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Optimized EMS and a Comparative Study of Hybrid Hydrogen Fuel Cell/Battery Vehicles
Jan 2022
Publication
This paper presents a new Fuel Cell Fuel Consumption Minimization Strategy (FCFCMS) for Hybrid Electric Vehicles (HEVs) powered by a fuel cell and an energy storage system in order to minimize as much as possible the consumption of hydrogen while maintaining the State Of Charge (SOC) of the battery. Compared to existing Energy Management Strategies (EMSs) (such as the well-known State Machine Strategy (SMC) Fuzzy Logic Control (FLC) Frequency Decoupling and FLC (FDFLC) and the Equivalent Consumption Minimization Strategy (ECMS)) the proposed strategy increases the overall vehicle energy efficiency and therefore minimizes the total hydrogen consumption while respecting the constraints of each energy and power element. A model of a hybrid vehicle has been built using the TruckMaker/MATLAB software. Using the Urban Dynamometer Driving Schedule (UDDS) which includes several stops and accelerations the performance of the proposed strategy has been compared with these different approaches (SMC FLC FDFLC and ECMS) through several simulations.
Opportunities and Challenges for Thermally Driven Hydrogen Production Using Reverse Electrodialysis System
Jul 2019
Publication
Ongoing and emerging renewable energy technologies mainly produce electric energy and intermittent power. As the energy economy relies on banking energy there is a rising need for chemically stored energy. We propose heat driven reverse electrodialysis (RED) technology with ammonium bicarbonate (AmB) as salt for producing hydrogen. The study provides the authors’ perspective on the commercial feasibility of AmB RED for low grade waste heat (333 K–413 K) to electricity conversion system. This is to our best of knowledge the only existing study to evaluate levelized cost of energy of a RED system for hydrogen production. The economic assessment includes a parametric study and a scenario analysis of AmB RED system for hydrogen production. The impact of various parameters including membrane cost membrane lifetime cost of heating inter-membrane distance and residence time are studied. The results from the economic study suggests RED system with membrane cost less than 2.86 €/m2 membrane life more than 7 years and a production rate of 1.19 mol/m2/h or more are necessary for RED to be economically competitive with the current renewable technologies for hydrogen production. Further salt solubility residence time and inter-membrane distance were found to have impact on levelized cost of hydrogen LCH. In the present state use of ammonium bicarbonate in RED system for hydrogen production is uneconomical. This may be attributed to high membrane cost low (0.72 mol/m2/h) hydrogen production rate and large (1281436 m2) membrane area requirements. There are three scenarios presented the present scenario market scenario and future scenario. From the scenario analysis it is clear that membrane cost and membrane life in present scenario controls the levelized cost of hydrogen. In market scenario and future scenario the hydrogen production rate (which depends on membrane properties inter-membrane distance etc.) the cost of regeneration system and the cost of heating controls the levelized cost of hydrogen. For a thermally driven RED system to be economically feasible the membrane cost not more than 20 €/m2; hydrogen production rate of 3.7 mol/m2/h or higher and cost of heating not more than 0.03 €/kWh for low grade waste heat to hydrogen production.
The Study on Permissible Value of Hydrogen Gas Concentration in Purge Gas of Fuel Cell Vehicles
Sep 2019
Publication
Ignition conditions and risks of ignition on a permissible value of hydrogen concentration in purge gas prescribed by HFCV-GTR were reevaluated. Experiments were conducted to investigate burning behavior and thermal influence of continuous evacuation of hydrogen under continuous purge of air / hydrogen premixed gas which is close to an actual purge condition of FCV and thermal evacuation of hydrogen. As a result of the re-evaluation it was shown from the viewpoint of safety that the permissible value of hydrogen concentration in purge gas prescribed by the current HFCV GTR is appropriate.
