United Arab Emirates

On average the shipping sector is responsible for 3% of annual global green-house gas emissions on a CO2-equivalent basis. International shipping represents around 9% of the global emissions associated with the transport sector.<br/>This report from the International Renewable Energy Agency (IRENA) explores the impact of maritime shipping on CO2 emissions the structure of the shipping sector and key areas that need to be addressed to reduce the sector’s carbon footprint.<br/>There is no clear-cut path to decarbonisation. Cutting CO2 emissions in half is therefore likely to require a combination of approaches including the use of alternative fuels upgrading of onshore infrastructure and reducing fuel demand by improving operational performance the report finds.<br/>The shipping sector is strategically important for global efforts against climate change and could be crucial in the long-term shift to a zero-carbon economy. Large-scale deployment of low-carbon fuel infrastructure for shipping could also help to build the necessary momentum to decarbonise other sectors.

As the world strives to cut carbon emissions electric power from renewables has emerged as a vital energy source. Yet transport and industry will still require combustible fuels for many purposes. Such needs could be met with hydrogen which itself can be produced using renewable power.



Hydrogen provides high-grade heat helping to meet a range of energy needs that would be difficult to address through direct electrification. This could make hydrogen the missing link in the transformation of the global energy system.  



Key sectors for renewable-based hydrogen uptake include:  

• Industry where it could replace fossil-based feedstocks including natural gas in high-emission applications.
• Buildings and power where it could be mixed with natural gas or combined with industrial carbon dioxide (CO2) emissions to produce syngas.
• Transport where it can provide low-carbon mobility through fuel-cell electric vehicles.  

Electrolysers – which split hydrogen and oxygen – can make power systems more flexible helping to integrate high shares of variable renewables. Power consumption for electrolysis can be adjusted to follow actual solar and wind output while producing the hydrogen needed for transport industry or injection into the gas grid.  



In the long run hydrogen could become a key element in 100% renewable energy systems. With technologies maturing actual scale-up should yield major cost reductions. The right policy and regulatory framework however remains crucial to stimulate private investment in in hydrogen production in the first place.

Jordan's energy diversification strategy is centred around renewables which are expected will provide the low-cost reliable secure and environmentally sustainable energy required to power its new engines of economic growth – manufacturing transport construction and agriculture.

The National Energy Strategy 2020–2030 presents the evolution of the energy sector under its vision for stimulating demand achieving efficiency and improving electricity system flexibility.

This Renewables Readiness Assessment (RRA) highlights key actions for the short and medium-term that could create more conductive conditions for renewable energy development. It aims to help unlock Jordan's renewable energy potential and provide the means to meet the energy diversification goals of its national strategy.

The study was undertaken by the Ministry of Energy and Mineral Resources (MEMR) in collaboration with the International Renewable Energy Agency (IRENA).

Key recommendations:

• Provide the necessary conditions for renewables growth in the power sector.
• Foster continued growth of renewable power generation.
• Plan the integration of higher shares of renewable power.
• Incentivise the use of renewables for heating and cooling.
• Support renewable transport and mobility options.
• Catalyse renewable energy investment. Strengthen local industries and create jobs in renewables.

Hydrogen produced with renewable energy sources – or “green” hydrogen – has emerged as a key element to achieve net-zero emissions from heavy industry and transport. Along with net-zero commitments by growing numbers of governments green hydrogen has started gaining momentum based on low-cost renewable electricity ongoing technological improvements and the benefits of greater power-system flexibility.



Hydrogen-based fuels previously attracted interest mainly as an alternative to shore up oil supply. However green hydrogen as opposed to the “grey” (fossil-based) or “blue” (hybrid) varieties also help to boost renewables in the energy mix and decarbonise energy-intensive industries.



This report from the International Renewable Energy Agency (IRENA) outlines the main barriers that inhibiting green hydrogen uptake and the policies needed to address these. It also offers insights on how to kickstart the green hydrogen sector as a key enabler of the energy transition at the national or regional level.



