Publications

A new spinelized Ni catalyst (Ni-UGSO) using Ni(NO₃)₂·6H₂O as the Ni precursor was prepared according to a less material intensive protocol. The support of this catalyst is a negative-value mining residue UpGraded Slag Oxide (UGSO) produced from a TiO2 slag production unit. Applied to dry reforming of methane (DRM) at atmospheric pressure T = 810 °C space velocity of 3400 mL/(h·g) and molar CO₂/CH₄ = 1.2 Ni-UGSO gives a stable over 168 h time-on-stream methane conversion of 92%. In this DRM reaction optimization study: (1) the best performance is obtained with the 10–13 wt% Ni load; (2) the Ni-UGSO catalysts obtained from two different batches of UGSO demonstrated equivalent performances despite their slight differences in composition; (3) the sulfur-poisoning resistance study shows that at up to 5.5 ppm no Ni-UGSO deactivation is observed. In steam reforming of methane (SRM) Ni-UGSO was tested at 900 °C and a molar ratio of H₂O/CH₄ = 1.7. In this experimental range CH4 conversion rapidly reached 98% and remained stable over 168 h time-on-stream (TOS). The same stability is observed for H₂ and CO yields at around 92% and 91% respectively while H₂/CO was close to 3. In mixed (dry and steam) methane reforming using a ratio of H₂O/CH₄ = 0.15 and CO2/CH4 = 0.97 for 74 h and three reaction temperature levels (828 °C 847 °C and 896 °C) CH₄ conversion remains stable; 80% at 828 °C (26 h) 85% at 847 °C (24 h) and 95% at 896 °C (24 h). All gaseous streams have been analyzed by gas chromatography. Both fresh and used catalysts are analyzed by scanning electron microscopy-electron dispersive X-ray spectroscopy (SEM-EDXS) X-ray diffraction (XRD) and thermogravimetric analysis (TGA) coupled with mass spectroscopy (MS) and BET Specific surface. In the reducing environment of reforming such catalytic activity is mainly attributed to (a) alloys such as FeNi FeNi3 and Fe3Ni2 (reduction of NiFe2O4 FeNiAlO4) and (b) to the solid solution NiO-MgO. The latter is characterized by a molecular distribution of the catalytically active Ni phase while offering an environment that prevents C deposition due to its alkalinity.

It is now well established that electrochemical systems can optimally perform only within a narrow range of temperature. Exposure to temperatures outside this range adversely affects the performance and lifetime of these systems. As a result thermal management is an essential consideration during the design and operation of electrochemical equipment and can heavily influence the success of electrochemical energy technologies. Recently significant attempts have been placed on the maturity of cooling technologies for electrochemical devices. Nonetheless the existing reviews on the subject have been primarily focused on battery cooling. Conversely heat transfer in other electrochemical systems commonly used for energy conversion and storage has not been subjected to critical reviews. To address this issue the current study gives an overview of the progress and challenges on the thermal management of different electrochemical energy devices including fuel cells electrolysers and supercapacitors. The physicochemical mechanisms of heat generation in these electrochemical devices are discussed in-depth. Physics of the heat transfer techniques currently employed for temperature control are then exposed and some directions for future studies are provided.

The decarbonization of the industrial sector is imperative to achieve a sustainable future. Carbon capture and storage technologies are the leading options but lately the use of CO2 is also being considered as a very attractive alternative that approaches a circular economy. In this regard power to gas is a promising option to take advantage of renewable H2 by converting it together with the captured CO2 into renewable gases in particular renewable methane. As renewable energy production or the mismatch between renewable production and consumption is not constant it is essential to store renewable H2 or CO2 to properly run a methanation installation and produce renewable gas. This work analyses and optimizes the system layout and storage pressure and presents an annual cost (including CAPEX and OPEX) minimization. Results show the proper compression stages need to achieve the storage pressure that minimizes the system cost. This pressure is just below the supercritical pressure for CO2 and at lower pressures for H2 around 67 bar. This last quantity is in agreement with the usual pressures to store and distribute natural gas. Moreover the H2 storage costs are higher than that of CO2 even with lower mass quantities; this is due to the lower H2 density compared with CO2 . Finally it is concluded that the compressor costs are the most relevant costs for CO2 compression but the storage tank costs are the most relevant in the case of H2.

The present work performed within the PRESLHY EC-project presents a simplified 1-d transient modelling methodology to account for discharge line effects during blowdown. The current formulation includes friction extra resistance area change and heat transfer through the discharge line walls and is able to calculate the mass flow rate and distribution of all physical variables along the discharge line. Choked flow at any time during the transient is calculated using the Possible Impossible Flow (PIF) algorithm. Hydrogen single phase physical properties and vapour-liquid equilibrium are calculated using the Helmholtz Free Energy (HFE) formulation. Homogeneous Equilibrium Mixture (HEM) model is used for two-phase physical properties. Validation is performed against the new experiments with compressed gaseous hydrogen performed at the DISCHA facility in the framework of PRESLHY (200 bar ambient and cryogenic initial tank temperature 77 K and 4 nozzle diameters 0.5 1 2 and 4 mm) and an older experiment at 900 bar ambient temperature and 2 mm nozzle. Predictions are compared against measured data from the experiments and the relative importance of line heat transfer compared to flow resistance is analysed.

