green Energy Transportation Costs—Application to Carbon Captured and Hydrogen
Mar 2023
Publication
Carbon dioxide (CO2 ) and hydrogen (H2 ) are essential energy vectors in the green energy transition. H2 is a fuel produced by electrolysis and is applied in heavy transportation where electrification is not feasible yet. The pollutant substance CO2 is starting to be captured and stored in different European locations. In Denmark the energy vision aims to use this CO2 to be reacted with H2 producing green methanol. Typically the production units are not co-located with consumers and thus the required transportation infrastructure is essential for meeting supply and demand. This work presents a novel scheme to allocate the transportation costs of CO2 and H2 in pipeline networks which can be applied to any network topology and with any allocation method. During the tariff formation process coordinated adjustments are made by the novel scheme on the original tariffs produced by the allocation method employed considering the location of each customer connected to pipeline network. Locational tariffs are provided as result and the total revenue recovery is guaranteed to the network owner. Considering active customers the novel scheme will lead to a decrease of distant pipeline flows thereby contributing to the prevention of bottlenecks in the transportation network. Thus structural reinforcements can be avoided reducing the total transportation cost paid by all customers in the long-term.
An Integrated Framework for Optimal Infrastructure Planning for Decarbonising Heating
Apr 2023
Publication
This paper presents the HEGIT (Heat Electricity and Gas Infrastructure and Technology) model for optimal infrastructure planning for decarbonising heating in buildings. HEGIT is an optimisation model based on Mixed Integer Linear Programming. The model co-optimises the integrated operation and capacity expansion planning of electricity and gas grids as well as heating technologies on the consumer side while maintaining the security of supply and subject to different environmental operational and system-wide constraints. The three main features of the HEGIT model are: • It incorporates an integrated unit commitment and capacity expansion problem for coordinated operation and long-term investment planning of the electricity and gas grids. • It incorporates the flexible operation of heating technologies in buildings and demand response in operation and long-term investment planning of gas and electricity grids. • It incorporates a multi-scale techno-economic representation of heating technologies design features into the whole energy system modelling and capacity planning. These features enable the model to quantify the impacts of different policies regarding decarbonising heating in buildings on the operation and long-term planning of electricity and gas grids identify the cost-optimal use of available resources and technologies and identify strategies for maximising synergies between system planning goals and minimising trade-offs. Moreover the multi-scale feature of the model allows for multi-scale system engineering analysis of decarbonising heating including system-informed heating technology design identifying optimal operational setups at the consumer end and assessing trade-offs between consumer investment in heating technologies and infrastructure requirements in different heat decarbonisation pathways.
Developments in Hydrogen Fuel Cells
Mar 2023
Publication
The rapid growth in fossil fuels has resulted in climate change that needs to be controlled in the near future. Several methods have been proposed to control climate change including the development of efficient energy conversion devices. Fuel cells are environmentally friendly energy conversion devices that can be fuelled by green hydrogen with only water as a by-product or by using different biofuels such as biomass in wastewater urea in wastewater biogas from municipal and agricultural wastes syngas from agriculture wastes and waste carbon. This editorial discusses the fundamentals of the operation of the fuel cell and their application in various sectors such as residential transportation and power generation.
Optimization of Integrated Energy System Considering Electricity and Hydrogen Coordination in the Context of Carbon Trading
Apr 2024
Publication
In order to improve the consumption of renewable energy and reduce the carbon emissions of integrated energy systems (IESs) this paper proposes an optimal operation strategy for an integrated energy system considering the coordination of electricity and hydrogen in the context of carbon trading. The strategy makes full use of the traditional power-to-gas hydrogen production process and establishes a coupling model comprising cogeneration and carbon capture equipment an electrolytic cell a methane reactor and a hydrogen fuel cell. Taking a minimum daily operating cost and minimal carbon emissions from the system as objective functions a mixed-integer nonlinear optimal scheduling model is established. This paper designs examples based on MATLAB R2021b and uses the GUROBI solver to solve them. The results show that compared with the traditional two-stage operation process the optimization method can reduce the daily operation cost of an IES by 26.01% and its carbon emissions by 90.32%. The results show that the operation mode of electro-hydrogen synergy can significantly reduce the carbon emissions of the system and realize a two-way flow of electro-hydrogen energy. At the same time the addition of carbon capture equipment and the realization of carbon recycling prove the scheduling strategy’s ability to achieve a lowcarbon economy of the scheduling strategy.
The Role of Biomass Gasification in Low-carbon Energy and Transport Systems
Mar 2021
Publication
The design of future energy systems requires the efficient use of all available renewable resources. Biomass can complement variable renewable energy sources by ensuring energy system flexibility and providing a reliable feedstock to produce renewable fuels. We identify biomass gasification suitable to utilise the limited biomass resources efficiently. In this study we inquire about its role in a 100% renewable energy system for Denmark and a net-zero energy system for Europe in the year 2050 using hourly energy system analysis. The results indicate bio-electrofuels produced from biomass gasification and electricity to enhance the utilisation of wind and electrolysis and reduce the energy system costs and fuels costs compared to CO2-electrofuels from carbon capture and utilisation. Despite the extensive biomass use overall biomass consumption would be higher without biomass gasification. The production of electromethanol shows low biomass consumption and costs while Fischer-Tropsch electrofuels may be an alternative for aviation. Syngas from biomass gasification can supplement biogas in stationary applications as power plants district heat or industry but future energy systems must meet a balance between producing transport fuels and syngas for stationary units. CO2-electrofuels are found complementary to bio-electrofuels depending on biomass availability and remaining non-fossil CO2 emitters
Deep Decarbonisation Pathways of the Energy System in Times of Unprecedented Uncertainty in the Energy Sector
May 2023
Publication
Unprecedented investments in clean energy technology are required for a net-zero carbon energy system before temperatures breach the Paris Agreement goals. By performing a Monte-Carlo Analysis with the detailed ETSAPTIAM Integrated Assessment Model and by generating 4000 scenarios of the world’s energy system climate and economy we find that the uncertainty surrounding technology costs resource potentials climate sensitivity and the level of decoupling between energy demands and economic growth influence the efficiency of climate policies and accentuate investment risks in clean energy technologies. Contrary to other studies relying on exploring the uncertainty space via model intercomparison we find that the CO2 emissions and CO2 prices vary convexly and nonlinearly with the discount rate and climate sensitivity over time. Accounting for this uncertainty is important for designing climate policies and carbon prices to accelerate the transition. In 70% of the scenarios a 1.5 ◦C temperature overshoot was within this decade calling for immediate policy action. Delaying this action by ten years may result in 2 ◦C mitigation costs being similar to those required to reach the 1.5 ◦C target if started today with an immediate peak in emissions a larger uncertainty in the medium-term horizon and a higher effort for net-zero emissions.
Simulation and Control Strategy Study of the Hydrogen Supply System of a Fuel Cell Engine
Jun 2023
Publication
The hydrogen supply system is one of the important components of a hydrogen fuel cell engine and its performance has an important impact on the economy and power of the engine system. In this paper a hydrogen supply system based on cyclic mode is designed for a hydrogen fuel cell stack with a full load power of 150 kW and the corresponding hydrogen fuel cell engine simulation model is built and validated. The control strategy of the fuel cell hydrogen supply system is developed and its effect is verified through bench tests. The results show that the developed control strategy can keep the volume fraction of nitrogen below 6% the hydrogen excess ratio does not exceed 1.5 under medium and high operating conditions the anode pressure is relatively stable and the stack can operate efficiently and reliably.
Conditions for Profitable Operation of P2X Energy Hubs to Meet Local Demand Under Energy Market Access
Feb 2023
Publication
This paper analyzes the operation of an energy hub on a community level with an integrated P2X facility and with access to energy markets. In our case P2X allows converting power to hydrogen heat methane or back to power. We consider the energy hub as a large prosumer who can be both a producer and consumer in the markets with the novelty that P2X technology is available. We investigate how such a P2X energy hub trades optimally in the electricity market and satisfies local energy demand under the assumption of a long-term strong climate scenario in year 2050. For numerical analysis a case study of a mountain village in Switzerland is used. One of the main contributions of this paper is to quantify key conditions for profitable operations of such a P2X energy hub. In particular the analysis includes impacts of influencing factors on profits and operational patterns in terms of different degrees of self-sufficiency and different availability of local renewable resources. Moreover the access to real-time wholesale market electricity price signals and a future retail hydrogen market is assessed. The key factors for the successful operation of a P2X energy hub are identified to be sufficient local renewable resources and access to a retail market of hydrogen. The results also show that the P2X operation leads to an increased deployment of local renewables especially in the case of low initial deployment; on the other hand seasonal storage plays a subordinated role. Additionally P2X lowers for the community the wholesale electricity market trading volumes.
Artificial Intelligence/Machine Learning in Energy Management Systems, Control, and Optimization of Hydrogen Fuel Cell Vehicles
Mar 2023
Publication
Environmental emissions global warming and energy-related concerns have accelerated the advancements in conventional vehicles that primarily use internal combustion engines. Among the existing technologies hydrogen fuel cell electric vehicles and fuel cell hybrid electric vehicles may have minimal contributions to greenhouse gas emissions and thus are the prime choices for environmental concerns. However energy management in fuel cell electric vehicles and fuel cell hybrid electric vehicles is a major challenge. Appropriate control strategies should be used for effective energy management in these vehicles. On the other hand there has been significant progress in artificial intelligence machine learning and designing data-driven intelligent controllers. These techniques have found much attention within the community and state-of-the-art energy management technologies have been developed based on them. This manuscript reviews the application of machine learning and intelligent controllers for prediction control energy management and vehicle to everything (V2X) in hydrogen fuel cell vehicles. The effectiveness of data-driven control and optimization systems are investigated to evolve classify and compare and future trends and directions for sustainability are discussed.
Introduction of Hydrogen in the Kosovo Transportation Sector
Oct 2022
Publication
Based on the energy strategy of the Republic of Kosovo from 2017–2026 the increase in the integration of renewable energy sources (RES) in the national energy system was aimed at. However the hydrogen potential was not mentioned. In this work a roadmap toward the introduction of hydrogen in the energy system with the main focus on the transportation sector through three phases is proposed. In the first phase (until 2024) the integration of hydrogen in the transportation sector produced via water electrolysis from the grid electricity with the increase of up to a 0.5% share of fuel cell vehicles is intended. In the second phase (2025–2030) the hydrogen integration in the transportation sector is increased by including renewable hydrogen where the share of fuel cell electric vehicles (FCEVs) will be around 4% while in the third phase (2031–2050) around an 8% share of FCEVs in the transportation was planned. The technical and environmental analysis of hydrogen integration is focused on both the impact of hydrogen in the decarbonization of the transportation sector and the energy system. To model the Kosovo energy system the hourly deterministic EnergyPLAN model was used. This research describes the methodology based on EnergyPLAN modeling that can be used for any energy system to provide a clear path of RES and hydrogen implementation needed to achieve a zero-emission goal which was also set by various other countries. The predicted decrease in GHG emissions from 8 Mt in the referent year 2017 amounts to 7 Mt at the end of the first phase 2024 and 4.4 Mt at the end of the second phase 2030 to achieve 0 Mt by 2050. In order to achieve it the required amount of hydrogen by 2030 resulted in 31840 kg/year and by 2050 around 89731 kg/year. The results show the concrete impact of hydrogen on transport system stabilization and its influence on greenhouse gas (GHG) emissions reduction.
Hydrogen Refueling Method for Heavy-duty FCV with Pressure Loss Compensation
Apr 2024
Publication
Current hydrogen stations are using a constant dispenser pressure ramp rate method. When a flow rate increases for heavy duty vehicle a large pressure loss occurs and it slows down refueling. This study developed a new method (cTPR method) that has the constant pressure ramp rate in the tank by compensating for the tube pressure loss without any feedback from the vehicle. A refueling simulation confirmed that a refueling was shortened − 49s with a lower ending gas temperature. Testing confirmed that the cTPR method can be realized simply by changing the control without any hardware modification.
Operation of a Solid Oxide Fuel Cell Based Power System with Ammonia as a Fuel: Experimental Test and System Design
Nov 2020
Publication
Ammonia has strong potentialities as sustainable fuel for energy applications. NH3 is carbon free and can be synthetized from renewable energy sources (RES). In Solid Oxide Fuel Cells NH3 reacts electrochemically thereby avoiding the production of typical combustion pollutants such as NOx. In this study an ammonia-fueled solid oxide fuel cells (SOFC) system design is proposed and a thermodynamic model is developed to evaluate its performance. A SOFC short stack was operated with NH3 in a wide range of conditions. Experimental results are implemented in the thermodynamic model. Electrical efficiency of 52.1% based on ammonia Lower Heating Value is calculated at a net power density of 0.36 W cmFC −2 . The operating conditions of the after burner and of the ammonia decomposition reactor are studied by varying the values of specific parameters. The levelized cost of energy of 0.221 $ kWh−1 was evaluated as introduced by the International Energy Agency for a system that operates at nominal conditions and at a reference power output of 100 kW. This supports the feasibility of ammonia-fueled SOFC systems with reference to the carbon free energy market specifically considering the potential development of green ammonia production.