End of Life of Fuel Cells and Hydrogen Products: From Technologies to Strategies
Feb 2019
Publication
End-of-Life (EoL) technologies and strategies are needed to support the deployment of fuel cells and hydrogen (FCH) products. This article explores current and novel EoL technologies to recover valuable materials from the stacks of proton exchange membrane fuel cells and water electrolysers alkaline water electrolysers and solid oxide fuel cells. Current EoL technologies are mainly based on hydrometallurgical and pyro-hydrometallurgical methods for the recovery of noble metals while novel methods attempt to recover additional materials through efficient safe and cost-competitive pathways. Strengths weaknesses opportunities and threats of the reviewed EoL technologies are identified under techno-economic environmental and regulatory aspects. Beyond technologies strategies for the EoL of FCH stacks are defined mainly based on the role of manufacturers and recovery centres in the short- mid- and long-term. In this regard a dual role manufacturer/recovery centre would characterise long-term scenarios within a potential context of a well-established hydrogen economy.
A Review of Techno-economic Data for Road Transportation Fuels
May 2019
Publication
Worldwide the road transport sector typically arises as one of the main sources of air pollutants due to its high energy intensity and the use of fossil fuels. Thus governments and social agents work on the development and prospective planning of decarbonisation strategies oriented towards sustainable transport. In this regard the increase in the use of alternative fuels is the recurrent approach to energy planning e.g. through the promotion of electric vehicles biofuels natural gas liquefied petroleum gas etc. However there is a lack of comprehensive information on the techno-economic performance of production pathways for alternative fuels. The acquisition of robust techno-economic data is still a challenge for energy planners modellers analysts and policy-makers when building their prospective models to support decision-making processes. Hence this article aims to fill this gap through a deep literature review including the most representative production routes for a wide range of road transportation fuels. This led to the development of datasets including investment costs operating and maintenance costs and transformation efficiencies for more than 40 production pathways. The techno-economic data presented in this work are expected to be especially useful to those energy actors interested in performing long-term studies on the transition to a sustainable transport system.
Validation of Two-Layer Model for Underexpanded Hydrogen Jets
Sep 2019
Publication
Previous studies have shown that the two-layer model more accurately predicts hydrogen dispersion than the conventional notional nozzle models without significantly increasing the computational expense. However the model was only validated for predicting the concentration distribution and has not been adequately validated for predicting the velocity distributions. In the present study particle imaging velocimetry (PIV) was used to measure the velocity field of an underexpanded hydrogen jet released at 10 bar from a 1.5 mm diameter orifice. The two-layer model was the used to calculate the inlet conditions for a two-dimensional axisymmetric CFD model to simulate the hydrogen jet downstream of the Mach disk. The predicted velocity spreading and centerline decay rates agreed well with the PIV measurements. The predicted concentration distribution was consistent with data from previous planar Rayleigh scattering measurements used to verify the concentration distribution predictions in an earlier study. The jet spreading was also simulated using several widely used notional nozzle models combined with the integral plume model for comparison. These results show that the velocity and concentration distributions are both better predicted by the two-layer model than the notional nozzle models to complement previous studies verifying only the predicted concentration profiles. Thus this study shows that the two-layer model can accurately predict the jet velocity distributions as well as the concentration distributions as verified earlier. Though more validation studies are needed to improve confidence in the model and increase the range of validity the present work indicates that the two-layer model is a promising tool for fast accurate predictions of the flow fields of underexpanded hydrogen jets.
Hydrogen: A Reviewable Energy Perspective
Sep 2019
Publication
Hydrogen has emerged as an important part of the clean energy mix needed to ensure a sustainable future. Falling costs for hydrogen produced with renewable energy combined with the urgency of cutting greenhouse-gas emissions has given clean hydrogen unprecedented political and business momentum.
This paper from the International Renewable Energy Agency (IRENA) examines the potential of hydrogen fuel for hard-to-decarbonise energy uses including energy-intensive industries trucks aviation shipping and heating applications. But the decarbonisation impact depends on how hydrogen is produced. Current and future sourcing options can be divided into grey (fossil fuel-based) blue (fossil fuel-based production with carbon capture utilisation and storage) and green (renewables-based) hydrogen. Green hydrogen produced through renewable-powered electrolysis is projected to grow rapidly in the coming years.
