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Ignition and Flow Stopping Considerations for the Transmission of Hydrogen in the Existing Natural Gas Network
Sep 2023
Publication
This work formed part of the H21 programme whose objective is to reach the point whereby it is feasible to convert the existing natural gas (NG) distribution network to 100% hydrogen (H2) and provide a contribution to decarbonising the UK’s heat and power sectors with the focus on decarbonised fuel at point of use. Hydrogen has an ATEX Gas Group of IIC compared to IIA for natural gas which means further precautions are necessary to prevent the ignition of hydrogen during network operations. Both electrostatic and friction ignition risks were considered. Network operations considered include electrostatic precautions for polyethylene (PE) pipe and cutting and drilling of metallic pipes. As a result of the updated basis of safety from ignition considerations existing flow stopping methods were reviewed to see if they were compatible. Commonly used flow stopping methods were tested under laboratory conditions with hydrogen following the methodologies specified in the Gas Industry Standards (GIS). A new basis of safety for flow stopping has been proposed that looks at the flow past the secondary stop as double isolations are recommended for use with hydrogen.
An Overview of Low-carbon Hydrogen Production via Water Splitting Driven by Piezoelectric and Pyroelectric Catalysis
Jun 2024
Publication
The focus on sustainable energy sources is intensifying as they present a viable alternative to conventional fossil fuels. The emergence of clean and renewable hydrogen fuel marks a significant technological shift toward decarbonizing the environment. Harnessing mechanical and thermal energy through piezoelectric and pyroelectric catalysis has emerged as an effective strategy for producing hydrogen and contributing to reducing dependence on carbon-based fuels. In this regard this review presents recent advances in piezoelectric and pyroelectric catalysis induced by mechanical and thermal excitations respectively towards hydrogen generation via the water splitting process. A thorough description of the fundamental principles underlying the piezoelectric and pyroelectric effects is provided complemented by an analysis of the catalytic processes induced by these effects. Subsequently these effects are examined to propose the prerequisites needed for such catalysts to achieve water splitting reaction and hydrogen generation. Special attention is devoted to identifying the various strategies adopted to enhance hydrogen production in order to provide new paths for increased efficiency.
A Physics Constrained Methodology for the Life Cycle Assessment of Sustainable Aviation Fuel Production
May 2024
Publication
Feedstock-to-fuel conversion or “Fuel Production” is a major contributor to greenhouse gas (GHG) emissions in life cycle assessment (LCA) of sustainable aviation fuels (SAF) from wastes. Here we construct and demonstrate an original mass and energy conserved chemically rigorous LCA methodology for the production of Hydroprocessed Esters and Fatty Acids-Synthetic Paraffinic Kerosene (HEFA-SPK) from Used Cooking Oil (UCO). This study proposes and demonstrates the use of; (i) the chemical composition of the UCO (ii) the ASTM properties of HEFA-SPK and (iii) the elemental mass and energy conserved reaction mechanism which converts one to the other as physical constraints for the specific LCA of any UCO derived HEFA-SPK. With application of these constraints the emissions embodied in UCO HEFA-SPK Fuel Production is found to range from 4.2 to 15.7 gCO2e/MJSAF depending on the renewability of the energy and hydrogen utilized. Imposition of (i)-(iii) as modelling constraints derives a HEFA-SPK yield of 49 mass% a priori. This finding aligns with experimental literature but brings attention to the higher yield estimations of 70–81% observed in current LCA tools. We show that this impacts the end LCA significantly as it adjusts allocation of emissions. A replication study of CORSIA’s (10.5 gCO2e/MJSAF) default core LCA value for Fuel Production quantifies the increase at +5.3 gCO2e/MJSAF or 15.8 gCO2e/MJSAF as total for Fuel Production. As the embodied emissions are significantly dependent on the specifics of the scenario assessed we highlight reporting a definitive GHG intensity for any UCO derived HEFA-SPK as generic will be inaccurate to an extent.
