China, People’s Republic
Multi-Objective Optimization-Based Health-Conscious Predictive Energy Management Strategy for Fuel Cell Hybrid Electric Vehicles
Feb 2022
Publication
The Energy Management Strategy (EMS) in Fuel Cell Hybrid Electric Vehicles (FCHEVs) is the key part to enhance optimal power distribution. Indeed the most recent works are focusing on optimizing hydrogen consumption without taking into consideration the degradation of embedded energy sources. In order to overcome this lack of knowledge this paper describes a new health-conscious EMS algorithm based on Model Predictive Control (MPC) which aims to minimize the battery degradation to extend its lifetime. In this proposed algorithm the health-conscious EMS is normalized in order to address its multi-objective optimization. Then weighting factors are assigned in the objective function to minimize the selected criteria. Compared to most EMSs based on optimization techniques this proposed approach does not require any information about the speed profile which allows it to be used for real-time control of FCHEV. The achieved simulation results show that the proposed approach reduces the economic cost up to 50% for some speed profile keeping the battery pack in a safe range and significantly reducing energy sources degradation. The proposed health-conscious EMS has been validated experimentally and its online operation ability clearly highlighted on a PEMFC delivery postal vehicle.
Performance of Three Typical Domestic Gas Stoves Operated with Methane-hydrogen Mixture
Dec 2022
Publication
Hydrogen blending into natural gas has attracted significant attention in domestic applications. The paper studied the effects of natural gas mixed with hydrogen at 0% (vol) 5% 10% 15% 20% and 25% on the performance of typical round-port gas stove (TRPGS) swirling strip-port gas stove (SSPGS) and radiant porous media gas stove (RPMGS). The experimental results show that flame length shortens with the increase of hydrogen proportion and the combustion remains stable when the hydrogen proportion is equal to or less than 25%. With increasing hydrogen proportion the measured heat inputs of the three types of domestic gas stoves decrease gradually and the average thermal efficiency of TRPGS and SSPGS increase by 0.82% and 1.18% respectively. In addition the average efficiency of the RPMGS first increases by 1.35% under a hydrogen proportion of 15% and then decreases by 1.36% under a hydrogen proportion of 25%. In terms of flue gas emission CO emission reduces significantly with increasing hydrogen proportion while NOX emissions remain almost unchanged.
Cost and Thermodynamic Analysis of Wind-Hydrogen Production via Multi-energy Systems
Mar 2024
Publication
With rising temperatures extreme weather events and environmental challenges there is a strong push towards decarbonization and an emphasis on renewable energy with wind energy emerging as a key player. The concept of multi-energy systems offers an innovative approach to decarbonization with the potential to produce hydrogen as one of the output streams creating another avenue for clean energy production. Hydrogen has significant potential for decarbonizing multiple sectors across buildings transport and industries. This paper explores the integration of wind energy and hydrogen production particularly in areas where clean energy solutions are crucial such as impoverished villages in Africa. It models three systems: distinct configurations of micro-multi-energy systems that generate electricity space cooling hot water and hydrogen using the thermodynamics and cost approach. System 1 combines a wind turbine a hydrogen-producing electrolyzer and a heat pump for cooling and hot water. System 2 integrates this with a biomass-fired reheat-regenerative power cycle to balance out the intermittency of wind power. System 3 incorporates hydrogen production a solid oxide fuel cell for continuous electricity production an absorption cooling system for refrigeration and a heat exchanger for hot water production. These systems are modeled with Engineering Equation Solver and analyzed based on energy and exergy efficiencies and on economic metrics like levelized cost of electricity (LCOE) cooling (LCOC) refrigeration (LCOR) and hydrogen (LCOH) under steady-state conditions. A sensitivity analysis of various parameters is presented to assess the change in performance. Systems were optimized using a multiobjective method with maximizing exergy efficiency and minimizing total product unit cost used as objective functions. The results show that System 1 achieves 79.78 % energy efficiency and 53.94 % exergy efficiency. System 2 achieves efficiencies of 55.26 % and 27.05 % respectively while System 3 attains 78.73 % and 58.51 % respectively. The levelized costs for micro-multi-energy System 1 are LCOE = 0.04993 $/kWh LCOC = 0.004722 $/kWh and LCOH = 0.03328 $/kWh. For System 2 these values are 0.03653 $/kWh 0.003743 $/kWh and 0.03328 $/kWh. In the case of System 3 they are 0.03736 $/kWh 0.004726 $/kWh and 0.03335 $/kWh and LCOR = 0.03309 $/kWh. The results show that the systems modeled here have competitive performance with existing multi-energy systems powered by other renewables. Integrating these systems will further the sustainable and net zero energy system transition especially in rural communities.
Net Hydrogen Consumption Minimization of Fuel Cell Hybrid Trains Using a Time-Based Co-Optimization Model
Apr 2022
Publication
With increasing concerns on transportation decarbonization fuel cell hybrid trains (FCHTs) attract many attentions due to their zero carbon emissions during operation. Since fuel cells alone cannot recover the regenerative braking energy (RBE) energy storage devices (ESDs) are commonly deployed for the recovery of RBE and provide extra traction power to improve the energy efficiency. This paper aims to minimize the net hydrogen consumption (NHC) by co-optimizing both train speed trajectory and onboard energy management using a time-based mixed integer linear programming (MILP) model. In the case with the constraints of speed limits and gradients the NHC of co-optimization reduces by 6.4% compared to the result obtained by the sequential optimization which optimizes train control strategies first and then the energy management. Additionally the relationship between NHC and employed ESD capacity is studied and it is found that with the increase of ESD capacity the NHC can be reduced by up to 30% in a typical route in urban railway transit. The study shows that ESDs play an important role for FCHTs in reducing NHC and the proposed time-based co-optimization model can maximize the energy-saving benefits for such emerging traction systems with hybrid energy sources including both fuel cells and ESD.
Toward to Hydrogen Energy of Electric Power: Characteristics and Main Case Studies in Shenzhen
Feb 2023
Publication
China has pledged that it will strive to achieve peak carbon emission by 2030 and realize carbon neutrality by 2060 which has spurred renewed interest in hydrogen for widespread decarbonization of the economy. Hydrogen energy is an important secondary clean energy with the advantage of high density high calorific value rich reserves extensive sources and high conversion efficiency that can be widely used in power generation transportation fuel and other fields. In recent years with the guidance of policies and the progress of technology China’s hydrogen energy industry has developed rapidly. About 42% of China’s carbon emissions comes from the power system and Shenzhen has the largest urban power grid in China. Bringing the utilization of hydrogen energy into Shenzhen’s power system is an important method to achieve industry transformation achieve the “double carbon” goal and promote sustainable development. This paper outlines the domestic and international development status of hydrogen energy introduces the characteristics of Shenzhen new power system the industrial utilization of hydrogen energy and the challenges of further integrating hydrogen energy into Shenzhen new power system and finally suggests on the integration of hydrogen energy into Shenzhen new power system in different dimensions.
Performance Evaluation of a Hydrogen-fired Combined Cycle with Water Recovery
Mar 2023
Publication
Hydrogen can alleviate the increasing environmental pollution and has good development prospects in power generation due to its high calorific value and low environmental impact. The previously designed hydrogen-fired combined cycle ignored water recycling which led to an inefficient application of hydrogen and the wastage of water. This paper proposes the concept of a hydrogen-fired combined cycle with water recovery to reuse the condensed water as an industrial heat supply. It was applied to an F-class combined cycle power plant. The results demonstrate that the efficiency of hydrogen-fired combined cycles with and without water recovery increased by 1.92% and 1.35% respectively compared to that of the natural-gas-fired combined cycle under full working conditions. In addition an economic comparison of the three cycles was conducted. The levelized cost of energy of the hydrogen-fired combined cycle with water recovery will be 52.22% lower than that of the natural-gas-fired combined cycle in 2050. This comparative study suggested that water recovery supplementation could improve the gas turbine efficiency. The proposed hydrogen-fired combined cycle with water recovery would provide both environmental and economic benefits.