Energy and Exergy Analysis of a Geothermal Sourced Multigeneration System for Sustainable City
Feb 2023
Publication
The issue of depleting fossil fuels has emphasized the use of renewable energy. Multigeneration systems fueled by renewables such as geothermal biomass solar etc. have proven to be cutting-edge technologies for the production of different valuable by-products. This study proposes a multigeneration system using a geothermal source of energy. The main outputs include power space heating cooling fresh and hot water dry air and hydrogen. The system includes a regenerative Rankine cycle a double effect absorption cycle and a double flash desalination cycle. A significant amount of electrical power hydrogen and fresh water is generated which can be used for commercial or domestic purposes. The power output is 103 MW. The thermal efficiency is 24.42% while energetic and exergetic efficiencies are 54.22% and 38.96% respectively. The COPen is found to be 1.836 and the COPex is found to be 1.678. The hydrogen and fresh water are produced at a rate of 0.1266 kg/s and 37.6 kg/s respectively.
Experimental Study on the Effects of Hydrogen Injection Strategy on the Combustion and Emissions of a Hydrogen/Gasoline Dual Fuel SI Engine under Lean Burn Condition
Oct 2022
Publication
Hydrogen addition can improve the performance and extend the lean burn limit of gasoline engines. Different hydrogen injection strategies lead to different types of hydrogen mixture distribution (HMD) which affects the engine performance. Therefore the present study experimentally investigated the effects of hydrogen injection strategy on the combustion and emissions of a hydrogen/gasoline dual-fuel port-injection engine under lean-burn conditions. Four different hydrogen injection strategies were explored: hydrogen direct injection (HDI) forming a stratified hydrogen mixture distribution (SHMD); hydrogen intake port injection forming a premixed hydrogen mixture distribution (PHMD); split hydrogen direct injection (SHDI) forming a partially premixed hydrogen mixture distribution (PPHMD); and no hydrogen addition (NHMD). The results showed that 20% hydrogen addition could extend the lean burn limit from 1.5 to 2.8. With the increase in the excess air ratio the optimum HMD changed from PPHMD to SHMD. The maximum brake thermal efficiency was obtained with an excess air ratio of 1.5 with PPHMD. The coefficient of variation (COV) with NHMD was higher than that with hydrogen addition since the hydrogen enhanced the stability of ignition and combustion. The engine presented the lowest emissions with PHMD. There were almost no carbon monoxide (CO) and nitrogen oxides (NOx) emissions when the excess air ratio was respectively more than 1.4 and 2.0.
On the Technology of Solid Oxide Fuel Cell (SOFC) Energy Systems for Stationary Power Generation: A Review
Nov 2022
Publication
This paper presents a comprehensive overview on the current status of solid oxide fuel cell (SOFC) energy systems technology with a deep insight into the techno-energy performance. In recent years SOFCs have received growing attention in the scientific landscape of high efficiency energy technologies. They are fuel flexible highly efficient and environmentally sustainable. The high working temperature makes it possible to work in cogeneration and drive downstream bottomed cycles such as Brayton and Hirn/Rankine ones thus configuring the hybrid system of a SOFC/turbine with very high electric efficiency. Fuel flexibility makes SOFCs independent from pure hydrogen feeding since hydrocarbons can be fed directly to the SOFC and then converted to a hydrogen rich stream by the internal thermochemical processes. SOFC is also able to convert carbon monoxide electrochemically thus contributing to energy production together with hydrogen. SOFCs are much considered for being supplied with biofuels especially biogas and syngas so that biomass gasifiers/SOFC integrated systems contribute to the “waste to energy” chain with a significant reduction in pollution. The paper also deals with the analysis of techno-energy performance by means of ad hoc developed numerical modeling in relation to the main operating parameters. Ample prominence is given to the aspect of fueling emphasizing fuel processing with a deep discussion on the impurities and undesired phenomena that SOFCs suffer. Constituent materials geometry and design methods for the balance of plant were studied. A wide analysis was dedicated to the hybrid system of the SOFC/turbine and to the integrated system of the biomass gasifier/SOFC. Finally an overview of SOFC system manufacturing companies on SOFC research and development worldwide and on the European roadmap was made to reflect the interest in this technology which is an important signal of how communities are sensitive toward clean low carbon and efficient technologies and therefore to provide a decisive and firm impulse to the now outlined energy transition.
Innovative Technology Strategies for the Sustainable Development of Self-Produced Energy in the Colombian Industry
Mar 2023
Publication
This research studies the current state of the Colombian industrial sector which is focused on self-generation processes. The study’s objective is to search for viable technological strategies that strengthen this particular sector’s competitiveness and sustainable development. The analysis shows that internal combustion engines represent 49% of the technologies used for self-generation. The main fuel used in the sector is natural gas with a percentage of 56%. The lack of strategies for the use of residual heat and technological inefficiencies caused a loss of 36% in the energy used in the Colombian industrial sector. Thermoelectric generators are a feasible way to recover energy from exhaust gases in engines used for self-generation. Additionally they allow a 4% reduction in fuel consumption and an improvement in the engine’s energy efficiency. The use of hydrogen as fuel allows a 30% reduction in polluting emissions such as CO2 CO HC and particulate matter. Hydrogen production processes such as water electrolysis allow the participation of Colombia’s solar energy potential leading to sustainable hydrogen production efficiency (60–80%) and a lower economic cost. In general the application of thermoelectric generators and the use of hydrogen gas allow the improvement of the Colombian industrial sector’s environmental social and economic aspects due to greater competitiveness and the reduction in emissions and operating costs.
Evaluation of Sourcing Decision for Hydrogen Supply Chain Using an Integrated Multi-Criteria Decision Analysis (MCDA) Tool
Apr 2023
Publication
The use of fossil fuels has caused many environmental issues including greenhouse gas emissions and associated climate change. Several studies have focused on mitigating this problem. One dynamic direction for emerging sources of future renewable energy is the use of hydrogen energy. In this research we evaluate the sourcing decision for a hydrogen supply chain in the context of a case study in Thailand using group decision making analysis for policy implications. We use an integrative multi-criteria decision analysis (MCDA) tool which includes an analytic hierarchy process (AHP) fuzzy AHP (FAHP) and data envelopment analysis (DEA) to analyze weighted criteria and sourcing alternatives using data collected from a group of selected experts. A list of criteria related to sustainability paradigms and sourcing decisions for possible use of hydrogen energy including natural gas coal biomass and water are evaluated. Our results reveal that political acceptance is considered the most important criterion with a global weight of 0.514 in the context of Thailand. Additionally natural gas is found to be the foreseeable source for hydrogen production in Thailand with a global weight of 0.313. We also note that the analysis is based on specific data inputs and that an alternative with a lower score does not imply that the source is not worth exploring.
A Review of Port Decarbonisation Options: Identified Opportunities for Deploying Hydrogen Technologies
Apr 2024
Publication
The utilisation of hydrogen is being explored as a viable solution for reducing carbon emissions in port operations with potential applications in cargo handling transportation and shipping vessel operations. To comprehensively list the decarbonisation options in ports this study conducted a Systematic Literature Review to identify and then survey twelve highly cited review papers. Initially a typology approach was used to categorise the decarbonisation options by activities and technologies. Subsequently the study introduced a novel Port Energy Map to reveal the energy system pathways and their interconnections. Each pathway was then converted into a simpler linear sequence of activities shown as a Port Energy System Taxonomy which outlines the energy supply and energy-using activities. By utilising this taxonomy and map the study identified opportunities and research gaps for integrating hydrogen technologies into port energy systems which serves as a valuable tool for assessing port decarbonisation options.
Progress of Performance, Emission, and Technical Measures of Hydrogen Fuel Internal-Combustion Engines
Oct 2022
Publication
To achieve the goals of low carbon emission and carbon neutrality some urgent challenges include the development and utilization of low-carbon or zero-carbon internal combustion engine fuels. Hydrogen as a clean efficient and sustainable fuel has the potential to meet the abovementioned challenges. Thereby hydrogen internal combustion engines have been attracting attention because of their zero carbon emissions high thermal efficiency high reliability and low cost. In this paper the opportunities and challenges faced by hydrogen internal-combustion engines were analyzed. The progress of hydrogen internal-combustion engines on the mixture formation combustion mode emission reduction knock formation mechanism and knock suppression measures were summarized. Moreover possible technical measures for hydrogen internal-combustion engines to achieve higher efficiency and lower emissions were suggested.
The Hydrogen Fuel Cell Battery: Replacing the Combustion Engine in Heavy Vehicles
Nov 2022
Publication
This opinion piece describes how the optimal integration of hydrogen-fuel-cell with battery in a heavy highly-utilised vehicle can extend vehicle range while cutting refuelling time and reducing cost compared to a pure battery electric vehicle.
Modelling and Simulation of a Hydrogen-Based Hybrid Energy Storage System with a Switching Algorithm
Oct 2022
Publication
Currently transitioning from fossil fuels to renewable sources of energy is needed considering the impact of climate change on the globe. From this point of view there is a need for development in several stages such as storage transmission and conversion of power. In this paper we demonstrate a simulation of a hybrid energy storage system consisting of a battery and fuel cell in parallel operation. The novelty in the proposed system is the inclusion of an electrolyser along with a switching algorithm. The electrolyser consumes electricity to intrinsically produce hydrogen and store it in a tank. This implies that the system consumes electricity as input energy as opposed to hydrogen being the input fuel. The hydrogen produced by the electrolyser and stored in the tank is later utilised by the fuel cell to produce electricity to power the load when needed. Energy is therefore stored in the form of hydrogen. A battery of lower capacity is coupled with the fuel cell to handle transient loads. A parallel control algorithm is developed to switch on/off the charging and discharging cycle of the fuel cell and battery depending upon the connected load. Electrically equivalent circuits of a polymer electrolyte membrane electrolyser polymer electrolyte membrane fuel cell necessary hydrogen oxygen water tanks and switching controller for the parallel operation were modelled with their respective mathematical equations in MATLAB® Simulink®. In this paper we mainly focus on the modelling and simulation of the proposed system. The results showcase the simulated system’s mentioned advantages and compare its ability to handle loads to a battery-only system.
Air Mass Flow and Pressure Optimisation of a PEM Fuel Cell Range Extender System
Aug 2022
Publication
In order to eliminate the local CO2 emissions from vehicles and to combat the associated climate change the classic internal combustion engine can be replaced by an electric motor. The two most advantageous variants for the necessary electrical energy storage in the vehicle are currently the purely electrochemical storage in batteries and the chemical storage in hydrogen with subsequent conversion into electrical energy by means of a fuel cell stack. The two variants can also be combined in a battery electric vehicle with a fuel cell range extender so that the vehicle can be refuelled either purely electrically or using hydrogen. The air compressor a key component of a PEM fuel cell system can be operated at different air excess and pressure ratios which influence the stack as well as the system efficiency. To asses the steady state behaviour of a PEM fuel cell range extender system a system test bench utilising a commercially available 30 kW stack (96 cells 409 cm2 cell area) was developed. The influences of the operating parameters (air excess ratio 1.3 to 1.7 stack temperature 20 °C–60 °C air compressor pressure ratio up to 1.67 load point 122 mA/cm2 to 978 mA/cm2) on the fuel cell stack voltage level (constant ambient relative humidity of 45%) and the corresponding system efficiency were measured by utilising current voltage mass flow temperature and pressure sensors. A fuel cell stack model was presented which correlates closely with the experimental data (0.861% relative error). The air supply components were modelled utilising a surface fit. Subsequently the system efficiency of the validated model was optimised by varying the air mass flow and air pressure. It is shown that higher air pressures and lower air excess ratios increase the system efficiency at high loads. The maximum achieved system efficiency is 55.21% at the lowest continuous load point and 43.74% at the highest continuous load point. Future work can utilise the test bench or the validated model for component design studies to further improve the system efficiency.
Optimal Design for a Hybrid Microgrid-hydrogen Storage Facility in Saudi Arabia
May 2022
Publication
Background: Sustainable development requires access to afordable reliable and efcient energy to lift billions of people out of poverty and improve their standard of living. The development of new and renewable forms of energy that emit less CO2 may not materialize quickly enough or at a price point that allows people to attain the standard of living they desire and deserve. As a result a parallel path to sustainability must be developed that uses both renewable and clean carbon-based methods. Hybrid microgrids are promoted to solve various electrical and energy-related issues that incorporate renewable energy sources such as photovoltaics wind diesel generation or a combination of these sources. Utilizing microgrids in electric power generation has several benefts including clean energy increased grid stability and reduced congestion. Despite these advantages microgrids are not frequently deployed because of economic concerns. To address these fnancial concerns it is necessary to explore the ideal confguration of micro-grids based on the quantity quality and availability of sustainable energy sources used to install the microgrid and the optimal design of microgrid components. These considerations are refected in net present value and levelized energy cost. Methods: HOMER was used to simulate numerous system confgurations and select the most feasible solution according to the net present value levelizied cost of energy and hydrogen operating cost and renewable fraction. HOMER performed a repeated algorithm process to determine the most feasible system configuration and parameters with the least economic costs and highest benefits to achieve a practically feasible system configuration. Results: This article aimed to construct a cost-effective microgrid system for Saudi Arabia’s Yanbu city using five configurations using excess energy to generate hydrogen. The obtained results indicate that the optimal configuration for the specified area is a hybrid photovoltaic/wind/battery/generator/fuel cell/hydrogen electrolyzer microgrid with a net present value and levelized energy cost of $10.6 billion and $0.15/kWh. Conclusion: With solar photovoltaic and wind generation costs declining building electrolyzers in locations with excellent renewable resource conditions such as Saudi Arabia could become a low-cost hydrogen supply option even when accounting for the transmission and distribution costs of transporting hydrogen from renewable resource locations to end-users. The optimum confguration can generate up to 32132 tons of hydrogen per year (tH2/year) and 380824 tons per year of CO2 emissions can be avoided.
