China, People’s Republic
Optimized Scheduling of Integrated Energy Systems Accounting for Hydrogen Energy Multi-Utilization Models
Jan 2024
Publication
To cope with the growing penetration rate of renewable energy and to enhance the absorption capacity of wind power this paper investigates the applications of an Integrated Energy System (IES) Hydrogen Compressed Natural Gas (HCNG) and power-to-hydrogen (P2H) devices within the IES. It employs power-to-gas and gas blending with hydrogen to construct an efficient electricity–gas–electricity energy flow loop establishing a Natural Gas–Electricity Coupling System (NGECS) model. On this basis a coordinated scheduling method for gas–electric coupling systems using gas blended with hydrogen is proposed. A carbon trading mechanism is introduced to constrain carbon emissions further reducing the system’s carbon footprint. Multiple scenarios are set up for a comparative analysis in order to validate the effectiveness of the proposed model. This study also analyzes the impact of different hydrogen blending ratios and methods on the low-carbon and economic performance of IES.
An Experimental Study on the Large-Volume Liquid Hydrogen Release in an Open Space
Apr 2024
Publication
Liquid hydrogen is one of the high-quality energy carriers but a large leak of liquid hydrogen can pose significant safety risks. Understanding its diffusion law after accidental leakage is an important issue for the safe utilization of hydrogen energy. In this paper a series of open-space large-volume liquid hydrogen release experiments are performed to observe the evolution of visible clouds during the release and an array of hydrogen concentration sensors is set up to monitor the fluctuation in hydrogen concentration at different locations. Based on the experimental conditions the diffusion of hydrogen clouds in the atmosphere under different release hole diameters and different ground materials is compared. The results show that with the release of liquid hydrogen the white visible cloud formed by air condensation or solidification is generated rapidly and spread widely and the visible cloud is most obvious near the ground. With the termination of liquid hydrogen release solid air is deposited on the ground and the visible clouds gradually shrink from the far field to the release source. Hydrogen concentration fluctuations in the far field in the case of the cobblestone ground are more dependent on spontaneous diffusion by the hydrogen concentration gradient. In addition compared with the concrete ground the cobblestone ground has greater resistance to liquid hydrogen extension; the diffusion of hydrogen clouds to the far field lags. The rapid increase stage of hydrogen concentration at N8 in Test 7 lags about 3 s behind N12 in Test 6 N3 lags about 7.5 s behind N1 and N16 lags about 8.25 s behind N14. The near-source space is prone to high-concentration hydrogen clouds. The duration of the high-concentration hydrogen cloud at N12 is about 15 s which is twice as long as the duration at N8 increasing the safety risk of the near-source space.
Knock Mitigation and Power Enhancement of Hydrogen Spark-Ignition Engine through Ammonia Blending
Jun 2023
Publication
Hydrogen and ammonia are primary carbon-free fuels that have massive production potential. In regard to their flame properties these two fuels largely represent the two extremes among all fuels. The extremely fast flame speed of hydrogen can lead to an easy deflagration-to-detonation transition and cause detonation-type engine knock that limits the global equivalence ratio and consequently the engine power. The very low flame speed and reactivity of ammonia can lead to a low heat release rate and cause difficulty in ignition and ammonia slip. Adding ammonia into hydrogen can effectively modulate flame speed and hence the heat release rate which in turn mitigates engine knock and retains the zero-carbon nature of the system. However a key issue that remains unclear is the blending ratio of NH3 that provides the desired heat release rate emission level and engine power. In the present work a 3D computational combustion study is conducted to search for the optimal hydrogen/ammonia mixture that is knock-free and meanwhile allows sufficient power in a typical spark-ignition engine configuration. Parametric studies with varying global equivalence ratios and hydrogen/ammonia blends are conducted. The results show that with added ammonia engine knock can be avoided even under stoichiometric operating conditions. Due to the increased global equivalence ratio and added ammonia the energy content of trapped charge as well as work output per cycle is increased. About 90% of the work output of a pure gasoline engine under the same conditions can be reached by hydrogen/ammonia blends. The work shows great potential of blended fuel or hydrogen/ammonia dual fuel in high-speed SI engines.