Computational Investigation of Combustion, Performance, and Emissions of a Diesel-Hydrogen Dual-Fuel Engine
Feb 2023
Publication
This paper aims to expose the effect of hydrogen on the combustion performance and emissions of a high-speed diesel engine. For this purpose a three-dimensional dynamic simulation model was developed using a reasonable turbulence model and a simplified reaction kinetic mechanism was chosen based on experimental data. The results show that in the hydrogen enrichment conditions hydrogen causes complete combustion of diesel fuel and results in a 17.7% increase in work capacity. However the increase in combustion temperature resulted in higher NOx emissions. In the hydrogen substitution condition the combustion phases are significantly earlier with the increased hydrogen substitution ratio () which is not conducive to power output. However when the is 30% the CO soot and THC reach near-zero emissions. The effect of the injection timing is also studied at an HSR of 90%. When delayed by 10° IMEP improves by 3.4% compared with diesel mode and 2.4% compared with dual-fuel mode. The NOx is reduced by 53% compared with the original dual-fuel mode. This study provides theoretical guidance for the application of hydrogen in rail transportation.
Optimal Capacity Planning of Power to Hydrogen in Integrated Electricity–Hydrogen–Gas Energy Systems Considering Flexibility and Hydrogen Injection
Apr 2022
Publication
With increasing penetration of renewable energy it is important to source adequate system flexibility to maintain security of supply and minimize renewable generation curtailment. Power to hydrogen (P2H) plays an important role in the low-carbon renewable dominated energy systems. By blending green hydrogen produced from renewable power into the natural gas pipelines it is possible to help integrate large-scale intermittent generation and smooth the variability of renewable power output through the interconnection of the natural gas network hydrogen energy network and electric network. A two-stage stochastic mixed-integer nonlinear planning framework for P2H sizing and siting is proposed in this paper considering system flexibility requirements. The problem is then reduced to a mixed-integer second-order cone (MISOC) model through convex transformation techniques in order to reduce the computation burden. Then a distributed algorithm based on Bender’s decomposition is applied to obtain the optimal solution. A modified hybrid IEEE 33-node and Gas 20-node system is then used for simulation tests. The results showed that investment of P2H can significantly reduce the total capital and operational costs with lower renewable generation curtailment and electricity demand shedding. Numerical tests demonstrated to demonstrate the validity of the proposed MISOC model.
Multi-layer Coordinated Optimization of Integrated Energy System with Electric Vehicles Based on Feedback Correction
Sep 2022
Publication
The integrated energy system with electric vehicles can realize multi-energy coordination and complementarity and effectively promote the realization of low-carbon environmental protection goals. However the temporary change of vehicle travel plan will have an adverse impact on the system. Therefore a multi-layer coordinated optimization strategy of electric-thermal-hydrogen integrated energy system including vehicle to grid (V2G) load feedback correction is proposed. The strategy is based on the coordination of threelevel optimization. The electric vehicle charging and discharging management layer comprehensively considers the variance of load curve and the dissatisfaction of vehicle owners and the charging and discharging plan is obtained through multi-objective improved sparrow search algorithm which is transferred to the model predictive control rolling optimization layer. In the rolling optimization process according to the actual situation selectively enter the V2G load feedback correction layer to update V2G load so as to eliminate the impact of temporary changes in electric vehicle travel plans. Simulation results show that the total operating cost with feedback correction is 4.19% lower than that without feedback correction and tracking situation of tie-line planned value is improved which verifies the proposed strategy.
Development Concept of Integrated Energy Network and Hydrogen Energy Industry Based on Hydrogen Production Using Surplus Hydropower
Apr 2020
Publication
The development of hydropower industry is progressing rapidly in China and the installed capacity and power generation are increasing year by year. However due to factors such as transmission channels and power grid peaking capacity hydropower consumption in some areas is facing greater pressure. As an excellent medium for energy interconnection hydrogen energy can play an important role in promoting hydropower consumption. This paper introduces the current status and trends of hydrogen energy development in major developed countries and China and analyzes the current status of China’s hydropower abandoned water. Based on the production of hydrogen using surplus hydropower in the Dadu River Basin in Sichuan an integrated energy network research plan including hydropower electrolytic hydrogen production storage and transportation hydrogen refueling and hydrogen-powered vehicles is proposed. At the same time the development concept of hydrogen energy industry including hydrogen energy source economy hydrogen energy industry ecosphere and hydrogen energy sky road in western Sichuan is also proposed.
Hydrogen-Electric Coupling Coordinated Control Strategy of Multi-Station Integrated System Based on the Honeycomb Topology
Mar 2022
Publication
With the high-proportion accession of renewable energy and randomness of the load side in the new energy power system unbalanced feeder power and heavy overload of the transformer caused by massive access of highly uncertain source loads become more and more serious. In order to solve the aforementioned problems a honeycomb topology of the multi-station integrated system is proposed. The soft open point (SOP) is used as the key integrated equipment of the internal unit of a multi-station integrated system. The honeycomb grid structure is composed of flexible nodes and the multi-station integrated system is composed of multi-network flexible interconnection. Based on the characteristics of the regional resource endowment hydrogen energy flow is deeply coupled in parts of honeycomb grids. In order to improve the reliability and flexibility of the multi-station integrated unit the structure of the new multi-station integrated unit the power balance constraints on the unit and the switching process of SOP control mode are studied. At the same time the hydrogen electricity coupling structure and the coordinated control strategy of hydrogen electricity conversion are proposed to solve the problem of deep application of hydrogen energy. Finally the effectiveness of the proposed multi-station integrated system is verified by using three simulation models.
Optimal Scheduling of Multi-microgrids with Power to Hydrogen Considering Federated Demand Response
Sep 2022
Publication
Hydrogen is regarded as a promising fuel in the transition to clean energy. Nevertheless as the demand for hydrogen increases some microgrids equipped with P2H (MGH) will encounter the issue of primary energy deficiency. Meanwhile some microgrids (MGs) face the difficulty of being unable to consume surplus energy locally. Hence we interconnect MGs with different energy characteristics and then establish a collaborative scheduling model of multi-microgrids (MMGs). In this model a federated demand response (FDR) program considering predictive mean voting is designed to coordinate controllable loads of electricity heat and hydrogen in different MGs. With the coordination of FDR the users’ satisfaction and comfort in each MG are kept within an acceptable range. To further adapt to an actual working condition of the microturbine (MT) in MGH a power interaction method is proposed to maintain the operating power of the MT at the optimum load level and shave peak and shorten the operating periods of MT. In the solution process the sequence operation theory is utilized to deal with the probability density of renewable energy. A series of case studies on a test system of MMG demonstrate the effectiveness of the proposed method.
Experimental Study on the Cycle Variation Characteristics of Direct Injection Hydrogen Engine
Jun 2022
Publication
Hydrogen energy is an important technical route to achieve carbon peak and carbon neutrality. Direct injection hydrogen engine is one of the ways of hydrogen energy application. It has the advantages of high thermal efficiency and limit/reduce abnormal combustion phenomena. In order to explore the cycle characteristics of direct injection hydrogen engine based on a 2.0L direct injection hydrogen engine an experimental study on the cycle characteristics of direct injection hydrogen engine was carried out. The experimental results show that cycle variation increases from 0.67% to 1.02% with the increasing of engine speed. The cycle variation decreases from 1.52% to 0.64% with the increasing of engine load. As the equivalence ratio increases the cycle variation first decreases significantly from 2.52% to 0.35% and then stabilizes. The ignition advance angle has a better angle to minimize the cycle variation. An experimental study on the influence of the start of injection on the cycle variation was carried out. As the engine speed/engine load is 2000rpm/4bar the cycle variation increases from 0.72% to 2.42% with the start of injection changing from -280°CA to -180°CA; then rapidly decreases to 0.99% and then increases to 2.26% with the start of injection changing from -180°CA to -100°CA. The experimental results show that SOI could cause significant influence on cycle variation because of intake valve closing and shortening mixing time and both the process of intake valve closing and lagging the SOI could cause the cycle variation to increase. The SOI remarkably affects the cycle variation at low engine load/equivalence ratio and high engine speed. This study lays the foundation for the follow-up research of hydrogen engine performance matching of the cycle variation.
