Applications & Pathways
A Review of Current Advances in Ammonia Combustion from the Fundamentals to Applications in Internal Combustion Engines
Aug 2023
Publication
The energy transition from hydrocarbon-based energy sources to renewable and carbon-free energy sources such as wind solar and hydrogen is facing increasing demands. The decarbonization of global transportation could come true via applying carbon-free fuel such as ammonia especially for internal combustion engines (ICEs). Although ammonia has advantages of high hydrogen content high octane number and safety in storage it is uninflammable with low laminar burning velocity thus limiting its direct usage in ICEs. The purpose of this review paper is to provide previous studies and current research on the current technical advances emerging in assisted combustion of ammonia. The limitation of ammonia utilization in ICEs such as large minimum ignition energy lower flame speed and more NOx emission with unburned NH3 could be solved by oxygen-enriched combustion ammonia–hydrogen mixed combustion and plasma-assisted combustion (PAC). In dual-fuel or oxygen-enriched NH3 combustion accelerated flame propagation speeds are driven by abundant radicals such as H and OH; however NOx emission should be paid special attention. Furthermore dissociating NH3 in situ hydrogen by non-noble metal catalysts or plasma has the potential to replace dual-fuel systems. PAC is able to change classical ignition and extinction S-curves to monotonic stretching which makes low-temperature ignition possible while leading moderate NOx emissions. In this review the underlying fundamental mechanism under these technologies are introduced in detail providing new insight into overcoming the bottleneck of applying ammonia in ICEs. Finally the feasibility of ammonia processing as an ICE power source for transport and usage highlights it as an appealing choice for the link between carbon-free energy and power demand.
Assessing the Feasibility of Hydrogen and Electric Buses for Urban Public Transportation using Rooftop Integrated Photovoltaic Energy in Cuenca Ecuador
Jul 2023
Publication
A main restriction of renewables from intermittent sources is the mismatch between energy resource availability and energy requirements especially when extensive power plants are producing at their highest potential causing huge energy surpluses. In these cases excess power must be stored or curtailed. One alternative is increasing urban solar potential which could be integrated to feed electric buses directly or alternatively through hydrogen (H2 ) as an energy vector. H2 from renewable electricity can be stored and used directly or through fuel cells. This study aims to determine the H2 capability that could be achieved when integrating large-scale photovoltaic (PV) generation in urban areas. This analysis was carried out by determining the PV energy potentially generated by installing PV in Cuenca City downtown (Ecuador). Cuenca is in the process of adopting renewal of the public transport vehicle fleet introducing a new model with an electric tram main network combined with “clean type buses”. The conventional diesel urban transport could be replaced establishing a required vehicle fleet of 475 buses spread over 29 routes emitting 112 tons of CO2 and burning 11175 gallons of diesel daily. Between the main findings we concluded that the electricity that could be produced in the total roof area exceeds the actual demand in the study area by 5.5 times. Taking into account the energy surplus it was determined that the available PV power will cover from 97% to 127% of the total demand necessary to mobilize the city bus fleet. The novelty of this work is the proposal of a combined methodology to find the potential to feed urban transport with urban solar power in cities close to the equatorial line.
Energy Management Strategy Based on Reinforcement Learning and Frequency Decoupling for Fuel Cell Hybrid Powertrain
Apr 2024
Publication
This study presents a Two-Layer Deep Deterministic Policy Gradient (TL-DDPG) energy management strategy for Hydrogen fuel cell hybrid train that aims to solve the problem that traditional reinforcement learning strategies require high initial values and are difficult to optimize global variables. Augmenting the optimization capabilities of the inner layer a frequency decoupling algorithm integrates into the outer layer furnishing a fitting initial value for strategy optimization. This addition aims to bolster the stability of fuel cell output thereby enhancing the overall efficiency of the hybrid power system. In comparison with the traditional reinforcement learning algorithm the proposed approach demonstrates notable improvements: a reduction in hydrogen consumption per 100 km by 16.3 kg a 9.7% increase in the output power stability of the fuel cell and a 1.8% enhancement in its efficiency.
The Role of Electricity-based Hydrogen in the Emerging Power-to-X Economy
Aug 2023
Publication
As energy system research into high shares of renewables has developed so have the perspectives of the fundamental nature of a highly renewable economy. Early energy system transition research suggested that current fossil fuel energy systems would transition to a ‘Hydrogen Economy’ whereas more recent insights suggest that a ‘Power-to-X Economy’ may be a more appropriate term as renewable electricity will become both the most important primary and final energy carrier through various Power-to-X conversion routes across the energy system. This paper provides a detailed overview on research insights of recent years on the core elements of the Power-to-X Economy and the role of hydrogen based on latest research results. These results suggest that by 2050 upwards of 61737 TWhLHV of hydrogen will be required to fully defossilise the global energy-industry system. Hydrogen therefore emerges as a central intermediate energy carrier and its relevance is driven by significant cost reductions in renewable electricity especially of solar photovoltaics and wind power. Efficiency and cost drivers position direct electrification as the primary solution for defossilisation of the global energy-industry system; however electron-to-molecule routes are essential for the large subset of remaining energy-related demands including chemical production marine and aviation fuels and steelmaking.
The Status of On-Board Hydrogen Storage in Fuel Cell Electric Vehicles
Aug 2023
Publication
Hydrogen as an energy carrier could help decarbonize industrial building and transportation sectors and be used in fuel cells to generate electricity power or heat. One of the numerous ways to solve the climate crisis is to make the vehicles on our roads as clean as possible. Fuel cell electric vehicles (FCEVs) have demonstrated a high potential in storing and converting chemical energy into electricity with zero carbon dioxide emissions. This review paper comprehensively assesses hydrogen’s potential as an innovative alternative for reducing greenhouse gas (GHG) emissions in transportation particularly for on-board applications. To evaluate the industry’s current status and future challenges the work analyses the technology behind FCEVs and hydrogen storage approaches for on-board applications followed by a market review. It has been found that to achieve long-range autonomy (over 500 km) FCEVs must be capable of storing 5–10 kg of hydrogen in compressed vessels at 700 bar with Type IV vessels being the primary option in use. Carbon fiber is the most expensive component in vessel manufacturing contributing to over 50% of the total cost. However the cost of FCEV storage systems has considerably decreased with current estimates around 15.7 $/kWh and is predicted to drop to 8 $/kWh by 2030. In 2021 Toyota Hyundai Mercedes-Benz and Honda were the major car brands offering FCEV technology globally. Although physical and chemical storage technologies are expected to be valuable to the hydrogen economy compressed hydrogen storage remains the most advanced technology for on-board applications.
Work Efficiency and Economic Efficiency of Actual Driving Test of Proton Exchange Membrane Fuel Cell Forklift
Aug 2023
Publication
A 3.5 tonne forklift containing proton exchange membrane fuel cells (PEMFCs) and lithium-ion batteries was manufactured and tested in a real factory. The work efficiency and economic applicability of the PEMFC forklift were compared with that of a lithium-ion battery-powered forklift. The results showed that the back-pressure of air was closely related to the power density of the stack whose stability could be improved by a reasonable control strategy and membrane electrode assemblies (MEAs) with high consistency. The PEMFC powered forklift displayed 40.6% higher work efficiency than the lithium-ion battery-powered forklift. Its lower use-cost compared to internal engine-powered forklifts is beneficial to the commercialization of this product.
Feasibility Assessment of Alternative Clean Power Systems onboard Passenger Short-Distance Ferry
Sep 2023
Publication
In order to promote low-carbon fuels such as hydrogen to decarbonize the maritime sector it is crucial to promote clean fuels and zero-emission propulsion systems in demonstrative projects and to showcase innovative technologies such as fuel cells in vessels operating in local public transport that could increase general audience acceptability thanks to their showcase potential. In this study a short sea journey ferry used in the port of Genova as a public transport vehicle is analyzed to evaluate a ”zero emission propulsion” retrofitting process. In the paper different types of solutions (batteries proton exchange membrane fuel cell (PEMFC) solid oxide fuel cell (SOFC)) and fuels (hydrogen ammonia natural gas and methanol) are investigated to identify the most feasible technology to be implemented onboard according to different aspects: ferry daily journey and scheduling available volumes and spaces propulsion power needs energy storage/fuel tank capacity needed economics etc. The paper presents a multi-aspect analysis that resulted in the identification of the hydrogen-powered PEMFC as the best clean power system to guarantee for this specific case study a suitable retrofitting of the vessel that could guarantee a zero-emission journey
Comparing Alternative Pathways for the Future Role of the Gas Grid in a Low-carbon Heating System
Aug 2023
Publication
This paper uses a whole-system approach to examine different strategies related to the future role of the gas grid in a low-carbon heat system. A novel model of integrated gas electricity and heat systems HEGIT is used to investigate four key sets of scenarios for the future of the gas grid using the UK as a case study: (a) complete electrification of heating; (b) conversion of the existing gas grid to deliver hydrogen; (c) a hybrid heat pump system; and (d) a greener gas grid. Our results indicate that although the infrastructure requirements the fuel or resource mix and the breakdown of costs vary significantly over the complete electrification to complete conversion of the gas grid to hydrogen spectrum the total system transition cost is relatively similar. This reduces the significance of total system cost as a guiding factor in policy decisions on the future of the gas grid. Furthermore we show that determining the roles of low-carbon gases and electrification for decarbonising heating is better guided by the trade-offs between short- and long-term energy security risks in the system as well as trade-offs between consumer investment in fuel switching and infrastructure requirements for decarbonising heating. Our analysis of these trade-offs indicates that although electrification of heating using heat pumps is not the cheapest option to decarbonise heat it has clear co-benefits as it reduces fuel security risks and dependency on carbon capture and storage infrastructure. Combining different strategies such as grid integration of heat pumps with increased thermal storage capacity and installing hybrid heat pumps with gas boilers on the consumer side are demonstrated to effectively moderate the infrastructure requirements consumer costs and reliability risks of widespread electrification. Further reducing demand on the electricity grid can be accomplished by complementary options at the system level such as partial carbon offsetting using negative emission technologies and partially converting the gas grid to hydrogen.
Modelling and Operation Strategy Approaches for On-site Hydrogen Refuelling Stations
Aug 2023
Publication
The number of Fuel Cell Electric Vehicles (FCEVs) in circulation has undergone a significant increase in recent years. This trend is foreseen to be stronger in the near future. In correlation with the FCEVs market increase the hydrogen delivery infrastructure must be developed. With this aim many countries have announced ambitious projects. For example Spain has the objective of increasing the number of Hydrogen Refuelling Stations (HRS) with public access from three units in operation currently to about 150 by 2030. HRSs are complex systems with high variability in terms of layout design size of components operational strategy hydrogen generation method or hydrogen generation location. This paper is focused on on-site HRS with electrolysis-based hydrogen production which provides interesting advantages when renewable energy is utilized compared to off-site hydrogen production despite their complexity. To optimize HRS design and operation a simulation model must be implemented. This paper describes a generic on-site HRS with electrolysis-based hydrogen production a cascaded multi-tank storage system with multiple compressors renewable energy sources and multiple types of dispensing formats. A modelling approach of the layout is presented and tested with real-based parameters of an HRS currently under development which is capable of producing 11.34 kg/h of green H2 with irradiation at 1000 W/m2. For the operation an operational strategy is proposed. The modelled system is tested through several simulations. A sensitivity analysis of the effects of hydrogen demand and day-ahead hydrogen production objective on emissions demand satisfaction and variable costs is performed. Simulation results show how the operational strategy has achieved service up to 310 FCEVs refuelling events of heavy duty and light duty FCEVs bringing the total H2 sold up to almost 7200 H2kg in one month of winter. Additionally considering variable costs of the energy from the utility grid the model shows a profit in the range of 21–50 k€ for a daily demand of 60 H2kg/day and 100 H2kg/day respectively. In terms of emissions a year simulation with 60 H2kg/day of demand shows specific emissions in the production of H2 in Spain of 6.26 kgCO2eq/H2kg which represents a greenhouse gas emission intensity of 52.26 kgCO2eq/H2MJ.
Transitioning towards Net-Zero Emissions in Chemical and Process Industries: A Holistic Perspective
Sep 2023
Publication
Given the urgency to combat climate change and ensure environmental sustainability this review examines the transition to net-zero emissions in chemical and process industries. It addresses the core areas of carbon emissions reduction efficient energy use and sustainable practices. What is new however is that it focuses on cutting-edge technologies such as biomass utilization biotechnology applications and waste management strategies that are key drivers of this transition. In particular the study addresses the unique challenges faced by industries such as cement manufacturing and highlights the need for innovative solutions to effectively reduce their carbon footprint. In particular the role of hydrogen as a clean fuel is at the heart of revolutionizing the chemical and process sectors pointing the way to cleaner and greener operations. In addition the manuscript explores the immense importance of the European Green Deal and the Sustainable Development Goals (SDGs) for the chemical industry. These initiatives provide a clear roadmap and framework for advancing sustainability driving innovation and reducing the industry’s environmental impact and are a notable contribution to the existing body of knowledge. Ultimately alignment with the European Green Deal and the SDGs can bring numerous benefits to the chemical industry increasing its competitiveness promoting societal well-being and supporting cross-sector collaboration to achieve shared sustainability goals. By highlighting the novelty of integrating cutting-edge technologies addressing unique industrial challenges and positioning global initiatives this report offers valuable insights to guide the chemical and process industries on their transformative path to a sustainable future.
Carbon Footprint of Hydrogen-powered Inland Shipping: Impacts and Hotspots
Aug 2023
Publication
The shipping sector is facing increasing pressure to implement clean fuels and drivetrains. Especially hydrogen fuel cell drivetrains seem attractive. Although several studies have been conducted to assess the carbon footprint of hydrogen and its application in ships their results remain hard to interpret and compare. Namely it is necessary to include a variety of drivetrain solutions and different studies are based on various assumptions and are expressed in other units. This paper addresses this problem by offering a three-step meta-review of life cycle assessment studies. First a literature review was conducted. Second results from the literature were harmonized to make the different analyses comparable serving cross-examination. The entire life cycle of both the fuels and drivetrains were included. The results showed that the dominant impact was fuel use and related fuel production. And finally life-cycle hot spots have been identified by looking at the effect of specific configurations in more detail. Hydrogen production by electrolysis powered by wind has the most negligible impact. For this ultra-low carbon pathway the modes of hydrogen transport and the use of specific materials and components become relevant.