Among other findings:
Important synergies exist between hydrogen and renewable energy. Hydrogen can boost renewable electricity market growth and broaden the reach of renewable solutions.
Trade of energy-intensive commodities produced with hydrogen including “e-fuels” could spur faster uptake or renewables and bring wider economic benefits.
This paper from the International Renewable Energy Agency (IRENA) examines the potential of hydrogen fuel for hard-to-decarbonise energy uses including energy-intensive industries trucks aviation shipping and heating applications. But the decarbonisation impact depends on how hydrogen is produced. Current and future sourcing options can be divided into grey (fossil fuel-based) blue (fossil fuel-based production with carbon capture utilisation and storage) and green (renewables-based) hydrogen. Green hydrogen produced through renewable-powered electrolysis is projected to grow rapidly in the coming years.
Among other findings:
Important synergies exist between hydrogen and renewable energy. Hydrogen can boost renewable electricity market growth and broaden the reach of renewable solutions.
- Electrolysers can add demand-side flexibility. In advanced European energy markets electrolysers are growing from megawatt to gigawatt scale.
- Blue hydrogen is not inherently carbon free. This type of production requires carbon-dioxide (CO2) monitoring verification and certification.
- Synergies may exist between green and blue hydrogen deployment given the chance for economies of scale in hydrogen use or logistics.
- A hydrogen-based energy transition will not happen overnight. Hydrogen use is likely to catch on for specific target applications. The need for new supply infrastructure could limit hydrogen use to countries adopting this strategy.
- Dedicated hydrogen pipelines have existed for decades and could be refurbished along with existing gas pipelines. The implications of replacing gas abruptly or changing mixtures gradually should be further explored.
Trade of energy-intensive commodities produced with hydrogen including “e-fuels” could spur faster uptake or renewables and bring wider economic benefits.
Carbon Capture and Storage Could Clear a Path to the UK's Carbon Reduction Targets: An ETI Technology Programme Highlight Report
Sep 2014
Publication
Capturing and sealing away carbon dioxide released from industrial processes and electricity generation is acknowledged internationally to be potentially a winning intervention in the battle against climate change. The collected technologies that make up Carbon Capture and Storage (CCS) could remove more than 90% of the carbon emissions from energy intensive industries and electricity production. In power generation CCS not only provides low-carbon output but it also preserves capacity in fossil fuel-fired plant to respond to shifts in demand. This is a near-unique combination that could mitigate the different shortcomings of harnessing the wind the sun or nuclear fission.<br/>CCS could clear a path to the UK’s carbon reduction targets; secure its energy supplies; and reduce the cost of those achievements. With CCS in play a low-carbon future with secure energy supplies becomes affordable. However without our research has found that the costs of meeting the UK’s lowcarbon targets could double to £60bn a year by 2050 at today’s prices.<br/>However CCS has to be honed technically and commercially before it can become a reality. ETI supported by its partners has made important progress and continues to do so.
Hydrogen Council Report- Decarbonization Pathways
Jan 2021
Publication
This report shows that low-carbon hydrogen supply at scale is economically and environmentally feasible and will have significant societal benefits if the right localised approach and best-practices for production are used. The report also demonstrates that there is not one single hydrogen production pathway to achieve low lifecycle greenhouse gas (GHG) emissions but rather the need for a fact-based approach that leverages regional resources and includes a combination of different production pathways. This will achieve both emission and cost reductions ultimately helping to decarbonize the energy system and limit global warming.
