United States
Everything About Hydrogen Podcast: The Other Hydrogen Vehicle?
Oct 2019
Publication
For this episode we speak to Amanda Lyne the Managing Director of ULEMCo and the Chair of the UK Hydrogen and Fuel Cell Association (UKHFCA). Below are a few links to some of the content discussed on the show and some further background reading.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Building an Integrated Clean Hydrogen Infrastructure from the Ground Up
Nov 2021
Publication
On this episode of EAH we are joined by Andrew Clennett Co-Founder and CEO of Hiringa Energy. Hiringa is headquartered in New Zealand where they are building clean hydrogen production projects using renewable energy to displace the use of fossil fuels for transport and industrial feedstock across New Zealand. We are delighted to have Andrew with us today to speak about how Hiringa are using hydrogen to change the energy and carbon landscape of New Zealand.
This podcast can be found on their website
This podcast can be found on their website
Everything About Hydrogen Podcast: Masters of Scale: How to Build the Hydrogen Infrastructure of the Future
Oct 2020
Publication
On this week's episode the EAH team speaks with Prof. Armin Schnettler CEO of New Energy Business at Siemens Energy to talk about where green hydrogen solutions fit into the path to decarbonisation how companies like Siemens are looking at those solutions and working to scale them to meet future demand timelines for deployment in different markets how governments can help the private sector and much much more.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Decarbonising the Gas Grid with Cadent
Mar 2020
Publication
On this weeks episode the team are talking all things hydrogen with Lorna Millington Future Networks Manager in the Safety and Network Strategy team at Cadent. On the show we discuss the role that Cadent and other gas distribution network operators (GDNOs) are playing in supporting the transition towards a low (and eventually zero) carbon gas grid through the use of hydrogen. The potential for hydrogen to support decarbonisation of heat through the gas network is one of the most exciting emerging themes for countries that have large existing gas networks and who are looking to repurpose those assets towards national net zero objectives. As a leader on hydrogen into the gas grid projects Cadent offer a wealth of knowledge around the potential opportunities and considerations for displacing natural gas with hydrogen over time. And given the chance to reduce up to 6 million tonnes of CO2 a year through using more hydrogen in the gas grid this is a show you won’t want to miss! All this and more on the show!
The podcast can be found on their website
The podcast can be found on their website
Hydrogen Production and Carbon Sequestration by Steam Methane Reforming and Fracking with Carbon Dioxide
Feb 2020
Publication
An opportunity to sequester large amounts of carbon dioxide (CO2) is made possible because hydraulic fracturing is used to produce most of America's natural gas. CO2 could be extracted from natural gas and water using steam methane reforming pressurized to its supercritical phase and used instead of water to fracture additional hydrocarbon-bearing rock. The useful energy carrier that remains is hydrogen with carbon returned to the ground. Research on the use of supercritical CO2 is reviewed with proppant entrainment identified as the major area where technical advances may be needed. The large potential for greenhouse-gas reduction through sequestration of CO2 and avoidance of methane leakage from the natural gas system is quantified.
Everything About Hydrogen Podcast: Supplying the Building Blocks of an Energy Revolution
Apr 2021
Publication
On this episode of Everything About Hydrogen the team is joined by Sam French Business Development Director at JM who spent some time speaking with us about the transition from grey hydrogen to low-carbon generation technologies and what steps the UK - and countries all over the world - to use hydrogen as part of the pathway to a sustainable energy future.
The podcast can be found on their website
The podcast can be found on their website
Seasonal Hydrogen Storage for Sustainable Renewable Energy Integration in the Electricity Sector: A Case Study of Finland
Nov 2021
Publication
Wind power is rapidly growing in the Finnish grid and Finland’s electricity consumption is low in the summer compared to the winter. Hence there is a need for storage that can absorb a large amount of energy during summer and discharge it during winter. This study examines one such storage technology geological hydrogen storage which has the potential to store energy on a GWh scale and also over longer periods of time. Finland’s electricity generation system was modelled with and without hydrogen storage using the LEAP-NEMO modeling toolkit. The results showed about 69% decline in carbon dioxide emissions as well as a decline in the fossil fuel-based power accompanied with a higher capability to meet demand with less imports in both scenarios. Finally a critical analysis of the Finnish electricity mix with and without hydrogen storage is presented.
The Future of Clean Hydrogen in the United States: Views from Industry, Market Innovators, and Investors
Sep 2021
Publication
This report The Future of Clean Hydrogen in the United States: Views from Industry Market Innovators and Investors sheds light on the rapidly evolving hydrogen market based on 72 exploratory interviews with organizations across the current and emerging hydrogen value chain. This report is part of a series From Kilograms to Gigatons: Pathways for Hydrogen Market Formation in the United States which will build on this study to evaluate policy opportunities for further hydrogen development in the United States. The goal of the interviews was to provide a snapshot of the clean hydrogen investment environment and better understand organizations’ market outlook investment rationale and areas of interest. This interview approach was supported by traditional research methods to contextualize and enrich the qualitative findings. This report should be understood as input to a more extensive EFI analysis of hydrogen market formation in the United States; the directions that companies are pursuing in hydrogen production transport and storage and end use at this early stage of value chain development will inform subsequent analysis in important ways.
Sector Coupling via Hydrogen to Lower the Cost of Energy System Decarbonization
Aug 2021
Publication
There is growing interest in using hydrogen (H2) as a long-duration energy storage resource in a future electric grid dominated by variable renewable energy (VRE) generation. Modeling H2 use exclusively for grid-scale energy storage often referred to as ‘‘power-to-gas-to-power (P2G2P)’’ overlooks the cost-sharing and CO2 emission benefits from using the deployed H2 assets to decarbonize other end-use sectors where direct electrification is challenging. Here we develop a generalized framework for co-optimizing infrastructure investments across the electricity and H2 supply chains accounting for the spatio-temporal variations in energy demand and supply. We apply this sector-coupling framework to the U.S. Northeast under a range of technology cost and carbon price scenarios and find greater value of power-to-H2 (P2G) vs. P2G2P routes. Specifically P2G provides grid flexibility to support VRE integration without the round-trip efficiency penalty and additional cost incurred by P2G2P routes. This form of sector coupling leads to: (a) VRE generation increase by 13–56% and (b) total system cost (and levelized costs of energy) reduction by 7–16% under deep decarbonization scenarios. Both effects increase as H2 demand for other end-uses increases more than doubling for a 97% decarbonization scenario as H2 demand quadruples. We also find that the grid flexibility enabled by sector coupling makes deployment of carbon capture and storage (CCS) for power generation less cost-effective than its use for low-carbon H2 production. These findings highlight the importance of using an integrated energy system framework with multiple energy vectors in planning cost-effective energy system decarbonization
Everything About Hydrogen Podcast: The Oracle of Hydrogen
Oct 2019
Publication
Nel Hydrogen is one of the largest electrolysis companies in the world with an array of Alkaline and PEM solutions that have been used in an array of energy and industrial applications. On the show we ask Bjørn Simonsen Vice President of Investor Relations and Corporate Communication at Nel Hydrogen to talk through how Nel has seen the green hydrogen market evolve and where Nel fits into this sector transition.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Rethinking Hydrogen Storage with H2GOPOWER
Sep 2019
Publication
For this episode we speak to Enass Abo-Hamed the CEO of H2GOPower about their cutting edge hydrogen storage technology. Below we have attached a few links to the content discussed on the show and some further background reading.
The podcast can be found on their website
The podcast can be found on their website
Techno-economic Analysis of Freight Railway Electrification by Overhead Line, Hydrogen and Batteries: Case Studies in Norway and USA
Aug 2019
Publication
Two non-electrified railway lines one in Norway and the other in the USA are analysed for their potential to be electrified with overhead line equipment batteries hydrogen or hydrogen-battery hybrid powertrains. The energy requirements are established with single-train simulations including the altitude profiles of the lines air and rolling resistances and locomotive tractive-effort curves. The composition of the freight trains in terms of the number of locomotives battery wagons hydrogen wagons etc. is also calculated by the same model. The different technologies are compared by the criteria of equivalent annual costs benefit–cost ratio payback period and up-front investment based on the estimated techno-economic parameters for years 2020 2030 and 2050. The results indicate the potential of batteries and fuel cells to replace diesel on rail lines with low traffic volumes.
Technologies and Policies to Decarbonize Global Industry: Review and Assessment of Mitigation Drivers Through 2070
Mar 2020
Publication
Jeffrey Rissman,
Chris Bataille,
Eric Masanet,
Nate Aden,
William R. Morrow III,
Nan Zhou,
Neal Elliott,
Rebecca Dell,
Niko Heeren,
Brigitta Huckestein,
Joe Cresko,
Sabbie A. Miller,
Joyashree Roy,
Paul Fennell,
Betty Cremmins,
Thomas Koch Blank,
David Hone,
Ellen D. Williams,
Stephane de la Rue du Can,
Bill Sisson,
Mike Williams,
John Katzenberger,
Dallas Burtraw,
Girish Sethi,
He Ping,
David Danielson,
Hongyou Lu,
Tom Lorber,
Jens Dinkel and
Jonas Helseth
Fully decarbonizing global industry is essential to achieving climate stabilization and reaching net zero greenhouse gas emissions by 2050–2070 is necessary to limit global warming to 2 °C. This paper assembles and evaluates technical and policy interventions both on the supply side and on the demand side. It identifies measures that employed together can achieve net zero industrial emissions in the required timeframe. Key supply-side technologies include energy efficiency (especially at the system level) carbon capture electrification and zero-carbon hydrogen as a heat source and chemical feedstock. There are also promising technologies specific to each of the three top-emitting industries: cement iron & steel and chemicals & plastics. These include cement admixtures and alternative chemistries several technological routes for zero-carbon steelmaking and novel chemical catalysts and separation technologies. Crucial demand-side approaches include material-efficient design reductions in material waste substituting low-carbon for high-carbon materials and circular economy interventions (such as improving product longevity reusability ease of refurbishment and recyclability). Strategic well-designed policy can accelerate innovation and provide incentives for technology deployment. High-value policies include carbon pricing with border adjustments or other price signals; robust government support for research development and deployment; and energy efficiency or emissions standards. These core policies should be supported by labeling and government procurement of low-carbon products data collection and disclosure requirements and recycling incentives. In implementing these policies care must be taken to ensure a just transition for displaced workers and affected communities. Similarly decarbonization must complement the human and economic development of low- and middle-income countries.
Everything About Hydrogen Podcast: Going "Green"
May 2021
Publication
Founded in 2007 and based in Denmark Green Hydrogen Systems designs and manufactures efficient standardized and modular electrolysers for the production of green hydrogen with renewable energy. Niels-Arne Baden has led the company to the upper echelons of the electrolysis sector and he now leads the company's strategy and and public-facing initiatives as the Vice President for Strategy and Public Affairs. On this episode of the Everything About Hydrogen podcast the EAH team sits down with Niels to talk about the journey of the clean hydrogen sector over the recent decades and its rise to prominence in the transition to a decarbonized energy future and how modular electrolysis fits into that picture.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Venturing into Hydrogen
Apr 2021
Publication
Since 2014 when the firm was founded within Anglo-American AP Ventures has been at the forefront of investment in hydrogen sector technologies. At the time the firm started the concerns around climate change and investment in renewable energy tech was gearing up but interest in hydrogen as part of the path to a decarbonized future was limited. The founders of AP Ventures felt differently and saw significant potential for hydrogen to offer a means for cleaning up highly carbon intensive sectors such as heavy transport industrial manufacturing and mining operations. Today that vision for hydrogen appears rather prescient. We are delighted to have two members from the team at AP Ventures with us on the show today. The team is joined by Kevin Eggers - a founding partner at AP - and Michell Robson - associate on the firm's investment team.
The podcast can be found on their website
The podcast can be found on their website
The Role of Hydrogen in Achieving Long Term Japanese Energy System Goals
Sep 2020
Publication
This research qualitatively reviews literature regarding energy system modeling in Japan specific to the future hydrogen economy leveraging quantitative model outcomes to establish the potential future deployment of hydrogen in Japan. The analysis focuses on the four key sectors of storage supplementing the gas grid power generation and transportation detailing the potential range of hydrogen technologies which are expected to penetrate Japanese energy markets up to 2050 and beyond. Alongside key model outcomes the appropriate policy settings governance and market mechanisms are described which underpin the potential hydrogen economy future for Japan. We find that transportation gas grid supplementation and storage end-uses may emerge in significant quantities due to policies which encourage ambitious implementation targets investment in technologies and research and development and the emergence of a future carbon pricing regime. On the other hand for Japan which will initially be dependent on imported hydrogen the cost of imports appears critical to the emergence of broad hydrogen usage particularly in the power generation sector. Further the consideration of demographics in Japan recognizing the aging shrinking population and peoples’ energy use preferences will likely be instrumental in realizing a smooth transition toward a hydrogen economy.
