Applications & Pathways

Since the beginning of the twenty-first century the limitations of the fossil age with regard to the continuing growth of energy demand the peaking mining rate of oil the growing impact of CO₂ emissions on the environment and the dependency of the economy in the industrialized world on the availability of fossil fuels became very obvious. A major change in the energy economy from fossil energy carriers to renewable energy fluxes is necessary. The main challenge is to efficiently convert renewable energy into electricity and the storage of electricity or the production of a synthetic fuel. Hydrogen is produced from water by electricity through an electrolyser. The storage of hydrogen in its molecular or atomic form is a materials challenge. Some hydrides are known to exhibit a hydrogen density comparable to oil; however these hydrides require a sophisticated storage system. The system energy density is significantly smaller than the energy density of fossil fuels. An interesting alternative to the direct storage of hydrogen are synthetic hydrocarbons produced from hydrogen and CO₂ extracted from the atmosphere. They are CO₂ neutral and stored like fossil fuels. Conventional combustion engines and turbines can be used in order to convert the stored energy into work and heat.

Link to document download on Royal Society Website 

The debate on low-carbon heat in Europe has become focused on a narrow range of technological options and has largely neglected hydrogen and fuel cell technologies despite these receiving strong support towards commercialisation in Asia. This review examines the potential benefits of these technologies across different markets particularly the current state of development and performance of fuel cell micro-CHP. Fuel cells offer some important benefits over other low-carbon heating technologies and steady cost reductions through innovation are bringing fuel cells close to commercialisation in several countries. Moreover fuel cells offer wider energy system benefits for high-latitude countries with peak electricity demands in winter. Hydrogen is a zero-carbon alternative to natural gas which could be particularly valuable for those countries with extensive natural gas distribution networks but many national energy system models examine neither hydrogen nor fuel cells for heating. There is a need to include hydrogen and fuel cell heating technologies in future scenario analyses and for policymakers to take into account the full value of the potential contribution of hydrogen and fuel cells to low-carbon energy systems.

With the rapid development of hydrogen production by water electrolysis the coupling between the electricity-hydrogen system has become closer providing an effective way to consume surplus new energy generation. As a form of centralized management of distributed energy resources virtual power plants can aggregate the integrated energy production and consumption segments in a certain region and participate in electricity market transactions as a single entity to enhance overall revenue. Based on this this paper proposes an optimal scheduling model of an electricity-hydrogen coupling virtual power plant (EHC-VPP) considering hydrogen load response relying on hydrogen to ammonia as a flexibly adjustable load-side resource in the EHC-VPP to enable the VPP to participate in the day-ahead energy market to maximize benefits. In addition this paper also considers the impact of the carbon emission penalty to practice the green development concept of energy saving and emission reduction. To validate the economy of the proposed optimization scheduling method in this paper the optimization scheduling results under three different operation scenarios are compared and analyzed. The results show that considering the hydrogen load response and fully exploiting the flexibility resources of the EHC-VPP can further reduce the system operating cost and improve the overall operating efficiency.

Coal and carbon-containing waste are valuable primary and secondary carbon carriers. In the current dominant linear economy such carbon resources are generally combusted to produce electricity and heat and as a way to resolve a nation’s waste issue. Not only is this a wastage of precious carbon resources which can be chemically utilized as raw materials for production of other value-added goods it is also contrary to international efforts to reduce carbon emissions and increase resource efficiency and conservation. This article presents a concept to support the transformation from a linear ‘one-way cradle to grave manufacturing model’ toward a circular carbon economy. The development of new and sustainable value chains through the utilization of coal and waste as alternative raw materials for the chemical industry via a coupling of the energy chemical and waste management sectors offers a viable and future-oriented perspective for closing the carbon cycle. Further benefits also include a lowering of the carbon footprint and increasing resource efficiency and conservation of primary carbon resources. In addition technological innovations and developments that are necessary to support a successful sector coupling will be identified. To illustrate our concept a case analysis of domestic coal and waste as alternative feedstock to imported crude oil for chemical production in Germany will be presented. Last but not least challenges posed by path dependency along technological institutional and human dimensions in the sociotechnical system for a successful transition toward a circular carbon economy will be discussed.

