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A Numerial Study on Hydrogen Blending in Natural Gas Pipeline by a T-pipe
Mar 2024
Publication
In order to study the flow blending and transporting process of hydrogen that injects into the natural gas pipelines a three-dimensional T-pipe blending model is established and the flow characteristics are investigated systematically by the large eddy simulation (LES). Firstly the mathematical formulation of hydrogen-methane blending process is provided and the LES method is introduced and validated by a benchmark gas blending model having experimental data. Subsequently the T-pipe blending model is presented and the effects of key parameters such as the velocity of main pipe hydrogen blending ratio diameter of hydrogen injection pipeline diameter of main pipe and operating pressure on the hydrogen-methane blending process are studied systematically. The results show that under certain conditions the gas mixture will be stratified downstream of the blending point with hydrogen at the top of the pipeline and methane at the bottom of the pipeline. For the no-stratified scenarios the distance required for uniformly mixing downstream the injection point increases when the hydrogen mixing ratio decreases the diameter of the hydrogen injection pipe and the main pipe increase. Finally based on the numerical results the underlying physics of the stratification phenomenon during the blending process are explored and an indicator for stratification is proposed using the ratio between the Reynolds numbers of the natural gas and hydrogen.
Inspection of Hydrogen Transport Equipment: A Data-driven Approach to Predict Fatigue Degradation
Jul 2024
Publication
Hydrogen is an environmentally friendly fuel that can facilitate the upcoming energy transition. The development of an extensive infrastructure for hydrogen transport and storage is crucial. However the mechanical properties of structural materials are significantly degraded in H2 environments leading to early component failures. Pipelines are designed following defect-tolerant principles and are subjected to periodic pressure fluctuations. Hence these systems are potentially prone to fatigue degradation often accelerated in pressurized hydrogen gas. Inspection and maintenance activities are crucial to guarantee the integrity and fitness for service of this infrastructure. This study predicts the severity of hydrogen-enhanced fatigue in low-alloy steels commonly employed for H2 transport and storage equipment. Three machine-learning algorithms i.e. Linear Model Deep Neural Network and Random Forest are used to categorize the severity of the fatigue degradation. The models are critically compared and the best-performing algorithm are trained to predict the Fatigue Acceleration Factor. This approach shows good prediction capability and can estimate the fatigue crack propagation in lowalloy steels. These results allow for estimating the probability of failure of hydrogen pipelines thus facilitating the inspection and maintenance planning.
Potential Capacity and Cost Assessments for Hydrogen Production from Marine Sources
May 2024
Publication
The current study comprehensively examines the application of wave tidal and undersea current energy sources of Turkiye for green hydrogen fuel production and cost analysis. The estimated potential capacity of each city is derived from official data and acceptable assumptions and is subject to discussion and evaluation in the context of a viable hydrogen economy. According to the findings the potential for green hydrogen generation in Turkiye is projected to be 7.33 million tons using a proton exchange membrane electrolyser (PEMEL). Cities with the highest hydrogen production capacities from marine applications are Mugla Izmir Antalya and Canakkale with 998.10 kt 840.31 kt 605.46 kt and 550.42 kt respectively. The study calculations obviously show that there is a great potential by using excess power in producing hydrogen which will result in an economic value of 3.01 billion US dollars. This study further helps develop a detailed hydrogen map for every city in Turkiye using the identified potential capacities of renewable energy sources and the utilization of electrolysers to make green hydrogen by green power. The potentials and specific capacities for every city are also highlighted. Furthermore the study results are expected to provide clear guidance for government authorities and industries to utilize such a potential of renewable energy for investment and promote clean energy projects by further addressing concerns caused by the usage of carbon-based (fossil fuels dependent) energy options. Moreover green hydrogen production and utilization in every sector will help achieve the national targets for a net zero economy and cope with international targets to achieve the United Nation's sustainable development goals.
Lower-Carbon Hydrogen Production from Wastewater: A Comprehensive Review
Oct 2024
Publication
Hydrogen has the capability of being a potential energy carrier and providing a long-term solution for sustainable lower-carbon and ecologically benign fuel supply. Because lower-carbon hydrogen is widely used in chemical synthesis it is regarded as a fuel with no emissions for transportation. This review paper offers a novel technique for producing hydrogen using wastewater in a sustainable manner. The many techniques for producing hydrogen with reduced carbon emissions from wastewater are recognized and examined in detail taking into account the available prospects significant obstacles and potential future paths. A comparison of the assessment showed that water electrolysis and dark fermentation technologies are the most effective methods for hydrogen generation from wastewater with microbial electrolysis and photofermentation. Thus the incorporation of systems that are simultaneously producing lower-carbon hydrogen and meant for wastewater treatment is important for the minimization of emissions from greenhouse gases and recovering the energy utilized in the treatment of wastewater.
Towards Sustainable Hydrogen Production: An Integrated Approach for Sustainability, Complexity, and Systems Thinking in the Energy Sector
Mar 2024
Publication
The energy sector constitutes a dynamic and complex system indicating that its actions are influenced not just by its individual components but also by the emergent behavior resulting from interactions among them. Moreover there are crucial limitations of previous approaches for addressing the sustainability challenge of the energy sector. Changing transforming and integrating paradigms are the most relevant leverage points for transforming a given system. In other words nowadays the integration of new predominant paradigms in order to provide a unified framework could aim at this actual transformation looking for a sustainable future. This research aims to develop a new unified framework for the integration of the following three paradigms: (1) Sustainability (2) Complexity and (3) Systems Thinking which will be applied to achieving sustainable energy production (using hydrogen production as a case study). The novelty of this work relies on providing a holistic perspective through the integration of the aforementioned paradigms considering the multiple and complex interdependencies among the economy the environment and the economy. For this purpose an integrated seven-stage approach is introduced which explores from the starting point of the integration of paradigms to the application of this integration to sustainable energy production. After applying the Three-Paradigm approach for sustainable hydrogen production as a case study 216 feedback loops are identified due to the emerged complexity linked to the analyzed system. Additionally three system dynamics-based models are developed (by increasing the level of complexity) as part of the application of the Three-Paradigm approach. This research can be of interest to a broad professional audience (e.g. engineers policymakers) as looks into the sustainability of the energy sector from a holistic perspective considering a newly developed Three-Paradigm model considering complexity and using a Systems Thinking approach.
Above-ground Hydrogen Storage: A State-of-the-art Review
Nov 2024
Publication
Hydrogen is increasingly recognized as a clean energy alternative offering effective storage solutions for widespread adoption. Advancements in storage electrolysis and fuel cell technologies position hydrogen as a pathway toward cleaner more efficient and resilient energy solutions across various sectors. However challenges like infrastructure development cost-effectiveness and system integration must be addressed. This review comprehensively examines above-ground hydrogen storage technologies and their applications. It highlights the importance of established hydrogen fuel cell infrastructure particularly in gaseous and LH2 systems. The review favors material-based storage for medium- and long-term needs addressing challenges like adverse thermodynamics and kinetics for metal hydrides. It explores hydrogen storage applications in mobile and stationary sectors including fuel-cell electric vehicles aviation maritime power generation systems off-grid stations power backups and combined renewable energy systems. The paper underscores hydrogen’s potential to revolutionize stationary applications and co-generation systems highlighting its significant role in future energy landscapes.
Safety of Hydrogen Storage Technologies
Oct 2024
Publication
While hydrogen is regularly discussed as a possible option for storing regenerative energies its low minimum ignition energy and broad range of explosive concentrations pose safety challenges regarding hydrogen storage and there are also challenges related to hydrogen production and transport and at the point of use. A risk assessment of the whole hydrogen energy system is necessary to develop hydrogen utilization further. Here we concentrate on the most important hydrogen storage technologies especially high-pressure storage liquid hydrogen in cryogenic tanks methanol storage and salt cavern storage. This review aims to study the most recent research results related to these storage techniques by describing typical sensors and explosion protection measures thus allowing for a risk assessment of hydrogen storage through these technologies.