Key pillars of green hydrogen policy making include:

• National hydrogen strategy. Each country needs to define its level of ambition for hydrogen outline the amount of support required and provide a reference on hydrogen development for private investment and finance.
• Setting policy priorities. Green hydrogen can support a wide range of end-uses. Policy makers should identify and focus on applications that provide the highest value.
• Guarantees of origin. Carbon emissions should be reflected over the whole lifecycle of hydrogen. Origin schemes need to include clear labels for hydrogen and hydrogen products to increase consumer awareness and facilitate claims of incentives.
• Governance system and enabling policies. As green hydrogen becomes mainstream policies should cover its integration into the broader energy system. Civil society and industry must be involved to maximise the benefits.
• Subsequent briefs will explore the entire hydrogen value chain providing sector-by-sector guidance on the design and implementation of green hydrogen policies.

Increased use of renewable energy combined with intensified electrification could prove decisive for the world to meet key climate goals by 2050. This study from the International Renewable Energy Agency (IRENA) highlights immediately deployable cost-effective options for countries to fulfil climate commitments and limit the rise of global temperatures. The envisaged energy transformation would also reduce net costs and bring significant socio-economic benefits such as increased economic growth job creation and overall welfare gains.<br/>The report – the second under the Global Energy Transformation banner – expands IRENA’s comprehensive roadmap which examines technology pathways and policy implications to ensure a sustainable energy future. Ramping up electricity to over half of the global energy mix (up from one-fifth currently) in combination with renewables would reduce the use of fossil fuels responsible for most greenhouse-gas emissions.

Heating and cooling accounts for almost half of global energy consumption. With most of this relying fossil fuels however it contributes heavily to greenhouse gas emissions and air pollution. In parts of the world lacking modern energy access meanwhile inefficient biomass use for cooking also harms people’s health damages the environment and reduces social well-being.



The transition to renewable-based energy-efficient heating and cooling could follow several possible pathways depending on energy demand resource availability and the needs and priorities of each country or region. Broad options include electrification with renewable power renewable-based gases (including “green” hydrogen) sustainable bioenergy use and the direct use of solar and geothermal heat.



This report developed jointly by the International Renewable Energy Agency (IRENA) the International Energy Agency (IEA) and the Renewable Energy Policy Network for the 21st Century (REN21) outlines the infrastructure and policies needed with each transition pathway. This edition focused on renewable-based heating and cooling follows a broader initial study Renewable Energy Policies in a Time of Transition (IRENA IEA and REN21 2018).



The shift to renewables for heating and cooling requires enabling infrastructure (e.g. gas grids district heating and cooling networks) as well as various combinations of deployment integrating and enabling policies. The policy framework can demonstrate a country’s commitment to the energy transition level the playing field with fossil fuels and create the necessary enabling conditions to attract investments.



Along with highlighting country experiences and best practices the study identifies barriers and highlights policy options for renewable heating and cooling.



Key recommendations include:

• Setting specific targets and developing an integrated long-term plan for the decarbonisation of heating and cooling in all end-uses including buildings industry and cooking and productive uses in areas with limited energy access.
• Creating a level playing field by phasing out fossil-fuel subsidies and introducing other fiscal policies to internalise environmental and socio-economic costs.
• Combining the electrification of heating and cooling with increasingly cost-competitive renewable power generation scaling up solar and wind use and boosting system flexibility via energy storage heat pumps and efficient electric appliances.
• Harnessing existing gas networks to accommodate renewable gases such as biogas and green hydrogen.
• Introducing standards certification and testing policies to promote the sustainable use of biomass combining efficient systems and bioenergy solutions such as pellets briquettes bioethanol or anaerobic digestion.
• Reducing investment risks for geothermal exploration and scaling up direct use of geothermal heat.
• Improving district heating and cooling networks through energy efficiency measures and the integration of low-temperature solar thermal geothermal and other renewable-based heat sources.
• Supporting clean cooking and introducing renewable-based food drying in areas lacking energy access with a combination of financing mechanisms capacity building and quality standards aimed at improving livelihoods and maximising socio-economic benefits.