An Estimation of Green Hydrogen Generation from Wind Energy: A Case Study from KSA
Sep 2023
Publication
Actually green hydrogen is viewed as a fundamental component in accelerating energy transition and empowering a sustainable future. The current study focuses on the estimation of green hydrogen generation by using wind energy via electrolysis in four sites located in Saudi Arabia. Results showed that the yearly amount of hydrogen that could be generated by using wind turbine ranges between 2542877 kg in Rafha and 3676925 kg in Dhahran. The hydrogen generated could be used to fuel vehicles and decrease the amount of GHG emission from vehicles in KSA. Also hydrogen may be used to store the excess of wind energy and to support the achievement of vision 2030 of the Kingdom. An economic assessment is carried out also in this paper. Results showed that the LCOH by using wind energy in KSA ranges from 2.82 $/kg to 3.81 $/kg.
Explaining Varying Speeds of Low-carbon Reorientation in the United Kingdom's Steel, Petrochemical, and Oil Refining Industries: A Multi-dimensional Comparative Analysis and Outlook
Feb 2024
Publication
Accelerated decarbonisation of steelmaking oil refining and petrochemical industries is essential for climate change mitigation. Drawing on three longitudinal case studies of these industries in the UK this synthesis article makes a comparative analysis of their varying low-carbon reorientation speeds. The paper uses the triple embeddedness framework to analyse five factors (policy support international competition financial health technical feasibility corporate strategy and mindset) that explain why UK oil refineries have in recent years been comparatively the fastest in their low-carbon reorientation and UK steelmakers the slowest. We find that policy support has been more beneficial for refining and petrochemicals than for steel although recent government deals with steelmakers addressed this imbalance. International competition has been high for steel and petrochemicals and comparatively lower for refining (meaning that decarbonisation costs are less detrimental for international competitiveness). Financial performance has comparatively been worst for steel and best for oil refining which shapes the economic feasibility of low-carbon options. Hydrogen and carbon-capture-and-storage are technologically feasible for refining and petrochemicals while Electric Arc Furnaces are technically feasible for steelmakers but face wider feasibility problems (with scrap steel supply electricity grids and electricity prices) which is why we question the recent government deals. Corporate strategy and perceptions changed in oil refining with firms seeing economic opportunities in decarbonisation while steelmakers and petrochemical firms still mostly see decarbonisation as a burden and threat. The paper ends with comparative conclusions a discussion of political considerations and future outlooks for the three UK industries policy and research.
Optimizing Underground Hydrogen Storage in Aquifers: The Impact of Cushion Gas Type
Aug 2023
Publication
This study investigated the impact of cushion gas type and presence on the performance of underground hydrogen storage (UHS) in an offshore North Sea aquifer. Using numerical simulation the relationship between cushion gas type and UHS performance was comprehensively evaluated providing valuable insights for designing an efficient UHS project delivery. Results indicated that cushion gas type can significantly impact the process's recovery efficiency and hydrogen purity. CO2 was found to have the highest storage capacity while lighter gases like N2 and CH4 exhibited better recovery efficiency. Utilising CH4 as a cushion gas can lead to a higher recovery efficiency of 80%. It was also determined that utilising either of these cushion gases was always more beneficial than hydrogen storage alone leading to an incremental hydrogen recovery up to 7%. Additionally hydrogen purity degraded as each cycle progressed but improved over time. This study contributes to a better understanding of factors affecting UHS performance and can inform the selection of cushion gas type and optimal operational strategies.
Numerical Simulations of the Critical Diameter and Flame Stability for the Hydrogen Jet Flames
Sep 2023
Publication
This study focuses on development of a CFD model able to simulate the experimentally observed critical nozzle diameter for hydrogen non-premixed flames. The critical diameter represents the minimum nozzle size through which a free jet flame will remain stable at all driving pressures. Hydrogen non-premixed flames will not blow-out at diameters equal to or greater than the critical diameter. Accurate simulation of this parameter is important for assessment of thermally activated pressure relief device (TPRD) performance during hydrogen blowdown from a storage tank. At TPRD diameters below the critical value there is potential for a hydrogen jet flame to blow-out as the storage tank vents potentially leading to hydrogen accumulation in an indoor release scenario. Previous experimental studies have indicated that the critical diameter for hydrogen is approximately 1 mm. In this study flame stability is considered across a range of diameters and overpressures from 0.1 mm to 2 mm and from 0.2 MPa to 20 MPa respectively. The impact of turbulent Schmidt number Sct which is the ratio of momentum diffusivity (kinematic viscosity) and mass diffusivity on the hydrogen concentration profile in the region near the nozzle exit and subsequent influence on critical diameter was investigated and discussed. For lower Sct values the enhanced mass mixing resulted in smaller predicted critical diameters. The use of value Sct=0.61 in the model demonstrated the best agreement with experimental values of the critical diameter. The model reproduced the critical diameter of 1 mm and then was applied to predict flame stability for under-expanded hydrogen jets.
