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The Hydrogen Bike: Communicating the Production and Safety of Green Hydrogen
Mar 2021
Publication
As the international community aims to reduce its reliance on fossil fuels green hydrogen has great potential to replace methane as a clean source of fuel. A novel public engagement activity The Hydrogen Bike has been developed to demonstrate the production and use of green hydrogen from water. The aim of the activity is to educate entertain and inform young people and adults so that they have an opportunity to form an opinion about the use of hydrogen as a fuel. Using a novel two-part data collection system participants are briefly surveyed for their opinion on hydrogen before and after participating in The Hydrogen Bike activity. Through this we have found that most participants (73%) are considered to have no opinion or a neutral opinion on hydrogen before participating in The Hydrogen Bike activity. After participation 88% of those who were originally neutral or had no opinion on hydrogen self-reported a positive feeling about hydrogen. The method of data collection was quick intuitive and suitable for an audience attracted from passing footfall.
Assessing the Social Acceptance of Key Technologies for the German Energy Transition
Jan 2022
Publication
Background: The widespread use of sustainable energy technologies is a key element in the transformation of the energy system from fossil-based to zero-carbon. In line with this technology acceptance is of great importance as resistance from the public can slow down or hinder the construction of energy technology projects. The current study assesses the social acceptance of three energy technologies relevant for the German energy transition: stationary battery storage biofuel production plants and hydrogen fuel station. Methods: An online survey was conducted to examine the public’s general and local acceptance of energy technologies. Explored factors included general and local acceptance public concerns trust in relevant stakeholders and attitudes towards financial support. Results: The results indicate that general acceptance for all technologies is slightly higher than local acceptance. In addition we discuss which public concerns exist with regard to the respective technologies and how they are more strongly associated with local than general acceptance. Further we show that trust in stakeholders and attitudes towards fnancial support is relatively high across the technologies discussed. Conclusions: Taken together the study provides evidence for the existence of a “general–local” gap despite measuring general and local acceptance at the same level of specifcity using a public sample. In addition the collected data can provide stakeholders with an overview of worries that might need to be addressed when planning to implement a certain energy project.
Life Cycle Cost Analysis for Scotland Short-Sea Ferries
Feb 2023
Publication
The pathway to zero carbon emissions passing through carbon emissions reduction is mandatory in the shipping industry. Regarding the various methodologies and technologies reviewed for this purpose Life Cycle Cost Analysis (LCCA) has been used as an excellent tool to determine economic feasibility and sustainability and to present directions. However insufficient commercial applications cause a conflict of opinion on which fuel is the key to decarbonisation. Many LCCA comparison studies about eco-friendly ship propulsion claim different results. In order to overcome this and discover the key factors that affect the overall comparative analysis and results in the maritime field it is necessary to conduct the comparative analysis considering more diverse case ships case routes and various types that combine each system. This study aims to analyse which greener fuels are most economically beneficial for the shipping sector and prove the factors influencing different results in LCCA. This study was conducted on hydrogen ammonia and electric energy which are carbon-free fuels among various alternative fuels that are currently in the limelight. As the power source a PEMFC and battery were used as the main power source and a solar PV system was installed as an auxiliary power source to compare economic feasibility. Several cost data for LCCA were selected from various feasible case studies. As the difficulty caused by the storage and transportation of hydrogen and ammonia should not be underestimated in this study the LCCA considers not only the CapEx and OpEx but also fuel transport costs. As a result fuel cell propulsion systems with hydrogen as fuel proved financial effectiveness for short-distance ferries as they are more inexpensive than ammonia-fuelled PEMFCs and batteries. The fuel cost takes around half of the total life-cycle cost during the life span.
Forecasting Hydrogen Production from Wind Energy in a Suburban Environment Using Machine Learning
Nov 2022
Publication
The environment is seriously threatened by the rising energy demand and the use of conventional energy sources. Renewable energy sources including hydro solar and wind have been the focus of extensive research due to the proliferation of energy demands and technological advancement. Wind energy is mostly harvested in coastal areas and little work has been done on energy extraction from winds in a suburban environment. The fickle behavior of wind makes it a less attractive renewable energy source. However an energy storage method may be added to store harvested wind energy. The purpose of this study is to evaluate the feasibility of extracting wind energy in terms of hydrogen energy in a suburban environment incorporating artificial intelligence techniques. To this end a site was selected latitude 33.64◦ N longitude 72.98◦ N and elevation 500 m above mean sea level in proximity to hills. One year of wind data consisting of wind speed wind direction and wind gust was collected at 10 min intervals. Subsequently long short-term memory (LSTM) support vector regression (SVR) and linear regression models were trained on the empirically collected data to estimate daily hydrogen production. The results reveal that the overall prediction performance of LSTM was best compared to that of SVR and linear regression models. Furthermore we found that an average of 6.76 kg/day of hydrogen can be produced by a 1.5 MW wind turbine with the help of an artificial intelligence method (LSTM) that is well suited for time-series data to classify process and predict.
Optimal Planning of Hybrid Electricity–Hydrogen Energy Storage System Considering Demand Response
Mar 2023
Publication
In recent years the stability of the distribution network has declined due to the large proportion of the uses of distributed generation (DG) with the continuous development of renewable energy power generation technology. Meanwhile the traditional distribution network operation mode cannot keep the balance of the source and load. The operation mode of the active distribution network (ADN) can effectively reduce the decline in operation stability caused by the high proportion of DG. Therefore this work proposes a bi-layer model for the planning of the electricity–hydrogen hybrid energy storage system (ESS) considering demand response (DR) for ADN. The upper layer takes the minimum load fluctuation maximum user purchase cost satisfaction and user comfort as the goals. Based on the electricity price elasticity matrix model the optimal electricity price formulation strategy is obtained for the lower ESS planning. In the lower layer the optimal ESS planning scheme is obtained with the minimum life cycle cost (LCC) of ESS the voltage fluctuation of ADN and the load fluctuation as the objectives. Finally the MOPSO algorithm is used to test the model and the correctness of the proposed method is verified by the extended IEEE-33 node test system. The simulation results show that the fluctuation in the voltage and load is reduced by 62.13% and 37.06% respectively.
