South Africa
Effect of a Ripple Current on the Efficiency of a PEM Electrolyser
Mar 2021
Publication
The aim of this study was to determine how the efficiency of a proton exchange membrane (PEM) electrolyser is affected by an electric ripple current and the different characteristics of the ripple current (frequency amplitude and waveform). This paper presents the experimental method and measured results used to analyse the effect of ripple currents at various frequencies ripple factors and waveforms on the hydrogen production power consumption and efficiency of a PEM electrolyser. An active laboratory-size PEM electrolysis system was used to investigate the impact of various ripple currents on the efficiency of the system. The results revealed that the average power consumption increases as the ripple factor increases and decreases as the frequency of the ripple increases while the waveform of the applied current has no effect. Furthermore the average hydrogen flow rate is unaffected by the ripple factor frequency or waveform of the applied ripple current.
Optimal Hybrid Renewable Energy System: A Comparative Study of Wind/Hydrogen/Fuel-Cell and Wind/Battery Storage
Dec 2020
Publication
This paper performs a technoeconomic comparison of two hybrid renewable energy supplies (HRES) for a specific location in Ghana and suggests the optimal solution in terms of cost energy generation capacity and emissions. (e two HRES considered in this paper were wind/hydrogen/fuel-cell and wind/battery storage respectively. (e necessity of this study was derived from the rise and expansion of hybrid renewable energy supply in a decentralised network. (e readiness to embrace these new technologies is apparently high but the best combination for a selected location that brings optimum benefits is not obvious and demands serious technical knowledge of their technical and economic models. In the methodology an analytical model of energy generation by the various RE sources was first established and data were collected about a rural-urban community in Doderkope Ghana to test the models. HOMER software was used to design the two hybrid systems based on the same load profiles and results were compared. It turns out that the HRES 1 (wind/hydrogen/fuel-cell) had the lowest net present cost (NPC) and levelized cost of electricity (COE) over the project life span of 25 years. (e energy reserve with the HRES 2 (wind/battery storage) was huge compared to that with the HRES 1 about 270% bigger. Furthermore with respect to the emissions the HRES 2 was environmentally friendlier than the HRES 1. Even though the battery storage seems to be more cost-effective than the hydrogen fuel cell technology the latter presents some merits regarding system capacity and emission that deserve greater attention as the world looks into more sustainable energy storage systems.
A Review of the Optimization Strategies and Methods Used to Locate Hydrogen Fuel Refueling Stations
Feb 2023
Publication
Increasing sales of conventional fuel-based vehicles are leading to an increase in carbon emissions which are dangerous to the environment. To reduce these conventional fuel-based vehicles must be replaced with alternative fuel vehicles such as hydrogen-fueled. Hydrogen can fuel vehicles with near-zero greenhouse gas emissions. However to increase the penetration of such alternative fuel vehicles there needs to be adequate infrastructure specifically refueling infrastructure in place. This paper presents a comprehensive review of the different optimization strategies and methods used in the location of hydrogen refueling stations. The findings of the review in this paper show that there are various methods which can be used to optimally locate refueling stations the most popular being the p-median and flow-capture location models. It is also evident from the review that there are limited studies that consider location strategies of hydrogen refueling stations within a rural setting; most studies are focused on urban locations due to the high probability of penetration into these areas. Furthermore it is apparent that there is still a need to incorporate factors such as the safety elements of hydrogen refueling station construction and for risk assessments to provide more robust realistic solutions for the optimal location of hydrogen refueling stations. Hence the methods reviewed in this paper can be used and expanded upon to create useful and accurate models for a hydrogen refueling network. Furthermore this paper will assist future studies to achieve an understanding of the extant studies on hydrogen refueling station and their optimal location strategies.