Everything About Hydrogen Podcast: Geopolitical Factors in Hydrogen Markets
Mar 2022
Publication
The EAH Team takes a break from standard format on this special episode of Everything About Hydrogen to discuss some of the geopolitical factors and considerations driving the evolution of global hydrogen markets.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Digging into the Mining Industry
Jan 2021
Publication
On this episode of Everything About Hydrogen Jan Klawitter Head of International Policy for Anglo American speaks with Andrew Chris and Patrick about Anglo American's strategy for decarbonizing its mining operations and how they plan to use hydrogen and fuel cell technologies as a key part of their approach.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Taking the Lead in the Hydrogen Economy
Sep 2021
Publication
On the season premier episode the EAH hosts are joined by the Governor of New Mexico Michelle Lujan Grisham. The State of New Mexico has the opportunity to lead the United States into the hydrogen era and the Governor and her team are poised to take the opportunity to make New Mexico the strategic center of the US hydrogen economy. The Governor is joined by New Mexico Environment Department Secretary James Kenney on the show to announce the forthcoming New Mexico Hydrogen Hub Act which her administration expects to drive investment in the state job growth in the energy sector and catapult New Mexico to top of the list of states driving the hydrogen revolution.
The podcast can be found on their website.
The podcast can be found on their website.
Photocatalytic Hydrogen Evolution from Biomass Conversion
Feb 2021
Publication
Biomass has incredible potential as an alternative to fossil fuels for energy production that is sustainable for the future of humanity. Hydrogen evolution from photocatalytic biomass conversion not only produces valuable carbon-free energy in the form of molecular hydrogen but also provides an avenue of production for industrially relevant biomass products. This photocatalytic conversion can be realized with efficient sustainable reaction materials (biomass) and inexhaustible sunlight as the only energy inputs. Reported herein is a general strategy and mechanism for photocatalytic hydrogen evolution from biomass and biomass-derived substrates (including ethanol glycerol formic acid glucose and polysaccharides). Recent advancements in the synthesis and fundamental physical/mechanistic studies of novel photocatalysts for hydrogen evolution from biomass conversion are summarized. Also summarized are recent advancements in hydrogen evolution efciency regarding biomass and biomass-derived substrates. Special emphasis is given to methods that utilize unprocessed biomass as a substrate or synthetic photocatalyst material as the development of such will incur greater benefts towards a sustainable route for the evolution of hydrogen and production of chemical feedstocks.
Prospects of Fuel Cell Combined Heat and Power Systems
Aug 2020
Publication
Combined heat and power (CHP) in a single and integrated device is concurrent or synchronized production of many sources of usable power typically electric as well as thermal. Integrating combined heat and power systems in today’s energy market will address energy scarcity global warming as well as energy-saving problems. This review highlights the system design for fuel cell CHP technologies. Key among the components discussed was the type of fuel cell stack capable of generating the maximum performance of the entire system. The type of fuel processor used was also noted to influence the systemic performance coupled with its longevity. Other components equally discussed was the power electronics. The thermal and water management was also noted to have an effect on the overall efficiency of the system. Carbon dioxide emission reduction reduction of electricity cost and grid independence were some notable advantages associated with fueling cell combined heat and power systems. Despite these merits the high initial capital cost is a key factor impeding its commercialization. It is therefore imperative that future research activities are geared towards the development of novel and cheap materials for the development of the fuel cell which will transcend into a total reduction of the entire system. Similarly robust systemic designs should equally be an active research direction. Other types of fuel aside hydrogen should equally be explored. Proper risk assessment strategies and documentation will similarly expand and accelerate the commercialization of this novel technology. Finally public sensitization of the technology will also make its acceptance and possible competition with existing forms of energy generation feasible. The work in summary showed that proton exchange membrane fuel cell (PEM fuel cell) operated at a lower temperature-oriented cogeneration has good efficiency and is very reliable. The critical issue pertaining to these systems has to do with the complication associated with water treatment. This implies that the balance of the plant would be significantly affected; likewise the purity of the gas is crucial in the performance of the system. An alternative to these systems is the PEM fuel cell systems operated at higher temperatures.
Everything About Hydrogen Podcast: 'Having Hydrogen for Breakfast, Lunch and Dinner'
Apr 2023
Publication
On today’s show Chris Patrick and Alicia speak with Petra Schwager from UNIDO about her work promoting global green hydrogen development with particular emphasis on the Global South.
The podcast can be found on their website.
The podcast can be found on their website.
Everything About Hydrogen Podcast: Reaching for the Stars
Mar 2023
Publication
Today Everything About Hydrogen had a chance to speak with Paul Barrett the CEO of Hysata and dig into what makes this electrolysis company different.
The podcast can be found on their website.
The podcast can be found on their website.
Everything About Hydrogen Podcast: Easter Eggs
Feb 2023
Publication
On today’s episode of Everything About Hydrogen we speak with Raffi Garabedian CEO and Co-Founder of Electric Hydrogen (EH2) a deep decarbonization company pioneering new technology for low cost high efficiency fossil free hydrogen systems. By using electrolyzers many times larger than the industry standard EH2 aims to help eliminate more than 30% of global GHG emissions from difficult to electrify sectors like steel ammonia and freight.
We are excited to learn more from Raffi about the EH2 technology lessons learned by scaling First Solar and what we might expect to see next.
The podcast can be found on their website.
We are excited to learn more from Raffi about the EH2 technology lessons learned by scaling First Solar and what we might expect to see next.
The podcast can be found on their website.
Transition to a Hydrogen-Based Economy: Possibilities and Challenges
Nov 2022
Publication
Across the globe energy production and usage cause the greatest greenhouse gas (GHG) emissions which are the key driver of climate change. Therefore countries around the world are aggressively striving to convert to a clean energy regime by altering the ways and means of energy production. Hydrogen is a frontrunner in the race to net-zero carbon because it can be produced using a diversity of feedstocks has versatile use cases and can help ensure energy security. While most current hydrogen production is highly carbon-intensive advances in carbon capture renewable energy generation and electrolysis technologies could help drive the production of low-carbon hydrogen. However significant challenges such as the high cost of production a relatively small market size and inadequate infrastructure need to be addressed before the transition to a hydrogen-based economy can be made. This review presents the state of hydrogen demand challenges in scaling up low-carbon hydrogen possible solutions for a speedy transition and a potential course of action for nations.
Improvement of Temperature and Humidity Control of Proton Exchange Membrane Fuel Cells
Sep 2021
Publication
Temperature and humidity are two important interconnected factors in the performance of PEMFCs (Proton Exchange Membrane Fuel Cells). The fuel and oxidant humidity and stack temperature in a fuel cell were analyzed in this study. There are many factors that affect the temperature and humidity of the stack. We adopt the fuzzy control method of multi-input and multi-output to control the temperature and humidity of the stack. A model including a driver vehicle transmission motor air feeding electrical network stack hydrogen supply and cooling system was established to study the fuel cell performance. A fuzzy controller is proven to be better in improving the output power of fuel cells. The three control objectives are the fan speed control for regulating temperature the solenoid valve on/off control of the bubble humidifier for humidity variation and the speed of the pump for regulating temperature difference. In addition the results from the PID controller stack model and the fuzzy controller stack model are compared in this research. The fuel cell bench test has been built to validate the effectiveness of the proposed fuzzy control. The maximum temperature of the stack can be reduced by 5 ◦C with the fuzzy control in this paper so the fuel cell output voltage (power) increases by an average of approximately 5.8%.
Addressing the Low-carbon Million-gigawatt-hour Energy Storage Challenge
Nov 2021
Publication
The energy system of the United States requires several million gigawatt hours of energy storage to meet variable demand for energy driven by (1) weather (heating and cooling) (2) social patterns (daily and weekday/weekend) of work play and sleep (3) weather-dependent energy production (wind and solar) and (4) industrial requirements. In a low-carbon world four storage options can meet this massive requirement at affordable costs: nuclear fuels heat storage hydrocarbon liquids made from biomass and hydrogen. Because of the different energy sector characteristics (electrical supply transportation commercial and industrial) each of these options must be developed. Capital costs associated with electricity storage at this scale using for example batteries and hydroelectric technologies are measured in hundreds of trillions of dollars for the United States alone and thus are not viable.
Electrolyzers Enhancing Flexibility in Electric Grids
Nov 2017
Publication
This paper presents a real-time simulation with a hardware-in-the-loop (HIL)-based approach for verifying the performance of electrolyzer systems in providing grid support. Hydrogen refueling stations may use electrolyzer systems to generate hydrogen and are proposed to have the potential of becoming smarter loads that can proactively provide grid services. On the basis of experimental findings electrolyzer systems with balance of plant are observed to have a high level of controllability and hence can add flexibility to the grid from the demand side. A generic front end controller (FEC) is proposed which enables an optimal operation of the load on the basis of market and grid conditions. This controller has been simulated and tested in a real-time environment with electrolyzer hardware for a performance assessment. It can optimize the operation of electrolyzer systems on the basis of the information collected by a communication module. Real-time simulation tests are performed to verify the performance of the FEC-driven electrolyzers to provide grid support that enables flexibility greater economic revenue and grid support for hydrogen producers under dynamic conditions. The FEC proposed in this paper is tested with electrolyzers however it is proposed as a generic control topology that is applicable to any load.
Numerical Predictions of a Swirl Combustor Using Complex Chemistry Fueled with Ammonia/Hydrogen Blends
Jan 2020
Publication
Ammonia a chemical that contains high hydrogen quantities has been presented as a candidate for the production of clean power generation and aerospace propulsion. Although ammonia can deliver more hydrogen per unit volume than liquid hydrogen itself the use of ammonia in combustion systems comes with the detrimental production of nitrogen oxides which are emissions that have up to 300 times the greenhouse potential of carbon dioxide. This factor combined with the lower energy density of ammonia makes new studies crucial to enable the use of the molecule through methods that reduce emissions whilst ensuring that enough power is produced to support high-energy intensive applications. Thus this paper presents a numerical study based on the use of novel reaction models employed to characterize ammonia combustion systems. The models are used to obtain Reynolds Averaged Navier-Stokes (RANS) simulations via Star-CCM+ with complex chemistry of a 70%–30% (mol) ammonia–hydrogen blend that is currently under investigations elsewhere. A fixed equivalence ratio (1.2) medium swirl (0.8) and confined conditions are employed to determine the flame and species propagation at various operating atmospheres and temperature inlet values. The study is then expanded to high inlet temperatures high pressures and high flowrates at different confinement boundary conditions. The results denote how the production of NOx emissions remains stable and under 400 ppm whilst higher concentrations of both hydrogen and unreacted ammonia are found in the flue gases under high power conditions. The reduction of heat losses (thus higher temperature boundary conditions) has a crucial impact on further destruction of ammonia post-flame with a raise in hydrogen water and nitrogen through the system thus presenting an opportunity of combustion efficiency improvement of this blend by reducing heat losses. Final discussions are presented as a method to raise power whilst employing ammonia for gas turbine systems.
The Viability of Implementing Hydrogen in the Commonwealth of Massachusetts
Sep 2022
Publication
In recent years there has been an increased interest in hydrogen energy due to a desire to reduce greenhouse gas emissions by utilizing hydrogen for numerous applications. Some countries (e.g. Japan Iceland and parts of Europe) have made great strides in the advancement of hydrogen generation and utilization. However in the United States there remains significant reservation and public uncertainty on the use and integration of hydrogen into the energy ecosystem. Massachusetts similar to many other states and small countries faces technical infrastructure policy safety and acceptance challenges with regards to hydrogen production and utilization. A hydrogen economy has the potential to provide economic benefits a reduction in greenhouse gas emissions and sector coupling to provide a resilient energy grid. In this paper the issues associated with integrating hydrogen into Massachusetts and other similar states or regions are studied to determine which hydrogen applications have the most potential understand the technical and integration challenges and identify how a hydrogen energy economy may be beneficial. Additionally hydrogen’s safety concerns and possible contribution to greenhouse gas emissions are also reviewed. Ultimately a set of eight recommendations is made to guide the Commonwealth’s consideration of hydrogen as a key component of its policies on carbon emissions and energy.
