Germany

HyResponder is a European Hydrogen Train the Trainer programme for responders. This paper describes the key outputs of the project and the steps taken to develop and implement a long-term sustainable train the trainer programme in hydrogen safety for responders across Europe and beyond. This FCH2 JU (now Clean Hydrogen Joint Undertaking) funded project has built on the successful outcomes of the previous HyResponse project. HyResponder has developed further and updated educational operational and virtual reality training for trainers of responders to reflect the state-of-the-art in hydrogen safety including liquid hydrogen and expand the programme across Europe and specifically within the 10 countries represented directly within the project consortium: Austria Belgium the Czech Republic France Germany Italy Norway Spain Switzerland and the United Kingdom. For the first time four levels of educational materials from fire fighter through to specialist have been developed. The digital training resources are available on the e-Platform (https://hyresponder.eu/e-platform/). The revised European Emergency Response Guide is now available to all stakeholders. The resources are intended to be used to support national training programs. They are available in 8 languages: Czech Dutch English French German Italian Norwegian and Spanish. Through the HyResponder activities trainers from across Europe have undertaken joint actions which are in turn being used to inform the delivery of regional and national training both within and beyond the project. The established pan-European network of trainers is shaping the future in the important for inherently safer deployment of hydrogen systems and infrastructure across Europe and enhancing the reach and impact of the programme.

In international regulations on explosion protection mechanical friction impact or abrasion is usually named as one of 13 ignition sources that must be avoided in hazardous zones with explosive atmospheres. In different studies it is even identified as one of the most frequent ignition sources in practice. The effectiveness of mechanical impacts as ignition source is dependent from several parameters including the minimum ignition energy of the explosive atmosphere the properties of the material pairing the kinetic impact energy or the impact velocity. By now there is no standard procedure to determine the effectiveness of mechanical impacts as ignition source. In some previous works test procedures with poor reproducibility or undefined kinetic impact energy were applied for this purpose. In other works only homogeneous material pairings were considered. In this work the effectiveness of mechanical impacts with defined and reproducible kinetic impact energy as ignition source for hydrogen containing atmospheres was studied systematically in dependence from the inhomogeneous material pairing considering materials with practical relevance like stainless steel low alloy steel concrete and non-iron-metals. It was found that ignition can be avoided if non-iron metals are used in combination with different metallic materials but in combination with concrete even the impact of non-iron-metals can be an effective ignition source if the kinetic impact energy is not further limited. Moreover the consequence of hydrogen admixture to natural gas on the effectiveness of mechanical impacts as ignition source was studied. In many cases ignition of atmospheres containing natural gas by mechanical impacts is rather unlikely. No influence could be observed for admixtures up to 25% hydrogen and even more. The results are mainly relevant in the context of repurposing the natural gas grid or adding hydrogen to the natural gas grid. Based on the test results it can be evaluated under which circumstances the use of tools made of non-iron-metals or other non-sparking materials can be an effective measure to avoid ignition sources in hazardous zones containing hydrogen for example during maintenance work.

The increase of using hydrogen as a replacement for fossil fuels in power generation and mobility is expected to witness a huge leap in the next decades. However several safety issues arise due to the physical and chemical properties of hydrogen especially its wide range of flammability. In case of Hydrogen leakage in confined areas Hydrogen clouds can accumulate in the space and their concentration can build up quickly to reach the lower flammability limit (LFL) in case of not applying a proper ventilation system. As a part of the Living Lab Energy Campus (LLEC) project at Jülich Research Centre the use of hydrogen mixed with natural gas as a fuel for the central heating system of the campus is being studied. The current research aims to investigate the release dispersion and formation and the spread of a hydrogen cloud inside the central utility building at the campus of Jülich Research Centre in case of hypothetical accidental leakage. Such a leakage is simulated using the opensource containmentFoam package base on OpenFOAM CFD code to numerically simulate the behavior of the air-hydrogen mixture. The critical locations where hydrogen concentrations can reach the LFL values are shown.