Forecasting Hydrogen Vehicle Refuelling for Sustainable Transportation: A Light Gradient-Boosting Machine Model
May 2024
Publication
Efficiently predicting and understanding refuelling patterns in the context of HFVs is paramount for optimising fuelling processes infrastructure planning and facilitating vehicle operation. This study evaluates several supervised machine learning methodologies for predicting the refuelling behaviour of HFVs. The LightGBM model emerged as the most effective predictive model due to its ability to handle time series and seasonal data. The selected model integrates various input variables encompassing refuelling metrics day of the week and weather conditions (e.g. temperature precipitation) to capture intricate patterns and relationships within the data set. Empirical testing and validation against real-world refuelling data underscore the efficacy of the LightGBM model demonstrating a minimal deviation from actual data given limited data and thereby showcasing its potential to offer valuable insights to fuelling station operators vehicle manufacturers and policymakers. Overall this study highlights the potential of sustainable predictive modelling for optimising fuelling processes infrastructure planning and facilitating vehicle operation in the context of HFVs.
A Techno-economic Assessment of the Viability of a Photovoltaic-wind-battery Storage-hydrogen Energy System for Electrifying Primary Healthcare Centre in Sub-Saharan Africa
Jun 2024
Publication
Healthcare facilities in isolated rural areas of sub-Saharan Africa face challenges in providing essential health services due to unreliable energy access. This study examines the use of hybrid renewable energy systems consisting of solar PV wind turbines batteries and hydrogen storage for the electrification of rural healthcare facilities in Nigeria and South Africa. The study deployed the efficacy of Hybrid Optimization of Multiple Energy Resources software for techno-economic analysis and the Evaluation based on the Distance from Average Solution method for multicriteria decision-making for sizing optimizing and selecting the optimal energy system. Results show that the optimal configurations achieve cost-effective levelized energy costs ranging from $0.336 to $0.410/kWh for both countries. For the Nigeria case study the optimal energy system includes 5 kW PV 10 kW fuel cell 10 kW inverter 10 kW electrolyzer and 16 kg hydrogen tank. South Africa's optimal configuration has 5 kW PV 10 kW battery 10 kW inverter and 7.5 kW rectifier. Solar PV provides more than 90% of energy with dual axis tracking yielding the highest output: 8889kWh/yr for Nigeria and 10470kWh/yr for South Africa. The multi-criteria decisionmaking analysis reveals that Nigeria's preferred option is the hybrid system without tracking. In contrast the horizontal axis weekly adjustment tracking configuration is optimal for South Africa considering technical economic and environmental criteria. The findings highlight the importance of context-specific optimization for hybrid renewable energy systems in rural healthcare facilities to accelerate Sustainable Development Goals 3 and 7.
Review on the Thermal Neutrality of Application-orientated Liquid Organic Hydrogen Carrier for Hydrogen Energy Storage and Delivery
Aug 2023
Publication
The depletion and overuse of fossil fuels present formidable challenge to energy supply system and environment. The human society is in great need of clean renewable and sustainable energy which can guarantee the long-term utilization without leading to escalation of greenhouse effect. Hydrogen as an extraordinary secondary energy is capable of realizing the target of environmental protection and transferring the intermittent primary energy to the application terminal while its nature of low volumetric energy density and volatility need suitable storage method and proper carrier. In this context liquid organic hydrogen carrier (LOHC) among a series of storage methods such as compressed and liquefied hydrogen provokes a considerable amount of research interest since it is proven to be a suitable carrier for hydrogen with safety and stability. However the dehydrogenation of hydrogen-rich LOHC materials is an endothermic process and needs large energy consumption which hampers the scale up of the LOHC system. The heat issue is thus essential to be addressed for fulfilling the potential of LOHC. In this work several strategies of heat intensification and management for LOHC system including the microwave irradiation circulation of exhaust heat and direct LOHC fuel cell are summarized and analyzed to provide suggestions and directions for future research.