Everything About Hydrogen Podcast: Manufacturing the Components of a Hydrogen Economy
Dec 2022
Publication
On today’s episode Alicia Chris and Patrick are chatting with Vonjy Rakajoba UK Managing Director at Robert Bosch. The Bosch Group is a leading global supplier of technology and services and employs roughly 402600 associates worldwide. Its operations are divided into four business sectors: Mobility Solutions Industrial Technology Consumer Goods and Energy and Building Technology. Bosch believes that hydrogen has a bright future as an energy carrier and is making considerable upfront investments in this area. From 2021 to 2024 the company plans to invest around 600 million euros in mobile fuel-cell applications and a further 400 million euros in stationary ones for the generation of electricity and heat. Vonjy is here with us to discuss more about what Bosch’s expansion into the hydrogen energy sector will look like and how the company expects the market to grow moving forward.
The podcast can be found on their website.
The podcast can be found on their website.
A Flexible Techno-economic Analysis Tool for Regional Hydrogen Hubs - A Case Study for Ireland
Apr 2023
Publication
The increasing urgency with which climate change must be addressed has led to an unprecedented level of interest in hydrogen as a clean energy carrier. Much of the analysis of hydrogen until this point has focused predominantly on hydrogen production. This paper aims to address this by developing a flexible techno-economic analysis (TEA) tool that can be used to evaluate the potential of future scenarios where hydrogen is produced stored and distributed within a region. The tool takes a full year of hourly data for renewables availability and dispatch down (the sum of curtailment and constraint) wholesale electricity market prices and hydrogen demand as well as other user-defined inputs and sizes electrolyser capacity in order to minimise cost. The model is applied to a number of case studies on the island of Ireland which includes Ireland and Northern Ireland. For the scenarios analysed the overall LCOH ranges from V2.75e3.95/kgH2. Higher costs for scenarios without access to geological storage indicate the importance of cost-effective storage to allow flexible hydrogen production to reduce electricity costs whilst consistently meeting a set demand.
Everything About Hydrogen Podcast: Plotting the Course for a Decarbonized Global Maritime Industry
Jan 2023
Publication
On this episode of EAH we sat down with Dr. Bo Cerup-Simonsen Chief Executive Officer of the Maersk Mc-Kinney Møller Center for Zero Carbon Shipping. Bo holds a PHD in Naval Architecture and Mechanical Engineering and spent seven years as a research engineer at MIT.
Bo explains the Center's work and we discuss decarbonization of shipping using hydrogen derived green fuels.
The podcast can be found on their website.
Bo explains the Center's work and we discuss decarbonization of shipping using hydrogen derived green fuels.
The podcast can be found on their website.
Opportunities for Low-carbon Generation and Storage Technologies to Decarbonise the Future Power System
Feb 2023
Publication
Alternatives to cope with the challenges of high shares of renewable electricity in power systems have been addressed from different approaches such as energy storage and low-carbon technologies. However no model has previously considered integrating these technologies under stability requirements and different climate conditions. In this study we include this approach to analyse the role of new technologies to decarbonise the power system. The Spanish power system is modelled to provide insights for future applications in other regions. After including storage and low-carbon technologies (currently available and under development) batteries and hydrogen fuel cells have low penetration and the derived emission reduction is negligible in all scenarios. Compressed air storage would have a limited role in the short term but its performance improves in the long term. Flexible generation technologies based on hydrogen turbines and long-duration storage would allow the greatest decarbonisation providing stability and covering up to 11–14 % of demand in the short and long term. The hydrogen storage requirement is equivalent to 18 days of average demand (well below the theoretical storage potential in the region). When these solutions are considered decarbonising the electricity system (achieving Paris targets) is possible without a significant increase in system costs (< € 114/MWh).
US-UK Scientific Forum on Sustainable Energy: Electrical Storage in Support of the Grid, Forum Report
Sep 2022
Publication
The effort to meet the ambitious targets of the Paris agreement is challenging many governments. The US and UK governments might have different approaches to achieving the targets but both will rely heavily on renewable energy sources such as wind and solar to power their economies. However these sources of power are unpredictable and ways will have to be developed to store renewable energy for hours days weeks seasons and maybe even years before it is used. As the disruptive and increasingly deadly impacts of climate change are being felt across the world the need to move to more sustainable sources of energy and to identify viable ways to store that energy has never been more important.<br/>This was the subject of the US–UK Science Forum on electrical storage in support of the grid which was held online from 17 – 18 March 2021. Co-organised by the Royal Society and the National Academy of Sciences it brought together a diverse group of 60 scientists policy makers industry leaders regulators and other key stakeholders for a wide-ranging discussion on all aspects of energy storage from the latest research in the field to the current status of deployment. It also considered the current national and international economic and policy contexts in which these developments are taking place. A number of key points emerged from the discussion. First it is clear that renewable energy will play an increasingly important role in the US and UK energy systems of the future and energy storage at a multi-terawatt hour scale has a vital role to play. Of course this will evolve differently to some extent in both countries and elsewhere according to the various geographical technological economic political social and regulatory environments. Second international collaboration is critical – no single nation will solve this problem alone. As two of the world’s leading scientific nations largest economies and per capita CO2 emitters with a long track record of collaboration the US and UK are well placed to play a vital role in addressing this critical challenge. As the discussion highlighted a wide range of energy storage technologies are now emerging and becoming increasingly available many of which have the potential to be critical components of a future net-zero energy system. A crucial next phase is in ensuring that these are technically developed as well as economically and political viable. This will require the support of a wide range of these potential solutions to ensure that their benefits remain widely available and to avoid costly ‘lock-in’. Scientists and science academies have a critical role to play in analysing technology options their combinations and their potential roles in future sustainable energy systems and in working with policymakers to incentivise investment and deployment.
Everything About Hydrogen Podcast: Masters of Scale: Mobilizing the Mobility Sector (Around Hydrogen Fuel Cells)
Nov 2020
Publication
We talk a lot on the EAH podcast series about where hydrogen fuel cell electric vehicles (FCEVs) fit into the overall zero emission vehicle (ZEV) ecosystem. From personal passenger vehicles and the family car to commercial trucking and public transportation fleets and everything in between. Different vehicles and different use cases call for different capabilities and that is what makes the future of decarbonized transportation co interesting.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: M&A in the Modern Hydrogen Economy
Sep 2021
Publication
This week we have Christopher Jackson in the hot seat as he catches up with BayoTech CEO Mo Vargas and BayoTech’s new President Michael Koonce to discuss the acquisition of IGX Group. Mergers & Acquisition activity has been growing in the hydrogen space with commentators suggesting the market is maturing faster than expected and customers seeking more integrated solutions. In this episode we look at the IGX acquisition by BayoTech and ask why the deal made sense what it means for the market and other participants and what listeners can learn from the deal to foreshadow future activity.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Championing a Clean Energy Future
Nov 2021
Publication
With COP starting this week we discuss with the HLC team the role of hydrogen in decarbonization and the critical need for hydrogen to scale quickly. Andrew and Patrick sit down with Kieran Coleman Energy & Industry Lead for the United Nations COP High Level Champions to chat about the work being done in advance of COP with partners and the level of ambition we’ve seen across various sectors about the future of hydrogen and a lot more!
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Hydrogen Technology: The Engineer's Perspective
Sep 2020
Publication
The team are joined by Dr. Jenifer Baxter of the Institution for Mechanical Engineers (IMECHE). Dr. Baxter is based in the UK and is the Chief Engineer at IMECHE. We often focus heavily on the business cases and development models at the heart of the hydrogen economy here at EAH. On this episode we bring the technical discussion to the forefront and speak with Dr. Baxter about the technical advantages and the challenges that hydrogen presents as an essential part of the path to decarbonizing the future. The team's conversation is a can't miss exploration of a wide range of potential applications for hydrogen technologies that brings a new and essential perspective to the podcast. Don't miss out on EAH's newest episode where we get the engineer's perspective on the future of hydrogen!
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Hydrogen: The Next Generation
May 2021
Publication
This is the inaugural episode of the EAH: Deep Dive podcast mini-series! Our first episode features the co-founders of Enapter Vaitea Cowan and Jan Justus-Schmidt. Enapter is a young company that has made a big splash in the hydrogen space with their modular scalable AEM electrolyzer technology. Last year they made headlines with their successful public offering on the DAX and the company is expected to be a the forefront of the hydrogen sector again in 2021 as they begin construction of their mass production facility in Germany and announce the upcoming Generation Hydrogen event on May 19 2021.
The podcast can be found on their website
The podcast can be found on their website
The Potential of Zero-carbon Bunker Fuels in Developing Countries
Apr 2015
Publication
To meet the climate targets set forth in the International Maritime Organization’s Initial GHG Strategy the maritime transport sector needs to abandon the use of fossil-based bunker fuels and turn toward zero-carbon alternatives which emit zero or at most very low greenhouse gas (GHG) emissions throughout their lifecycles. This report “The Potential of Zero-Carbon Bunker Fuels in Developing Countries” examines a range of zero-carbon bunker fuel options that are considered to be major contributors to shipping’s decarbonized future: biofuels hydrogen and ammonia and synthetic carbon-based fuels. The comparison shows that green ammonia and green hydrogen strike the most advantageous balance of favorable features due to their lifecycle GHG emissions broader environmental factors scalability economics and technical and safety implications. Furthermore the report finds that many countries including developing countries are very well positioned to become future suppliers of zero-carbon bunker fuels—namely ammonia and hydrogen. By embracing their potential these countries would be able to tap into an estimated $1+ trillion future fuel market while modernizing their own domestic energy and industrial infrastructure. However strategic policy interventions are needed to unlock these potentials.
Green-hydrogen Research: What Have We Achieved, and Where Are We Going? Bibliometrics Analysis
Jul 2022
Publication
In response to the global challenge of climate change 136 countries accounting for 90% of global GDP and 85% of the population have now set net-zero targets. A transition to net-zero will require the decarbonization of all sectors of the economy. Green-hydrogen produced from renewable energy sources poses little to no threat to the environment and increasing its production will support net-zero targets Our study examined the evolution of green-hydrogen research themes since the UN Sustainable Development Goals were adopted in 2015 by utilizing bibliographic couplings keyword co-occurrence and keyphrase analysis of 642 articles from 2016 to 2021 in the Scopus database. We studied bibliometrics indicators and temporal evolution of publications and citations patterns of open access the effect of author collaboration influential publications and top contributing countries. We also consider new indicators like publication views keyphrases topics with prominence and field weighted citation impact and Altmetrics to understand the research direction further. We find four major thematic distributions of green-hydrogen research based on keyword co-occurrence networks: hydrogen storage hydrogen production electrolysis and the hydrogen economy. We also find networks of four research clusters that provide new information on the journal’s contributions to green-hydrogen research. These are materials chemistry hydrogen energy and cleaner production applied energy and fuel cells. Most green-hydrogen research aligns with Affordable and Clean Energy (SDG 7) and Climate Action (SDG 13). The outcomes of policy decisions in the United States Europe India and China will profoundly impact green-hydrogen production and storage over the next five years. If these policies are implemented these countries will account for two-thirds of this growth. Asia will account for the most significant part and become the second-largest producer globally.
Protocol for Heavy-duty Hydrogen Refueling: A Modelling Benchmark
Sep 2021
Publication
For the successful deployment of the Heavy Duty (HD) hydrogen vehicles an associated infrastructure in particular hydrogen refueling stations (HRS) should be reliable compliant with regulations and optimized to reduce the related costs. FCH JU project PRHYDE aims to develop a sophisticated protocol dedicated to HD applications. The target of the project is to develop protocol and recommendations for an efficient refueling of 350 500 and 700 bar HD tanks of types III and IV. This protocol is based on modeling results as well as experimental data. Different partners of the PRHYDE European project are closely working together on this target. However modeling approaches and corresponding tools must first be compared and validated to ensure the high level of reliability for the modeling results. The current paper presents the benchmark performed in the frame of the project by Air Liquide Engie Wenger Engineering and NREL. The different models used were compared and calibrated to the configurations proposed by the PRHYDE project. In addition several scenarios were investigated to explore different cases with high ambient temperatures.
Life Cycle Assessment of Hydrogen Transportation Pathways via Pipelines and Truck Trailers: Implications as a Low Carbon Fuel
Sep 2022
Publication
Hydrogen fuel cells have the potential to play a significant role in the decarbonization of the transportation sector globally and especially in California given the strong regulatory and policy focus. Nevertheless numerous questions arise regarding the environmental impact of the hydrogen supply chain. Hydrogen is usually delivered on trucks in gaseous form but can also be transported via pipelines as gas or via trucks in liquid form. This study is a comparative attributional life cycle analysis of three hydrogen production methods alongside truck and pipeline transportation in gaseous form. Impacts assessed include global warming potential (GWP) nitrogen oxide volatile organic compounds and particulate matter 2.5 (PM2.5). In terms of GWP the truck transportation pathway is more energy and ecologically intensive than pipeline transportation despite gaseous truck transport being more economical. A sensitivity analysis of pipeline transportation and life cycle inventories (LCI) attribution is included. Results are compared across multiple scenarios of the production and transportation pathways to discover the strongest candidates for minimizing the environmental footprint of hydrogen production and transportation. The results indicate the less ecologically intensive pathway is solar electrolysis through pipelines. For 1 percent pipeline attribution the total CO2eq produced per consuming 1 MJ of hydrogen in a fuel cell pickup truck along this pathway is 50.29 g.