Evaluation of Process Simulation and Reactor Technologies of an Integrated Power-to-liquid Plant at a Cement Factory
Mar 2023
Publication
A novel carbon capture and utilization (CCU) process is described in which process-related carbon dioxide is captured from cement plant exhaust gas (10000 tons/year) and converted with green hydrogen in a Fischer Tropsch synthesis to liquid mainly paraffinic hydrocarbons (syncrude approx. 3000 tons/year) which is finally processed to polyolefins. This CCU process chain is simulated with the software package ASPEN Plus V12.1®. In a first step the influence of hydrogen production technology such as PEM and SOEC and reverse water-gas shift reactor (rWGS) technology (electrified and autothermal design) on plant specific efficiencies (Power-to-Liquid PtL carbon conversion) product volumes and investment operating and net production costs (NPC) is investigated. Furthermore process routes reducing the CO2 content in the Fischer Tropsch feed gas are elaborated implementing a CO2 separation unit or recycle streams back to the rWGS reactor. Unexpectedly CO2 capture and recycle streams back to the rWGS show no significant impact on the performance of each process scenario particularly in terms of the product quantity. However lower PtL efficiencies and higher NPC are noticeable for these cases. The techno-economic assessment reveals that the use of a SOEC and an electrified rWGS reactor offers the technologically best and economically most optimized process chain with NPC of 8.40 EUR/kgsyncrude a PtL efficiency of 54% and a carbon conversion of 85%.
Estimates of the Decarbonization Potential of Alternative Fuels for Shipping as a Function of Vessel Type, Cargo, and Voyage
Oct 2022
Publication
Fuel transition can decarbonize shipping and help meet IMO 2050 goals. In this paper HFO with CCS LNG with CCS bio-methanol biodiesel hydrogen ammonia and electricity were studied using empirical ship design models from a fleet-level perspective and at the Tank-ToWake level to assist operators technology developers and policy makers. The cargo attainment rate CAR (i.e. cargo that must be displaced due to the low-C propulsion system) the ES (i.e. TTW energy needed per ton*n.m.) the CS (economic cost per ton*n.m.) and the carbon intensity index CII (gCO2 per ton*n.m.) were calculated so that the potential of the various alternatives can be compared quantitatively as a function of different criteria. The sensitivity of CAR towards ship type fuel type cargo type and voyage distance were investigated. All ship types had similar CAR estimates which implies that considerations concerning fuel transition apply equally to all ships (cargo containership tankers). Cargo type was the most sensitive factor that made a ship either weight or volume critical indirectly impacting on the CAR of different fuels; for example a hydrogen ship is weight-critical and has 2.3% higher CAR than the reference HFO ship at 20000 nm. Voyage distance and fuel type could result in up to 48.51% and 11.75% of CAR reduction. In addition to CAR the ES CS and CII for a typical mission were calculated and it was found that HFO and LNG with CCS gave about 20% higher ES and CS than HFO and biodiesel had twice the cost while ammonia methanol and hydrogen had 3–4 times the CS of HFO and electricity about 20 times suggesting that decarbonisation of the world’s fleet will come at a large cost. As an example of including all factors in an effort to create a normalized scoring system an equal weight was allocated to each index (CAR ES CS and CII). Biodiesel achieved the highest score (80%) and was identified as the alternative with the highest potential for a deep-seagoing containership followed by ammonia hydrogen bio-methanol and CCS. Electricity has the lowest normalized score of 33%. A total of 100% CAR is achievable by all alternative fuels but with compromises in voyage distance or with refuelling. For example a battery containership carrying an equal amount of cargo as an HFO-fuelled containership can only complete 13% of the voyage distance or needs refuelling seven times to complete 10000 n.m. The results can guide decarbonization strategies at the fleet level and can help optimise emissions as a function of specific missions.
Recent Progress in Ammonia Fuel Cells and their Potential Applications
Nov 2020
Publication
Conventional technologies are largely powered by fossil fuel exploitation and have ultimately led to extensive environmental concerns. Hydrogen is an excellent carbon-free energy carrier but its storage and long-distance transportation remain big challenges. Ammonia however is a promising indirect hydrogen storage medium that has well-established storage and transportation links to make it an accessible fuel source. Moreover the notion of ‘green ammonia’ synthesised from renewable energy sources is an emerging topic that may open significant markets and provide a pathway to decarbonise a variety of applications reliant on fossil fuels. Herein a comparative study based on the chosen design working principles advantages and disadvantages of direct ammonia fuel cells is summarised. This work aims to review the most recent advances in ammonia fuel cells and demonstrates how close this technology type is to integration with future applications. At present several challenges such as material selection NOx formation CO2 tolerance limited power densities and long-term stability must still be overcome and are also addressed within the contents of this review
Options for Methane Fuel Processing in PEMFC System with Potential Maritime Applications
Nov 2022
Publication
Proton-exchange membrane fuel cells (PEMFCs) are low-temperature fuel cells that have excellent starting performance due to their low operating temperature can respond quickly to frequent load fluctuations and can be manufactured in small packages. Unlike existing studies that mainly used hydrogen as fuel for PEMFCs in this study methane is used as fuel for PEMFCs to investigate its performance and economy. Methane is a major component of natural gas which is more economically competitive than hydrogen. In this study methane gas is reformed by the steam reforming method and is applied to the following five gas post-treatment systems: (a) Case 1—water– gas shift only (WGS) (b) Case 2—partial oxidation reforming only (PROX) (c) Case 3—methanation only (d) Case 4—WGS + methanation (e) Case 5—WGS + PROX. In the evaluation the carbon monoxide concentration in the gas did not exceed 10 ppm and the methane component which has a very large greenhouse effect was not regenerated in the post-treated exhaust gas. As a result Case 5 (WGS and PROX) is the only case that satisfied both criteria. Therefore we propose Case 5 as an optimized post-treatment system for methane reforming gas in ship PEMFCs.
Low-Carbon Optimal Scheduling Model for Peak Shaving Resources in Multi-Energy Power Systems Considering Large-Scale Access for Electric Vehicles
May 2023
Publication
Aiming at the synergy between a system’s carbon emission reduction demand and the economy of peak shaving operation in the process of optimizing the flexible resource peaking unit portfolio of a multi-energy power system containing large-scale electric vehicles this paper proposes a low-carbon optimal scheduling model for peak shaving resources in multi-energy power systems considering large-scale access for electric vehicles. Firstly the charging and discharging characteristics of electric vehicles were studied and a comprehensive cost model for electric vehicles heat storage and hydrogen storage was established. At the same time the carbon emission characteristics of multienergy power systems and their emission cost models under specific carbon trading mechanisms were established. Secondly the change characteristics of the system’s carbon emissions were studied and a carbon emission cost model of multi-energy power was established considering the carbon emission reduction demand of the system. Then taking the carbon emission of the system and the peak regulating operation costs of traditional units energy storage and new energy unit as optimization objectives the multi-energy power system peak regulation multi-objective optimization scheduling model was established and NSGA-II was used to solve the scheduling model. Finally based on a regional power grid data in Northeast China the improved IEEE 30 node multi-energy power system peak shaving simulation model was built and the simulation analysis verified the feasibility of the optimal scheduling model proposed in this paper.
Performance and Emission Optimisation of an Ammonia/ Hydrogen Fuelled Linear Joule Engine Generator
Mar 2024
Publication
This paper presents a Linear Joule Engine Generator (LJEG) powered by ammonia and hydrogen co-combustion to tackle decarbonisation in the electrification of transport propulsion systems. A dynamic model of the LJEG which integrates mechanics thermodynamics and electromagnetics sub-models as well as detailed combustion chemistry analysis for emissions is presented. The dynamic model is integrated and validated and the LJEG performance is optimised for improved performance and reduced emissions. At optimal conditions the engine could generate 1.96 kWe at a thermal efficiency of 34.3% and an electrical efficiency of 91%. It is found that the electromagnetic force of the linear alternator and heat addition from the external combustor and engine valve timing have the most significant influences on performance whereas the piston stroke has a lesser impact. The impacts of hydrogen ratio oxygen concentration inlet pressure and equivalence ratio of ammonia-air on nitric oxide (NO) formation and reduction are revealed using a detailed chemical kinetic analysis. Results indicated that rich combustion and elevated pressure are beneficial for NO reduction. The rate of production analysis indicates that the equivalence ratio significantly changes the relative contribution among the critical NO formation and reduction reaction pathways.
Optimal Sizing of a Stand-Alone Hybrid Power System Based on Battery/Hydrogen with an Improved Ant Colony Optimization
Sep 2016
Publication
A distributed power system with renewable energy sources is very popular in recent years due to the rapid depletion of conventional sources of energy. Reasonable sizing for such power systems could improve the power supply reliability and reduce the annual system cost. The goal of this work is to optimize the size of a stand-alone hybrid photovoltaic (PV)/wind turbine (WT)/battery (B)/hydrogen system (a hybrid system based on battery and hydrogen (HS-BH)) for reliable and economic supply. Two objectives that take the minimum annual system cost and maximum system reliability described as the loss of power supply probability (LPSP) have been addressed for sizing HS-BH from a more comprehensive perspective considering the basic demand of load the profit from hydrogen which is produced by HS-BH and an effective energy storage strategy. An improved ant colony optimization (ACO) algorithm has been presented to solve the sizing problem of HS-BH. Finally a simulation experiment has been done to demonstrate the developed results in which some comparisons have been done to emphasize the advantage of HS-BH with the aid of data from an island of Zhejiang China.
Coordinated Control of a Wind-Methanol-Fuel Cell System with Hydrogen Storage
Dec 2017
Publication
This paper presents a wind-methanol-fuel cell system with hydrogen storage. It can manage various energy flow to provide stable wind power supply produce constant methanol and reduce CO2 emissions. Firstly this study establishes the theoretical basis and formulation algorithms. And then computational experiments are developed with MATLAB/Simulink (R2016a MathWorks Natick MA USA). Real data are used to fit the developed models in the study. From the test results the developed system can generate maximum electricity whilst maintaining a stable production of methanol with the aid of a hybrid energy storage system (HESS). A sophisticated control scheme is also developed to coordinate these actions to achieve satisfactory system performance.
Thermodynamic and Emission Analysis of a Hydrogen/Methane Fueled Gas Turbine
May 2023
Publication
The importance of hydrogen in the effort to decarbonize the power sector has grown immensely in recent years. Previous studies have investigated the effects of mixing hydrogen into natural gas for gas turbine combustors but limited studies have examined the resulting effects hydrogen addition has on the entire system. In this work a thermodynamic model of a gas turbine with combustion chemical kinetics integrated is created and the effects hydrogen addition (0-100 volume percent addition) has on the system performance emissions and combustion kinetics are analyzed. The maximum system performance is achieved when the maximum turbine inlet temperature is reached and the resulting optimal fuel/air equivalence ratio is determined. As hydrogen is added to the fuel mixture the optimal equivalence ratio shifts leaner causing non-linearity in emissions and system performance at optimal conditions. An analysis of variance is conducted and it is shown that isentropic efficiencies of the turbine and compressor influences the system performance the most out of any system parameter. While isentropic efficiencies of the turbine and compressor increase towards 100% an operating regime where the optimal system efficiency cannot be achieved is discovered due to the lower flammability limit of the fuel being reached. This can be overcome by mixing hydrogen into the fuel.
Design Investigation of Potential Long-Range Hydrogen Combustion Blended Wing Body Aircraft with Future Technologies
Jun 2023
Publication
Present work investigates the potential of a long-range commercial blended wing body configuration powered by hydrogen combustion engines with future airframe and propulsion technologies. Future technologies include advanced materials load alleviation techniques boundary layer ingestion and ultra-high bypass ratio engines. The hydrogen combustion configuration was compared to the configuration powered by kerosene with respect to geometric properties performance characteristics energy demand equivalent CO2 emissions and Direct Operating Costs. In addition technology sensitivity studies were performed to assess the potential influence of each technology on the configuration. A multi-fidelity sizing methodology using low- and mid-fidelity methods for rapid configuration sizing was created to assess the configuration and perform robust analyses and multi-disciplinary optimizations. To assess potential uncertainties of the fidelity of aerodynamic analysis tools high-fidelity aerodynamic analysis and optimization framework MACHAero was used for additional verification. Comparison of hydrogen and kerosene blended wing body aircraft showed a potential reduction of equivalent CO2 emission by 15% and 81% for blue and green hydrogen compared to the kerosene blended wing body and by 44% and 88% with respect to a conventional B777-300ER aircraft. Advancements in future technologies also significantly affect the geometric layout of aircraft. Boundary layer ingestion and ultra-high bypass ratio engines demonstrated the highest potential for fuel reduction although both technologies conflict with each other. However operating costs of hydrogen aircraft could establish a significant problem if pessimistic and base hydrogen price scenarios are achieved for blue and green hydrogen respectively. Finally configurational problems featured by classical blended wing body aircraft are magnified for the hydrogen case due to the significant volume requirements to store hydrogen fuel.