An Overview of Application-orientated Multifunctional Large-scale Stationary Battery and Hydrogen Hybrid Energy Storage System
Dec 2023
Publication
The imperative to address traditional energy crises and environmental concerns has accelerated the need for energy structure transformation. However the variable nature of renewable energy poses challenges in meeting complex practical energy requirements. To address this issue the construction of a multifunctional large-scale stationary energy storage system is considered an effective solution. This paper critically examines the battery and hydrogen hybrid energy storage systems. Both technologies face limitations hindering them from fully meeting future energy storage needs such as large storage capacity in limited space frequent storage with rapid response and continuous storage without loss. Batteries with their rapid response (90%) excel in frequent short-duration energy storage. However limitations such as a selfdischarge rate (>1%) and capacity loss (~20%) restrict their use for long-duration energy storage. Hydrogen as a potential energy carrier is suitable for large-scale long-duration energy storage due to its high energy density steady state and low loss. Nevertheless it is less efficient for frequent energy storage due to its low storage efficiency (~50%). Ongoing research suggests that a battery and hydrogen hybrid energy storage system could combine the strengths of both technologies to meet the growing demand for large-scale long-duration energy storage. To assess their applied potentials this paper provides a detailed analysis of the research status of both energy storage technologies using proposed key performance indices. Additionally application-oriented future directions and challenges of the battery and hydrogen hybrid energy storage system are outlined from multiple perspectives offering guidance for the development of advanced energy storage systems.
Advances in Hydrogen-Powered Trains: A Brief Report
Sep 2023
Publication
The majority of rail vehicles worldwide use diesel as a primary fuel source. Diesel engine carbon emissions harm the environment and human health. Although railway electrification can reduce emissions it is not always the most economical option especially on routes with low vehicle demand. As a result interest in hydrogen-powered trains as a way to reduce greenhouse gas (GHG) emissions has steadily grown in recent years. In this paper we discuss advancements made in hydrogen-powered freight and commuter trains as well as the technology used in some aspects of hydrogen-powered vehicles. It was observed that hydrogen-powered trains are already in use in Europe and Asia unlike most developing countries in Africa. Commuter trains have received most of the research and development (R&D) attention but interest in hydrogen-powered freight trains has recently picked up momentum. Despite the availability and use of gray and blue hydrogen green hydrogen is still the preferred fuel for decarbonizing the rail transport sector.
Process Integration of Hydrogen Production Using Steam Gasification and Water-Gas Shift Reactions: A Case of Response Surface Method and Machine Learning Techniques
May 2024
Publication
An equilibrium-based steady-state simulator model that predicts and optimizes hydrogen production from steam gasification ofbiomass is developed using ASPEN Plus software and artificial intelligence techniques. Corn cob’s chemical composition wascharacterized to ensure the biomass used as a gasifier and with potential for production of hydrogen. Artificial intelligence is usedto examine the effects of the significant input variables on response variables such as hydrogen mole fraction and hydrogen energycontent. Optimizing the steam-gasification process using response surface methodology (RSM) considering a variety of biomass-steam ratios was carried out to achieve the best results. Hydrogen yield and the impact of main operating parameters wereconsidered. A maximum hydrogen concentration is found in the gasifier and water-gas shift (WGS) reactor at the highest steam-to-biomass (S/B) ratio and the lowest WGS reaction temperature while the gasification temperature has an optimum value. ANFISwas used to predict hydrogen of mole fraction 0.5045 with the input parameters of S/B ratio of 2.449 and reactor pressure andtemperature of 1 bar and 848°C respectively. With the steam-gasification model operating at temperature (850°C) pressure (1 bar)and S/B ratio of 2.0 an ASPEN simulator achieved a maximum of 0.5862 mole fraction of hydrogen while RSM gave an increaseof 19.0% optimum hydrogen produced over the ANFIS prediction with the input parameters of S/B ratio of 1.053 and reactorpressure and temperature of 1 bar and 850°C respectively. Varying the gasifier temperature and S/B ratio have on the other handa crucial effect on the gasification process with artificial intelligence as a unique tool for process evaluation prediction andoptimization to increase a significant impact on the products especially hydrogen.