Global demand for alternative renewable energy sources is increasing due to the consumption of fossil fuels and the increase in greenhouse gas emissions. Hydrogen (H2 ) from biomass gasification is a green energy segment among the alternative options as it is environmentally friendly renewable and sustainable. Accordingly researchers focus on conducting experiments and modeling the reforming reactions in conventional and membrane reactors. The construction of computational fluid dynamics (CFD) models is an essential tool used by researchers to study the performance of reforming and membrane reactors for hydrogen production and the effect of operating parameters on the methane stream improving processes for reforming untreated biogas in a catalyst-fixed bed and membrane reactors. This review article aims to provide a good CFD model overview of recent progress in catalyzing hydrogen production through various reactors sustainable steam reforming systems and carbon dioxide utilization. This article discusses some of the issues challenges and conceivable arrangements to aid the efficient generation of hydrogen from steam reforming catalytic reactions and membrane reactors of bioproducts and fossil fuels.

Rapid industrialization is consuming too much energy and non-renewable energy resources are currently supplying the world’s majority of energy requirements. As a result the global energy mix is being pushed towards renewable and sustainable energy sources by the world’s future energy plan and climate change. Thus hydrogen has been suggested as a potential energy source for sustainable development. Currently the production of hydrogen from fossil fuels is dominant in the world and its utilization is increasing daily. As discussed in the paper a large amount of hydrogen is used in rocket engines oil refining ammonia production and many other processes. This paper also analyzes the environmental impacts of hydrogen utilization in various applications such as iron and steel production rocket engines ammonia production and hydrogenation. It is predicted that all of our fossil fuels will run out soon if we continue to consume them at our current pace of consumption. Hydrogen is only ecologically friendly when it is produced from renewable energy. Therefore a transition towards hydrogen production from renewable energy resources such as solar geothermal and wind is necessary. However many things need to be achieved before we can transition from a fossil-fuel-driven economy to one based on renewable energy

The concerns regarding the consumption of traditional fuels such as oil and coal have driven the proposals for several cleaner alternatives in recent years. Hydrogen energy is one of the most attractive alternatives for the currently used fossil fuels with several superiorities such as zero-emission and high energy content. Hydrogen has numerous advantages compared to conventional fuels and as such has been employed in gas turbines (GTs) in recent years. The main benefit of using hydrogen in power generation with the GT is the considerably lower emission of greenhouse gases. The performance of the GTs using hydrogen as a fuel is influenced by several factors including the performance of the components the operating condition ambient condition etc. These factors have been investigated by several scholars and scientists in this field. In this article studies on hydrogen-fired GTs are reviewed and their results are discussed. Furthermore some recommendations are proposed for the upcoming works in this field.

This review critically evaluates the latest trends in fuel cell development for portable and stationary fuel cell applications and their integration into the automotive industry. Fast start-up high efficiency no toxic emissions into the atmosphere and good modularity are the key advantages of fuel cell applications. Despite the merits associated with fuel cells the high cost of the technology remains a key factor impeding its widespread commercialization. Therefore this review presents detailed information into the best operating conditions that yield maximum fuel cell performance. The paper recommends future research geared towards robust fuel cell geometry designs as this determines the cell losses and material characterization of the various cell components. When this is done properly it will support a total reduction in the cost of the cell which in effect will reduce the total cost of the system. Despite the strides made by the fuel cell research community there is a need for public sensitization as some people have reservations regarding the safety of the technology. This hurdle can be overcome if there is a well-documented risk assessment which also needs to be considered in future research activities.