Everything About Hydrogen Podcast: Show Me the Money!
Jul 2020
Publication
This week on the show the team catch up with Alena Fargere Principal at SWEN Capital Partners and a former special advisor to the World Energy Council on Hydrogen projects. As one of the few current project finance funds in Europe with a green gas mandate and a dedicated allocation for investing in hydrogen project finance SWEN Capital Partners provide an invaluable perspective on the challenges and opportunities for hydrogen project investment in Europe and the synergies that exist from Green Gas funds that support biogas and hydrogen opportunities. On the show our hosts discuss the rationale for this fund the profile of projects SWEN are considering and Alena’s broader perspective on the hydrogen market. All this and many more themes this week so don’t miss this episode!
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Using Hydrogen to Decarbonise Steel Manufacturing
Mar 2022
Publication
Hydrogen could be used in many hard-to-decarbonize sectors. Foremost amongst them is the steel manufacturing industry. On this episode of EAH we speak with Dr. Martin Pei Executive Vice President and CTO of SSAB and the first Chairman of the Board for Hybrit Development AB. SSAB is a global steel company with a leading position in high-strength steels and related services. Together with their partners LKAB and Vattenfall SSAB are making a unique joint effort to change the Swedish iron and steel industry fundamentally. With HYBRIT technology SSAB aims to be the first steel company in the world to bring fossil-free steel to the market already in 2026 and largely eliminate carbon dioxide emissions from the company's own operations as soon as 2030.
The podcast can be found on their website.
The podcast can be found on their website.
Everything About Hydrogen Podcast: Ending on a Hy Note
Jul 2021
Publication
This week's show is the last episode of Season 2! To celebrate we invited our friend and colleague Markus Wilthaner partner at McKinsey & Company to come speak with us. Markus has been a leader in the hydrogen space for the past ten years and has drafted a number of the Hydrogen Council's reports since its founding including the newly released - and highly anticipated - Hydrogen Insights 2021 (link below). In this episode we speak with Markus about the state of the market and the innovation he has seen in the last couple of years that make hydrogen a critical part of the energy transition. We had a lot of fun recording this interview and it was the perfect way to end a fantastic EAH season!
The podcast can be found on their website
The podcast can be found on their website
Can Industrial-Scale Solar Hydrogen Supplied from Commodity Technologies Be Cost Competitive by 2030?
Sep 2020
Publication
Expanding decarbonization efforts beyond the power sector are contingent on cost-effective production of energy carriers like H2 with near-zero life-cycle carbon emissions. Here we assess the levelized cost of continuous H2 supply (95% availability) at industrial-scale quantities (100 tonnes/day) in 2030 from integrating commodity technologies for solar photovoltaics electrolysis and energy storage. Our approach relies on modeling the least-cost plant design and operation that optimize component sizes while adhering to hourly solar availability production requirements and component inter-temporal operating constraints. We apply the model to study H2 production costs spanning the continental United States and through extensive sensitivity analysis explore system configurations that can achieve $2.5/kg levelized costs or less for a range of plausible 2030 technology projections at high-irradiance locations. Notably we identify potential sites and system configurations where PV-electrolytic H2 could substitute natural gas-derived H2 at avoided CO2 costs (%$120/ton) similar to the cost of deploying carbon capture and sequestration.
Repurposing Pipelines for Hydrogen: Legal and Policy Considerations
Nov 2022
Publication
As the world looks to implement the Energy Transition repurposing existing fossil fuel infrastructure to produce or distribute “clean” energy will be critical. The most promising is using natural gas pipelines for moving hydrogen. This is the cheapest and fastest method of transport and reducing the cost of transporting hydrogen is a key step in making it economically viable. However while there are technical challenges the greater challenge is in the legal arena. This paper seeks to outline the numerous legal — treaty statutory and contractual — and regulatory obstacles to repurposing natural gas pipelines for hydrogen transport. Gas pipelines exist in a complex microclimate of international public and private law and domestic law and contracts. Ownership is often layered and tangled; financing doubly so; and myriad state interests compound the private interests including national security concerns energy supply imperatives and geopolitical balance. State aid — investment subsidies and tax breaks — may encumber the project with additional legal obligations. And the contracts that control the development of a pipeline project may inject further legal complexity such as dispute mediation procedures and fora and applicable law. This paper seeks to map all the likely areas of future conflict or difficulty so that work on developing the requisite legal regime and remedies to permit use of natural gas pipelines for hydrogen transport can begin now. For policy and lawmakers as well as the private sector evaluating these known unknowns is a good starting point for reconsidering legislation regulation contracts and project risk in preparation for the future probability of hydrogen pipelines.
Fission Battery Markets and Economic Requirements
Oct 2022
Publication
Fission Batteries (FBs) are nuclear reactors for customers with heat demands less than 250 MWt—replacing oil and natural gas in a low-carbon economy. Individual FBs would have outputs between 5 and 30 MWt. The small FB size has two major benefits: (1) the possibility of mass production and (2) ease of transport and leasing with return of used FBs to factory for refurbishing and reuse. Comparatively these two features are lacking in larger conventional reactors. Larger reactors are not transportable and thus can’t obtain the manufacturing economics possible with mass production or the operational advantages of returning the FB to the factory after use. Leasing places the regulatory maintenance and fuel-cycle burden on the leasing company that is minimized by large-fleet operations of identical units. The markets and economic requirements for FBs were examined. The primary existing markets are industrial biofuels off-grid electricity and container ships. Two major future markets were identified—advanced biofuels and hydrogen. In a low-carbon world the competitive price range for heat is $20–50/MWh ($6–15/million BTU) and $70–115/MWh for non-grid electricity. The primary competition in these sectors is likely to be biofuels and hydrogen produced using alternative energy sources—grid electricity is non-competitive. Larger users of energy have alternative low-carbon energy choices including modular nuclear reactors and fossil fuels with carbon capture and sequestration (CCS).
Alternative-energy-vehicles Deployment Delivers Climate, Air Quality, and Health Co-benefits when Coupled with Decarbonizing Power Generation in China
Aug 2021
Publication
China is the world’s largest carbon emitter and suffers from severe air pollution which results in approximately one million premature deaths/year. Alternative energy vehicles (AEVs) (electric hydrogen fuel cell and natural gas vehicles) can reduce carbon emissions and improve air quality. However climate air quality and health benefits of AEVs powered with deeply decarbonized power generation are poorly quantified. Here we quantitatively estimate the air quality health carbon emission and economic benefits of replacing internal combustion engine vehicles with various AEVs. We find co-benefits increase dramatically as the electricity grid decarbonizes and hydrogen is produced from non-fossil fuels. Relative to 2015 a conversion to AEVs using largely non-fossil power can reduce air pollution and associated premature mortalities and years of life lost by 329000 persons/year and 1611000 life years/year. Thus maximizing climate air quality and health benefits of AEV deployment in China requires rapid decarbonization of the power system.
Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
Oct 2021
Publication
Consumption of fossil fuels especially in transport and energy-dependent sectors has led to large greenhouse gas production. Hydrogen is an exciting energy source that can serve our energy purposes and decrease toxic waste production. Decomposition of methane yields hydrogen devoid of COx components thereby aiding as an eco-friendly approach towards large-scale hydrogen production. This review article is focused on hydrogen production through thermocatalytic methane decomposition (TMD) for hydrogen production. The thermodynamics of this approach has been highlighted. Various methods of hydrogen production from fossil fuels and renewable resources were discussed. Methods including steam methane reforming partial oxidation of methane auto thermal reforming direct biomass gasification thermal water splitting methane pyrolysis aqueous reforming and coal gasification have been reported in this article. A detailed overview of the different types of catalysts available the reasons behind their deactivation and their possible regeneration methods were discussed. Finally we presented the challenges and future perspectives for hydrogen production via TMD. This review concluded that among all catalysts nickel ruthenium and platinum-based catalysts show the highest activity and catalytic efficiency and gave carbon-free hydrogen products during the TMD process. However their rapid deactivation at high temperatures still needs the attention of the scientific community.
Electric Aircraft Fueled by Liquid Hydrogen and Liquefied Natural Gas
Jul 2021
Publication
The paper is a review of the opportunities and challenges of cryogenic power devices of electric aircraft and the ongoing research and development efforts of the government agencies and the industry. Liquid Hydrogen (LH2) and Liquefied Natural Gas (LNG) are compared to support high temperature superconducting (HTS) and normal metal devices respectively. The power devices were assumed to operate at the normal boiling point of the fuel used. The efficiencies of the electrical devices are estimated based on state-of-the-art technology. The mass flow rates and total fuel requirements for both the cryogenic fuels required to maintain the operating temperatures of the devices were simulated using thermal network models. A twin-aisle 300 passenger aircraft with a 5.5 h flight duration was used for the models. The results show that the required masses of LH2 and LNG are 744 kg and 13638 kg respectively for the cooling requirement. The corresponding volumes of LH2 and LNG required are 9760 and 30300 L respectively. In both cases the estimated mass of the fuel needed for the aircraft is more than what is needed to maintain the cryogenic environment of the power devices. It was concluded that an electric aircraft with LNG cooled normal metal devices is feasible. However an aircraft with HTS devices and cooled with LH2 is more attractive if the ongoing R&D efforts on HTS devices and LH2 infrastructure are successful. The emission reductions would be substantially higher with LH2 particularly when H2 is produced using renewable energy sources.
The Hydrogen Economy and Jobs of the Future
Nov 2018
Publication
Growth in the hydrogen and fuel cell industries will lead to vast new employment opportunities and these will be created in a wide variety of industries skills tasks and earnings. Many of these jobs do not currently exist and do not have occupational titles defined in official classifications. In addition many of these jobs require different skills and education than current jobs and training requirements must be assessed so that this rapidly growing part of the economy has a sufficient supply of trained and qualified workers. We discuss the current hydrogen economy and technologies. We then identify by occupational titles the new jobs that will be created in the expanding hydrogen/fuel cell economy estimate the average US salary for each job identify the minimum educational attainment required to gain entry into that occupation and specify the recommended university degree for the advanced educational requirements. We provide recommendations for further research.
Water Electrolysis: From Textbook Knowledge to the Latest Scientific Strategies and Industrial Developments
May 2022
Publication
Replacing fossil fuels with energy sources and carriers that are sustainable environmentally benign and affordable is amongst the most pressing challenges for future socio-economic development. To that goal hydrogen is presumed to be the most promising energy carrier. Electrocatalytic water splitting if driven by green electricity would provide hydrogen with minimal CO2 footprint. The viability of water electrolysis still hinges on the availability of durable earth-abundant electrocatalyst materials and the overall process efficiency. This review spans from the fundamentals of electrocatalytically initiated water splitting to the very latest scientific findings from university and institutional research also covering specifications and special features of the current industrial processes and those processes currently being tested in large-scale applications. Recently developed strategies are described for the optimisation and discovery of active and durable materials for electrodes that ever-increasingly harness first principles calculations and machine learning. In addition a technoeconomic analysis of water electrolysis is included that allows an assessment of the extent to which a large-scale implementation of water splitting can help to combat climate change. This review article is intended to cross-pollinate and strengthen efforts from fundamental understanding to technical implementation and to improve the ‘junctions’ between the field’s physical chemists materials scientists and engineers as well as stimulate much-needed exchange among these groups on challenges encountered in the different domains.
A New Model for Constant Fuel Utilization and Constant Fuel Flow in Fuel Cells
Mar 2019
Publication
This paper presents a new model of fuel cells for two different modes of operation: constant fuel utilization control (constant stoichiometry condition) and constant fuel flow control (constant flow rate condition). The model solves the long-standing problem of mixing reversible and irreversible potentials (equilibrium and non-equilibrium states) in the Nernst voltage expression. Specifically a Nernstian gain term is introduced for the constant fuel utilization condition and it is shown that the Nernstian gain is an irreversibility in the computation of the output voltage of the fuel cell. A Nernstian loss term accounts for an irreversibility for the constant fuel flow operation. Simulation results are presented. The model has been validated against experimental data from the literature.