Investigation of Mixing Behavior of Hydrogen Blended to Natural Gas in Gas Network
Apr 2021
Publication
Hydrogen is of great significance for replacing fossil fuels and reducing carbon dioxide emissions. The application of hydrogen mixing with natural gas in gas network transportation not only improves the utilization rate of hydrogen energy but also reduces the cost of large-scale updating household or commercial appliance. This paper investigates the necessity of a gas mixing device for adding hydrogen to existing natural gas pipelines in the industrial gas network. A three-dimensional helical static mixer model is developed to simulate the mixing behavior of the gas mixture. In addition the model is validated with experimental results. Parametric studies are performed to investigate the effect of mixer on the mixing performance including the coefficient of variation (COV) and pressure loss. The research results show that based on the the optimum number of mixing units is three. The arrangement of the torsion angle of the mixing unit has a greater impact on the COV. When the torsion angle θ = 120◦ the COV has a minimum value of 0.66% and when the torsion angle θ = 60◦ the COV has a maximum value of 8.54%. The distance of the mixing unit has little effect on the pressure loss of the mixed gas but has a greater impact on the COV. Consecutive arrangement of the mixing units (Case A) is the best solution. Increasing the distance of the mixing unit is not effective for the gas mixing effect. Last but not least the gas mixer is optimized to improve the mixing performance.
Influence of Hydrogen Environment on Fatigue Fracture Morphology of X80 Pipeline Steel
Dec 2022
Publication
The rapid development of hydrogen energy requires the use of natural gas infrastructure for hydrogen transportation. It is very important to study hydrogen-added natural gas transportation technology which is a key way to rapidly develop coal-based gas and renewable energy. This study aims to study the influence of X80 pipeline steel's fatigue performance in hydrogen environment and perform fatigue tests on notched round rod specimens under different hydrogen concentration. The experimental results show that hydrogen seriously affects the fatigue life of pipeline steel. After reaching a certain hydrogen concentration as the hydrogen concentration continues to increase the fatigue life decreases gradually. Combined with SEM analysis of fracture morphology the decrease in the size and density of the dimples reduces the displacement amplitude while the increase in the planar area increases the displacement during fatigue fracture due to accelerated crack propagation. From this study we can know the influence of hydrogen concentration on the fracture morphology of pipeline steel which provides an understanding of the effect of hydrogen on fatigue fracture morphology and a broader safety analysis.
Deep Reinforcement Learning Based Energy Management Strategy for Fuel Cell/Battery/Supercapacitor Powered Electric Vehicle
Sep 2022
Publication
Vehicles using a single fuel cell as a power source often have problems such as slow response and inability to recover braking energy. Therefore the current automobile market is mainly dominated by fuel cell hybrid vehicles. In this study the fuel cell hybrid commercial vehicle is taken as the research object and a fuel cell/ battery/supercapacitor energy topology is proposed and an energy management strategy based on a doubledelay deep deterministic policy gradient is designed for this topological structure. This strategy takes fuel cell hydrogen consumption fuel cell life loss and battery life loss as the optimization goals in which supercapacitors play the role of coordinating the power output of the fuel cell and the battery providing more optimization ranges for the optimization of fuel cells and batteries. Compared with the deep deterministic policy gradient strategy (DDPG) and the nonlinear programming algorithm strategy this strategy has reduced hydrogen consumption level fuel cell loss level and battery loss level which greatly improves the economy and service life of the power system. The proposed EMS is based on the TD3 algorithm in deep reinforcement learning and simultaneously optimizes a number of indicators which is beneficial to prolong the service life of the power system.
A Review of Key Components of Hydrogen Recirculation Subsystem for Fuel Cell Vehicles
Jul 2022
Publication
Hydrogen energy and fuel cell technology are critical clean energy roads to pursue carbon neutrality. The proton exchange membrane fuel cell (PEMFC) has a wide range of commercial application prospects due to its simple structure easy portability and quick start-up. However the cost and durability of the PEMFC system are the main barriers to commercial applications of fuel cell vehicles. In this paper the core hydrogen recirculation components of fuel cell vehicles including mechanical hydrogen pumps ejectors and gas–water separators are reviewed in order to understand the problems and challenges in the simulation design and application of these components. The types and working characteristics of mechanical pumps used in PEMFC systems are summarized. Furthermore corresponding design suggestions are given based on the analysis of the design challenges of the mechanical hydrogen pump. The research on structural design and optimization of ejectors for adapting wide power ranges of PEMFC systems is analyzed. The design principle and difficulty of the gas–water separator are summarized and its application in the system is discussed. In final the integration and control of hydrogen recirculation components controlled cooperatively to ensure the stable pressure and hydrogen supply of the fuel cell under dynamic loads are reviewed.
A Review on Numerical Simulation of Hydrogen Production from Ammonia Decomposition
Jan 2023
Publication
Ammonia (NH3 ) is regarded as a promising medium of hydrogen storage due to its large hydrogen storage density decent performance on safety and moderate storage conditions. On the user side NH3 is generally required to decompose into hydrogen for utilization in fuel cells and therefore it is vital for the NH3 -based hydrogen storage technology development to study NH3 decomposition processes and improve the decomposition efficiency. Numerical simulation has become a powerful tool for analyzing the NH3 decomposition processes since it can provide a revealing insight into the heat and mass transfer phenomena and substantial guidance on further improving the decomposition efficiency. This paper reviews the numerical simulations of NH3 decomposition in various application scenarios including NH3 decomposition in microreactors coupled combustion chemical reactors solid oxide fuel cells and membrane reactors. The models of NH3 decomposition reactions in various scenarios and the heat and mass transport in the reactor are elaborated. The effects of reactor structure and operating conditions on the performance of NH3 decomposition reactor are analyzed. It can be found that NH3 decomposition in microchannel reactors is not limited by heat and mass transfer and NH3 conversion can be improved by using membrane reactors under the same conditions. Finally research prospects and opportunities are proposed in terms of model development and reactor performance improvement for NH3 decomposition.
Exergy and Exergoeconomic Analysis for the Proton Exchange Membrane Water Electrolysis under Various Operating Conditions and Design Parameters
Nov 2022
Publication
Integrating the exergy and economic analyses of water electrolyzers is the pivotal way to comprehend the interplay of system costs and improve system performance. For this a 3D numerical model based on COMSOL Multiphysics Software (version 5.6 COMSOL Stockholm Sweden) is integrated with the exergy and exergoeconomic analysis to evaluate the exergoeconomic performance of the proton exchange membrane water electrolysis (PEMWE) under different operating conditions (operating temperature cathode pressure current density) and design parameter (membrane thickness). Further the gas crossover phenomenon is investigated to estimate the impact of gas leakage on analysis reliability under various conditions and criteria. The results reveal that increasing the operating temperature or decreasing the membrane thickness improves both the efficiency and cost of hydrogen exergy while increasing the gas leakage through the membrane. Likewise raising the current density and the cathode pressure lowers the hydrogen exergy cost and improves the economic performance. The increase in exergy destroyed and hydrogen exergy cost as well as the decline in second law efficiency due to the gas crossover are more noticeable at higher pressures. As the cathode pressure rises from 1 to 30 bar at a current density of 10000 A/m2 the increase in exergy destroyed and hydrogen exergy cost as well as the decline in second law efficiency are increased by 37.6 kJ/mol 4.49 USD/GJ and 7.1% respectively. The cheapest green electricity source which is achieved using onshore wind energy and hydropower reduces hydrogen production costs and enhances economic efficiency. The growth in the hydrogen exergy cost is by about 4.23 USD/GJ for a 0.01 USD/kWh increase in electricity price at the current density of 20000 A/m2. All findings would be expected to be quite useful for researchers engaged in the design development and optimization of PEMWE.