Conventional fuels for vehicular applications generate hazardous pollutants which have an adverse effect on the environment. Therefore there is a high demand to shift towards environment-friendly vehicles for the present mobility sector. This paper highlights sustainable mobility and specifically sustainable transportation as a solution to reduce GHG emissions. Thus hydrogen fuel-based vehicular technologies have started blooming and have gained significance following the zero-emission policy focusing on various types of sustainable motilities and their limitations. Serving an incredible deliverance of energy by hydrogen fuel combustion engines hydrogen can revolution various transportation sectors. In this study the aspects of hydrogen as a fuel for sustainable mobility sectors have been investigated. In order to reduce the GHG (Green House Gas) emission from fossil fuel vehicles researchers have paid their focus for research and development on hydrogen fuel vehicles and proton exchange fuel cells. Also its development and progress in all mobility sectors in various countries have been scrutinized to measure the feasibility of sustainable mobility as a future. This paper is an inclusive review of hydrogen-based mobility in various sectors of transportation in particular fuel cell cars that provides information on various technologies adapted with time to add more towards perfection. When compared to electric vehicles with a 200-mile range fuel cell cars have a lower driving cost in all of the 2035 and 2050 scenarios. To stimulate the use of hydrogen as a passenger automobile fuel the cost of a hydrogen fuel cell vehicle (FCV) must be brought down to at least the same level as an electric vehicle. Compared to gasoline cars fuel cell vehicles use 43% less energy and generate 40% less CO2.

About 95% of the hydrogen presently produced is from natural gas and coal and the remaining 5% is generated as a by-product from the production of chlorine through electrolysis1 . In the hydrogen economy (Crabtree et al. 2004; Penner 2006; Marbán and Valdés-Solís 2007) hydrogen is produced entirely from renewable energy. The easiest approach to advance renewable energy production is through solar photovoltaic and electrolysis a pathway of high technology readiness level (TRL) suffering however from two downfalls. First of all electricity is already an energy carrier and transformation with a penalty into another energy carrier hydrogen is in principle flawed. The second problem is that the efficiency of commercial solar panels is relatively low. The cadmium telluride (CdTe) thin-film solar cells have a solar energy conversion efficiency of 17%. Production of hydrogen using the current best processes for water electrolysis has an efficiency of ∼70%. As here explained the concentrated solar energy may be used to produce hydrogen using thermochemical water-splitting cycles at much global higher efficiency (fuel energy to incident sun energy). This research and development (R&D) effort is therefore undertaken to increase the TRL of this approach as a viable and economical option.

In this paper we propose an optimization model that considers two pathways for injecting renewable content into natural gas pipeline networks. The pathways include (1) power-to-hydrogen or PtH where off-peak electricity is converted to hydrogen via electrolysis and (2) power-to-methane or PtM where carbon dioxide from different source locations is converted into renewable methane (also known as synthetic natural gas SNG). The above pathways result in green hydrogen and methane which can be injected into an existing natural gas pipeline network. Based on these pathways a multi-period network optimization model that integrates the design and operation of hydrogen from PtH and renewable methane is proposed. The multi-period model is a mixed-integer non-linear programming (MINLP) model that determines (1) the optimal concentration of hydrogen and carbon dioxide in the natural gas pipelines (2) the optimal location of PtH and carbon dioxide units while minimizing the overall system cost. We show using a case study in Ontario the optimal network structure for injecting renewable hydrogen and methane within an integrated natural gas network system provides a $12M cost reduction. The optimal concentration of hydrogen ranges from 0.2 vol % to a maximum limit of 15.1 vol % across the network while reaching a 2.5 vol % at the distribution point. This is well below the maximum limit of 5 vol % specification. Furthermore the optimizer realized a CO2 concentration ranging from 0.2 vol % to 0.7 vol %. This is well below the target of 1% specified in the model. The study is essential to understanding the practical implication of hydrogen penetration in natural gas systems in terms of constraints on hydrogen concentration and network system costs.