A Comparative Environmental Life Cycle Assessment Study of Hydrogen Fuel Electricity and Diesel Fuel for Public Buses
Aug 2023
Publication
Hydrogen fuel and electricity are energy carriers viewed as promising alternatives for the modernization and decarbonization of public bus transportation fleets. In order to choose development pathways that will lead transportation systems toward a sustainable future the authors developed an environmental model based on the Life Cycle Assessment approach. The model tested the impact of energy carrier consumption during driving as well as the electricity origin employed to power electric buses and produce hydrogen. Energy sources such as wind solar waste and grid electricity were investigated. The scope of the study included the life cycles of the energy carrier and the necessary infrastructure. The results were presented from two perspectives: the total environmental impact and global warming potential. In order to create a roadmap an original method for choosing sustainable development pathways was prepared. It was shown that the modernization of conventional bus fleets using hydrogen and electrical pathways can provide significant environmental benefits from both perspectives but especially in terms of global warming potential. It was emphasized that attention should be paid to the use of low- and zero-emission energy sources because their impact often strongly influenced the final environmental judgment. The energy carrier consumption also had a strong impact on the results obtained and that is why efforts should be made to reduce it. In addition it was confirmed that hydrogen and electricity production systems based on electricity generated by a waste-to-energy plant could be an environmentally reasonable dual solution for both sustainable waste management and meeting transport needs.
Industrial Development Status and Prospects of the Marine Fuel Cell: A Review
Jan 2023
Publication
In the context of the increasingly strict pollutant emission regulations and carbon emission reduction targets proposed by the International Maritime Organization the shipping industry is seeking new types of marine power plants with the advantages of high efficiency and low emissions. Among the possible alternatives the fuel cell is considered to be the most practical technology as it provides an efficient means to generate electricity with low pollutant emissions and carbon emissions. Very few comprehensive reviews focus on the maritime applications of the fuel cell. Thus news reports and literature on the maritime applications of the fuel cell in the past sixty years were collected and the industrial development status and prospects of the marine fuel cell were summarized as follows. Some countries in Europe North America and Asia have invested heavily in researching and developing the marine fuel cell and a series of research projects have achieved concrete results such as the industrialized marine fuel cell system or practical demonstration applications. At present the worldwide research of the marine fuel cell focuses more on the proton exchange membrane fuel cell (PEMFC). However the power demand of the marine fuel cell in the future will show steady growth and thus the solid oxide fuel cell (SOFC) with the advantages of higher power and fuel diversity will be the mainstream in the next research stage. Although some challenges exist the SOFC can certainly lead the upgrading and updating of the marine power system with the cooperative efforts of the whole world.
Comprehensive Techno-economic Assessment of Power Technologies and Synthetic Fuels under Discussion for Ship Applications
Jun 2023
Publication
The decarbonization of the global ship traffic is one of the industry’s greatest challenges for the next decades and will likely only be achieved with the introduction of synthetic fuels. Until now however not one single best technology solution emerged to ideally fit this task. Instead different energy carriers including hydrogen ammonia methanol methane and synthetic diesel are subject of discussion for usage in either internal combustion engines or fuel cells. In order to drive the selection procedure a case study for the year 2030 with all eligible combinations of power technologies and fuels is conducted. The assessment quantifies the technologies’ economic performances for cost-optimized system designs and in dependence of a ship’s mission characteristics. Thereby the influence of trends for electrofuel prices and shipboard volume opportunity costs are examined. Even if gaseous hydrogen is often considered not suitable for large ship applications due to its low volumetric energy density both the comparatively small fuel price and the high efficiency of fuel cells lead to the overall smallest system costs for passages up to 21 days depending on assumed cost parameters. Only for missions longer than seven days fuel cells operating on methanol or ammonia can compete with gaseous hydrogen economically.
Techno-economic Assessment on Hybrid Energy Storage Systems Comprising Hydrogen and Batteries: A Case Study in Belgium
Jun 2023
Publication
This paper introduces a Techno-Economic Assessment (TEA) on present and future scenarios of different energy storage technologies comprising hydrogen and batteries: Battery Energy Storage System (BESS) Hydrogen Energy Storage System (H2ESS) and Hybrid Energy Storage System (HESS). These three configurations were assessed for different time horizons: 2019 2022 and 2030 under both on-grid and off-grid conditions. For 2030 a sensitivity analysis under different energy scenarios was performed covering other trends in on-grid electric consumption and prices CO2 taxation and the evolution of hydrogen technology prices from 2019 until 2030. The selected case study is the Research Park Zellik (RPZ) a CO2- neutral sustainable Local Energy Community (LEC) in Zellik Belgium. The software HOMER (Hybrid Optimisation Model for Electric Renewable) has been selected to design model and optimise the defined case study. The results showed that BESS was the most competitive when the electric grid was available among the three possible storage options. Additionally HESS was overall more competitive than H2ESS-only regardless of the grid connection mode. Finally as per HESS hydrogen was proved to play a complementary role when combined with batteries enhancing the flexibility of the microgrid and enabling deeper decarbonisation by reducing the electricity bought from the grid increasing renewable energy production and balancing toward an island operating mode.
Strategic Transport Fleet Analysis of Heavy Goods Vehicle Technology for Net-zero Targets
Jul 2022
Publication
This paper addresses the decarbonisation of the heavy-duty transport sector and develops a strategy towards net-zero greenhouse gas (GHG) emissions in heavy-goods vehicles (HGVs) by 2040. By conducting a literature review and a case study on the vehicle fleet of a large UK food and consumer goods retailer the feasibilities of four alternative vehicle technologies are evaluated from environmental economic and technical perspectives. Socio-political factors and commercial readiness are also examined to capture non-technical criteria that influences decision-makers. Strategic analysis frameworks such as PEST-SWOT models were developed for liquefied natural gas biomethane electricity and hydrogen to allow a holistic comparison and identify their long-term deployment potential. Technology innovation is needed to address range and payload limitations of electric trucks whereas government and industry support are essential for a material deployment of hydrogen in the 2030s. Given the UK government’s plan to phase out new diesel HGVs by 2040 fleet operators should commence new vehicle trials by 2025 and replace a considerable amount of their lighter diesel trucks with zero-emission vehicles by 2030 and the remaining heavier truck fleet by 2035.
Numerical Simulation on Pressure Dynamic Response Characteristics of Hydrogen Systems for Fuel Cell Vehicles
Mar 2022
Publication
A proton exchange membrane fuel cell (PEMFC) is known as one of the most promising energy sources for electric vehicles. A hydrogen system is required to provide hydrogen to the stack in time to meet the flow and pressure requirements according to the power requirements. In this study a 1-D model of a hydrogen system including the fuel cell stack was established. Two modes one with and one without a proportion integration differentiation (PID) control strategy were applied to analyze the pressure characteristics and performance of the PEMFC. The results showed that the established model could be well verified with experimental data. The anode pressure fluctuation with a PID control strategy was more stable which reduced the damage to the fuel cell stack caused by sudden changes of anode pressure. In addition the performance of the stack with the PID control mode was slightly improved. There was an inflection point for hydrogen utilization; the hydrogen utilization rate was higher under the mode without PID control when the current density was greater than 0.4 A/cm2 . What is more a hierarchical control strategy was proposed which made the pressure difference between the anode and cathode meet the stack working requirements and more importantly maintained the high hydrogen utilization of the hydrogen system.
Hydrogen Technology for Supply Chain Sustainability: The Mexican Transportation Impacts on Society
Mar 2022
Publication
This study sheds light on the Hydrogen technology in transportation for reaching the sustainability goals of societies illustrated by the case of Mexico. In terms of the affected supply chains the study explores how the packaging and distribution of a fuel-saving tool that allows the adoption of hydrogen as complementary energy for maritime transportation to improve economic and environmental performance in Mexico. This exploratory study performs interviews observations simulations and tests involving producers suppliers and users at 26 ports in Mexico. The study shows that environmental and economic performance are related to key processes in Supply Chain Management (SCM) in which packaging and distribution are critical for achieving logistics and transportation sustainability goals. Reusable packaging and the distribution of a fuel-saving tool can help decrease costs - of transport and downstream/upstream processes in SCM while at the same time increasing the environmental performance.
Synergistic Value in Vertically Integrated Power-to-Gas Energy Systems
Oct 2019
Publication
In vertically integrated energy systems integration frequently entails operational gains that must be traded off against the requisite cost of capacity investments. In the context of the model analyzed in this study the operational gains are subject to inherent volatility in both the price and the output of the intermediate product transferred within the vertically integrated structure. Our model framework provides necessary and sufficient conditions for the value (NPV) of an integrated system to exceed the sum of two optimized subsystems on their own. We then calibrate the model in Germany and Texas for systems that combine wind energy with Power-to-Gas (PtG) facilities that produce hydrogen. Depending on the prices for hydrogen in different market segments we find that a synergistic investment value emerges in some settings. In the context of Texas for instance neither electricity generation from wind power nor hydrogen production from PtG is profitable on its own in the current market environment. Yet provided both subsystems are sized optimally in relative terms the attendant operational gains from vertical integration more than compensate for the stand-alone losses of the two subsystems.
Everything About Hydrogen Podcast: Using Hydrogen to Decarbonise Steel Manufacturing
Mar 2022
Publication
Hydrogen could be used in many hard-to-decarbonize sectors. Foremost amongst them is the steel manufacturing industry. On this episode of EAH we speak with Dr. Martin Pei Executive Vice President and CTO of SSAB and the first Chairman of the Board for Hybrit Development AB. SSAB is a global steel company with a leading position in high-strength steels and related services. Together with their partners LKAB and Vattenfall SSAB are making a unique joint effort to change the Swedish iron and steel industry fundamentally. With HYBRIT technology SSAB aims to be the first steel company in the world to bring fossil-free steel to the market already in 2026 and largely eliminate carbon dioxide emissions from the company's own operations as soon as 2030.
The podcast can be found on their website.
The podcast can be found on their website.
Optimal Configuration of Multi-Energy Storage in an Electric–Thermal–Hydrogen Integrated Energy System Considering Extreme Disaster Scenarios
Mar 2024
Publication
Extreme disasters have become increasingly common in recent years and pose significant dangers to the integrated energy system’s secure and dependable energy supply. As a vital part of an integrated energy system the energy storage system can help with emergency rescue and recovery during major disasters. In addition it can improve energy utilization rates and regulate fluctuations in renewable energy under normal conditions. In this study the sizing scheme of multienergy storage equipment in the electric–thermal–hydrogen integrated energy system is optimized; economic optimization in the regular operating scenario and resilience enhancement in extreme disaster scenarios are also considered. A refined model of multi-energy storage is constructed and a two-layer capacity configuration optimization model is proposed. This model is further enhanced by the integration of a Markov two-state fault transmission model which simulates equipment defects and improves system resilience. The optimization process is solved using the tabu chaotic quantum particle swarm optimization (TCQPSO) algorithm to provide reliable and accurate optimization results. The results indicate that addressing severe disaster situations in a capacity configuration fully leverages the reserve energy function of energy storage and enhances system resilience while maintaining economic efficiency; furthermore adjusting the load loss penalty coefficients offers a more targeted approach to the balancing of the system economy and resilience. Thus new algorithmic choices and planning strategies for future research on enhancing the resilience of integrated energy systems under extreme disaster scenarios are provided.
Design and Implementation of an Intelligent Energy Management System for Smart Home Utilizing a Multi-agent System
Jul 2022
Publication
Green Hydrogen Microgrid System has been selected as a source of clean and renewable alternative energy because it is undergoing a global revolution and has been identified as a source of clean energy that may aid the country in achieving net-zero emissions in the coming years. The study proposes an innovative Microgrid Renewable hybrid system to achieve these targets. The proposed hybrid renewable energy system combines a photovoltaic generator (PVG) a fuel cell (FC) a supercapacitor (SC) and a home vehicle power supply (V2H) to provide energy for a predefined demand. The proposed architecture is connected to the grid and is highly dependent on solar energy during peak periods. During the night or shading period it uses FC as a backup power source. The SC assists the FC with high charge power. SC performs this way during load transients or quick load changes. A multi-agent system (MAS) was used to build a real energy management system (RT-HEMS) for intelligent coordination between components (MAS). The scheduling algorithm reduces energy consumption by managing the required automation devices without the need for additional network power. It will meet household energy requirements regardless of weather conditions including bright cloudy or rainy conditions. Implementation and discussion of the RT-HEMS ensures that the GHS is functioning properly and that the charge request is satisfied.
Fuel Cell Electrical Vehicles as Mobile Coupled Heat and Power Backup-Plant in Neighbourhoods
Apr 2022
Publication
Fuel cell electric vehicles (FCEVs) can be used during idle times to convert hydrogen into electricity in a decentralised manner thus ensuring a completely renewable energy supply. In addition to the electric power waste heat is generated in the fuel cell stack that can also be used. This paper investigates how the energy demand of a compiled German neighbourhood can be met by FCEVs and identifies potential technical problems. For this purpose energy scenarios are modelled in the Open Energy System Modelling Framework (oemof). An optimisation simulation finds the most energetically favourable solution for the 10-day period under consideration. Up to 49% of the heat demand for heating and hot water can be covered directly by the waste heat of the FCEVs. As the number of battery electric vehicles (BEVs) to be charged increases so does this share. 5 of the 252 residents must permanently provide an FCEV to supply the neighbourhood. The amount of hydrogen required was identified as a problem. If the vehicles cannot be supplied with hydrogen in a stationary way 15 times more vehicles are needed than required in terms of performance due to the energy demand.
Intelligent Hydrogen Fuel Cell Range Extender for Battery Electric Vehicles
May 2019
Publication
Road transport is recognized as having a negative impact on the environment. Policy has focused on replacement of the internal combustion engine (ICE) with less polluting forms of technology including battery electric and fuel cell electric powertrains. However progress is slow and both battery and fuel cell based vehicles face considerable commercialization challenges. To understand these challenges a review of current electric battery and fuel cell electric technologies is presented. Based on this review this paper proposes a battery electric vehicle (BEV) where components are sized to take into account the majority of user requirements with the remainder catered for by a trailer-based demountable intelligent fuel cell range extender. The proposed design can extend the range by more than 50% for small BEVs and 25% for large BEVs (the extended range of vehicles over 250 miles) reducing cost and increasing efficiency for the BEV. It enables BEV manufacturers to design their vehicle battery for the most common journeys decreases charging time to provide convenience and flexibility to the drivers. Adopting a rent and drop business model reduces the demand on the raw materials bridging the gap in the amount of charging (refueling) stations and extending the lifespan for the battery pack.