In 2020 more than 15 countries launched major hydrogen plans and policies and industry players announced new projects of more than 35GW until 2030. As this hydrogen momentum accelerates it is increasingly clear that decision makers must put the focus on decarbonization to ensure hydrogen can fulfil its potential as a key solution in the global clean energy transition making a significant contribution to net zero emissions. To support this effort the two-part Hydrogen Council report provides new data based on an assessment of the GHG emissions generated through different hydrogen supply pathways and the lifecycle GHG emissions for different hydrogen applications (see report part 1 – A Life-cycle Assessment). In addition the report explores 3 hypothetical hydrogen supply scenarios to measure the feasibility and impact of deploying renewable and low-carbon hydrogen at scale (report part 2 – Potential Supply Scenarios).
The report outlines that there are many ways of producing hydrogen and although GHG emissions vary widely very high CO2 savings can be achieved across a broad range of different hydrogen production pathways and end-uses. For example while “green” hydrogen produced through water electrolysis with renewable power achieves the lowest emissions “blue” hydrogen produced from natural gas with high CO2 capture rate and storage can also achieve low emissions if best technologies are used and best practices are followed. Across eight illustrative pathways explored in the report analysis shows that if hydrogen is used significant GHG emission reductions can be made: as much as 60-90% or more compared to conventional fossil alternatives. The study also looked into the gross water demand of hydrogen supply pathways. Water electrolysis has a very low specific water demand of 9 kg per kg of hydrogen compared to cooling of thermal power plants (hundreds of kg/kg) or biomass cultivation (hundreds to thousands of kg/kg).
Furthermore low-carbon hydrogen supply at scale is fully achievable. Having investigated two hypothetical boundary scenarios (a “green-only” and a “blue-only” scenario) to assess the feasibility and impact of decarbonized hydrogen supply the report found that both scenarios are feasible: they are not limited by the world’s renewables potential or carbon sequestration (CCS) capacities and they do not exceed the speed at which industry can scale. In the Hydrogen Council’s “Scaling up” study a demand of 21800 TWh hydrogen has been identified for the year 2050. To achieve this a compound annual growth rate of 30-35% would be needed for electrolysers and CCS. This deployment rate is in line with the growth of the offshore wind and solar PV industry over the last decade.
Hydrogen Council data released in January 2020 showed that a wide range of hydrogen applications can become competitive by 2030 driven also by falling costs of renewable and low-carbon hydrogen[1]. The new study indicates that a combination of “green” and “blue” production pathways would lead to hydrogen cost reductions relative to either boundary scenario. By making use of the near-term cost advantage of “blue” while also scaling up “green” hydrogen as the most cost-efficient option in many regions in the medium and long-term the combined approach lowers average hydrogen costs between now and 2050 relative to either boundary scenario.
Part 1 – A Life-cycle Assessment
You can download the full reports from the Hydrogen Council website
Hydrogen Council Report- Decarbonization Pathways Part 1: Life Cycle Assessment here
Hydrogen Council Report-Decarbonization Pathways Part 2: Supply Scenarios here
An executive summary of the whole project can be found here
In 2020 more than 15 countries launched major hydrogen plans and policies and industry players announced new projects of more than 35GW until 2030. As this hydrogen momentum accelerates it is increasingly clear that decision makers must put the focus on decarbonization to ensure hydrogen can fulfil its potential as a key solution in the global clean energy transition making a significant contribution to net zero emissions. To support this effort the two-part Hydrogen Council report provides new data based on an assessment of the GHG emissions generated through different hydrogen supply pathways and the lifecycle GHG emissions for different hydrogen applications (see report part 1 – A Life-cycle Assessment). In addition the report explores 3 hypothetical hydrogen supply scenarios to measure the feasibility and impact of deploying renewable and low-carbon hydrogen at scale (report part 2 – Potential Supply Scenarios).