Low Carbon Scenario Analysis of a Hydrogen-Based Energy Transition for On-Road Transportation in California
Nov 2021
Publication
Fuel cell electric vehicles (FCEV) are emerging as one of the prominent zero emission vehicle technologies. This study follows a deterministic modeling approach to project two scenarios of FCEV adoption and the resulting hydrogen demand (low and high) up to 2050 in California using a transportation transition model. The study then estimates the number of hydrogen production and refueling facilities required to meet demand. The impact of system scale-up and learning rates on hydrogen price is evaluated using standalone supply chain models: H2A HDSAM HRSAM and HDRSAM. A sensitivity analysis explores key factors that affect hydrogen prices. In the high scenario light and heavy-duty fuel cell vehicle stocks reach 12.5 million and 1 million by 2050 respectively. The resulting annual hydrogen demand is 3.9 billion kg making hydrogen the dominant transportation fuel. Satisfying such high future demands will require rapid increases in infrastructure investments starting now but especially after 2030 when there is an exponential increase in the number of production plants and refueling stations. In the long term electrolytic hydrogen delivered using dedicated hydrogen pipelines to larger stations offers substantial cost savings. Feedstock prices size of the hydrogen market and station utilization are the prominent parameters that affect hydrogen price.
Everything About Hydrogen Podcast: Why the Fuel Cell World is Different This Time
Aug 2019
Publication
The fuel cell game is not new and for many it is has been a long time coming. Few know this better than Ballard Power Systems the third ever founded Fuel Cell company that has operated since the 1970s. On the show we ask Nicolas Pocard about Ballards history and why this time the market is different for fuel cell companies.
The podcast can be found on their website
The podcast can be found on their website
Hydrogen Storage Assessment in Depleted Oil Reservoir and Saline Aquifer
Oct 2022
Publication
Hydrogen (H2 ) is an attractive energy carrier to move store and deliver energy in a form that can be easily used. Field proven technology for underground hydrogen storage (UHS) is essential for a successful hydrogen economy. Options for this are manmade caverns salt domes/caverns saline aquifers and depleted oil/gas fields where large quantities of gaseous hydrogen have been stored in caverns for many years. The key requirements intrinsic of a porous rock formation for seasonal storage of hydrogen are: adequate capacity ability to contain H2 capability to inject/extract high volumes of H2 and a reliable caprock to prevent leakage. We have carefully evaluated a commercial non-isothermal compositional gas reservoir simulator and its suitability for hydrogen storage and withdrawal from saline aquifers and depleted oil/gas reservoirs. We have successfully calibrated the gas equation of state model against published laboratory H2 density and viscosity data as a function of pressure and temperature. Comparisons between the H2 natural gas and CO2 storage in real field models were also performed. Our numerical models demonstrated more lateral spread of the H2 when compared to CO2 and natural gas with a need for special containment in H2 projects. It was also observed that the experience with CO2 and natural gas storage cannot be simply replicated with H2 .
The Role of LNG in the Transition Toward Low- and Zero-carbon Shipping
Apr 2021
Publication
Due to its much lower air pollution and potential greenhouse gas (GHG) emissions benefits liquefied natural gas (LNG) is frequently discussed as a fuel pathway towards greener maritime transport. While LNG’s air quality improvements are undeniable there is debate within the sector as to what extent LNG may be able to contribute to decarbonizing shipping. This report “The Role of LNG in the Transition Toward Low- and Zero-Carbon Shipping” considers the potential of LNG to play either a transitional role in which existing LNG infrastructure and vessels could continue to be used with compatible zero-carbon bunker fuels after 2030 or a temporary one in which LNG would be rapidly supplanted by zero-carbon alternatives from 2030. Over concerns about methane leakage which could diminish or even offset any GHG benefits associated with LNG and additional capital expenditures the risk of stranded assets as well as a technology lock-in the report concludes that LNG is unlikely to play a significant role in decarbonizing maritime transport. Instead the research finds that LNG is likely to only be used in niche shipping applications or in its non-liquefied form as a feedstock to kickstart the production of zero-carbon bunker fuels when used in conjunction with carbon capture and storage technology. The research further suggests that new public policy in support of LNG as a bunker fuel should be avoided existing policy support should be reconsidered and methane emissions should be regulated.
Everything About Hydrogen Podcast: Taking Hydrogen off the Grid
Jun 2022
Publication
On this episode of Everything About Hydrogen we chat with Andrew Cunningham Founder and Director at GeoPura. GeoPura is enabling the production transport and use of zero-emissions fuels with innovative and commercially viable technology to decarbonise the global economy. As the world transitions away from fossils fuels there is an increasing need for reliable clean electricity. If global power demand continues to grow as expected the electricity grid system will need support from renewable energy sources such as hydrogen and fuel cell power generator. GeoPura seeks to address exactly that kind of need.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Decarbonizing Steel and Industrial Manufacturing
May 2022
Publication
H2 Green Steel was founded in 2020 with the aim to build a large-scale green steel production in northern Sweden. H2 Green Steel is on a mission to undertake the global steel industry’s greatest ever technological shift. By 2024 H2 Green Steel will be in production at their Boden site and by 2030 will produce five million tonnes of green steel annually. Vargas co-founder and a major shareholder in Northvolt is also H2 Green Steel’s founder and largest shareholder. The EAH team speaks with Kajsa Ryttberg-Wallgren head of the Hydrogen Business Unit at H2 Green Steel.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: So, What's the Big Deal with Hydrogen?
Aug 2019
Publication
This episode is a whistle-stop tour of the hydrogen world. The team explore why hydrogen is making a resurgence as an energy carrier how decarbonising the existing hydrogen market is a huge opportunity and how fuel cells fit into the story.
The podcast can be found on their website
The podcast can be found on their website
A Global Review of the Hydrogen Energy Eco-System
Feb 2023
Publication
Climate change primarily caused by the greenhouse gases emitted as a result of the consumption of carbon-based fossil fuels is considered one of the biggest challenges that humanity has ever faced. Moreover the Ukrainian crisis in 2022 has complicated the global energy and food status quo more than ever. The permanency of this multifaceted fragility implies the need for increased efforts to have energy independence and requires long-term solutions without fossil fuels through the use of clean zero-carbon renewables energies. Hydrogen technologies have a strong potential to emerge as an energy eco-system in its production-storage-distribution-utilization stages with its synergistic integration with solar-wind-hydraulic-nuclear and other zero-carbon clean renewable energy resources and with the existing energy infrastructure. In this paper we provide a global review of hydrogen energy need related policies practices and state of the art for hydrogen production transportation storage and utilization.
Transition to Renewable Energy for Communities: Energy Storage Requirements and Dissipation
Aug 2022
Publication
The transition of residential communities to renewable energy sources is one of the first steps for the decarbonization of the energy sector the reduction of CO2 emissions and the mitigation of global climate change. This study provides information for the development of a microgrid supplied by wind and solar energy which meets the hourly energy demand of a community of 10000 houses in the North Texas region; hydrogen is used as the energy storage medium. The results are presented for two cases: (a) when the renewable energy sources supply only the electricity demand of the community and (b) when these sources provide the electricity as well as the heating needs (for space heating and hot water) of the community. The results show that such a community can be decarbonized with combinations of wind and solar installations. The energy storage requirements are between 2.7 m3 per household and 2.2 m3 per household. There is significant dissipation in the storage–regeneration processes—close to 30% of the current annual electricity demand. The entire decarbonization (electricity and heat) of this community will result in approximately 87500 tons of CO2 emissions avoidance.
Everything About Hydrogen Podcast: Hydrogen on a Global Scale
Aug 2022
Publication
On today’s episode of Everything About Hydrogen we are speaking with Dan Sadler Vice President for UK Low Carbon Solutions at Equinor. Equinor is of course a giant in the global energy sector and is taking a prominent role in the development of the international hydrogen economy with high-profile investments in a number of large-scale production projects in major markets such as the UK. Dan has spent the better part of a decade focused on how to leverage hydrogen’s potential as a fuel for the energy transition and we are excited to have him with us to discuss how Equinor is deploying hydrogen technologies and how he and Equinor expect hydrogen to play a role in a decarbonized energy future.
The podcast can be found on their website.
The podcast can be found on their website.
Enabling Safe and Sustainable Hydrogen Mobility: Circular Economy-Driven Management of Hydrogen Vehicle Safety
Sep 2023
Publication
Hydrogen vehicles encompassing fuel cell electric vehicles (FCEVs) are pivotal within the UK’s energy landscape as it pursues the goal of net-zero emissions by 2050. By markedly diminishing dependence on fossil fuels FCEVs including hydrogen vehicles wield substantial influence in shaping the circular economy (CE). Their impact extends to optimizing resource utilization enabling zero-emission mobility facilitating the integration of renewable energy sources supplying adaptable energy storage solutions and interconnecting diverse sectors. The widespread adoption of hydrogen vehicles accelerates the UK’s transformative journey towards a sustainable CE. However to fully harness the benefits of this transition a robust investigation and implementation of safety measures concerning hydrogen vehicle (HV) use are indispensable. Therefore this study takes a holistic approach integrating quantitative risk assessment (QRA) and an adaptive decision-making trial and evaluation laboratory (DEMATEL) framework as pragmatic instruments. These methodologies ensure both the secure deployment and operational excellence of HVs. The findings underscore that the root causes of HV failures encompass extreme environments material defects fuel cell damage delivery system impairment and storage system deterioration. Furthermore critical driving factors for effective safety intervention revolve around cultivating a safety culture robust education/training and sound maintenance scheduling. Addressing these factors is pivotal for creating an environment conducive to mitigating safety and risk concerns. Given the intricacies of conducting comprehensive hydrogen QRAs due to the absence of specific reliability data this study dedicates attention to rectifying this gap. A sensitivity analysis encompassing a range of values is meticulously conducted to affirm the strength and reliability of our approach. This robust analysis yields precise dependable outcomes. Consequently decision-makers are equipped to discern pivotal underlying factors precipitating potential HV failures. With this discernment they can tailor safety interventions that lay the groundwork for sustainable resilient and secure HV operations. Our study navigates the intersection of HVs safety and sustainability amplifying their importance within the CE paradigm. Using the careful amalgamation of QRA and DEMATEL methodologies we chart a course towards empowering decision-makers with the insights to steer the hydrogen vehicle domain to safer horizons while ushering in an era of transformative eco-conscious mobility.
Designing Off-grid Green Hydrogen Plants Using Dynamic Polymer Electrolyte Membrane Electrolyzers to Minimize the Hydrogen Production Cost
Oct 2023
Publication
Hydrogen produced from electrolysis is an attractive carbon-free fuel and feedstock but potential benefits depend on the carbon intensity of electricity production. This study uses technoeconomic modeling to analyze the benefits of producing zero-carbon hydrogen through dynamically operated polymer electrolyte membrane electrolyzers connected to photovoltaic and wind variable renewable energy (VRE) sources. Dynamic operation is considered for current densities between 0 and 6 A cm2 and compared to a constant current density of 2 A cm2 for different combinations of VRE to electrolysis (VRE:E) capacity ratios and compositions of photovoltaic and wind energy in four locations across the United States. For optimal VRE:E and wind:photovoltaic capacity ratios dynamic operation is found to reduce the levelized cost of hydrogen by 5%–9% while increasing hydrogen production by 134%–173% and decreasing excess electrical power by 82%–95%. The framework herein may be used to determine the optimal VRE:E capacity and VRE mix for dynamically operated green hydrogen systems.
Dispersion, Ignition and Combustion Characteristics of Low-pressure Hydrogen-Methane Blends
Sep 2023
Publication
In this paper we study the dispersion ignition and flame characteristics of blended jets of hydrogen and methane (as a proxy for natural gas) at near-atmospheric pressure for a fixed volumetric flow rate which mimics the scenario of a small-scale unintended leak. A reduction in flame height is observed with increasing hydrogen concentration. A laser is tightly focused to generate a spark with sufficient energy to ignite the fuel. The light-up boundary defined as the delineating location at which a spark ignites into a jet flame or extinguishes is determined as a contour. The light-up boundary increases in both width and length as the hydrogen content increases up to 75% hydrogen at which point the axial ignition boundary decreases slightly for pure hydrogen relative to 75% hydrogen. Ignition probability a key parameter regarding safety is computed at various axial locations and is also shown to be higher near the nozzle as well as non-zero at further downstream locations as the hydrogen content in the blend increases. Planar laser Raman scattering is used in separate experiments to determine the concentration of both fuel species. Mean fuel concentrations well below the lower flammability limit are both within the light-up boundary and have non-zero ignition probabilities.
U.S. National Clean Hydrogen Strategy and Roadmap
Jun 2023
Publication
The U.S. National Clean Hydrogen Strategy and Roadmap explores opportunities for clean hydrogen to contribute to national decarbonization goals across multiple sectors of the economy. It provides a snapshot of hydrogen production transport storage and use in the United States today and presents a strategic framework for achieving large-scale production and use of clean hydrogen examining scenarios for 2030 2040 and 2050.