Recently with the large-scale integration of renewable energy sources into microgrid (µGs) power electronics distributed energy systems have gained popularity. However low inertia reduces system frequency stability and anti-disturbance capabilities exposing power quality to intermittency and uncertainty in photovoltaics or wind turbines. To ensure system stability the virtual inertia control (VIC) is presented. This paper proposes two solutions to overcome the low inertia problem and the surplus in capacities resulting from renewable energy sources. The first solution employs superconducting magnetic energy storage (SMES) which can be deemed as an efficient solution for damping the frequency oscillations. Therefore in this work SMES that is managed by a simple proportional-integral-derivative controller (PID) controller is utilized to overcome the low inertia. In the second solution the hydrogen storage system is employed to maintain the stability of the microgrid by storing surplus power generated by renewable energy sources (RESs). Power-to-Power is a method of storing excess renewable energy as chemical energy in the form of hydrogen. Hydrogen can be utilized locally or delivered to a consumption node. The proposed µG operation demonstrates that the integration of the photovoltaics (PVs) wind turbines (WTs) diesel engine generator (DEG) electrolyzer micro gas turbine (µGT) and SMES is adequate to fulfill the load requirements under transient operating circumstances such as a low and high PV output power as well as to adapt to sudden changes in the load demand. The effectiveness of the proposed schemes is confirmed using real irradiance data (Benban City Egypt) using a MATLAB/SIMULINK environment.

The rapid increase in anthropogenic greenhouse gas concentrations in the last several decades means that the effects of climate change are fast becoming the familiar horsemen of a planetary apocalypse. Catalysis one of the pillars of the chemical and petrochemical industries will play a critical role in the effort to reduce the flow of greenhouse gases into the atmosphere. This Special Issue is timely as it provides a collection of high-quality manuscripts in a diverse range of topics which include the production of green hydrogen via water electrolysis the steam reforming of ethanol propane or glycerol the dry reforming of methane and the autothermal reforming of diesel surrogate fuel. The topic of the transformation of biomass waste to chemicals is also well represented as is the tackling of CO₂ emissions via novel utilization technologies. The Editors are grateful to all authors for their valuable contributions and confident that this Special Issue will prove valuable to scholars university professors and students alike.

The world’s economy heavily depends on the energy resources used by various countries. India is one of the promising developing nations with very low crude reserves actively looking for new renewable energy resources to power its economy. Higher energy consumption and environmental pollution are two big global challenges for our sustainable development. The world is currently facing a dual problem of an energy crisis as well as environmental degradation. So there is a strong need to reduce our dependency on fossil fuels and greenhouse gas emissions. This can be achieved to a great extent by universally adopting clean fuels for all daily life uses like ethanol or liquified natural gas (LNG) as these burn very clean and do not emit many pollutants. Nowadays green hydrogen has emerged as a new clean energy source which is abundantly available and does not pollute much. This article explores the various benefits of green hydrogen with respect to fossil fuels various techniques of producing it and its possible use in different sectors such as industry transport and aviation as well as in day-to-day life. Finally it explores the use of green hydrogen as fuel in automobile engines its blending with CNG gas and its benefits in reducing emissions compared to fossil fuels. On combustion green hydrogen produces only water vapours and is thus a highly clean fuel. Thus it can potentially help humanity preserve the environment due to its ultra-low emissions and can be a consistent and reliable source of energy for generations to come thereby ending the clean energy security debate forever.

Demand for hydrogen has grown and continues to rise as a versatile energy carrier. Hydrogen can be produced from renewable and non-renewable energy sources. A wide range of technologies to produce hydrogen in an environmentally friendly way have been developed. As the life cycle assessment (LCA) approach has become popular recently including in the hydrogen energy system this paper comprehensively reviews the LCA of hydrogen production technology. A subdivision based on the trends in the LCA studies hydrogen production technology goal and scope definition system boundary and environmental performance of hydrogen production is discussed in this review. Thermochemical hydrogen production is the most studied technology in LCA. However utilizing natural resources especially wind power in the electrolysis process stands out as an environmentally preferable solution when compared to alternative production processes. It is crucial to rethink reactors and other production-related equipment to improve environmental performance and increase hydrogen production efficiency. Since most of the previous LCA studies were conducted in developed countries and only a few were from developing countries a way forward for LCA application on hydrogen in developing countries was also highlighted and discussed. This review provides a comprehensive insight for further research on hydrogen production technology from an LCA perspective.