Low-Carbon Economic Dispatch of Integrated Energy Systems in Industrial Parks Considering Comprehensive Demand Response and Multi-Hydrogen Supply
Mar 2024
Publication
To address the increasing hydrogen demand and carbon emissions of industrial parks this paper proposes an integrated energy system dispatch strategy considering multi-hydrogen supply and comprehensive demand response. This model adopts power-to-gas technology to produce green hydrogen replacing a portion of gray hydrogen and incorporates a carbon capture system to effectively reduce the overall carbon emissions of the industrial park. Meanwhile incentive-based and price-based demand response strategies are implemented to optimize the load curve. A scheduling model is established targeting the minimization of procurement operation carbon emission and wind curtailment costs. The case study of a northern industrial park in China demonstrates that the joint supply of green and gray hydrogen reduces carbon emissions by 40.98% and costs by 17.93% compared to solely using gray hydrogen. The proposed approach successfully coordinates the economic and environmental performance of the integrated energy system. This study provides an effective scheduling strategy for industrial parks to accommodate high shares of renewables while meeting hydrogen needs and carbon reduction targets.
Hydrogen Production from the Air
Sep 2022
Publication
Green hydrogen produced by water splitting using renewable energy is the most promising energy carrier of the low-carbon economy. However the geographic mismatch between renewables distribution and freshwater availability poses a significant challenge to its production. Here we demonstrate a method of direct hydrogen production from the air namely in situ capture of freshwater from the atmosphere using hygroscopic electrolyte and electrolysis powered by solar or wind with a current density up to 574 mA cm−2 . A prototype of such has been established and operated for 12 consecutive days with a stable performance at a Faradaic efficiency around 95%. This so-called direct air electrolysis (DAE) module can work under a bone-dry environment with a relative humidity of 4% overcoming water supply issues and producing green hydrogen sustainably with minimal impact to the environment. The DAE modules can be easily scaled to provide hydrogen to remote (semi-) arid and scattered areas.
Investigating the Impact of Economic Uncertainty on Optimal Sizing of Grid-Independent Hybrid Renewable Energy Systems
Aug 2021
Publication
One of the many barriers to decarbonization and decentralization of the energy sector in developing countries is the economic uncertainty. As such this study scrutinizes economics of three grid-independent hybrid renewable-based systems proposed to co-generate electricity and heat for a small-scale load. Accordingly the under-study systems are simulated and optimized with the aid of HOMER Pro software. Here a 20-year average value of discount and inflation rates is deemed a benchmark case. The techno-economic-environmental and reliability results suggest a standalone solar/wind/electrolyzer/hydrogen-based fuel cell integrated with a hydrogen-based boiler system is the best alternative. Moreover to ascertain the impact of economic uncertainty on optimal unit sizing of the nominated model the fluctuations of the nominal discount rate and inflation respectively constitute within the range of 15–20% and 10–26%. The findings of economic uncertainty analysis imply that total net present cost (TNPC) fluctuates around the benchmark value symmetrically between $478704 and $814905. Levelized energy cost varies from an amount 69% less than the benchmark value up to two-fold of that. Furthermore photovoltaic (PV) optimal size starts from a value 23% less than the benchmark case and rises up to 55% more. The corresponding figures for wind turbine (WT) are respectively 21% and 29%. Eventually several practical policies are introduced to cope with economic uncertainty.
Numerical Investigation on the Liquid Hydrogen Leakage and Protection Strategy
Apr 2023
Publication
One of China’s ambitious hydrogen strategies over the past few years has been to promote fuel cells. A number of hydrogen refueling stations (HRSs) are currently being built in China to refuel hydrogen-powered automobiles. In this context it is crucial to assess the dangers of hydrogen leaking in HRSs. The present work simulated the liquid hydrogen (LH2) leakage with the goal of undertaking an extensive consequence evaluation of the LH2 leakage on an LH2 refueling station (LHRS). Furthermore the utilization of an air curtain to prevent the diffusion of the LH2 leakage is proposed and the defending effect is studied accordingly. The results reveal that the Richardson number effectively explained the variation of plume morphology. Furthermore different facilities have great influence on the gas cloud diffusion trajectory with the consideration of different leakage directions. The air curtain shows satisfactory prevention of the diffusion of the hydrogen plume. Studies show that with the increase in air volume (equivalent to wind speed) and the narrowing of the air curtain width (other factors remain unchanged) the maximum flammable distance of hydrogen was shortened.
Optimal Scheduling of Integrated Energy System Considering Hydrogen Blending Gas and Demand Response
Apr 2024
Publication
In the context of carbon neutrality and carbon peaking in order to achieve low carbon emissions and promote the efficient utilization of wind energy hydrogen energy as an important energy carrier is proposed to mix hydrogen and natural gas to form hydrogen-enriched compressed natural gas (HCNG). It is also injected into the natural gas pipeline network to achieve the transmission and utilization of hydrogen energy. At the same time the participation of demand response is considered the load’s peak and trough periods are adjusted and the large-scale consumption of renewable energy and the reduction in carbon emissions are achieved. First of all a fine model of hydrogen production and hydrogen use equipment is established to analyze the impact of adding hydrogen mixing on the economy and the low-carbon property of the system. With green certificates and demand response the utilization rate of hydrogen energy is improved to further explore the energy utilization rate and emission reduction capacity of the system. Secondly on the basis of modeling the optimal scheduling strategy is proposed with the sum of energy purchase cost equipment operation cost carbon emission cost wind curtailment cost and green certificate income as the lowest objective function. Considering the constraints such as hydrogen blending ratio and flexible load ratio of the pipeline network a low-carbon economic scheduling model of hydrogen mixed natural gas was established. The model was linearized and solved by using MATLAB 2021a and CPLEX solver. By comparing different scenarios the superiority of the model and the effectiveness of the strategy are verified.
Research on the Adaptability of Proton Exchange Membrane Electrolysis in Green Hydrogen-Electric Coupling System Under Multi-operating Conditions
Mar 2023
Publication
The green hydrogen–electric coupling system can consume locally generated renewable energy thereby improving energy utilization and enabling zero-carbon power supply within a certain range. This study focuses on a green hydrogen–electric coupling system that integrates photovoltaic energy storage and proton exchange membrane electrolysis (PEME). Firstly the impact of operating temperature power quality and grid auxiliary services on the characteristics of the electrolysis cell is analyzed and a voltage model and energy model for the cell are established. Secondly a multi-operating conditions adaptability experiment for PEME grid-connected operation is designed. A test platform consisting of a grid simulator simulated photovoltaic power generation system lithium battery energy storage system PEME and measurement and acquisition device is then built. Finally experiments are conducted to simulate multi-operating conditions such as temperature changes voltage fluctuations frequency offsets harmonic pollution and current adjustment speed. The energy efficiency and consumption is calculated based on the recorded data and the results are helpful to guide the operation of the system.
