Production & Supply Chain
Chitosan Flocculation Associated with Biofilms of C. Saccharolyticus and C. Owensensis Enhances Biomass Retention in a CSTR
Jun 2021
Publication
Cell immobilization and co-culture techniques have gained attention due to its potential to obtain high volumetric hydrogen productivities (QH2). Chitosan retained biomass in the fermentation of co-cultures of Caldicellulosiruptor saccharolyticus and C. owensensis efficiently up to a maximum dilution rate (D) of 0.9 h−1. Without chitosan wash out of the co-culture occurred earlier accompanied with approximately 50% drop in QH2 (D > 0.4 h−1). However Read More
Cyclic Voltammetry of a Cobaloxime Catalyst
Jul 2019
Publication
Cyclic Voltammetry Measurements performed on a Cobaloxime Catalyst designed for photochemical hydrogen production.
Modelling and Optimization of a Flexible Hydrogen-fueled Pressurized PEMFC Power Plant for Grid Balancing Purposes
Feb 2021
Publication
In a scenario characterized by an increasing penetration of non-dispatchable renewable energy sources and the need of fast-ramping grid-balancing power plants the EU project GRASSHOPPER aims to setup and demonstrate a highly flexible PEMFC Power Plant hydrogen fueled and scalable to MW-size designed to provide grid support.In this work different layouts proposed for the innovative MW-scale plant are simulated to optimize design and off-design oper Read More
High-pressure Hydrogen Production with Inherent Sequestration of a Pure Carbon Dioxide Stream Via Fixed Bed Chemical Looping
Feb 2019
Publication
The proof of concept for the production of pure pressurized hydrogen from hydrocarbons in combination with the sequestration of a pure stream of carbon dioxide with the reformer steam iron cycle is presented. The iron oxide based oxygen carrier (95% Fe2O3 5% Al2O3) is reduced with syngas and oxidized with steam at 1023 K. The carbon dioxide separation is achieved via partial reduction of the oxygen carrier from Fe2O3 to Fe3O4 yielding thermodyna Read More
Synthesis and Characterisation of Platinum-cobalt-manganese Ternary Alloy Catalysts Supported on Carbon Nanofibers: An Alternative Catalyst for Hydrogen Evolution Reaction
Mar 2020
Publication
A systematic method for obtaining a novel electrode structure based on PtCoMn ternary alloy catalyst supported on graphitic carbon nanofibers (CNF) for hydrogen evolution reaction (HER) in acidic media is proposed. Ternary alloy nanoparticles (Co0.6Mn0.4 Pt) with a mean crystallite diameter under 10 nm were electrodeposited onto a graphitic support material using a two-step pulsed deposition technique. Initially a surface functionalisation of the ca Read More
Life-cycle Assessment of Hydrogen Technologies with the Focus on EU Critical Raw Materials and End-of-life Strategies
Aug 2020
Publication
We present the results of a life-cycle assessment (LCA) for the manufacturing and end-of-life (EoL) phases of the following fuel-cell and hydrogen (FCH) technologies: alkaline water electrolyser (AWE) polymer-electrolyte-membrane water electrolyser (PEMWE) high-temperature (HT) and low-temperature (LT) polymer-electrolyte-membrane fuel cells (PEMFCs) together with the balance-of-plant components. New life-cycle inventories (LCIs) i.e. material in Read More
Achievements of European Projects on Membrane Reactor for Hydrogen Production
May 2017
Publication
Membrane reactors for hydrogen production can increase both the hydrogen production efficiency at small scale and the electric efficiency in micro-cogeneration systems when coupled with Polymeric Electrolyte Membrane fuel cells. This paper discusses the achievements of three European projects (FERRET FluidCELL BIONICO) which investigate the application of the membrane reactor concept to hydrogen production and micro-cogeneration Read More
Thermal Efficiency of On-site, Small-scale Hydrogen Production Technologies using Liquid Hydrocarbon Fuels in Comparison to Electrolysis a Case Study in Norway
Oct 2018
Publication
The main goal of this study was to assess the energy efficiency of a small-scale on-site hydrogen production and dispensing plant for transport applications. The selected location was the city of Narvik in northern Norway where the hydrogen demand is expected to be 100 kg/day. The investigated technologies for on-site hydrogen generation starting from common liquid fossil fuels such as heavy naphtha and diesel were based on steam reforming and partia Read More
Magnetic Field Enhancement of Electrochemical Hydrogen Evolution Reaction Probed by Magneto-optics
Nov 2020
Publication
External magnetic fields affect various electrochemical processes and can be used to enhance the efficiency of the electrochemical water splitting reaction. However the driving forces behind this effect are poorly understood due to the analytical challenges of the available interface-sensitive techniques. Here we present a set-up based on magneto- and electro-optical probing which allows to juxtapose the magnetic properties of the electrode with the electr Read More
Opportunities and Challenges for Thermally Driven Hydrogen Production Using Reverse Electrodialysis System
Jul 2019
Publication
Ongoing and emerging renewable energy technologies mainly produce electric energy and intermittent power. As the energy economy relies on banking energy there is a rising need for chemically stored energy. We propose heat driven reverse electrodialysis (RED) technology with ammonium bicarbonate (AmB) as salt for producing hydrogen. The study provides the authors’ perspective on the commercial feasibility of AmB RED for low grade waste Read More
End of Life of Fuel Cells and Hydrogen Products: From Technologies to Strategies
Feb 2019
Publication
