Applications & Pathways
Society, Materials, and the Environment: The Case of Steel
Mar 2020
Publication
This paper reviews the relationship between the production of steel and the environment as it stands today. It deals with raw material issues (availability scarcity) energy resources and generation of by-products i.e. the circular economy the anthropogenic iron mine and the energy transition. The paper also deals with emissions to air (dust Particulate Matter heavy metals Persistant Organics Pollutants) water and soil i.e. with toxicity ecotoxicity epidemiology and health issues but also greenhouse gas emissions i.e. climate change. The loss of biodiversity is also mentioned. All these topics are analyzed with historical hindsight and the present understanding of their physics and chemistry is discussed stressing areas where knowledge is still lacking. In the face of all these issues technological solutions were sought to alleviate their effects: many areas are presently satisfactorily handled (the circular economy—a historical’ practice in the case of steel energy conservation air/water/soil emissions) and in line with present environmental regulations; on the other hand there are important hanging issues such as the generation of mine tailings (and tailings dam failures) the emissions of greenhouse gases (the steel industry plans to become carbon-neutral by 2050 at least in the EU) and the emission of fine PM which WHO correlates with premature deaths. Moreover present regulatory levels of emissions will necessarily become much stricter.
Computational Analysis of Liquid Hydrogen Storage Tanks for Aircraft Applications
Mar 2023
Publication
During the last two decades the use of hydrogen (H2 ) as fuel for aircraft applications has been drawing attention; more specifically its storage in liquid state (LH2 ) which is performed in extreme cryogenic temperatures (−253 ◦C) is a matter of research. The motivation for this effort is enhanced by the predicted growth of the aviation sector; however it is estimated that this growth could be sustainable only if the strategies and objectives set by global organizations for the elimination of greenhouse gas emissions during the next decades such as the European Green Deal are taken into consideration and consequently technologies such as hydrogen fuel are promoted. Regarding LH2 in aircraft substantial effort is required to design analyze and manufacture suitable tanks for efficient storage. Important tools in this process are computational methods provided by advanced engineering software (CAD/CAE). In the present work a computational study with the finite element method is performed in order to parametrically analyze proper tanks examining the effect of the LH2 level stored as well as the tank geometric configuration. In the process the need for powerful numerical models is demonstrated owing to the highly non-linear dependence on temperature of the involved materials. The present numerical models’ efficiency could be further enhanced by integrating them as part of a total aircraft configuration design loop.
Comprehensive Analysis of the Operation of an Internal Combustion Engine Fueled by Hydrogen-containing Mixtures
Mar 2023
Publication
At present hydrogen is considered as one of the most promising motor fuels capable of replacing traditional hydrocarbons. This article presents the results of a comprehensive experimental study of the effect of hydrogen additives on the main parameters of a gasoline spark-ignition ICE. The thermophysical parameters of the processes of ignition and combustion inside the cylinder with the addition of hydrogen in the amount of 0%–20% of the air volume as well as the fuel and energy characteristics of the engine and its impact on the environment were studied. It has been established that hydrogen leads to significant changes in the engine operation. It increases some parameters and reduces others improving or worsening them compared to running on pure gasoline. So with a 20% H2 addition at an average engine load the following parameters increase: the maximum pressure in the cylinder by almost 20%; the rate of pressure increase in the combustion chamber by 2.8 times; the highest combustion temperature by 140 K. At the same time the following parameters decrease: average indicator pressure by 18%; ignition timing by 82% (6◦ to TDC versus 34◦ for gasoline); crank angle corresponding to the maximum pressure by 32% (9.4◦ versus 13.9◦ for gasoline); crank angle corresponding to maximum temperature by 54% (17.7◦ after TDC versus 38.3◦ for clean gasoline); ignition delay time (τind = 0.32 ms) and visible combustion time (τvis = 1.58 ms) by 4 and 2.3 times respectively.