Drifting toward Alliance Innovation: Patent Collaboration Relationships and Development in China’s Hydrogen Energy Industry from a Network Perspective
Mar 2024
Publication
The hydrogen energy industry as one of the most important directions for future energy transformation can promote the sustainable development of the global economy and of society. China has raised the development of hydrogen energy to a strategic position. Based on the patent data in the past two decades this study investigates the collaborative innovation relationships in China’s hydrogen energy field using complex network theory. Firstly patent data filed between 2003 and 2023 are analyzed and compared in terms of time geography and institutional and technological dimensions. Subsequently a patent collaborative innovation network is constructed to explore the fundamental characteristics and evolutionary patterns over five stages. Furthermore centrality measures and community detection algorithms are utilized to identify core entities and innovation alliances within the network which reveal that China’s hydrogen energy industry is drifting toward alliance innovation. The study results show the following: (1) the network has grown rapidly in size and scope over the last two decades and evolved from the initial stage to the multi-center stage before forming innovation alliances; (2) core innovative entities are important supports and bridges for China’s hydrogen energy industry and control most resources and maintain the robustness of the whole network; (3) innovation alliances reveal the closeness of the collaborative relationships between innovative entities and the potential landscape of China’s hydrogen energy industry; and (4) most of the innovation alliances cooperate only on a narrow range of technologies which may hinder the overall sustainable growth of the hydrogen energy industry. Thereafter some suggestions are put forward from the perspective of an industrial chain and innovation chain which may provide a theoretical reference for collaborative innovation and the future development and planning in the field of hydrogen energy in China.
Comprehensive Review of Carbon Capture and Storage Integration in Hydrogen Production: Opportunities, Challenges, and Future Perspectives
Oct 2024
Publication
The growing emphasis on renewable energy highlights hydrogen’s potential as a clean energy carrier. However traditional hydrogen production methods contribute significantly to carbon emissions. This review examines the integration of carbon capture and storage (CCS) technologies with hydrogen production processes focusing on their ability to mitigate carbon emissions. It evaluates various hydrogen production techniques including steam methane reforming electrolysis and biomass gasification and discusses how CCS can enhance environmental sustainability. Key challenges such as economic technical and regulatory obstacles are analyzed. Case studies and future trends offer insights into the feasibility of CCS–hydrogen integration providing pathways for reducing greenhouse gases and facilitating a clean energy transition.
The Impact of the Configuration of a Hydrogen Refueling Station on Risk Level
Nov 2024
Publication
The paper discusses potential hazards at hydrogen refueling stations for transportation vehicles: cars and trucks. The main hazard analyzed here is an uncontrolled gas release due to a failure in one of the structures in the station: storage tanks of different pressure levels or a dispenser. This may lead to a hydrogen cloud occurring near the source of the release or at a given distance. The range of the cloud was analyzed in connection to the amount of the released gas and the wind velocity. The results of the calculations were compared for chosen structures in the station. Then potential fires and explosions were investigated. The hazard zones were calculated with respect to heat fluxes generated in the fires and the overpressure generated in explosions. The maximum ranges of these zones vary from about 14 to 30 m and from about 9 to 14 m for a fires and an explosions of hydrogen respectively. Finally human death probabilities are presented as functions of the distance from the sources of the uncontrolled hydrogen releases. These are shown for different amounts and pressures of the released gas. In addition the risk of human death is determined along with the area where it reaches the highest value in the whole station. The risk of human death in this area is 1.63 × 10−5 [1/year]. The area is approximately 8 square meters.
Green Hydrogen Energy Systems: A Review on Their Contribution to a Renewable Energy System
Jun 2024
Publication
Accelerating the transition to a cleaner global energy system is essential for tackling the climate crisis and green hydrogen energy systems hold significant promise for integrating renewable energy sources. This paper offers a thorough evaluation of green hydrogen’s potential as a groundbreaking alternative to achieve near-zero greenhouse gas (GHG) emissions within a renewable energy framework. The paper explores current technological options and assesses the industry’s present status alongside future challenges. It also includes an economic analysis to gauge the feasibility of integrating green hydrogen providing a critical review of the current and future expectations for the levelized cost of hydrogen (LCOH). Depending on the geographic location and the technology employed the LCOH for green hydrogen can range from as low as EUR 1.12/kg to as high as EUR 16.06/kg. Nonetheless the findings suggest that green hydrogen could play a crucial role in reducing GHG emissions particularly in hard-to-decarbonize sectors. A target LCOH of approximately EUR 1/kg by 2050 seems attainable in some geographies. However there are still significant hurdles to overcome before green hydrogen can become a cost-competitive alternative. Key challenges include the need for further technological advancements and the establishment of hydrogen policies to achieve cost reductions in electrolyzers which are vital for green hydrogen production.
Underground Hydrogen Storage (UHS) in Natural Storage Sites: A Perspective of Subsurface Characterization and Monitoring
Jan 2024
Publication
With the long-standing efforts of green transition in our society underground hydrogen storage (UHS) has emerged as a viable solution to buffering seasonal fluctuations of renewable energy supplies and demands. Like operations in hydrocarbon production and geological CO2 storage a successful UHS project requires a good understanding of subsurface formations while having different operational objectives and practical challenges. Similar to the situations in hydrocarbon production and geological CO2 storage in UHS problems the information of subsurface formations at the field level cannot be obtained through direct measurements due to the resulting high costs. As such there is a need for subsurface characterization and monitoring at the field scale which uses a certain history matching algorithm to calibrate a numerical subsurface model based on available field data. Whereas subsurface characterization and monitoring have been widely used in hydrocarbon production activities for a better understanding of hydrocarbon reservoirs to the best of our knowledge at present it appears to be a relatively less touched area in UHS problems. This work aims to narrow this noticed gap and investigates the use of an ensemble-based workflow for subsurface characterization and monitoring in a 3D UHS case study. Numerical results in this case study indicate that the ensemble-based workflow works reasonably well while also identifying some particular challenges that would be relevant to real-world problems.
Electrification or Hydrogen? The Challenge of Decarbonizing Industrial (High-Temperature) Process Heat
Oct 2024
Publication
The decarbonization of industrial process heat is one of the bigger challenges of the global energy transition. Process heating accounts for about 20% of final energy demand in Germany and the situation is similar in other industrialized nations around the globe. Process heating is indispensable in the manufacturing processes of products and materials encountered every day ranging from food beverages paper and textiles to metals ceramics glass and cement. At the same time process heating is also responsible for significant greenhouse gas emissions as it is heavily dependent on fossil fuels such as natural gas and coal. Thus process heating needs to be decarbonized. This review article explores the challenges of decarbonizing industrial process heat and then discusses two of the most promising options the use of electric heating technologies and the substitution of fossil fuels with low-carbon hydrogen in more detail. Both energy carriers have their specific benefits and drawbacks that have to be considered in the context of industrial decarbonization but also in terms of necessary energy infrastructures. The focus is on high-temperature process heat (>400 ◦C) in energy-intensive basic materials industries with examples from the metal and glass industries. Given the heterogeneity of industrial process heating both electricity and hydrogen will likely be the most prominent energy carriers for decarbonized high-temperature process heat each with their respective advantages and disadvantages.
Net Zero Fuel (Mixed Hydrogen and Biofuels) Cement Clinker: Characterisation, Microstructure, and Performance
Oct 2024
Publication
Over 35% of the CO2 associated with cement production comes from operational energy. The cement industry needs alternative fuels to meet its net zero emissions target. This study investigated the influence of hydrogen mixed with biofuels herein designated net zero fuel as an alternative to coal on the clinker quality and performance of cement produced in an industrial cement plant. Scanning electron microscopy X-ray diffraction and nuclear magnetic resonance were coupled to study the clinker mineralogy and polymorphs. Hydration and microstructure development in plain and slag blended cements based on the clinker were compared to commercial cement equivalent. The results revealed a lower alite/belite ratio but a significant proportion of the belite was of the α’H-C2S polymorph. These reacted faster and compensated for the alite/belite ratio. Gel and micro-capillary pores were densified which reduced total porosity and attained comparable strength to the reference plain and blended cement. This study demonstrates that the investigated net zero fuel-produced clinker meets compositional and strength requirements for plain and blended cement providing a feasible pathway for the cement industry to lower its operational carbon significantly.
Batteries or Hydrogen or Both for Grid Electricity Storage Upon Full Electrification of 145 Countries with Wind-Water-Solar?