Future of Hydrogen in Industry: Initial Industrial Site Surveys
Jul 2023
Publication
This is a summary report of a study which aimed to understand the safety feasibility cost and impacts for 7 industrial sites to switch from natural gas to 100% hydrogen for heating. The volunteer industrial sites:<br/>♦ are located away from industrial clusters<br/>♦ use natural gas to meet most of their energy demand<br/>♦ will likely be most impacted by decisions on the future of the natural gas grid<br/>We have published the report in order to share its findings with other industrial sites and wider industry in particular those considering hydrogen as an option for decarbonisation.<br/>Note that:<br/>♦ some work was carried out on a non-hydrogen alternative energy source but to a lesser level of detail and not to determine the optimal decarbonisation solution<br/>♦ the findings do not apply to other end user environments because of differences between these environments and the consumption of gas<br/>The study was commissioned in 2022 by the former Department for Business and Energy and undertaken by AECOM and their safety sub-contractor ESR.<br/>The evidence will inform strategic decisions in 2026 on the role of low carbon hydrogen as a replacement for natural gas heating.
Optimal Pathways for the Decarbonisation of the Transport Sector: Trade-offs Between Battery and Hydrogen Technologies Using a Whole Energy System Perspective
Jun 2023
Publication
Several countries have revised their targets in recent years to reach net-zero CO2 emissions across all sectors by 2050 and the transport sector is responsible for a significant share of these emissions. This study compares possible pathways to decarbonise the transport sector through electrification including passenger cars light commercial vehicles and heavy commercial vehicles. To do so we explore 125 scenarios by varying the share of battery and hydrogen-based fuel cell electric vehicles in each of the three categories above independently. We further model the decarbonisation of the industrial hydrogen demand using electrolysers with hydrogen storage. To explore the potential role of electric and hydrogen transport as well as their trade-offs we use GRIMSEL an open-source sector coupling energy system model of Switzerland which includes the residential commercial industrial and transport sectors with four energy carriers namely electricity heat hot water and hydrogen. The total costs are minimised from a social planner perspective. We find that the full electrification of the transport sector could lead on average to a 12% increase in costs by 2050 and 1.3 MtCO2/year which represents a 90% CO2 emissions reduction for the whole sector. Second the transport energy self-sufficiency (i.e. the share of domestic electricity generation in final transport demand) may reach up to 50% for the scenarios with the largest share of battery electric vehicles mainly due to a smaller energy demand than with hydrogen vehicles. Third more than three quarters of the industrial hydrogen production is met by local photovoltaic electricity coupled with battery at minimum costs i.e. green hydrogen. Finally the use of hydrogen as an energy carrier to store electricity over a long period is not cost-optimal.
Prospects and Impediments for Hydrogen Fuel Cell Buses
Jun 2021
Publication
The number of demonstration projects with fuel cell buses has been increasing worldwide. The goal of this paper is to analyse prospects and barriers for fuel cell buses focusing on their economic- technical- and environmental performance. Our results show that the prices of fuel cell buses although decreasing over time are still about 40% higher than those of diesel buses. With the looming ban of diesel vehicles and current limitations of battery electric vehicles fuel cell buses could become a viable alternative in the mid-to long-term. With the requirements for a better integration of renewable energy sources in the transport system interest in hydrogen is rising. Hydrogen produced from renewables used in fuel cell buses has the potential to save about 93% of CO2 emissions in comparison to diesel buses. Yet from environmental point-of-view it has to be ensured that hydrogen is produced from renewables. Currently the major barrier for a faster penetration of fuel cell buses are their high purchase prices which could be significantly reduced with the increasing number of buses through technological learning. The final conclusion is that a tougher transport policy framework is needed which fully reflects the environmental impact of different buses used.
Synthetic Fuels in the German Industry Sector Depending on Climate Protection Level
Aug 2021
Publication
Especially the electrification of the industry sector is highly complex and challenging mainly due to process-specific requirements. In this context there are several industrial processes where the direct and indirect use of electricity is subject to technical restrictions. In order to achieve the national climate goals the fossil energy consumption remaining after the implementation of efficiency and sufficiency measures as well as direct electrification has to be substituted through hydrogen and synthetic gaseous liquid and solid hydrocarbons. As the main research object the role of synthetic fuels in industrial transformation paths is investigated and analyzed by combining individual greenhouse gas abatement measures within the Sector Model Industry. Sector Model Industry is an energy consumption model that performs discrete deterministic energy and emission dynamic calculations with a time horizon up to 2050 at macroeconomic level. The results indicate that the use of synthetic fuels can be expected with a high level of climate protection. The industrial CO2 target in the model makes it necessary to replace CO2 -intensive fossil with renewable fuels. The model uses a total of 163 TWh of synthetic fuels in the climate protection scenario and thus achieves an 88% decrease in CO2 emissions in 2050 compared to 1990. This means that the GHG abatement achieved in industry is within the range of the targeted CO2 mitigation of the overall system in Germany of between 80 and 95% in 2050 compared to 1990. Due to technical restrictions the model mainly uses synthetic methane instead of hydrogen (134 TWh). The results show that despite high costs synthetic fuels are crucial for defossilization as a fall back option in the industrial scenario considering high climate ambition. The scenario does not include hydrogen technologies for heat supply. Accordingly the climate protection scenario uses hydrogen only in the steel industry for the direct reduction of iron (21 TWh). 8 TWh of synthetic oil substitute the same amount of fossil oil in the climate protection scenario. A further analysis conducted on the basis of the model results shows that transformation in the energy system and the use of smart ideas concepts and technologies are a basic prerequisite for enabling the holistic defossilisation of industry. The findings in the research can contribute to the cost-efficient use of synthetic fuels in industry and thus serve as a basis for political decision making. Moreover the results may have a practical relevance not only serving as a solid comparison base for the outcome of other studies but also as input data for further simulation of energy system transformation paths.
Analysis of Power to Gas Technologies for Energy Intensive Industries in European Union
Jan 2023
Publication
Energy Intensive Industries (EII) are high users of energy and some of these facilities are extremely dependent on Natural Gas for processing heat production. In European countries where Natural Gas is mostly imported from external producers the increase in international Natural Gas prices is making it difficult for some industries to deliver the required financial results. Therefore they are facing complex challenges that could cause their delocalization in regions with lower energy costs. European countries lack on-site Natural Gas resources and the plans to reduce greenhouse gas emissions in the industrial sector make it necessary to find an alternative. Many different processes cannot be electrified and in these cases synthetic methane is one of the solutions and also represents an opportunity to reduce external energy supply dependency. This study analyzes the current development of power-to-gas technological solutions that could be implemented in large industrial consumers to produce Synthetic Methane using Green Hydrogen as a raw source and using Renewable Energy electricity mainly produced with photovoltaic or wind energy. The study also reviews the triple bottom line impact and the current development status and associated costs for each key component of a power-to-gas plant and the requirements to be fulfilled in the coming years to develop a cost-competitive solution available for commercial use.
Optimal Battery and Hydrogen Fuel Cell Sizing in Heavy-haul Locomotives
Jul 2023
Publication
Global supply chains must be decarbonised as part of meeting climate targets set by the United Nations and world leaders. Rail networks are vital infrastructure in passenger and freight transport however have not received the same push for decarbonisation as road transport. In this investigation we used real world data from locomotives operating on seven rail corridors to identify optimal battery capacity and hydrogen fuel cell (HFC) power in hybrid systems. We found that the required battery capacity is dependent on both the available regenerative braking energy and on the capacity required to buffer surpluses and deficits from the HFC. The optimal system for each corridor was identified however it was found that one 3.6 MWh battery and 860 kW HFC system could service six of the seven corridors. The optimal systems presented in this work suggest an average of around 5 h of battery storage for the HFC power which is larger than the 2 h previously reported in literature. This may indicate a gap between purely theoretical works that use only route topography and speed and those that employ real world locomotive data.
The Potential of Zero-carbon Bunker Fuels in Developing Countries
Apr 2015
Publication
To meet the climate targets set forth in the International Maritime Organization’s Initial GHG Strategy the maritime transport sector needs to abandon the use of fossil-based bunker fuels and turn toward zero-carbon alternatives which emit zero or at most very low greenhouse gas (GHG) emissions throughout their lifecycles. This report “The Potential of Zero-Carbon Bunker Fuels in Developing Countries” examines a range of zero-carbon bunker fuel options that are considered to be major contributors to shipping’s decarbonized future: biofuels hydrogen and ammonia and synthetic carbon-based fuels. The comparison shows that green ammonia and green hydrogen strike the most advantageous balance of favorable features due to their lifecycle GHG emissions broader environmental factors scalability economics and technical and safety implications. Furthermore the report finds that many countries including developing countries are very well positioned to become future suppliers of zero-carbon bunker fuels—namely ammonia and hydrogen. By embracing their potential these countries would be able to tap into an estimated $1+ trillion future fuel market while modernizing their own domestic energy and industrial infrastructure. However strategic policy interventions are needed to unlock these potentials.
Optimal Configuration and Scheduling Model of a Multi-Park Integrated Energy System Based on Sustainable Development
Mar 2023
Publication
To maximize the utilization of renewable energy (RE) as much as possible in cold areas while reducing traditional energy use and carbon dioxide emissions a three-layer configuration optimization and scheduling model considering a multi-park integrated energy system (MPIES) a shared energy storage power station (SESPS) and a hydrogen refueling station (HRS) cooperation based on the Wasserstein generative adversarial networks the simultaneous backward reduction technique and the Quantity-Contour (WGAN-SBR_QC) method is proposed. Firstly the WGAN-SBR_QC method is used to generate typical scenarios of RE output. Secondly a three-layer configuration and schedule optimization model is constructed using MPIES SESPS and HRS. Finally the model’s validity is investigated by selecting a multi-park in Eastern Mongolia. The results show that: (1) the typical scenario of RE output improved the overall robustness of the system. (2) The profits of the MPIES and HRS increased by 1.84% and 52.68% respectively and the SESPS profit increased considerably. (3) The proposed approach increased RE utilization to 99.47% while reducing carbon emissions by 32.67%. Thus this model is a reference for complex energy system configuration and scheduling as well as a means of encouraging RE use.
Location Optimization of Hydrogen Refueling Stations in Hydrogen Expressway Based on Hydrogen Supply Chain Cost
Jan 2021
Publication
Hydrogen energy is regarded as an important way to achieve carbon emission reduction. This paper focuses on the combination of the design of the hydrogen supply chain network and the location of hydrogen refueling stations on the expressway. Based on the cost analysis of the hydrogen supply chain a multi-objective model is developed to determine the optimal scale and location of hydrogen refueling stations on the hydrogen expressway. The proposed model considers the hydrogen demand forecast hydrogen source selection hydrogen production and storage and transportation hydrogen station refueling mode etc. Taking Dalian City China as an example with offshore wind power as a reliable green hydrogen supply to select the location and capacity of hydrogen refueling stations for the hydrogen energy demonstration section of a certain expressway under multiple scenarios. The results of the case show that 4 and 5 stations are optimized on the expressway section respectively and the unit hydrogen cost is $14.3 /kg H2 and $11.8 /kg H2 respectively which are equal to the average hydrogen price in the international range. The optimization results verify the feasibility and effectiveness of the model.
Combustion Characteristics of Hydrogen in a Noble Gas Compression Ignition Engine
Jul 2021
Publication
Hydrogen eliminates carbon emissions from compression ignition (CI) engines while noble gases eliminate nitrogen oxide (NOx) emissions by replacing nitrogen. Noble gases can increase the in-cylinder temperature during the compression stroke due to their high specific heat ratio. This paper aims to find the optimum parameters for hydrogen combustion in an argon–oxygen atmosphere and to study hydrogen combustion in all noble gases providing hydrogen combustion data with suitable engine parameters to predict hydrogen ignitability under different conditions. Simulations are performed with Converge CFD software based on the Yanmar NF19SK direct injection CI (DICI) engine parameters. The results are validated with the experimental results of hydrogen combustion in an argon–oxygen atmosphere with a rapid compression expansion machine (RCEM) and modifications of the hydrogen injection timing and initial temperature are proposed. Hydrogen ignition in an argon atmosphere is dependent on a minimum initial temperature of 340 K but the combustion is slightly unstable. Helium and neon are found to be suitable for hydrogen combustion in low compression ratio (CR) engines. However krypton and xenon require temperature modification and a high CR for stable ignition. Detailed parameter recommendations are needed to improve hydrogen ignitability in conventional diesel engines with the least engine modification.
