Hydrogen Embrittlement Behaviors During SSRT Tests in Gaseous Hydrogen for Cold-word Type 316 Austenitic Stainless Steel and Iron-based Supperalloy A286 Used in Hydrogen Refueling Station

To consider an appropriate evaluation method for hydrogen compatibility, slow strain rate tensile (SSRT) tests were conducted on high strength piping materials, cold-worked type 316 austenitic stainless steel (SUS316CW) and iron-based superalloy A286, used in hydrogen stations for two years.
SUS316CW, used at room temperature in 82 MPa gaseous hydrogen, contained 7.8 mass ppm hydrogen. The SSRT test of SUS316CW was conducted in nitrogen at -40 °C. The fracture surface showed dimples, and no hydrogen embrittlement behavior was observed. While, the SSRT test of SUS316CW in 70 MPa gaseous hydrogen at -40 °C showed a slight decrease in reduction area and a brittle fracture morphology in the outer layer. This was considered to be the effect of high-pressure gaseous hydrogen during the SSRT test in addition to the pre-contained hydrogen.
A286, used at -40 °C in 82 MPa gaseous hydrogen, contained negligible hydrogen (0.14 mass ppm). SSRT tests were conducted at 150 °C in 70 MPa gaseous hydrogen and in air, and showed a low relative reduction in area (RRA) value. To investigate the decrease in the RRA, we switched the gas from hydrogen to air in the middle of the SSRT test and closely examined the RRA values and fracture morphology including side cracks. The hydrogen embrittlement was found to originate from the elastic deformation region. Stress cycling in the elastic deformation region also accelerated the effect of hydrogen. These were attributed to an increase in the lattice hydrogen content. While in the plastic deformation region, hydrogen trapped in the defects and hydrogen through the generated surface cracks increased the hydrogen content at the crack tips, reducing the RRA value. And there was a good correlation between the crack lengths and RRA values.
Then, hydrogen embrittlement mechanism depends on the operating conditions (stress and temperature) of the material, and evaluating the hydrogen compatibility of materials by controlling their hydrogen content and strain according to the service environment is desirable.