ASSET Study on Geolocation of Hydrogen Production in the EU
Oct 2021
Publication
The modelling underpinning the scenarios for the EU long-term strategy did not include hydrogen trade. The assumption was that each Member State (MS) supplies its own needs for hydrogen and synthetic fuels. The goal of this study is to develop a model to undertake optimal geolocation of hydrogen production between MS including the possibility to trade hydrogen and therefore use the RES potential more optimally and decrease energy system costs at EU level. Specifically the new model helps to identify the geo-location of: 1. Renewable energy production (PV wind biomass hydro) 2. Location of RES and hydrogen production facilities 3. Storage infrastructure also for natural gas and storage technologies i.e. batteries pumping etc. 4. Infrastructure by road and pipeline
Review of Energy Portfolio Optimization in Energy Markets Considering Flexibility of Power-to-X
Mar 2023
Publication
Power-to-X is one of the most attention-grabbing topics in the energy sector. Researchers are exploring the potential of harnessing power from renewable technologies and converting it into fuels used in various industries and the transportation sector. With the current market and research emphasis on Power-to-X and the accompanying substantial investments a review of Power-to-X is becoming essential. Optimization will be a crucial aspect of managing an energy portfolio that includes Power-to-X and electrolysis systems as the electrolyzer can participate in multiple markets. Based on the current literature and published reviews none of them adequately showcase the state-of-the-art optimization algorithms for energy portfolios focusing on Power-to-X. Therefore this paper provides an in-depth review of the optimization algorithms applied to energy portfolios with a specific emphasis on Power-to-X aiming to uncover the current state-of-the-art in the field.
Power-to-gas and the Consequences: Impact of Higher Hydrogen Concentrations in Natural Gas on Industrial Combustion Processes
Sep 2017
Publication
Operators of public electricity grids today are faced with the challenge of integrating increasing numbers of renewable and decentralized energy sources such as wind turbines and photovoltaic power plants into their grids. These sources produce electricity in a very inconstant manner due to the volatility of wind and solar power which further complicates power grid control and management. One key component that is required for modern energy infrastructures is the capacity to store large amounts of energy in an economically feasible way.<br/>One solution that is being discussed in this context is “power-to-gas” i.e. the use of surplus electricity to produce hydrogen (or even methane with an additional methanation process) which is then injected into the public natural gas grid. The huge storage capacity of the gas grid would serve as a buffer offering benefits with regards to sustainability and climate protection while also being cost-effective since the required infrastructure is already in place.<br/>One consequence would be however that the distributed natural gas could contain larger and fluctuating amounts of hydrogen. There is some uncertainty how different gas-fired applications and processes react to these changes. While there have already been several investigations for domestic appliances (generally finding that moderate amounts of H2 do not pose any safety risks which is the primary focus of domestic gas utilization) there are still open questions concerning large-scale industrial gas utilization. Here in addition to operational safety factors like efficiency pollutant emissions (NOX) process stability and of course product quality have to be taken into account.<br/>In a German research project Gas- und Wärme-Institut Essen e. V. (GWI) investigated the impact of higher and fluctuating hydrogen contents (up to 50 vol.-% much higher than what is currently envisioned) on a variety of industrial combustion systems using both numerical and experimental methods. The effects on operational aspects such as combustion behavior flame monitoring and pollutant emissions were analyzed.<br/>Some results of these investigations will be presented in this contribution.
Fuel Cell Hybrid Model for Predicting Hydrogen Inflow through Energy Demand
Nov 2019
Publication
Hydrogen-based energy storage and generation is an increasingly used technology especially in renewable systems because they are non-polluting devices. Fuel cells are complex nonlinear systems so a good model is required to establish efficient control strategies. This paper presents a hybrid model to predict the variation of H2 flow of a hydrogen fuel cell. This model combining clusters’ techniques to get multiple Artificial Neural Networks models whose results are merged by Polynomial Regression algorithms to obtain a more accurate estimate. The model proposed in this article use the power generated by the fuel cell the hydrogen inlet flow and the desired power variation to predict the necessary variation of the hydrogen flow that allows the stack to reach the desired working point. The proposed algorithm has been tested on a real proton exchange membrane fuel cell and the results show a great precision of the model so that it can be very useful to improve the efficiency of the fuel cell system.
A Review on Experimental Studies Investigating the Effect of Hydrogen Supplementation in CI Diesel Engines—The Case of HYMAR
Aug 2022
Publication
Hydrogen supplementation in diesel Compression Ignition (CI) engines is gaining more attention since it is considered as a feasible solution to tackle the challenges that are related to the emission regulations that will be applied in the forthcoming years. Such a solution is very attractive because it requires only limited modifications to the existing technology of internal combustion CI engines. To this end numerous work on the investigation of an engine’s performance and the effects of emissions when hydrogen is supplied in the engine’s cylinders has been completed by researchers. However contradictory results were found among these studies regarding the efficiency of the engine and the emission characteristics achieved compared to the diesel-only operation. The different conclusions might be attributed to the different characteristics and technology level of the engines that were utilized as well as on the chosen operational parameters. This paper aims to present an overview of the experimental studies that have examined the effects of hydrogen addition in CI four-stroke diesel engines reporting the characteristics of the utilized engines the quantities of hydrogen tested the method of hydrogen induction used as well as the operational conditions tested in order to help interested researchers to easily identify relevant and appropriate studies to perform comparisons or validations by repeating certain cases. The presented data do not include any results or conclusions from these studies. Furthermore an experimental configuration along with the appropriate modifications on a heavy-duty auxiliary generator-set engine that was recently developed by the authors for the purposes of the HYMAR project is presented.