Analysing the Prospects of Grid-connected Green Hydrogen Production in Predominantly Fossil-based Countries - A Case Study of South Africa
Aug 2024
Publication
Importing substantial amount of green hydrogen from countries like South Africa which have abundant solar and wind potentials to replace fossil fuels has attracted interest in developed regions. This study analyses South African strategies for improving and decarbonizing the power sector while also producing hydrogen for export. These strategies include the Integrated Resource Plan the Transmission Development Plan Just Energy Transition and Hydrogen Society Roadmap for grid connected hydrogen production in 2030. Results based on an hourly resolution optimisation in Plexos indicate that annual grid-connected hydrogen production of 500 kt can lead to a 20–25% increase in the cost of electricity in scenarios with lower renewable energy penetration due to South African emission constraints by 2030. While the price of electricity is still in acceptable range and the price of hydrogen can be competitive on the international market (2–3 USD/kgH2 for production) the emission factor of this hydrogen is higher than the one of grey hydrogen ranging from 13 to 24 kgCO2/kgh2. When attempting to reach emission factors based on EU directives the three policy roadmaps become unfeasible and free capacity expansion results in significant sixteen-fold increase of wind and seven-fold increase in solar installations compared to 2023 levels by 2030 in South Africa.
Emerging Borophene Two-dimensional Nanmaterials for Hydrogen Storage
May 2023
Publication
The growing demand for energy and the need to reduce the carbon footprint has made green hydrogen a promising alternative to traditional fossil fuels. Green hydrogen is produced using renewable energy sources making it a sustainable and environmentally friendly energy source. Solid-state hydrogen storage aims to store hydrogen in a solid matrix offering potential advantages such as higher safety and improved energy density compared to traditional storage methods such as compressed gas or liquid hydrogen. However the development of efficient and economically viable solid-state storage materials is still a challenge and research continues in this field. Borophene is a two-dimensional material that offers potential as an intermediate hydrogen storage material due to its moderate binding energy and reversible behavior. Its unique geometry and electronic properties also allow for higher hydrogen adsorption capacity than metal-based complex hydrides surpassing the goals set by the U.S. Department of Energy. Borophene has shown great potential for hydrogen storage but it is still not practical for commercial use. In this review borophene nanomaterials chemical and physical properties are discussed related to hydrogen storage and binding energy. The importance of borophene for hydrogen storage the challenges it faces and its future prospects are also being discussed.
Hydrogen Production, Storage, and Transportation: Recent Advances
Feb 2024
Publication
One such technology is hydrogen-based which utilizes hydrogen to generate energy without emission of greenhouse gases. The advantage of such technology is the fact that the only by-product is water. Efficient storage is crucial for the practical application of hydrogen. There are several techniques to store hydrogen each with certain advantages and disadvantages. In gaseous hydrogen storage hydrogen gas is compressed and stored at high pressures requiring robust and expensive pressure vessels. In liquid hydrogen storage hydrogen is cooled to extremely low temperatures and stored as a liquid which is energy-intensive. Researchers are exploring advanced materials for hydrogen storage including metal hydrides carbonbased materials metal–organic frameworks (MOFs) and nanomaterials. These materials aim to enhance storage capacity kinetics and safety. The hydrogen economy envisions hydrogen as a clean energy carrier utilized in various sectors like transportation industry and power generation. It can contribute to decarbonizing sectors that are challenging to electrify directly. Hydrogen can play a role in a circular economy by facilitating energy storage supporting intermittent renewable sources and enabling the production of synthetic fuels and chemicals. The circular economy concept promotes the recycling and reuse of materials aligning with sustainable development goals. Hydrogen availability depends on the method of production. While it is abundant in nature obtaining it in a clean and sustainable manner is crucial. The efficiency of hydrogen production and utilization varies among methods with electrolysis being a cleaner but less efficient process compared to other conventional methods. Chemisorption and physisorption methods aim to enhance storage capacity and control the release of hydrogen. There are various viable options that are being explored to solve these challenges with one option being the use of a multilayer film of advanced metals. This work provides an overview of hydrogen economy as a green and sustainable energy system for the foreseeable future hydrogen production methods hydrogen storage systems and mechanisms including their advantages and disadvantages and the promising storage system for the future. In summary hydrogen holds great promise as a clean energy carrier and ongoing research and technological advancements are addressing challenges related to production storage and utilization bringing us closer to a sustainable hydrogen economy.