Jan 2024
Publication
Grids require electricity storage. Two emerging storage technologies are battery storage (BS) and green hydrogen storage (GHS) (hydrogen produced and compressed with clean-renewable electricity stored then returned to electricity with a fuel cell). An important question is whether GHS alone decreases system cost versus BS alone or BS+GHS. Here energy costs are modeled in 145 countries grouped into 24 regions. Existing conventional hydropower (CH) storage is used along with new BS and/or GHS. A method is developed to treat CH for both baseload and peaking power. In four regions only CH is needed. In five CH+BS is lowest cost. Otherwise CH+BS+GHS is lowest cost. CH+GHS is never lowest cost. A metric helps estimate whether combining GHS with BS reduces cost. In most regions merging (versus separating) grid and non-grid hydrogen infrastructure reduces cost. In sum worldwide grid stability may be possible with CH+BS or CH+BS+GHS. Results are subject to uncertainties.
Whole System Impacts of Decarbonising Transport with Hydrogen: A Swedish Case Study
Oct 2024
Publication
This study aims to carry out a techno-economic analysis of different hydrogen supply chain designs coupled with the Swedish electricity system to study the inter-dependencies between them. Both the hydrogen supply chain designs and the electricity system were parameterized with data for 2030. The supply chain designs comprehend centralised production decentralised production a combination of both and with/without seasonal variation in hydrogen demand. The supply chain design is modelled to minimize the overall cost while meeting the hydrogen demands. The outputs of the supply chain model include the hydrogen refuelling stations’ locations the electrolyser’s locations and their respective sizes as well as the operational schedule. The electricity system model shows that the average electricity prices in Sweden for zones SE1 SE2 SE3 and SE4 will be 4.28 1.88 8.21 and 8.19 €/MWh respectively. The electricity is mainly generated from wind and hydropower (around 42% each) followed by nuclear (14%) solar (2%) and then bio-energy (0.3%). In addition the hydrogen supply chain design that leads to a lower overall cost is the decentralised design with a cost of 1.48 and 1.68 €/kgH2 in scenarios without and with seasonal variation respectively. The seasonal variation in hydrogen demand increases the cost of hydrogen regardless of the supply chain design.
Life Cycle Analysis of Hydrogen Production by Different Alkaline Electrolyser Technologies Sourced with Renewable Energy
Jul 2024
Publication
Green hydrogen has been considered a promising alternative to fossil fuels in chemical and energy applications. In this study a life cycle analysis is conducted for green hydrogen production sourced with a mixture of renewable energy sources (50 % solar and 50 % wind energy). Two advanced technologies of alkaline electrolysis are selected and compared for hydrogen production: pressurised alkaline electrolyser and capillary-fed alkaline electrolyser. The different value chain stages were assessed in SimaPro enabling the assessment of the environmental impacts of a green hydrogen production project with 60 MW capacity and 20 years lifetime. The results evaluate the environmental impacts depending on the components construction and operation requirements. The results demonstrated that capillary-fed alkaline electrolyser technology has lower potential environmental impacts by around 17 % than pressurised alkaline electrolyser technology for all the process stages. The total global warming potential was found to be between 1.98 and 2.39 kg of carbon dioxide equivalent per kg of hydrogen. This study contributes to the electrolysers industry and the planning of green hydrogen projects for many applications towards decarbonization and sustainability.
Potential-risk and No-regret Options for Urban Energy System Design - A Sensitivity Analysis
Jan 2024
Publication
This study identifies supply options for sustainable urban energy systems which are robust to external system changes. A multi-criteria optimization model is used to minimize greenhouse gas (GHG) emissions and financial costs of a reference system. Sensitivity analyses examine the impact of changing boundary conditions related to GHG emissions energy prices energy demands and population density. Options that align with both financial and emission reduction and are robust to system changes are called “no-regret” options. Options sensitive to system changes are labeled as “potential-risk” options.<br/>There is a conflict between minimizing GHG emissions and financial costs. In the reference case the emission-optimized scenario enables a reduction of GHG emissions (-93%) but involves higher costs (+160%) compared to the financially-optimized scenario.<br/>No-regret options include photovoltaic systems decentralized heat pumps thermal storages electricity exchange between sub-systems and with higher-level systems and reducing energy demands through building insulation behavioral changes or the decrease of living space per inhabitant. Potential-risk options include solar thermal systems natural gas technologies high-capacity battery storages and hydrogen for buildiing energy supply.<br/>When energy prices rise financially-optimized systems approach the least-emission system design. The maximum profitability of natural gas technologies was already reached before the 2022 European energy crisis.
Regional Capabilities and Hydrogen Adoption Barriers
Dec 2023
Publication
Hydrogen is gaining importance to decarbonize the energy system and tackle the climate crisis. This exploratory study analyzes three focus groups with representatives from relevant organizations in a Northern German region that has unique beneficial characteristics for the transition to a hydrogen economy. Based upon this data (1) a category system of innovation adoption barriers for hydrogen technologies is developed (2) decision levels associated with the barriers are identified (3) detailed insights on how decision levels contribute to the adoption barriers are provided and (4) the barriers are evaluated in terms of their importance. Our analysis adds to existing literature by focusing on short-term barriers and exploring relevant decision levels and their associated adoption barriers. Our main results comprise the following: flaws in the funding system complex approval procedures lack of networks and high costs contribute to hydrogen adoption barriers. The (Sub-)State level is relevant for the uptake of the hydrogen economy. Regional entities have leeway to foster the hydrogen transition especially with respect to the distribution infrastructure. Funding policy technological suitability investment and operating costs and the availability of distribution infrastructure and technical components are highly important adoption barriers that alone can impede the transition to a hydrogen economy.
A Systematic Review: The Role of Emerging Carbon Capture and Conversion Rechnologies for Energy Transition to Clean Hydrogen
Feb 2024
Publication
The exploitation of fossil fuels in various sectors such as power and heat generation and the transportation sector has been the primary source of greenhouse gas (GHG) emissions which are the main contributors to global warming. Qatar's oil and gas sector notably contributes to CO2 emissions accounting for half of the total emissions. Globally it is essential to transition into cleaner fossil fuel production to achieve carbon neutrality on a global scale. In this paper we focus on clean hydrogen considering carbon capture to make hydrogen a viable low carbon energy alternative for the transition to clean energy. This paper systematically reviews emerging technologies in carbon capture and conversion (CCC). First the road map stated by the Intergovernmental Panel on Climate Change (IPCC) to reach carbon neutrality is discussed along with pathways to decarbonize the energy sector in Qatar. Next emerging CO2 removal technologies including physical absorption using ionic liquids chemical looping and cryogenics are explored and analyzed regarding their advancement and limitations CO2 purity scalability and prospects. The advantages limitations and efficiency of the CO2 conversion technology to value-added products are grouped into chemical (plasma catalysis electrochemical and photochemical) and biological (photosynthetic and non-photosynthetic). The paper concludes by analyzing pathways to decarbonize the energy sector in Qatar via coupling CCC technologies for low-carbon hydrogen highlighting the challenges and research gaps.
A 500 kW Hydrogen Fuel Cell-powered Vessel: From Concept to Sailing
Sep 2024
Publication
This paper presents the “Three Gorges Hydrogen Boat No. 1” a novel green hydrogen-powered vessel that has been successfully delivered and is currently sailing. This vessel integrated with a hydrogen production and bunkering station at its dedicated dock achieves zero-carbon emissions. It stores 240 kg of 35 MPa gaseous hydrogen and has a fuel cell system rated at 500 kW. We analysed the engineering details of the marine hydrogen system including hydrogen bunkering storage supply fuel cell and the hybrid power system with lithium-ion batteries. In the first bunkering trial the vessel was safely refuelled with 200 kg of gaseous hydrogen in 156 min via a bunkering station 13 m above the water surface. The maximum hydrogen pressure and temperature recorded during bunkering were 35.05 MPa and 39.04 ◦C respectively demonstrating safe and reliable shore-toship bunkering. For the sea trial the marine hydrogen system operated successfully during a 3-h voyage achieving a maximum speed of 28.15 km/h (15.2 knots) at rated propulsion power. The vessel exhibited minimal noise and vibration and its dynamic response met load change requirements. To prevent rapid load changes to the fuel cells 68 s were used to reach 483 kW from startup and 62 s from 480 kW to zero. The successful bunkering and operation of this hydrogen-powered vessel demonstrates the feasibility of zero-carbon emission maritime transport. However four lessons were identified concerning bunkering speed hydrogen cylinder leakage hydrogen pressure regulator malfunctions and fuel cell room space. The novelty of this work lies in the practical demonstration of a fully operational hydrogen-powered maritime vessel achieving zero emissions encompassing its design building operation and lessons learned. These parameters and findings can be used as a baseline for further engineering research.