Low-carbon Economic Dispatch of Power Systems Based on Mobile Hydrogen Storage
Mar 2022
Publication
To alleviate the global warming crisis carbon reduction is an inevitable trend of sustainable development. The energy carrier with Hydrogen (H2) is considered to be one of the promising choices for realizing a low-carbon economy. With the increasing penetration level of wind power generation and for well-balancing wind generation fluctuations this paper proposes a low-carbon economic dispatch method for power systems based on mobile hydrogen storage(MHS). The wind power surplus during off-peak load periods is first utilized to generate green H2. Afterward the green H2 is optimally transported to multiple hydrogen storage(HS) stations for generating power electricity by flexibly controlling the electrolysis(EL) methanation(ME) carbon capture(CCS) and H2 power generation processes in such a way the wind power is coordinated with the hydrogen production transport and utilization to reduce the total carbon emission and minimize the operation cost of power systems. Finally the proposed power system low-carbon economic dispatch model is verified by case studies.
Hybrid PEM Fuel Cell Power Plants Fuelled by Hydrogen for Improving Sustainability in Shipping: State of the Art and Review on Active Projects
Feb 2023
Publication
The interest in hybrid polymer electrolyte membrane fuel cells (PEMFC) fuelled by hydrogen in shipping has seen an unprecedented growth in the last years as it could allow zero-emission navigation. However technical safety and regulatory barriers in PEMFC ship design and operation are hampering the use of such systems on a large scale. While several studies analyse these aspects a comprehensive and up-to-date overview on hydrogen PEMFCs for shipping is missing. Starting from the survey of past/ongoing projects on FCs in shipping this paper presents an extensive review on maritime hydrogen PEMFCs outlining the state of the art and future trends for hydrogen storage and bunkering powertrain and regulations. In addition to the need for a clear regulatory framework future studies should investigate the development of an efficient fuel supply chain and bunkering facilities ashore. As for the onboard power system health-conscious energy management low-temperature heat recovery and advancements in fuel processing have emerged as hot research topics.
Multi-Objective Optimization-Based Health-Conscious Predictive Energy Management Strategy for Fuel Cell Hybrid Electric Vehicles
Feb 2022
Publication
The Energy Management Strategy (EMS) in Fuel Cell Hybrid Electric Vehicles (FCHEVs) is the key part to enhance optimal power distribution. Indeed the most recent works are focusing on optimizing hydrogen consumption without taking into consideration the degradation of embedded energy sources. In order to overcome this lack of knowledge this paper describes a new health-conscious EMS algorithm based on Model Predictive Control (MPC) which aims to minimize the battery degradation to extend its lifetime. In this proposed algorithm the health-conscious EMS is normalized in order to address its multi-objective optimization. Then weighting factors are assigned in the objective function to minimize the selected criteria. Compared to most EMSs based on optimization techniques this proposed approach does not require any information about the speed profile which allows it to be used for real-time control of FCHEV. The achieved simulation results show that the proposed approach reduces the economic cost up to 50% for some speed profile keeping the battery pack in a safe range and significantly reducing energy sources degradation. The proposed health-conscious EMS has been validated experimentally and its online operation ability clearly highlighted on a PEMFC delivery postal vehicle.
Advances in Hydrogen Production from Natural Gas Reforming
Jun 2021
Publication
Steam natural gas reforming is the preferred technique presently used to produce hydrogen. Proposed in 1932 the technique is very well established but still subjected to perfections. Herein first the improvements being sought in catalysts and processes are reviewed and then the advantage of replacing the energy supply from burning fuels with concentrated solar energy is discussed. It is especially this advance that may drastically reduce the economic and environmental cost of hydrogen production. Steam reforming can be easily integrated into concentrated solar with thermal storage for continuous hydrogen production.
Electric Aircraft Fueled by Liquid Hydrogen and Liquefied Natural Gas
Jul 2021
Publication
The paper is a review of the opportunities and challenges of cryogenic power devices of electric aircraft and the ongoing research and development efforts of the government agencies and the industry. Liquid Hydrogen (LH2) and Liquefied Natural Gas (LNG) are compared to support high temperature superconducting (HTS) and normal metal devices respectively. The power devices were assumed to operate at the normal boiling point of the fuel used. The efficiencies of the electrical devices are estimated based on state-of-the-art technology. The mass flow rates and total fuel requirements for both the cryogenic fuels required to maintain the operating temperatures of the devices were simulated using thermal network models. A twin-aisle 300 passenger aircraft with a 5.5 h flight duration was used for the models. The results show that the required masses of LH2 and LNG are 744 kg and 13638 kg respectively for the cooling requirement. The corresponding volumes of LH2 and LNG required are 9760 and 30300 L respectively. In both cases the estimated mass of the fuel needed for the aircraft is more than what is needed to maintain the cryogenic environment of the power devices. It was concluded that an electric aircraft with LNG cooled normal metal devices is feasible. However an aircraft with HTS devices and cooled with LH2 is more attractive if the ongoing R&D efforts on HTS devices and LH2 infrastructure are successful. The emission reductions would be substantially higher with LH2 particularly when H2 is produced using renewable energy sources.
Stoichiometric Equilibrium Model based Assessment of Hydrogen Generation through Biomass Gasification
Sep 2016
Publication
Hydrogen produced from renewable energy sources is clean and sustainable. Biomass gasification has a significant role in the context of hydrogen generation from biomass. Assessment of the performance of biomass gasification process regarding the product gas yield and composition can be performed using mathematical models. Among the different mathematical models thermodynamic equilibrium models are simple and useful tools for the first estimate and preliminary comparison and assessment of gasification process. A stoichiometric thermodynamic equilibrium model is developed here and its performance is validated for steam gasification and air-steam gasification. The model is then used to assess the feasibility of different biomass feedstock for gasification based on hydrogen yield and lower heating value.