Hydrogen (H2 ) can be a promising energy carrier for decarbonizing the economy and especially the transport sector which is considered as one of the sectors with high carbon emissions due to the extensive use of fossil fuels. H2 is a nontoxic energy carrier that could replace fossil fuels. Fuel Cell Electric Vehicles (FCEVs) can decrease air pollution and reduce greenhouse gases when H2 is produced from Renewable Energy Sources (RES) and at the same time being accessible through a widespread network of Hydrogen Refueling Stations (HRSs). In this study both the sizing of the equipment and financial analysis were performed for an HRS supplied with H2 from the excess electrical energy of a 10 MW wind park. The aim was to determine the optimum configuration of an HRS under the investigation of six different scenarios with various numbers of FCEVs and monthly demands as well as ascertaining the economic viability of each examined scenario. The effect of the number of vehicles that the installation can refuel to balance the initial cost of the investment and the fuel cost in remote regions was investigated. The results showed that a wind-powered HRS could be a viable solution when sized appropriately and H2 can be used as a storage mean for the rejected wind energy. It was concluded that scenarios with low FCEVs penetration have low economic performance since the payback period presented significantly high values.

Numerous studies have shown that a full electrification of passenger cars is needed to stay within the 1.5° C temperature rise. This article deals with the question of how the required shares of alternative vehicles can be achieved by the year 2050. In literature the preferred technology are battery electric vehicles as these are more energy efficient than hydrogen vehicles. To be able to demonstrate how alternative vehicles diffuse into the German market the passenger car investment behavior of private persons was investigated. For this purpose a discrete choice experiment (DCE) with 1921 participants was carried out empirically. The results of the DCE show that the investment costs in particular are important when choosing a vehicle. This is followed by the driving range fuel costs and vehicle type. Less important are the charging infrastructure and CO₂ emissions of the vehicle. A CO₂ tax is of least importance. The utility values of the DCE were used to simulate future market shares. For this purpose the open-source software Invest was developed and different scenarios were defined and calculated. This paper shows that conservative assumptions on attribute development leave a large gap until full electrification as conventional vehicles still account for around 62% of market shares in 2050. In order to achieve full electrification extreme efforts must be made targeting the technical and economic characteristics of the vehicles but also addressing person-related characteristics such as level of information the subjective norm or the technological risk attitude. A ban on new registrations of combustion engines from 2030 could also lead to a full electrification by 2050. An average annual increase in the market share of alternative vehicles of 2.4 percentage points is needed to achieve full electrification. Other important factors are measures that address the modal shift to other modes of transport (rail public transport car-sharing).

Hydrogen is a promising avenue for decarbonising energy systems and providing flexibility. In this paper the JRC-EU-TIMES model – a bottom-up technology-rich model of the EU28 energy system – is used to assess the role of hydrogen in a future decarbonised Europe under two climate scenarios current policy initiative (CPI) and long-term decarbonisation (CAP). Our results indicate that hydrogen could become a viable option already in 2030 – however a long-term CO₂ cap is needed to sustain the transition. In the CAP scenario the share of hydrogen in the final energy consumption of the transport and industry sectors reaches 5% and 6% by 2050. Low-carbon hydrogen production technologies dominate and electrolysers provide flexibility by absorbing electricity at times of high availability of intermittent sources. Hydrogen could also play a significant role in the industrial and transport sectors while the emergence of stationary hydrogen fuel cells for hydrogen-to-power would require significant cost improvements over and above those projected by the experts.

This report shows that low-carbon hydrogen supply at scale is economically and environmentally feasible and will have significant societal benefits if the right localised approach and best-practices for production are used. The report also demonstrates that there is not one single hydrogen production pathway to achieve low lifecycle greenhouse gas (GHG) emissions but rather the need for a fact-based approach that leverages regional resources and includes a combination of different production pathways. This will achieve both emission and cost reductions ultimately helping to decarbonize the energy system and limit global warming.

In 2020 more than 15 countries launched major hydrogen plans and policies and industry players announced new projects of more than 35GW until 2030. As this hydrogen momentum accelerates it is increasingly clear that decision makers must put the focus on decarbonization to ensure hydrogen can fulfil its potential as a key solution in the global clean energy transition making a significant contribution to net zero emissions. To support this effort the two-part Hydrogen Council report provides new data based on an assessment of the GHG emissions generated through different hydrogen supply pathways and the lifecycle GHG emissions for different hydrogen applications (see report part 1 – A Life-cycle Assessment). In addition the report explores 3 hypothetical hydrogen supply scenarios to measure the feasibility and impact of deploying renewable and low-carbon hydrogen at scale (report part 2 – Potential Supply Scenarios).