Hydrogen as a Transition Tool in a Fossil Fuel Resource Region: Taking China’s Coal Capital Shanxi as an Example
Aug 2023
Publication
Because of the pressure to meet carbon neutrality targets carbon reduction has become a challenge for fossil fuel resource-based regions. Even though China has become the most active country in carbon reduction its extensive energy supply and security demand make it difficult to turn away from its dependence on coal-based fossil energy. This paper analyzes the Chinese coal capital—Shanxi Province—to determine whether the green low-carbon energy transition should be focused on coal resource areas. In these locations the selection and effect of transition tools are key to ensuring that China meets its carbon reduction goal. Due to the time window of clean coal utilization the pressure of local governments and the survival demands of local high energy consuming enterprises Shanxi Province chose hydrogen as its important transition tool. A path for developing hydrogen resources has been established through lobbying and corporative influence on local and provincial governments. Based on such policy guidance Shanxi has realized hydrogen applications in large-scale industrial parks regional public transport and the iron and steel industry. This paper distinguishes between the development strategies of gray and green hydrogen. It shows that hydrogen can be an effective development model for resource-based regions as it balances economic stability and energy transition.
Electrocatalysts for the Generation of Hydrogen, Oxygen and Synthesis Gas
Sep 2016
Publication
Water electrolysis is the most promising method for efficient production of high purity hydrogen (and oxygen) while the required power input for the electrolysis process can be provided by renewable sources (e.g. solar or wind). The thus produced hydrogen can be used either directly as a fuel or as a reducing agent in chemical processes such as in Fischer–Tropsch synthesis. Water splitting can be realized both at low temperatures (typically below 100 °C) and at high temperatures (steam water electrolysis at 500– 1000 °C) while different ionic agents can be electrochemically transferred during the electrolysis process (OH− H+ O2− ). Singular requirements apply in each of the electrolysis technologies (alkaline polymer electrolyte membrane and solid oxide electrolysis) for ensuring high electrocatalytic activity and long-term stability. The aim of the present article is to provide a brief overview on the effect of the nature and structure of the catalyst–electrode materials on the electrolyzer’s performance. Past findings and recent progress in the development of efficient anode and cathode materials appropriate for large-scale water electrolysis are presented. The current trends limitations and perspectives for future developments are summarized for the diverse electrolysis technologies of water splitting while the case of CO2/H2O co-electrolysis (for synthesis gas production) is also discussed.
Collaborative Optimization Scheduling of Multi-Microgrids Incorporating Hydrogen-Doped Natural Gas and P2G–CCS Coupling under Carbon Trading and Carbon Emission Constraints
Apr 2024
Publication
In the context of “dual carbon” restrictions on carbon emissions have aĴracted widespread aĴention from researchers. In order to solve the issue of the insufficient exploration of the synergistic emission reduction effects of various low-carbon policies and technologies applied to multiple microgrids we propose a multi-microgrid electricity cooperation optimization scheduling strategy based on stepped carbon trading a hydrogen-doped natural gas system and P2G–CCS coupled operation. Firstly a multi-energy microgrid model is developed coupled with hydrogendoped natural gas system and P2G–CCS and then carbon trading and a carbon emission restriction mechanism are introduced. Based on this a model for multi-microgrid electricity cooperation is established. Secondly design optimization strategies for solving the model are divided into the dayahead stage and the intraday stage. In the day-ahead stage an improved alternating direction multiplier method is used to distribute the model to minimize the cooperative costs of multiple microgrids. In the intraday stage based on the day-ahead scheduling results an intraday scheduling model is established and a rolling optimization strategy to adjust the output of microgrid equipment and energy purchases is adopted which reduces the impact of uncertainties in new energy output and load forecasting and improves the economic and low-carbon operation of multiple microgrids. SeĴing up different scenarios for experimental validation demonstrates the effectiveness of the introduced low-carbon policies and technologies as well as the effectiveness of their synergistic interaction
Optimal Capacity Configuration of Wind–Solar Hydrogen Storage Microgrid Based on IDW-PSO
Aug 2023
Publication
Because the new energy is intermittent and uncertain it has an influence on the system’s output power stability. A hydrogen energy storage system is added to the system to create a wind light and hydrogen integrated energy system which increases the utilization rate of renewable energy while encouraging the consumption of renewable energy and lowering the rate of abandoning wind and light. Considering the system’s comprehensive operation cost economy power fluctuation and power shortage as the goal considering the relationship between power generation and load assigning charging and discharging commands to storage batteries and hydrogen energy storage and constructing a model for optimal capacity allocation of wind–hydrogen microgrid system. The optimal configuration model of the wind solar and hydrogen microgrid system capacity is constructed. A particle swarm optimization with dynamic adjustment of inertial weight (IDW-PSO) is proposed to solve the optimal allocation scheme of the model in order to achieve the optimal allocation of energy storage capacity in a wind–hydrogen storage microgrid. Finally a microgrid system in Beijing is taken as an example for simulation and solution and the results demonstrate that the proposed approach has the characteristics to optimize the economy and improve the capacity of renewable energy consumption realize the inhibition of the fluctuations of power reduce system power shortage and accelerate the convergence speed.