Modelling Guided Energy Management System for a Hydrogen-fuelled Harbour Tug
May 2024
Publication
The use of hydrogen as a source of fuel for marine applications is relatively nascent. As the maritime industry pivots to the use of alternate low and zero-emission fuels to adapt to a changing regulatory landscape hydrogen energy needs to present and substantiate a technical and commercially viable use case to secure its value proposition in the future fuel mix. This paper leverages the technoeconomic and environmental assessment previously performed on HyForce a hydrogen-fuelled harbour tug which has shown encouraging results for both technical and commercial aspects. This study aims to create a digital twin of HyForce to accurately predict her operability in real-world scenarios. The results from this study identify the strengths and drawbacks of the proposed use case. This is achieved by embedding the detailed design of HyForce in a virtual environment to further evaluate its operational performance through Computational Fluid Dynamics (CFD) simulations of realistic environmental conditions such as wind wave sea currents and friction attributed to the properties of seawater. The results from this study indicate a base case power requirement of 93 kW to 1892 kW to achieve speeds of 5 to 12 knots in the absence of external environmental influences. Consequently the speed of HyForce has a profound impact on total resistance peaking at 97.3 kN at 12 knots. Seawater properties such as low seawater temperature of 0C and a high salinity of 50g/kg increased friction. Additionally wind speeds of 10 m/s acting on HyForce delivered a resistance of 3 kN. However these will be well mitigated through the design of the propulsion system which will be able to deliver a thrust power of 1892 kW and with assistance from the energy storage systems produce 2 MW of power to overcome the resistance experienced. The findings presented in this paper can serve as a foundation for constructing a robust model for the development of a predictive controller for future work. This controller has the potential to optimize the configuration of hydrogen and battery energy storage aligning with desired cost functions.
Renewable Electricity and Green Hydrogen Integration for Decarbonization of “Hard-to-Abate” Industrial Sectors
Jul 2024
Publication
This paper investigates hydrogen’s potential to accelerate the energy transition in hardto-abate sectors such as steel petrochemicals glass cement and paper. The goal is to assess how hydrogen produced from renewable sources can foster both industrial decarbonization and the expansion of renewable energy installations especially solar and wind. Hydrogen’s dual role as a fuel and a chemical agent for process innovation is explored with a focus on its ability to enhance energy efficiency and reduce CO2 emissions. Integrating hydrogen with continuous industrial processes minimizes the need for energy storage making it a more efficient solution. Advances in electrolysis achieving efficiencies up to 60% and storage methods consuming about 10% of stored energy for compression are discussed. Specifically in the steel sector hydrogen can replace carbon as a reductant in the direct reduced iron (DRI) process which accounts for around 7% of global steel production. A next-generation DRI plant producing one million tons of steel annually would require approximately 3200 MW of photovoltaic capacity to integrate hydrogen effectively. This study also discusses hydrogen’s role as a co-fuel in steel furnaces. Quantitative analyses show that to support typical industrial plants hydrogen facilities of several hundred to a few thousand MW are necessary. “Virtual” power plants integrating with both the electrical grid and energy-intensive systems are proposed highlighting hydrogen’s critical role in industrial decarbonization and renewable energy growth.
A Novel Hydrogen Supply Chain Optimization Model - Case Study of Texas and Louisiana
Jun 2024
Publication
The increasing political momentum advocating for decarbonization efforts has led many governments around the world to unveil national hydrogen strategies. Hydrogen is viewed as a potential enabler of deep decarbonization notably in hard-to-abate sectors such as the industry. A multi-modal hourly resolved linear programming model was developed to assess the infrastructure requirements of a low-carbon supply chain over a large region. It optimizes the deployment of infrastructure from 2025 up to 2050 by assessing four years: 2025 2030 2040 and 2050 and is location agnostic. The considered infrastructure encompasses several technologies for production transmission and storage. Model results illustrate supply chain requirements in Texas and Louisiana. Edge cases considering 100% electrolytic production were analyzed. Results show that by 2050 with an assumed industrial demand of 276 TWh/year Texas and Louisiana would require 62 GW of electrolyzers 102 GW of onshore wind and 32 GW of solar panels. The resulting levelized cost of hydrogen totaled $5.6–6.3/kgH2 in 2025 decreasing to $3.2–3.5/ kgH2 in 2050. Most of the electricity production occurs in Northwest Texas thanks to high capacity factors for both renewable technologies. Hydrogen is produced locally and transmitted through pipelines to demand centers around the Gulf Coast instead of electricity being transmitted for electrolytic production co-located with demand. Large-scale hydrogen storage is highly beneficial in the system to provide buffer between varying electrolytic hydrogen production and constant industrial demand requirements. In a system without low-cost storage liquid and compressed tanks are deployed and there is a significant renewable capacity overbuild to ensure greater electrolyzer capacity factors resulting in higher electricity curtailment. A system under carbon constraint sees the deployment of natural gas-derived hydrogen production. Lax carbon constraint target result in an important reliance on this production method due to its low cost while stricter targets enforce a great share of electrolytic production.
Current Status of Green Hydrogen Production Technology: A Review
Oct 2024
Publication
As a clean energy source hydrogen not only helps to reduce the use of fossil fuels but also promotes the transformation of energy structure and sustainable development. This paper firstly introduces the development status of green hydrogen at home and abroad and then focuses on several advanced green hydrogen production technologies. Then the advantages and shortcomings of different green hydrogen production technologies are compared. Among them the future source of hydrogen tends to be electrolysis water hydrogen production. Finally the challenges and application prospects of the development process of green hydrogen technology are discussed and green hydrogen is expected to become an important part of realizing sustainable global energy development.
Evaluating the Economic Influence of Water Sources on Green Hydrogen Production: A Cost Analysis Approach
Sep 2024
Publication
The production of green hydrogen requires significant water usage making the economic evaluation of different water sources crucial for optimizing the Levelized Cost of Hydrogen (LCOH). This study examines the economic impact of using seawater groundwater grid water industrial wastewater and rainwater for hydrogen production through PEM electrolysis considering the water abstraction transport treatment and storage costs across various plant sizes (1 MW 10 MW 20 MW 50 MW and 100 MW) were assessed and a sensitivity analysis on electricity prices was conducted. Findings reveal that while water-related costs are minimal.
Transitioning to Sustainable Economic Resilience through Renewable Energy and Green Hydrogen: The Case of Iraq
Sep 2024
Publication
The study investigates the potential of transitioning Iraq a nation significantly dependent on fossil fuels toward a green hydrogen-based energy system as a pathway to achieving sustainable economic resilience. As of 2022 Iraqi energy supply is over 90% reliant on hydrocarbons which also account for 95% of the country foreign exchange earnings. The global energy landscape is rapidly shifting towards cleaner alternatives and the volatility of oil prices has made it imperative for the country to diversify its energy sources. Green hydrogen produced through water electrolysis powered by renewable energy sources such as solar and wind offers a promising alternative given country vast renewable energy potential. The analysis indicates that with strategic investments in green hydrogen infrastructure the country could reduce its hydrocarbon dependency by 30% by the year 2030. This transition could not only address pressing environmental challenges but also contribute to the economic stability of the country. However the shift to green hydrogen is not without significant challenges including water scarcity technological limitations and the necessity for a robust regulatory framework. The findings underscore the importance of international partnerships and supportive policies in facilitating this energy transition. Adopting renewable energy and green hydrogen technologies the country has the potential to become a leader in sustainable energy within the region. This shift would not only drive economic growth and energy security but also contribute to global efforts towards environmental sustainability positioning country favorably in a future low-carbon economy.