Hydrogen energy is recognized by many European governments as an important part of the development to achieve a more sustainable energy infrastructure. Great efforts are spent to build up a hydrogen supply chain to support the increasing number of hydrogen-powered vehicles. Naturally these vehicles will use the common traffic infrastructure. Thus it has to be ensured these infrastructures are capable to withstand the hazards and associated risks that may arise from these new technologies. In order to have an appropriate assessment tool for hydrogen vehicles transport through tunnels a new QRA methodology is developed and presented here. In Europe the PIARC is a very common approach. It is therefore chosen as a starting point for the new methodology. It provides data on traffic statistics accident frequencies tunnel geometries including certain prevention and protection measures. This approach is enhanced by allowing better identification of hazards and their respective sources for hydrogen vehicles. A detailed analysis of the accident scenarios that are unique for hydrogen vehicles hereunder the initiating events severity of collision types that may result in a release of hydrogen gas in a tunnel and the location of such an accident are included. QRA enables the assessment and evaluation of scenarios involving external fires or vehicles that burst into fire because of an accident or other fire sources. Event Tree Analysis is the technique used to estimate the event frequencies. The consequence analysis includes the hazards from blast waves hydrogen jet fires DDT.

A growing share of renewable energy production in the energy supply systems is key to reaching the European political goal of zero CO2 emission in 2050 highlighted in the green deal. Linked to the irregular production of solar and wind energies which have the highest potential for development in Europe massive energy storage solutions are needed as energy buffers. The European project HyPSTER [1] (Hydrogen Pilot STorage for large Ecosystem Replication) granted by the Clean Hydrogen Partnership addresses this topic by demonstrating a cyclic test in an experimental salt cavern filled with hydrogen up to 3 tons using hydrogen that is produced onsite by a 1 MW electrolyser. One specific objective of the project is the assessment of the risks and environmental impacts of cyclic hydrogen storage in salt caverns and providing guidelines for safety regulations and standards. This paper highlights the first outcome of the task WP5.5 of the HyPSTER project addressing the regulatory and normative frameworks for the safety of hydrogen storage in salt caverns from some selected European Countries which is dedicated to defining recommendations for promoting the safe development of this industry within Europe.

In case of accidental conditions involving high-speed hydrogen combustion the considerable pressure and thermal loads could result in substantial deformation and/or destruction of the industrial appliances. Accounting of such effects in the safety analysis with CFD tools can provide critical information on the design and construction of the sensitive appliances’ elements. The current paper presents the development and the implementation of a new 3D-technique which makes possible to perform simulations of the gas-dynamic processes simultaneously with adaptation of the geometry of complex configurations. Using the data obtained in the experiments on the flame acceleration and DDT in the tubes of industrial arrangements performed in MPA and KIT the authors performed a series of the combustion simulations corresponding to the experimental conditions. The combustion gas-dynamics was simulated using COM3D code and the tube wall material behavior was modelled using finite-element code ABAQUS - © Dassault Systèmes with real-time data exchange between the codes. Obtained numerical results demonstrated good agreement with the observed experimental data on both pressure dynamics and tube deformation history.

The PRHYDE project (PRotocol for heavy duty HYDrogEn refueling) funded by the Clean Hydrogen partnership aims at developing recommendations for heavy-duty refueling protocols used for future standardization activities for trucks and other heavy duty transport systems applying hydrogen technologies. Development of a protocol requires a validated approach. Due to the limited time and budget the experimental data cannot cover the whole possible ranges of protocol parameters such as initial vehicle pressure and temperature ambient and precooling temperatures pressure ramp refueling time hardware specifications etc. Hence a validated numerical tool is essential for a safe and efficient protocol development. For this purpose engineering tools are used. They give good results in a very reasonable computation time of several seconds or minutes. These tools provide the heat parameters estimation in the gas (volume average temperature) and 1D temperature distribution in the tank wall. The following models were used SOFIL (Air Liquide tool) HyFill (by ENGIE) and H2Fills (open access code by NREL). The comparison of modelling results and experimental data demonstrated a good capability of codes to predict the evolution of average gas temperature in function of time. Some recommendations on model validation for the future protocol development are given.