Fuel Cell Cars in a Microgrid for Synergies Between Hydrogen and Electricity Networks
Nov 2016
Publication
Fuel cell electric vehicles convert chemical energy of hydrogen into electricity to power their motor. Since cars are used for transport only during a small part of the time energy stored in the on-board hydrogen tanks of fuel cell vehicles can be used to provide power when cars are parked. In this paper we present a community microgrid with photovoltaic systems wind turbines and fuel cell electric vehicles that are used to provide vehicle-to-grid power when renewable power generation is scarce. Excess renewable power generation is used to produce hydrogen which is stored in a refilling station. A central control system is designed to operate the system in such a way that the operational costs are minimized. To this end a hybrid model for the system is derived in which both the characteristics of the fuel cell vehicles and their traveling schedules are considered. The operational costs of the system are formulated considering the presence of uncertainty in the prediction of the load and renewable energy generation. A robust minmax model predictive control scheme is developed and finally a case study illustrates the performance of the designed system.
Fuel Cell Electric Vehicle as a Power Plant and SOFC as a Natural Gas Reformer: An Exergy Analysis of Different System Designs
Apr 2016
Publication
Delft University of Technology under its ‘‘Green Village” programme has an initiative to build a power plant (car parking lot) based on the fuel cells used in vehicles for motive power. It is a trigeneration system capable of producing electricity heat and hydrogen. It comprises three main zones: a hydrogen production zone a parking zone and a pump station zone. This study focuses mainly on the hydrogen production zone which assesses four different system designs in two different operation modes of the facility: Car as Power Plant (CaPP) mode corresponding to the open period of the facility which uses fuel cell electric vehicles (FCEVs) as energy and water producers while parked; and Pump mode corresponding to the closed period which compresses the hydrogen and pumps to the vehicle’s fuel tank. These system designs differ by the reforming technology: the existing catalytic reformer (CR) and a solid oxide fuel cell operating as reformer (SOFCR); and the option of integrating a carbon capture and storage (CCS). Results reveal that the SOFCR unit significantly reduces the exergy destruction resulting in an improvement of efficiency over 20% in SOFCR-based system designs compared to CR-based system designs in both operation modes. It also mitigates the reduction in system efficiency by integration of a CCS unit achieving a value of 2% whereas in CR-based systems is 7–8%. The SOFCR-based system running in Pump mode achieves a trigeneration efficiency of 60%.
Potentialities of Hydrogen Enriched Natural Gas for Residential Heating Decarbonization and Impact Analysis on Premixed Boilers
Sep 2019
Publication
Nowadays decarbonization of energy economy is a topical theme and several pathways are under discussion. Gaseous fuels will play a primary role during this transition and the production of renewable or low carbon-impact gaseous fuels is necessary to deal with this challenge. Decarbonization will be sustained by an increasing share of renewables which production intermittency can be critical for the energy system. Renewable hydrogen generation is a viable solution since this energy vector can be produced from electricity with a fast response and injected in the existing natural gas infrastructures granting storage capacity and easy transport. Parallelly to the renewable-based energy production fossil-based energy can be exploited with a low carbon impact using methane from reservoirs to produce hydrogen capturing CO2. The mentioned scenarios will lead to hydrogen enrichment of natural gas which impact on the infrastructures is being actively studied. The effect on end-user devices instead is poorly analysed but is fundamental to be assessed. This paper highlights the impact on the widely used premixed condensing boilers which will be fired with hydrogen enriched natural gas in the near future and the changes required to components.
Economic Evaluation of Renewable Hydrogen Integration into Steelworks for the Production of Methanol and Methane
Jun 2022
Publication
This work investigates the cost-efficient integration of renewable hydrogen into steelworks for the production of methane and methanol as an efficient way to decarbonize the steel industry. Three case studies that utilize a mixture of steelworks off-gases (blast furnace gas coke oven gas and basic oxygen furnace gas) which differ on the amount of used off-gases as well as on the end product (methane and/or methanol) are analyzed and evaluated in terms of their economic performance. The most influential cost factors are identified and sensitivity analyses are conducted for different operating and economic parameters. Renewable hydrogen produced by PEM electrolysis is the most expensive component in this scheme and responsible for over 80% of the total costs. Progress in the hydrogen economy (lower electrolyzer capital costs improved electrolyzer efficiency and lower electricity prices) is necessary to establish this technology in the future.
Optimization of Energy Management Strategy for Fuel Cell Hybrid Electric Vehicles Based on Dynamic Programming
Jun 2022
Publication
Fuel cell hybrid electric vehicles have attracted a large amount of attention in recent years owing to their advantages of zero emissions high efficiency and low noise. To improve the fuel economy and system durability of vehicles this paper proposes an energy management strategy optimization method for fuel cell hybrid electric vehicles based on dynamic programming. Rule-based and dynamic-programming-based strategies are developed based on building a fuel cell/battery hybrid system model. The rule-based strategy is improved with a power distribution scheme of dynamic programming strategy to improve the fuel economy of the vehicle. Furthermore a limit on the rate of change of the output power of the fuel cell system is added to the rule-based strategy to avoid large load changes to improve the durability of the fuel cell. The simulation results show that the equivalent 100 km hydrogen consumption of the strategy based on the dynamic programming optimization rules is reduced by 6.46% compared with that before the improvement and by limiting the rate of change of the output power of the fuel cell system the times of large load changes are reduced. Therefore the strategy based on the dynamic programming optimization rules effectively improves the fuel economy and system durability of vehicles.
Investigation on the Effects of Blending Hydrogen-rich Gas in the Spark-ignition Engine
May 2022
Publication
In order to improve the energy efficiency of the internal combustion engine and replace fossil fuel with alternative fuels a concept of the methanol-syngas engine was proposed and the prototype was developed. Gasoline and dissociated methanol gas (GDM) were used as dual fuels and the engine performance was investigated by simulation and experiments. Dissociated methanol gas is produced by recycling the exhaust heat. The performance and combustion process was studied and compared with the gasoline engine counterpart. There is 1.9% energy efficiency improvement and 5.5% fuel consumption reduction under 2000r/min 100 N · m working condition with methanol substitution ratio of 10%. In addition the engine efficiency further improves with an increase of dissociated methanol gas substitution ratio because of the increased heating value of the fuel and effects of hydrogen. The peak pressure in the cylinder and the peak heat release rate of the GDM engine are higher than that of the original gasoline engine with a phase closer to the top dead center (TDC). Therefore blending hydrogen-rich gas in the spark-ignition engine can recycle the exhaust heat and improve the thermal efficiency of the engine.
Improvement of SI Engine Combustion with Ammonia as Fuel: Effect of Ammonia Dissociation Prior to Combustion
Mar 2022
Publication
Although recent studies have shown the possibility of running ‘standard’ spark-ignition engines with 6 pure ammonia the operating range remains limited mainly due to the unfavorable characteristics of 7 ammonia for premixed combustion and often requires the addition of a complementary fuel such as H2 8 to extend it. As the best way to add H2 is to crack ammonia directly on-board this paper focuses on 9 the impact of the upstream cracking level of ammonia on the performance and emissions of a single 10 cylinder spark ignition engine. Experiments were performed over several equivalence ratios 11 dissociation rates and load conditions. It is confirmed that only a slight rate of ammonia dissociation 12 (10%) upstream of the combustion considerably enhances the engine's operating range thanks to a 13 better combustion stability. In terms of pollutant emissions the partial dissociation of ammonia 14 especially for slightly lean mixtures induces a very clear trade-off between high NOx and high 15 unburned ammonia level for high and low ammonia dissociation rates respectively. Therefore 16 cracking NH3 does not only improve the operating range of ammonia-fueled spark ignition engines but 17 can also help to reduce NH3. However to reach the same engine output work higher ammonia fuel 18 consumption will be necessary since the global system efficiency is lower using fuel dissociation. In 19 addition the global warming effect is increased with dissociation level since a higher level of N2O is 20 generated by the hydrogen contribution.
Study on Applicability of Energy-Saving Devices to Hydrogen Fuel Cell-Powered Ships
Mar 2022
Publication
The decarbonisation of waterborne transport is arguably the biggest challenge faced by the maritime industry presently. By 2050 the International Maritime Organization (IMO) aims to reduce greenhouse gas emissions from the shipping industry by 50% compared to 2008 with a vision to phase out fossil fuels by the end of the century as a matter of urgency. To meet such targets action must be taken immediately to address the barriers to adopt the various clean shipping options currently at different technological maturity levels. Green hydrogen as an alternative fuel presents an attractive solution to meet future targets from international bodies and is seen as a viable contributor within a future clean shipping vision. The cost of hydrogen fuel—in the shortterm at least—is higher compared to conventional fuel; therefore energy-saving devices (ESDs) for ships are more important than ever as implementation of rules and regulations restrict the use of fossil fuels while promoting zero-emission technology. However existing and emerging ESDs in standalone/combination for traditional fossil fuel driven vessels have not been researched to assess their compatibility for hydrogen-powered ships which present new challenges and considerations within their design and operation. Therefore this review aims to bridge that gap by firstly identifying the new challenges that a hydrogen-powered propulsion system brings forth and then reviewing the quantitative energy saving capability and qualitive additional benefits of individual existing and emerging ESDs in standalone and combination with recommendations for the most applicable ESD combinations with hydrogen-powered waterborne transport presented to maximise energy saving and minimise the negative impact on the propulsion system components. In summary the most compatible combination ESDs for hydrogen will depend largely on factors such as vessel types routes propulsion operation etc. However the mitigation of load fluctuations commonly encountered during a vessels operation was viewed to be a primary area of interest as it can have a negative impact on hydrogen propulsion system components such as the fuel cell; therefore the ESD combination that can maximise energy savings as well as minimise the fluctuating loads experienced would be viewed as the most compatible with hydrogen-powered waterborne transport.
Incentive Structures for Power-to-X and E-fuel Pathways for Transport in EU and Member States
Jun 2022
Publication
Though Power-to-X pathways primarily Power-to-Liquids attract interest as solutions for decarbonising parts of the transport sector that are not suitable for electrification the regulatory framework until recently slowed down their implementation. This paper examines the updates in the main aspects of the legal framework in the European Union from 2019 to the beginning of 2022 related to Power-to-X: support schemes specific targets and potential barriers. The results show increasing interest and market entrance of electrolysis and push from the different actors and regulatory parties to establish solutions that will enable faster upscaling. However it is visible from the National Energy and Climate Plans and hydrogen strategies that the most emphasis is still on hydrogen as an end fuel for personal vehicles or power-to-gas. On the other hand few countries have implemented legal frameworks facilitating diverse PtX pathways without focusing solely on hydrogen. Nevertheless revisions of RED II have finally set up specific targets for electrofuels and Fit for 55 has introduced new actions supporting electrofuels in aviation and marine transport.
Fostering Macroeconomic Research on Hydrogen-Powered Aviation: A Systematic Literature Review on General Equilibrium Models
Feb 2023
Publication
Hydrogen is a promising fuel to decarbonize aviation but macroeconomic studies are currently missing. Computable general equilibrium (CGE) models are suitable to conduct macroeconomic analyses and are frequently employed in hydrogen and aviation research. The main objective of this paper is to investigate existing CGE studies related to (a) hydrogen and (b) aviation to derive a macroeconomic research agenda for hydrogen-powered aviation. Therefore the well-established method of systematic literature review is conducted. First we provide an overview of 18 hydrogen-related and 27 aviation-related CGE studies and analyze the literature with respect to appropriate categories. Second we highlight key insights and identify research gaps for both the hydrogen and aviation-related CGE literature. Our findings comprise inter alia hydrogen’s current lack of cost competitiveness and the macroeconomic relevance of air transportation. Research gaps include among others a stronger focus on sustainable hydrogen and a more holistic perspective on the air transportation system. Third we derive implications for macroeconomic research on hydrogen-powered aviation including (I) the consideration of existing modeling approaches (II) the utilization of interdisciplinary data and scenarios (III) geographical suitability (IV) the application of diverse policy tools and (V) a holistic perspective. Our work contributes a meaningful foundation for macroeconomic studies on hydrogen-powered aviation. Moreover we recommend policymakers to address the macroeconomic perspectives of hydrogen use in air transportation.
Sizing and Performance Analysis of Hydrogen- and Battery-Based Powertrains, Integrated into a Passenger Train for a Regional Track, Located in Calabria (Italy)
Aug 2022
Publication
In order to decarbonize the rail industry the development of innovative locomotives with the ability to use multiple energy sources constituting hybrid powertrains plays a central role in transitioning from conventional diesel trains. In this paper four configurations based on suitable combinations of fuel cells and/or batteries are designed to replace or supplement a diesel/overhead line powertrain on a real passenger train (the Hitachi Blues) tested on an existing regional track the Catanzaro Lido–Reggio Calabria line (Italy) managed by Trenitalia SpA. (Italy). The configurations (namely battery–electrified line full-battery fuel cell–battery–electrified line and fuel cell–battery) are first sized with the intention of completing a round trip then integrated on board with diesel engine replacement in mind and finally occupy a portion of the passenger area within two locomotives. The achieved performance is thoroughly examined in terms of fuel cell efficiency (greater than 47%) hydrogen consumption (less than 72 kg) braking energy recovery (approximately 300 kWh) and battery interval SOC.
Fuel Flexibility of Solid Oxide Fuel Cells
Aug 2021
Publication
One of the major advantages of SOFCs is their high fuel flexibility. Next to natural gas and hydrogen which are today’s most common fuels for SOFC-systems and cell-/stack-testing respectively various other fuels are applicable as well. In the literature a number of promising results show that available fuels as propane butane ammonia gasoline diesel etc. can be applied. Here the performance of an anode supported cell operated in specialized single cell test benches with different gaseous and liquid fuels and reformates thereof is presented. Fuels as ammonia dissolved urea (AddBlueTM) methane/steam and ethanol/water mixtures can directly be fed to the cell whereas propane and diesel require external reforming. It is shown that in case of a stable fuel supply the cell performance with such fuels is similar to that of appropriate mixtures of H2 N2 CO CO2 and steam if the impact of endothermic reforming or decomposition reactions is considered. Even though a stable fuel cell operation with such fuels is possible in a single cell test bench it should be pointed out that an appropriate fuel processing will be mandatory on the system level.