Performance of Three Typical Domestic Gas Stoves Operated with Methane-hydrogen Mixture
Dec 2022
Publication
Hydrogen blending into natural gas has attracted significant attention in domestic applications. The paper studied the effects of natural gas mixed with hydrogen at 0% (vol) 5% 10% 15% 20% and 25% on the performance of typical round-port gas stove (TRPGS) swirling strip-port gas stove (SSPGS) and radiant porous media gas stove (RPMGS). The experimental results show that flame length shortens with the increase of hydrogen proportion and the combustion remains stable when the hydrogen proportion is equal to or less than 25%. With increasing hydrogen proportion the measured heat inputs of the three types of domestic gas stoves decrease gradually and the average thermal efficiency of TRPGS and SSPGS increase by 0.82% and 1.18% respectively. In addition the average efficiency of the RPMGS first increases by 1.35% under a hydrogen proportion of 15% and then decreases by 1.36% under a hydrogen proportion of 25%. In terms of flue gas emission CO emission reduces significantly with increasing hydrogen proportion while NOX emissions remain almost unchanged.
Cost and Thermodynamic Analysis of Wind-Hydrogen Production via Multi-energy Systems
Mar 2024
Publication
With rising temperatures extreme weather events and environmental challenges there is a strong push towards decarbonization and an emphasis on renewable energy with wind energy emerging as a key player. The concept of multi-energy systems offers an innovative approach to decarbonization with the potential to produce hydrogen as one of the output streams creating another avenue for clean energy production. Hydrogen has significant potential for decarbonizing multiple sectors across buildings transport and industries. This paper explores the integration of wind energy and hydrogen production particularly in areas where clean energy solutions are crucial such as impoverished villages in Africa. It models three systems: distinct configurations of micro-multi-energy systems that generate electricity space cooling hot water and hydrogen using the thermodynamics and cost approach. System 1 combines a wind turbine a hydrogen-producing electrolyzer and a heat pump for cooling and hot water. System 2 integrates this with a biomass-fired reheat-regenerative power cycle to balance out the intermittency of wind power. System 3 incorporates hydrogen production a solid oxide fuel cell for continuous electricity production an absorption cooling system for refrigeration and a heat exchanger for hot water production. These systems are modeled with Engineering Equation Solver and analyzed based on energy and exergy efficiencies and on economic metrics like levelized cost of electricity (LCOE) cooling (LCOC) refrigeration (LCOR) and hydrogen (LCOH) under steady-state conditions. A sensitivity analysis of various parameters is presented to assess the change in performance. Systems were optimized using a multiobjective method with maximizing exergy efficiency and minimizing total product unit cost used as objective functions. The results show that System 1 achieves 79.78 % energy efficiency and 53.94 % exergy efficiency. System 2 achieves efficiencies of 55.26 % and 27.05 % respectively while System 3 attains 78.73 % and 58.51 % respectively. The levelized costs for micro-multi-energy System 1 are LCOE = 0.04993 $/kWh LCOC = 0.004722 $/kWh and LCOH = 0.03328 $/kWh. For System 2 these values are 0.03653 $/kWh 0.003743 $/kWh and 0.03328 $/kWh. In the case of System 3 they are 0.03736 $/kWh 0.004726 $/kWh and 0.03335 $/kWh and LCOR = 0.03309 $/kWh. The results show that the systems modeled here have competitive performance with existing multi-energy systems powered by other renewables. Integrating these systems will further the sustainable and net zero energy system transition especially in rural communities.
Everything About Hydrogen Podcast: A Green Future for Oman
Feb 2023
Publication
On this episode of Everything About Hydrogen we are speaking with Nashwa Al Rawahy Director of HMR Environmental Consultants based in Muscat Oman with regional offices in the United Arab Emirates.
We are excited to have an expert like Nashwa join us to discuss environmental and social impact studies their value to the communities and projects and the importance of building long term In Country Value (ICV).
The podcast can be found on their website.
We are excited to have an expert like Nashwa join us to discuss environmental and social impact studies their value to the communities and projects and the importance of building long term In Country Value (ICV).
The podcast can be found on their website.
Hydrogen-Fuel Cell Hybrid Powertrain: Conceptual Layouts and Current Applications
Nov 2022
Publication
Transportation is one of the largest sources of CO2 emissions accounting for more than 20% of worldwide emissions. However it is one of the areas where decarbonization presents the greatest hurdles owing to its capillarity and the benefits that are associated with the use of fossil fuels in terms of energy density storage and transportation. In order to accomplish comprehensive decarbonization in the transport sector it will be required to encourage a genuine transition to low-carbon fuels and the widespread deployment of the necessary infrastructures to allow for a large-scale innovation. Renewable hydrogen shows potential for sustainable transportation applications whether in fuel cell electric vehicles (FCEVs) such as automobiles trucks and trains or as a raw material for ship and airplane synthetic fuels. The present paper aims to present how hydrogen-fuel cell hybrid powertrains for road vehicles work in terms of conceptual layouts and operating strategies. A comprehensive overview of real and current applications is presented concerning existing prototypes and commercially available vehicles with a focus on the main key performance indicators such as efficiency mileage and energy consumption.
A Hydrogen-fuelled Compressed Air Energy Storage System for Flexibility Reinforcement and Variable Renewable Energy Integration in Grids with High Generation Curtailment
Mar 2024
Publication
Globally the increasing share of renewables prominently driven by intermittent sources such as solar and wind power poses significant challenges to the reliability of current electrical infrastructures leading to the adoption of extreme measures such as generation curtailment to preserve grid security. Within this framework it is essential to develop energy storage systems that contribute to reinforce the flexibility and security of power grids while simultaneously reducing the share of generation curtailment. Therefore this study investigates the performance of an integrated photovoltaic-hydrogen fuelled-compressed air energy storage system whose configuration is specifically conceived to enable the connection of additional intermittent sources in already saturated grids. The yearly and seasonal performance of the integrated energy storage system specifically designed to supply flexibility services are evaluated for a scenario represented by a real grid with high-variable renewables penetration and frequent dispatchability issues. Results show that the integrated system with performanceoptimized components and a new energy management strategy minimizes photovoltaic energy curtailment otherwise around 50% to as low as 4% per year achieving system efficiencies of up to 62% and reinforces the grid by supplying inertial power for up to 20% of nighttime hours. In conclusion the integrated plant operating with zero emissions on-site hydrogen production and optimized for non-dispatchable photovoltaic energy utilization proves to be effective in integrating new variable renewable sources and reinforcing saturated grids particularly during spring and summer.