Inter-Zone Optimal Scheduling of Rural Wind–Biomass-Hydrogen Integrated Energy System
Aug 2023
Publication
To solve the problems of low utilization of biomass and uncertainty and intermittency of wind power (WP) in rural winter an interval optimization model of a rural integrated energy system with biogas fermentation and electrolytic hydrogen production is constructed in this paper. Firstly a biogas fermentation kinetic model and a biogas hydrogen blending model are developed. Secondly the interval number is used to describe the uncertainty of WP and an interval optimization scheduling model is developed to minimize daily operating cost. Finally a rural integrated energy system in Northeast China is taken as an example and a sensitivity analysis of electricity price gas production and biomass price is conducted. The simulation results show that the proposed strategy can significantly reduce the wind abandonment rate and improve the economy by 3.8–22.3% compared with conventional energy storage under optimal dispatch.
Low-carbon Economy Dispatching of Integrated Energy System with P2G-HGT Coupling Wind Power Absorption Based on Stepped Carbon Emission Trading
Aug 2023
Publication
To improve the renewable energy consumption capacity of integrated energy system (IES) and reduce the carbon emission level of the system a low-carbon economic dispatch model of IES with coupled power-to-gas (P2G) and hydrogen-doped gas units (HGT) under the stepped carbon trading mechanism is proposed. On the premise of wind power output uncertainty the operating characteristics of the coupled electricity-to-gas equipment in the system are used to improve the wind abandonment problem of IES and increase its renewable energy consumption capacity; HGT is introduced to replace the traditional combustion engine for energy supply and on the basis of refined P2G a part of the volume fraction of hydrogen obtained from the production is extracted and mixed with methane to form a gas mixture for HGT combustion so as to improve the low-carbon economy of the system. The ladder type carbon trading mechanism is introduced into IES to guide the system to control carbon emission behavior and reduce the carbon emission level of IES. Based on this an optimal dispatching strategy is constructed with the economic goal of minimizing the sum of system operation cost wind abandonment cost carbon trading cost and energy purchase cost. After linearization of the established model and comparison analysis by setting different scenarios the wind power utilization rate of the proposed model is increased by 24.5% and the wind abandonment cost and CO2 emission are reduced by 86.3% and 10.5% respectively compared with the traditional IES system which achieves the improvement of renewable energy consumption level and low carbon economy.
Study on the Dynamic Optimal Control Strategy of an Electric-Hydrogen Hybrid Energy Storage System for a Direct Drive Wave Power Generation System
Jul 2023
Publication
A direct drive wave power generation system (DDWPGS) has the advantages of a simple structure and easy deployment and is the first choice to provide electricity for islands and operation platforms in the deep sea. However due to the off-grid the source and load cannot be matched so accommodation is an important issue. Hydrogen storage is the optimal choice for offshore wave energy accommodation. Therefore aiming at the source-load mismatch problem of the DDWPGS an electric-hydrogen hybrid energy storage system (HESS) for the DDWPGS is designed in this paper. Based on the characteristics of the devices in the electric-hydrogen HESS a new dynamic power allocation strategy and its control strategy are proposed. Firstly empirical mode decomposition (EMD) is utilized to allocate the power fluctuations that need to be stabilized. Secondly with the state of charge (SOC) of the battery and the operating characteristics of the alkaline electrolyzer being considered the power assignments of the battery and the electrolyzer are determined using the rule-based method. In addition model predictive control (MPC) with good tracking performance is used to adjust the output power of the battery and electrolyzer. Finally the supercapacitor (SC) is controlled to maintain the DC bus voltage while also balancing the system’s power. A simulation was established to verify the feasibility of the designed system. The results show that the electric-hydrogen HESS can stabilize the power fluctuations dynamically when the DDWPGS captures instantaneous power. Moreover its control strategy can not only reduce the start-stop times of the alkaline electrolyzer but also help the energy storage devices to maintain a good state and extend the service life.