Overview of the Method and State of Hydrogenization of Road Transport in the World and the Resulting Development Prospects in Poland
Jan 2021
Publication
National Implementation Plans (NIP) in regard hydrogenation motor transport are in place in European Union (EU) countries e.g.Germany France or Belgium Denmark Netherlands. Motor transport hydrogenization plans exist in the Japan and USA. In Poland the methodology deployment Hydrogen Refuelling Stations (HRS) developed in Motor Transport Institute is of multi-stage character are as follows: Stage I: Method allowing to identify regions in which HRS should be located. Stage II: Method allowing to identify urban centres in which should be located the said stations. Stage III: Method for determining the area of the station location. The presentation of the aforesaid NIPS and based on that and the mentioned methodology the conditions for hydrogenization of motor transport in Poland is the purpose of this article which constitutes its novelty. The scope of the article concerns the hydrogenization of motor transport in the abovementioned countries. With the above criteria the order the construction in Poland of a HRS in the order of their creation along the TEN-T corridors is as follows: 1 - Poznan 2 - Warsaw 3 - Bialystok 4 - Szczecin 5 - the Lodz region 6 - the Tri-City region 7 - Wrocław 8 - the Katowice region 9 – Krakow. The concluding discussion sets out the status of deployment HRS and FCEVs in the analysed countries.
Hydrogenerally - Episode 8: Hydrogen for Combustion
Jan 2023
Publication
In this episode Steffan Eldred Hydrogen Knowledge Transfer Manager and Debra Jones Chemistry Knowledge Transfer Manager from Innovate UK KTN talk about hydrogen combustion with special guest Duncan Engeham European Research and Development Director at Cummins Inc.
The podcast can be found on their website.
The podcast can be found on their website.
Climate Action for the Shipping Industry: Some Perspectives on the Role of Nuclear Power in Maritime Decarbonization
Feb 2023
Publication
The shipping industry is a major enabler of globalization trade commerce and human welfare. But it is still heavily served by fossil fuels which make it one of the foremost greenhouse gas emitting sectors operational today. It is also one of the hardest to abate segments of the transport industry. As part of the economy-wide climate change mitigation and adaptation efforts it is necessary to consider a low carbon energy transition for this segment as well. This study examines the potential role of nuclear power and cogeneration towards greening this sector and identifies the associated techno-commercial and policy challenges associated with the transition. Quantitative estimates of the economics and investments associated with some of the possible routes are also presented. Alternatives such as nuclear-powered ships along commercial maritime trading routes ships working on nuclear derived green hydrogen ammonia or other sustainable power fuels will enable not only decarbonization of the shipping industry but also allow further diversification of the nuclear industry through non-electric applications of nuclear power and new sector coupling opportunities. In the run-up to the UNFCCC-COP28 meeting in 2023 in UAE nuclear equipped nations heavily engaged in and dependent on maritime trade and commerce should definitely consider nuclear driven decarbonization of shipping and some of the options presented here as part of their climate action strategies.
Prioritization and Optimal Location of Hydrogen Fueling Stations in Seoul: Using Multi-Standard Decision-Making and ILP Optimization
Mar 2023
Publication
Thus far the adoption of hydrogen fuel cell vehicles (HCEVs) has been hampered by the lack of hydrogen fueling infrastructure. This study aimed to determine the optimal location and prioritization of hydrogen fueling stations (HFSs) in Seoul by utilizing a multi-standard decision making approach and optimization method. HFS candidate sites were evaluated with respect to relevant laws and regulations. Key factors such as safety economy convenience and demand for HCEVs were considered. Data were obtained through a survey of experts in the fields of HCEV and fuel cells and the Analytic Hierarchy Process method was applied to prioritize candidate sites. The optimal quantity and placement of HFSs was then obtained using optimization software based on the acceptable travel time from intersections of popular roads in Seoul. Our findings suggest that compliance with legal safety regulations is the most important factor when constructing HFSs. Furthermore sensitivity analysis revealed that the hydrogen supply cost currently holds the same weight as other elements. The study highlights the importance of utilizing a multi-standard decision-making approach and optimization methods when determining the optimal location and prioritization of HFSs and can help develop a systematic plan for the nationwide construction of HFSs in South Korea.
