Synergizing Water Desalination and Hydrogen Production using Solar Stills with Novel Sensible Heat Storage and an Alkaline Electrolyzer

This study tested a cogeneration (desalination/hydrogen production) system with natural and black sand as sensible heat storage, considering the thermal efficiencies, environmental impact, water quality, cost aspects, and hydrogen generation rate. The black sand-modified distiller attained the highest water production of 4645 mL, more than the conventional distiller by 1595 mL. It also offered better energy and exergy efficiencies of 45.26% and 3.72%, respectively, compared to 32.10% and 2.19% for the conventional one. Both modified distillers showed impressive improvements in water quality by significant reductions in total dissolved solids (TDS) from 29,300 mg/L to 60–61 mg/L. Moreover, the black sand-modified still reduced chemical oxygen demand (COD) to 135 mg/L. The production cost was minimized by using black sand to 0.0111$/L, higher than one-fifth in the case of the lab-based distiller. Regarding hydrogen production, the highest rate was obtained using distilled water from a labbased distiller of 0.742 gH₂/hr with an energy efficiency of 11.00%; however, it was not much higher than the case of black sand-modified still (0.736 gH₂/hr production rate and 10.91% efficiency). Moreover, the black sand-modified still showed the highest annual exergy output of 70.4 kWh/year, with a significant annual decarbonization of 1.69 ton-CO2.