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Numerical Study of the Near-field of Highly Under-expanded Turbulent Gas Jets
Sep 2011
Publication
For safety issues related to the storage of hydrogen under high pressure it is necessary to determine how the gas is released in the case of failure. In particular there exist limited quantitative information on the near-field properties of the gas jets which are important for establishing proper decay laws in the far-field. This paper reports recent CFD results for air and helium obtained in the near-field of the highly under-expanded jets. The gas jets are rele Read More
Generation of Hydrogen and Oxygen from Water by Solar Energy Conversion
Dec 2021
Publication
Photosynthesis is considered to be one of the promising areas of cheap and environmentally friendly energy. Photosynthesis involves the process of water oxidation with the formation of molecular oxygen and hydrogen as byproducts. The aim of the present article is to review the energy (light) phase of photosynthesis based on the published X-ray studies of photosystems I and II (PS-I and PS-II). Using modern ideas about semiconductors and biolo Read More
Experimental Results on The Dispersion of Buoyant Gas in a Full Scale Garage from a Complex Source
Sep 2009
Publication
The lack of experimental data on hydrogen dispersion led to the experimental project DRIVE (Experimental Data for Hydrogen Automotive Risks Assessment for the validation of numerical tools and for the Edition of guidelines) that involves the CEA (French Atomic Energy Commission) the National Institute of Industrial Environment and Risks (INERIS) the French car manufacturer PSA PEUGEOT CITROËN and the Research Institute on Out of Equilibrium P Read More
Accelerated Degradation for Solid Oxide Electrolysers: Analysis and Prediction of Performance for Varying Operating Environments
Jan 2022
Publication
Solid oxide electrolysis cells (SOECs) are an efficient technology for the production of green hydrogen that has great potential to contribute to the energy transition and decarbonization of industry. To date however time- and resource-intensive experimental campaigns slow down the development and market penetration of the technology. In order to speed-up the evaluation of SOEC performance and durability accelerated testing protocols are required. Read More
Hydrogen Production from Biomass and Organic Waste Using Dark Fermentation: An Analysis of Literature Data on the Effect of Operating Parameters on Process Performance
Jan 2022
Publication
In the context of hydrogen production from biomass or organic waste with dark fermentation this study analysed 55 studies (339 experiments) in the literature looking for the effect of operating parameters on the process performance of dark fermentation. The effect of substrate concentration pH temperature and residence time on hydrogen yield productivity and content in the biogas was analysed. In addition a linear regression model was Read More
Experimental Study of Explosion Wave Propagation in Hydrogen-Air Mixtures of Variable Compositions
Sep 2009
Publication
Results are given of experimental study of propagation of explosion waves in hydrogen-air mixtures of different compositions under conditions of cumulation. The investigations are performed in a setup consisting of two parts namely the upper part in the form of a metal cone and the lower part in the form of a rubber envelope hermetically attached to the cone. The upper and lower parts of the experimental setup are separated by a thin rubber film and Read More
Effect of Hydrogen Concentration on Vented Explosion Overpressures from Lean Hydrogen–air Deflagrations
Sep 2011
Publication
Experimental data from vented explosion tests using lean hydrogen–air mixtures with concentrations from 12 to 19% vol. are presented. A 63.7-m3 chamber was used for the tests with a vent size of either 2.7 or 5.4 m2. The tests were focused on the effect of hydrogen concentration ignition location vent size and obstacles on the pressure development of a propagating flame in a vented enclosure. The dependence of the maximum pressure generated on th Read More
Wide Area and Distributed Hydrogen Sensors
Sep 2009
Publication
Recent advances in optical sensors show promise for the development of new wide area monitoring and distributed optical network hydrogen detection systems. Optical hydrogen sensing technologies reviewed here are: 1) open path Raman scattering systems 2) back scattering from chemically treated solid polymer matrix optical fiber sensor cladding; and 3) schlieren and shearing interferometry imaging. Ultrasonic sensors for hydrogen release detec Read More
A Barrier Analysis of a Generic Hydrogen Refuelling Station
Sep 2009
Publication
Any technical installation need appropriate safety barriers installed to prevent or mitigate any adverse effects concerning people property and environment. In this context a safety barrier is a series of elements each consisting of a technical system or human action that implement a planned barrier function to prevent control or mitigate the propagation of a condition or event into an undesired condition or event. This is also important for new technologie Read More
Compatibility and Suitability of Existing Steel Pipelines for Transport of Hydrogen and Hydrogen-natural Gas Blends
Sep 2017
Publication
Hydrogen is being considered as a pathway to decarbonize large energy systems and for utility-scale energy storage. As these applications grow transportation infrastructure that can accommodate large quantities of hydrogen will be needed. Many millions of tons of hydrogen are already consumed annually some of which is transported in dedicated hydrogen pipelines. The materials and operation of these hydrogen pipeline systems however Read More