Safe Design of a Hydrogen-Powered Ship: CFD Simulation on Hydrogen Leakage in the Fuel Cell Room
Mar 2023
Publication
Adopting proton exchange membrane fuel cells fuelled by hydrogen presents a promising solution for the shipping industry’s deep decarbonisation. However the potential safety risks associated with hydrogen leakage pose a significant challenge to the development of hydrogen-powered ships. This study examines the safe design principles and leakage risks of the hydrogen gas supply system of China’s first newbuilt hydrogen-powered ship. This study utilises the computational fluid dynamics tool FLACS to analyse the hydrogen dispersion behaviour and concentration distributions in the hydrogen fuel cell room based on the ship’s parameters. This study predicts the flammable gas cloud and time points when gas monitoring points first reach the hydrogen volume concentrations of 0.8% and 1.6% in various leakage scenarios including four different diameters (1 3 5 and 10 mm) and five different directions. This study’s findings indicate that smaller hydrogen pipeline diameters contribute to increased hydrogen safety. Specifically in the hydrogen fuel cell room a single-point leakage in a hydrogen pipeline with an inner diameter not exceeding 3 mm eliminates the possibility of flammable gas cloud explosions. Following a 10 mm leakage diameter the hydrogen concentration in nearly all room positions reaches 4.0% within 6 s of leakage. While the leakage diameter does not impact the location of the monitoring point that first activates the hydrogen leak alarm and triggers an emergency hydrogen supply shutdown the presence of obstructions near hydrogen detectors and the leakage direction can affect it. These insights provide guidance on the optimal locations for hydrogen detectors in the fuel cell room and the pipeline diameters on hydrogen gas supply systems which can facilitate the safe design of hydrogen-powered ships.
Hydrogen Leakage Simulation and Risk Analysis of Hydrogen Fueling Station in China
Sep 2022
Publication
Hydrogen is a renewable energy source with various features clean carbon-free high energy density which is being recognized internationally as a “future energy.” The US the EU Japan South Korea China and other countries or regions are gradually clarifying the development position of hydrogen. The rapid development of the hydrogen energy industry requires more hydrogenation infrastructure to meet the hydrogenation need of hydrogen fuel cell vehicles. Nevertheless due to the frequent occurrence of hydrogen infrastructure accidents their safety has become an obstacle to large-scale construction. This paper analyzed five sizes (diameters of 0.068 mm 0.215 mm 0.68 mm 2.15 mm and 6.8 mm) of hydrogen leakage in the hydrogen fueling station using Quantitative Risk Assessment (QRA) and HyRAM software. The results show that unignited leaks occur most frequently; leaks caused by flanges valves instruments compressors and filters occur more frequently; and the risk indicator of thermal radiation accident and structure collapse accident caused by over-pressure exceeds the Chinese individual acceptable risk standard and the risk indicator of a thermal radiation accident and head impact accident caused by overpressure is below the Chinese standard. On the other hand we simulated the consequences of hydrogen leak from the 45 MPa hydrogen storage vessels by the physic module of HyRAM and obtained the ranges of plume dispersion jet fire radiative heat flux and unconfined overpressure. We suggest targeted preventive measures and safety distance to provide references for hydrogen fueling stations’ safe construction and operation.
Can Africa Serve Europe with Hydrogen Energy from Its Renewables?—Assessing the Economics of Shipping Hydrogen and Hydrogen Carriers to Europe from Different Parts of the Continent
Apr 2023
Publication
There exists no single optimal way for transporting hydrogen and other hydrogen carriers from one port to the other globally. Its delivery depends on several factors such as the quantity distance economics and the availability of the required infrastructure for its transportation. Europe has a strategy to invest in the production of green hydrogen in Africa to meet its needs. This study assessed the economic viability of shipping liquefied hydrogen (LH2 ) and hydrogen carriers to Germany from six African countries that have been identified as countries with great potential in the production of hydrogen. The results obtained suggest that the shipping of LH2 to Europe (Germany) will cost between 0.47 and 1.55 USD/kg H2 depending on the distance of travel for the ship. Similarly the transportation of hydrogen carriers could range from 0.19 to 0.55 USD/kg H2 for ammonia 0.25 to 0.77 USD/kg H2 for LNG 0.24 to 0.73 USD/kg H2 for methanol and 0.43 to 1.28 USD/kg H2 for liquid organic hydrogen carriers (LOHCs). Ammonia was found to be the ideal hydrogen carrier since it recorded the least transportation cost. A sensitivity analysis conducted indicates that an increase in the economic life by 5 years could averagely decrease the cost of LNG by some 13.9% NH3 by 13.2% methanol by 7.9% LOHC by 8.03% and LH2 by 12.41% under a constant distance of 6470 nautical miles. The study concludes with a suggestion that if both foreign and local participation in the development of the hydrogen market is increased in Africa the continent could supply LH2 and other hydrogen carriers to Europe at a cheaper price using clean fuel.
Configuration Optimization of Hydrogen-Based Multi-Microgrid Systems under Electricity Market Trading and Different Hydrogen Production Strategies
Apr 2023
Publication
Hydrogen-based multi-microgrid systems (HBMMSs) are beneficial for energy saving and emission reductions. However the optimal sizing of HBMMSs lacks a practical configuration optimization model and a reasonable solution method. To address these problems we designed a novel structure of HBMMSs that combines conventional energy renewable energy and a hydrogen energy subsystem. Then we established a bi-level multi-objective capacity optimization model while considering electricity market trading and different hydrogen production strategies. The objective of the inner model which is the minimum annual operation cost and the three objectives of the outer model which are the minimum total annual cost (TAC); the annual carbon emission (ACE); and the maximum self-sufficiency rate (SSR) are researched simultaneously. To solve the above optimization model a two-stage solution method which considers the conflicts between objectives and the objectivity of objective weights is proposed. Finally a case study is performed. The results show that when green hydrogen production strategies are adopted the three objectives of the best configuration optimization scheme are USD 404.987 million 1.106 million tons and 0.486 respectively.
A Review of Hydrogen-based Hybrid Renewable Energy Systems: Simulation and Optimization with Artificial Intelligence
Nov 2021
Publication
With the massive use of traditional fossil fuels greenhouse gas emissions are increasing and environmental pollution is becoming an increasingly serious problem which led to an imminent energy transition. Therefore the development and application of renewable energy are particularly important. This paper reviews a wide range of issues associated with hybrid renewable energy systems (HRESs). The issues concerning system configurations energy storage options simulation and optimization with artificial intelligence are discussed in detail. Storage technology options are introduced for stand-alone (off-grid) and grid-connected (on-grid) HRESs. Different optimization methodologies including classical techniques intelligent techniques hybrid techniques and software tools for sizing system components are presented. Besides the artificial intelligence methods for optimizing the solar/wind HRESs are discussed in detail.
Minimizing Emissions from Grid-based Hydrogen Production in the United States
Jan 2023
Publication
Low-carbon hydrogen could be an important component of a net-zero carbon economy helping to mitigate emissions in a number of hard-to-abate sectors. The United States recently introduced an escalating production tax credit (PTC) to incentivize production of hydrogen meeting increasingly stringent embodied emissions thresholds. Hydrogen produced via electrolysis can qualify for the full subsidy under current federal accounting standards if the input electricity is generated by carbon-free resources but may fail to do so if emitting resources are present in the generation mix. While use of behind-the-meter carbon-free electricity inputs can guarantee compliance with this standard the PTC could also be structured to allow producers using grid-supplied electricity to qualify subject to certain clean energy procurement requirements. Herein we use electricity system capacity expansion modeling to quantitatively assess the impact of grid-connected electrolysis on the evolution of the power sector in the western United States through 2030 under multiple possible implementations of the clean hydrogen PTC. We find that subsidized grid-connected hydrogen production has the potential to induce additional emissions at effective rates worse than those of conventional fossil-based hydrogen production pathways. Emissions can be minimized by requiring grid-based hydrogen producers to match 100% of their electricity consumption on an hourly basis with physically deliverable ‘additional’ clean generation which ensures effective emissions rates equivalent to electrolysis exclusively supplied by behind-the-meter carbon-free generation. While these requirements cannot eliminate indirect emissions caused by competition for limited clean resources which we find to be a persistent result of large hydrogen production subsidies they consistently outperform alternative approaches relying on relaxed time matching or marginal emissions accounting. Added hydrogen production costs from enforcing an hourly matching requirement rather than no requirements are less than $1 kg−1 and can be near zero if clean firm electricity resources are available for procurement.