Low Carbon Economic Dispatch of Integrated Energy Systems Considering Utilization of Hydrogen and Oxygen Energy
Mar 2024
Publication
Power-to-gas (P2G) facilities use surplus electricity to convert to natural gas in integrated energy systems (IES) increasing the capacity of wind power to be consumed. However the capacity limitation of P2G and the antipeaking characteristic of wind power make the wind abandonment problem still exist. Meanwhile the oxygen generated by P2G electrolysis is not fully utilized. Therefore this study proposes a low-carbon economic dispatch model considering the utilization of hydrogen and oxygen energy. First the two-stage reaction model of P2G is established and the energy utilization paths of hydrogen blending and oxygen-rich deep peaking are proposed. Specifically hydrogen energy is blended into the gas grid to supply gas-fired units and oxygen assists oxygenrich units into deep peaking. Subsequently the stochastic optimization is used to deal with the uncertainty of the system and the objective function and constraints of the IES are given to establish a low-carbon dispatch model under the energy utilization model. Finally the effectiveness of the proposed method is verified based on the modified IEEE 39-node electric network 20-node gas network and 6-node heat network models.
Low Carbon Optimal Operation of Integrated Energy System Based on Concentrating Solar Power Plant and Power to Hydrogen
Mar 2023
Publication
A new integrated energy system (IES) framework is created in order to encourage the consumption of renewable energy which is represented by wind and solar energy and lower carbon emissions. The connection between the units in the composite system is examined in this research. In-depth analysis is done on how energy is transferred between electricity heat gas and hydrogen. The system model and constraints are used to build an objective function with the lowest total operating cost. The calculation of carbon trading includes the ladder carbon trading method. And set up 6 cases for analysis which verifies the effectiveness of the participation of the concentrated solar power plant (CSPP) in the heat supply and power to hydrogen system (P2HS) in reducing the total operating cost of the system reducing wind curtailment and light curtailment and reducing carbon emissions. Under the model considered in this paper reduces the total operating cost reduces by 27.04% when the concentrated solar power plant is involved in the supply of thermal load. And the carbon emission is reduced by 14.529%. Compared with the traditional power to gas considers the power to hydrogen system in this paper which reduces the total operating cost by 4.79%.
Thermoacoustic Combustion Stability Analysis of a Bluff Body-Stabilized Burner Fueled by Methane–Air and Hydrogen–Air Mixtures
Apr 2023
Publication
Hydrogen can play a key role in the gradual transition towards a full decarbonization of the combustion sector e.g. in power generation. Despite the advantages related to the use of this carbon-free fuel there are still several challenging technical issues that must be addressed such as the thermoacoustic instability triggered by hydrogen. Given that burners are usually designed to work with methane or other fossil fuels it is important to investigate their thermoacoustic behavior when fueled by hydrogen. In this framework the present work aims to propose a methodology which combines Computational Fluid Dynamics CFD (3D Reynolds-Averaged Navier-Stokes (RANS)) and Finite Element Method (FEM) approaches in order to investigate the fluid dynamic and the thermoacoustic behavior introduced by hydrogen in a burner (a lab-scale bluff body stabilized burner) designed to work with methane. The case of CH4 -air mixture was used for the validation against experimental results and benchmark CFD data available in the literature. Numerical results obtained from CFD simulations namely thermofluidodynamic properties and flame characteristics (i.e. time delay and heat release rate) are used to evaluate the effects of the fuel change on the Flame Response Function to the acoustic perturbation by means of a FEM approach. As results in the H2 -air mixture case the time delay decreases and heat release rate increases with respect to the CH4 -air mixture. A study on the Rayleigh index was carried out in order to analyze the influence of H2 -air mixture on thermoacoustic instability of the burner. Finally an analysis of both frequency and growth rate (GR) on the first four modes was carried out by comparing the two mixtures. In the H2 -air case the modes are prone to become more unstable with respect to the same modes of the case fueled by CH4 -air due to the change in flame topology and variation of the heat release rate and time delay fields.
An Inter-laboratory Comparison between 13 International Laboratories for Eight Components Relevant for Hydrogen Fuel Quality Assessment
Mar 2024
Publication
The quality of the hydrogen delivered by refuelling stations is critical for end-users and society. The purity of the hydrogen dispensed at hydrogen refuelling points should comply with the technical specifications included in the ISO 14687:2019 and EN 17124:2022 standards. Once laboratories have set up methods they need to verify their performances for example through participation in interlaboratory comparisons. Due to the challenge associated with the production of stable reference materials and transport of these which are produced in hydrogen at high pressure (>10 bar) interlaboratory comparisons have been organized in different steps with increasing extent. This study describes an inter-laboratory comparison exercise for hydrogen fuel involving a large number of participants (13 laboratories) completed in less than a year and included eight key contaminants of hydrogen fuel at level close to the ISO14687 threshold. These compounds were selected based on their high probability of occurrence or because they have been found in hydrogen fuel samples. For the results of the intercomparison it appeared that fully complying with ISO 21087:2019 is still challenging for many participants and highlighted the importance of organising these types of exercises. Many laboratories performed corrective actions based on their results which in turn significantly improved their performances.