Prospective Roles for Green Hydrogen as Part of Ireland's Decarbonisation Strategy
Mar 2023
Publication
In recent decades governments and society have been making increasing efforts to address and mitigate climate change by reducing emissions and decarbonising energy generation. Ireland has invested greatly in renewable electricity installing 4 GW of wind capacity since 2002 and has set assertive energy targets such as the aim to reduce overall emissions by 51% by 2030. Nonetheless considerable acceleration is needed in the decarbonisation of the country’s energy sector. This paper investigates the potential role hydrogen can play in Ireland’s energy transition proposing hydrogen as an energy vector and storage medium that may help the country achieve its targets and reduce greenhouse gas emissions. Through literature review research and from industry insights the current state of the Irish energy sector is analysed and recommendations are made as to how where and when hydrogen can be integrated into the decarbonisation of Ireland’s electricity heating and transport. It is concluded that; with significant effort from the government policymakers industry and organisations; the effective deployment of hydrogen technologies in Ireland could avoid up to 6.1 MtCO2eq of emissions annually reflecting a trend observed in many other developed countries in which hydrogen plays an important part in the path to a low-carbon future. Prospective roles for hydrogen in Ireland include renewable energy storage and grid balancing through the deployment of Power-to-Gas systems a replacement for fossil natural gas in the gas grid for backup electricity production as well as industry and heating requirements and the use of hydrogen as a fuel for heavy transport.
Brief Review on High-Temperature Electrochemical Hydrogen Sensors
Dec 2022
Publication
Hydrogen sensors especially those operating at high temperatures are essential tools for the emerging hydrogen economy. Monitoring hydrogen under process conditions to control the reactions for detecting confined species is crucial to the safe widespread use and public acceptance of hydrogen as fuel. Hydrogen sensors must have a sensitivity ranging from traces of hydrogen (parts per million (ppm)) up to levels near the lower explosive limit (LEL = 4% H2 in the air) for safety reasons. Furthermore they need to operate in cryogenic ambient and high-temperature environments. Herein emphasis is given to hydrogen sensors based on solid oxide electrolytes (operating at high temperatures) in particular oxygen ion and proton conductors. The review is devoted to potentiometric amperometric and combined amperometric-potentiometric hydrogen sensors. Experimental results already reported in the international literature are presented and analyzed to reveal the configuration principle of operation and the applied solid electrolytes and electrodes of the high-temperature hydrogen sensors. Additionally an amperometric sensor able to detect hydrogen and steam in atmospheric air through a two-stage procedure is presented and thoroughly discussed. The discussion reveals that high-temperature hydrogen sensors face different challenges in terms of the electrodes and solid electrolytes to be used depending on the operating principle of each sensor type.
Potential Role of Renewable Gas in the Transition of Electricity and District Heating Systems
Dec 2019
Publication
With the constant increase in variable renewable energy production in electricity and district heating systems integration with the gas system is a way to provide flexibility to the overall energy system. In the sustainable transition towards a zero-emission energy system traditional natural gas can be substituted by renewable gasses derived from anaerobic digestion or thermal gasification and hydrogen. In this paper we present a methodology for modelling renewable gas options and limits on biomass resources across sectors in the energy optimisation model Balmorel. Different scenarios for socio-economic pathways to emission neutral electricity and district heating systems in Denmark Sweden Norway and Germany show that a renewable based energy system benefits from a certain percentage of gas as a supplement to other flexibility options like interconnectors. Especially upgraded biogas from anaerobic digestion serves as a substitute for natural gas in all scenarios. Allocating only 10% of available biomass to the electricity and district heating sector leads to full exploitation of the scarce biomass resource by boosting biogas and syngas with hydrogen. The need for renewable gasses is highest in Germany and least in Norway where hydro-power provides flexibility in terms of storable and dispatchable electricity production. The scenarios show that a required ‘‘late sprint" from fossils to achieve a zero-emission energy system in 2050 causes (1) significant higher accumulated emissions and (2) a system which strongly relies on fuels also in an emission free system instead of stronger integration of the electricity and district heating systems through electrification as well as stronger integration of the power systems across countries through interconnectors.
CFD Modelling of Hydrogen and Hydrogen-methane Explosions - Analysis of Varying Concentration and Reduced Oxygen Atmospheres
Feb 2023
Publication
This paper evaluates the predictive capabilities of the advanced consequence model FLACS-CFD for deflagrations involving hydrogen. Two modelling approaches are presented: the extensively validated model system originally developed for hydrocarbons included in FLACS-CFD 22.1 and a Markstein number dependent model implemented in the in-house version FLACS-CFD 22.1 IH. The ability of the models to predict the overpressure and the flame arrival time for scenarios with different concentrations of hydrogen and thus different Lewis and Markstein numbers is assessed. Furthermore the effect of adding methane or nitrogen on overpressure for different regimes of premixed combustion are investigated. The validation dataset includes deflagrations in the open or in congested open areas and vented deflagrations in empty or congested enclosures. The overpressure predictions by FLACS-CFD 22.1 IH are found to be more accurate than those obtained with FLACS-CFD 22.1 for scenarios with varying hydrogen concentrations and/or added nitrogen or methane in the mixture. The predictions by FLACS-CFD 22.1 IH for lean hydrogen mixtures are within a factor of 2 of the values observed in the experiments. Further development of the model is needed for more accurate prediction of deflagrations involving rich hydrogen mixtures as well as scenarios with other fuels and/or conditions where the initial pressure or temperature deviate significantly from ambient conditions.