The report outlines that there are many ways of producing hydrogen and although GHG emissions vary widely very high CO2 savings can be achieved across a broad range of different hydrogen production pathways and end-uses. For example while “green” hydrogen produced through water electrolysis with renewable power achieves the lowest emissions “blue” hydrogen produced from natural gas with high CO2 capture rate and storage can also achieve low emissions if best technologies are used and best practices are followed. Across eight illustrative pathways explored in the report analysis shows that if hydrogen is used significant GHG emission reductions can be made: as much as 60-90% or more compared to conventional fossil alternatives. The study also looked into the gross water demand of hydrogen supply pathways. Water electrolysis has a very low specific water demand of 9 kg per kg of hydrogen compared to cooling of thermal power plants (hundreds of kg/kg) or biomass cultivation (hundreds to thousands of kg/kg).
Furthermore low-carbon hydrogen supply at scale is fully achievable. Having investigated two hypothetical boundary scenarios (a “green-only” and a “blue-only” scenario) to assess the feasibility and impact of decarbonized hydrogen supply the report found that both scenarios are feasible: they are not limited by the world’s renewables potential or carbon sequestration (CCS) capacities and they do not exceed the speed at which industry can scale. In the Hydrogen Council’s “Scaling up” study a demand of 21800 TWh hydrogen has been identified for the year 2050. To achieve this a compound annual growth rate of 30-35% would be needed for electrolysers and CCS. This deployment rate is in line with the growth of the offshore wind and solar PV industry over the last decade.
Hydrogen Council data released in January 2020 showed that a wide range of hydrogen applications can become competitive by 2030 driven also by falling costs of renewable and low-carbon hydrogen[1]. The new study indicates that a combination of “green” and “blue” production pathways would lead to hydrogen cost reductions relative to either boundary scenario. By making use of the near-term cost advantage of “blue” while also scaling up “green” hydrogen as the most cost-efficient option in many regions in the medium and long-term the combined approach lowers average hydrogen costs between now and 2050 relative to either boundary scenario.
Part 1 – A Life-cycle Assessment
- The life-cycle assessment (LCA) analysis in this study addresses every aspect of the supply chain from primary energy extraction to end use. Eight primary-energy-to-hydrogen value chains have been selected for illustrative purposes.
- Across the hydrogen pathways and applications depicted very high to high GHG emission reduction can be demonstrated using green (solar wind) and blue hydrogen.
- In the LCA study renewables + electrolysis shows strongest GHG reduction of the different hydrogen supply pathways assessed in this study with a best-case blue hydrogen pathway also coming into the same order of magnitude.
- Currently the vast majority of hydrogen is produced by fossil pathways. To achieve a ten-fold build-out of hydrogen supply by 2050 as envisaged by the Hydrogen Council in its ‘Scaling Up’ report (2017) the existing use of hydrogen – and all its many potential new roles – need to be met by decarbonized sources.
- Three hypothetical supply scenarios with decarbonized hydrogen sources are considered in the study: 1) a “green-only” renewables-based world; 2) a “blue-only” world relying on carbon sequestration; and 3) a combined scenario that uses a region-specific combination of green and blue hydrogen based on the expected regional cost development of each source.
- The study finds that a decarbonized hydrogen supply is possible regardless of the production pathway: while both the green and blue boundary scenario would be highly ambitious regarding the required speed of scale-up they do not exceed the world’s resources on either renewable energy or carbon sequestration capabilities.
- A combination of production pathways would result in the least-cost global supply over the entire period of scale-up. It does so by making best use of the near-term cost advantage of “blue” in some regions while simultaneously achieving a scale-up in electrolysis.
- In reality the decarbonized supply scenario will combine a range of different renewable and low-carbon hydrogen production pathways that are optimally suited to local conditions political and societal preferences and regulations as well as industrial and cost developments for different technologies.