Green hydrogen is considered to be one of the best candidates for fossil fuels in the near future. Bio-hydrogen production from the dark fermentation of organic materials including organic wastes is one of the most cost-effective and promising methods for hydrogen production. One of the main challenges posed by this method is the low production rate. Therefore optimizing the operating parameters such as the initial pH value operating temperature N/C ratio and organic concentration (xylose) plays a significant role in determining the hydrogen production rate. The experimental optimization of such parameters is complex expensive and lengthy. The present research used an experimental data asset adaptive network fuzzy inference system (ANFIS) modeling and particle swarm optimization to model and optimize hydrogen production. The coupling between ANFIS and PSO demonstrated a robust effect which was evident through the improvement in the hydrogen production based on the four input parameters. The results were compared with the experimental and RSM optimization models. The proposed method demonstrated an increase in the biohydrogen production of 100 mL/L compared to the experimental results and a 200 mL/L increase compared to the results obtained using ANOVA.

Technical economic and environmental assessments of projected power-to-gas (PtG) deployment scenarios at distributed- to national-scale are reviewed as well as their extensions to nuclear-assisted renewable hydrogen. Their collective research trends outcomes challenges and limitations are highlighted leading to suggested future work areas. These studies have focused on the conversion of excess wind and solar photovoltaic electricity in European-based energy systems using low-temperature electrolysis technologies. Synthetic natural gas either solely or with hydrogen has been the most frequent PtG product. However the spectrum of possible deployment scenarios has been incompletely explored to date in terms of geographical/sectorial application environment electricity generation technology and PtG processes products and their end-uses to meet a given energy system demand portfolio. Suggested areas of focus include PtG deployment scenarios: (i) incorporating concentrated solar- and/or hybrid renewable generation technologies; (ii) for energy systems facing high cooling and/or water desalination/treatment demands; (iii) employing high-temperature and/or hybrid hydrogen production processes; and (iv) involving PtG material/energy integrations with other installations/sectors. In terms of PtG deployment simulation suggested areas include the use of dynamic and load/utilization factor-dependent performance characteristics dynamic commodity prices more systematic comparisons between power-to-what potential deployment options and between product end-uses more holistic performance criteria and formal optimizations.

It is now well established that electrochemical systems can optimally perform only within a narrow range of temperature. Exposure to temperatures outside this range adversely affects the performance and lifetime of these systems. As a result thermal management is an essential consideration during the design and operation of electrochemical equipment and can heavily influence the success of electrochemical energy technologies. Recently significant attempts have been placed on the maturity of cooling technologies for electrochemical devices. Nonetheless the existing reviews on the subject have been primarily focused on battery cooling. Conversely heat transfer in other electrochemical systems commonly used for energy conversion and storage has not been subjected to critical reviews. To address this issue the current study gives an overview of the progress and challenges on the thermal management of different electrochemical energy devices including fuel cells electrolysers and supercapacitors. The physicochemical mechanisms of heat generation in these electrochemical devices are discussed in-depth. Physics of the heat transfer techniques currently employed for temperature control are then exposed and some directions for future studies are provided.