Spatiotemporal Analysis of Hydrogen Requirement to Minimize Seasonal Variability in Future Solar and Wind Energy in South Korea
Nov 2022
Publication
Renewable energy supply is essential for carbon neutrality; however technologies aiming to optimally utilize renewable energy sources remain insufficient. Seasonal variability in renewable energy is a key issue which many studies have attempted to overcome through operating systems and energy storage. Currently hydrogen is the only technology that can solve this seasonal storage problem. In this study the amount of hydrogen required to circumvent the seasonal variability in renewable energy supply in Korea was quantified. Spatiotemporal analysis was conducted using renewable energy resource maps and power loads. It was predicted that 50% of the total power demand in the future will be met using solar and wind power and a scenario was established based on the solar-to-wind ratio. It was found that the required hydrogen production differed by approximately four-times depending on the scenarios highlighting the importance of supplying renewable energy at an appropriate ratio. Spatially wind power was observed to be unsuitable for the physical transport of hydrogen because it has a high potential at mountain peaks and islands. The results of this study are expected to aid future hydrogen research and solve renewable energy variability problems.
Modeling and Simulation of an Isolated Hybrid Micro-grid with Hydrogen Production and Storage
Jan 2014
Publication
This work relates the study of system performance in operational conditions for an isolated micro-grid powered by a photovoltaic system and a wind turbine. The electricity produced and not used by the user will be accumulated in two different storage systems: a battery bank and a hydrogen storage system composed of two PEM electrolyzers four pressurized tanks and a PEM fuel cell. One of the main problems to be solved in the development of isolated micro-grids is the management of the various devices and energy flows to optimize their functioning in particular in relation to the load profile and power produced by renewable energy systems depending on weather conditions. For this reason through the development and implementation of a specific simulation program three different energy management systems were studied to evaluate the best strategy for effectively satisfying user requirements and optimizing overall system efficiency.
Influence of Hydrogen Enrichment Strategy on Performance Characteristics, Combustion and Emissions of a Rotary Engine for Unmanned Aerial Vehicles (UAVs)
Dec 2022
Publication
In recent years there has been great interest in Wankel-type rotary engines which are one of the most suitable power sources for unmanned aerial vehicle (UAV) applications due to their high power-to-size and power-to-weight ratios. The purpose of the present study was to investigate the potential of a hydrogen enrichment strategy for the improvement of the performance and reduction of the emissions of Wankel engines. The main motivation behind this study was to make Wankel engines which are already very advantageous for UAV applications even more advantageous by applying the hydrogen enrichment technique. In this study hydrogen addition was implemented in a spark-ignition rotary engine model operating at a constant engine speed of 6000 rpm. The mass fraction of hydrogen in the intake gradually increased from 0% to 10%. Simulation results revealed that addition of hydrogen to the fuel accelerated the flame propagation and increased the burning speed of the fuel the combustion temperature and the peak pressure in the working chamber. These phenomena had a very positive effect on the performance and emissions of the Wankel engine. The indicated mean effective pressure (IMEP) increased by 8.18% and 9.68% and the indicated torque increased by 6.15% and 7.99% for the 5% and 10% hydrogen mass fraction cases respectively compared to those obtained with neat gasoline. In contrast CO emissions were reduced by 33.35% and 46.21% and soot emissions by 11.92% and 20.06% for 5% and 10% hydrogen additions respectively. NOx emissions increased with the application of the hydrogen enrichment strategy for the Wankel engine.
Net Hydrogen Consumption Minimization of Fuel Cell Hybrid Trains Using a Time-Based Co-Optimization Model
Apr 2022
Publication
With increasing concerns on transportation decarbonization fuel cell hybrid trains (FCHTs) attract many attentions due to their zero carbon emissions during operation. Since fuel cells alone cannot recover the regenerative braking energy (RBE) energy storage devices (ESDs) are commonly deployed for the recovery of RBE and provide extra traction power to improve the energy efficiency. This paper aims to minimize the net hydrogen consumption (NHC) by co-optimizing both train speed trajectory and onboard energy management using a time-based mixed integer linear programming (MILP) model. In the case with the constraints of speed limits and gradients the NHC of co-optimization reduces by 6.4% compared to the result obtained by the sequential optimization which optimizes train control strategies first and then the energy management. Additionally the relationship between NHC and employed ESD capacity is studied and it is found that with the increase of ESD capacity the NHC can be reduced by up to 30% in a typical route in urban railway transit. The study shows that ESDs play an important role for FCHTs in reducing NHC and the proposed time-based co-optimization model can maximize the energy-saving benefits for such emerging traction systems with hybrid energy sources including both fuel cells and ESD.
Maximizing Green Hydrogen Production from Water Electrocatalysis: Modeling and Optimization
Mar 2023
Publication
The use of green hydrogen as a fuel source for marine applications has the potential to significantly reduce the carbon footprint of the industry. The development of a sustainable and cost-effective method for producing green hydrogen has gained a lot of attention. Water electrolysis is the best and most environmentally friendly method for producing green hydrogen-based renewable energy. Therefore identifying the ideal operating parameters of the water electrolysis process is critical to hydrogen production. Three controlling factors must be appropriately identified to boost hydrogen generation namely electrolysis time (min) electric voltage (V) and catalyst amount (µg). The proposed methodology contains the following two phases: modeling and optimization. Initially a robust model of the water electrolysis process in terms of controlling factors was established using an adaptive neuro-fuzzy inference system (ANFIS) based on the experimental dataset. After that a modern pelican optimization algorithm (POA) was employed to identify the ideal parameters of electrolysis duration electric voltage and catalyst amount to enhance hydrogen production. Compared to the measured datasets and response surface methodology (RSM) the integration of ANFIS and POA improved the generated hydrogen by around 1.3% and 1.7% respectively. Overall this study highlights the potential of ANFIS modeling and optimal parameter identification in optimizing the performance of solar-powered water electrocatalysis systems for green hydrogen production in marine applications. This research could pave the way for the more widespread adoption of this technology in the marine industry which would help to reduce the industry’s carbon footprint and promote sustainability.