The Strategy and Roadmap also identifies needs for collaboration among federal government agencies industry academia national laboratories state local and Tribal communities environmental and justice communities labor unions and numerous stakeholder groups to accelerate progress and market liftoff. This roadmap establishes concrete targets market-driven metrics and tangible actions to measure success across sectors.
The Strategy and Roadmap responds to legislative language set forth in section 40314 of the Infrastructure Investment and Jobs Act (Public Law 117-58) also known as the Bipartisan Infrastructure Law (BIL). This document was posted for in draft form for public comment in September 2022 and the final version of the report was informed by stakeholder feedback further analysis on market liftoff as well as engagement across several federal agencies and the White House Climate Policy Office. There will also be future opportunities for stakeholder feedback as the report will be updated at least every three years as required by the BIL.
The report can be found on their website.
The Strategy and Roadmap also identifies needs for collaboration among federal government agencies industry academia national laboratories state local and Tribal communities environmental and justice communities labor unions and numerous stakeholder groups to accelerate progress and market liftoff. This roadmap establishes concrete targets market-driven metrics and tangible actions to measure success across sectors.
The Strategy and Roadmap responds to legislative language set forth in section 40314 of the Infrastructure Investment and Jobs Act (Public Law 117-58) also known as the Bipartisan Infrastructure Law (BIL). This document was posted for in draft form for public comment in September 2022 and the final version of the report was informed by stakeholder feedback further analysis on market liftoff as well as engagement across several federal agencies and the White House Climate Policy Office. There will also be future opportunities for stakeholder feedback as the report will be updated at least every three years as required by the BIL.
The report can be found on their website.
Economic Assessment of Clean Hydrogen Production from Fossil Fuels in the Intermountain-west Region, USA
Jan 2024
Publication
The transition from fossil fuels to carbon-neutral energy sources is necessary to reduce greenhouse gas (GHG) emissions and combat climate change. Hydrogen (H2) provides a promising path to harness fossil fuels to reduce emissions in sectors such as transportation. However regional economic analyses of various H2 production techniques are still lacking. We selected a well-known fossil fuel-exporting region the USA’s Intermountain-West (I-WEST) to analyze the carbon intensity of H2 production and demonstrate regional tradeoffs. Currently 78 % of global H2 production comes from natural gas and coal. Therefore we considered steam methane reforming (SMR) surface coal gasification (SCG) and underground coal gasification (UCG) as H2 production methods in this work. We developed the cost estimation frameworks of SMR SCG and UCG with and without carbon capture utilization and sequestration (CCUS). In addition we identified optimal sites for H2 hubs by considering the proximity to energy sources energy markets storage sites and CO2 sequestration sites. We included new production tax credits (PTCs) in the cost estimation to quantify the economic benefit of CCUS. Our results suggest that the UCG has the lowest levelized cost of H2 production due to the elimination of coal production cost. H2 production using the SMR process with 99 % carbon capture is profitable when the PTCs are considered. We also analyzed carbon utilization opportunities where CO2 conversion to formic acid is a promising profitable option. This work quantifies the potential of H2 production from fossil fuels in the I-WEST region a key parameter for designing energy transition pathways.
Natural Hydrogen in the Energy Transition: Fundamentals, Promise, and Enigmas
Oct 2023
Publication
Beyond its role as an energy vector a growing number of natural hydrogen sources and reservoirs are being discovered all over the globe which could represent a clean energy source. Although the hydrogen amounts in reservoirs are uncertain they could be vast and they could help decarbonize energy-intensive economic sectors and facilitate the energy transition. Natural hydrogen is mainly produced through a geochemical process known as serpentinization which involves the reaction of water with low-silica ferrous minerals. In favorable locations the hydrogen produced can become trapped by impermeable rocks on its way to the atmosphere forming a reservoir. The safe exploitation of numerous natural hydrogen reservoirs seems feasible with current technology and several demonstration plants are being commissioned. Natural hydrogen may show variable composition and require custom separation purification storage and distribution facilities depending on the location and intended use. By investing in research in the mid-term more hydrogen sources could become exploitable and geochemical processes could be artificially stimulated in new locations. In the long term it may be possible to leverage or engineer the interplay between microorganisms and geological substrates to obtain hydrogen and other chemicals in a sustainable manner.
Visualisation and Quantification of Wind-induced Variability in Hydrogen Clouds Following Releases of Liquid Hydrogen
Sep 2023
Publication
Well characterized experimental data for consequence model validation is important in progressing the use of liquid hydrogen as an energy carrier. In 2019 the Health and Safety Executive (HSE) undertook a series of liquid hydrogen dispersion and combustion experiments as a part of the Pre-normative Research for Safe Use of Liquid Hydrogen (PRESLHY) project. In partnership between the National Renewable Energy Laboratory (NREL) and HSE time and spatially varying hydrogen concentration measurements were made in 25 dispersion experiments and 23 congested ignition experiments associated with PRESLHY WP3 and WP5 respectively. These measurements were undertaken using the hydrogen wide area monitoring system developed by NREL. During the 23 congested ignition experiments high variability was observed in the measured explosion severity during experiments with similar initial conditions. This led to the conclusion that wind including localized gusts had a large influence on the dispersion of the hydrogen and therefore the quantity of hydrogen that was present in the congested region of the explosions. Using the hydrogen concentration measurements taken immediately prior to ignition the hydrogen clouds were visualized in an attempt to rationalize the variability in overpressure between the tests. Gaussian process regression was applied to quantify the variability of the measured hydrogen concentrations. This analysis could also be used to guide modifications in experimental designs for future research on hydrogen combustion behavior.
Deploying Green Hydrogen to Decarbonize China's Coal Chemical Sector
Dec 2023
Publication
China’s coal chemical sector uses coal as both a fuel and feedstock and its increasing greenhouse gas (GHG) emissions are hard to abate by electrification alone. Here we explore the GHG mitigation potential and costs for onsite deployment of green H2 and O2 in China’s coal chemical sector using a lifecycle assessment and techno-economic analyses. We estimate that China’s coal chemical production resulted in GHG emissions of 1.1 gigaton CO2 equivalent (GtCO2eq) in 2020 equal to 9% of national emissions. We project GHG emissions from China’s coal chemical production in 2030 to be 1.3 GtCO2eq ~50% of which can be reduced by using solar or wind power-based electrolytic H2 and O2 to replace coal-based H2 and air separation-based O2 at a cost of 10 or 153 Chinese Yuan (CNY)/tCO2eq respectively. We suggest that provincial regions determine whether to use solar or wind power for water electrolysis based on lowest cost options which collectively reduce 53% of the 2030 baseline GHG emissions at a cost of 9 CNY/tCO2eq. Inner Mongolia Shaanxi Ningxia and Xinjiang collectively account for 52% of total GHG mitigation with net cost reductions. These regions are well suited for pilot policies to advance demonstration projects.
Technology Assessment for the Transition to a Renewable Electric Grid
Jun 2024
Publication
To reduce carbon emissions generation of electricity from combustion systems is being replaced by renewable resources. However the most abundant renewable sources – solar and wind – are not dispatchable vary diurnally and are subject to intermittency and produce electricity at times in excess of demand (excess production). To manage this variability and capture the excess renewable energy energy storage technologies are being developed and deployed such as battery energy storage (BES) hydrogen production with electrolyzers (ELY) paired with hydrogen energy storage (HES) and fuel cells (FCs) and renewable natural gas (RNG) production. While BES may be better suited for short duration storage hydrogen is suited for long duration storage and RNG can decarbonize the natural gas system. California Senate Bill 100 (SB100) sets a goal that all retail electricity sold in the State must be sourced from renewable and zero-carbon resources by 2045 raising the questions of which set of technologies and in what proportion are required to meet the 2045 target in the required timeframe as well as the role of the natural gas infrastructure if any. To address these questions this study combines electric grid dispatch modeling and optimization to identify the energy storage and dispatchable technologies in 5-year increments from 2030 to 2045 required to transition from a 60% renewable electric grid in 2035 to a 100% renewable electric grid in 2045. The results show that by utilizing the established natural gas system to store and transmit hydrogen and RNG the deployment of battery energy storage is dramatically reduced. The required capacity for BES in 2045 for example is 40 times lower by leveraging the natural gas infrastructure with a concomitant reduction in cost and associated challenges to transform the electric grid.
A Review of Ni Based Powder Catalyst for Urea Oxidation in Assisting Water Splitting Reaction
Jan 2022
Publication
Water splitting has been regarded as a sustainable and environmentally-friendly technique to realize green hydrogen generation while more energy is consumed due to the high overpotentials required for the anode oxygen evolution reaction. Urea electrooxidation an ideal substitute is thus received increasing attention in assisting water-splitting reactions. Note that highly efficient catalysts are still required to drive urea oxidation and the facile generation of high valence state species is significant in the reaction based on the electrochemical-chemical mechanisms. The high cost and rareness make the noble metal catalysts impossible for further consideration in large-scale application. Ni-based catalysts are very promising due to their cheap price facile structure tuning good compatibility and easy active phase formation. In the light of the significant advances made recently herein we reviewed the recent advances of Ni-based powder catalysts for urea oxidation in assisting water-splitting reaction. The fundamental of urea oxidation is firstly presented to clarify the mechanism of urea-assisted water splitting and then the prevailing evaluation indicators are briefly expressed based on the electrochemical measurements. The catalyst design principle including synergistic effect electronic effect defect construction and surface reconstruction as well as the main fabrication approaches are presented and the advances of various Ni-based powder catalysts for urea assisted water splitting are summarized and discussed. The problems and challenges are also concluded for the Ni-based powder catalysts fabrication the performance evaluation and their application. Considering the key influence factors for catalytic process and their application attention should be given to structure-property relationship deciphering novel Ni-based powder catalysts development and their construction in the real device; specifically the effort should be directed to the Ni-based powder catalyst with multi-functions to simultaneously promote the fundamental steps and high anti-corrosion ability by revealing the local structure reconstruction as well as the integration in the practical application. We believe the current summarization will be instructive and helpful for the Ni-based powder catalysts development and understanding their catalytic action for urea-assisted hydrogen generation via water splitting technique.
A Review of the Status of Fossil and Renewable Energies in Southeast Asia and Its Implications on the Decarbonization of ASEAN
Mar 2022
Publication
The ten nations of Southeast Asia collectively known as ASEAN emitted 1.65 Gtpa CO2 in 2020 and are among the most vulnerable nations to climate change which is partially caused by anthropogenic CO2 emission. This paper analyzes the history of ASEAN energy consumption and CO2 emission from both fossil and renewable energies in the last two decades. The results show that ASEAN’s renewable energies resources range from low to moderate are unevenly distributed geographically and contributed to only 20% of total primary energy consumption (TPEC) in 2015. The dominant forms of renewable energies are hydropower solar photovoltaic and bioenergy. However both hydropower and bioenergy have substantial sustainability issues. Fossil energies depend heavily on coal and oil and contribute to 80% of TPEC. More importantly renewable energies’ contribution to TPEC has been decreasing in the last two decades despite the increasing installation capacity. This suggests that the current rate of the addition of renewable energy capacity is inadequate to allow ASEAN to reach net-zero by 2050. Therefore fossil energies will continue to be an important part of ASEAN’s energy mix. More tools such as carbon capture and storage (CCS) and hydrogen will be needed for decarbonization. CCS will be needed to decarbonize ASEAN’s fossil power and industrial plants while blue hydrogen will be needed to decarbonize hard-to-decarbonize industrial plants. Based on recent research into regional CO2 source-sink mapping this paper proposes six large-scale CCS projects in four countries which can mitigate up to 300 Mtpa CO2 . Furthermore this paper identifies common pathways for ASEAN decarbonization and their policy implications.
Integrated Power and Propulsion System Optimization for a Planetary-Hopping Robot
Aug 2022
Publication
Missions targeting the extreme and rugged environments on the moon and Mars have rich potential for a high science return although several risks exist in performing these exploration missions. The current generation of robots is unable to access these high-priority targets. We propose using teams of small hopping and rolling robots called SphereX that are several kilograms in mass and can be carried by a large rover or lander and tactically deployed for exploring these extreme environments. Considering that the importance of minimizing the mass and volume of these robot platforms translates into significant mission-cost savings we focus on the optimization of an integrated power and propulsion system for SphereX. Hydrogen is used as fuel for its high energy and it is stored in the form of lithium hydride and oxygen in the form of lithium perchlorate. The system design undergoes optimization using Genetic Algorithms integrated with gradient-based search techniques to find optimal solutions for a mission. Our power and propulsion system as we show in this paper is enabling because the robots can travel long distances to perform science exploration by accessing targets not possible with conventional systems. Our work includes finding the optimal mass and volume of SphereX such that it can meet end-to-end mission requirements.