Analysis of the Use of Recycled Aluminum to Generate Green Hydrogen in an Electric Bicycle
Feb 2023
Publication
This article proposes using recycled aluminum generating hydrogen in situ at low pressure to power a 250 W electric bicycle with a fuel cell (FC) to increase the average speed and autonomy compared to a conventional electric bicycle with a battery. To generate hydrogen the aluminum–water reaction with a 6 M NaOH solution is used as a catalyst. This article details the parts of the generation system the electronic configuration used the aluminum- and reagent-loading procedure and the by-products obtained as well as the results of the operation without pedaling with a resistance equivalent to a flat terrain and at maximum power of the accelerator for one and two loads of about 100 g of aluminum each. This allows us to observe different hybrid strategies with a low-capacity battery in each case. The goal is to demonstrate that it is possible to store energy in a long-lasting transportable low-pressure and sustainable manner using recycled-aluminum test tubes and to apply this to mobility
The Potential of Fuel Cells as a Drive Source of Maritime Transport
Nov 2017
Publication
The state of environmental pollution brought about as a result of the modern civilization has been monitored in the interests of the environment and human health since the seventies of the last century. Ensuring the energy security is one of the most basic existential requirements for a functional civilized society. The growing civilizational needs caused by broadly understood development generate demand for the production of all kinds of goods in all sectors of the economy as well as world-wide information transfer. The current energy demand is mostly covered using fossil fuels such as coal oil and natural gas. Some of the energy demand is covered by the energy generated in nuclear reactions and a small part of it comes from renewable energy sources. Energy derived from fossil fuels is inevitably associated with fuel oxidation processes. These processes in addition to generating heat are responsible for the emission of harmful compounds to the atmosphere: carbon monoxide carbon dioxide nitrogen oxides hydrocarbons and particulate matter. These pollutants pose a serious threat to the people as well as the environment in which they live. Due to the large share of fossil fuel energy generation in the process of combustion it becomes necessary to seek other means of obtaining the so-called "clean energy". Fuel cells may have a very high potential in this respect. Their development has enabled attempts to use them in all modes of transport. An important factor in the development of fuel cells is their relatively high efficiency and the coinciding strictening of the emission norms from internal combustion engines used to power maritime transport. Therefore the aim of this article has been to assess the potential of fuel cells as a main source of propulsion power source. A review of the designs of fuel cell systems and their use was performed. The article summarizes the assessment of the potential role of fuel cells as a power source of maritime transport.
Power Scheduling Optimization Method of Wind-Hydrogen Integrated Energy System Based on the Improved AUKF Algorithm test2
Nov 2022
Publication
With the proposal of China’s green energy strategy the research and development technologies of green energy such as wind energy and hydrogen energy are becoming more and more mature. However the phenomenon of wind abandonment and anti-peak shaving characteristics of wind turbines have a great impact on the utilization of wind energy. Therefore this study firstly builds a distributed wind-hydrogen hybrid energy system model then proposes the power dispatching optimization technology of a wind-hydrogen integrated energy system. On this basis a power allocation method based on the AUKF (adaptive unscented Kalman filter) algorithm is proposed. The experiment shows that the power allocation strategy based on the AUKF algorithm can effectively reduce the incidence of battery overcharge and overdischarge. Moreover it can effectively deal with rapid changes in wind speed. The wind hydrogen integrated energy system proposed in this study is one of the important topics of renewable clean energy technology innovation. Its grid-connected power is stable with good controllability and the DC bus is more secure and stable. Compared with previous studies the system developed in this study has effectively reduced the ratio of abandoned air and its performance is significantly better than the system with separate grid connected fans and single hydrogen energy storage. It is hoped that this research can provide some solutions for the research work on power dispatching optimization of energy systems.
Green Hydrogen for Heating and its Impact on the Power System
Jun 2021
Publication
With a relatively high energy density hydrogen is attracting increasing attention in research commercial and political spheres specifically as a fuel for residential heating which is proving to be a difficult sector to decarbonise in some circumstances. Hydrogen production is dependent on the power system so any scale use of hydrogen for residential heating will impact various aspects of the power system including electricity prices and renewable generation curtailment (i.e. wind solar). Using a linearised optimal power flow model and the power infrastructure on the island of Ireland this paper examines least cost optimal investment in electrolysers in the presence of Ireland's 70% renewable electricity target by 2030. The introduction of electrolysers in the power system leads to an increase in emissions from power generation which is inconsistent with some definitions of green hydrogen. Electricity prices are marginally higher with electrolysers whereas the optimal location of electrolysers is driven by a combination of residential heating demand and potential surplus power supplies at electricity nodes.
A Study into Proton Exchange Membrane Fuel Cell Power and Voltage Prediction using Artificial Neural Network
Sep 2022
Publication
Polymer Electrolyte Membrane fuel cell (PEMFC) uses hydrogen as fuel to generate electricity and by-product water at relatively low operating temperatures which is environmentally friendly. Since PEMFC performance characteristics are inherently nonlinear and related predicting the best performance for the different operating conditions is essential to improve the system’s efficiency. Thus modeling using artificial neural networks (ANN) to predict its performance can significantly improve the capabilities of handling multi-variable nonlinear performance of the PEMFC. This paper predicts the electrical performance of a PEMFC stack under various operating conditions. The four input terms for the 5 W PEMFC include anode and cathode pressures and flow rates. The model performances are based on ANN using two different learning algorithms to estimate the stack voltage and power. The models have shown consistently to be comparable to the experimental data. All models with at least five hidden neurons have coefficients of determination of 0.95 or higher. Meanwhile the PEMFC voltage and power models have mean squared errors of less than 1 × 10−3 V and 1 × 10−3 W respectively. Therefore the model results demonstrate the potential use of ANN into the implementation of such models to predict the steady state behavior of the PEMFC system (not limited to polarization curves) for different operating conditions and help in the optimization process for achieving the best performance of the system.
Performance and Failure Analysis of a Retrofitted Cessna Aircraft with a Fuel Cell Power System Fuelled with Liquid Hydrogen
Jan 2022
Publication
Proton-Exchange Membrane-Fuel Cells (PEM-FC) are regarded as one of the prime candidates to provide emissions-free electricity for propulsion systems of aircraft. Here a turbocharged Fuel Cell Power System (FCPS) powered with liquid H2 (LH2) is designed and modelled to provide a primary power source in retrofitted Cessna 208 Caravan aircraft. The proposed FCPS comprises multiple PEM-FCs assembled in stacks two single-stage turbochargers to mitigate the variation of the ambient pressure with altitude two preheaters two humidifiers and two combustors. Interlinked component sub-models are constructed in MATLAB and referenced to commercially available equipment. The FCPS model is used to simulate steady-state responses in a proposed 1.5 h (∼350 km) mission flight determining the overall efficiency of the FCPS at 43% and hydrogen consumption of ∼28 kg/h. The multi-stack FCPS is modelled applying parallel fluidic and electrical architectures analysing two power-sharing methods: equally distributed and daisy-chaining. The designed LH2-FCPS is then proposed as a power system to a retrofitted Cessna 208 Caravan and with this example analysed for the probability of failure occurrence. The results demonstrate that the proposed “dual redundant” FCPS can reach failure rates comparable to commercial jet engines with a rate below 1.6 failures per million hours.
A Hydrogen-Fueled Micro Gas Turbine Unit for Carbon-Free Heat and Power Generation
Oct 2022
Publication
The energy transition with transformation into predominantly renewable sources requires technology development to secure power production at all times despite the intermittent nature of the renewables. Micro gas turbines (MGTs) are small heat and power generation units with fast startup and load-following capability and are thereby suitable backup for the future’s decentralized power generation systems. Due to MGTs’ fuel flexibility a range of fuels from high-heat to lowheat content could be utilized with different greenhouse gas generation. Developing micro gas turbines that can operate with carbon-free fuels will guarantee carbon-free power production with zero CO2 emission and will contribute to the alleviation of the global warming problem. In this paper the redevelopment of a standard 100-kW micro gas turbine to run with methane/hydrogen blended fuel is presented. Enabling micro gas turbines to run with hydrogen blended fuels has been pursued by researchers for decades. The first micro gas turbine running with pure hydrogen was developed in Stavanger Norway and launched in May 2022. This was achieved through a collaboration between the University of Stavanger (UiS) and the German Aerospace Centre (DLR). This paper provides an overview of the project and reports the experimental results from the engine operating with methane/hydrogen blended fuel with various hydrogen content up to 100%. During the development process the MGT’s original combustor was replaced with an innovative design to deal with the challenges of burning hydrogen. The fuel train was replaced with a mixing unit new fuel valves and an additional controller that enables the required energy input to maintain the maximum power output independent of the fuel blend specification. This paper presents the test rig setup and the preliminary results of the test campaign which verifies the capability of the MGT unit to support intermittent renewable generation with minimum greenhouse gas production. Results from the MGT operating with blended methane/hydrogen fuel are provided in the paper. The hydrogen content varied from 50% to 100% (volume-based) and power outputs between 35 kW to 100kW were tested. The modifications of the engine mainly the new combustor fuel train valve settings and controller resulted in a stable operation of the MGT with NOx emissions below the allowed limits. Running the engine with pure hydrogen at full load has resulted in less than 25 ppm of NOx emissions with zero carbon-based greenhouse gas production.
The Role of Hydrogen in Heavy Transport to Operate within Planetary Boundaries
Jul 2021
Publication
Green hydrogen i.e. produced from renewable resources is attracting attention as an alternative fuel for the future of heavy road transport and long-distance driving. However the benefits linked to zero pollution at the usage stage can be overturned when considering the upstream processes linked to the raw materials and energy requirements. To better understand the global environmental implications of fuelling heavy transport with hydrogen we quantified the environmental impacts over the full life cycle of hydrogen use in the context of the Planetary Boundaries (PBs). The scenarios assessed cover hydrogen from biomass gasification (with and without carbon capture and storage [CCS]) and electrolysis powered by wind solar bioenergy with CCS nuclear and grid electricity. Our results show that the current diesel-based-heavy transport sector is unsustainable due to the transgression of the climate change-related PBs (exceeding standalone by two times the global climate-change budget). Hydrogen-fuelled heavy transport would reduce the global pressure on the climate change-related PBs helping the transport sector to stay within the safe operating space (i.e. below one-third of the global ecological budget in all the scenarios analysed). However the best scenarios in terms of climate change which are biomass-based would shift burdens to the biosphere integrity and nitrogen flow PBs. In contrast burden shifting in the electrolytic scenarios would be negligible with hydrogen from wind electricity emerging as an appealing technology despite attaining higher carbon emissions than the biomass routes
Numerical Modeling for Rapid Charging of Hydrogen Gas Vessel in Fuel Cell Vehicle
Feb 2023
Publication
As a fuel for power generation high-pressure hydrogen gas is widely used for transportation and its efficient storage promotes the development of fuel cell vehicles (FCVs). However as the filling process takes such a short time the maximum temperature in the storage tank usually undergoes a rapid increase which has become a thorny problem and poses great technical challenges to the steady operation of hydrogen FCVs. For security reasons SAE J2601/ISO 15869 regulates a maximum temperature limit of 85 ◦C in the specifications for refillable hydrogen tanks. In this paper a two-dimensional axisymmetric and a three-dimensional numerical model for fast charging of Type III 35 MPa and 70 MPa hydrogen vehicle cylinders are proposed in order to effectively evaluate the temperature rise within vehicle tanks. A modified standard k-ε turbulence model is utilized to simulate hydrogen gas charging. The equation of state for hydrogen gas is adopted with the thermodynamic properties taken from the National Institute of Standards and Technology (NIST) database taking into account the impact of hydrogen gas’ compressibility. To validate the numerical model three groups of hydrogen rapid refueling experimental data are chosen. After a detailed comparison it is found that the simulated results calculated by the developed numerical model are in good agreement with the experimental results with average temperature differences at the end time of 2.56 K 4.08 K and 4.3 K. The present study provides a foundation for in-depth investigations on the structural mechanics analysis of hydrogen gas vessels during fast refueling and may supply some technical guidance on the design of charging experiments.
A Comparison of Well-to-Wheels Energy Use and Emissions of Hydrogen Fuel Cell, Electric, LNG, and Diesel-Powered Logistics Vehicles in China
Jul 2023
Publication
Global energy and environmental issues are becoming increasingly serious and the promotion of clean energy and green transportation has become a common goal for all countries. In the logistics industry traditional fuels such as diesel and natural gas can no longer meet the requirements of energy and climate change. Hydrogen fuel cell logistics vehicles are expected to become the mainstream vehicles for future logistics because of their “zero carbon” advantages. The GREET model is computer simulation software developed by the Argonne National Laboratory in the USA. It is extensively utilized in research pertaining to the energy and environmental impact of vehicles. This research study examines four types of logistics vehicles: hydrogen fuel cell vehicles (FCVs) electric vehicles LNG-fueled vehicles and diesel-fueled vehicles. Diesel-fueled logistics vehicles are currently the most abundant type of vehicle in the logistics sector. LNG-fueled logistics vehicles are considered as a short-term alternative to diesel logistics vehicles while electric logistics vehicles are among the most popular types of new-energy vehicles currently. We analyze and compare their well-to-wheels (WTW) energy consumption and emissions with the help of GREET software and conduct lifecycle assessments (LCAs) of the four types of vehicles to analyze their energy and environmental benefits. When comparing the energy consumption of the four vehicle types electric logistics vehicles (EVs) have the lowest energy consumption with slightly lower energy consumption than FCVs. When comparing the nine airborne pollutant emissions of the four vehicle types the emissions of the FCVs are significantly lower than those of spark-ignition internal combustion engine logistics vehicles (SI ICEVs) compression-ignition direct-injection internal combustion engine logistics vehicles (CIDI ICEVs) and EVs. This study fills a research gap regarding the energy consumption and environmental impact of logistics vehicles in China.