Techno-Economic Analysis of Hydrogen Storage Technologies for Railway Engineering: A Review
Sep 2022
Publication
According to the specific requirements of railway engineering a techno-economic comparison for onboard hydrogen storage technologies is conducted to discuss their feasibility and potentials for hydrogen-powered hybrid trains. Physical storage methods including compressed hydrogen (CH2 ) liquid hydrogen (LH2 ) and cryo-compressed hydrogen (CcH2 ) and material-based (chemical) storage methods such as ammonia liquid organic hydrogen carriages (LOHCs) and metal hydrides are carefully discussed in terms of their operational conditions energy capacity and economic costs. CH2 technology is the most mature now but its storage density cannot reach the final target which is the same problem for intermetallic compounds. In contrast LH2 CcH2 and complex hydrides are attractive for their high storage density. Nevertheless the harsh working conditions of complex hydrides hinder their vehicular application. Ammonia has advantages in energy capacity utilisation efficiency and cost especially being directly utilised by fuel cells. LOHCs are now considered as a potential candidate for hydrogen transport. Simplifying the dehydrogenation process is the important prerequisite for its vehicular employment. Recently increasing novel hydrogen-powered trains based on different hydrogen storage routes are being tested and optimised across the world. It can be forecasted that hydrogen energy will be a significant booster to railway decarbonisation.
Designing Hydrogen Recirculation Ejectors for Proton Exchange Membrane Fuel Cell Systems
Jan 2023
Publication
The proton exchange membrane fuel cell (PEMFC) is a promising device in the fields of power generation energy storage aerospace and public transportation. The hydrogen recirculation ejector with the advantages of low cost high durability and no parasitic power is the key component of PEMFC systems. However it is challenging to design a hydrogen recirculation ejector to cover the wide operating conditions of PEMFC systems. In order to design an ejector for fuel cell systems a comprehensive understanding of ejector research is required. Consequently the state-of-the-art research work on the hydrogen recirculation ejector is analyzed including characteristics of the ejector in PEM fuel cell systems geometry design and optimization different types of ejectors and a comparison between them and system integration and control. Through a comprehensive analysis of ejectors further research suggestions on designing high-performance ejectors are presented.
Optimal Design of Photovoltaic, Biomass, Fuel Cell, Hydrogen Tank Units and Electrolyzer Hybrid System for a Remote Area in Egypt
Jul 2022
Publication
In this paper a new isolated hybrid system is simulated and analyzed to obtain the optimal sizing and meet the electricity demand with cost improvement for servicing a small remote area with a peak load of 420 kW. The major configuration of this hybrid system is Photovoltaic (PV) modules Biomass gasifier (BG) Electrolyzer units Hydrogen Tank units (HT) and Fuel Cell (FC) system. A recent optimization algorithm namely Mayfly Optimization Algorithm (MOA) is utilized to ensure that all load demand is met at the lowest energy cost (EC) and minimize the greenhouse gas (GHG) emissions of the proposed system. The MOA is selected as it collects the main merits of swarm intelligence and evolutionary algorithms; hence it has good convergence characteristics. To ensure the superiority of the selected MOA the obtained results are compared with other well-known optimization algorithms namely Sooty Tern Optimization Algorithm (STOA) Whale Optimization Algorithm (WOA) and Sine Cosine Algorithm (SCA). The results reveal that the suggested MOA achieves the best system design achieving a stable convergence characteristic after 44 iterations. MOA yielded the best EC with 0.2106533 $/kWh the net present cost (NPC) with 6170134 $ the loss of power supply probability (LPSP) with 0.05993% and GHG with 792.534 t/y.
Impact of Hydrogen Liquefaction on Hydrogen Fuel Quality for Transport Applications (ISO-14687:2019)
Aug 2022
Publication
Decarbonisation of the energy sector is becoming increasingly more important to the reduction in climate change. Renewable energy is an effective means of reducing CO2 emissions but the fluctuation in demand and production of energy is a limiting factor. Liquid hydrogen allows for long-term storage of energy. Hydrogen quality is important for the safety and efficiency of the end user. Furthermore the quality of the hydrogen gas after liquefaction has not yet been reported. The purity of hydrogen after liquefaction was assessed against the specification of Hydrogen grade D in the ISO-14687:2019 by analysing samples taken at different locations throughout production. Sampling was carried out directly in gas cylinders and purity was assessed using multiple analytical methods. The results indicate that the hydrogen gas produced from liquefaction is of a higher purity than the starting gas with all impurities below the threshold values set in ISO-14687:2019. The amount fraction of water measured in the hydrogen sample increased with repeated sampling from the liquid hydrogen tank suggesting that the sampling system used was affected by low temperatures (−253 ◦C). These data demonstrate for the first time the impact of liquefaction on hydrogen purity assessed against ISO-14687:2019 showing that liquified hydrogen is a viable option for long-term energy storage whilst also improving quality.
Integrated Power and Propulsion System Optimization for a Planetary-Hopping Robot
Aug 2022
Publication
Missions targeting the extreme and rugged environments on the moon and Mars have rich potential for a high science return although several risks exist in performing these exploration missions. The current generation of robots is unable to access these high-priority targets. We propose using teams of small hopping and rolling robots called SphereX that are several kilograms in mass and can be carried by a large rover or lander and tactically deployed for exploring these extreme environments. Considering that the importance of minimizing the mass and volume of these robot platforms translates into significant mission-cost savings we focus on the optimization of an integrated power and propulsion system for SphereX. Hydrogen is used as fuel for its high energy and it is stored in the form of lithium hydride and oxygen in the form of lithium perchlorate. The system design undergoes optimization using Genetic Algorithms integrated with gradient-based search techniques to find optimal solutions for a mission. Our power and propulsion system as we show in this paper is enabling because the robots can travel long distances to perform science exploration by accessing targets not possible with conventional systems. Our work includes finding the optimal mass and volume of SphereX such that it can meet end-to-end mission requirements.
Sizing of a Fuel Cell–battery Backup System for a University Building Based on the Probability of the Power Outages Length
Jul 2022
Publication
Hydrogen is a bright energy vector that could be crucial to decarbonise and combat climate change. This energy evolution involves several sectors including power backup systems to supply priority facility loads during power outages. As buildings now integrate complex automation domotics and security systems energy backup systems cause interest. A hydrogen-based backup system could supply loads in a multi-day blackout; however the backup system should be sized appropriately to ensure the survival of essential loads and low cost. In this sense this work proposes a sizing of fuel cell (FC) backup systems for low voltage (LV) buildings using the history of power outages. Historical data allows fitting a probability function to determine the appropriate survival of loads. The proposed sizing is applied to a university building with a photovoltaic generation system as a case study. Results show that the sizing of an FC–battery backup system for the installation is 7.6% cheaper than a battery-only system under a usual 330-minutes outage scenario. And 59.3% cheaper in the case of an unusual 48-hours outage scenario. It ensures a 99% probability of supplying essential load during power outages. It evidences the pertinence of an FC backup system to attend to outages of long-duration and the integration of batteries to support the abrupt load variations. This research is highlighted by using historical data from actual outages to define the survival of essential loads with total service probability. It also makes it possible to determine adequate survival for non-priority loads. The proposed sizing is generalisable and scalable for other buildings and allows quantifying the reliability of the backup system tending to the resilience of electrical systems.
Economic Operation Strategy of Integrated Hydrogen Energy System Considering the Uncertainty of PV Power Output
Jan 2023
Publication
To address the negative influence caused by power randomness of distributed PV output on energy system’s economic operation in this work an economic operation strategy considering the uncertainty features of PV output has been designed and applied on an integrated hydrogen energy system. First the thermal system operation model and the thermoelectric output control model are precisely built for the integrated hydrogen energy system and the hydrogen-based fuel cell respectively. Then referring to the PV output prediction data the uncertainty of light intensity variation is analyzed to correct the PV output prediction curve. Finally a cost–benefit model for the optimal economic operation of the integrated hydrogen energy system including PV hydrogen fuel cell and cogeneration unit is designed with an objective function of achieving an optimal economic operation of the multi-energy coupling devices. The simulation tests validate that considering the influence of PV output uncertainty on hydrogen fuel cell output can make the system operation more reasonable which ensures the economic and reliable operation of hydrogen energy systems.
Investigation of Emission Characteristics and Lubrication Oil Properties in a Dual Diesel–Hydrogen Internal Combustion Engine
Apr 2022
Publication
Hydrogen is considered one of the main gaseous fuels due to its ability to improve thermal performance in diesel engines. However its influence on the characteristics of lubricating oil is generally ignored. Thus in the present investigation an analysis of the effect on the physical and chemical properties of lubricating oil with mixtures of diesel fuel–hydrogen was carried out and the environmental impacts of this type of mixture were assessed. The development of the research was carried out using a diesel engine under four torque conditions (80 Nm 120 Nm 160 Nm and 200 Nm) and three hydrogen gas flow conditions (0.75 lpm 1.00 lpm and 1.25 lpm). From the results it was possible to demonstrate that the presence of hydrogen caused decreases of 3.50% 6.79% and 4.42% in the emissions of CO HC and smoke opacity respectively. However hydrogen further decreased the viscosity of the lubricating oil by 26%. Additionally hydrogen gas produced increases of 17.7% 29.27% 21.95% and 27.41% in metallic components such as Fe Cu Al and Cr respectively. In general hydrogen favors the contamination and oxidation of lubricating oil which implies a greater wear of the engine components. Due to the significantly negative impact of hydrogen on the lubrication system it should be considered due to its influence on the economic and environmental cost during the engine’s life cycle.
Transient Modeling and Performance Analysis of Hydrogen-Fueled Aero Engines
Jan 2023
Publication
With the combustor burning hydrogen as well as the strongly coupled fuel and cooling system the configuration of a hydrogen-fueled aero engine is more complex than that of a conventional aero engine. The performance and especially the dynamic behavior of a hydrogen-fueled aero engine need to be fully understood for engine system design and optimization. In this paper both the transient modeling and performance analysis of hydrogen-fueled engines are presented. Firstly the models specific to the hydrogen-fueled engine components and systems including the hydrogen-fueled combustor the steam injection system a simplified model for a quick NOx emission assessment and the heat exchangers are developed and then integrated to a conventional engine models. The simulations with both Simulink and Speedgoat-based hardware in the loop system are carried out. Secondly the performance analysis is performed for a typical turbofan engine configuration CF6 and for the two hydrogen-fueled engine configurations ENABLEH2 and HySIITE which are currently under research and development by the European Union and Pratt & Whitney respectively. At last the simulation results demonstrate that the developed transient models can effectively reflect the characteristics of hydrogen burning heat exchanging and NOx emission for hydrogen-fueled engines. In most cases the hydrogen-fueled engines show lower specific fuel consumption lower turbine entry temperature and less NOx emissions compared with conventional engines. For example at max thrust state the advanced hydrogen-fueled engine can reduce the parameters mentioned above by about 68.5% 3.7% and 12.7% respectively (a mean value of two configurations).
Design of Fuel Cell Systems for Aviation: Representative Mission Profiles and Sensitivity Analyses
Apr 2019
Publication
The global transition to a clean and sustainable energy infrastructure does not stop at aviation. The European Commission defined a set of environmental goals for the “Flight Path 2050”: 75% CO2 reduction 90% NOx reduction and 65% perceived noise reduction. Hydrogen as an energy carrier fulfills these needs while it would also offer a tenable and flexible solution for intermittent large-scale energy storage for renewable energy networks. If hydrogen is used as an energy carrier there is no better device than a fuel cell to convert its stored chemical energy. In order to design fuel cell systems for passenger aircraft it is necessary to specify the requirements that the system has to fulfill. In this paper a statistical approach to analyze these requirements is presented which accounts for variations in the flight mission profile. Starting from a subset of flight data within the desired class (e.g. mid-range inter-European flights) a stochastic model of the random mission profile is inferred. This model allows for subsequent predictions under uncertainty as part of the aircraft design process. By using Monte Carlo-based sampling of flight mission profiles the range of necessary component sizes as well as optimal degrees of hybridization with a battery is explored and design options are evaluated. Furthermore Monte Carlo-based sensitivity analysis of performance parameters explores the potential of future technological developments. Results suggest that the improvement of the specific power of the fuel cell is the deciding factor for lowering the energy system mass. The specific energy of the battery has a low influence but acts in conjunction with the specific power of the fuel cell.
Smart Energy Management System: Design of a Smart Grid Test Bench for Educational Purposes
Apr 2022
Publication
The presented article aims to design an educational test bench setup for smart grids and renewable energies with multiple features and techniques used in a microgrid. The test bench is designed for students laboratory engineers and researchers which enables electrical microgrid system studies and testing of new advanced control algorithms to optimize the energy efficiency. The idea behind this work is to design hybrid energy sources such as wind power solar photovoltaic power hydroelectric power hydrogen energy and different types of energy storage systems such as batteries pumped storage and flywheel integrating different electrical loads. The user can visualize the state of the components of each emulated scenario through an open-source software that interacts and communicates using OPC Unified Architecture protocol. The researchers can test and validate new solutions to manage the energy behavior in the grid using machine learning and optimization algorithms integrated in the software in form of blocks that can be modified and improved and then simulate the results. A model-based system of engineering is provided which describes the different requirements and case studies of the designed test bench respecting the open-source software and the frugal innovation features in which there is use of low-cost hardware and open-source software. The users obtain the opportunity to add new sources and new loads change software platforms and communicate with other simulators and equipment. The students can understand the different features of smart grids such as defect classification energy forecasting energy optimization and basics of production transmission and consumption.
Aluminium Redox Cycle in Comparison to Pressurized Hydrogen for the Energy Supply of Multi-family Houses
Nov 2022
Publication
Power-to-X technologies that convert renewable electricity to chemically stored energy in “X” may provide a gaseous liquid or solid fuel that can be used in winter to provide both heat and electricity and thus replace fossil fuels that are currently used in many countries with cold winters. This contribution compares two options for power-to-X technologies for providing heat and electricity supply of buildings with high solar photovoltaic coverage at times of low solar availability. The option “compressed hydrogen” is based on water electrolysis that produces hydrogen on-site. This hydrogen is subsequently compressed and stored at high pressure (350 bar) for use in winter by a fuel cell. The option “aluminium redox-cycle” includes an inert electrode high temperature electrolysis process that is carried out at industrial scale. Produced aluminium is subseqeuntly transported to the site of use and converted to hydrogen and heat – and finally to electricity and heat - by aluminium-water reaction in combination with a fuel cell. Results of cost and LCA analysis show that the overall energetic efficiency of the compressed hydrogen process is slightly higher than for the aluminium redox cycle. However the aluminium redox-cycles needs far less on-site storage volume and is likely to become available at lower investment cost for the end user. Total annual cost of ownership and global warming potential of the two options are quite similar.
Progress in Electrical Energy Storage System: A Critical Review
Jan 2009
Publication
Electrical energy storage technologies for stationary applications are reviewed. Particular attention is paid to pumped hydroelectric storage compressed air energy storage battery flow battery fuel cell solar fuel superconducting magnetic energy storage flywheel capacitor/supercapacitor and thermal energy storage. Comparison is made among these technologies in terms of technical characteristics applications and deployment status.