You can download the full reports from the Hydrogen Council website
Hydrogen Council Report- Decarbonization Pathways Part 1: Life Cycle Assessment here
Hydrogen Council Report-Decarbonization Pathways Part 2: Supply Scenarios here
An executive summary of the whole project can be found here
How Far Away is Hydrogen? Its Role in the Medium and Long-term Decarbonisation of the European Energy System
Nov 2015
Publication
Hydrogen is a promising avenue for decarbonising energy systems and providing flexibility. In this paper the JRC-EU-TIMES model – a bottom-up technology-rich model of the EU28 energy system – is used to assess the role of hydrogen in a future decarbonised Europe under two climate scenarios current policy initiative (CPI) and long-term decarbonisation (CAP). Our results indicate that hydrogen could become a viable option already in 2030 – however a long-term CO2 cap is needed to sustain the transition. In the CAP scenario the share of hydrogen in the final energy consumption of the transport and industry sectors reaches 5% and 6% by 2050. Low-carbon hydrogen production technologies dominate and electrolysers provide flexibility by absorbing electricity at times of high availability of intermittent sources. Hydrogen could also play a significant role in the industrial and transport sectors while the emergence of stationary hydrogen fuel cells for hydrogen-to-power would require significant cost improvements over and above those projected by the experts.
Hydrogen-fueled Car Fire Spread to Adjacent Vehicles in Car Parks
Sep 2019
Publication
Car park fires are known to be dangerous due to the risk of fast fire spread from one car to another. In general no fatalities are recorded in such fires but they may have a great cost in relation to damaged cars and structural repair. A very recent example is the Liverpool multi-storey car park fire from December 31 2017. It destroyed 1400 cars and parts of the building structure collapsed. This questions the validity of current design praxis of car parks. Literature studies assumes a 12 minutes period for the fire spread from one gasoline fuelled car to another. Statistical research and test from the European commission of steel structures states that in an open car park at most 3-4 vehicles are expected to be on fire at the same time.<br/>A number of investigations have been made concerning vehicles performance in car park fires but only a few are concerned with hydrogen-fuelled vehicles (HFV). It is therefore important to investigate how these new vehicles may contribute to potential fire spread scenario. The aim of the paper is to report the outcome of car park fire spread simulations involving common fuelled and hydrogen fuelled cars. The case study is based on a typical car park found in Denmark. The simulation applied numerical models implemented in the Fire Dynamic Simulator (FDS). In particular the focus of the study is on the influence of the parking distance to fire spread to adjacent vehicles in case a TPRD is activated during a car fire. The results help understanding whether different design rules should be envisaged for such structures or how a sufficient safety level can be obtained by ensuring specific parking condition for the hydrogen-fuelled cars.
Non-adiabatic Under-expanded Jet Theory for Blowdown and Fire Resistance Rating of Hydrogen Tank
Sep 2019
Publication
The European Regulations on type-approval of hydrogen vehicles require thermally-activated pressure relief device (TPRD) to be installed on hydrogen onboard storage tanks to release its content in a fire event to prevent its catastrophic rupture. The aim of this study is to develop a model for design of an inherently safer system TPRD-storage tank. Parameters of tank materials and hydrogen external heat flux from the fire to the tank wall TPRD diameter time to initiate TPRD are input parameters of the model. The energy conservation equation and real gas equation of state are employed to describe the dynamic behaviour of the system. The under-expanded jet theory developed previously for adiabatic release from a storage tank is applied here to non-adiabatic blowdown of a tank in a fire. Unsteady heat transfer equation is used to calculate heat conduction through the tank wall. It includes the decomposition of the wall material due to high heat flux. The convective heat transfer between tank wall and hydrogen is modelled through the dimensionless Nusselt number correlations. The model is validated against two types of experiments i.e. realistic (non-adiabatic) blowdown of high-pressure storage tank and failure of a tank without TPRD in a fire. The model is confirmed to be time efficient for computations and accurately predicts the dynamic pressure and temperature of the gas inside the tank temperature profile within the tank wall time to tank rupture in a fire and the blowdown time.