Techno-economic Assessment of Hydrogen Supply Solutions for Industrial Site
Sep 2024
Publication
In Austria one of the highest priorities of hydrogen usage lies in the industrial sector particularly as a feedstock and for high-temperature applications. Connecting hydrogen producers with consumers is challenging and requires comprehensive research to outline the advantages and challenges associated with various hydrogen supply options. This study focuses on techno-economic assessment of different supply solutions for industrial sites mainly depicted in two categories: providing hydrogen by transport means and via on-site production. The technologies needed for the investigation of these scenarios are identified based on the predictions of available technologies in near future (2030). The transportation options analyzed include delivering liquid hydrogen by truck liquid hydrogen by railway and gaseous hydrogen via pipeline. For on-site low-carbon hydrogen production a protonexchange membrane (PEM) electrolysis was selected as resent research suggests lower costs for PEM electrolysis compared to alkaline electrolysis (AEL). The frequency of deliveries and storage options vary by scenario and are determined by the industrial demand profile transport capacity and electrolyser production capacity. The assessment evaluates the feasibility and cost-effectiveness of each option considering factors such as infrastructure requirements energy efficiency and economic viability. At a hydrogen demand of 80 GWh the transport options indicate hydrogen supply costs in the range of 14–24 ct/kWh. In contrast the scenarios investigating on-site production of hydrogen show costs between 29 and 49 ct/ kWh. Therefore transport by truck rail or pipeline is economically advantageous to own-production under the specific assumptions and conditions. However the results indicate that as energy demand increases on-site production becomes more attractive. Additionally the influence of electricity prices and the hydrogen production/import price were identified as decisive factors for the overall hydrogen supply costs.
Solar Hydrogen Production and Storage in Solid Form: Prospects for Materials and Methods
Sep 2024
Publication
Climatic changes are reaching alarming levels globally seriously impacting the environment. To address this environmental crisis and achieve carbon neutrality transitioning to hydrogen energy is crucial. Hydrogen is a clean energy source that produces no carbon emissions making it essential in the technological era for meeting energy needs while reducing environmental pollution. Abundant in nature as water and hydrocarbons hydrogen must be converted into a usable form for practical applications. Various techniques are employed to generate hydrogen from water with solar hydrogen production—using solar light to split water—standing out as a cost-effective and environmentally friendly approach. However the widespread adoption of hydrogen energy is challenged by transportation and storage issues as it requires compressed and liquefied gas storage tanks. Solid hydrogen storage offers a promising solution providing an effective and low-cost method for storing and releasing hydrogen. Solar hydrogen generation by water splitting is more efficient than other methods as it uses self-generated power. Similarly solid storage of hydrogen is also attractive in many ways including efficiency and cost-effectiveness. This can be achieved through chemical adsorption in materials such as hydrides and other forms. These methods seem to be costly initially but once the materials and methods are established they will become more attractive considering rising fuel prices depletion of fossil fuel resources and advancements in science and technology. Solid oxide fuel cells (SOFCs) are highly efficient for converting hydrogen into electrical energy producing clean electricity with no emissions. If proper materials and methods are established for solar hydrogen generation and solid hydrogen storage under ambient conditions solar light used for hydrogen generation and utilization via solid oxide fuel cells (SOFCs) will be an efficient safe and cost-effective technique. With the ongoing development in materials for solar hydrogen generation and solid storage techniques this method is expected to soon become more feasible and cost-effective. This review comprehensively consolidates research on solar hydrogen generation and solid hydrogen storage focusing on global standards such as 6.5 wt% gravimetric capacity at temperatures between −40 and 60 ◦C. It summarizes various materials used for efficient hydrogen generation through water splitting and solid storage and discusses current challenges in hydrogen generation and storage. This includes material selection and the structural and chemical modifications needed for optimal performance and potential applications.
Techno-economics of Renewable Hydrogen Export: A Case Study for Australia-Japan
Jul 2024
Publication
The shift from fossil fuels to clean energy carriers such as renewable H2 is imminent. Consequently a global H2 market is taking shape involving countries with limited or insufficient energy resources importing from renewable-rich countries. This study evaluates the techno-economics of renewable hydrogen (H2) export in a globally significant scenario in which Australia exports to Japan. To gain insight into the immediate realisable future the base year was selected as 2030 with a consequently small (in export terms) hydrogen production rate of 100 t/day landed capacity. Electricity was generated by photovoltaic arrays (PV) connected directly to proton exchange membrane (PEM) electrolyser plant allowing for flexible gaseous hydrogen (GH2) production. To enhance the fidelity of the technoeconomic model we incorporated rarely applied but impactful parameters including dynamic efficiency and the overload capacity of PEM electrolysers. The GH2 produced was assumed to be converted into condensed forms suitable for export by sea: liquid hydrogen (LH2) and the chemical carriers liquid ammonia (LNH3) methanol (MeOH) methylcyclohexane (MCH). These were assumed to be reconverted to GH2 at the destination. LNH3 and MCH emerged as promising carriers for export yielding the lowest landed levelised cost of hydrogen (LCOH). LH2 yielded the highest LCOH unless boiloff gas could be managed effectively and cheaply. A sensitivity analysis showed that a lower weighted average cost of capital (WACC) and scale-up can significantly reduce the landed LCOH. Increasing the production rate to 1000 t/day landed capacity very significantly lowered the landed LCOH providing a strong incentive to scale up and optimise the entire supply chain as fast as possible.
Hydrogen as an Energy Source: A Review of Production Technologies and Challenges of Fuel Cell Vehicles
Oct 2024
Publication
The significant growth of both the global population and economy in recent years has led to a rise in global energy demand. Fossil fuels have a significant contribution to generating energy which has raised concerns about sustainability and environmental impact. There are widespread efforts to find alternative sources in order to reduce dependence on fossil fuels and mitigate their environmental consequences. Among the alternative sources hydrogen has emerged as a promising option due to its potential to be a clean and sustainable energy source. Hydrogen possesses several advantages such as a high calorific value a high reaction rate various sources and the ability to integrate with other renewable energy sources and existing systems. These attributes render hydrogen a stable and reliable energy resource which can help reduce greenhouse gas emissions (GHG) and transition towards a sustainable future. In this review paper distinct hydrogen production technologies such as conventional renewable and nuclear energy are investigated and compared. In addition the challenges and limitations of the application of hydrogen fuel cells on vehicles and hydrogen circulation components are explored. Finally the environmental impact of hydrogen vehicles specifically their role in promoting sustainable development is investigated.
Renewable Fuel Production and the Impact of Hydrogen Infrastructure - A Case Study of the Nordics
Apr 2024
Publication
Hard-to-electrify sectors will require renewable fuels to facilitate the green transition in the future. Therefore it is crucial to identify promising production locations while taking into account the local biomass resources variable renewable energy sources and the synergies between sectors. In this study investments and dispatch operations are optimised of a large catalogue of renewable fuel production technologies in the opensource software SpineOpt and this is soft-linked to the comprehensive energy system model Balmorel. We analyse future production pathways by comparing various levels of hydrogen infrastructure including large-scale hydrogen storage and assess system impacts. The results indicate that methanol may provide synergies in its multipurpose use as an early (2030-2040) shipping fuel and later as an aviation fuel through further refining if ammonia becomes more competitive (2050). We furthermore show that a hydrogen infrastructure increases the competitiveness of non-flexible hydrogen-based fuel production technologies. Offshore electrolysis hubs decrease energy system impacts in scenarios with 105 TWh of Nordic hydrogen export. However hydrogen export scenarios are much costlier compared to scenarios with no export unless a high hydrogen price is received. Finally we find that emission taxes in the range of 250-265 euro/tCO2 will be necessary for renewable fuels to become competitive.
Design Considerations and Preliminary Hydrodynamic Analysis of an Offshore Decentralised Floating Wind-hydrogen System
Sep 2024
Publication
Despite the number of works on the techno-economics of offshore green hydrogen production there is a lack of research on the design of floating platforms to concomitantly support hydrogen production facilities and wind power generation equipment. Indeed previous studies on offshore decentralised configuration for hydrogen production implicitly assume that a floating platform designed for wind power generation (FOWT) can be also suitable as a floating wind hydrogen system (FWHS). This work proposes a novel design for an offshore decentralised FWHS and analyses the effects of the integration of the hydrogen facilities on the platform’s dynamics and how this in turn affects the performances of the wind turbine and the hydrogen equipment. Our findings indicate that despite the reduction in platform’s stability the performance of the wind turbine is barely affected. Regarding the hydrogen system our results aim at contributing to further assessment and design of this equipment for offshore conditions.
