Production & Supply Chain
Enhancing Energy Recovery in Form of Biogas, from Vegetable and Fruit Wholesale Markets By-Products and Wastes, with Pretreatments
Jun 2021
Publication
Residues and by-products from vegetables and fruit wholesale markets are suitable for recovery in the form of energy through anaerobic digestion allowing waste recovery and introducing them into the circular economy. This suitability is due to their composition structural characteristics and to the biogas generation process which is stable and without inhibition. However it has been observed that the proportion of methane and the level of degradati Read More
Enhanced Hydrogen Generation Efficiency of Methanol using Dielectric Barrier Discharge Plasma Methodology and Conducting Sea Water as an Electrode
Aug 2020
Publication
In this work methanol decomposition method has been discussed for the production of hydrogen gas with the application of plasma. A simple dielectric barrier discharge (DBD) plasma reactor was designed for this purpose with two types of electrode. The DBD plasma reactor was experimented by substituting one of the metal electrodes with feebly conducting sea water which yielded better efficiency in producing hydrogen gas. Experimental parameters Read More
Optimization of Geothermal- and Solar-driven Clean Electricity and Hydrogen Production Multi-generation Systems to Address the Energy Nexus
Jan 2022
Publication
Given the limited sources of fossil fuels mankind should find new ways to meet its energy demands. In this regard geothermal and solar energy are acknowledged as reliable safe promising and clean means for this purpose. In this research study a comparative analysis is applied on geothermal and solar-driven multi-generation systems for clean electricity and hydrogen production through energy and exergy assessments. The system consists of an Read More
Scenario-Based Techno-Economic Analysis of Steam Methane Reforming Process for Hydrogen Production
Jun 2021
Publication
Steam methane reforming (SMR) process is regarded as a viable option to satisfy the growing demand for hydrogen mainly because of its capability for the mass production of hydrogen and the maturity of the technology. In this study an economically optimal process configuration of SMR is proposed by investigating six scenarios with different design and operating conditions including CO2 emission permits and CO2 capture and sale. Of the six sce Read More
Metal‐Supported Biochar Catalysts for Sustainable Biorefinery, Electrocatalysis and Energy Storage Applications: A Review
Feb 2022
Publication
Biochar (BCH) is a carbon‐based bio‐material produced from thermochemical conversion of biomass. Several activation or functionalization methods are usually used to improve physicochemical and functional properties of BCHs. In the context of green and sustainable future development activated and functionalized biochars with abundant surface functional groups and large surface area can act as effective catalysts or catalyst supports for che Read More
Hollow CdS-Based Photocatalysts
Oct 2020
Publication
In recent years photocatalytic technology driven by solar energy has been extensively investigated to ease energy crisis and environmental pollution. Nevertheless efficiency and stability of photocatalysts are still unsatisfactory. To address these issues design of advanced photocatalysts is important. Cadmium sulphide (CdS) nanomaterials are one of the promising photocatalysts. Among them hollow-structured CdS featured with enhanced light Read More
Simulation of a Multi-Functional Energy System for Cogeneration of Steam, Power and Hydrogen in a Coke Making Plant
Mar 2013
Publication
In this paper a multifunctional energy system (MES) is proposed for recovering energy from the extra of coke oven gas (COG) which is usually flared or vented out as a waste stream in coke making plants. The proposed system consists of a pressure swing adsorption (PSA) unit for extracting some of the hydrogen from COG a gas turbine for producing heat and power from PSA offgas and a heat recovery steam generator (HRSG) for generating the Read More
Sub-second and Ppm-level Optical Sensing of Hydrogen Using Templated Control of Nano-hydride Geometry and Composition
Apr 2021
Publication
The use of hydrogen as a clean and renewable alternative to fossil fuels requires a suite of flammability mitigating technologies particularly robust sensors for hydrogen leak detection and concentration monitoring. To this end we have developed a class of lightweight optical hydrogen sensors based on a metasurface of Pd nano-patchy particle arrays which fulfills the increasing requirements of a safe hydrogen fuel sensing system with no risk of sp Read More
Options for Producing Low-carbon Hydrogen at Scale
Feb 2018
Publication
Low-carbon hydrogen has the potential to play a significant role in tackling climate change and poor air quality. This policy briefing considers how hydrogen could be produced at a useful scale to power vehicles heat homes and supply industrial processes.Four groups of hydrogen production technologies are examined:Thermochemical Routes to HydrogenThese methods typically use heat and fossil fuels. Steam methane reforming is the dominant com Read More
Blue Hydrogen
Apr 2021
Publication
The urgency of reaching net-zero emissions requires a rapid acceleration in the deployment of all emissions reducing technologies. Near-zero emissions hydrogen (clean hydrogen) has the potential to make a significant contribution to emissions reduction in the power generation transportation and industrial sectors.As part of the Circular Carbon Economy: Keystone to Global Sustainability series with the Center on Global Energy Policy at Columbia Unive Read More