Integration of Gas Switching Combustion and Membrane Reactors for Exceeding 50% Efficiency in Flexible IGCC Plants with Near-zero CO2 Emissions
Jul 2020
Publication
Thermal power plants face substantial challenges to remain competitive in energy systems with high shares of variable renewables especially inflexible integrated gasification combined cycles (IGCC). This study addresses this challenge through the integration of Gas Switching Combustion (GSC) and Membrane Assisted Water Gas Shift (MAWGS) reactors in an IGCC plant for flexible electricity and/or H2 production with inherent CO2 capture. When electricity prices are high H2 from the MAWGS reactor is used for added firing after the GSC reactors to reach the high turbine inlet temperature of the H-class gas turbine. In periods of low electricity prices the turbine operates at 10% of its rated power to satisfy the internal electricity demand while a large portion of the syngas heating value is extracted as H2 in the MAWGS reactor and sold to the market. This product flexibility allows the inflexible process units such as gasification gas treating air separation unit and CO2 compression transport and storage to operate continuously while the plant supplies variable power output. Two configurations of the GSC-MAWGS plant are presented. The base configuration achieves 47.2% electric efficiency and 56.6% equivalent hydrogen production efficiency with 94.8–95.6% CO2 capture. An advanced scheme using the GSC reduction gases for coal-water slurry preheating and pre-gasification reached an electric efficiency of 50.3% hydrogen efficiency of 62.4% and CO2 capture ratio of 98.1–99.5%. The efficiency is 8.4%-points higher than the pre-combustion CO2 capture benchmark and only 1.9%-points below the unabated IGCC benchmark.
Inhibition of Hydrogen-yielding Dark Fermentation by Ascomycetous Yeasts
May 2018
Publication
Hydrogen-yielding fermentation conducted in bioreactors is an alternative method of hydrogen production. However unfavourable processes can seriously inhibit bio-hydrogen generation during the acidogenic step of anaerobic digestion. Here ascomycetous yeasts were identified as a major factor inhibiting the production of bio-hydrogen by fermentation. Changes in the performance of hydrogen-producing bioreactors including metabolic shift quantitative changes in the fermentation products decreased pH instability of the microbial community and consequently a dramatic drop in bio-hydrogen yield were observed following yeast infection. Ascomycetous yeasts from the genera Candida Kazachstania and Geotrichum were isolated from hydrogen-producing bioreactors. Yeast metabolites secreted into the growth medium showed antibacterial activity. Our studies indicate that yeast infection of hydrogen-producing microbial communities is one of the serious obstacles to use dark fermentation as an alternative method of bio-hydrogen production. It also explains why studies on hydrogen fermentation are still limited to the laboratory or pilot-scale systems.
Large-scale Storage of Hydrogen
Mar 2019
Publication
The large-scale storage of hydrogen plays a fundamental role in a potential future hydrogen economy. Although the storage of gaseous hydrogen in salt caverns already is used on a full industrial scale the approach is not applicable in all regions due to varying geological conditions. Therefore other storage methods are necessary. In this article options for the large-scale storage of hydrogen are reviewed and compared based on fundamental thermodynamic and engineering aspects. The application of certain storage technologies such as liquid hydrogen methanol ammonia and dibenzyltoluene is found to be advantageous in terms of storage density cost of storage and safety. The variable costs for these high-density storage technologies are largely associated with a high electricity demand for the storage process or with a high heat demand for the hydrogen release process. If hydrogen is produced via electrolysis and stored during times of low electricity prices in an industrial setting these variable costs may be tolerable.
Near-term Location of Hydrogen Refueling Stations in Yokohama City from the Perspective of Safety
Sep 2019
Publication
The roll-out of hydrogen refuelling stations is a key step in the transition to a hydrogen economy. Since Japan has been shifting from the demonstration stage to the implementation stage of a hydrogen economy a near-term city-level roll-out plan is required. The aim of this study is to plan near-term locations for building hydrogen refuelling stations in Yokohama City from a safety perspective. Our planning provides location information for hydrogen refuelling stations in Yokohama City for the period 2020–2030. Mobile type and parallel siting type refuelling stations have been considered in our planning and locations were determined by matching supply and demand to safety concerns. Supply and demand were estimated from hybrid vehicle ownership data and from space availability in existing gas stations. The results reaffirmed the importance of hydrogen station location planning and showed that use of mobile type stations is a suitable solution in response to the uncertain fuel cell vehicle fuel demand level during the implementation stage of a hydrogen economy.