Cost, Footprint, and Reliability Implications of Deploying Hydrogen in Off-grid Electric Vehicle Charging Stations: A GIS-assisted Study for Riyadh, Saudi Arabia
Jul 2022
Publication
For the first time we quantify cost footprint and reliability implications of deploying hydrogen-based generation in off-grid electric vehicle charging stations (CS) using an optimization model coupled with a geographic information system (GIS) analysis for the city of Riyadh Saudi Arabia. We also account for the challenges associated with wind energy deployment as a candidate generation technology within city centers. The analysis was restricted to carbon-free technologies: photovoltaics (PV) wind battery and hydrogen fuel-cells. At current prevailing technology costs hydrogen can reduce the required footprint of off-grid CSs by 25% at a small incremental cost increase without impacting the charging reliability. By 2030 however hydrogen will simultaneously provide the footprint and cost advantages. If we allow as little as 5% of the annual load to be unmet the required footprint of the CS decreases by 60%. The levelized cost of energy values for the CS by 2030 can range between 0.13 and 0.20 $/kWh depending on learning-curve assumptions. The footprints calculated are then mapped to five land parcel categories in Riyadh: gas station hospital mall school and university. Incorporating hydrogen in CS design increases the number of parcels that could accommodate CSs by 15e45% via reducing the required PV array (i.e. footprint).
Optimization and Sustainability of Gasohol/hydrogen Blends for Operative Spark Ignition Engine Utilization and Green Environment
Aug 2022
Publication
One of the many technical benefits of green diesel (GD) is its ability to be oxygenated lubricated and adopted in diesel engines without requiring hardware modifications. The inability of GD to reduce exhaust tail emissions and its poor performance in endurance tests have spurred researchers to look for new clean fuels. Improving gasohol/hydrogen blend (GHB) spark ignition is critical to its long-term viability and accurate demand forecasting. This study employed the Response Surface Methodology (RSM) to identify the appropriate GHB and engine speed (ES) for efficient performance and lower emissions in a GHB engine. The RSM model output variables included brake specific fuel consumption (BSFC) brake thermal efficiency (BTE) hydrocarbon (HC) carbon dioxide (CO2) and carbon monoxide (CO) while the input variables included ES and GHB. The Analysis of Variance-assisted RSM revealed that the most affected responses are BSFC and BTE. Based on the desirability criteria the best values for the GHB and the ES were determined to be 20% and 1500 rpm respectively while the validation between experimental and numerical results was calculated to be 4.82. As a result the RSM is a useful tool for predicting the optimal GHB and ES for optimizing spark-ignition engine characteristics and ensuring benign environment.
Studies Concerning Electrical Repowering of a Training Airplane Using Hydrogen Fuel Cells
Mar 2024
Publication
The increase in greenhouse gas emissions as well as the risk of fossil fuel depletion has prompted a transition to electric transportation. The European Union aims to substantially reduce pollutant emissions by 2035 through the use of renewable energies. In aviation this transition is particularly challenging mainly due to the weight of onboard equipment. Traditional electric motors with radial magnetic flux have been replaced by axial magnetic flux motors with reduced weight and volume high efficiency power and torque. These motors were initially developed for electric vehicles with in-wheel motors but have been adapted for aviation without modifications. Worldwide there are already companies developing propulsion systems for various aircraft categories using such electric motors. One category of aircraft that could benefit from this electric motor development is traditionally constructed training aircraft with significant remaining flight resource. Electric repowering would allow their continued use for pilot training preparing them for future electrically powered aircraft. This article presents a study on the feasibility of repowering a classic training aircraft with an electric propulsion system. The possibilities of using either a battery or a hybrid source composed of a battery and a fuel cell as an energy source are explored. The goal is to utilize components already in production to eliminate the research phase for specific aircraft components.
Multi-Model Assessment for Secondary Smelting Decarbonisation: The Role of Hydrogen in the Clean Energy Transition
Jan 2023
Publication
Extensive decarbonisation efforts result in major changes in energy demand for the extractive industry. In 2021 the extraction and primary processing of metals and minerals accounted for 4.5 Gt of CO2 eq. per year. The aluminium industry was responsible for 1.1 Gt CO2 eq. direct and indirect emissions. To reach the European milestone of zero emissions by 2050 a reduction of 3% annually is essential. To this end the industry needs to take a turn towards less impactful production practices coupling secondary production with green energy sources. The present work aims to comprehensively compare the lifecycle energy consumption and environmental performance of a secondary aluminium smelter employing alternative thermal and electricity sources. In this frame a comparative analysis of the environmental impact of different thermal energy sources namely natural gas light fuel oil liquified petroleum gas hydrogen and electricity for a secondary aluminium smelter is presented. The results show that H2 produced by renewables (green H2 ) is the most environmentally beneficial option accounting for −84.156 kg CO2 eq. By producing thermal energy as well as electricity on site H2 technologies also serve as a decentralized power station for green energy production. These technologies account for a reduction of 118% compared to conventionally used natural gas. The results offer a comprehensive overview to aid decision-makers in comparing environmental impacts caused by different energy sources.
First Hydrogen Fuel Sampling from a Fuel Cell Hydrogen Electrical Vehicle–Validation of Hydrogen Fuel Sampling System to Investigate FCEV Performance
Aug 2022
Publication
Fuel cell electric vehicles (FCEV) are developing quickly from passenger vehicles to trucks or fork-lifts. Policymakers are supporting an ambitious strategy to deploy fuel cell electrical vehicles with infrastructure as hydrogen refueling stations (HRS) as the European Green deal for Europe. The hydrogen fuel quality according to international standard as ISO 14687 is critical to ensure the FCEV performance and that poor hydrogen quality may not cause FCEV loss of performance. However the sampling system is only available for nozzle sampling at HRS. If a FCEV may show a lack of performance there is currently no methodology to sample hydrogen fuel from a FCEV itself. It would support the investigation to determine if hydrogen fuel may have caused any performance loss. This article presents the first FCEV sampling system and its comparison with the hydrogen fuel sampling from the HRS nozzle (as requested by international standard ISO 14687). The results showed good agreement with the hydrogen fuel sample. The results demonstrate that the prototype developed provides representative samples from the FCEV and can be an alternative to determine hydrogen fuel quality. The prototype will require improvements and a larger sampling campaign.
Economic Analysis of a Hydrogen Power Plant in the Portuguese Electricity Market
Feb 2023
Publication
Hydrogen is regarded as a flexible energy carrier with multiple applications across several sectors. For instance it can be used in industrial processes transports heating and electrical power generation. Green hydrogen produced from renewable sources can have a crucial role in the pathway towards global decarbonization. However the success of green hydrogen production ultimately depends on its economic sustainability. In this context this work evaluates the economic performance of a hydrogen power plant participating in the electricity market and supplying multiple hydrogen consumers. The analysis includes technical and economical details of the main components of the hydrogen power plant. Its operation is simulated using six different scenarios which admit the production of either grey or green hydrogen. The scenarios used for the analysis include data from the Iberian electricity market for the Portuguese hub. An important conclusion is that the combination of multiple services in a hydrogen power plant has a positive effect on its economic performance. However as of today consumers who would wish to acquire green hydrogen would have to be willing to pay higher prices to compensate for the shorter periods of operation of hydrogen power plants and for their intrinsic losses. Nonetheless an increase in green hydrogen demand based on a greater environmental awareness can lead to the need to not only build more of these facilities but also to integrate more services into them. This could promote the investment in hydrogen-related technologies and result in changes in capital and operating costs of key components of these plants which are necessary to bring down production costs.
Hydrogen Fuel Cell Aircraft for the Nordic Market
Mar 2024
Publication
A model for a fuel cell propelled 50 PAX hydrogen aircraft is developed. In terms of year 2045 Nordic air travel demand this aircraft is expected to cover 97% of travel distances and 58% of daily passenger volume. Using an ATR 42 as a baseline cryogenic tanks and fuel cell stacks are sized and propulsion system masses updated. Fuselage and wing resizing are required which increases mass and wetted area. Sizing methods for the multi-stack fuel cell and the cryogenic tanks are implemented. The dynamic aircraft model is updated with models for hydrogen consumption and tank pressure control. For the Multi-layer insulation (MLI) tank a trade study is performed. A ventilation pressure of 1.76 bar and 15 MLI layers are found to be optimal for the design mission. A return-without-refuel mission is explored where for a 10-hour ground hold 38.4% of the design range is retained out of the theoretically achievable 50%.
A Review of the Integrated Renewable Energy Systems for Sustainable Urban Mobility
Aug 2022
Publication
Several challenges have emerged due to the increasing deterioration of urban mobility and its severe impacts on the environment and human health. Primary dependence on internal combustion engines that use petrol or diesel has led to poor air quality time losses noise traffic jams and further environmental pollution. Hence the transitions to using rail and or seaway-based public transportation cleaner fuels and electric vehicles are some of the ultimate goals of urban and national decision-makers. However battery natural gas hybrid and fuel cell vehicles require charging stations to be readily available with a sustainable energy supply within urban regions in different residential and business neighborhoods. This study aims to provide an updated and critical review of the concept and recent examples of urban mobility and transportation modes. It also highlights the adverse impacts of several air pollutants emitted from internal combustion engine vehicles. It also aims to shed light on several possible systems that integrate the electric vehicle stations with renewable energy sources. It was found that using certain components within the integrated system and connecting the charging stations with a grid can possibly provide an uninterrupted power supply to electric vehicles leading to less pollution which would encourage users to use more clean vehicles. In addition the environmental impact assessments as well as several implementation challenges are discussed. To this end the main implementation issues related to consumer incentives infrastructure and recommendations are also reported.
Strategies to Accelerate the Production and Diffusion of Fuel Cell Electric Vehicles: Experiences from California
Sep 2020
Publication
Fuel cell electric vehicles (FCEVs) can play a key role in accelerating the electrification of road transport. Specifically they offer longer driving ranges and shorter refuelling times relative to Battery Electric Vehicles (BEVs) while reducing needs for space-intensive public charging infrastructure. Although the maturity and market penetration of hydrogen is currently trailing batteries transport planners in several countries are looking to both technologies to reduce carbon emissions and air pollution. Home to the world’s largest on-road fleet of FCEVs California is one such jurisdiction. Experiences in California provide an ideal opportunity to address a gap in literature whereby barriers to FCEV diffusion are well understood but knowledge on actual strategies to overcome these has lacked. This study thus examines governance strategies in California to accelerate the production and diffusion of FCEVs key outcomes lessons learned and unresolved challenges. Evidence is sourced from 19 expert interviews and an examination of diverse documents. Strategies are examined from four perspectives: (i) supply-side (i.e. stimulation of vehicle production) (ii) infrastructure (i.e. construction of refuelling stations and hydrogen production) (iii) demand-side (i.e. stimulation of vehicle adoption) and (iv) institutional (i.e. cross-cutting measures to facilitate collaboration innovation and cost-reduction). Findings reveal a comprehensive mix of stringent regulation market and consumer incentives and public–private collaboration. However significant challenges remain for spurring the development of fuel cell transport in line with initial ambitions. Highlighting these provides important cues for public policy to accelerate the deployment of FCEVs and hydrogen in California and elsewhere.
Potential for Hydrogen and Power-to-Liquid in a Low-carbon EU Energy System Using Cost Optimization
Oct 2018
Publication
Hydrogen represents a versatile energy carrier with net zero end use emissions. Power-to-Liquid (PtL) includes the combination of hydrogen with CO2 to produce liquid fuels and satisfy mostly transport demand. This study assesses the role of these pathways across scenarios that achieve 80–95% CO2 reduction by 2050 (vs. 1990) using the JRC-EU-TIMES model. The gaps in the literature covered in this study include a broader spatial coverage (EU28+) and hydrogen use in all sectors (beyond transport). The large uncertainty in the possible evolution of the energy system has been tackled with an extensive sensitivity analysis. 15 parameters were varied to produce more than 50 scenarios. Results indicate that parameters with the largest influence are the CO2 target the availability of CO2 underground storage and the biomass potential.
Hydrogen demand increases from 7 mtpa today to 20–120 mtpa (2.4–14.4 EJ/yr) mainly used for PtL (up to 70 mtpa) transport (up to 40 mtpa) and industry (25 mtpa). Only when CO2 storage was not possible due to a political ban or social acceptance issues was electrolysis the main hydrogen production route (90% share) and CO2 use for PtL became attractive. Otherwise hydrogen was produced through gas reforming with CO2 capture and the preferred CO2 sink was underground. Hydrogen and PtL contribute to energy security and independence allowing to reduce energy related import cost from 420 bln€/yr today to 350 or 50 bln€/yr for 95% CO2 reduction with and without CO2 storage. Development of electrolyzers fuel cells and fuel synthesis should continue to ensure these technologies are ready when needed. Results from this study should be complemented with studies with higher spatial and temporal resolution. Scenarios with global trading of hydrogen and potential import to the EU were not included.
Hydrogen demand increases from 7 mtpa today to 20–120 mtpa (2.4–14.4 EJ/yr) mainly used for PtL (up to 70 mtpa) transport (up to 40 mtpa) and industry (25 mtpa). Only when CO2 storage was not possible due to a political ban or social acceptance issues was electrolysis the main hydrogen production route (90% share) and CO2 use for PtL became attractive. Otherwise hydrogen was produced through gas reforming with CO2 capture and the preferred CO2 sink was underground. Hydrogen and PtL contribute to energy security and independence allowing to reduce energy related import cost from 420 bln€/yr today to 350 or 50 bln€/yr for 95% CO2 reduction with and without CO2 storage. Development of electrolyzers fuel cells and fuel synthesis should continue to ensure these technologies are ready when needed. Results from this study should be complemented with studies with higher spatial and temporal resolution. Scenarios with global trading of hydrogen and potential import to the EU were not included.
A Review of The Methanol Economy: The Fuel Cell Route
Jan 2020
Publication
This review presents methanol as a potential renewable alternative to fossil fuels in the fight against climate change. It explores the renewable ways of obtaining methanol and its use in efficient energy systems for a net zero-emission carbon cycle with a special focus on fuel cells. It investigates the different parts of the carbon cycle from a methanol and fuel cell perspective. In recent years the potential for a methanol economy has been shown and there has been significant technological advancement of its renewable production and utilization. Even though its full adoption will require further development it can be produced from renewable electricity and biomass or CO2 capture and can be used in several industrial sectors which make it an excellent liquid electrofuel for the transition to a sustainable economy. By converting CO2 into liquid fuels the harmful effects of CO2 emissions from existing industries that still rely on fossil fuels are reduced. The methanol can then be used both in the energy sector and the chemical industry and become an all-around substitute for petroleum. The scope of this review is to put together the different aspects of methanol as an energy carrier of the future with particular focus on its renewable production and its use in high-temperature polymer electrolyte fuel cells (HT-PEMFCs) via methanol steam reforming.