Environmental and Climate Impacts of a Large-scale Deployment of Green Hydrogen in Europe
Apr 2024
Publication
Green hydrogen is expected to play a vital role in decarbonizing the energy system in Europe. However large-scale deployment of green hydrogen has associated potential trade-offs in terms of climate and other environmental impacts. This study aims to shed light on a comprehensive sustainability assessment of this large-scale green hydrogen deployment based on the EMPIRE energy system modeling compared with other decarbonization paths. Process-based Life Cycle Assessment (LCA) is applied and connected with the output of the energy system model revealing 45% extra climate impact caused by the dedicated 50% extra renewable infrastructure to deliver green hydrogen for the demand in the sectors of industry and transport in Europe towards 2050. Whereas the analysis shows that green hydrogen eventually wins on the climate impact within four designed scenarios (with green hydrogen with blue hydrogen without green hydrogen and baseline) mainly compensated by its clean usage and renewable electricity supply. On the other hand green hydrogen has a lower performance in other environmental impacts including human toxicity ecotoxicity mineral use land use and water depletion. Furthermore a monetary valuation of Life Cycle Impact (LCI) is estimated to aggregate 13 categories of environmental impacts between different technologies. Results indicate that the total monetized LCI cost of green hydrogen production is relatively lower than that of blue hydrogen. In overview a large-scale green hydrogen deployment potentially shifts the environmental pressure from climate and fossil resource use to human health mineral resource use and ecosystem damage due to its higher material consumption of the infrastructure.
Detailed Analysis of a Pure Hydrogen-fueled Dual-fuel Engine in Terms of Performance and Greenhouse Gas Emissions
Sep 2024
Publication
The current study seeks to greenhouse gas emissions reduction in an existing engine under dual-fuel combustion fueled with diesel fuel and natural gas due to great concerns about global warming. This simulation study focuses on the identification of areas prone to the formation of greenhouse gas emissions in engine cylinders. The simulation results of dual-fuel combustion confirmed that the possibility of incomplete combustion and the formation of greenhouse gas emissions in high levels are not far from expected. Therefore an efficient combustion strategy along with replacing natural gas with hydrogen was considered. Only changing the combustion mode to reactivity-controlled compression ignition has led to the improvement of the natural gas burning rate and guarantees a 32 % reduction in unburned methane and 50 % carbon monoxide. To further reduce engine emissions while changing the combustion mode a part of natural gas replacement with hydrogen to the complete elimination of it was evaluated. Increasing the share of hydrogen energy in the intake air-natural gas mixture up to 54 % without exhaust gas recirculation does not lead to diesel knock. Moreover improvement of engine load and efficiency can be achieved by up to 18 % and 6 % respectively. Natural gas consumption can be reduced by up to 67 %. Meanwhile the unburned methane and carbon dioxide mass known as greenhouse gas emissions can be reduced to less than 1 % and up to 50 % respectively. Continued replacement of natural gas with hydrogen until its complete elimination guarantees a reduction of 92000 cubic meters of natural gas per year in one engine cylinder. Although the engine efficiency and load face a decrease of 0.8 % and 5.0 % respectively; the amount of carbon dioxide can be decreased by about 4.5 times. Unburned methane carbon monoxide and nitrogen oxides can be reduced to below the relevant EURO VI range while the amount of unburned hydrogen compared to the hydrogen entering the engine is about 0.5 %.
Advancing Life Cycle Assessment of Sustainable Green Hydrogen Production Using Domain-Specific Fine-Tuning by Large Language Models Augmentation
Nov 2024
Publication
Assessing the sustainable development of green hydrogen and assessing its potential environmental impacts using the Life Cycle Assessment is crucial. Challenges in LCA like missing environmental data are often addressed using machine learning such as artificial neural networks. However to find an ML solution researchers need to read extensive literature or consult experts. This research demonstrates how customised LLMs trained with domain-specific papers can help researchers overcome these challenges. By starting small by consolidating papers focused on the LCA of proton exchange membrane water electrolysis which produces green hydrogen and ML applications in LCA. These papers are uploaded to OpenAI to create the LlamaIndex enabling future queries. Using the LangChain framework researchers query the customised model (GPT-3.5-turbo) receiving tailored responses. The results demonstrate that customised LLMs can assist researchers in providing suitable ML solutions to address data inaccuracies and gaps. The ability to quickly query an LLM and receive an integrated response across relevant sources presents an improvement over manually retrieving and reading individual papers. This shows that leveraging fine-tuned LLMs can empower researchers to conduct LCAs more efficiently and effectively.
Performance Comparison of Hydrogen Dispersion Models in Enclosure Adapted to Forced Ventilation
Sep 2023
Publication
In confined spaces hydrogen released with low momentum tends to accumulate in a layer below the ceiling; the concentration in this layer rises and can rapidly enter the flammability range. In this context ventilation is a key safety equipment to prevent the formation of such flammable volumes. To ensure its well-sizing to each specific industrial context it is necessary to dispose of reliable engineering models. Currently the existing engineering models dealing with the buoyancy-driven H2 dispersion in a ventilated enclosure mainly focus on the natural-ventilation phenomenon. However forced ventilation is in some situations more adapted to the industrial context as the wind direction and intensity remains constant and under control. Therefore two existing wind-assisted ventilation models elaborated by Hunt and Linden [1] and Lowesmith et al. [2] were tested on forced ventilation applications. The main assumption consists in assuming a blowing ventilation system rather than a suction system as the composition and velocity of the entering air are known. The fresh air enters the down opening and airhydrogen mixture escapes through the upper one. The adapted models are then validated with experimental data releasing helium rather than hydrogen. Experiments are conducted on a 1-m3 ventilated box controlling the release and ventilation rates. The agreement between both analytical and experimental results is discussed from the different comparisons performed.
Future of Hydrogen in the U.S. Energy Sector: MARKAL Modeling Results
Mar 2024
Publication
Hydrogen is an attractive energy carrier which could play a role in decarbonizing process heat power or transport applications. Though the U.S. already produces about 10 million metric tons of H2 (over 1 quadrillion BTUs or 1% of the U.S. primary energy consumption) production technologies primarily use fossil fuels that release CO2 and the deployment of other cleaner H2 production technologies is still in the very early stages in the U.S. This study explores (1) the level of current U.S. hydrogen production and demand (2) the importance of hydrogen to accelerate a net-zero CO2 future and (3) the challenges that must be overcome to make hydrogen an important part of the U.S. energy system. The study discusses four scenarios and hydrogen production has been shown to increase in the future but this growth is not enough to establish a hydrogen economy. In this study the characteristics of hydrogen technologies and their deployments in the long-term future are investigated using energy system model MARKAL. The effects of strong carbon constraints do not cause higher hydrogen demand but show a decrease in comparison to the business-as-usual scenario. Further according to our modeling results hydrogen grows only as a fuel for hard-to-decarbonize heavy-duty vehicles and is less competitive than other decarbonization solutions in the U.S. Without improvements in reducing the cost of electrolysis and increasing the performance of near-zero carbon technologies for hydrogen production hydrogen will remain a niche player in the U.S. energy system in the long-term future. This article provides the reader with a comprehensive understanding of the role of hydrogen in the U.S. energy system thereby explaining the long-term future projections.