Techno-economic Study of Power-to-Power Renewable Energy Storage Based on the Smart Integration of Battery, Hydrogen, and Micro Gas Turbine Technologies
Mar 2023
Publication
This paper deals with the integration of a Power-to-Power Energy Storage System (P2P-ESS) based on a hydrogen driven micro gas turbine (mGT) for an off-grid application with a continuous demand of 30 kWe for three European cities: Palermo Frankfurt and Newcastle. In the first part of the analysis the results show that the latitude of the location is a very strong driver in determining the size of the system (hence footprint) and the amount of seasonal storage. The rated capacity of the PV plant and electrolyzer are 37%/41% and 58%/64% higher in Frankfurt and Newcastle respectively as compared to the original design for Palermo. And not only this but seasonal storage also increases largely from 3125 kg H2 to 5023 and 5920 kg H2 . As a consequence of this LCOE takes values of 0.86 e/kWh 1.26 e/kWh and 1.5 e/kWh for the three cities respectively whilst round-trip efficiency is approximately 15.7% for the three designs at the 3 cities. Finally with the aim to reduce the footprint and rating of the different systems a final assessment of the system hybridised with battery storage shows a 20% LCOE reduction and a 10% higher round-trip efficiency.
Seasonal Hydrogen Storage for Residential On- and Off-grid Solar Photovoltaics Prosumer Applications: Revolutionary Solution or Niche Market for the Energy Transition until 2050?
Apr 2023
Publication
Appropriate climate change mitigation requires solutions for all actors of the energy system. The residential sector is a major part of the energy system and solutions for the implementation of a seasonal hydrogen storage system in residential houses has been increasingly discussed. A global analysis of prosumer systems including seasonal hydrogen storage with water electrolyser hydrogen compressor storage tank and a fuel cell studying the role of such a seasonal household storage in the upcoming decades is not available. This study aims to close this research gap via the improved LUT-PROSUME model which models a fully micro sector coupled residential photovoltaic prosumer system with linear optimisation for 145 regions globally. The modelling of the cost development of hydrogen storage components allows for the simulation of a residential system from 2020 until 2050 in 5-year steps in hourly resolution. The systems are cost-optimised for either on– or off-grid operation in eight scenarios including battery electric vehicles which can act as an additional vehicle-to-home electricity storage for the system. Results show that implementation of seasonal hydrogen systems only occurs in least cost solutions in high latitude countries when the system is forced to run in off-grid mode. In general a solar photovoltaic plus battery system including technologies that can cover the heat demand is the most economic choice and can even achieve lower cost than a full grid supply in off-grid operation for most regions until 2050. Additional parameters including the self-consumption ratio the demand cover ratio and the heat cover ratio can therefore not be improved by seasonal storage systems if economics is the main deciding factor for a respective system. Further research opportunities and possible limitations of the system are then identified.