Energy Use and Greenhouse Gas Emissions of Traction Alternatives for Regional Railways
Feb 2024
Publication
This paper presents a method for estimating Well-to-Wheel (WTW) energy use and greenhouse gas (GHG) emissions attributed to the advanced railway propulsion systems implemented in conjunction with different energy carriers and their production pathways. The analysis encompasses diesel-electric multiple unit vehicles converted to their hybrid-electric plug-in hybrid-electric fuel cell hybrid-electric or battery-electric counterparts combined with biodiesel or hydrotreated vegetable oil (HVO) as the first and second generation biofuels liquefied natural gas (LNG) hydrogen and/or electricity. The method is demonstrated using non-electrified regional railway network with heterogeneous vehicle fleet in the Netherlands as a case. Battery-electric system utilizing green electricity is identified as the only configuration leading to emission-free transport while offering the highest energy use reduction by 65–71% compared to the current diesel-powered hybrid-electric system. When using grey electricity based on the EU2030 production mix these savings are reduced to about 27–39% in WTW energy use and around 68–73% in WTW GHG emissions. Significant reductions in overall energy use and emissions are obtained for the plug-in hybrid-electric concept when combining diesel LNG or waste cooking oil-based HVO with electricity. The remaining configurations that reduce energy use and GHG emissions are hybrid-electric systems running on LNG or HVO from waste cooking oil. The latter led to approximately 88% lower WTW emissions than the baseline for each vehicle type. When produced from natural gas or EU2030-mix-based electrolysis hydrogen negatively affected both aspects irrespective of the prime mover technology. However when produced via green electricity it offers a GHG reduction of approximately 90% for hybrid-electric and fuel cell hybrid-electric configurations with a further reduction of up to 92–93% if combined with green electricity in plug-in hybrid-electric systems. The results indicate that HVO from waste cooking oil could be an effective and instantly implementable transition solution towards carbon–neutral regional trains allowing for a smooth transition and development of supporting infrastructure required for more energy-efficient and environment-friendly technologies.
Research of the Impact of Hydrogen Metallurgy Technology on the Reduction of the Chinese Steel Industry’s Carbon Dioxide Emissions
Feb 2024
Publication
The steel industry which relies heavily on primary energy is one of the industries with the highest CO2 emissions in China. It is urgent for the industry to identify ways to embark on the path to “green steel”. Hydrogen metallurgy technology uses hydrogen as a reducing agent and its use is an important way to reduce CO2 emissions from long-term steelmaking and ensure the green and sustainable development of the steel industry. Previous research has demonstrated the feasibility and emission reduction effects of hydrogen metallurgy technology; however further research is needed to dynamically analyze the overall impact of the large-scale development of hydrogen metallurgy technology on future CO2 emissions from the steel industry. This article selects the integrated MARKAL-EFOM system (TIMES) model as its analysis model constructs a China steel industry hydrogen metallurgy model (TIMES-CSHM) and analyzes the resulting impact of hydrogen metallurgy technology on CO2 emissions. The results indicate that in the business-as-usual scenario (BAU scenario) applying hydrogen metallurgy technology in the period from 2020 to 2050 is expected to reduce emissions by 203 million tons and make an average 39.85% contribution to reducing the steel industry’s CO2 emissions. In the carbon emission reduction scenario applying hydrogen metallurgy technology in the period from 2020 to 2050 is expected to reduce emissions by 353 million tons contributing an average of 41.32% to steel industry CO2 reduction. This study provides an assessment of how hydrogen metallurgy can reduce CO2 emissions in the steel industry and also provides a reference for the development of hydrogen metallurgy technology.