Editorial—Special Issue “Catalysis for Energy Production”
Jun 2021
Publication
The rapid increase in anthropogenic greenhouse gas concentrations in the last several decades means that the effects of climate change are fast becoming the familiar horsemen of a planetary apocalypse. Catalysis one of the pillars of the chemical and petrochemical industries will play a critical role in the effort to reduce the flow of greenhouse gases into the atmosphere. This Special Issue is timely as it provides a collection of high-quality manuscripts in a Read More
Australian Hydrogen Hubs Study
Nov 2019
Publication
Arup have conducted interviews with targeted industry and government stakeholders to gather data and perspectives to support the development of this study. Arup have also utilised private and publicly available data sources building on recent work undertaken by Geoscience Australia and Deloitte and the comprehensive stakeholder engagement process to inform our research. This study considers the supply chain and infrastructure requirements to Read More
A Solar Thermal Sorption-enhanced Steam Methane Reforming (SE-SMR) Approach and its Performance Assessment
Feb 2022
Publication
This paper proposes an integration of concentrating solar power (CSP) with a sorption-enhanced steam methane reforming (SE-SMR) process and assesses its overall solar-to-fuel conversion performance. A thermodynamic treatment of the SE-SMR process for H2 production is presented and evaluated in an innovative two reactors system configuration using CSP as a heat input. Four metal carbonate/metal oxide pairs are considered and the equilibriu Read More
Ex Situ Thermo-catalytic Upgrading of Biomass Pyrolysis Vapors Using a Traveling Wave Microwave Reactor
Sep 2016
Publication
Microwave heating offers a number of advantages over conventional heating methods such as rapid and volumetric heating precise temperature control energy efficiency and lower temperature gradient. In this article we demonstrate the use of 2450 MHz microwave traveling wave reactor to heat the catalyst bed for thermo-catalytic upgrading of pyrolysis vapors. HZSM-5 catalyst was tested at three different temperatures (290 330 and 370°C) at a cat Read More
Suspension Plasma Sprayed Coatings Using Dilute Hydrothermally Produced Titania Feedstocks for Photocatalytic Applications
May 2015
Publication
Titanium dioxide coatings have potential applications including photocatalysts for solar assisted hydrogen production solar water disinfection and self-cleaning windows. Herein we report the use of suspension plasma spraying (SPS) for the deposition of conformal titanium dioxide coatings. The process utilises a nanoparticle slurry of TiO2 (ca. 6 and 12 nm respectively) in water which is fed into a high temperature plasma jet (ca. 7000–20 000 K). This facilit Read More
Kinetic Parameters Estimation via Dragonfly Algorithm (DA) and Comparison of Cylindrical and Spherical Reactors Performance for CO2 Hydrogenation to Hydrocarbons
Oct 2020
Publication
Climate change and global warming as well as growing global demand for hydrocarbons in industrial sectors make great incentives to investigate the utilization of CO2 for hydrocarbons production. Therefore finding an in-depth understanding of the CO2 hydrogenation reactors along with simulating reactor responses to different operating conditions are of paramount importance. However the reaction mechanisms for CO2 hydrogenation and their cor Read More
Analysis of Hydrogen Production Potential from Waste Plastics by Pyrolysis and In Line Oxidative Steam Reforming
Oct 2021
Publication
A study was carried out on the valorization of different waste plastics (HDPE PP PS and PE) their mixtures and biomass/HDPE mixtures by means of pyrolysis and in line oxidative steam reforming. A thermodynamic equilibrium simulation was used for determining steam reforming data whereas previous experimental results were considered for setting the pyrolysis volatile stream composition. The adequacy of this simulation tool was validated usin Read More
Microwave Absorption of Aluminum/Hydrogen Treated Titanium Dioxide Nanoparticles
Dec 2018
Publication
Interactions between incident electromagnetic energy and matter are of critical importance for numerous civil and military applications such as photocatalysis solar cells optics radar detection communications information processing and transport et al. Traditional mechanisms for such interactions in the microwave frequency mainly rely on dipole rotations and magnetic domain resonance. In this study we present the first report of the microwa Read More
Dual Z-scheme Charge Transfer in TiO2–Ag–Cu2O Composite for Enhanced Photocatalytic Hydrogen Generation
Apr 2015
Publication
Photocatalytic hydrogen generation is one of the most promising solutions to convert solar power into green chemical energy. In this work a multi-component TiO2–Ag–Cu2O composite was obtained through simple impregnation-calcination of Cu2O and subsequent photodeposition of Ag onto electrospun TiO2 nanotubes. The resulting TiO2–Ag–Cu2O photocatalyst exhibits excellent photocatalytic H2 evolution activity due to the synergetic effect of Ag and Read More
Raw Biomass Electroreforming Coupled to Green Hydrogen Generation
Mar 2021
Publication
Despite the tremendous progress of coupling organic electrooxidation with hydrogen generation in a hybrid electrolysis electroreforming of raw biomass coupled to green hydrogen generation has not been reported yet due to the rigid polymeric structures of raw biomass. Herein we electrooxidize the most abundant natural amino biopolymer chitin to acetate with over 90% yield in hybrid electrolysis. The overall energy consumption of electrolysis can Read More
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