The Key Techno-Economic and Manufacturing Drivers for Reducing the Cost of Power-to-Gas and a Hydrogen-Enabled Energy System
Jul 2021
Publication
Water electrolysis is a process which converts electricity into hydrogen and is seen as a key technology in enabling a net-zero compatible energy system. It will enable the scale-up of renewable electricity as a primary energy source for heating transport and industry. However displacing the role currently met by fossil fuels might require a price of hydrogen as low as 1 $/kg whereas renewable hydrogen produced using electrolysis is currently 10 $/kg. This article explores how mass manufacturing of proton exchange membrane (PEM) electrolysers can reduce the capital cost and thus make the production of renewable power to hydrogen gas (PtG) more economically viable. A bottom up direct manufacturing model was developed to determine how economies of scale can reduce the capital cost of electrolysis. The results demonstrated that (assuming an annual production rate of 5000 units of 200 kW PEM electrolysis systems) the capital cost of a PEM electrolysis system can reduce from 1990 $/kW to 590 $/kW based on current technology and then on to 431 $/kW and 300 $/kW based on the an installed capacity scale-up of ten- and one-hundred-fold respectively. A life-cycle costing analysis was then completed to determine the importance of the capital cost of an electrolysis system to the price of hydrogen. It was observed that based on current technology mass manufacturing has a large impact on the price of hydrogen reducing it from 6.40 $/kg (at 10 units units per year) to 4.16 $/kg (at 5000 units per year). Further analysis was undertaken to determine the cost at different installed capacities and found that the cost could reduce further to 2.63 $/kg and 1.37 $/kg based on technology scale-up by ten- and one hundred-fold respectively. Based on the 2030 (and beyond) baseline assumptions it is expected that hydrogen production from PEM electrolysis could be used as an industrial process feed stock provide power and heat to buildings and as a fuel for heavy good vehicles (HGVs). In the cases of retrofitted gas networks for residential or industrial heating solutions or for long distance transport it represents a more economically attractive and mass-scale compatible solution when compared to electrified heating or transport solutions.
Potential Global Warming Impact of 1 kW Polymer Electrolyte Membrane Fuel Cell System for Residential Buildings on Operation Phase
Mar 2023
Publication
This study established global warming potential(GWP) emission factors through a life cycle assessment on the operation phases of two different 1 kW polymer electrolyte membrane fuel cell (PEMFC) systems for residential buildings (NG-PEMFC fed with hydrogen from natural gas reforming; WE-PEMFC fed with hydrogen from photovoltaics-powered water electrolyzer). Their effectiveness was also compared with conventional power grid systems in Korea specifically in the area of greenhouse gas emissions. The operation phases of the NG-PEMFC and the WE-PEMFC were divided into burner reformer and stack and into water electrolysis and stack respectively. The functional unit of each fuel cell system was defined as 1 kWh of electricity production. In the case of NG-PEMFC the GWP was 3.72E-01 kg-CO2eq/kWh the embodied carbon emissions due to using city gas during the life cycle process was about 20.87 % the carbon emission ratio according to the reformer's combustion burner was 6.07 % and the direct carbon emission ratio of the air emissions from the reformer was 73.06 % indicating that the carbon emission from the reformer contributed over 80 % of the total GWP. As for the WE-PEMFC the GWP was 1.76E-01 kg-CO2eq/kWh and the embodied carbon emissions from photovoltaic power generation during the life cycle process contributed over 99 % of the total GWP.
Life Cycle Assessment of Alternative Ship Fuels for Coastal Ferry Operating in Republic of Korea
Aug 2020
Publication
In this study the environmental impacts of various alternative ship fuels for a coastal ferry were assessed by the life cycle assessment (LCA) analysis. The comparative study was performed with marine gas oil (MGO) natural gas and hydrogen with various energy sources for a 12000 gross tonne (GT) coastal ferry operating in the Republic of Korea (ROK). Considering the energy imports of ROK i.e. MGO from Saudi Arabia and natural gas from Qatar these countries were chosen to provide the MGO and the natural gas for the LCA. The hydrogen is considered to be produced by steam methane reforming (SMR) from natural gas with hard coal nuclear energy renewable energy and electricity in the ROK model. The lifecycles of the fuels were analyzed in classifications of Well-toTank Tank-to-Wake and Well-to-Wake phases. The environmental impacts were provided in terms of global warming potential (GWP) acidification potential (AP) photochemical potential (POCP) eutrophication potential (EP) and particulate matter (PM). The results showed that MGO and natural gas cannot be used for ships to meet the International Maritime Organization’s (IMO) 2050 GHG regulation. Moreover it was pointed out that the energy sources in SMR are important contributing factors to emission levels. The paper concludes with suggestions for a hydrogen application plan for ships from small nearshore ships in order to truly achieve a ship with zero emissions based on the results of this study.
Hydrogen Europe Podcast: The Commision's Support to the Hydrogen Ecosystem
Jul 2022
Publication
In this episode titled "The Commission's support to the hydrogen ecosystem" our CEO Jorgo Chatzimarkakis discusses with Rosalinde van der Vlies Clean Planet Director DG RTD - European Commission. Starting off on how Rosalinde joined the Commission the two speakers discuss the Commission's support in developing a hydrogen ecosystem also in light of its participation in the Clean Hydrogen Partnership and the implications arising from the REPowerEU.
Aboveground Hydrogen Storage - Assessment of the Potential Market Releveance in a Carbon-Neutral European Energy System
Mar 2024
Publication
Hydrogen storage is expected to play a crucial role in the comprehensive defossilization of energy systems. In this context the focus is typically on underground hydrogen storage (e.g. in salt caverns). However aboveground storage which is independent of geological conditions and might offer other technical advantages could provide systemic benefits and thereby gain shares in the hydrogen storage market. Against this background this paper examines the market relevance of aboveground compared to underground hydrogen storage. Using the opensource energy system model and optimization framework of Europe PyPSA-Eur the influence of geological independence storage cost relations and technical storage characteristics (i.e. efficiencies) on mentioned market relevance of aboveground hydrogen storage are investigated. Further the expectable market relevance based on current cost projections for the future is assessed. The studies show that in terms of hydrogen capacities aboveground hydrogen storage plays a considerably smaller role compared to underground hydrogen storage. Even when assuming comparatively low aboveground storage cost it will not exceed 1.7% (1.9 TWhH2LHV) of total hydrogen storage capacities in a cost-optimal European energy system. Regarding the amounts of annually stored hydrogen aboveground storage could play a larger role reaching a maximum share of 32.5% (168 TWhH2 LHV a-1) of total stored hydrogen throughout Europe. However these shares are only achievable for low cost storage in particularly suited energy system supply configurations. For higher aboveground storage costs or lower efficiencies shares drop below 10% sharply. The analysis identifies some especially influential factors for achieving higher market relevance. Besides storage costs the demand-orientation of a particular aboveground storage system (e.g. hydrogen storage at demand pressure levels) plays an essential role in market relevance. Further overall efficiency can be a beneficial factor. Still current projections of future techno-economic characteristics show that aboveground hydrogen storage is too expensive or too inefficient compared to underground storage. Therefore to achieve notable market relevance rather drastic cost reductions beyond current expectations would be needed for all assessed aboveground hydrogen storage technologies.