Energy Management Strategy Based on Dynamic Programming with Durability Extension for Fuel Cell Hybrid Tramway
Sep 2021
Publication
This paper proposes an energy management strategy for a fuel cell (FC) hybrid power system based on dynamic programming and state machine strategy which takes into account the durability of the FC and the hydrogen consumption of the system. The strategy first uses the principle of dynamic programming to solve the optimal power distribution between the FC and supercapacitor (SC) and then uses the optimization results of dynamic programming to update the threshold values in each state of the finite state machine to realize real-time management of the output power of the FC and SC. An FC/SC hybrid tramway simulation platform is established based on RTLAB real-time simulator. The compared results verify that the proposed EMS can improve the durability of the FC increase its working time in the high-efficiency range effectively reduce the hydrogen consumption and keep the state of charge in an ideal range.
A Review on Production and Implementation of Hydrogen as a Green Fuel in Internal Combustion Engines
Nov 2022
Publication
Huge and continuously growing non-renewable energy consumption due to human daily activities is accountable for the fossil fuel source crisis in recent decades. The growing concern about the emissions from internal combustion engines also impels the development of new energy sources to replace or reduce conventional non-renewable energy usage. In this context hydrogen is found to be a promising solution in internal combustion engines to address these issues. The novelty of this review is to provide an overview of the use of hydrogen as internal combustion fuel covering the operations in both spark-ignition (SI) and compression-ignition (CI) engines. Majority of the studies had shown that hydrogen enrichment fuels marked incredible engine performance in terms of thermal efficiency fuel consumption and energy consumption. In addition reductions in exhaust emissions such as smoke soot HC CO CO2 and NOx can be achieved in both SI and CI engines with proper operating conditions. Moreover outstanding combustion behaviours were observed in both internal combustion engines with the application of hydrogen fuel. These enhancements were mainly attributed to the physico-chemical properties of hydrogen which exhibits higher calorific value and rapid flaming speed as discussed in this paper. To summarize hydrogen utilisation in the IC and SI engines aided improvements in engine performance exhaust emissions and combustion behaviours under appropriate operating conditions and minor engine modifications such as ignition system and iridium spark plug for SI engines.
Feasibility of Hydrogen Fuel Cell Technology for Railway Intercity Services: A Case Study for the Piedmont in North Carolina
Jul 2021
Publication
Diesel fuel combustion results in exhaust containing air pollutants and greenhouse gas emissions. Many railway vehicles use diesel fuel as their energy source. Exhaust emissions as well as concerns about economical alternative power supply have driven efforts to move to hydrogen motive power. Hydrogen fuel cell technology applied to railways offers the opportunity to eliminate harmful exhaust emissions and the potential for a low- or zero-emission energy supply chain. Currently only multiple-unit trains with hydrail technology operate commercially. Development of an Integrated Hybrid Train Simulator for intercity railway is presented. The proposed tool incorporates the effect of powertrain components during the wheel-to-tank process. Compared to its predecessors the proposed reconfigurable tool provides high fidelity with medium requirements and minimum computation time. Single train simulation and the federal government’s Greenhouse gases Regulated Emissions and Energy use in Transportation (GREET) model are used in combination to evaluate the feasibility of various train and powertrain configurations. The Piedmont intercity service operating in North Carolina is used as a case study. The study includes six train configurations and powertrain options as well as nine hydrogen supply options in addition to the diesel supply. The results show that a hydrail option is not only feasible but a low- or zero-carbon hydrogen supply chain could be possible.
The Impact of Fuel Cell Electric Freight Vehicles on Fuel Consumption and CO2 Emissions: The Case of Italy
Oct 2022
Publication
The Italian Recovery and Resilience Plan promotes among its many actions the use of hydrogen by the deployment of refuelling stations for heavy-duty vehicles predicting a 5–7% penetration rate of fuel cell electric vehicles (FCEVs) for long-distance freight transport. In this work the impact of this action on the reduction of greenhouse gas emissions and consumption was estimated assuming the plan’s objectives are met. To achieve this aim a national simulation model of the road freight transport system was implemented consisting of a graph of the national road network and an inter-provincial origin-destination matrix; the graph was based on data available from OpenStreetMap while the interprovincial matrix was estimated from the interregional matrix with the use of two linear regression models one for emitted goods and one for attracted goods. The simulation of the system made it possible to estimate the impact of this action on CO2 emissions and fuel consumption under three different scenarios. From 2025 to 2040 a reduction in CO2 emissions ranging from around 9 to around 16.5 million tonnes was estimated and a reduction in consumption ranging from around 3 billion to around 5.6 billion litres of diesel. These results show how this action can be seen as one of the bricks contributing to the fight against global warming.
Cold Start Cycling Durability of Fuel Cell Stacks for Commercial Automotive Applications
Sep 2022
Publication
System durability is crucial for the successful commercialization of polymer electrolyte fuel cells (PEFCs) in fuel cell electric vehicles (FCEVs). Besides conventional electrochemical cycling durability during long-term operation the effect of operation in cold climates must also be considered. Ice formation during start up in sub-zero conditions may result in damage to the electrocatalyst layer and the polymer electrolyte membrane (PEM). Here we conduct accelerated cold start cycling tests on prototype fuel cell stacks intended for incorporation into commercial FCEVs. The effect of this on the stack performance is evaluated the resulting mechanical damage is investigated and degradation mechanisms are proposed. Overall only a small voltage drop is observed after the durability tests only minor damage occurs in the electrocatalyst layer and no increase in gas crossover is observed. This indicates that these prototype fuel cell stacks successfully meet the cold start durability targets for automotive applications in FCEVs.
Data-driven Scheme for Optimal Day-ahead Operation of a Wind/hydrogen System Under Multiple Uncertainties
Nov 2022
Publication
Hydrogen is believed as a promising energy carrier that contributes to deep decarbonization especially for the sectors hard to be directly electrified. A grid-connected wind/hydrogen system is a typical configuration for hydrogen production. For such a system a critical barrier lies in the poor cost-competitiveness of the produced hydrogen. Researchers have found that flexible operation of a wind/hydrogen system is possible thanks to the excellent dynamic properties of electrolysis. This finding implies the system owner can strategically participate in day-ahead power markets to reduce the hydrogen production cost. However the uncertainties from imperfect prediction of the fluctuating market price and wind power reduce the effectiveness of the offering strategy in the market. In this paper we proposed a decision-making framework which is based on data-driven robust chance constrained programming (DRCCP). This framework also includes multi-layer perception neural network (MLPNN) for wind power and spot electricity price prediction. Such a DRCCP-based decision framework (DDF) is then applied to make the day-ahead decision for a wind/hydrogen system. It can effectively handle the uncertainties manage the risks and reduce the operation cost. The results show that for the daily operation in the selected 30 days offering strategy based on the framework reduces the overall operation cost by 24.36% compared to the strategy based on imperfect prediction. Besides we elaborate the parameter selections of the DRCCP to reveal the best parameter combination to obtain better optimization performance. The efficacy of the DRCCP method is also highlighted by the comparison with the chance-constrained programming method.
Effects of Fuel Cell Size and Dynamic Limitations on the Durability and Efficiency of Fuel Cell Hybrid Electric Vehicles under Driving Conditions
Mar 2024
Publication
In order to enhance the durability of fuel cell systems in fuel cell hybrid electric vehicles (FCHEVs) researchers have been dedicated to studying the degradation monitoring models of fuel cells under driving conditions. To predict the actual degradation factors and lifespan of fuel cell systems a semi-empirical and semi-physical degradation model suitable for automotive was proposed and developed. This degradation model is based on reference degradation rates obtained from experiments under known conditions which are then adjusted using coefficients based on the electrochemical model. By integrating the degradation model into the vehicle simulation model of FCHEVs the impact of different fuel cell sizes and dynamic limitations on the efficiency and durability of FCHEVs was analyzed. The results indicate that increasing the fuel cell stack power improves durability while reducing hydrogen consumption but this effect plateaus after a certain point. Increasing the dynamic limitations of the fuel cell leads to higher hydrogen consumption but also improves durability. When considering only the rated power of the fuel cell a comparison between 160 kW and 100 kW resulted in a 6% reduction in hydrogen consumption and a 10% increase in durability. However when considering dynamic limitation factors comparing the maximum and minimum limitations of a 160 kW fuel cell hydrogen consumption increased by 10% while durability increased by 83%.
Technology Portfolio Assessment for Near-zero Emission Iron and Steel Industry in China
May 2023
Publication
China aims to peak CO2 emissions before 2030 and to achieve carbon neutrality before 2060; hence industrial sectors in China are keen to figure out appropriate pathways to support the national target of carbon neutrality. The objective of this study is to explore near-zero emission pathways for the steel industry of China through a detailed technology assessment. The innovative technology development has been simulated using the AIM-China/steel model developed by including material-based technologies and optimal cost analysis. Six scenarios have been given in terms of different levels of production output emission reduction and carbon tax. Near-zero emission and carbon tax scenarios have shown that China’s steel industry can achieve near-zero emission using electric furnaces and hydrogen-based direct reduction iron technologies with policy support. Based on these technologies minimised production costs have been calculated revealing that the steel produced by these technologies is cost-effective. Moreover the feedstock cost can play a key role in these technology portfolios especially the cost of scrap iron ore and hydrogen. In addition the feedstock supply can have strong regional effects and can subsequently impact the allocation of steelmaking in the future. Therefore China can achieve near-zero emissions in the steel industry and electric furnace and hydrogen-based direct reduction iron technologies are crucial to achieving them.
THyGA - Long Term Effect of H2 on Appliances Tested
May 2023
Publication
The goals of the long-term tests were to see the impact of blends of hydrogen and natural gas on the technical condition of the appliances and their performance after several hours of operation. To do so they were run through an accelerated test program amounting to more than 3000 testing hours for the boilers and more than 2500 testing hours for the cookers. The percentage of hydrogen in the test gas was 30% by volume. Three boilers and two cookers were tested by DGC and two boilers by GWI. This report describes the test protocol the results and analysis on the seven appliances tested.
Global Warming Potential and Societal-governmental Impacts of the Hydrogen Ecosystem in the Transportation Sector
Apr 2024
Publication
The environmental and societal challenges of our contemporary society are leading us to reconsider our approaches to vehicle design. The aim of this article is to provide the reader with the essential knowledge needed to responsibly design a vehicle equipped with a hydrogen fuel cell system. Two pivotal aspects of hydrogen-electric powertrain eco-design are examined. First the global warming potential is assessed for both PEMFC systems and Type IV hydrogen tanks accounting for material extraction production and end-of-life considerations. The usage phase was omitted from the study in order to facilitate data adaptation for each type of use. PEMFC exhibits a global warming potential of about 29.2 kgCO2eq/kW while the tank records 12.4 kgCO2eq/kWh with transportation factors considered. Secondly the societal and governmental impacts are scrutinized with the carbon-intensive hydrogen tank emerging as having the most significant societal and governmental risks. In fact on a scale of 1–5 with 5 representing the highest level of risk the PEMFC system has a societal impact and governance risk of 2.98. The Type IV tank has a societal impact and governance risk of 3.31. Although uncertainties persist regarding the results presented in this study the values obtained provide an overview of the societal and governmental impacts of the hydrogen ecosystem in the transportation sector. The next step will be to compare for the same usage which solution between hydrogen-electric and 100% battery is more respectful of humans and the environment.
Refuelling Infrastructure Requirements for Renewable Hydrogen Road Fuel through the Energy Transition
Nov 2022
Publication
Current commercially available options for decarbonisation of road transport are battery electric vehicles or hydrogen fuel cell electric vehicles. BEVs are increasingly deployed while hydrogen is in its infancy. We examine the infrastructure necessary to support hydrogen fuelling to various degrees of market penetration. Scotland makes a good exemplar of transport transition with a world leading Net-Zero ambition and proven pathways for generating ample renewable energy. We identified essential elements of the new transport systems and the associated capital expenditure. We developed nine scenarios based on the pace of change and the ultimate market share of hydrogen and constructed a model to analyse their infrastructure requirements. This is a multi-period model incorporating Monte Carlo and Markov Chain elements. A “no-regrets” initial action is rapid deployment of enough hydrogen infrastructure to facilitate the early years of a scenario where diesel fuel becomes replaced with hydrogen. Even in a lower demand scenario of only large and heavy goods vehicles using hydrogen the same infrastructure would be required within a further two years. Subsequent investment in infrastructure could be considered in the light of this initial development.
Design and Analysis of Cryogenic Cooling System for Electric Propulsion System Using Liquid Hydrogen
Jan 2023
Publication
As the demand for eco-friendly energy increases hydrogen energy and liquid hydrogen storage technologies are being developed as an alternative. Hydrogen has a lower liquefaction point and higher thermal conductivity than nitrogen or neon used in general cryogenic systems. Therefore the application of hydrogen to cryogenic systems can increase efficiency and stability. This paper describes the design and analysis of a cryogenic cooling system for an electric propulsion system using liquid hydrogen as a refrigerant and energy source. The proposed aviation propulsion system (APS) consists of a hydrogen fuel cell a battery a power distribution system and a motor. For a lab-scale 5 kW superconducting motor using a 2G high-temperature superconducting (HTS) wire the HTS motor and cooling system were analyzed for electromagnetic and thermal characteristics using a finite element method-based analysis program. The liquid hydrogen-based cooling system consists of a pre-cooling system a hydrogen liquefaction system and an HTS coil cooling system. Based on the thermal load analysis results of the HTS coil the target temperature for hydrogen gas pre-cooling the number of buffer layers and the cryo-cooler capacity were selected to minimize the thermal load of the hydrogen liquefaction system. As a result the hydrogen was stably liquefied and the temperature of the HTS coil corresponding to the thermal load of the designed lab-scale HTS motor was maintained at 30 K.