Secure, Affordable, Low Carbon: Gas in our Future Energy System
Feb 2020
Publication
Our gas network is one of the best developed in the world providing safe secure affordable energy to homes and businesses across the UK.<br/><br/>To meet the biggest energy challenge of our generation – making deep cuts to carbon emissions by 2050 – it needs to embrace new technology which builds on these strengths and delivers the integrated flexible network of the future. This briefing sets out how it is already doing that. Take a look at our Gas Futures Messages booklet attached.
Experimental Study on Accumulation of Helium Released into a Semi-confined Enclosure without Ventilation
Sep 2019
Publication
This paper examines the helium dispersion behaviour in a 16.6 m3 enclosure with a small opening in the floor and distributed leaks along the edges. Helium a simulant for hydrogen was injected near the center of the floor with an injection rate ranging from 2 to 50 standard liters per minute (Richardson number of 0.3–134) through an upward-facing nozzle. In a short-term transient the helium distribution predicted with the models of Baines & Turner (1969) and Worster & Huppert (1983) matched the measured distributions reasonably well. In a long-term transient the vertical helium profile always reached a steady state which consisted of a homogenous layer at the top overlaying a stratified layer at the bottom. The helium transients in the uniform layer predicted with the models of Lowesmith (2009) and Prasad & Yang (2010) assuming a vent was located in the ceiling were in good agreement with the measured transients.
Validation of a 3d Multiphase-multicomponent CFD Model for Accidental Liquid and Gaseous Hydrogen Releases
Sep 2017
Publication
As hydrogen-air mixtures are flammable in a wide range of concentrations and the minimum ignition energy is low compared to hydrocarbon fuels the safe handling of hydrogen is of utmost importance. Additional hazards may arise with the accidental spill of liquid hydrogen. Such a release of LH2 leads to a formation of a cryogenic pool a dynamic vaporization process and consequently a dispersion of gaseous hydrogen into the environment. Several LH2 release experiments as well as modelling approaches address this phenomenology. In contrast to existing approaches a new CFD model capable of simulating liquid and gaseous distribution was developed at Forschungszentrum Jülich. It is validated against existing experiments and yields no substantial lacks in the physical model and reveals a qualitatively consistent prediction. Nevertheless the deviation between experiment and simulation raises questions on the completeness of the database in particular with regard to the boundary conditions and available measurements.
Effect of Gasoline Pool Fire on Liquid Hydrogen Storage Tank in Hybrid Hydrogen-gasoline Fueling Station
Nov 2015
Publication
Multiple-energy-fuelling stations which can supply several types of energy such as gasoline CNG and hydrogen could guarantee the efficient use of space. To guide the safety management of hybrid hydrogen–gasoline fuelling stations which utilize liquid hydrogen as an energy carrier the scale of gasoline pool fires was estimated using the hazard assessment tool Toxic Release Analysis of Chemical Emissions (TRACE). Subsequently the temperature and the stress due to temperature distribution were estimated using ANSYS. Based on the results the safety of liquid hydrogen storage tanks was discussed. It was inferred that the emissivity of the outer material of the tank and the safety distance between liquid hydrogen storage tanks and gasoline dispensers should be less than 0.2 and more than 8.5 m respectively to protect the liquid hydrogen storage tank from the gasoline pool fire. To reduce the safety distance several measures are required e.g. additional thermal shields such as protective intumescent paint and water sprinkler systems and an increased slope to lead gasoline off to a safe domain away from the liquid hydrogen storage tank
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