Regional Supply Chains for Decarbonising Steel: Energy Efficiency and Green Premium Mitigation
Jan 2022
Publication
Decarbonised steel enabled by green hydrogen-based iron ore reduction and renewable electricity-based steel making will disrupt the traditional supply chain. Focusing on the energetic and techno-economic assessment of potential green supply chains this study investigates the direct reduced iron-electric arc furnace production route enabled by renewable energy and deployed in regional settings. The hypothesis that co-locating manufacturing processes with renewable energy resources would offer highest energy efficiency and cost reduction is tested through an Australia-Japan case study. The binational partnership is structured to meet Japanese steel demand (for domestic use and regional exports) and source both energy and iron ore from the Pilbara region of Western Australia. A total of 12 unique supply chains differentiated by spatial configuration timeline and energy carrier were simulated which validated the hypothesis: direct energy and ore exports to remote steel producers (i.e. Japan-based production) as opposed to co-locating iron and steel production with abundant ore and renewable energy resources (i.e. Australia-based production) increased energy consumption and the levelised cost of steel by 45% and 32% respectively when averaged across 2030 and 2050. Two decades of technological development and economies of scale realisation would be crucial; 2030 supply chains were on average 12% more energy-intense and 23% more expensive than 2050 equivalents. On energy vectors liquefied hydrogen was more efficient than ammonia for export-dominant supply chains due to the pairing of its process flexibility and the intermittent solar energy profile as well as the avoidance of the need for ammonia cracking prior to direct reduction. To mitigate the green premium a carbon tax in the range of A$66–192/t CO2 would be required in 2030 and A$0–70/t CO2 in 2050; the diminished carbon tax requirement in the latter is achievable only by wholly Australia-based production. Further the modelled system scale was immense; producing 40 Mtpa of decarbonised steel will require 74–129% of Australia’s current electricity output and A$137–328 billion in capital investment for solar power production and shipping vessel infrastructure. These results call for strategic planning of regional resource pairing to drive energy and cost efficiencies which accelerate the global decarbonisation of steel.
Pre-cooling Systems for Hydrogen Fueling Stations: Techno-economic Analysis for Scaled Enactment
Mar 2023
Publication
Hydrogen fueling standards stipulates a sustainable cooling system technically and economically. Accordingly the interior surface temperature of the on-board H2 storage tank in fuel cell electric vehicles must not exceed the maximum specified limit (358.15 K) and the fueling rate must be ≤ 42.86 sec / kg-H2 with T40 dispenser at 70 MPa. In this context H2 refueling stations often employ double-tube and block heat exchangers for heat transfer. This study examines the H2 pre-cooling system for various loads and provides a comparative techno-economic analysis of double tube heat exchangers (DTHE) and microchannel heat exchangers (MCHE) under stipulated technical operational and outlet gas standards. For this purpose thermal and hydraulic performances were simulated using ANSYS-CFX. Technical and cost models utilize manufacturer specifications and literature-based technical and economic characteristics to derive the minimum sustainable price defined as the price to sustain the product. The results showed that the MCHE outperformed the DTHE for setups in mass manufacturing improved effective heat transfer area and predicted long term unit cost. The annual quantitative output affects manufacturing expenses and profit margins substantially. With high production rates it is expected that the unit cost of the MCHE will decrease by up to 74%. In switching from DTHE to MCHE general material requirements decreased by ~60% with scrap waste savings of ~45% reflecting an appreciable footprint reduction.
Everything About Hydrogen Podcast: Highway to the Hydrogen Zone
May 2020
Publication
On this weeks episode the team discuss hydrogen for aviation with ZeroAvia. Val launched ZeroAvia to provide a genuinely zero emission flight proposition with two aircraft currently undergoing trials in California and the UK. The company is due to complete a 300 mile flight of its six seater aircraft from the Orkney islands to the Scottish mainland this summer 2020 with plans for twenty seat planes flying regional routes as early as 20205. On the show we discuss why Val set up ZeroAvia how the proposition stacks up against conventional alternatives infrastructure and plans for the future. All this and more on the show!
The podcast can be found on their website
The podcast can be found on their website
Energy Management Control Strategy for Saving Trip Costs of Fuel Cell/Battery Electric Vehicles
Mar 2022
Publication
Fuel cell vehicles (FCVs) should control the energy management between two energy sources for fuel economy using the stored energy in a battery or generation of energy through a fuel cell system. The fuel economy for an FCV includes trip costs for hydrogen consumption and the lifetime of two energy sources. This paper proposes an implementable energy management control strategy for an FCV to reduce trip costs. The concept of the proposed control strategy is first to analyze the allowable current of a fuel cell system from the optimal strategies for various initial battery state of charge (SOC) conditions using dynamic programming (DP) and second to find a modulation ratio determining the current of a fuel cell system for driving a vehicle using the particle swarm optimization method. The control strategy presents the on/off moment of a fuel cell system and the proper modulation ratio of the turned-on fuel cell system with respect to the battery SOC and the power demand. The proposed strategy reduces trip costs in real-time similar to the DP-based optimal strategy and more than the simple energy control strategy of switching a fuel cell system on/off at the battery SOC boundary conditions even for long-term driving cycles.