Advances in Hydrogen-Powered Trains: A Brief Report
Sep 2023
Publication
The majority of rail vehicles worldwide use diesel as a primary fuel source. Diesel engine carbon emissions harm the environment and human health. Although railway electrification can reduce emissions it is not always the most economical option especially on routes with low vehicle demand. As a result interest in hydrogen-powered trains as a way to reduce greenhouse gas (GHG) emissions has steadily grown in recent years. In this paper we discuss advancements made in hydrogen-powered freight and commuter trains as well as the technology used in some aspects of hydrogen-powered vehicles. It was observed that hydrogen-powered trains are already in use in Europe and Asia unlike most developing countries in Africa. Commuter trains have received most of the research and development (R&D) attention but interest in hydrogen-powered freight trains has recently picked up momentum. Despite the availability and use of gray and blue hydrogen green hydrogen is still the preferred fuel for decarbonizing the rail transport sector.
Italian Offshore Platform and Depleted Reservoir Conversion in the Energy Transition Perspective
Aug 2023
Publication
New hypotheses for reusing platforms reaching their end-of-life have been investigated in several works discussing the potential conversions of these infrastructures from recreational tourism to fish farming. In this perspective paper we discuss the conversion options that could be of interest in the context of the current energy transition with reference to the off-shore Italian scenario. The study was developed in support of the development of a national strategy aimed at favoring a circular economy and the reuse of existing infrastructure for the implementation of the energy transition. Thus the investigated options include the onboard production of renewable energy hydrogen production from seawater through electrolyzers CO2 capture and valorization and platform reuse for underground fluid storage in depleted reservoirs once produced through platforms. Case histories are developed with reference to a typical fictitious platform in the Adriatic Sea Italy to provide an engineering-based approach to these different conversion options. The coupling of the platform with the underground storage to set the optimal operational conditions is managed through the forecast of the reservoir performance with advanced numerical models able to simulate the complexity of the phenomena occurring in the presence of coupled hydrodynamic geomechanical geochemical thermal and biological processes. The results of our study are very encouraging because they reveal that no technical environmental or safety issues prevent the conversion of offshore platforms into valuable infrastructure contributing to achieving the energy transition targets as long as the selection of the conversion option to deploy is designed taking into account the system specificity and including the depleted reservoir to which it is connected when relevant. Socio-economic issues were not investigated as they were out of the scope of the project.
Green Hydrogen Integration in Aluminium Recycling: Techno-economic Analysis Towards Sustainability Transition in the Expanding Aluminium Market
Feb 2024
Publication
The use of aluminum-based products is widespread and growing particularly in industries such as automotive food packaging and construction. Obtaining aluminum is expensive and energy-intensive making the recycling of existing products essential for economic and environmental viability. This work explores the potential of using green hydrogen as a replacement for natural gas in the smelting and refining furnaces in aluminum recycling facilities. The adoption of green hydrogen has the potential to curtail approximately 4.54 Ktons/year of CO2 emissions rendering it a sustainable and economically advantageous solution. The work evaluates the economic viability of a case study through assessing the Net Present Value (NPV) and the Internal Rate of Return (IRR). Furthermore it is employed single- and multi-parameter sensitivity analyses to obtain insight on the most relevant conditions to achieve economic viability. Results demonstrate that integrating on-site green hydrogen generation yields a favorable NPV of €57370 an IRR of 9.83% and a 19.63-year payback period. The primary factors influencing NPV are the initial electricity consumption stack and the H2 price.
Towards a Future Hydrogen Supply Chain: A Review of Technologies and Challenges
Feb 2024
Publication
The overuse of fossil fuels has caused a serious energy crisis and environmental pollution. Due to these challenges the search for alternative energy sources that can replace fossil fuels is necessary. Hydrogen is a widely acknowledged future energy carrier because of its nonpolluting properties and high energy density. To realize a hydrogen economy in the future it is essential to construct a comprehensive hydrogen supply chain that can make hydrogen a key energy carrier. This paper reviews the various technologies involved in the hydrogen supply chain encompassing hydrogen production storage transportation and utilization technologies. Then the challenges of constructing a hydrogen supply chain are discussed from techno-economic social and policy perspectives and prospects for the future development of a hydrogen supply chain are presented in light of these challenges.