A Control Strategy Study of a Renewable CCHP Energy System Integrated Hydrogen Production Unit - A Case Study of an Industrial Park in Jiangsu Province
Aug 2023
Publication
This paper describes a renewable energy system incorporating a hydrogen production unit to address the imbalance between energy supply and demand. The system utilizes renewable energy and hydrogen production energy to release energy to fill the power gap during peak demand power supply for demand peaking and valley filling. The system is optimized by analyzing marine predator behavioral logic and optimizing the system for maximum operational efficiency and best economic value. The results of the study show that after the optimized scheduling of the hydrogen production coupled renewable energy integrated energy system using the improved marine predator optimization algorithm the energy distribution of the whole energy system is good with the primary energy saving rate maintained at 24.75% the CO2 emission reduction rate maintained at 42.32% and the cost saving rate maintained at 0.78%. In addition this paper uses the Adaboost-BP prediction model to predictively analyze the system. The results show that as the price of natural gas increases the advantages of the combined hydrogen production renewable integrated energy system proposed in this paper become more obvious and the cumulative cost over three years is better than other related systems. These research results provide an important reference for the application and development of the system.
Genesis and Energy Significance of Natural Hydrogen
Jan 2023
Publication
H2 is clean energy and an important component of natural gas. Moreover it plays an irreplaceable role in improving the hydrocarbon generation rate of organic matter and activating ancient source rocks to generate hydrocarbon in Fischer-Tropsch (FT) synthesis and catalytic hydrogenation. Compared with hydrocarbon reservoir system a complete hydrogen (H2) accumulation system consists of H2 source,reservoirs and seal. In nature the four main sources of H2 are hydrolysis organic matter degradation the decomposition of substances such as methane and ammonia and deep mantle degassing. Because the complex tectonic activities the H2 produced in a geological environment is generally a mixture of various sources. Compared with the genetic mechanisms of H2 the migration and preservation of H2 especially the H2 trapping are rarely studied. A necessary condition for large-scale H2 accumulation is that the speed of H2 charge is much faster than diffusion loss. Dense cap rock and continuous H2 supply are favorable for H2 accumulation. Moreover H2O in the cap rock pores may provide favorable conditions for short-term H2 accumulation.
Optimal Scheduling of Power Systems with High Proportions of Renewable Energy Accounting for Operational Flexibility
Jul 2023
Publication
Yi Lin,
Wei Lin,
Wei Wu and
Zhenshan Zhu
The volatility and uncertainty of high-penetration renewable energy pose significant challenges to the stability of the power system. Current research often fails to consider the insufficient system flexibility during real-time scheduling. To address this issue this paper proposes a flexibility scheduling method for high-penetration renewable energy power systems that considers flexibility index constraints. Firstly a quantification method for flexibility resources and demands is introduced. Then considering the constraint of the flexibility margin index optimization scheduling strategies for different time scales including day-ahead scheduling and intra-day scheduling are developed with the objective of minimizing total operational costs. The intra-day optimization is divided into 15 min and 1 min time scales to meet the flexibility requirements of different time scales in the power system. Finally through simulation studies the proposed strategy is validated to enhance the system’s flexibility and economic performance. The daily operating costs are reduced by 3.1% and the wind curtailment rate is reduced by 4.7%. The proposed strategy not only considers the economic efficiency of day-ahead scheduling but also ensures a sufficient margin to cope with the uncertainty of intra-day renewable energy fluctuations.
Investment Timing Analysis of Hydrogen-Refueling Stations and the Case of China: Independent or Co-Operative Investment?
Jun 2023
Publication
The investment in hydrogen-refueling stations (HRS) is key to the development of a hydrogen economy. This paper focuses on the decision-making for potential investors faced with the thought-provoking question of when the optimal timing to invest in HRS is. To fill the gap that exists due to the fact that few studies explain why HRS investment timing is critical we expound that earlier investment in HRS could induce the first mover advantages of the technology diffusion theory. Additionally differently from the previous research that only considered that HRS investment is just made by one individual firm we innovatively examine the HRS co-investment made by two different firms. Accordingly we compare these two optional investment modes and determine which is better considering either independent investment or co-operative investment. We then explore how the optimal HRS investment timing could be figured out under conditions of uncertainty with the real options approach. Given the Chinese HRS case under the condition of demand uncertainty the hydrogen demand required for triggering investment is viewed as the proxy for investment timing. Based on analytical and numerical results we conclude that one-firm independent investment is better than two-firm cooperative investment to develop HRS not only in terms of the earlier investment timing but also in terms of the attribute for dealing with the uncertainty. Finally we offer recommendations including stabilizing the hydrogen demand for decreasing uncertainty and accelerating firms’ innovation from both technological and strategic perspectives in order to ensure firms can make HRS investments on their own.
Current Development Status, Policy Support and Promotion Path of China’s Green Hydrogen Industries under the Target of Carbon Emission Peaking and Carbon Neutrality
Jun 2023
Publication
The green hydrogen industry highly efficient and safe is endowed with flexible production and low carbon emissions. It is conducive to building a low-carbon efficient and clean energy structure optimizing the energy industry system and promoting the strategic transformation of energy development and enhancing energy security. In order to achieve carbon emission peaking by 2030 and neutrality by 2060 (dual carbon goals) China is vigorously promoting the green hydrogen industry. Based on an analysis of the green hydrogen industry policies of the U.S. the EU and Japan this paper explores supporting policies issued by Chinese central and local authorities and examines the inherent advantages of China’s green hydrogen industry. After investigating and analyzing the basis for the development of the green hydrogen industry in China we conclude that China has enormous potential including abundant renewable energy resources as well as commercialization experience with renewable energy robust infrastructure and technological innovation capacity demand for large-scale applications of green hydrogen in traditional industries etc. Despite this China’s green hydrogen industry is still in its early stage and has encountered bottlenecks in its development including a lack of clarity on the strategic role and position of the green hydrogen industry low competitiveness of green hydrogen production heavy reliance on imports of PEMs perfluorosulfonic acid resins (PFSR) and other core components the development dilemma of the industry chain lack of installed capacity for green hydrogen production and complicated administrative permission etc. This article therefore proposes that an appropriate development road-map and integrated administration supervision systems including safety supervision will systematically promote the green hydrogen industry. Enhancing the core technology and equipment of green hydrogen and improving the green hydrogen industry chain will be an adequate way to reduce dependence on foreign technologies lowering the price of green hydrogen products through the scale effect and thus expanding the scope of application of green hydrogen. Financial support mechanisms such as providing tax breaks and project subsidies will encourage enterprises to carry out innovative technological research on and invest in the green hydrogen industry.
Impacts of Wind Conditions on Hydrogen Leakage During Refilling Hydrogen-powered Vehicles
Mar 2023
Publication
Although hydrogen leakage at hydrogen refueling stations has been a concern less effort has been devoted to hydrogen leakage during the refueling of hydrogen-powered vehicles. In this study hydrogen leakage and dilution from the hydrogen dispenser during the refueling of hydrogen-powered vehicles were numerically investigated under different wind configurations. The shape size and distribution of flammable gas clouds (FGC) during the leakage and dilution processes were analyzed. The results showed that the presence of hydrogen-powered vehicles resulted in irregular FGC shapes. Greater wind speeds (vwv) were associated with longer FGC propagation distances. At vwv =2 m/s and 10 m/s the FGC lengths at the end of the leakage were 7.9 m and 20.4 m respectively. Under downwind conditions higher wind speeds corresponded to lower FGC heights. The FGC height was larger under upwind conditions and was slightly affected by the magnitude of the wind speed. In the dilution process the existence of a region with a high hydrogen concentration led to the FGC volume first increasing and then gradually decreasing. Wind promoted the mixing of hydrogen and air accelerated FGC dilution inhibited hydrogen uplifting and augmented the horizontal movement of the FGC. At higher wind speeds the low-altitude FGC movements could induce potential safety hazards.