HydroGenerally - Episode 3: Lift Off for Hydrogen in Aviation
Apr 2022
Publication
In this third episode Steffan Eldred and Hannah Abson from Innovate UK KTN are exploring the scale of the opportunity that hydrogen and aviation present alongside their special guest Katy Milne Head of Industrial Strategy at FlyZero.
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: What's Brewing in the UK Clean Hydrogen Sector?
Dec 2021
Publication
Chris Jackson is the Founder and CEO of Protium Green Solutions based in London. Protium is a hydrogen energy services company that designs develops finances owns and operates clean hydrogen solutions for clients to achieve net zero energy emissions at their industrial/manufacturing sites. Chris will talk to us about the Protium story and also give us some insight into a major project that Protium recently announced in conjunction Budweiser Brewing Group UK&Ireland to explore the deployment of zero emission green hydrogen at Magor brewery in South Wales one of the largest breweries in the UK. To that end in order to get the full story about this project we are delighted to say that we have yet another great guest on this episode. Tom Brewer who leads Global Environmental Sustainability efforts at AB InBev the parent company of Budweiser Brewing Group will join us for the final segment of the show to talk about how hydrogen fits into AB InBev’s vision of a sustainable future for the company.
The podcast can be found on their website
The podcast can be found on their website
Hydrogen Fuel Cell Road Vehicles: State of the Art and Perspectives
Nov 2020
Publication
Driven by a small number of niche markets and several decades of application research fuel cell systems (FCS) are gradually reaching maturity to the point where many players are questioning the interest and intensity of its deployment in the transport sector in general. This article aims to shed light on this debate from the road transport perspective. It focuses on the description of the fuel cell vehicle (FCV) in order to understand its assets limitations and current paths of progress. These vehicles are basically hybrid systems combining a fuel cell and a lithium-ion battery and different architectures are emerging among manufacturers who adopt very different levels of hybridization. The main opportunity of Fuel Cell Vehicles is clearly their design versatility based on the decoupling of the choice of the number of Fuel Cell modules and hydrogen tanks. This enables manufacturers to meet various specifications using standard products. Upcoming developments will be in line with the crucial advantage of Fuel Cell Vehicles: intensive use in terms of driving range and load capacity. Over the next few decades long-distance heavy-duty vehicles and fleets of taxis or delivery vehicles will develop based on range extender or mild hybrid architectures and enable the hydrogen sector to mature the technology from niche markets to a large-scale market.
Everything About Hydrogen Podcast: Toyota's global hydrogen ambitions
Feb 2020
Publication
On this weeks episode the team are talking all things hydrogen with Craig Scott the Group Manager for Toyota North America a global automotive giant and a recognised pioneer in the field of fuel cell mobility. On the show we get into the story of Toyota’s roll out of fuel cell mobility solutions in North America the challenges and opportunities that fuel cell vehicles can offer in the hydrogen market and the challenges around infrastructure. Importantly we also dive into the scaling up work that Toyota is undertaking and some of its plans for next steps on the mission to become the world’s leader in fuel cell mobility solutions. All this and more on the show!
The podcast can be found on their website
The podcast can be found on their website
Everything About Hydrogen Podcast: Building Europe's Hydrogen Mobility Network
Jan 2020
Publication
On this weeks episode the team are talking all things hydrogen with Jacob Krogsgaard the CEO of Everfuel a leading supplier of green hydrogen for mobility and industry in Europe. Since its establishment by Nel and a Consortium of parties and investors Everfuel has become a market leader in establishing green hydrogen solutions for mobility in Europe and has recently expanded into areas such as power-to-gas as well. The team catch up with Jacob on Everfuels business model the establishment of the H2Bus Consortium Jacob’s views on how the market for green hydrogen is evolving in Europe and where he sees the greatest early potential for scaling.…..All this and more on the show!
The podcast can be found on their website
The podcast can be found on their website
How to Decarbonise the UKs Freight Sector by 2050
Dec 2020
Publication
To achieve the UK’s net zero target vehicles including heavy-duty vehicles (HDVs) will need to be entirely decarbonised. The UK government has announced that it plans to phase out the sale of all new cars and vans with engines between 2030 and 2035. It has also announced its intention to consult on a similar phase-out for diesel-powered heavy-goods vehicles (HGVs). This study analyses policies and technologies which can contribute to the decarbonisation of the UK's inland freight sector.
It comprises an emissions modelling exercise and a cost analysis for total cost of ownership (TCO) of long-haul trucks. The study shows that for urban and regional deliveries battery electric trucks offer the best option to decarbonise. It also shows that battery electric trucks and those using an overhead catenary infrastructure are likely to be the most cost-effective pathway to decarbonise long-haul trucks by 2050 but that renewable hydrogen could also be an option.
Link to Document Download on Transport & Environment website
It comprises an emissions modelling exercise and a cost analysis for total cost of ownership (TCO) of long-haul trucks. The study shows that for urban and regional deliveries battery electric trucks offer the best option to decarbonise. It also shows that battery electric trucks and those using an overhead catenary infrastructure are likely to be the most cost-effective pathway to decarbonise long-haul trucks by 2050 but that renewable hydrogen could also be an option.
Link to Document Download on Transport & Environment website
Everything About Hydrogen Podcast: Changing the Game in Hydrogen Compression
Oct 2021
Publication
In the second episode of EAH's Season 3 Patrick Andrew and Chris sit down with Maria Fennis CEO of HyET. HyET Hydrogen is a leading SME in the field of electrochemical hydrogen compression founded in 2008. HyET has introduced the first commercially viable Electrochemical Hydrogen Compressor (EHPC) the HCS 100 in 2017. HyET enters partnerships with key stakeholders to develop products with a focus on application. Maria is a leading voice in the compression arena and it is a pleasure to have her on the show!
The podcast can be found on their website
The podcast can be found on their website
Fuel Cell Electric Vehicle (FCEV) Energy Flow Analysis in Real Driving Conditions (RDC)
Aug 2021
Publication
The search for fossil fuels substitutes forces the use of new propulsion technologies applied to means of transportation. Already widespread hybrid vehicles are beginning to share the market with hydrogen-powered propulsion systems. These systems are fuel cells or internal combustion engines powered by hydrogen fuel. In this context road tests of a hydrogen fuel cell drive were conducted under typical traffic conditions according to the requirements of the RDE test. As a result of the carried-out work energy flow conditions were presented for three driving phases (urban rural and motorway). The different contributions to the vehicle propulsion of the hydrogen system and the electric system in each phase of the driving route are indicated. The characteristic interaction of power train components during varying driving conditions was presented. A wide variation in the contribution of the fuel cell and the battery to the vehicle’s propulsion was identified. In urban conditions the share of the fuel cell in the vehicle’s propulsion is more than three times that contributed by the battery suburban—7 times highway—28 times. In the entire test the ratio of FC/BATT use was more than seven while the energy consumption was more than 22 kWh/100 km. The amounts of battery energy used and recovered were found to be very close to each other under RDE test conditions.
Optimal Allocation of Energy Sources in Hydrogen Production for Sustainable Deployment of Electric Vehicles
Jan 2023
Publication
We analyze the use of hydrogen as a fuel for the automotive industry with the aim of decarbonizing the economy. Hydrogen is a suitable option for avoiding pollutant gas emissions developing environmentally friendly technologies replacing fossil fuels with clean renewable energies and complying with the Paris Agreement and Glasgow resolutions. In this sense renewable energies such as wind solar photovoltaic geothermal biomass etc. can be used to produce the necessary hydrogen to power vehicles. In this way the entire process from hydrogen production to its consumption as fuel will be 100% clean. If we are to meet future energy demands it is necessary to forecast the amount of hydrogen needed taking into account the facilities currently available and new ones that will be required for its generation storage and distribution. This paper presents a process for optimizing hydrogen production for the automotive industry that considers the amount of hydrogen needed the type of facilities from which it will be produced how the different sources of production are to be combined to achieve a competitive product and the potential environmental impacts of each energy source. It can serve as a frame of reference for the various actors in the hydropower and automotive industries so that more efficient designs can be planned for the gradual introduction of hydrogen fuel cell vehicles (HFCVs). The methodology implemented in this paper sets an optimization problem for minimizing energy production costs and reducing environmental impacts according to the source of energy production. The EU framework with respect to the decarbonization of the economy the percentages of the different types of energy sources used and the non-polluting vehicle fleet in the automotive sector will be considered.
Impact of Hydrogen in the Road Transport Sector for Portugal 2010-2050
Nov 2014
Publication
This paper presents an analysis of the potential economic-wide energy and CO2 emissions implications of hydrogen vehicle penetration into the Portuguese road transport over the time-horizon 2010-2050. The energy and emissions implications are obtained using PATTS (Projections for Alternative Transportation Technologies Simulation) an excel spreadsheet model based on forecast scenarios. Historical data and trends of gasoline versus diesel share fleet scrappadge representative light-duty vehicle technologies life cycle energy and emission factors are used to estimate on a yearly basis the total fleet life cycle energy consumption CO2 emissions and air quality related impact. The macroeconomic effects are assessed with a Computable General Equilibrium model that is solved as a non-linear optimization problem formulated in GAMS software capable of dealing with substitution between labour capital stock electric energy and non-electric energy factors of production. It integrates parameter inputs obtained from PATTS tool where the transportation sector becomes hydrogen driven and a wide hydrogen refuelling infrastructure is deployed. The simulation experiments show that "hydrogen technologies" are likely to become economically viable. Household consumption real GDP and investment increase from baseline. The positive impact upon the economic variables is supplemented by energy costs reductions of just -0.1 to -0.3 percent per annum in both high-price and low-price cases. The economy grows faster in the low-price case where the reductions in energy costs are also more pronounced. CO2 avoided emissions due to hydrogen economy reach a maximum of 2 kton/km in 2050 if the natural gas steam reforming production method is adopted.
Fuzzy Logic-based Energy Management System for Grid-connected Residential DC Microgrids with Multi-stack Fuel Cell Systems: A Multi-objective Approach
Aug 2022
Publication
Hybrid energy storage systems (HESS) are considered for use in renewable residential DC microgrids. This architecture is shown as a technically feasible solution to deal with the stochasticity of renewable energy sources however the complexity of its design and management increases inexorably. To address this problem this paper proposes a fuzzy logic-based energy management system (EMS) for use in grid-connected residential DC microgrids with HESS. It is a hydrogen-based HESS composed of batteries and multi-stack fuel cell system. The proposed EMS is based on a multivariable and multistage fuzzy logic controller specially designed to cope with a multi-objective problem whose solution increases the microgrid performance in terms of efficiency operating costs and lifespan of the HESS. The proposed EMS considers the power balance in the microgrid and its prediction the performance and degradation of its subsystems as well as the main electricity grid costs. This article assesses the performance of the developed EMS with respect to three reference EMSs present in the literature: the widely used dual-band hysteresis and two based on multi-objective model predictive control. Simulation results show an increase in the performance of the microgrid from a technical and economic point of view.
Numerical 1-D Simulations on Single-Cylinder Stationary Spark Ignition Engine using Micro-Emulsions, Gasoline, and Hydrogen in Dual Fuel Mode
Mar 2022
Publication
This work is contributing towards reducing the emissions from stationary spark ignition engine single cylinder by adopting the state of the Art Technology Hydrogen fuel and H2O based Emulsion fuel in dual fuel mode. In addition comparing its combustion emissions and performance with conventional 100% Gasoline fuel. This research work has been done on 1-D AVL Boost Simulation Software by using the single cylinder engine model setup. The main objectives of this research work is to comply with the strict emission rules Euro VII. This work predicted the overall combustion parameters NOx CO and HC emissions as well as several performance measures like power torque BSFC and BMEP of stationary spark ignition engine test rig. Since Hydrogen is zero carbon emission based fuel so it is not creating any carbon-based emissions and has shown to be the most efficient source of energy. Although Hydrogen fuel showed no carbon emissions but NOx emissions were slightly higher than micro-emulsion fuel. Since Hydrogen fuel burns at very high temperature so it produced slightly more NOx emissions. The NOx emissions were 20% higher than emulsion fuel and 10% higher than Gasoline 100% fuel. The H2O based emulsion fuel is also investigated which helped in reducing the emissions and improved the performance of single-cylinder stationary spark Gasoline+ Micro-Emulsion +Hydrogen fuel Lower CO HC and NOx Emissions Improved Power Torque Bsfc & Pressure Constant Speed & variable Load ignition test rig. The Brake power BSFC BMEP & Torque were also investigated power and showed greater improvement for emulsion fuel. At 60% load the Hydrogen fuel showed 50% increase in power as compared to emulsion fuel and 38% more power than Gasoline fuel. Exhaust emissions CO HC were compared for gasoline and emulsion fuel. The CO emissions are 18% lower for micro-emulsion as compared to Gasoline 100% and HC emissions are 12.5% lower than gasoline 100% fuel at 20% load.
Sector Coupling and Business Models Towards Sustainability: The Case of the Hydrogen Vehicle Industry
Mar 2022
Publication
The concept of sector coupling has been gaining increased momentum in political discourses during 18 the past few years but it has only recently received the attention of international academics. The 19 private sector is particularly relevant to foster sector coupling through entrepreneurial action – 20 specifically innovative business models for more sustainable technologies are needed to promote a 21 transition towards more sustainability. So far however the literature on business models from a 22 sector coupling perspective is scarce yet strongly emerging. To address the identified research gaps 23 and enhance the current knowledge on the emerging hydrogen vehicle industry and sector coupling 24 this study adopts a qualitative and exploratory research approach and builds on information gained 25 in 103 semi-structured interviews to discuss emerging business models in Germany. In particular 33 26 business cases have been analyzed. Anchoring business model theory to the concept of sector 27 coupling this study identifies 12 business model archetypes in the emerging hydrogen vehicle 28 industry and its value chain. It can be shown that while the market is still emerging and the market 29 players are not defined and are evolving companies are currently engaged in finding their position 30 along the value chain fostering vertical integration and promoting cooperation between the 31 different sectors. While this study is relevant for both the academia and the industry it is particularly 2 32 interesting for policy makers shaping the future of sustainable development specifically considering 33 integrated energy systems.