Numerical Simulation of Hydrogen Release From High-Pressure Storage Vessel
Sep 2009
Publication
In this paper the deflagration region and characteristics of the hydrogen flow which was generated by high-pressure hydrogen discharge from storage vessels were studied. A 3-D analytic model is established based on the species transfer model and the SST k −ω turbulence model. The established model is applied to the research of the flow characteristics of the hydrogen under-expanded jet under different filling pressures of 30 MPa 35 MPa and 40 M Read More
Numerical Study of Hydrogen Explosions in a Vehicle Refill Environment
Sep 2009
Publication
Numerical simulations have been carried out for pressurised hydrogen release through a nozzle in a simulated vehicle refilling environment of an experiment carried out in a joint industry project by Shell bp Exxon and the UK HSE Shirvill[1]. The computational domain mimics the experimental set up for a vertical downwards release in a vehicle refuelling environment. Due to lack of detailed data on pressure decay in the storage cylinder following the releas Read More
Hydrogen Uptake and Embrittlement of Carbon Steels in Various Environments
Aug 2020
Publication
To avoid failures due to hydrogen embrittlement it is important to know the amount of hydrogen absorbed by certain steel grades under service conditions. When a critical hydrogen content is reached the material properties begin to deteriorate. The hydrogen uptake and embrittlement of three different carbon steels (API 5CT L80 Type 1 P110 and 42CrMo4) was investigated in autoclave tests with hydrogen gas (H2) at elevated pressure and in ambient pr Read More
Safe Testing of Catalytic Devices in Hydrogen-Air Flow
Sep 2009
Publication
Any experimental study of catalysts and catalytic recombining devices for removal of hydrogen gas from industrial environments is known to carry a risk of ignition of hydrogen. Experiments conducted in an atmosphere with a high concentration of hydrogen present a particular danger. Here a technique is reported that allows conducting such experiments with relative safety. This technique has been developed and applied by the company ‘Russian E Read More
Enhanced Production of Hydrogen from Methanol Using Spark Discharge Generated in a Small Portable Reactor
Nov 2021
Publication
An efficient production of hydrogen from a mixture of methanol and water is possible in a spark discharge. In this discharge there is a synergistic effect of high-energy electrons and high temperature interactions which enables an efficient course of endothermic processes such as the production of hydrogen from methanol. The water to methanol molar ratio of 1:1 was kept constant during the study. While the discharge power and feed flow rate were Read More
Safe Operation of Natural Gas Appliances Fuelled with Hydrogen & Natural Gas Mixtures (Progress Obtained in the Naturalhy-Project)
Sep 2007
Publication
Considering the transition towards the hydrogen economy dependent on hydrogen penetration scenario the cost of a new hydrogen pipeline infrastructure in Europe may amount to several thousands of billions of EURO’s. Therefore the examination of the potential contribution of the existing natural gas assets is a practical and logical first step. As the physical and chemical properties of hydrogen differ significantly from those of natural gas it is not at all possi Read More
Dynamics of Vented Hydrogen-air Deflagrations
Sep 2011
Publication
The use of hydrogen as an energy carrier is a real perspective for Europe since a number of breakthroughs now enable to envision a deployment at the industrial scale. However some safety issues need to be further addressed but experimental data are still lacking especially about the explosion dynamics in realistic dimensions. A set of hydrogen-air vented explosions were thus performed in two medium scale chambers (1 m3 and 10 m3). Homogeneo Read More
Improvements in Two-Step Model of Hydrogen Detonative Combustion: Model Description and Sensitivity to its Parameters
Sep 2009
Publication
In the present paper the two-stage model of detonative combustion of hydrogen is presented. The following improvements are described: accurate description of the heat release stage of combustion; the clear physics-based procedure for calculation of the parameters of the proposed model; sample calculations of the detonation wave in hydrogen/air mixtures in wide range of conditions showing that the proposed model performs well in a wide Read More
Numerical Simulations of a Large Hydrogen Release in a Process Plant
Sep 2009
Publication
This paper describes a series of numerical simulations with release and ignition of hydrogen. The objective of this work was to re-investigate the accidental explosion in an ammonia plant which happened in Norway in 1985 with modern CFD tools. The severe hydrogen-air explosion led to two fatalities and complete destruction of the factory building where the explosion occurred. A case history of the accident was presented at the 1.st ICHS in Pisa 20 Read More
Hydrogen-Air Explosive Envelope Behaviour in Confined Space at Different Leak Velocities
Sep 2009
Publication
The report summarizes experimental results on the mechanisms and kinetics of hydrogen-air flammable gas cloud formation and evolution due to foreseeable (less than 10-3 kg/sec) hydrogen leaks into confined spaces with different shapes sizes and boundary conditions. The goals were - 1) to obtain qualitative information on the basic gas-dynamic patterns of flammable cloud formation at different leak velocities (between 935 and 905 m/sec) f Read More
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