Anion Exchange Membrane Water Electrolyzer: Electrode Design, Lab-scaled Testing System and Performance Evaluation
Aug 2022
Publication
Green hydrogen produced by water electrolysis is one of the most promising technologies to realize the efficient utilization of intermittent renewable energy and the decarbonizing future. Among various electrolysis technologies the emerging anion-exchange membrane water electrolysis (AEMWE) shows the most potential for producing green hydrogen at a competitive price. In this review we demonstrate a comprehensive introduction to AEMWE including the advanced electrode design the lab-scaled testing system establishment and the electrochemical performance evaluation. Specifically recent progress in developing high activity transition metal-based powder electrocatalysts and self-supporting electrodes for AEMWE is summarized. To improve the synergistic transfer behaviors between electron charge water and gas inside the gas diffusion electrode (GDE) two optimizing strategies are concluded by regulating the pore structure and interfacial chemistry. Moreover we provide a detailed guideline for establishing the AEMWE testing system and selecting the electrolyzer components. The influences of the membrane electrode assembly (MEA) technologies and operation conditions on cell performance are also discussed. Besides diverse electrochemical methods to evaluate the activity and stability implement the failure analyses and realize the in-situ characterizations are elaborated. In end some perspectives about the optimization of interfacial environment and cost assessments have been proposed for the development of advanced and durable AEMWE.
A Theoretical Study on the Hydrogen Filling Process of the On-board Storage Cylinder in Hydrogen Refueling Station
May 2023
Publication
With the development of the hydrogen fuel automobile industry higher requirements are put forward for the construction of hydrogen energy infrastructure the matching of parameters and the control strategy of hydrogen filling rate in the hydrogen charging process of hydrogen refueling stations. At present the technological difficulty of hydrogen fueling is mainly reflected in the balanced treatment of reducing the temperature rise of hydrogen and shortening the filling time during the fast filling process. Vehicle hydrogen storage cylinder (VHSC) is one of the important components of hydrogen fuel cell vehicles. This study proposed a theoretical model for calculating the temperature rise in the VHSC during the high pressure refueling process and revealed the hydrogen temperature rise during refueling. A hydrogen temperature rise prediction model was constructed to elucidate the relationship between filling parameters and temperature rise. The filling process of VHSC was analyzed from the theoretical method. The theoretical analysis results were consistent with the simulation and experimental analysis results which provided a theoretical basis for the current hydrogen temperature control algorithm of the gas source in the hydrogen refueling station and then reduced the energy consumption required for hydrogen cooling in the hydrogen refueling station.
A Comprehensive Resilience Assessment Framework for Hydrogen Energy Infrastructure Development
Jun 2023
Publication
In recent years sustainable development has become a challenge for many societies due to natural or other disruptive events which have disrupted economic environmental and energy infrastructure growth. Developing hydrogen energy infrastructure is crucial for sustainable development because of its numerous benefits over conventional energy sources. However the complexity of hydrogen energy infrastructure including production utilization and storage stages requires accounting for potential vulnerabilities. Therefore resilience needs to be considered along with sustainable development. This paper proposes a decision-making framework to evaluate the resilience of hydrogen energy infrastructure by integrating resilience indicators and sustainability contributing factors. A holistic taxonomy of resilience performance is first developed followed by a qualitative resilience assessment framework using a novel Intuitionistic fuzzy Weighted Influence Nonlinear Gauge System (IFWINGS). The results highlighted that Regulation and legislation Government preparation and Crisis response budget are the most critical resilience indicators in the understudy hydrogen energy infrastructure. A comparative case study demonstrates the practicality capability and effectiveness of the proposed approach. The results suggest that the proposed model can be used for resilience assessment in other areas.
The Effect of Explosions on the Protective Wall of a Containerized Hydrogen Fuel Cell System
Jun 2023
Publication
With the development of hydrogen energy containerized hydrogen fuel cell systems are being used in distributed energy-supply systems. Hydrogen pipelines and electronic equipment of fuel cell containers can trigger hydrogen-explosion accidents. In the present study Computational Fluid Dynamics (CFD) software was used to calculate the affected areas of hydrogen fuel cell container-explosion accidents with and without protective walls. The protective effects were studied for protective walls at various distances and heights. The results show that strategically placing protective walls can effectively block the propagation of shock waves and flames. However the protective wall has a limited effect on the reduction of overpressure and temperature behind the wall when the protective wall is insufficiently high. Reflected explosion shock waves and flames will cause damage to the area inside the wall when the protective wall is too close to the container. In this study a protective wall that is 5 m away from the container and 3 m high can effectively protect the area behind the wall and prevent damage to the container due to the reflection of shock waves and flame. This paper presents a suitable protective wall setting scheme for hydrogen fuel cell containers.
Linking Cost Decline and Demand Surge in the Hydrogen Market: A Case Study in China
Jun 2023
Publication
Hydrogen is crucial in achieving global energy transition and carbon neutrality goals. Existing market estimates typically presume linear or exponential growth but fail to consider how market demand responds to the declining cost of underlying technologies. To address this this study utilizes a learning curve model to project the cost of electrolyzers and its subsequent impact on hydrogen market aligning with a premise that the market demand is proportional to the cost of hydrogen. In a case study of China’s hydrogen market projecting from 2020 to 2060 we observed substantial differences in market evolution compared to exponential growth scenarios. Contrary to exponential growth scenarios China’s hydrogen market experiences faster growth during the 2020–2040 period rather than later. Such differences underscore the necessity for proactive strategic planning in emerging technology markets particularly for those experiencing rapid cost decline such as hydrogen. The framework can also be extended to other markets by using local data providing valuable insights to investors policymakers and developers engaged in the hydrogen market.
A Green Route for Hydrogen Producton from Alkaline Thermal Treatment (ATT) of Biomass with Carbon Storage
Apr 2023
Publication
Hydrogen a green energy carrier is one of the most promising energy sources. However,it is currently mainly produced from depleting fossil fuels with high carbon emissions which has serious negative effects on the economy and environment. To address this issue sustainable hydrogen production from bio-energy with carbon capture and storage (HyBECCS) is an ideal technology to reduce global carbon emissions while meeting energy demand. This review presents an overview of the latest progress in alkaline thermal treatment (ATT) of biomass for hydrogen production with carbon storage especially focusing on the technical characteristics and related challenges from an industrial application perspective. Additionally the roles of alkali and catalyst in the ATT process are critically discussed and several aspects that have great influences on the ATT process such as biomass types reaction parameters and reactors are expounded. Finally the potential solutions to the general challenges and obstacles to the future industrial-scale application of ATT of biomass for hydrogen production are proposed.
Life Cycle Assessment of Electric Vehicles and Hydrogen Fuel Cell Vehicles Using the GREET Model—A Comparative Study
Apr 2021
Publication
Facing global warming and recent bans on the use of diesel in vehicles there is a growing need to develop vehicles powered by renewable energy sources to mitigate greenhouse gas and pollutant emissions. Among the various forms of non-fossil energy for vehicles hydrogen fuel is emerging as a promising way to combat global warming. To date most studies on vehicle carbon emissions have focused on diesel and electric vehicles (EVs). Emission assessment methodologies are usually developed for fast-moving consumer goods (FMCG) which are non-durable household goods such as packaged foods beverages and toiletries instead of vehicle products. There is an increase in the number of articles addressing the product carbon footprint (PCF) of hydrogen fuel cell vehicles in the recent years while relatively little research focuses on both vehicle PCF and fuel cycle. Zero-emission vehicles initiative has also brought the importance of investigating the emission throughout the fuel cycle of hydrogen fuel cell and its environmental impact. To address these gaps this study uses the life-cycle assessment (LCA) process of GREET (greenhouse gases regulated emissions and energy use in transportation) to compare the PCF of an EV (Tesla Model 3) and a hydrogen fuel cell car (Toyota MIRAI). According to the GREET results the fuel cycle contributes significantly to the PCF of both vehicles. The findings also reveal the need for greater transparency in the disclosure of relevant information on the PCF methodology adopted by vehicle manufacturers to enable comparison of their vehicles’ emissions. Future work will include examining the best practices of PCF reporting for vehicles powered by renewable energy sources as well as examining the carbon footprints of hydrogen production technologies based on different methodologies.