Design and Optimization of a Type-C Tank for Liquid Hydrogen Marine Transport
May 2023
Publication
As one of the most promising renewable energy sources hydrogen has the excellent environmental benefit of producing zero emissions. A key technical challenge in using hydrogen across sectors is placed on its storage technology. The storage temperature of liquid hydrogen (20 K or 253 C) is close to absolute zero so the storage materials and the insulation layers are subjected to extremely stringent requirements against the cryogenic behaviour of the medium. In this context this research proposed to design a large liquid hydrogen type-C tank with AISI (American Iron and Steel Institution) type 316 L stainless steel as the metal barrier using Vapor-Cooled Shield (VCS) and Rigid Polyurethane Foams (RPF) as the insulation layer. A parametric study on the design of the insulation layer was carried out by establishing a thermodynamic model. The effects of VCS location on heat ingress to the liquid hydrogen transport tank and insulation temperature distribution were investigated and the optimal location of the VCS in the insulation was identified. Research outcomes finally suggest two optimal design schemes: (1) when the thickness of the insulation layer is determined Self-evaporation Vapor-Cooled Shield (SVCS) and Forcedevaporation Vapor-Cooled Shield (FVCS) can reduce heat transfer by 47.84% and 85.86% respectively; (2) when the liquid hydrogen evaporation capacity is determined SVCS and FVCS can reduce the thickness of the insulation layer by 50% and 67.93% respectively.
Research on Capacity Optimization Configuration of Renewable Energy Off Grid Hydrogen Production System Considering Collaborative Electrolysis
Apr 2024
Publication
This study proposes a multitype electrolytic collaborative hydrogen production model for optimizing the capacity configuration of renewable energy off grid hydrogen production systems. The electrolytic hydrogen production process utilizes the synergistic electrolysis of an alkaline electrolyzer (AEL) and proton exchange membrane electrolyzer (PEMEL) fully leveraging the advantages of the low cost of the AEL and strong regulation characteristics of the PEMEL. For the convenience of the optimization solution the article constructs a mixed linear optimization model that considers the constraints during system operation with the objective function of minimizing total costs while meeting industrial production requirements. Gurobi is used for the optimal solution to obtain the optimal configuration of a renewable energy off grid hydrogen production system. By comparing and analyzing the optimal configuration under conventional load and high-load conditions it is concluded that collaborative electrolysis has advantages in improving resource consumption and reducing hydrogen production costs. This is of great significance for optimizing the capacity configuration of off grid hydrogen production systems and improving the overall economic benefits of the system.
Leakage and Diffusion Characteristics of Underground Hydrogen Pipeline
Jun 2023
Publication
Soil corrosion and hydrogen embrittlement are the main factors of hydrogen pipeline failure. The gas escapes diffuses and accumulating in the soil and entering the atmosphere when leak occurs. The mechanism of gas diffusion in buried pipelines is very complicated. Mastering the evolution law of hydrogen leakage diffusion is conducive to quickly locating the leakage point and reducing the loss. The leakage model of the underground hydrogen pipeline is established in this paper. Effect of leakage hole soil type pipeline pressure pipeline diameter on hydrogen leakage diffusion were investigated. The results show that when the hydrogen pipeline leaks the hydrogen concentration increases with the increase of leakage time showing a symmetrical distribution trend. With the pipeline pressure increase hydrogen leakage speed is accelerated and longitudinal diffusion gradually becomes the dominant direction. With the leakage diameter increases hydrogen leakage per unit of time increases sharply. Hydrogen diffuses more easily in sandy soil and diffusion speed concentration and range are higher than that in clay soil. The research content provides a reference and basis for the detection and evaluation of buried hydrogen pipeline leakage.