Green Energy Hubs for the Military That Can Also Support he Civilian Mobility Sector with Green Hydrogen
May 2023
Publication
To support the energy transition in the area of defence we developed a tool and conducted a feasibility study to transform a military site from being a conventional energy consumer to becoming an energy-positive hub (or prosumer). Coupling a green energy source (e.g. photovoltaic wind) with fuel cells and hydrogen storage satisfied the dynamic energy consumption and dynamic hydrogen demand for both the civilian and military mobility sectors. To make the military sector independent of its civilian counterpart a military site was connected to a renewable energy hub. This made it possible to develop a stand-alone green-energy system transform the military site into a positive energy hub and achieve autonomous energy operation for several days or weeks. An environmental and economic assessment was conducted to determine the carbon footprint and the economic viability. The combined installed capacity of the solar power plant and the wind turbine was 2.5 times the combined peak consumption with about 19% of the total electricity and 7% of the hydrogen produced still available to external consumers.
Technological Pathways for Decarbonizing Petroleum Refining
Sep 2021
Publication
This paper discusses the technical specifications of how U.S. petroleum refineries can reduce facility emissions and shift to produce low-carbon fuels for hard to abate sectors by utilizing existing innovative technologies.
Low-carbon Economic Dispatch of Hydrogen-containing Integrated Energy System Considering Stepped Demand Response
Apr 2024
Publication
Vigorously developing an integrated energy system (IES) centered on the utilization of hydrogen energy is a crucial strategy to achieve the goal of carbon peaking and carbon neutrality. During the energy conversion process a hydrogen storage system releases a large amount of heat. By integrating a heat recovery mechanism we have developed a sophisticated hydrogen energy utilization model that accommodates multiple operational conditions and maximizes heat recovery thereby enhancing the efficiency of energy use on the supply side. To harness the potential of load-side response an integrated demand response (IDR) model accounting for price and incentives is established and a ladder-type subsidy incentive mechanism is proposed to deeply unlock load-side response capacity. Considering system economics and low carbon an IES source-load coordinated optimal scheduling model is proposed optimizing source-load coordinated operation for optimally integrated economy factoring in reward and punishment ladder-type carbon trading. Demonstrations reveal that the proposed methodology not only improves the efficiency of energy utilization but also minimizes wind energy wastage activates consumer engagement and reduces both system costs and carbon emissions thus proving the effectiveness of our optimization approach.
Topology and Control of Fuel Cell Generation Converters
Jun 2023
Publication
Fuel cell power generation is one of the important ways of utilizing hydrogen energy which has good prospects for development. However fuel cell volt-ampere characteristics are nonlinear the output voltage is low and the fluctuation range is large and a power electronic converter matching its characteristics is required to achieve efficient and stable work. Based on the analysis of the fuel cell’s characteristic mechanism maximum power point tracking algorithm fuel cell converter characteristics application and converter control strategy the paper summarizes the general principles of the topology of fuel cell converters. In addition based on the development status of new energy hydrogen energy is organically combined with other new energy sources and the concept of 100% absorption system of new energy with green hydrogen as the main body is proposed to provide a reference for the development of hydrogen energy.
Numerical Investigation on NOx Emission of a Hydrogen-Fuelled Dual-Cylinder Free-Piston Engine
Jan 2023
Publication
The free-piston engine is a type of none-crank engine that could be operated under variable compression ratio and this provides it flexible fuel applicability and low engine emission potential. In this work several 1-D engine models including conventional gasoline engines free-piston gasoline engines and free-piston hydrogen engines have been established. Both engine performance and emission performance under engine speeds between 5–11 Hz and with different equivalent ratios have been simulated and compared. Results indicated that the free-piston engine has remarkable potential for NOx reduction and the largest reduction is 57.37% at 6 Hz compared with a conventional gasoline engine. However the figure of NOx from the hydrogen free-piston engine is slightly higher than that of the gasoline free-piston engine and the difference increases with the increase of engine speed. In addition several factors and their relationships related to hydrogen combustion in the free-piston engine have been investigated and results show that the equivalent ratio ϕ = 0.88 is a vital point that affects NOx production and the ignition advance timing could also affect combustion duration the highest in-cylinder temperature and NOx production to a large extent.
Sector Coupling and Migration towards Carbon-Neutral Power Systems
Feb 2023
Publication
There is increasing interest in migrating to a carbon-neutral power system that relies on renewable energy due to concerns about greenhouse gas emissions energy shortages and global warming. However the increasing share of renewable energy has added volatility and uncertainty to power system operations. Introducing new devices and using flexible resources may help solve the problem but expanding the domain of the problem can be another solution. Sector coupling which integrates production consumption conversion and storage by connecting various energy domains could potentially meet the needs of each energy sector. It can also reduce the generation of surplus energy and unnecessary carbon emissions. As a result sector coupling an integrated energy system increases the acceptance of renewable energy in the traditional power system and makes it carbon neutral. However difficulties in large-scale integration low conversion efficiency and economic feasibility remain obstacles. This perspective paper discusses the background definition and components of sector coupling as well as its functions and examples in rendering power systems carbon-neutral. The current limitations and outlook of sector coupling are also examined.
Time‐Decoupling Layered Optimization for Energy and Transportation Systems under Dynamic Hydrogen Pricing
Jul 2022
Publication
The growing popularity of renewable energy and hydrogen‐powered vehicles (HVs) will facilitate the coordinated optimization of energy and transportation systems for economic and en‐ vironmental benefits. However little research attention has been paid to dynamic hydrogen pricing and its impact on the optimal performance of energy and transportation systems. To reduce the dependency on centralized controllers and protect information privacy a time‐decoupling layered optimization strategy is put forward to realize the low‐carbon and economic operation of energy and transportation systems under dynamic hydrogen pricing. First a dynamic hydrogen pricing mechanism was formulated on the basis of the share of renewable power in the energy supply and introduced into the optimization of distributed energy stations (DESs) which will promote hydro‐ gen production using renewable power and minimize the DES construction and operation cost. On the basis of the dynamic hydrogen price optimized by DESs and the traffic conditions on roads the raised user‐centric routing optimization method can select a minimum cost route for HVs to purchase fuels from a DES with low‐cost and/or low‐carbon hydrogen. Finally the effectiveness of the proposed optimization strategy was verified by simulations.
One-dimensional Numerical Investigation on Multi-cylinder Gasoline Engine Fueled by Micro-emulsions, CNG, and Hydrogen in Dual Fuel Mode
Aug 2022
Publication
This research work is the novel state-of-the-art technology performed on multi-cylinder SI engine fueled compressed natural gas emulsified fuel and hydrogen as dual fuel. This work predicts the overall features of performance combustion and exhaust emissions of individual fuels based on AVL Boost simulation technology. Three types of alternative fuels have been compared and analyzed. The results show that hydrogen produces 20% more brake power than CNG and 25% more power than micro-emulsion fuel at 1500 r/min which further increases the brake power of hydrogen CNG and micro-emulsions in the range of 25% 20% and 15% at higher engine speeds of 2500–4000 r/min respectively. In addition the brake-specific fuel consumption is the lowest for 100% hydrogen followed by CNG 100% and then micro-emulsions at 1500 r/min. At 2500– 5000 r/min there is a significant drop in brake-specific fuel consumption due to a lean mixture at higher engine speeds. The CO HC and NOx emissions significantly improve for hydrogen CNG and micro-emulsion fuel. Hydrogen fuel shows zero CO and HC emissions and is the main objective of this research to produce 0% carbon-based emissions with a slight increase in NOx emissions and CNG shows 30% lower CO emissions than micro-emulsions and 21.5% less hydrocarbon emissions than micro-emulsion fuel at stoichiometric air/fuel ratio.
A Parametric Approach for Conceptual Integration and Performance Studies of Liquid Hydrogen Short–Medium Range Aircraft
Jul 2022
Publication
The present paper deals with the investigation at conceptual level of the performance of short–medium-range aircraft with hydrogen propulsion. The attention is focused on the relationship between figures of merit related to transport capability such as passenger capacity and flight range and the parameters which drive the design of liquid hydrogen tanks and their integration with a given aircraft geometry. The reference aircraft chosen for such purpose is a box-wing short–mediumrange airplane the object of study within a previous European research project called PARSIFAL capable of cutting the fuel consumption per passenger-kilometre up to 22%. By adopting a retrofitting approach non-integral pressure vessels are sized to fit into the fuselage of the reference aircraft under the assumption that the main aerodynamic flight mechanic and structural characteristics are not affected. A parametric model is introduced to generate a wide variety of fuselage-tank cross-section layouts from a single tank with the maximum diameter compatible with a catwalk corridor to multiple tanks located in the cargo deck and an assessment workflow is implemented to perform the structural sizing of the tanks and analyse their thermodynamic behaviour during the mission. This latter is simulated with a time-marching approach that couples the fuel request from engines with the thermodynamics of the hydrogen in the tanks which is constantly subject to evaporation and depending on the internal pressure vented-out in gas form. Each model is presented in detail in the paper and results are provided through sensitivity analyses to both the technologic parameters of the tanks and the geometric parameters influencing their integration. The guidelines resulting from the analyses indicate that light materials such as the aluminium alloy AA2219 for tanks’ structures and polystyrene foam for the insulation should be selected. Preferred values are also indicted for the aspect ratios of the vessel components i.e. central tube and endcaps as well as suggestions for the integration layout to be adopted depending on the desired trade-off between passenger capacity as for the case of multiple tanks in the cargo deck and achievable flight ranges as for the single tank in the section.
Optimized Design of a H2-Powered Moped for Urban Mobility
Mar 2024
Publication
Micro-mobility plays an increasingly important role in the current energy transition thanks to its low energy consumption and reduced contribution to urban congestion. In this scenario fuel cell hybrid electric vehicles have several advantages over state-of-the-art battery electric vehicles such as increased driving ranges and reduced recharge times. In this paper we study the conversion of a commercial electric moped (Askoll eS3 ®) into a fuel cell hybrid electric vehicle by finding the optimal design of the components through an optimization methodology based on backward dynamic programming. This optimal design and operation strategy can also be implemented with a rulesbased approach. The results show that a system composed of a 1 kW proton exchange membrane fuel cell a 2000 Sl metal hydride hydrogen tank and a 240 Wh buffer battery can cover the same driving range as the batteries in an electric moped (119 km). Such a hybrid system occupies considerably less volume (almost 40 L) and has a negligibly higher mass. The free volume can be used to extend the driving range up to almost three times the nominal value. Moreover by using a high-pressure composite tank it is possible to increase the mass energy density of the onboard energy storage (although compression can require up to 10% of the hydrogen’s chemical energy). The fuel cell hybrid electric vehicle can be recharged with green hydrogen that is locally produced. In detail we analyze a residential scenario and a shared mobility scenario in the small Italian city of Viterbo.
Thermodynamic Analysis of Hydrogen Utilization as Alternative Fuel in Cement Production
Jul 2022
Publication
Growing attention to the environmental aspect has urged the effort to reduce CO2 emission as one of the greenhouse gases. The cement industry is one of the biggest CO2 emitters in this world. Alternative fuel is one of the challenging issues in cement production due to the limited fossil fuel resources and environmental concerns. Meanwhile hydrogen (H2) has been reported as a promising non-carbon fuel with ammonia (NH3) as the main candidate for chemical storage methods. In this work an integrated system of cement production with an alternative H2-based fuel is proposed consisting of the dehydrogenation process of NH3 and the H2 combustion to provide the required thermal energy for clinker production. Different catalysts are employed and evaluated to analyze the specific energy input (SEI). The result shows that the conversion rate strongly determines the SEI with minimum SEI (3829.8 MJ t-clinker-1 ) achieved by Ni-Pt-based catalyst at a reaction temperature of 600 ºC. Compared to the conventional fuel of coal the H2-based integrated cement production system shows a significant decrease of 44% in CO2 emission due to carbon-free combustion using H2 as the fuel. The current study on the proposed integrated system of H2-based cement production also provides an initial thermodynamic analysis and basic observation for the adoption of non-carbon-based H2 including the storage system of NH3 in the cement production process.
Optimising Fuel Supply Chains within Planetary Boundaries: A Case Study of Hydrogen for Road Transport in the UK
Jul 2020
Publication
The world-wide sustainability implications of transport technologies remain unclear because their assessment often relies on metrics that are hard to interpret from a global perspective. To contribute to filling this gap here we apply the concept of planetary boundaries (PBs) i.e. a set of biophysical limits critical for operating the planet safely to address the optimal design of sustainable fuel supply chains (SCs) focusing on hydrogen for vehicle use. By incorporating PBs into a mixed-integer linear programming model (MILP) we identify SC configurations that satisfy a given transport demand while minimising the PBs transgression level i.e. while reducing the risk of surpassing the ecological capacity of the Earth. On applying this methodology to the UK we find that the current fossil-based sector is unsustainable as it transgresses the energy imbalance CO2 concentration and ocean acidification PBs heavily i.e. five to 55-fold depending on the downscale principle. The move to hydrogen would help to reduce current transgression levels substantially i.e. reductions of 9–86% depending on the case. However it would be insufficient to operate entirely within all the PBs concurrently. The minimum impact SCs would produce hydrogen via water electrolysis powered by wind and nuclear energy and store it in compressed form followed by distribution via rail which would require as much as 37 TWh of electricity per year. Our work unfolds new avenues for the incorporation of PBs in the assessment and optimisation of energy systems to arrive at sustainable solutions that are entirely consistent with the carrying capacity of the planet.