The transformation of fossil fuel-based power generation systems towards greenhouse gas-neutral ones based on renewable energy sources is one of the key challenges facing contemporary society. The temporal volatility that accompanies the integration of renewable energy (e.g. solar radiation and wind) must be compensated to ensure that at any given time a sufficient supply of electrical energy for the demands of different sectors is available. Green hydrogen which is produced using renewable energy sources via electrolysis can be used to chemically store electrical energy on a seasonal basis. Reconversion technologies are needed to generate electricity from stored hydrogen during periods of low renewable electricity generation. This study presents a detailed technoeconomic assessment of hydrogen gas turbines. These technologies are also superior to fuel cells due to their comparatively low investment costs especially when it comes to covering the residual loads. As of today hydrogen gas turbines are only available in laboratory or small-scale settings and have no market penetration or high technology readiness level. The primary focus of this study is to analyze the effects on gas turbine component costs when hydrogen is used instead of natural gas. Based on these findings an economic analysis addressing the current state of these turbine components is conducted. A literature review on the subsystems is performed considering statements from leading manufactures and researchers to derive the cost deviations and total cost per installed capacity (€/kWel). The results reveal that a hydrogen gas turbine power plant has an expected cost increase of 8.5% compared to a conventional gas turbine one. This leads to an average cost of 542.5 €/kWel for hydrogen gas turbines. For hydrogen combined cycle power plants the expected cost increase corresponds to the cost of the gas turbine system as the steam turbine subsystem remains unaffected by fuel switching. Additionally power plant retrofit potentials were calculated and the respective costs in the case of an upgrade were estimated. For Germany as a case study for an industrialized country the potential of a possible retrofit is between 2.7 and 11.4 GW resulting to a total investment between 0.3 and 1.1 billion €.

We investigate the challenges and options for repurposing existing natural gas pipelines for hydrogen transportation. Challenges of re-purposing are mainly related to safety and due to the risk of hydrogen embrittlement of pipeline steels and the smaller molecular size of the gas. From an economic perspective the lower volumetric energy density of hydrogen compared to natural gas is a challenge. We investigate three pipeline repurposing options in depth: a) no modification to the pipeline but enhanced maintenance b) use of gaseous inhibitors and c) the pipe-in-pipe approach. The levelized costs of transportation of these options are compared for the case of the German Norddeutsche Erdgasleitung (NEL) pipeline. We find a similar cost range for all three options. This indicates that other criteria such as the sunk costs public acceptance and consumer requirements are likely to shape the decision making for gas pipeline repurposing.

Côte d’Ivoire has substantially neglected crop residues from farms in rural areas so this study aimed to provide strategies for the sustainable conversion of these products to hydrogen. The use of existing data showed that in the Côte d’Ivoire there were up to 16801306 tons of crop residues from 11 crop types in 2019 from which 1296424.84 tons of hydrogen could potentially be derived via theoretical gasification and dark fermentation approaches. As 907497.39 tons of hydrogen is expected annually the following estimations were derived. The three hydrogen-project implementation scenarios developed indicate that Ivorian industries could be supplied with 9026635 gigajoules of heat alongside 17910 cars and 4732 buses in the transport sector. It was estimated that 817293.95 tons of green ammonia could be supplied to farmers. According to the study 5727992 households could be expected to have access to 1718.40 gigawatts of electricity. Due to these changes in the transport energy industry and agricultural sectors a reduction of 1644722.08 tons of carbon dioxide per year could theoretically be achieved. With these scenarios around 263276.87 tons of hydrogen could be exported to other countries. The conversion of crop residues to hydrogen is a promising opportunity with environmental and socio-economic impacts. Therefore this study requires further extensive research.