Molten Carbonate Fuel Cells for Simultaneous CO2 Capture, Power Generation, and H2 Generation
Mar 2022
Publication
This article presents a new technology for the generation of power and steam or other process heat with very low CO2 emissions. It is well known that cogeneration of electricity and steam is highly efficient and that amine units can be used to remove CO2 from combustion flue gas but that the amine unit consumes a significant amount of steam and power reducing the overall system efficiency. In this report the use of molten carbonate fuel cells (MCFCs) to capture CO2 from cogen units is investigated and shown to be highly efficient due to the additional power that they produce while capturing the CO2. Furthermore the MCFCs are capable of reforming methane to hydrogen simultaneous to the power production and CO2 capture. This hydrogen can either be recycled as fuel for consumption by the cogen or MCFCs or exported to an independent combustion unit as low carbon fuel thereby decarbonizing that unit as well. The efficiency of MCFCs for CO2 capture is higher than use of amines in all cases studied often by a substantial margin while at the same time the MCFCs avoid more CO2 than the amine technology. As one example the use of amines on a cogeneration unit can avoid 87.6% of CO2 but requires 4.91 MJ/kg of additional primary energy to do so. In contrast the MCFCs avoid 89.4% of CO2 but require only 1.37 MJ/kg of additional primary energy. The high thermal efficiency and hydrogen export option demonstrate the potential of this technology for widespread deployment in a low carbon energy economy.
Numerical Modelling of H2 Storage with Cushion Gas of CO2 in Subsurface Porous Media: Filter Effects of CO2 Solubility
Jun 2022
Publication
The central objective of this study is to improve the understanding of flow behaviour during hydrogen (H2) storage in subsurface porous media with a cushion gas of carbon dioxide (CO2). In this study we investigate the interactions between various factors driving the flow behaviour including the underlying permeability heterogeneity viscous instability and the balance between the viscous and gravity forces. In particular we study the impact of CO2 solubility in water on the level of H2 purity. This effect is demonstrated for the first time in the context of H2 storage. We have performed a range of 2D vertical cross-sectional simulations at the decametre scale with a very fine cell size (0.1 m) to capture the flow behaviour in detail. This is done since it is at this scale that much of the mixing between injected and native fluids occurs in physical porous media. It is found that CO2 solubility may have different (positive and negative) impacts on the H2 recovery performance (i.e. on the purity of the produced H2) depending on the flow regimes in the system. In the viscous dominated regime the less viscous H2 may infiltrate and bypass the cushion gas of CO2 during the period of H2 injection. This leads to a quick and dramatic reduction in the H2 purity when back producing H2 due to the co-production of the previously bypassed CO2. Interestingly the impurity levels in the H2 are much less severe in the case when CO2 solubility in water is considered. This is because the bypassed CO2 will redissolve into the water surrounding the bypassed zones which greatly retards the movement of CO2 towards the producer. In the gravity dominated scenario H2 accumulates at the top of the model and displaces the underlying cushion gas in an almost piston-like fashion. Approximately 58% of H2 can be recovered at a purity level above 98% (combustion requirements by ISO) in this gravity-dominated case. However when CO2 solubility is considered the H2 recovery performance is slightly degraded. This is because the dissolved CO2 is also gradually vaporised during H2 injection which leads to an expansion of mixing zone of CO2 and H2. This in turn reduces the period of high H2 purity level (>98%) during back-production.
Optimized Configuration of Diesel Engine-Fuel Cell-Battery Hybrid Power Systems in a Platform Supply Vessel to Reduce CO2 Emissions
Mar 2022
Publication
The main objective of this paper is to select the optimal configuration of a ship’s power system considering the use of fuel cells and batteries that would achieve the lowest CO2 emissions also taking into consideration the number of battery cycles. The ship analyzed in this work is a Platform Supply Vessel (PSV) used to support oil and gas offshore platforms transporting goods equipment and personnel. The proposed scheme considers the ship’s retrofitting. The ship’s original main generators are maintained and the fuel cell and batteries are installed as complementary sources. Moreover a sensitivity analysis is pursued on the ship’s demand curve. The simulations used to calculate the CO2 emissions for each of the new hybrid configurations were developed using HOMER software. The proposed solutions are auxiliary generators three types of batteries and a protonexchange membrane fuel cell (PEMFC) with different sizes of hydrogen tanks. The PEMFC and batteries were sized as containerized solutions and the sizing of the auxiliary engines was based on previous works. Each configuration consists of a combination of these solutions. The selection of the best configuration is one contribution of this paper. The new configurations are classified according to the reduction of CO2 emitted in comparison to the original system. For different demand levels the results indicate that the configuration classification may vary. Another valuable contribution of this work is the sizing of the battery and hydrogen storage systems. They were installed in 20 ft containers since the installation of batteries fuel cells and hydrogen tanks in containers is widely used for ship retrofit. As a result the most significant reduction of CO2 emissions is 10.69%. This is achieved when the configuration includes main generators auxiliary generators a 3119 kW lithium nickel manganese cobalt (LNMC) battery a 250 kW PEMFC and 581 kg of stored hydrogen.
Spherically Expanding Flame Simulations in Cantera Using a Lagrangian Formulation
Sep 2021
Publication
A Lagrangian-based one-dimensional approach has been developed using Cantera to study the dynamics of spherically expanding flames. The detailed reaction model USC-Mech II has been employed to examine flame propagating in hydrogen-air mixtures. In the first part our approach has been validated against laminar flame speed and Markstein number data from the literature. It was shown that the laminar flame speed was predicted within 5% on average but that discrepancies were observed for the Markstein number especially for rich mixtures. In the second part a detailed analysis of the thermo-chemical dynamics along the path of Lagrangian particles propagating in stretched flames was performed. For mixtures with negative Markstein lengths it was found that at high stretch rates the mixture entering the reaction-dominated period is less lean with respect to the initial mixture than at low stretch rate. This induces a faster rate of chemical heat release and of active radical production which results in a higher flame propagation speed. Opposite effects were observed for mixtures with positive Markstein lengths for which slower flame propagation was observed at high stretch rates compared to low stretch rates."
Safety and Other Considerations in the Development of a Hydrogen Fueling Protocol for Heavy-duty Vehicles
Sep 2021
Publication
Several manufacturers are developing heavy duty (HD) hydrogen stations and vehicles as zeroemissions alternatives to diesel and gasoline. In order to meet customer demands the new technology must be comparable to conventional approaches including safety reliability fueling times and final fill levels. For a large HD vehicle with a storage rated to 70 MPa nominal working pressure the goal to meet liquid fuel parity means providing 100 kg of hydrogen in 10 minutes. This paper summarizes the results to date of the PRHYDE project efforts to define the concepts of HD fueling which thereby lays the groundwork for the development of the safe and effective approach to filling these large vehicles. The project starts by evaluating the impact of several different assumptions such as the availability of static vehicle data (e.g. vehicle tank type and volume) and station data (e.g. expected station precooling capability) but also considers using real time dynamic data (e.g. vehicle tank gas temperature and pressure station gas temperature etc.) for optimisation to achieve safety and efficiency improvements. With this information the vehicle or station can develop multiple maps of fill time versus the hydrogen delivery temperature which are used to determine the speed of fueling. This will also allow the station or vehicle to adjust the rate of fueling as the station pre-cooling levels and other conditions change. The project also examines different steps for future protocol development such as communication of data between the vehicle and station and if the vehicle or station is controlling the fueling.
1921–2021: A Century of Renewable Ammonia Synthesis
Apr 2022
Publication
Synthetic ammonia manufactured by the Haber–Bosch process and its variants is the key to securing global food security. Hydrogen is the most important feedstock for all synthetic ammonia processes. Renewable ammonia production relies on hydrogen generated by water electrolysis using electricity generated from hydropower. This was used commercially as early as 1921. In the present work we discuss how renewable ammonia production subsequently emerged in those countries endowed with abundant hydropower and in particular in regions with limited or no oil gas and coal deposits. Thus renewable ammonia played an important role in national food security for countries without fossil fuel resources until after the mid-20th century. For economic reasons renewable ammonia production declined from the 1960s onward in favor of fossil-based ammonia production. However renewable ammonia has recently gained traction again as an energy vector. It is an important component of the rapidly emerging hydrogen economy. Renewable ammonia will probably play a significant role in maintaining national and global energy and food security during the 21st century.
A Brief History of Process Safety Management
Sep 2021
Publication
Common root causes are often to be found in many if not most process safety incidents. Whilst largescale events are relatively rare such events can have devastating consequences. The subsequent investigations often uncover that the risks are rarely visible the direct causes are often hidden and that a ‘normalization of deviation’ is a common human characteristic. Process Safety Management (PSM) builds on the valuable lessons learned from past incidents to help prevent future recurrences. An understanding of how PSM originated and has evolved as a discipline over the past 200 years can be instructive when considering the safety implications of emerging technologies. An example is hydrogen production where risks must be effectively identified mitigated and addressed to provide safe production transportation storage and use .
Ammonia Production from Clean Hydrogen and the Implications for Global Natural Gas Demand
Jan 2023
Publication
Non-energy use of natural gas is gaining importance. Gas used for 183 million tons annual ammonia production represents 4% of total global gas supply. 1.5-degree pathways estimate an ammonia demand growth of 3–4-fold until 2050 as new markets in hydrogen transport shipping and power generation emerge. Ammonia production from hydrogen produced via water electrolysis with renewable power (green ammonia) and from natural gas with CO2 storage (blue ammonia) is gaining attention due to the potential role of ammonia in decarbonizing energy value chains and aiding nations in achieving their net-zero targets. This study assesses the technical and economic viability of different routes of ammonia production with an emphasis on a systems level perspective and related process integration. Additional cost reductions may be driven by optimum sizing of renewable power capacity reducing losses in the value chain technology learning and scale-up reducing risk and a lower cost of capital. Developing certification and standards will be necessary to ascertain the extent of greenhouse gas emissions throughout the supply chain as well as improving the enabling conditions including innovative finance and de-risking for facilitating international trade market creation and large-scale project development.
Outlook of Fermentative Hydrogen Production Techniques: An Overview of Dark, Photo and Integrated Dark-photo Fermentative Approach to Biomass
Jan 2019
Publication
Biomass can be a sustainable choice for bioenergy production worldwide. Biohydrogen production using fermentative conversion of biomass has gained great interest during the last decade. Besides being an efficient transportation fuel biohydrogen can also be also be a low-carbon source of heat and electricity. Microbes assisted conversion (bioconversion) can be take place either in presence or absence of light. This is called photofermentation or dark-fermentation respectively. This review provides an overview of approaches of fermentative hydrogen production. This includes: dark photo and integrated fermentative modes of hydrogen production; the molecular basis behind its production and diverse range of its applicability industrially. Mechanistic understanding of the metabolic pathways involved in biomass-based fermentative hydrogen production are also reviewed.
Influence of Non-equilibrium Conditions on Liquid Hydrogen Storage Tank Behavior
Sep 2021
Publication
In a liquid hydrogen storage tank hydrogen vapor exists above the cryogenic liquid. A common modeling assumption of a liquid hydrogen tank is thermodynamic equilibrium. However this assumption may not hold in all conditions. A non-equilibrium storage tank with a pressure relief valve and a burst disc in parallel was modeled in this work. The model includes different boiling regimes to handle scenarios with high heat transfer. The model was first validated with a scenario where normal boil-off from an unused tank was compared to experimental data. Then four abnormal tank scenarios were explored: a loss of vacuum in the insulation layer a high ambient temperature (to simulate an engulfing fire) a high ambient temperature with a simultaneous loss of vacuum and high conduction through the insulation layer. The burst disc of the tank opened only in the cases with extreme heat transfer to the tank (i.e. fire with a loss of vacuum and high insulation conductivity) quickly releasing the hydrogen. In the cases with only a loss of vacuum or only external heat from fire the pressure relief valve on the tank managed to moderate the pressure below the burst disc activation pressure. The high insulation conductivity case highlights differences between the equilibrium and non-equilibrium tank models. The mass loss from the tank through the burst disc is slower using a non-equilibrium model because mass transfer from the liquid to gas phase within the tank becomes limiting. The implications of this model and how it can be used to help inform safety codes and standards are discussed.
Everything About Hydrogen Podcast: Could Electrolysers Replicate Moore's Law?
Apr 2020
Publication
On this weeks episode the team are talking all things hydrogen with Sebastian-Justus Schmidt Chairman of Enapter and Thomas Chrometzka Head of Strategy at Enapter. On the show we discuss Enapter’s Anion Exchange Membrane (AEM) electrolyser and why Enapter believe that their modular electrolyser approach will revolutionise the cost of green hydrogen. We also discuss the wide array of use cases and sectors that Enapter are already working with to provide their solution as well as their view on where the current barriers exist for the hydrogen market. All this and more on the show!