Optimal Capacity Planning of Green Electricity-Based Industrial Electricity-Hydrogen Multi-Energy System Considering Variable Unit Cost Sequence
Apr 2024
Publication
Utilizing renewable energy sources (RESs) such as wind and solar to convert electrical energy into hydrogen energy can promote the accommodation of green electricity. This paper proposes an optimal capacity planning approach for an industrial electricity-hydrogen multi-energy system (EHMES) aimed to achieve the local utilization of RES and facilitate the transition to carbon reduction in industrial settings. The proposed approach models the EHMES equipment in detail and divides the system’s investment and operation into producer and consumer sides with energy trading for effective integration. Through this effort the specialized management for different operators and seamless incorporation of RES into industrial users can be achieved. In addition the variations in investment and operating costs of equipment across different installed capacities are considered to ensure a practical alignment with real-world scenarios. By conducting a detailed case study the influence of various factors on the capacity configuration outcomes within an EHMES is analyzed. The results demonstrate that the proposed method can effectively address the capacity configuration of equipment within EHMES based on the local accommodation of RES and variable unit cost sequence. Wind power serves as the primary source of green electricity in the system. Energy storage acts as crucial equipment for enhancing the utilization rate of RES.
Advantages and Technological Progress of Hydrogen Fuel Cell Vehicles
Jun 2023
Publication
The automotive industry is undergoing a profound transformation driven by the need for sustainable and environmentally friendly transportation solutions [1]. In this context fuel cell technology has emerged as a promising alternative offering clean efficient and high-performance power sources for vehicles [2]. Fuel cell vehicles are electric vehicles that use fuel cell systems as a single power source or as a hybrid power source in combination with rechargeable energy storage systems. A typical fuel cell system for electric vehicle is exhibited in Figure 1 which provides a comprehensive demonstration of this kind of complex system. Hydrogen energy is a crucial field in the new energy revolution and will become a key pillar in building a green efficient and secure new energy system. As a critical field for hydrogen utilization fuel cell vehicles will play an important role in the transformation and development of the automotive industry. The development of fuel cell vehicles offers numerous advantages such as strong power outputs safety reliability and economic energy savings [3]. However improvements must urgently be made in existing technologies such as fuel cell stacks (including proton exchange membranes catalysts gas diffusion layers and bipolar plates) compressors and onboard hydrogen storage systems [4]. The advantages and current technological status are analyzed here.
The Necessity and Feasibility of Hydrogen Storage for Large-Scale, Long-Term Energy Storage in the New Power System in China
Jun 2023
Publication
In the process of building a new power system with new energy sources as the mainstay wind power and photovoltaic energy enter the multiplication stage with randomness and uncertainty and the foundation and support role of large-scale long-time energy storage is highlighted. Considering the advantages of hydrogen energy storage in large-scale cross-seasonal and cross-regional aspects the necessity feasibility and economy of hydrogen energy participation in long-time energy storage under the new power system are discussed. Firstly power supply and demand production simulations were carried out based on the characteristics of new energy generation in China. When the penetration of new energy sources in the new power system reaches 45% long-term energy storage becomes an essential regulation tool. Secondly by comparing the storage duration storage scale and application scenarios of various energy storage technologies it was determined that hydrogen storage is the most preferable choice to participate in large-scale and long-term energy storage. Three long-time hydrogen storage methods are screened out from numerous hydrogen storage technologies including salt-cavern hydrogen storage natural gas blending and solid-state hydrogen storage. Finally by analyzing the development status and economy of the above three types of hydrogen storage technologies and based on the geographical characteristics and resource endowment of China it is pointed out that China will form a hydrogen storage system of “solid state hydrogen storage above ground and salt cavern storage underground” in the future.
Comparative Techno-economic Analysis of Large-scale Renewable Energy Storage Technologies
Jun 2023
Publication
Energy storage is an effective way to address the instability of renewable energy generation modes such as wind and solar which are projected to play an important role in the sustainable and low-carbon society. Economics and carbon emissions are important indicators that should be thoroughly considered for evaluating the feasibility of energy storage technologies (ESTs). In this study we study two promising routes for large-scale renewable energy storage electrochemical energy storage (EES) and hydrogen energy storage (HES) via technical analysis of the ESTs. The levelized cost of storage (LCOS) carbon emissions and uncertainty assessments for EESs and HESs over the life cycle are conducted with full consideration of the critical links for these routes. In order to reduce the evaluation error we use the Monte Carlo method to derive a large number of data for estimating the economy and carbon emission level of ESTs based on the collected data. The results show that lithium ion (Li-ion) batteries show the lowest LCOS and carbon emissions at 0.314 US$ kWh-1 and 72.76 gCO2e kWh-1 compared with other batteries for EES. Different HES routes meaning different combinations of hydrogen production delivery and refueling methods show substantial differences in economics and the lowest LCOS and carbon emissions at 0.227 US$ kWh-1 and 61.63 gCO2e kWh-1 are achieved using HES routes that involve hydrogen production by alkaline electrolyzer (AE) delivery by hydrogen pipeline and corresponding refueling. The findings of this study suggest that HES and EES have comparable levels of economics and carbon emissions that should be both considered for large-scale renewable energy storage to achieve future decarbonization goals.