Proton Exchange Membrane Hydrogen Fuel Cell as the Grid Connected Power Generator
Dec 2020
Publication
In this paper a proton exchange membrane fuel cell (PEMFC) is implemented as a grid-connected electrical generator that uses hydrogen gas as fuel and air as an oxidant to produce electricity through electrochemical reactions. Analysis demonstrated that the performance of the PEMFC greatly depends on the rate of fuel supply and air supply pressure. Critical fuel and air supply pressures of the PEMFC are analysed to test its feasibility for the grid connection. Air and fuel supply pressures are varied to observe the effects on the PEMFC characteristics efficiency fuel supply and air consumption over time. The PEMFC model is then implemented into an electrical power system with the aid of power electronics applications. Detailed mathematical modelling of the PEMFC is discussed with justification. The PEMFC functions as an electrical generator that is connected to the local grid through a power converter and a transformer. Modulation of the converter is controlled by means of a proportional-integral controller. The two-axis control methodology is applied to the current control of the system. The output voltage waveform and control actions of the controller on the current and frequency of the proposed system are plotted as well. Simulation results show that the PEMFC performs efficiently under certain air and fuel pressures and it can effectively supply electrical power to the grid.
Green Hydrogen Production for Oil Refining - Finnish Case
Jan 2023
Publication
This study investigates the production of green hydrogen for use in oil refining as specified in the draft of European union delegated act published in May 2022. The European union plans to set strict requirements of additionality and reporting regarding the criteria of renewable electricity used in hydrogen production. Alkaline electrolyzer proton exchange membrane electrolyzer and solid oxide electrolyzer are evaluated in various scenarios supplied by wind power: power purchase agreement-based scenarios and wind power investment-based scenarios. In power purchase agreement-based scenarios baseload and pay as produced power purchase agreements (with and without electricity storage) are assessed. According to results the use of 600 MW compressed air energy storage could reduce the dependency on the grid by 7% but increase the cost of green hydrogen significantly. Investment-based scenarios produce green hydrogen with a lower operation cost but higher break-even price compared to power purchase agreement-based scenarios. The cheapest green hydrogen can be achieved by alkaline electrolyzer with baseload power purchase agreement. Direct ownership of wind power is outside the operation of oil refining industry thus power purchase agreements contracting is more likely to realize.
Design Challenges in Hydrogen-Fueled Rotary Engine-A Review
Jan 2023
Publication
The rotary engine (RE) is a potential power plant for unmanned aerial vehicles (UAVs) and automobiles because of its structural and design merits. However it has some serious drawbacks such as frequent maintenance requirements and excessive fuel consumption. This review paper presents the current status of hydrogen-fueled rotary engine (HRE) technology and identifies the existing research and development gaps in combustion efficiency and performance of this engine that might benefit transportation sector. Focusing primarily on the research from past ten years the crucial challenges encountered in hydrogen-powered rotary engines have been reviewed in terms of knock hydrocarbon (HC) emissions and seal leakages. The paper identifies the recent advances in design concepts and production approaches used in hydrogen-fueled rotary engines such as geometric models of trochoid profiles port configurations fuel utilization systems and currently available computational fluid dynamics (CFD) tools. This review article is an attempt to collect and organize literature on existing design methods up to date and provide recommendations for further improvements in RE technology.
How Long Will Combustion Vehicles Be Used? Polish Transport Sector on the Pathway to Climate Neutrality
Nov 2021
Publication
Transformation of road transport sector through replacing of internal combustion vehicles with zero-emission technologies is among key challenges to achievement of climate neutrality by 2050. In a constantly developing economy the demand for transport services increases to ensure continuity in the supply chain and passenger mobility. Deployment of electric technologies in the road transport sector involves both businesses and households its pace depends on the technological development of zero-emission vehicles presence of necessary infrastructure and regulations on emission standards for new vehicles entering the market. Thus this study attempts to estimate how long combustion vehicles will be in use and what the state of the fleet will be in 2050. For obtainment of results the TR3E partial equilibrium model was used. The study simulates the future fleet structure in passenger and freight transport. The results obtained for Poland for the climate neutrality (NEU) scenario show that in 2050 the share of vehicles using fossil fuels will be ca. 30% in both road passenger and freight transport. The consequence of shifts in the structure of the fleet is the reduction of CO2 emissions ca. 80% by 2050 and increase of the transport demand for electricity and hydrogen.
Sustainable Aviation—Hydrogen Is the Future
Jan 2022
Publication
As the global search for new methods to combat global warming and climate change continues renewable fuels and hydrogen have emerged as saviours for environmentally polluting industries such as aviation. Sustainable aviation is the goal of the aviation industry today. There is increasing interest in achieving carbon-neutral flight to combat global warming. Hydrogen has proven to be a suitable alternative fuel. It is abundant clean and produces no carbon emissions but only water after use which has the potential to cool the environment. This paper traces the historical growth and future of the aviation and aerospace industry. It examines how hydrogen can be used in the air and on the ground to lower the aviation industry’s impact on the environment. In addition while aircraft are an essential part of the aviation industry other support services add to the overall impact on the environment. Hydrogen can be used to fuel the energy needs of these services. However for hydrogen technology to be accepted and implemented other issues such as government policy education and employability must be addressed. Improvement in the performance and emissions of hydrogen as an alternative energy and fuel has grown in the last decade. However other issues such as the storage and cost and the entire value chain require significant work for hydrogen to be implemented. The international community’s alternative renewable energy and hydrogen roadmaps can provide a long-term blueprint for developing the alternative energy industry. This will inform the private and public sectors so that the industry can adjust its plan accordingly.
Assessment of an Innovative Way to Store Hydrogen in Vehicles
May 2019
Publication
The use of hydrogen as an alternative to fossil fuels for vehicle propulsion is already a reality. However due to its physical characteristics storage is still a challenge. There is an innovative way presented in this study to store hydrogen in conventional vehicles propelled by spark-ignition reciprocating engines and fuel cells using hydrogen as fuel; the storage of hydrogen will be at high pressure within small spheres randomly packed in a tank like the conventional tank of fuel used nowadays in current vehicles. Therefore the main purpose of the present study is to assess the performance of this storage system and compare it to others already applied by car manufacturers in their cars. In order to evaluate the performance of this storage system some parameters were taken into account: The energy stored by volume and stored by weight hydrogen leakage and compliance with current standards. This system is safer than conventional storage systems since hydrogen is stored inside small spheres containing small amounts of hydrogen. Besides its gravimetric energy density (GED) is threefold and the volumetric energy density (VED) is about half when compared with homologous values for conventional systems and both exceed the targets set by the U.S. Department of Energy. Regarding the leakage of hydrogen it complies with the European Standards provided a suitable choice of materials and dimensions is made.
Progress and Challenges on the Thermal Management of Electrochemical Energy Conversion and Storage Technologies: Fuel Cells, Electrolysers, and Supercapacitors
Oct 2021
Publication
It is now well established that electrochemical systems can optimally perform only within a narrow range of temperature. Exposure to temperatures outside this range adversely affects the performance and lifetime of these systems. As a result thermal management is an essential consideration during the design and operation of electrochemical equipment and can heavily influence the success of electrochemical energy technologies. Recently significant attempts have been placed on the maturity of cooling technologies for electrochemical devices. Nonetheless the existing reviews on the subject have been primarily focused on battery cooling. Conversely heat transfer in other electrochemical systems commonly used for energy conversion and storage has not been subjected to critical reviews. To address this issue the current study gives an overview of the progress and challenges on the thermal management of different electrochemical energy devices including fuel cells electrolysers and supercapacitors. The physicochemical mechanisms of heat generation in these electrochemical devices are discussed in-depth. Physics of the heat transfer techniques currently employed for temperature control are then exposed and some directions for future studies are provided.
Detection of Contaminants in Hydrogen Fuel for Fuel Cell Electrical Vehicles with Sensors—Available Technology, Testing Protocols and Implementation Challenges
Dec 2021
Publication
Europe’s low-carbon energy policy favors a greater use of fuel cells and technologies based on hydrogen used as a fuel. Hydrogen delivered at the hydrogen refueling station must be compliant with requirements stated in different standards. Currently the quality control process is performed by offline analysis of the hydrogen fuel. It is however beneficial to continuously monitor at least some of the contaminants onsite using chemical sensors. For hydrogen quality control with regard to contaminants high sensitivity integration parameters and low cost are the most important requirements. In this study we have reviewed the existing sensor technologies to detect contaminants in hydrogen then discussed the implementation of sensors at a hydrogen refueling stations described the state-of-art in protocols to perform assessment of these sensor technologies and finally identified the gaps and needs in these areas. It was clear that sensors are not yet commercially available for all gaseous contaminants mentioned in ISO14687:2019. The development of standardized testing protocols is required to go hand in hand with the development of chemical sensors for this application following a similar approach to the one undertaken for air sensors.
Renewable Hydrogen Potential for Low-carbon Retrofit of the Building Stocks
Dec 2015
Publication
Energy-related GHG emissions mainly from fossil fuels combustion account for around 70% of total emissions. Those emissions are the target of the recent sustainability policies. Indeed renewables exploitation is considered widely the weapon to deal with this challenge thanks to their carbon neutrality. But the biggest drawback is represented by the mismatching between their production and users consumption. The storage would be a possible solution but its viability consists of economic sustainability and energy process efficiency as well. The cutting edge technologies of batteries have not still solved these issues at the same time. So a paradigm shift towards the identification of an energy carrier as storage option the so called Power-to-Gas could be the viable solution. From viability to feasibility a mandatory step is required: the opportunity to integrate the new solution in the proven infrastructures system. Thus the recent studies on Hydrogen (H2) enrichment in Natural Gas demonstrating a lower environmental impact and an increase in energy performance are the base to build the hydrogen transition in the urban environment. The aim of this paper is to evaluate the environmental benefits at building and district scale.
High Energy Density Storage of Gaseous Marine Fuels: An Innovative Concept and its Application to a Hydrogen Powered Ferry
Apr 2020
Publication
The upcoming stricter limitations on both pollutant and greenhouse gases emissions represent a challenge for the shipping sector. The entire ship design process requires an approach to innovation with a particular focus on both the fuel choice and the power generation system. Among the possible alternatives natural gas and hydrogen based propulsion systems seem to be promising in the medium and long term. Nonetheless natural gas and hydrogen storage still represents a problem in terms of cargo volume reduction. This paper focuses on the storage issue considering compressed gases and presents an innovative solution which has been developed in the European project GASVESSEL® that allows to store gaseous fuels with an energy density higher than conventional intermediate pressure containment systems. After a general overview of natural gas and hydrogen as fuels for shipping a case study of a small Roll-on/Rolloff passenger ferry retrofit is proposed. The study analyses the technical feasibility of the installation of a hybrid power system with batteries and polymer electrolyte membrane fuel cells fuelled by hydrogen. In particular a process simulation model has been implemented to assess the quantity of hydrogen that can be stored on board taking into account boundary conditions such as filling time on shore storage capacity and cylinder wall temperature. The simulation results show that if the fuel cells system is run continuously at steady state to cover the energy need for one day of operation 140 kg of hydrogen are required. Using the innovative pressure cylinder at a storage pressure of 300 bar the volume required by the storage system assessed on the basis of the containment system outer dimensions is resulted to be 15.2 m3 with a weight of 2.5 ton. Even if the innovative type of pressure cylinder allows to reach an energy density higher than conventional intermediate pressure cylinders the volume necessary to store a quantity of energy typical for the shipping sector is many times higher than that required by conventional fuels today used. The analysis points out as expected that the filling process is critical to maximize the stored hydrogen mass and that it is critical to measure the temperature of the cylinder walls in order not to exceed the material limits. Nevertheless for specific application such as the one considered in the paper the introduction of gaseous hydrogen as fuel can be considered for implementing zero local emission propulsion system in the medium term.
Everything About Hydrogen Podcast: Commercial Trucking at the Speed of Hydrogen
Jun 2021
Publication
The transportation and mobility sector is vast complex unwieldy and most excitingly an obvious area of focus for hydrogen fuel cell technology applications. Hydrogen FCEVs allow vehicles to run in a wide range of environments with zero tailpipe emissions and can do so without the need for extremely heavy battery cells and can be refueled in the same amount of time as a modern ICE vehicle. This makes hydrogen FCEVs an ideal fit for the heavy commercial transportation industry and is why Hyzon Motors has jumped at the opportunity to revolutionize the industry. The company has grabbed headlines all over the world with its ambitious plans for rolling out its trucks in the United States and other major markets. It has also made news with its recent announcement that the company is going public and has attracted significant investor interest. The EAH team is joined on this episode by Hyzon's CEO Craig Knight to talk about how the company is tackling some of the most significant challenges in decarbonizing transport and how it can make trucking a zero-emission operation.
The podcast can be found on their website
The podcast can be found on their website
Modeling Hydrogen Refueling Infrastructure to Support Passenger Vehicles
May 2018
Publication
The year 2014 marked hydrogen fuel cell electric vehicles (FCEVs) first becoming commercially available in California where significant investments are being made to promote the adoption of alternative transportation fuels. A refueling infrastructure network that guarantees adequate coverage and expands in line with vehicle sales is required for FCEVs to be successfully adopted by private customers. In this paper we provide an overview of modelling methodologies used to project hydrogen refueling infrastructure requirements to support FCEV adoption and we describe in detail the National Renewable Energy Laboratory’s scenario evaluation and regionalization analysis (SERA) model. As an example we use SERA to explore two alternative scenarios of FCEV adoption: one in which FCEV deployment is limited to California and several major cities in the United States; and one in which FCEVs reach widespread adoption becoming a major option as passenger vehicles across the entire country. Such scenarios can provide guidance and insights for efforts required to deploy the infrastructure supporting transition toward different levels of hydrogen use as a transportation fuel for passenger vehicles in the United States.
Sustainability Assessment of Fuel Cell Buses in Public Transport
May 2018
Publication
Hydrogen fuel cell (H2FC) buses operating in every day public transport services around Europe are assessed for their sustainability against environmental economic and social criteria. As part of this assessment the buses are evaluated against diesel buses both in terms of sustainability and in terms of meeting real world requirements with respect to operational performance. The study concludes that H2FC buses meet operability and performance criteria and are sustainable environmentally when ‘green’ hydrogen is used. The economic sustainability of the buses in terms of affordability achieves parity with their fossil fuel equivalent by 2030 when the indirect costs to human health and climate change are included. Societal acceptance by those who worked with and used the buses supports the positive findings of earlier studies although satisfactory operability and performance are shown to be essential to positive attitudes. Influential policy makers expressed positive sentiments only if ‘green’ hydrogen is used and the affordability issues can be addressed. No “show-stopper” is identified that would prevent future generations from using H2FC buses in public transport on a broad scale due to damage to the environment or to other factors that impinge on quality of life.