The podcast can be found on their website
The podcast can be found on their website
Analysis to Support Revised Distances between Bulk Liquid Hydrogen Systems and Exposures
Sep 2021
Publication
The minimum distances between exposures and bulk liquid hydrogen listed in the National Fire Protection Agency’s Hydrogen Technology Code NFPA 2 are based on historical consensus without a documented scientific analysis. This work follows a similar analysis as the scientific justification provided in NFPA 2 for exposure distances from bulk gaseous hydrogen storage systems but for liquid hydrogen. Validated physical models from Sandia’s HyRAM software are used to calculate distances to a flammable concentration for an unignited release the distance to critical heat flux values and the visible flame length for an ignited release and the overpressure that would occur for a delayed ignition of a liquid hydrogen leak. Revised exposure distances for bulk liquid hydrogen systems are calculated. These distances are related to the maximum allowable working pressure of the tank and the line size as compared to the current exposure distances which are based on system volume. For most systems the exposure distances calculated are smaller than the current distances for Group 1 they are similar for Group 2 while they increase for some Group 3 exposures. These distances could enable smaller footprints for infrastructure that includes bulk liquid hydrogen storage tanks especially when using firewalls to mitigate Group 3 hazards and exposure distances. This analysis is being refined as additional information on leak frequencies is incorporated and changes have been proposed to the 2023 edition of NFPA 2.
Development of Dispensing Hardware for Safe Fueling of Heavy Duty Vehicles
Sep 2021
Publication
The development of safe dispensing equipment for the fueling of heavy duty (HD) vehicles is critical to the expansion of this newly and quickly expanding market. This paper discusses the development of a HD dispenser and nozzles assembly (nozzle hose breakaway) for these new larger vehicles where flow rates are more than double compared to light duty (LD) vehicles. This equipment must operate at nominal pressures of 700 bar -40o C gas temperature and average flow rate of 5-10 kg/min at a high throughput commercial hydrogen fueling station without leaking hydrogen. The project surveyed HD vehicle manufacturers station developers and component suppliers to determine the basic specifications of the dispensing equipment and nozzle assembly. The team also examined existing codes and standards to determine necessary changes to accommodate HD components. From this information the team developed a set of specifications which will be used to design the dispensing equipment. In order to meet these goals the team performed computational fluid dynamic pressure modelling and temperature analysis in order to determine the necessary parameters to meet existing safety standards modified for HD fueling. The team also considered user operational and maintenance requirements such as freeze lock which has been an issue which prevents the removal of the nozzle from LD vehicles. The team also performed a failure mode and effects analysis (FMEA) to identify the possible failures in the design. The dispenser and nozzle assembly will be tested separately and then installed on an innovative HD fueling station which will use a HD vehicle simulator to test the entire system.
Advances in Hydrogen, Carbon Dioxide, and Hydrocarbon Gas Sensor Technology Using GaN and ZnO-Based Devices
Jun 2009
Publication
In this paper we review our recent results in developing gas sensors for hydrogen using various device structures including ZnO nanowires and GaN High Electron Mobility Transistors (HEMTs). ZnO nanowires are particularly interesting because they have a large surface area to volume ratio which will improve sensitivity and because they operate at low current levels will have low power requirements in a sensor module. GaN-based devices offer the advantage of the HEMT structure high temperature operation and simple integration with existing fabrication technology and sensing systems. Improvements in sensitivity recoverability and reliability are presented. Also reported are demonstrations of detection of other gases including CO2 and C2H4 using functionalized GaN HEMTs. This is critical for the development of lab-on-a-chip type systems and can provide a significant advance towards a market-ready sensor application.
On the Climate Impacts of Blue Hydrogen Production
Nov 2021
Publication
Natural gas based hydrogen production with carbon capture and storage is referred to as blue hydrogen. If substantial amounts of CO2 from natural gas reforming are captured and permanently stored such hydrogen could be a low-carbon energy carrier. However recent research raises questions about the effective climate impacts of blue hydrogen from a life cycle perspective. Our analysis sheds light on the relevant issues and provides a balanced perspective on the impacts on climate change associated with blue hydrogen. We show that such impacts may indeed vary over large ranges and depend on only a few key parameters: the methane emission rate of the natural gas supply chain the CO2 removal rate at the hydrogen production plant and the global warming metric applied. State-of-the-art reforming with high CO2 capture rates combined with natural gas supply featuring low methane emissions does indeed allow for substantial reduction of greenhouse gas emissions compared to both conventional natural gas reforming and direct combustion of natural gas. Under such conditions blue hydrogen is compatible with low-carbon economies and exhibits climate change impacts at the upper end of the range of those caused by hydrogen production from renewable-based electricity. However neither current blue nor green hydrogen production pathways render fully “net-zero” hydrogen without additional CO2 removal.
Hydrogen Blending in Gas Pipeline Networks—A Review
May 2022
Publication
Replacing fossil fuels with non-carbon fuels is an important step towards reaching the ultimate goal of carbon neutrality. Instead of moving directly from the current natural gas energy systems to pure hydrogen an incremental blending of hydrogen with natural gas could provide a seamless transition and minimize disruptions in power and heating source distribution to the public. Academic institutions industry and governments globally are supporting research development and deployment of hydrogen blending projects such as HyDeploy GRHYD THyGA HyBlend and others which are all seeking to develop efficient pathways to meet the carbon reduction goal in coming decades. There is an understanding that successful commercialization of hydrogen blending requires both scientific advances and favorable techno-economic analysis. Ongoing studies are focused on understanding how the properties of methane-hydrogen mixtures such as density viscosity phase interactions and energy densities impact large-scale transportation via pipeline networks and enduse applications such as in modified engines oven burners boilers stoves and fuel cells. The advantages of hydrogen as a non-carbon energy carrier need to be balanced with safety concerns of blended gas during transport such as overpressure and leakage in pipelines. While studies on the short-term hydrogen embrittlement effect have shown essentially no degradation in the metal tensile strength of pipelines the long-term hydrogen embrittlement effect on pipelines is still the focus of research in other studies. Furthermore pressure reduction is one of the drawbacks that hydrogen blending brings to the cost dynamics of blended gas transport. Hence techno-economic models are also being developed to understand the energy transportation efficiency and to estimate the true cost of delivery of hydrogen blended natural gas as we move to decarbonize our energy systems. This review captures key large-scale efforts around the world that are designed to increase the confidence for a global transition to methane-hydrogen gas blends as a precursor to the adoption of a hydrogen economy by 2050.
Everything About Hydrogen Podcast: Producing Hydrogen with Wind Energy
Sep 2022
Publication
On this episode of Everything About Hydrogen we are speaking with David Wellard Regulatory Affairs Manager at Orsted. Orsted is a global leader in renewable energy generation projects particularly when it comes to the rapidly expanding wind energy sector. Headquartered in Denmark the company has a global reach across multiple continents and technologies. David helps lead Orsted’s policy and regulatory engagement in the United Kingdom and beyond. We are excited to have him with us to discuss how Orsted is looking at and deploying hydrogen technologies and how they expect to utilized hydrogen in a decarbonized energy future.
The podcast can be found on their website.
The podcast can be found on their website.
Non-precious Electrocatalysts for Oxygen Evolution Reaction in Anion Exchange Membrane Water Electrolysis: A Mini Review
Sep 2021
Publication
Anion exchange membrane water electrolysis (AEMWE) is considered the next generation of green hydrogen production method because it uses low-cost non-noble metal oxide electrocatalyst electrodes and can store highpurity hydrogen under high pressure. However the commercialization of AEMWE with non-precious metal oxide electrocatalysts is challenging due to low electrocatalytic activity and durability. Overcoming the low kinetics caused by four-electron transfer is vital in addressing the low activity of non-noble metal oxide electrocatalysts for oxygen evolution reaction. This article overviews the synthesis methods and related techniques for various anode electrodes applied to AEMWE systems. We highlight effective strategies that have been developed to improve the performance and durability of the non-precious electrocatalysts and ensure the stable operation of AEMWE followed by a critical perspective to encourage the development of this technology.
The NREL Sensor Laboratory: Status and Future Directions for Hydrogen Detection
Sep 2021
Publication
The NREL Hydrogen Sensor Laboratory was commissioned in 2010 as a resource for the national and international hydrogen community to ensure the availability and proper use of hydrogen sensors. Since then the Sensor Laboratory has provided unbiased verification of hydrogen sensor performance for sensor developers end-users and regulatory agencies and has also provided active support for numerous code and standards development organizations. Although sensor performance assessment remains a core capability the mission of the NREL Sensor Laboratory has expanded toward a more holistic approach regarding the role of hydrogen detection and its implementation strategy for both assurance of facility safety and for process control applications. Active monitoring for detection of unintended releases has been identified as a viable approach for improving facility safety and lowering setbacks. The current research program for the Sensor Laboratory addresses both conventional and advanced developing detection strategies in response to the emerging large-scale hydrogen markets such as those envisioned by H2@Scale. These emerging hydrogen applications may require alternative detection strategies that supplement and may ultimately supplant the use of traditional sensors for monitoring hydrogen releases. Research focus areas for the NREL Sensor Laboratory now encompass the characterization of released hydrogen behavior to optimize detection strategies for both indoor and outdoor applications assess advanced methods of hydrogen leak detection such as hydrogen wide area monitoring for large scale applications implement active monitoring as a risk reduction strategy to improve safety at hydrogen facilities and to provide continuing support of hydrogen safety codes and standards. In addition to assurance of safety detection will be critical for process control applications such as hydrogen fuel quality verification for fuel cell vehicle applications and for monitoring and controlling of hydrogen-natural gas blend composition.
Strength, Hardness, and Ductility Evidence of Solid Solution Strengthening and Limited Hydrogen Embrittlement in the Alloy System Palladium-Copper (Cu wt. % 5–25)
Jul 2021
Publication
Strength hardness and ductility characteristics were determined for a series of palladium-copper alloys that compositionally vary from 5 to 25 weight percent copper. Alloy specimens subjected to vacuum annealing showed clear evidence of solid solution strengthening. These specimens showed as a function of increasing copper content increased yield strength ultimate strength and Vickers microhardness while their ductility was little affected by compositional differences. Annealed alloy specimens subsequently subjected to exposure to hydrogen at 323 K and PH2 = 1 atm showed evidence of hydrogen embrittlement up to a composition of ~15 wt. % Cu. The magnitude of the hydrogen embrittlement decreased with increasing copper content in the alloy.
Recent Developments in State-of-the-art Hydrogen Energy Technologies – Review of Hydrogen Storage Materials
Jan 2023
Publication
Hydrogen energy has been assessed as a clean and renewable energy source for future energy demand. For harnessing hydrogen energy to its fullest potential storage is a key parameter. It is well known that important hydrogen storage characteristics are operating pressure-temperature of hydrogen hydrogen storage capacity hydrogen absorption-desorption kinetics and heat transfer in the hydride bed. Each application needs specific properties. Every class of hydrogen storage materials has a different set of hydrogenation characteristics. Hence it is required to understand the properties of all hydrogen storage materials. The present review is focused on the state-of– the–art hydrogen storage materials including metal hydrides magnesium-based materials complex hydride systems carbonaceous materials metal organic frameworks perovskites and materials and processes based on artificial intelligence. In each category of materials‘ discovery hydrogen storage mechanism and reaction crystal structure and recent progress have been discussed in detail. Together with the fundamental synthesis process latest techniques of material tailoring like nanostructuring nanoconfinement catalyzing alloying and functionalization have also been discussed. Hydrogen energy research has a promising potential to replace fossil fuels from energy uses especially from automobile sector. In this context efforts initiated worldwide for clean hydrogen production and its use via fuel cell in vehicles is much awaiting steps towards sustainable energy demand.
Deep Decarbonization of the Indian Economy: 2050 Prospects for Wind, Solar, and Green Hydrogen
May 2022
Publication
The paper explores options for a 2050 carbon free energy future for India. Onshore wind and solar sources are projected as the dominant primary contributions to this objective. The analysis envisages an important role for so-called green hydrogen produced by electrolysis fueled by these carbon free energy sources. This hydrogen source can be used to accommodate for the intrinsic variability of wind and solar complementing opportunities for storage of power by batteries and pumped hydro. The green source of hydrogen can be used also to supplant current industrial uses of grey hydrogen produced in the Indian context largely from natural gas with important related emissions of CO2. The paper explores further options for use of green hydrogen to lower emissions from otherwise difficult to abate sectors of both industry and transport. The analysis is applied to identify the least cost options to meet India’s zero carbon future.
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