The Use of Hydrogen as Alternative Fuel for Ship Propulsion: A Case Study of Full and Partial Retrofitting of Roll-on/Roll-off Vessels for Short Distance Routes
Oct 2023
Publication
Roll-on/Roll-Off (Ro-Ro) vessels including those without and with passenger accommodation Roll-on/roll-off passenger (Ro-Pax) can be totally or partially retrofitted to reduce the greenhouse gas (GHG) emissions in maritime transport not only during hoteling operation at the dock but also during service. This study is based on data of the vessel routes connecting the Port of Piombino to the Elba Island in Italy. Three retrofitting scenarios have been considered: replacement of the main and auxiliary engines with fuel cells (FC) (full retrofitting) replacement of the auxiliary engines with FCs (partial retrofitting) and replacement of the auxiliary engines with FCs and hoteling only with auxiliary engines for one specific vessel. The amount of hydrogen the filling time and the energy needed for production compression and pre-cooling of hydrogen have been calculated for the different scenarios.
Sudden Releases of Hydrogen into a Tunnel
Sep 2023
Publication
This paper presents work undertaken by the HSE as part of the Hytunnel-CS project a consortium investigating safety considerations for fuel cell hydrogen (FCH) vehicles in tunnels and similar confined spaces. The sudden failure of a pressurised hydrogen vessel was identified as a scenario of concern due to the severity of the consequences associated with such an event. In order to investigate this scenario experimentally HSE designed a bespoke and reusable ‘sudden release’ vessel. This paper presents an overview of the vessel and the results of a series of 13 tests whereby hydrogen was released from the bespoke vessel into a tunnel at pressures up to 65 MPa. The starting pressure and the volume of hydrogen in the vessel were altered throughout the campaign. Four of the tests also included congestion in the tunnel. The tests reliably autoignited. Overpressure measurements and flame arrival times measured with exposed-tip thermocouples enabled analysis of the severity of the events. A high-pressure fast-acting pressure transducer in the body of the vessel showed the pressure decay in the vessel which shows that 90% of the hydrogen was evacuated in between 1.8 and 3.2 ms (depending on the hydrogen inventory). Schlieren flow imagery was also used at the release point of the hydrogen showing the progression of the shock front following initiation of the tests. An assessment of the footage shows an estimated initial velocity of Mach 3.9 at 0.4 m from the release point. Based on this an ignition mechanism is proposed based upon the temperature behind the initial shock front.
H2-powered Aviation - Design and Economics of Green LH2 Supply for Airports
Aug 2023
Publication
The economic competitiveness of hydrogen-powered aviation highly depends on the supply costs of green liquid hydrogen to enable true-zero CO2 flying. This study uses non-linear energy system optimization to analyze three main liquid hydrogen (LH2) supply pathways for five locations. Final liquid hydrogen costs at the dispenser supply costs could reach 2.04 USD/kgLH2 in a 2050 base case scenario for locations with strong renewable energy source conditions. This could lead to cost-competitive flying with hydrogen. Reflecting techno-economic uncertainties in two additional scenarios the liquid hydrogen cost span at all five airport locations ranges between 1.37–3.48 USD/kgLH2 if hydrogen import options from larger hydrogen markets are also available. Import setups are of special importance for airports with a weaker renewable energy source situation e.g. selected Central European airports. There on-site supply might not only be too expensive but space requirements for renewable energy sources could be too large for feasible implementation in densely populated regions. Furthermore main costs for liquid hydrogen are caused by renewable energy sources electrolysis systems and liquefaction plants. Seven detailed design rules are derived for optimized energy systems for these and the storage components. This and the cost results should help infrastructure planners and general industry and policy players prioritize research and development needs
Hydrogen Fuel Cell Electric Trains: Technologies, Current Status, and Future
Feb 2024
Publication
Trains have been a crucial part of modern transport and their high energy efficiency and low greenhouse gas emissions make them ideal candidates for the future transport system. Transitioning from diesel trains to hydrogen fuel cell electric trains is a promising way to decarbonize rail transport. That’s because the fuel cell electric trains have several advantages over other electric trains such as lower life-cycle emissions and shorter refueling time than battery ones and less requirements for wayside infrastructure than the ones with overhead electric wires. However hydrogen fuel technology still needs to be advanced in areas including hydrogen production storage refueling and on-board energy management. Currently there are several pilot projects of hydrogen fuel cell electric trains across the globe especially in developed countries including one commercialized and permanent route in Germany. The experiences from the pilot projects will promote the technological and economic feasibility of hydrogen fuel in rail transport.