Process Path for Reducing Carbon Emissions from Steel Industry—Combined Electrification and Hydrogen Reduction
Jan 2024
Publication
This review focuses on the energy structure of iron and steel production and a feasible development path for carbon reduction. The process path and feasible development direction of carbon emission reduction in the iron and steel industry have been analyzed from the perspective of the carbon–electricity–hydrogen ternary relationship. Frontier technologies such as “hydrogen replacing carbon” are being developed worldwide. Combining the high efficiency of microwave electric-thermal conversion with the high efficiency and pollution-free advantages of hydrogen-reducing agents may drive future developments. In this review a process path for “microwave + hydrogen” synergistic metallurgy is proposed. The reduction of magnetite powder by H2 (CO) in a microwave field versus in a conventional field is compared. The driving effect of the microwave field is found to be significant and the synergistic reduction effect of microwaves with H2 is far greater than that of CO.
Parametric Study and Optimization of Hydrogen Production Systems Based on Solar/Wind Hybrid Renewable Energies: A Case Study in Kuqa, China
Jan 2024
Publication
Based on the concept of sustainable development to promote the development and application of renewable energy and enhance the capacity of renewable energy consumption this paper studies the design and optimization of renewable energy hydrogen production systems. For this paper six different scenarios for grid-connected and off-grid renewable energy hydrogen production systems were designed and analyzed economically and technically and the optimal grid-connected and off-grid systems were selected. Subsequently the optimal system solution was optimized by analyzing the impact of the load data and component capacity on the grid dependency of the grid-connected hydrogen production system and the excess power rate of the off-grid hydrogen production system. Based on the simulation results the most matched load data and component capacity of different systems after optimization were determined. The grid-supplied power of the optimized grid-connected hydrogen production system decreased by 3347 kWh and the excess power rate of the off-grid hydrogen production system decreased from 38.6% to 10.3% resulting in a significant improvement in the technical and economic performance of the system.
Optimal Energy Management of an Integrated Energy System with Multiple Hydrogen Sources
Sep 2023
Publication
Hydrogen is considered a promising alternative to fossil fuels in an integrated energy system (IES). In order to reduce the cost of hydrogen energy utilization and the carbon emissions of the IES this paper proposes a low-carbon dispatching strategy for a coordinated integrated energy system using green hydrogen and blue hydrogen. The strategy takes into account the economic and low-carbon complementarity between hydrogen production by water electrolysis and hydrogen production from natural gas. It introduces the green hydrogen production–storage–use module (GH-PSUM) and the blue hydrogen production–storage–use module (BH-PSUM) to facilitate the refined utilization of different types of hydrogen energy. Additionally the flexibility in hydrogen load supply is analyzed and the dynamic response mechanism of the hydrogen load supply structure (DRM-HLSS) is proposed to further reduce operating costs and carbon emissions. Furthermore a carbon trading mechanism (CTM) is introduced to constrain the carbon emissions of the integrated energy system. By comprehensively considering the constraints of each equipment the proposed model aims to minimize the total economic cost which includes wind power operation and curtailment penalty costs energy purchase costs blue hydrogen purification costs and carbon transaction costs. The rationality of the established scheduling model is verified through a comparative analysis of the scheduling results across multiple operating scenarios.
An Experimental Investigation of Hydrogen Production through Biomass Electrolysis
Jan 2024
Publication
This work investigated hydrogen production from biomass feedstocks (i.e. glucose starch lignin and cellulose) using a 100 mL h-type proton exchange membrane electrolysis cell. Biomass electrolysis is a promising process for hydrogen production although low in technology readiness level but with a series of recognised advantages: (i) lower-temperature conditions (compared to thermochemical processes) (ii) minimal energy consumption and low-cost post-production (iii) potential to synthesise high-volume H2 and (iv) smaller carbon footprint compared to thermochemical processes. A Lewis acid (FeCl3 ) was employed as a charge carrier and redox medium to aid in the depolymerisation/oxidation of biomass components. A comprehensive analysis was conducted measuring the H2 and CO2 emission volume and performing electrochemical analysis (i.e. linear sweep voltammetry and chronoamperometry) to better understand the process. For the first time the influence of temperature on current density and H2 evolution was studied at temperatures ranging from ambient temperature (i.e. 19 ◦C) to 80 ◦C. The highest H2 volume was 12.1 mL which was produced by FeCl3 -mediated electrolysis of glucose at ambient temperature which was up to two times higher than starch lignin and cellulose at 1.20 V. Of the substrates examined glucose also showed a maximum power-to-H2 -yield ratio of 30.99 kWh/kg. The results showed that hydrogen can be produced from biomass feedstock at ambient temperature when a Lewis acid (FeCl3 ) is employed and with a higher yield rate and a lower electricity consumption compared to water electrolysis.
Research on Multi-market Strategies for Virtual Power Plants with Hydrogen Energy Storage
Oct 2023
Publication
As the main body of resource aggregation Virtual Power Plant (VPP) not only needs to participate in the external energy market but also needs to optimize the management of internal resources. Different from other energy storage hydrogen energy storage systems can participate in the hydrogen market in addition to assuming the backup supplementary function of electric energy. For the Virtual Power Plant Operator (VPPO) it needs to optimize the scheduling of internal resources and formulate bidding strategies for the electric-hydrogen market based on external market information. In this study a two-stage model is constructed considering the internal and external interaction mechanism. The first stage model optimizes the operation of renewable energy flexible load extraction storage and hydrogen energy storage system based on the complementary characteristics of internal resources; the second stage model optimizes the bidding strategy to maximize the total revenue of the electricity energy market auxiliary service market and hydrogen market. Finally a typical scenario is constructed and the rationality and effectiveness of the strategy are verified. The results show that the hybrid VPP with hydrogen storage has better economic benefits resource benefits and reliability.
Experimental Investigations of the Hydrogen Injectors on the Combustion Characteristics and Performance of a Hydrogen Internal Combustion Engine
Feb 2024
Publication
Hydrogen is regarded as an ideal zero-carbon fuel for an internal combustion engine. However the low mass flow rate of the hydrogen injector and the low volume heat value of the hydrogen strongly restrict the enhancement of the hydrogen engine performance. This experimental study compared the effects of single-injectors and double-injectors on the engine performance combustion pressure heat release rate and the coefficient of variation (CoVIMEP) based on a singlecylinder 0.5 L port fuel injection hydrogen engine. The results indicated that the number of hydrogen injectors significantly influences the engine performance. The maximum brake power is improved from 4.3 kW to 6.12 kW when adding the injector. The test demonstrates that the utilization of the double-injector leads to a reduction in hydrogen obstruction in the intake manifold consequently minimizing the pumping losses. The pump mean effective pressure decreased from −0.049 MPa in the single-injector condition to −0.029 MPa in the double-injector condition with the medium loads. Furthermore the double-injector exhibits excellent performance in reducing the coefficient of variation. The maximum CoVIMEP decreased from 2.18% in the single-injector configuration to 1.92% in the double-injector configuration. This result provides new insights for optimizing hydrogen engine injector design and optimizing the combustion process.
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