End-of-Life (EoL) technologies and strategies are needed to support the deployment of fuel cells and hydrogen (FCH) products. This article explores current and novel EoL technologies to recover valuable materials from the stacks of proton exchange membrane fuel cells and water electrolysers alkaline water electrolysers and solid oxide fuel cells. Current EoL technologies are mainly based on hydrometallurgical and pyro-hydrometallurgical methods for Read More
Integration of Gas Switching Combustion and Membrane Reactors for Exceeding 50% Efficiency in Flexible IGCC Plants with Near-zero CO2 Emissions
Jul 2020
Publication
Thermal power plants face substantial challenges to remain competitive in energy systems with high shares of variable renewables especially inflexible integrated gasification combined cycles (IGCC). This study addresses this challenge through the integration of Gas Switching Combustion (GSC) and Membrane Assisted Water Gas Shift (MAWGS) reactors in an IGCC plant for flexible electricity and/or H2 production with inherent CO2 capture. Wh Read More
Secure, Affordable, Low Carbon: Gas in our Future Energy System
Feb 2020
Publication
Our gas network is one of the best developed in the world providing safe secure affordable energy to homes and businesses across the UK.To meet the biggest energy challenge of our generation – making deep cuts to carbon emissions by 2050 – it needs to embrace new technology which builds on these strengths and delivers the integrated flexible network of the future. This briefing sets out how it is already doing that. Take a look at our Gas Future Read More
Pyrolysis-gasification of Wastes Plastics for Syngas Production Using Metal Modified Zeolite Catalysts Under Different Ratio of Nitrogen/Oxygen
Jun 2020
Publication
The aim of this study was the syngas production by the gasification of plastic waste (polyethylene polypropylene and terephthalate polyethylene). Ca Ce La Mg and Mn were used to promote the Ni/ZSM-5 catalyst in order to enhance the production of higher syngas yield. The modified catalysts can enhanced the reaction rate of the pyrolysis process and resulting in high syngas in the product yields. Especially cerium lanthanum promoted catalysts can enha Read More
The Global Status of CCS 2019: Targeting Climate Change
Dec 2019
Publication
CCS is an emissions reduction technology critical to meeting global climate targets. The Global Status of CCS 2019 documents important milestones for CCS over the past 12 months its status across the world and the key opportunities and challenges it faces. We hope this report will be read and used by governments policy-makers academics media commentators and the millions of people who care about our climate.
Hydrogen Production by Steam Reforming of Ethanol on Rh-Pt Catalysts: Influence of CeO2, ZrO2, and La2O3 as Supports
Nov 2015
Publication
CeO2- ZrO2- and La2O3-supported Rh-Pt catalysts were tested to assess their ability to catalyze the steam reforming of ethanol (SRE) for H2 production. SRE activity tests were performed using EtOH:H2O:N2 (molar ratio 1:3:51) at a gaseous space velocity of 70600 h−1 between 400 and 700 °C at atmospheric pressure. The SRE stability of the catalysts was tested at 700 °C for 27 h time on stream under the same conditions. RhPt/CeO2 which showed the Read More
Power-to-fuels Via Solid-oxide Electrolyzer: Operating Window and Techno-economics
May 2019
Publication
Power-to-fuel systems via solid-oxide electrolysis are promising for storing excess renewable electricity by efficient electrolysis of steam (or co-electrolysis of steam and CO2) into hydrogen (or syngas) which can be further converted into synthetic fuels with plant-wise thermal integration. Electrolysis stack performance and durability determine the system design performance and long-term operating strategy; thus solid-oxide electrolyzer based powe Read More
A Novel Self-Assembly Strategy for the Fabrication of Nano-Hybrid Satellite Materials with Plasmonically Enhanced Catalytic Activity
Jun 2021
Publication
The generation of hydrogen from water using light is currently one of the most promising alternative energy sources for humankind but faces significant barriers for large-scale applications due to the low efficiency of existing photo-catalysts. In this work we propose a new route to fabricate nano-hybrid materials able to deliver enhanced photo-catalytic hydrogen evolution combining within the same nanostructure a plasmonic antenna nanoparticl Read More
Hydrogen Production from Natural Gas and Biomethane with Carbon Capture and Storage – A Techno-environmental Analysis
Mar 2020
Publication
This study presents an integrated techno-environmental assessment of hydrogen production from natural gas and biomethane combined with CO2 capture and storage (CCS). We have included steam methane reforming (SMR) and autothermal reforming (ATR) for syngas production. CO2 is captured from the syngas with a novel vacuum pressure swing adsorption (VPSA) process that combines hydrogen purification and CO2 separation in one cycle. As c Read More
Low-carbon Hydrogen Via Integration of Steam Methane Reforming with Molten Carbonate Fuel Cells at Low Fuel Utilization
Feb 2021
Publication
Hydrogen production is critical to many modern chemical processes – ammonia synthesis petroleum refining direct reduction of iron and more. Conventional approaches to hydrogen manufacture include steam methane reforming and autothermal reforming which today account for the lion's share of hydrogen generation. Without CO2 capture these processes emit about 8.7 kg of CO2 for each kg of H2 produced. In this study a molten carbonate fuel cell Read More
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