Flexible Electricity Use for Heating in Markets with Renewable Energy
Mar 2020
Publication
Using electricity for heating can contribute to decarbonization and provide flexibility to integrate variable renewable energy. We analyze the case of electric storage heaters in German 2030 scenarios with an open-source electricity sector model. We find that flexible electric heaters generally increase the use of generation technologies with low variable costs which are not necessarily renewables. Yet making customary night-time storage heaters temporally more flexible offers only moderate benefits because renewable availability during daytime is limited in the heating season. Respective investment costs accordingly have to be very low in order to realize total system cost benefits. As storage heaters feature only short-term heat storage they also cannot reconcile the seasonal mismatch of heat demand in winter and high renewable availability in summer. Future research should evaluate the benefits of longer-term heat storage.
Exergetic Aspects of Hydrogen Energy Systems—The Case Study of a Fuel Cell Bus
Feb 2017
Publication
Electrifying transportation is a promising approach to alleviate climate change issues arising from increased emissions. This study examines a system for the production of hydrogen using renewable energy sources as well as its use in buses. The electricity requirements for the production of hydrogen through the electrolysis of water are covered by renewable energy sources. Fuel cells are being used to utilize hydrogen to power the bus. Exergy analysis for the system is carried out. Based on a steady-state model of the processes exergy efficiencies are calculated for all subsystems. The subsystems with the highest proportion of irreversibility are identified and compared. It is shown that PV panel has exergetic efficiency of 12.74% wind turbine of 45% electrolysis of 67% and fuel cells of 40%.
Micro Gas Turbine Role in Distributed Generation with Renewable Energy Sources
Jan 2023
Publication
To become sustainable the production of electricity has been oriented towards the adoption of local and renewable sources. Distributed electric and thermal energy generation is more suitable to avoid any possible waste and the Micro Gas Turbine (MGT) can play a key role in this scenario. Due to the intrinsic properties and the high flexibility of operation of this energy conversion system the exploitation of alternative fuels and the integration of the MGT itself with other energy conversion systems (solar field ORC fuel cells) represent one of the most effective strategies to achieve higher conversion efficiencies and to reduce emissions from power systems. The present work aims to review the results obtained by the researchers in the last years. The different technologies are analyzed in detail both separately and under a more complete view considering two or more solutions embedded in micro-grid configurations.
Impacts of Load Profiles on the Optimization of Power Management of a Green Building Employing Fuel Cells
Dec 2018
Publication
This paper discusses the performance improvement of a green building by optimization procedures and the influences of load characteristics on optimization. The green building is equipped with a self-sustained hybrid power system consisting of solar cells wind turbines batteries proton exchange membrane fuel cell (PEMFC) electrolyzer and power electronic devices. We develop a simulation model using the Matlab/SimPowerSystemTM and tune the model parameters based on experimental responses so that we can predict and analyze system responses without conducting extensive experiments. Three performance indexes are then defined to optimize the design of the hybrid system for three typical load profiles: the household the laboratory and the office loads. The results indicate that the total system cost was reduced by 38.9% 40% and 28.6% for the household laboratory and office loads respectively while the system reliability was improved by 4.89% 24.42% and 5.08%. That is the component sizes and power management strategies could greatly improve system cost and reliability while the performance improvement can be greatly influenced by the characteristics of the load profiles. A safety index is applied to evaluate the sustainability of the hybrid power system under extreme weather conditions. We further discuss two methods for improving the system safety: the use of sub-optimal settings or the additional chemical hydride. Adding 20 kg of NaBH4 can provide 63 kWh and increase system safety by 3.33 2.10 and 2.90 days for the household laboratory and office loads respectively. In future the proposed method can be applied to explore the potential benefits when constructing customized hybrid power systems.
Integrated Energy System Powered a Building in Sharjah Emirates in the United Arab Emirates
Jan 2023
Publication
In this study a green hydrogen system was studied to provide electricity for an office building in the Sharjah emirate in the United Arab Emirates. Using a solar PV a fuel cell a diesel generator and battery energy storage; a hybrid green hydrogen energy system was compared to a standard hybrid system (Solar PV a diesel generator and battery energy storage). The results show that both systems adequately provided the power needed for the load of the office building. The cost of the energy for both the basic and green hydrogen energy systems was 0.305 USD/kWh and 0.313 USD/kWh respectively. The cost of the energy for both systems is very similar even though the capital cost of the green hydrogen energy system was the highest value; however the replacement and operational costs of the basic system were higher in comparison to the green hydrogen energy system. Moreover the impact of the basic system in terms of the carbon footprint was more significant when compared with the green hydrogen system. The reduction in carbon dioxide was a 4.6 ratio when compared with the basic system.
Solid-State Hydrogen Fuel by PSII–Chitin Composite and Application to Biofuel Cell
Dec 2021
Publication
Biomaterials attract a lot of attention as next-generation materials. Especially in the energy field fuel cells based on biomaterials can further develop clean next-generation energy and are focused on with great interest. In this study solid-state hydrogen fuel (PSII–chitin composite) composed of the photosystem II (PSII) and hydrated chitin composite was successfully created. Moreover a biofuel cell consisting of the electrolyte of chitin and the hydrogen fuel using the PSII– chitin composite was fabricated and its characteristic feature was investigated. We found that proton conductivity in the PSII–chitin composite increases by light irradiation. This result indicates that protons generate in the PSII–chitin composite by light irradiation. It was also found that the biofuel cell using the PSII–chitin composite hydrogen fuel and the chitin electrolyte exhibits the maximum power density of 0.19 mW/cm2 . In addition this biofuel cell can drive an LED lamp. These results indicate that the solid-state biofuel cell based on the bioelectrolyte “chitin” and biofuel “the PSII–chitin composite” can be realized. This novel solid-state fuel cell will be helpful to the fabrication of next-generation energy.
Hydrogen-powered Aviation and its Reliance on Green Hydrogen Infrastructure - Review and Research Gaps
Oct 2021
Publication
Aircraft powered by green hydrogen (H2) are a lever for the aviation sector to reduce the climate impact. Previous research already focused on evaluations of H2 aircraft technology but analyses on infrastructure related cost factors are rarely undertaken. Therefore this paper aims to provide a holistic overview of previous efforts and introduces an approach to assess the importance of a H2 infrastructure for aviation. A short and a medium-range aircraft are modelled and modified for H2 propulsion. Based on these a detailed cost analysis is used to compare both aircraft and infrastructure related direct operating costs (DOC). Overall it is shown that the economy of H2 aviation highly depends on the availability of low-cost green liquid hydrogen (LH2) supply infrastructure. While total DOC might even slightly decrease in a best LH2 cost case total DOC could also increase between 10 and 70% (short-range) and 15e102% (medium-range) due to LH2 costs alone.
Numerical Study on Tri-fuel Combustion: Ignition Properties of Hydrogen-enriched Methane-diesel and Methanol-diesel Mixtures
Jan 2020
Publication
Simultaneous and interactive combustion of three fuels with differing reactivities is investigated by numerical simulations. In the present study conventional dual-fuel (DF) ignition phenomena relevant to DF compression ignition (CI) engines are extended and explored in tri-fuel (TF) context. In the present TF setup a low reactivity fuel (LRF) methane or methanol is perfectly mixed with hydrogen and air to form the primary fuel blend at the lean equivalence ratio of 0.5. Further such primary fuel blends are ignited by a high-reactivity fuel (HRF) here n-dodecane under conditions similar to HRF spray assisted ignition. Here ignition is relevant to the HRF containing parts of the tri-fuel mixtures while flame propagation is assumed to occur in the premixed LRF/ containing end gas regions. The role of hydrogen as TF mixture reactivity modulator is explored. Mixing is characterized by n-dodecane mixture fraction ξ and molar ratio . When x < 0.6 minor changes are observed for the first- and second-stage ignition delay time (IDT) of tri-fuel compared to dual-fuel blends (x = 0). For methane when x > 0.6 first- and second-stage IDT increase by factor 1.4–2. For methanol a respective decrease by factor 1.2–2 is reported. Such contrasting trends for the two LRFs are explained by reaction sensitivity analysis indicating the importance of OH radical production/consumption in the ignition process. Observations on LRF/ end gas laminar flame speed () indicate that increases with x due to the highly diffusive features of . For methane increase with x is more significant than for methanol.
Integrating Housing Stock and Energy System Models as a Strategy to Improve Heat Decarbonisation Assessments
Aug 2014
Publication
The UK government heat strategy is partially based on decarbonisation pathways from the UK MARKAL energy system model. We review how heat provision is represented in UK MARKAL identifying a number of shortcomings and areas for improvement. We present a completely revised model with improved estimations of future heat demands and a consistent representation of all heat generation technologies. This model represents all heat delivery infrastructure for the first time and uses dynamic growth constraints to improve the modelling of transitions according to innovation theory. Our revised model incorporates a simplified housing stock model which is used produce highly-refined decarbonisation pathways for residential heat provision. We compare this disaggregated model against an aggregated equivalent which is similar to the existing approach in UK MARKAL. Disaggregating does not greatly change the total residential fuel consumption in two scenarios so the benefits of disaggregation will likely be limited if the focus of a study is elsewhere. Yet for studies of residential heat disaggregation enables us to vary consumer behaviour and government policies on different house types as well as highlighting different technology trends across the stock in comparison with previous aggregated versions of the model.
Regional Uptake of Direct Reduction Iron Production Using Hydrogen Under Climate Policy
Nov 2022
Publication
The need to reduce CO2 emissions to zero by 2050 has meant an increasing focus on high emitting industrial sectors such as steel. However significant uncertainties remain as to the rate of technology diffusion across steel production pathways in different regions and how this might impact on climate ambition. Informed by empirical analysis of historical transitions this paper presents modelling on the regional deployment of Direction Reduction Iron using hydrogen (DRI-H2). We find that DRI-H2 can play a leading role in the decarbonisation of the sector leading to near-zero emissions by 2070. Regional spillovers from early to late adopting regions can speed up the rate of deployment of DRI-H2 leading to lower cumulative emissions and system costs. Without such effects cumulative emissions are 13% higher than if spillovers are assumed and approximately 15% and 20% higher in China and India respectively. Given the estimates of DRI-H2 cost-effectiveness relative to other primary production technologies we also find that costs increase in the absence of regional spillovers. However other factors can also have impacts on deployment emission reductions and costs including the composition of the early adopter group material efficiency improvements and scrap recycling rates. For the sector to achieve decarbonisation key regions will need to continue to invest in low carbon steel projects recognising their broader global benefit and look to develop and strengthen policy coordination on technologies such as DRI-H2.
Integrating a Top-Gas Recycling and CO2 Electrolysis Process for H2-Rich Gas Injection and Reduce CO2 Emissions from an Ironmaking Blast Furnace
Mar 2022
Publication
Introducing CO2 electrochemical conversion technology to the iron-making blast furnace not only reduces CO2 emissions but also produces H2 as a byproduct that can be used as an auxiliary reductant to further decrease carbon consumption and emissions. With adequate H2 supply to the blast furnace the injection of H2 is limited because of the disadvantageous thermodynamic characteristics of the H2 reduction reaction in the blast furnace. This paper presents thermodynamic analysis of H2 behaviour at different stages with the thermal requirement consideration of an iron-making blast furnace. The effect of injecting CO2 lean top gas and CO2 conversion products H2–CO gas through the raceway and/or shaft tuyeres are investigated under different operating conditions. H2 utilisation efficiency and corresponding injection volume are studied by considering different reduction stages. The relationship between H2 injection and coke rate is established. Injecting 7.9–10.9 m3/tHM of H2 saved 1 kg/tHM coke rate depending on injection position. Compared with the traditional blast furnace injecting 80 m3/tHM of H2 with a medium oxygen enrichment rate (9%) and integrating CO2 capture and conversion reduces CO2 emissions from 534 to 278 m3/tHM. However increasing the hydrogen injection amount causes this iron-making process to consume more energy than a traditional blast furnace does.
Evolutions in Hydrogen and Fuel Cell Standardization: The HarmonHy Experience
Dec 2007
Publication
HarmonHy is a European Union-funded Specific Support Action aiming to make an assessment of the activities on hydrogen and fuel cell regulations codes and standards (RCS) on a worldwide level. On this basis gaps have been identified and potential conflicts between regulations codes and standards have been investigated. Types of document to be referred to include international regional and national standards EU directives UNECE regulations… Particular attention will be paid to the identification of the needs for standards as perceived by the industry as well as to actions aiming to ensure concordance between standards codes and regulations. Standards and regulations require harmonization. HarmonHy pursues the elaboration of an action plan and a roadmap for future work on harmonizing regulations codes and standards on hydrogen and fuel cells on an international level.
Review of the Liquid Hydrogen Storage Tank and Insulation System for the High-Power Locomotive
Jun 2022
Publication
Hydrogen has been attracting attention as a fuel in the transportation sector to achieve carbon neutrality. Hydrogen storage in liquid form is preferred in locomotives ships drones and aircraft because these require high power but have limited space. However liquid hydrogen must be in a cryogenic state wherein thermal insulation is a core problem. Inner materials including glass bubbles multi-layer insulation (MLI) high vacuum and vapor-cooled shields are used for thermal insulation. An analytic study is preferred and proceeds liquid hydrogen tanks due to safety regulations in each country. This study reviewed the relevant literature for thermodynamic modeling. The literature was divided into static dynamic and systematic studies. In summary the authors summarized the following future research needs: The optimal design of the structure including suspension baffle and insulation system can be studied to minimize the boil-off gas (BOG). A dynamic study of the pressure mass flow and vaporizer can be completed. The change of the components arrangement from the conventional diesel–electric locomotive is necessary.
Fuel Cell Solution for Marine Applications
Sep 2021
Publication
With future regulations on the horizon port authorities and ship owners/operators are looking at alternative propulsion solutions to reduce emission. Fuel cell technology provides an attractive zeroemission solution to generate electric power on board using hydrogen as a fuel. Fuel cell systems are scalable from 200kW to multi-MW providing high efficiency dispatchable clean quiet power generation. Several innovative pilot projects are on the way to demonstrate the marine application of this proven technology. Electrification of propulsion systems is advancing and fuel cell technology provides the opportunity to produce on board large quantity of power with zero-emission using hydrogen as a fuel. We will present the value proposition of having a fuel cell power generator on board of an electric vessel while discussing the safety considerations with the fuel cell module and the onboard fuel storage. We will present some of our current fuel cell marine projects and review some of the product development considerations including system architecture and safety as well as hydrogen supply and on-board fuel storage.
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