Heating and hot water within buildings account for almost a quarter of global energy consumption. Approximately 90% of this heat is derived directly from the combustion of fossil fuels primarily natural gas leading to the unabated emission of carbon dioxide. This paper assesses the environmental sustainability of a range of heating technologies and scenarios on a life cycle basis. The major technologies considered are natural gas boilers air source heat pumps hydrogen boilers and direct electric heaters. The scenarios use the UK as an example due to its status as a major economy with a legally-binding net-zero carbon target for 2050; they consider plausible future electricity and natural gas mixes including the potential growth of domestic shale gas. The environmental impacts are estimated using ReCiPe 2016. Current gas boilers have a climate change impact of 220 g CO₂ eq./kWh of heat which could fall to 64 g CO₂ eq./kWh for boilers fuelled by hydrogen derived from natural gas with carbon capture. Heat from electric air source heat pumps or hydrogen from electrolysis can achieve net zero with a decarbonised electricity mix but electrolysis has the highest energy demand of all options which leads to the highest impacts across 17 of the 19 categories. Despite their high carbon emissions gas boilers remain the lowest impact option across 12 categories as they avoid the impacts related to electricity generation including metal depletion toxicities and eutrophication. By 2050 the best performing scenario sees the climate change impact of the heating mix fall by 95%; this is achieved by prioritising electric air source heat pumps without hydrofluorocarbon refrigerants alongside demand reduction. The results show that if infrastructure and financial challenges can be overcome there are several viable decarbonisation strategies for heating with heat pumps offering the most environmentally sustainable option of those considered here. However increased renewable electricity demand may worsen some environmental impacts compared to natural gas boilers.

Hydrogen is currently enjoying a renewed and widespread momentum in many national and international climate strategies. This review paper is focused on analysing the challenges and opportunities that are related to green and blue hydrogen which are at the basis of different perspectives of a potential hydrogen society. While many governments and private companies are putting significant resources on the development of hydrogen technologies there still remains a high number of unsolved issues including technical challenges economic and geopolitical implications. The hydrogen supply chain includes a large number of steps resulting in additional energy losses and while much focus is put on hydrogen generation costs its transport and storage should not be neglected. A low-carbon hydrogen economy offers promising opportunities not only to fight climate change but also to enhance energy security and develop local industries in many countries. However to face the huge challenges of a transition towards a zero-carbon energy system all available technologies should be allowed to contribute based on measurable indicators which require a strong international consensus based on transparent standards and targets.

Investigating metal-ion solvation—in particular the fundamental binding interactions—enhances the understanding of many processes including hydrogen production via catalysis at metal centers and metal corrosion. Infrared spectra of the hydrated zinc dimer (Zn₂+(H₂O)n; n = 1–20) were measured in the O–H stretching region using infrared multiple photon dissociation (IRMPD) spectroscopy. These spectra were then compared with those calculated by using density functional theory. For all cluster sizes calculated structures adopting asymmetric solvation to one Zn atom in the dimer were found to lie lower in energy than structures adopting symmetric solvation to both Zn atoms. Combining experiment and theory the spectra show that water molecules preferentially bind to one Zn atom adopting water binding motifs similar to the Zn+(H₂O)n complexes studied previously. A lower coordination number of 2 was observed for Zn2+(H₂O)3 evident from the highly red-shifted band in the hydrogen bonding region. Photodissociation leading to loss of a neutral Zn atom was observed only for n = 3 attributed to a particularly low calculated Zn binding energy for this cluster size.

Electrochemical cells and systems play a key role in a wide range of industry sectors. These devices are critical enabling technologies for renewable energy; energy management conservation and storage; pollution control/monitoring; and greenhouse gas reduction. A large number of electrochemical energy technologies have been developed in the past. These systems continue to be optimized in terms of cost life time and performance leading to their continued expansion into existing and emerging market sectors. The more established technologies such as deep-cycle batteries and sensors are being joined by emerging technologies such as fuel cells large format lithium-ion batteries electrochemical reactors; ion transport membranes and supercapacitors. This growing demand (multi-billion dollars) for electrochemical energy systems along with the increasing maturity of a number of technologies is having a significant effect on the global research and development effort which is increasing in both in size and depth. A number of new technologies which will have substantial impact on the environment and the way we produce and utilize energy are under development. This paper presents an overview of several emerging electrochemical energy technologies along with a discussion some of the key technical challenges.

This paper proposes a novel hybrid marine renewable energy-harvesting system to increase energy production reduce levelized costs of energy and promote renewable marine energy. Firstly various marine renewable energy resources and state-of-art technologies for energy exploitation and storage were reviewed. The site selection criteria for each energy-harvesting approach were identified and a scoring matrix for site selection was proposed to screen suitable locations for the hybrid system. The Triton Knoll wind farm was used to demonstrate the effectiveness of the scoring matrix. An integrated energy system was designed and FE modeling was performed to assess the effects of additional energy devices on the structural stability of the main wind turbine structure. It has been proven that the additional energy structures have a negligible influence on foundation/structure deflection.

This study investigates and controls the optimal operating oxygen excess ratio (OER) for PEMFC which effectively prevents oxygen starvation and improves the hydrogen economy of proton exchange membrane fuel cells (PEMFC). Firstly the PEMFC output characteristic model and the five-order nonlinear air supply system model are established. Moreover an adaptive algebraic observer was developed to observe the partial pressure of gas in PEMFC and further reconstruct OER. Secondly to achieve the minimum hydrogen consumption under the required power the reference OER is determined by analyzing the PEMFC system output power with its minimum current. Finally the super-twisting algorithm is adopted to track reference OER. Simulation results show that the average absolute observation errors of oxygen nitrogen and cathode pressures under the Highway Fuel Economy Test are 1351.1 Pa (5.1%) 1724.2 Pa (0.9%) and 409.9 Pa (1.6%) respectively. The OER adjust average absolute error is 0.03. Compared with the commonly used fixed OER (e.g. OER of 1.5 and 2.3) the optimal OER strategy can reduce the hydrogen consumption of the PEMFC system by 5.2% and 1.8% respectively. Besides a DSP hardware in loop test is conducted to show the real-time performance of the proposed optimal method.