Hydrogen Embrittlement Behaviors During SSRT Tests in Gaseous Hydrogen for Cold-word Type 316 Austenitic Stainless Steel and Iron-based Supperalloy A286 Used in Hydrogen Refueling Station
Feb 2024
Publication
To consider an appropriate evaluation method for hydrogen compatibility slow strain rate tensile (SSRT) tests were conducted on high strength piping materials cold-worked type 316 austenitic stainless steel (SUS316CW) and iron-based superalloy A286 used in hydrogen stations for two years.<br/>SUS316CW used at room temperature in 82 MPa gaseous hydrogen contained 7.8 mass ppm hydrogen. The SSRT test of SUS316CW was conducted in nitrogen at -40 °C. The fracture surface showed dimples and no hydrogen embrittlement behavior was observed. While the SSRT test of SUS316CW in 70 MPa gaseous hydrogen at -40 °C showed a slight decrease in reduction area and a brittle fracture morphology in the outer layer. This was considered to be the effect of high-pressure gaseous hydrogen during the SSRT test in addition to the pre-contained hydrogen.<br/>A286 used at -40 °C in 82 MPa gaseous hydrogen contained negligible hydrogen (0.14 mass ppm). SSRT tests were conducted at 150 °C in 70 MPa gaseous hydrogen and in air and showed a low relative reduction in area (RRA) value. To investigate the decrease in the RRA we switched the gas from hydrogen to air in the middle of the SSRT test and closely examined the RRA values and fracture morphology including side cracks. The hydrogen embrittlement was found to originate from the elastic deformation region. Stress cycling in the elastic deformation region also accelerated the effect of hydrogen. These were attributed to an increase in the lattice hydrogen content. While in the plastic deformation region hydrogen trapped in the defects and hydrogen through the generated surface cracks increased the hydrogen content at the crack tips reducing the RRA value. And there was a good correlation between the crack lengths and RRA values.<br/>Then hydrogen embrittlement mechanism depends on the operating conditions (stress and temperature) of the material and evaluating the hydrogen compatibility of materials by controlling their hydrogen content and strain according to the service environment is desirable.
Design and Analysis of Hydrogen Storage Tank with Different Materials by Ansys
Dec 2019
Publication
Pressure vessels are used for large commercial and industrial applications such as softening filtration and storage. It is expected that high-pressure hydrogen storage vessels will be widely used in hydrogen-fuelled vehicles. Progressive failure properties the burst pressure and fatigue life should be taken into account in the design of composite pressure vessels. In this work the model and analysis of hydrogen storage vessels along with complete structural and thermal analysis. Liquid hydrogen is seen as an outstanding candidate for the fuel of high altitude long-endurance unmanned aircraft. The design of lightweight and super-insulated storage tanks for cryogenic liquid hydrogen is since long identified as crucial to enable the adoption of the liquid hydrogen. The basic structural design of the airborne cryogenic liquid hydrogen tank was completed in this paper. The problem of excessive heat leakage of the traditional support structure was solved by designing and using a new insulating support structure. The thermal performance of the designed tank was evaluated. The structure of the tank was analyzed by the combination of the film container theory and finite element numerical simulation method. The structure of the adiabatic support was analyzed by using the Hertz contact theory and numerical simulation method. A simple and effective structure analysis method for a similar container structure and point-contact support structure was provided. Bases for further structural optimization design of hydrogen tank will be provided also. The analysis will be carried out with different materials like titanium nickel alloy and some coated powders like alumina Titania and zirconium oxide. The results will be compared with that.
Accidental Releases of Hydrogen in Maintenance Garages: Modelling and Assessment
Sep 2023
Publication
This study investigates the light gas dispersion behaviour in a maintenance garage with natural or forced ventilation. A scaled-down garage model (0.71 m high 3.07 m long and 3.36 m wide) equipped with gas and velocity sensors was used in the experiments. The enclosure had four rectangular vents at the ceiling and four at the bottom on two opposing side walls. The experiments were performed by injecting helium continuously through a 1-mm downward-facing nozzle until a steady state was reached. The sensitivity parameters included helium injection rate the elevation of the injection nozzle and forced flow speeds. Exhaust fans were placed at one or all of the top vent(s) to mimic forced ventilation. Numerical simulations conducted using GOTHIC a general-purpose thermal-hydraulic code and calculations with engineering models were compared with experimental measurements to determine the relative suitability of each approach to predict the light gas transport behaviour. The GOTHIC simulations captured the trends of the helium distribution gas movement in the enclosure and the passive vent flows reasonably well. Lowesmith’s model predictions for the helium transients in the upper uniform layer were also in good agreement with the natural venting experiments.
Hydrogen UK Manifesto
Jul 2024
Publication
Hydrogen presents the UK with a substantial opportunity to drive economic growth and secure skilled jobs by leveraging our natural geological and geographical advantages robust supply chain and existing energy expertise. Hydrogen UK’s most recent Economic Impact Assessment estimates that the hydrogen sector in the UK could support approximately 30000 direct jobs and contribute more than £7 billion gross value added annually by 2030. On a global scale the hydrogen market is projected to be worth $2.5 trillion by 2050.
With international competition increasing the UK must act now to capitalise on this potential. These projections are supported by a recognition that hydrogen is one of the key solutions to decarbonising the UK economy complementing other low-carbon solutions such as electrification carbon capture biofuels and energy efficiency. Additionally hydrogen will play a vital role in enhancing the UK’s energy security by storing domestically produced energy to balance intermittent renewable sources like wind and solar. As a critical component of the clean energy transition hydrogen is indispensable to achieving net zero.
As it stands the UK is well placed to capitalise on the hydrogen opportunity and emerge as a global leader. We have made early strides in establishing a framework for hydrogen development with various pilot projects and strategic investments already underway. However the next five years will be critical for the sector as we move from strategy and planning to development and delivery. It is imperative to get the first lowcarbon production projects over the line and into construction as a matter of urgency and then deliver substantial infrastructure development regulatory clarity and sustained financial support to scale-up production and distribution. A new Government presents an opportunity for policymakers to solidify commitments and accelerate the deployment of hydrogen technology ensuring the UK remains competitive in the global race.
Our manifesto outlines policy recommendations for the new UK Government to take across production distribution and storage infrastructure end use applications trade and beyond which will support a thriving British industrial base that creates jobs and growth for British people. To achieve this the UK hydrogen industry calls on policymakers to speed up the deployment of hydrogen through the recommendations set out in this Manifesto.
This report can be found on Hydrogen UK's website.
With international competition increasing the UK must act now to capitalise on this potential. These projections are supported by a recognition that hydrogen is one of the key solutions to decarbonising the UK economy complementing other low-carbon solutions such as electrification carbon capture biofuels and energy efficiency. Additionally hydrogen will play a vital role in enhancing the UK’s energy security by storing domestically produced energy to balance intermittent renewable sources like wind and solar. As a critical component of the clean energy transition hydrogen is indispensable to achieving net zero.
As it stands the UK is well placed to capitalise on the hydrogen opportunity and emerge as a global leader. We have made early strides in establishing a framework for hydrogen development with various pilot projects and strategic investments already underway. However the next five years will be critical for the sector as we move from strategy and planning to development and delivery. It is imperative to get the first lowcarbon production projects over the line and into construction as a matter of urgency and then deliver substantial infrastructure development regulatory clarity and sustained financial support to scale-up production and distribution. A new Government presents an opportunity for policymakers to solidify commitments and accelerate the deployment of hydrogen technology ensuring the UK remains competitive in the global race.
Our manifesto outlines policy recommendations for the new UK Government to take across production distribution and storage infrastructure end use applications trade and beyond which will support a thriving British industrial base that creates jobs and growth for British people. To achieve this the UK hydrogen industry calls on policymakers to speed up the deployment of hydrogen through the recommendations set out in this Manifesto.
This report can be found on Hydrogen UK's website.
A Prospective Approach to the Optimal Deployment of a Hydrogen Supply Chain for Sustainable Mobility in Island Territories: Application to Corsica
Oct 2024
Publication
This study develops a framework for designing hydrogen supply chains (HSC) in island territories using Mixed Integer Linear Programming (MILP) with a multi-period approach. The framework minimizes system costs greenhouse gas emissions and a risk-based index. Corsica is used as a case study with a Geographic Information System (GIS) identifying hydrogen demand regions and potential sites for production storage and distribution. The results provide an optimal HSC configuration for 2050 specifying the size location and technology while accounting for techno-economic factors. This work integrates the unique geographical characteristics of islands using a GIS-based approach incorporates technology readiness levels and utilizes renewable electricity from neighboring regions. The model proposes decentralized configurations that avoid hydrogen transport between grids achieving a levelized cost of hydrogen (LCOH) of €8.54/kg. This approach offers insight into future options and incentive mechanisms to support the development of hydrogen economies in isolated territories.