Design of a Multi-inlet Solar Thermochemical Reactor for Steam Methane Reforming with Improved Performance
Feb 2023
Publication
Reactor structure design plays an important role in the performance of solar-thermal methane reforming reactors. Based on a conventional preheating reactor this study proposed a cylindrical solar methane reforming reactor with multiple inlets to vary the temperature field distribution which improved the temperature of the reaction region in the reactor thereby improving the reactor performance. A multi-physical model that considers mass momentum species and energy conservation as well as thermochemical reaction kinetics of methane reforming was applied to numerically investigate the reactor performance and analyze the factors that affect performance improvement. It was found that compared with a conventional preheating reactor the proposed cylindrical reactor with inner and external inlets for gas feeding enhanced heat recovery from the exhausted gas and provided a more suitable temperature field for the reaction in the reactor. Under different operating conditions the methane conversion in the cylindrical reactor with multi-inlet increased by 9.5% to 19.1% and the hydrogen production was enhanced by 12.1% to 40.3% in comparison with the conventional design even though the total reaction catalyst volume was reduced.
Potential of Salt Caverns for Hydrogen Storage in Southern Ontario, Canada
Jul 2023
Publication
Salt caverns produced by solution mining in Southern Ontario provide ideal spaces for gas storage due to their low permeability. Underground hydrogen storage (UHS) is an important part of the future renewable energy market in Ontario in order to achieve global carbon neutrality and to fill the gap left by retiring nuclear power plants. However large-scale hydrogen storage is still restricted by limited storage space on the ground’s surface. In this study hydrogen’s physical and chemical properties are first introduced and characterized by low molecular weight high diffusivity low solubility and low density. Then the geological conditions of the underground reservoirs are analyzed especially salt caverns. Salt caverns with their inert cavity environments and stable physical properties offer the most promising options for future hydrogen storage. The scales heights and thicknesses of the roof and floor salt layers and the internal temperatures and pressures conditions of salt caverns can affect stabilities and storage capacities. Finally several potential problems that may affect the safe storage of hydrogen in salt caverns are discussed. Through the comprehensive analysis of the influencing factors of hydrogen storage in salt caverns this study puts forward the most appropriate development strategy for salt caverns which provides theoretical guidance for UHS in the future and helps to reduce the risk of large-scale storage design.
Economic Analysis of a Photovoltaic Hydrogen Refueling Station Based on Hydrogen Load
Sep 2023
Publication
With the goal of achieving “carbon peak in 2030 and carbon neutrality in 2060” as clearly proposed by China the transportation sector will face long–term pressure on carbon emissions and the application of hydrogen fuel cell vehicles will usher in a rapid growth period. However true “zero carbon” emissions cannot be separated from “green hydrogen”. Therefore it is of practical significance to explore the feasibility of renewable energy hydrogen production in the context of hydrogen refueling stations especially photovoltaic hydrogen production which is applied to hydrogen refueling stations (hereinafter referred to “photovoltaic hydrogen refueling stations”). This paper takes a hydrogen refueling station in Shanghai with a supply capacity of 500 kg/day as the research object. Based on a characteristic analysis of the hydrogen demand of the hydrogen refueling station throughout the day this paper studies and analyzes the system configuration operation strategy environmental effects and economics of the photovoltaic hydrogen refueling station. It is estimated that when the hydrogen price is no less than 6.23 USD the photovoltaic hydrogen refueling station has good economic benefits. Additionally compared with the conventional hydrogen refueling station it can reduce carbon emissions by approximately 1237.28 tons per year with good environmental benefits.
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