Advancing a Hydrogen Economy in Australia: Public Perceptions and Aspirations
Nov 2023
Publication
Supporters of hydrogen energy urge scaling up technology and reducing costs for competitiveness. This paper explores how hydrogen energy technologies (HET) are perceived by Australia’s general population and considers the way members of the public imagine their role in the implementation of hydrogen energy now and into the future. The study combines a nationally representative survey (n = 403) and semi-structured interviews (n = 30). Results show age and gender relationships with self-reported hydrogen knowledge. Half of the participants obtained hydrogen information from televised media. Strong support was observed for renewable hydrogen while coal (26%) and natural gas (41%) versions had less backing. Participants sought more safety-related information (41% expressed concern). Most felt uncertain about influencing hydrogen decisions and did not necessarily recognise they had agency beyond their front fence. Exploring the link between political identity and agency in energy decision-making is needed with energy democracy a potentially productive direction.
Grid-neutral Hydrogen Mobility: Dynamic Modelling and Techno-economic Assessment of a Renewable-powered Hydrogen Plant
Jun 2024
Publication
The seasonally varying potential to produce electricity from renewable sources such as wind PV and hydropower is a challenge for the continuous supply of hydrogen for transport and mobility. Seasonal storage of energy allows to avoid the use of grid electricity when it is scarce; storage systems can thus increase the resilience of the energy system. For grid-neutral and renewable hydrogen production an electrolyser is considered together with a Power-to-Gas seasonal storage system which consists of a methanation the gas grid as intermediate storage and a steam reformer. As feed stream electricity from an own photovoltaic (PV) system is considered and for some cases additional electricity from the grid or from a wind turbine. The dynamic operation of the plant during a year is simulated. It is possible to safely supply fuel cell vehicles with hydrogen from the grid-neutral plant without using electricity when it is scarce and expensive. To supply 135 kgH2/day unit sizes of 1 MW–2.9 MW for the PV system and 0.9 MW–2.6 MW for the electrolysis are required depending on the amount of available grid-electricity. The usage of grid-electricity increases the capacity factor of the electrolysis which results in decreased unit sizes and in a better economic performance. Seasonal storage of energy is required which results in an increased hydrogen production in summer of approximately 50% more than directly needed by the fuel cell vehicles. The overall efficiency from electricity to hydrogen is decreased due to the storage path by 10%-points to 56% based on the higher heating value. Assuming a cost-equivalent hydrogen price per driven kilometre in comparison to the actual diesel price and electricity costs of 10 Ct/kWhel from the grid the revenues of the system are higher than the operating costs.
Comparison of Battery Electric Vehicles and Fuel Cell Vehicles
Sep 2023
Publication
In the current context of the ban on fossil fuel vehicles (diesel and petrol) adopted by several European cities the question arises of the development of the infrastructure for the distribution of alternative energies namely hydrogen (for fuel cell electric vehicles) and electricity (for battery electric vehicles). First we compare the main advantages/constraints of the two alternative propulsion modes for the user. The main advantages of hydrogen vehicles are autonomy and fast recharging. The main advantages of battery-powered vehicles are the lower price and the wide availability of the electricity grid. We then review the existing studies on the deployment of new hydrogen distribution networks and compare the deployment costs of hydrogen and electricity distribution networks. Finally we conclude with some personal conclusions on the benefits of developing both modes and ideas for future studies on the subject.
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