The Competitive Edge of Norway's Hydrogen by 2030: Socio-environmental Considerations
Aug 2024
Publication
Can Norway be an important hydrogen exporter to the European Union (EU) by 2030? We explore three scenarios in which Norway’s hydrogen export market may develop: A Business-as-usual B Moderate Onshore C Accelerated Offshore. Applying a sector-coupled energy system model we examine the techno-economic viability spatial and socio-economic considerations for blue and green hydrogen export in the form of ammonia by ship. Our results estimate the costs of low-carbon hydrogen to be 3.5–7.3€/kg hydrogen. While Norway may be cost-competitive in blue hydrogen exports to the EU its sustainability is limited by the reliance on natural gas and the nascent infrastructure for carbon transport and storage. For green hydrogen exports Norway may leverage its strong relations with the EU but is less cost-competitive than countries like Chile and Morocco which benefit from cheaper solar power. For all scenarios significant land use is needed to generate enough renewable energy. Developing a green hydrogen-based export market requires policy support and strategic investments in technology infrastructure and stakeholder engagement ensuring a more equitable distribution of renewable installations across Norway and national security in the north. Using carbon capture and storage technologies and offshore wind to decarbonise the offshore platforms is a win-win solution that would leave more electricity for developing new industries and demonstrate the economic viability of these technologies. Finally for Norway to become a key hydrogen exporter to the EU will require a balanced approach that emphasises public acceptance and careful land use management to avoid costly consequences.
Determining Onshore or Offshore Hydrogen Storage for Large Offshore Wind Parks: The North Sea Wind Power Hub Case
Aug 2024
Publication
The large-scale integration of renewable energy sources leads to daily and seasonal mismatches between supply and demand and the curtailment of wind power. Hydrogen produced from surplus wind power offers an attractive solution to these challenges. In this paper we consider a large offshore wind park and analyze the need for hydrogen storage at the onshore and offshore sides of a large transportation pipeline that connects the wind park to the mainland. The results show that the pipeline with line pack storage though important for day-to-day fluctuations will not offer sufficient storage capacity to bridge seasonal differences. Furthermore the results show that if the pipeline is sufficiently sized additional storage is only needed on one side of the pipeline which would limit the needed investments. Results show that the policy which determines what part of the wind power is fed into the electricity grid and what part is converted into hydrogen has a significant influence on these seasonal storage needs. Therefore investment decisions for hydrogen systems should be made by considering both the onshore and offshore storage requirements in combination with electricity transport to the mainland.
Numerical Investigations of Hydrogen Release and Dispersion Due to Silane Decomposition in a Ventilated Container
Sep 2023
Publication
In recent years new chemical release agents based on silane are being used in the tire industry. Silane is an inorganic chemical compound consisting of a silicon backbone and hydrogen. Silanes can be thermally decomposed into high-purity silicon and hydrogen. If silane is stored and transported in Intermediate Bulk Containers (IBCs) equipped with safety valves in vented semi-confined spaces such as ISO-Containers hydrogen can be accumulated and become explosive mixture with air. A conservative CFD analysis using the GASFLOW-MPI code has been carried out to assess the hydrogen risk inside the vented containers. Two types of containers with different natural ventilation systems were investigated under various hypothetical accident scenarios. A continuous release of hydrogen due to the chemical decomposition of silane from IBCs was studied as the reference case. The effect of the safety valves on hydrogen accumulation in the container which results in small pulsed releases of hydrogen was investigated. The external effects of the sun and wind on hydrogen distribution and ventilation were also evaluated. The results can provide detailed information on hydrogen dispersion and mixing within the vented enclosures and used to evaluate the hydrogen risks such as flammability. Based on the assumptions used in this study it indicates that the geometry of ventilation openings plays a key role in the efficiency of the indoor air exchange process. In addition the use of safety valves makes it possible to reduce the concentration of hydrogen by volume in air compared to the reference case. The effect of the sun which results in a temperature difference between two container walls allows a strong mixing of hydrogen and air which helps to obtain a concentration lower than both the base case and the case of the pulsed releases. But the best results for the venting process are obtained with the wind that can drive the mixture to the downwind wall vent holes.
Green Hydrogen Production: Integrating Environmental and Social Criteria to Ensure Sustainability
Jul 2023
Publication
Hydrogen is experiencing an unprecedented global hype. Hydrogen is globally discussed as a possible future energy carrier and regarded as the urgently needed building block for the much needed carbon-neutral energy transition of hard-to-abate sectors to mitigate the effects of global warming. This article provides synthesised measurable sustainability criteria for analysing green hydrogen production proposals and strategies. Drawn from expert interviews and an extensive literature review this article proposes that a sustainable hydrogen production should consider six impact categories; Energy transition Environment Basic needs Socio-economy Electricity supply and Project planning. The categories are broken down into sixteen measurable sustainability criteria which are determined with related indicators. The article concludes that low economic costs can never be the only decisive criterion for the hydrogen production; social aspects must be integrated along the entire value chain. The compliance with the criteria may avoid social and ecological injustices in the planning of green hydrogen projects and increases inter alia the social welfare of the affected population.
Storage and Transportation Technology Solutions Selection for Large-scale Hydrogen Energy Utilization Scenarios under the Trend of Carbon Neutralization
Apr 2021
Publication
This paper mainly introduces the main pain point of China's civil hydrogen energy supply chain - the problem of storage and transportation and analyzes the safety economy and scale effect and other issues of the existing hydrogen energy storage and transportation compares with other storage and transportation technology solutions and comprehensively screens out the storage and transportation technology solution mainly based on liquid hydrogen technology. The liquid hydrogen technology solution has significant advantages over the existing compressed hydrogen system in terms of safety economy and scale effect especially for future large-scale hydrogen energy application scenarios. In addition the future hydrogen energy storage and transportation system based on liquid hydrogen technology can help improve the overall utilization efficiency of country’s renewable energy promote the country's energy transition promote the electrification of the country's transportation sector and help achieve China's carbon emission reduction 2030/2060 target.
Decarbonizing Hard-to-Abate Sectors with Renewable Hydrogen: A Real Case Application to the Ceramics Industry
Jul 2024
Publication
Hydrogen produced from renewable energy sources is a valuable energy carrier for linking growing renewable electricity generation with the hard-to-abate sectors such as cement steel glass chemical and ceramics industries. In this context this paper presents a new model of hydrogen production based on solar photovoltaics and wind energy with application to a real-world ceramics factory. For this task a novel multipurpose profit-maximizing model is implemented using GAMS. The developed model explores hydrogen production with multiple value streams that enable technical and economical informed decisions under specific scenarios. Our results show that it is profitable to sell the hydrogen produced to the gas grid rather than using it for self-consumption for low-gas-price scenarios. On the other hand when the price of gas is significantly high it is more profitable to use as much hydrogen as possible for self-consumption to supply the factory and reduce the internal use of natural gas. The role of electricity self-consumption has proven to be key for the project’s profitability as without this revenue stream the project would not be profitable in any analysed scenario.
Functional Resonance Analysis for Emerging Risks in Hydrogen Handling: An Analysis of an Experimental Test
Oct 2024
Publication
Hydrogen is on the rise as a substitute for fossil fuel in the energy sector. While this substitution does not happen dramatically the steady increase in hydrogen related research might be a good indicator of such desire. As it stands there are issues regarding its safe handling and use; consequently the health and safety subsectors observe the situation conspicuously. As we yet to know the behavior of hydrogen in critical situations uncertainties make these tasks prone to emerging risks. Thus hydrogen safety falls under emerging risk studies. Conventional perspective on safety especially regarding the flammable material focuses on calculating the hypothetical risks of failures in system. Resilience Engineering has another perspective as it focuses on normal operations offering new perspectives to tackle emerging risks from a new angle. Born from the heart of Resilience Engineering the Functional Resonance Analysis Method (FRAM) captures sociotechnical systems’ essence in a tangible way. In this study FRAM has been used to model a series of experiments done on hydrogen management to analyze its jet fire. FRAM is used to test whether the method could be suitable to model a system in which emerging risks are present. It is the conclusion of this study that FRAM seems promising in raising risk awareness especially when available data is limited.
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