Electric Mobility in Portugal: Current Situation and Forecasts for Fuel Cell Vehicles
Nov 2021
Publication
In recent years the growing concern for air quality has led to the development of sustainable vehicles to replace conventional internal combustion engine (ICE) vehicles. Currently the most widespread technology in Europe and Portugal is that of Battery Electric Vehicles (BEV) or plug‐in HEV (PHEV) electric cars but hydrogen‐based transport has also shown significant growth in the commercialization of Fuel Cell Electric Vehicles (FCEV) and in the development of new infrastructural schemes. In the current panorama of EV particular attention should be paid to hydrogen technology i.e. FCEVs which is potentially a valid alternative to BEVs and can also be hybrid (FCHEV) and plug‐in hybrid (FCPHEV). Several sources cited show a positive trend of hydrogen in the transport sector identifying a growing trend in the expansion of hydrogen infrastructure although at this time it is still at an early stage of development. At the moment the cost of building the infrastructure is still high but on the basis of medium/long‐term scenarios it is clear that investments in hydrogen refueling stations will be profitable if the number of Fuel Cell vehicles increases. Conversely the Fuel Cell vehicle market is hampered if there is no adequate infrastructure for hydrogen development. The opportunity to use Fuel Cells to store electrical energy is quite fascinating and bypasses some obstacles encountered with BEVs. The advantages are clear since the charging times are reduced compared to charging from an electric charging post and the long‐distance voyage is made easier as the autonomy is much larger i.e. the psycho‐ sociological anxiety is avoided. Therefore the first part of the paper provides an overview of the current state of electric mobility in Portugal and the strategies adopted by the country. This is necessary to have a clear vision of how a new technology is accepted by the population and develops on the territory that is the propensity of citizens to technological change. Subsequently using current data on EV development and comparing information from recent years this work aims to investigate the future prospects of FCEVs in Portugal by adopting a dynamic model called SERA (Scenario Evaluation and Regionalization Analysis) with which it is possible to identify the Portuguese districts and cities where an FC charging infrastructure is expected to be most beneficial. From the results obtained the districts of Lisbon Porto and Aveiro seem to be the most interested in adopting FC technology. This analysis aims to ensure a measured view of the credible development of this market segment.
Climate Impact Reduction Potentials of Synthetic Kerosene and Green Hydrogen Powered Mid-Range Aircraft Concepts
Jun 2022
Publication
One of aviation’s major challenges for the upcoming decades is the reduction in its climate impact. As synthetic kerosene and green hydrogen are two promising candidates their potentials in decreasing the climate impact is investigated for the mid-range segment. Evolutionary advancements for 2040 are applied first with an conventional and second with an advanced low-NOx and low-soot combustion chamber. Experts and methods from all relevant disciplines are involved starting from combustion turbofan engine overall aircraft design fleet level and climate impact assessment allowing a sophisticated and holistic evaluation. The main takeaway is that both energy carriers have the potential to strongly reduce the fleet level climate impact by more than 75% compared with the reference. Applying a flight-level constraint of 290 and a cruise Mach number of 0.75 causing 5% higher average Direct Operating Costs (DOC) the reduction is even more than 85%. The main levers to achieve this are the advanced combustion chamber an efficient contrail avoidance strategy in this case a pure flight-level constraint and the use of CO2 neutral energy carrier in a descending priority order. Although vehicle efficiency gains only lead to rather low impact reduction they are very important to compensate the increased costs of synthetic fuels or green hydrogen.
Everything About Hydrogen Podcast: FCEV's "Down Under"
Dec 2020
Publication
On today's show the EAH team will be joined by Brendan Norman to talk about deployment of sustainable FCEV technologies across many different segments of the transport sector and utility vehicles. Brendan is the CEO of H2X a new vehicle manufacturing company based in Sydney with a manufacturing facility in Port Kembla will deliver its first hydrogen FCEVs to market beginning in 2022 before expanding its vehicle offerings in subsequent years. Brendan joined the EAH team via SquadCast from Kuala Lumpur to talk fuel cells with us and you don't want to miss the excellent discussion that we had on this week's episode.
The podcast can be found on their website
The podcast can be found on their website
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