Research and Development of Hydrogen Carrier Based Solutions for Hydrogen Compression and Storage
Aug 2022
Publication
Martin Dornheim,
Lars Baetcke,
Etsuo Akiba,
Jose-Ramón Ares,
Tom Autrey,
Jussara Barale,
Marcello Baricco,
Kriston Brooks,
Nikolaos Chalkiadakis,
Véronique Charbonnier,
Steven Christensen,
José Bellosta von Colbe,
Mattia Costamagna,
Erika Michela Dematteis,
Jose-Francisco Fernández,
Thomas Gennett,
David Grant,
Tae Wook Heo,
Michael Hirscher,
Katherine Hurst,
Mykhaylo V. Lototskyy,
Oliver Metz,
Paola Rizzi,
Kouji Sakaki,
Sabrina Sartori,
Emmanuel Stamatakis,
Alastair D. Stuart,
Athanasios Stubos,
Gavin Walker,
Colin Webb,
Brandon Wood,
Volodymyr A. Yartys and
Emmanuel Zoulias
Industrial and public interest in hydrogen technologies has risen strongly recently as hydrogen is the ideal means for medium to long term energy storage transport and usage in combination with renewable and green energy supply. In a future energy system the production storage and usage of green hydrogen is a key technology. Hydrogen is and will in future be even more used for industrial production processes as a reduction agent or for the production of synthetic hydrocarbons especially in the chemical industry and in refineries. Under certain conditions material based systems for hydrogen storage and compression offer advantages over the classical systems based on gaseous or liquid hydrogen. This includes in particular lower maintenance costs higher reliability and safety. Hydrogen storage is possible at pressures and temperatures much closer to ambient conditions. Hydrogen compression is possible without any moving parts and only by using waste heat. In this paper we summarize the newest developments of hydrogen carriers for storage and compression and in addition give an overview of the different research activities in this field.
Optimal Design of Hydrogen-based Storage with a Hybrid Renewable energy System Considering Economic and Environmental Uncertainties
Dec 2023
Publication
Hydrogen and electricity derived from renewable sources present feasible alternative energy options for the decarbonisation of the transportation and power sectors. This study presents the utilisation of hydrogen generated from solar and wind energy resources as a clean fuel for mobility and backup storage for stationary applications under economic and environmental uncertainties. This is achieved by developing a detailed technoeconomic model of an integrated system consisting of a hydrogen refuelling station and an electric power generation system using Mixed Integer Quadratic Constrained Programming (MIQCP) which is further relaxed to Mixed Integer Linear Programming (MILP). The model is implemented in the Advanced Interactive Multidi mensional Modelling Software (AIMMS) and considering the inherent uncertainties in the wind resource solar resource costs and discount rate the total cost of the three configurations (Hybrid PV-Wind Standalone PV and Standalone wind energy system) was minimised using robust optimisation technique and the corresponding optimal sizes of the components levelised cost of energy (LCOE) excess energy greenhouse emission avoided and carbon tax were evaluated. The levelised cost of the deterministic optimisation solution for all the config uration ranges between 0.0702 $/kWh to 0.0786 $/kWh while the levelised cost of the robust optimisation solution ranges between 0.07188 $/kWh to 0.1125 $/kWh. The proposed integration has the advantages of affordable hydrogen and electricity prices minimisation of carbon emissions and grid export of excess energy.
No more items...