Significant research efforts are directed towards finding new ways to reduce the cost increase efficiency and decrease the environmental impact of power-generation systems. The poly-generation concept is a promising strategy that enables the development of a sustainable power system. Over the past few years the Proton Exchange Membrane Fuel Cell-based Poly-Generation Systems (PEMFC-PGSs) have received accelerated developments due to the low-temperature operation high efficiency and low environmental impact. This paper provides a comprehensive review of the main PEMFC-PGSs including Combined Heat and Power (CHP) co-generation systems Combined Cooling and Power (CCP) co-generation systems Combined Cooling Heat and Power (CCHP) tri-generation systems and Combined Water and Power (CWP) co-generation systems. First the main technologies used in PEMFC-PGSs such as those related to hydrogen production energy storage and Waste Heat Recovery (WHR) etc. are detailed. Then the research progresses on the economic energy and environmental performance of the different PEMFC-PGSs are presented. Also the recent commercialization activities on these systems are highlighted focusing on the leading countries in this field. Furthermore the remaining economic and technical obstacles of these systems along with the future research directions to mitigate them are discussed. The review reveals the potential of the PEMFC-PGS in securing a sustainable future of the power systems. However many economic and technical issues particularly those related to high cost and degradation rate still need to be addressed before unlocking the full benefits of such systems.

Rapidly declining costs of renewable energy technologies have made solar and wind the cheapest sources of energy in many parts of the world. This has been seen primarily as enabling the rapid decarbonization of the electricity sector but low-cost low-carbon energy can have a great secondary impact by reducing the costs of energy-intensive decarbonization efforts in other areas. In this study we consider by way of an exemplary carbon capture and utilization cycle based on mature technologies the energy requirements of the “industrial carbon cycle” an emerging paradigm in which industrial CO2 emissions are captured and reprocessed into chemicals and fuels and we assess the impact of declining renewable energy costs on overall economics of these processes. In our exemplary process CO2 is captured from a cement production facility via an amine scrubbing process and combined with hydrogen produced by a solar-powered polymer electrolyte membrane using electrolysis to produce methanol. We show that solar heat and electricity generation costs currently realized in the Middle East lead to a large reduction in the cost of this process relative to baseline assumptions found in published literature and extrapolation of current energy price trends into the near future would bring costs down to the level of current fossil-fuel-based processes.

Combined heat and power (CHP) in a single and integrated device is concurrent or synchronized production of many sources of usable power typically electric as well as thermal. Integrating combined heat and power systems in today’s energy market will address energy scarcity global warming as well as energy-saving problems. This review highlights the system design for fuel cell CHP technologies. Key among the components discussed was the type of fuel cell stack capable of generating the maximum performance of the entire system. The type of fuel processor used was also noted to influence the systemic performance coupled with its longevity. Other components equally discussed was the power electronics. The thermal and water management was also noted to have an effect on the overall efficiency of the system. Carbon dioxide emission reduction reduction of electricity cost and grid independence were some notable advantages associated with fueling cell combined heat and power systems. Despite these merits the high initial capital cost is a key factor impeding its commercialization. It is therefore imperative that future research activities are geared towards the development of novel and cheap materials for the development of the fuel cell which will transcend into a total reduction of the entire system. Similarly robust systemic designs should equally be an active research direction. Other types of fuel aside hydrogen should equally be explored. Proper risk assessment strategies and documentation will similarly expand and accelerate the commercialization of this novel technology. Finally public sensitization of the technology will also make its acceptance and possible competition with existing forms of energy generation feasible. The work in summary showed that proton exchange membrane fuel cell (PEM fuel cell) operated at a lower temperature-oriented cogeneration has good efficiency and is very reliable. The critical issue pertaining to these systems has to do with the complication associated with water treatment. This implies that the balance of the plant would be significantly affected; likewise the purity of the gas is crucial in the performance of the system. An alternative to these systems is the PEM fuel cell systems operated at higher temperatures.

With the growing demand for green technologies hydrogen energy devices such as Proton Exchange Membrane (PEM) fuel cells and water electrolysers have received accelerated developments. However the materials and manufacturing cost of these technologies are still relatively expensive which impedes their widespread commercialization. Additive Manufacturing (AM) commonly termed 3D Printing (3DP) with its advanced capabilities could be a potential pathway to solve the fabrication challenges of PEM parts. Herein in this paper the research studies on the novel AM fabrication methods of PEM components are thoroughly reviewed and analysed. The key performance properties such as corrosion and hydrogen embrittlement resistance of the additively manufactured materials in the PEM working environment are discussed to emphasise their reliability for the PEM systems. Additionally the major challenges and required future developments of AM technologies to unlock their full potential for PEM fabrication are identified. This paper provides insights from the latest research developments on the significance of advanced manufacturing technologies in developing sustainable energy systems to address the global energy challenges and climate change effects.