The report outlines that there are many ways of producing hydrogen and although GHG emissions vary widely very high CO2 savings can be achieved across a broad range of different hydrogen production pathways and end-uses. For example while “green” hydrogen produced through water electrolysis with renewable power achieves the lowest emissions “blue” hydrogen produced from natural gas with high CO2 capture rate and storage can also achieve low emissions if best technologies are used and best practices are followed. Across eight illustrative pathways explored in the report analysis shows that if hydrogen is used significant GHG emission reductions can be made: as much as 60-90% or more compared to conventional fossil alternatives. The study also looked into the gross water demand of hydrogen supply pathways. Water electrolysis has a very low specific water demand of 9 kg per kg of hydrogen compared to cooling of thermal power plants (hundreds of kg/kg) or biomass cultivation (hundreds to thousands of kg/kg).

Furthermore low-carbon hydrogen supply at scale is fully achievable. Having investigated two hypothetical boundary scenarios (a “green-only” and a “blue-only” scenario) to assess the feasibility and impact of decarbonized hydrogen supply the report found that both scenarios are feasible: they are not limited by the world’s renewables potential or carbon sequestration (CCS) capacities and they do not exceed the speed at which industry can scale. In the Hydrogen Council’s “Scaling up” study a demand of 21800 TWh hydrogen has been identified for the year 2050. To achieve this a compound annual growth rate of 30-35% would be needed for electrolysers and CCS. This deployment rate is in line with the growth of the offshore wind and solar PV industry over the last decade.

Hydrogen Council data released in January 2020 showed that a wide range of hydrogen applications can become competitive by 2030 driven also by falling costs of renewable and low-carbon hydrogen[1]. The new study indicates that a combination of “green” and “blue” production pathways would lead to hydrogen cost reductions relative to either boundary scenario. By making use of the near-term cost advantage of “blue” while also scaling up “green” hydrogen as the most cost-efficient option in many regions in the medium and long-term the combined approach lowers average hydrogen costs between now and 2050 relative to either boundary scenario.

Part 1 – A Life-cycle Assessment

• The life-cycle assessment (LCA) analysis in this study addresses every aspect of the supply chain from primary energy extraction to end use. Eight primary-energy-to-hydrogen value chains have been selected for illustrative purposes.
• Across the hydrogen pathways and applications depicted very high to high GHG emission reduction can be demonstrated using green (solar wind) and blue hydrogen.
• In the LCA study renewables + electrolysis shows strongest GHG reduction of the different hydrogen supply pathways assessed in this study with a best-case blue hydrogen pathway also coming into the same order of magnitude.

Part 2 – Potential Supply Scenarios

• Currently the vast majority of hydrogen is produced by fossil pathways. To achieve a ten-fold build-out of hydrogen supply by 2050 as envisaged by the Hydrogen Council in its ‘Scaling Up’ report (2017) the existing use of hydrogen – and all its many potential new roles – need to be met by decarbonized sources.
• Three hypothetical supply scenarios with decarbonized hydrogen sources are considered in the study: 1) a “green-only” renewables-based world; 2) a “blue-only” world relying on carbon sequestration; and 3) a combined scenario that uses a region-specific combination of green and blue hydrogen based on the expected regional cost development of each source.
• The study finds that a decarbonized hydrogen supply is possible regardless of the production pathway: while both the green and blue boundary scenario would be highly ambitious regarding the required speed of scale-up they do not exceed the world’s resources on either renewable energy or carbon sequestration capabilities.
• A combination of production pathways would result in the least-cost global supply over the entire period of scale-up. It does so by making best use of the near-term cost advantage of “blue” in some regions while simultaneously achieving a scale-up in electrolysis.
• In reality the decarbonized supply scenario will combine a range of different renewable and low-carbon hydrogen production pathways that are optimally suited to local conditions political and societal preferences and regulations as well as industrial and cost developments for different technologies.

You can download the full reports from the Hydrogen Council website

Hydrogen Council Report- Decarbonization Pathways Part 1: Life Cycle Assessment here

Hydrogen Council Report-Decarbonization Pathways Part 2: Supply Scenarios here

An executive summary of the whole project can be found here

Only emissions-free vehicles which include battery electric (BEVs) and hydrogen fuel cell trucks (FCEVs) can provide for a credible long-term pathway towards the full decarbonisation of the road freight sector. This document lays out the methodology and assumptions which were used to calculate the total cost of ownership (TCO) of the two vehicle technologies for regional delivery and long-haul truck applications. It also discusses other criteria such as refuelling and recharging times as well as potential payload losses.

Link to Document Download on Transport & Environment website

The use of clean hydrogen is likely to form a key part of a net-zero emissions future and has the potential to replace natural gas for end use heating. As part of BDR Thermea Group Baxi Heating UK are at the forefront of hydrogen boiler development. Working with the Hy4Heat programme hydrogen fuelled boilers have been produced for inclusion in trial sites across the UK. This presentation will explore progress to date together with the hydrogen-ready boiler concept.