Alternative Fuels for Internal Combustion Engines
Aug 2020
Publication
The recent transport electrification trend is pushing governments to limit the future use of Internal Combustion Engines (ICEs). However the rationale for this strong limitation is frequently not sufficiently addressed or justified. The problem does not seem to lie within the engines nor with the combustion by themselves but seemingly rather with the rise in greenhouse gases (GHG) namely CO2 rejected to the atmosphere. However it is frequent that the distinction between fossil CO2 and renewable CO2 production is not made or even between CO2 emissions and pollutant emissions. The present revision paper discusses and introduces different alternative fuels that can be burned in IC Engines and would eliminate or substantially reduce the emission of fossil CO2 into the atmosphere. These may be non-carbon fuels such as hydrogen or ammonia or biofuels such as alcohols ethers or esters including synthetic fuels. There are also other types of fuels that may be used such as those based on turpentine or even glycerin which could maintain ICEs as a valuable option for transportation.
Hydrogen-based Integrated Energy and Mobility System for a Real-life Office Environment
Mar 2020
Publication
The current focus on the massive CO2 reduction highlights the need for the rapid development of technology for the production storage transportation and distribution of renewable energy. In addition to electricity we need other forms of energy carriers that are more suitable for energy storage and transportation. Hydrogen is one of the main candidates for this purpose since it can be produced from solar or wind energy and then stored; once needed it can be converted back to electricity using fuel cells. Another important aspect of future energy systems is sector coupling where different sectors e.g. mobility and energy work together to provide better services. In such an integrated system electric vehicles – both battery and hydrogen-based fuel cell – can provide when parked electricity services such as backup power and balancing; when driving they produce no emissions. In this paper we present the concept design and energy management of such an integrated energy and mobility system in a real-life environment at the Shell Technology Centre in Amsterdam. Our results show that storage using hydrogen and salt caverns is much cheaper than using large battery storage systems. We also show that the integration of electric vehicles into the electricity network is technically and economically feasible and that they can provide a flexible energy buffer. Ultimately the results of this study show that using both electricity and hydrogen as energy carriers can create a more flexible reliable and cheaper energy system at an office building.
Standalone Renewable Energy and Hydrogen in an Agricultural Context: A Demonstrative Case
Feb 2019
Publication
Standalone renewable energy is widely used to power irrigation systems. However in agricultural facilities electricity from the grid and diesel are also consumed. The design and sizing of renewable generation involves difficulties derived from the different seasonal profiles of production and demand. If the generation is 100% renewable a considerable energy surplus is usually included. This paper is focused on a renewable energy system which has been installed in a vineyard located in the northeast of Spain. With energy from the photovoltaic fields the wastewater treatment plant of the winery a drip irrigation system and other ancillary consumptions are fed. The favourable effect of combining consumptions with different seasonal profiles is shown. The existence of some deferrable loads and the energy management strategy result in an aggregate consumption curve that is well suited to production. Besides the required energy storage is relatively small. The surplus energy is used for the on-site production of hydrogen by the electrolysis of water. The hydrogen refuels a hybrid fuel cell electric vehicle used for the mobility of workers in the vineyard. In summary electricity and hydrogen are produced on-site (to meet the energy needs) from 100% renewable sources and without operating emissions.
Life Cycle Assessment Integration into Energy System Models: An Application for Power-to-Methane in the EU
Nov 2019
Publication
As the EU energy system transitions to low carbon the technology choices should consider a broader set of criteria. The use of Life Cycle Assessment (LCA) prevents burden shift across life cycle stages or impact categories while the use of Energy System Models (ESM) allows evaluating alternative policies capacity evolution and covering all the sectors. This study does an ex-post LCA analysis of results from JRC-EU-TIMES and estimates the environmental impact indicators across 18 categories in scenarios that achieve 80–95% CO2 emission reduction by 2050. Results indicate that indirect CO2 emissions can be as large as direct ones for an 80% CO2 reduction target and up to three times as large for 95% CO2 reduction. Impact across most categories decreases by 20–40% as the CO2 emission target becomes stricter. However toxicity related impacts can become 35–100% higher. The integrated framework was also used to evaluate the Power-to-Methane (PtM) system to relate the electricity mix and various CO2 sources to the PtM environmental impact. To be more attractive than natural gas the climate change impact of the electricity used for PtM should be 123–181 gCO2eq/kWh when the CO2 comes from air or biogenic sources and 4–62 gCO2eq/kWh if the CO2 is from fossil fuels. PtM can have an impact up to 10 times larger for impact categories other than climate change. A system without PtM results in ~4% higher climate change impact and 9% higher fossil depletion while having 5–15% lower impact for most of the other categories. This is based on a scenario where 9 parameters favor PtM deployment and establishes the upper bound of the environmental impact PtM can have. Further studies should work towards integrating LCA feedback into ESM and standardizing the methodology.
Power-to-Steel: Reducing CO2 through the Integration of Renewable Energy and Hydrogen into the German Steel Industry
Apr 2017
Publication
This paper analyses some possible means by which renewable power could be integrated into the steel manufacturing process with techniques such as blast furnace gas recirculation (BF-GR) furnaces that utilize carbon capture a higher share of electrical arc furnaces (EAFs) and the use of direct reduced iron with hydrogen as reduction agent (H-DR). It is demonstrated that these processes could lead to less dependence on—and ultimately complete independence from—coal. This opens the possibility of providing the steel industry with power and heat by coupling to renewable power generation (sector coupling). In this context it is shown using the example of Germany that with these technologies reductions of 47–95% of CO2 emissions against 1990 levels and 27–95% of primary energy demand against 2008 can be achieved through the integration of 12–274 TWh of renewable electrical power into the steel industry. Thereby a substantial contribution to reducing CO2 emissions and fuel demand could be made (although it would fall short of realizing the German government’s target of a 50% reduction in power consumption by 2050).
Experimental Investigation of the Effects of Simultaneous Hydrogen and Nitrogen Addition on the Emissions and Combustion of a Diesel Engine
Jan 2014
Publication
Overcoming diesel engine emissions trade-off effects especially NOx and Bosch smoke number (BSN) requires investigation of novel systems which can potentially serve the automobile industry towards further emissions reduction. Enrichment of the intake charge with H2 þ N2 containing gas mixture obtained from diesel fuel reforming system can lead to new generation low polluting diesel engines. This paper investigates the effect of simultaneous H2 þ N2 intake charge enrichment on the emissions and combustion of a compression ignition engine. Bottled H2 þ N2 was simultaneously admitted into the intake pipe of the engine in 4% steps starting from 4% (2% H2 þ 2% N2) up to 16% (v/v). The results showed that under specific operating conditions H2 þ N2 enrichment can offer simultaneous NOx BSN and CO emissions reduction. Apart from regulated emissions nitrogen exhaust components were measured. Marginal N2O and zero NH3 emissions were obtained. NO/NO2 ratio increases when speed or load increases. Under low speed low load operation the oxidation of NO is enhanced by the addition of H2 þ N2 mixture. Finally admission of H2 þ N2 has a detrimental effect on fuel consumption
Everything About Hydrogen Podcast: Masters of Scale: Mobilizing the Mobility Sector (Around Hydrogen Fuel Cells)
Nov 2020
Publication
We talk a lot on the EAH podcast series about where hydrogen fuel cell electric vehicles (FCEVs) fit into the overall zero emission vehicle (ZEV) ecosystem. From personal passenger vehicles and the family car to commercial trucking and public transportation fleets and everything in between. Different vehicles and different use cases call for different capabilities and that is what makes the future of decarbonized transportation co interesting.
The podcast can be found on their website
The podcast can be found on their website
Impact of Hydrogen Fuel for CO2 Emission Reduction in Power Generation Sector in Japan
Jun 2017
Publication
Japan’s energy consumption derives mostly from fossil fuels which are un-secure and release a much greenhouse gas emissions. To meet goals of reducing GHG hydrogen gas can be utilized in power generation in hydrogen fired and firing / co-combustion power plants. This paper analyses the impact of hydrogen in the power generation sector using the MARKAL-TIMES Japan optimization model framework. Two models are used: a base scenario without hydrogen and hydrogen scenario in which hydrogen is supplied from 2020 onwards. In the hydrogen scenario other processes which are normally supplied by natural gas are reduced because the gas is instead used to generate power. Adding hydrogen to the energy supply leads to a decrease in projected use of fossil fuels. The hydrogen scenario produces fewer emissions than the base scenario; by 2050 the hydrogen scenario’s estimated 388 metric tons of CO2 emissions is over 250 tons less than the base scenario’s emissions of 588 metric tons.
Hydrogen Fuel Cell Technology for the Sustainable Future of Stationary Applications
Dec 2019
Publication
The climate changes that are becoming visible today are a challenge for the global research community. The stationary applications sector is one of the most important energy consumers. Harnessing the potential of renewable energy worldwide is currently being considered to find alternatives for obtaining energy by using technologies that offer maximum efficiency and minimum pollution. In this context new energy generation technologies are needed to both generate low carbon emissions as well as identifying planning and implementing the directions for harnessing the potential of renewable energy sources. Hydrogen fuel cell technology represents one of the alternative solutions for future clean energy systems. This article reviews the specific characteristics of hydrogen energy which recommends it as a clean energy to power stationary applications. The aim of review was to provide an overview of the sustainability elements and the potential of using hydrogen as an alternative energy source for stationary applications and for identifying the possibilities of increasing the share of hydrogen energy in stationary applications respectively. As a study method was applied a SWOT analysis following which a series of strategies that could be adopted in order to increase the degree of use of hydrogen energy as an alternative to the classical energy for stationary applications were recommended. The SWOT analysis conducted in the present study highlights that the implementation of the hydrogen economy depends decisively on the following main factors: legislative framework energy decision makers information and interest from the end beneficiaries potential investors and existence of specialists in this field.
Optimal Energy Management System Using Biogeography Based Optimization for Grid-connected MVDC Microgrid with Photovoltaic, Hydrogen System, Electric Vehicles and Z-source Converters
Oct 2021
Publication
Currently the technology associated with charging stations for electric vehicles (EV) needs to be studied and improved to further encourage its implementation. This paper presents a new energy management system (EMS) based on a Biogeography-Based Optimization (BBO) algorithm for a hybrid EV charging station with a configuration that integrates Z-source converters (ZSC) into medium voltage direct current (MVDC) grids. The EMS uses the evolutionary BBO algorithm to optimize a fitness function defining the equivalent hydrogen consumption/generation. The charging station consists of a photovoltaic (PV) system a local grid connection two fast charging units and two energy storage systems (ESS) a battery energy storage (BES) and a complete hydrogen system with fuel cell (FC) electrolyzer (LZ) and hydrogen tank. Through the use of the BBO algorithm the EMS manages the energy flow among the components to keep the power balance in the system reducing the equivalent hydrogen consumption and optimizing the equivalent hydrogen generation. The EMS and the configuration of the charging station based on ZSCs are the main contributions of the paper. The behaviour of the EMS is demonstrated with three EV connected to the charging station under different conditions of sun irradiance. In addition the proposed EMS is compared with a simpler EMS for the optimal management of ESS in hybrid configurations. The simulation results show that the proposed EMS achieves a notable improvement in the equivalent hydrogen consumption/generation with respect to the simpler EMS. Thanks to the proposed configuration the output voltage of the components can be upgraded to MVDC while reducing the number of power converters compared with other configurations without ZSC.
Controller Design for Polymer Electrolyte Membrane Fuel Cell Systems for Automotive Applications
May 2021
Publication
Continuous developments in Proton Exchange Membrane Fuel Cells (PEMFC) make them a promising technology to achieve zero emissions in multiple applications including mobility. Incremental advancements in fuel cells materials and manufacture processes make them now suitable for commercialization. However the complex operation of fuel cell systems in automotive applications has some open issues yet. This work develops and compares three different controllers for PEMFC systems in automotive applications. All the controllers have a cascade control structure where a generator of setpoints sends references to the subsystems controllers with the objective to maximize operational efficiency. To develop the setpoints generators two techniques are evaluated: off-line optimization and Model Predictive Control (MPC). With the first technique the optimal setpoints are given by a map obtained off-line of the optimal steady state conditions and corresponding setpoints. With the second technique the setpoints time profiles that maximize the efficiency in an incoming time horizon are continuously computed. The proposed MPC architecture divides the fast and slow dynamics in order to reduce the computational cost. Two different MPC solutions have been implemented to deal with this fast/slow dynamics separation. After the integration of the setpoints generators with the subsystems controllers the different control systems are tested and compared using a dynamic detailed model of the automotive system in the INN-BALANCE project running under the New European Driving Cycle.
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