The commercialization of hydrogen as a fuel faces severe technological economic and environmental challenges. As a method to overcome these challenges microalgal biohydrogen production has become the subject of growing research interest. Microalgal biohydrogen can be produced through different metabolic routes the economic considerations of which are largely missing from recent reviews. Thus this review briefly explains the techniques and economics associated with enhancing microalgae-based biohydrogen production. The cost of producing biohydrogen has been estimated to be between $10 GJ-1 and $20 GJ−1 which is not competitive with gasoline ($0.33 GJ−1 ). Even though direct biophotolysis has a sunlight conversion efficiency of over 80% its productivity is sensitive to oxygen and sunlight availability. While the electrochemical processes produce the highest biohydrogen (>90%) fermentation and photobiological processes are more environmentally sustainable. Studies have revealed that the cost of producing biohydrogen is quite high ranging between $2.13 kg−1 and 7.24 kg−1 via direct biophotolysis $1.42kg−1 through indirect biophotolysis and between $7.54 kg−1 and 7.61 kg−1 via fermentation. Therefore low-cost hydrogen production technologies need to be developed to ensure long-term sustainability which requires the optimization of critical experimental parameters microalgal metabolic engineering and genetic modification.

The increase in the feasibility of hydrogen-based generation makes it a promising addition to the realm of renewable energies that are being employed to address the issue of electric vehicle charging. This paper presents technical and an economical approach to evaluate a newer off-grid hybrid PV-hydrogen energy-based recharging station in the city of Jamshoro Pakistan to meet the everyday charging needs of plug-in electric vehicles. The concept is designed and simulated by employing HOMER software. Hybrid PV-hydrogen and PV-hydrogenbattery are the two different scenarios that are carried out and compared based on their both technical as well as financial standpoints. The simulation results are evident that the hybrid PV- hydrogen-battery energy system has much more financial and economic benefits as compared with the PV-hydrogen energy system. Moreover it is also seen that costs of energy from earlier from hybrid PV-hydrogen-battery is more appealing i.e. 0.358 $/kWh from 0.412 $/kWh cost of energy from hybrid PV-hydrogen. The power produced by the hybrid PV- hydrogen - battery energy for the daily load demand of 1700 kWh /day consists of two powers produced independently by the PV and fuel cells of 87.4 % and 12.6 % respectively.

Hydrogen and methane as secondary fuels in diesel engines can be promising solutions to meet energy demand. The current study investigated the effect of the specialty gases of different compositions on diesel engine performance and exhaust gases. Four gases with various compositions of exhaust gas recirculation (Carbon monoxide Carbon dioxide and Nitrogen) and fuels (Hydrogen and Methane) were used at various mass flow rates of 10 20 and 25 LPM (liter per minute) and various engine speeds of 2000 2500 3000 and 3500 rpm (revolutions per minute). The procured results revealed that adding specialty gases improved brake thermal efficiency and power. Similarly the brake-specific fuel consumption was also massively retarded compared to diesel due to the influence of the hydrogen and methane composition. However the fuel with the higher nitrogen reported less BTE (brake thermal efficiency) and comparatively higher exhaust gas temperature owing to the higher presence of nitrogen in their composition. Regarding emissions including exhaust gas recirculation dropped the formation of pollutants efficiently compared to diesel. Among various fuels Case 1 (30 % H2 5 % CH4 5 CO2 and 60 % CO) reported the lowest emission of NOx and Case 2 (25 % H2 5 % CH4 5 CO2 30 % CO and 35 % N2) of CO and CO2 emissions. Generally specialty gases with a variable composition of exhaust gas recirculation gases can be a promising sustainable replacement for existing fossil fuels.