Life Cycle Cost Analysis of an Autonomous Underwater Vehicle that Employs Hydrogen Fuel Cell
Feb 2024
Publication
The use of autonomous vehicles for marine and submarine work has risen considerably in the last decade. Developing new monitoring systems navigation and communications technologies allows a wide range of operational possibilities. Autonomous Underwater Vehicles (AUVs) are being used in offshore missions and applications with some innovative purposes by using sustainable and green energy sources. This paper considers an AUV that uses a hydrogen fuel cell achieving zero emissions. This paper analyses the life cycle cost of the UAV and compares it with a UAV powered by conventional energy. The EN 60300-3-3 guidelines have been employed to develop the cost models. The output results show estimations for the net present value under different scenarios and financial strategies. The study has been completed with the discount rate sensibility analysis in terms of financial viability.
A Power Dispatch Allocation Strategy to Produce Green Hydrogen in a Grid-integrated Offshore Hybrid Energy System
Mar 2024
Publication
A dedicated grid-tied offshore hybrid energy system for hydrogen production is a promising solution to unlock the full benefit of offshore wind and solar energy and realize decarbonization and sustainable energy security targets in electricity and other sectors. Current knowledge of these offshore hybrid systems is limited particularly in the integration component control and allocation aspects. Therefore a grid-integrated analytical model with a power dispatch allocation strategy between the grid and electrolyzer for the co-production of hydrogen from the offshore hybrid energy system is developed in this paper. While producing hydrogen the proposed offshore hybrid energy system supplies a percentage of its capacity to the onshore grid facility and the amount of the electricity is quantified based on the electricity market price and available total offshore generation. The detailed controls of each component are discussed. A case study considers a hypothetical hybrid offshore energy system of 10 MW situated in a potential offshore off the NSW of Australia based on realistic metrological data. A grid-scale proton-exchange membrane electrolyzer stack is used and a model predictive power controller is implemented on the distributed hydrogen generation scheme. The model is helpful for the assessment or optimization of both the economics and feasibility of the dedicated offshore hybrid energy farm for hydrogen production systems.
Hydrogenerally - Episode 10: Green Hydrogen Production
Feb 2023
Publication
Debra Jones Chemistry Knowledge Transfer Manager and Simon Buckley Zero Emission Mobility Knowledge Transfer Manager from Innovate UK KTN talk about green hydrogen production with their special guest Chris Jackson CEO & Founder at Protium.
This podcast discussion centres around methods of producing clean hydrogen from renewable energy sources the innovative projects Protium is working on and how much green hydrogen will the UK produce by 2030 and beyond.
The podcast can be found on their website.
This podcast discussion centres around methods of producing clean hydrogen from renewable energy sources the innovative projects Protium is working on and how much green hydrogen will the UK produce by 2030 and beyond.
The podcast can be found on their website.
Evaluation of a Hydrogen Powered Scooter Toy Prototype
Nov 2022
Publication
Electric scooters are used as alternative ways of transport because they easily make travel faster. However the batteries can take around 5 h to charge and have an autonomy of 30 km. With the presence of the hydrogen cell a hybrid system reduces the charging times and increases the autonomy of the vehicle by using two types of fuel. An increase of up to 80% in maximum distance and of 34% in operating times is obtained with a 1:10 scale prototype with the hydrogen cell; although more energy is withdrawn the combined fuel efficiency increases too. This suggests the cell that is used has the same behavior as some official reported vehicles which have a long range but low power. This allows concluding that use of the cell is functional for load tests and that the comparison factor obtained works as input for real-scale scooter prototypes to compete with the traditional electric scooters.
Next for Net Zero Podcast: Transporting to a Greener World
Oct 2022
Publication
Decarbonisation will need a significant societal shift. The when why and how we travel is going to look very different within a decade. Joining us is Florentine Roy – a leading expert on electric vehicles and Innovation Project Lead at UK Power Networks and Matt Hindle - Head of Net Zero and Sustainability at Wales and West Utilities. Let’s talk about the energy system implications of this massive undertaking and how it can be enabled by innovation in a fair and just way.
The podcast can be found here.
The podcast can be found here.
Behavior of Barrier Wall under Hydrogen Storage Tank Explosion with Simulation and TNT Equivalent Weight Method
Mar 2023
Publication
Hydrogen gas storage place has been increasing daily because of its consumption. Hydrogen gas is a dream fuel of the future with many social economic and environmental benefits to its credit. However many hydrogen storage tanks exploded accidentally and significantly lost the economy infrastructure and living beings. In this study a protection wall under a worst-case scenario explosion of a hydrogen gas tank was analyzed with commercial software LS-DYNA. TNT equivalent method was used to calculate the weight of TNT for Hydrogen. Reinforced concrete and composite protection wall under TNT explosion was analyzed with a different distance of TNT. The initial dimension of the reinforced concrete protection wall was taken from the Korea gas safety code book (KGS FP217) and studied the various condition. H-beam was used to make the composite protection wall. Arbitrary-Lagrangian-Eulerian (ALE) simulation from LS-DYNA and ConWep pressure had a good agreement. Used of the composite structure had a minimum displacement than a normal reinforced concrete protection wall. During the worst-case scenario explosion of a hydrogen gas 300 kg storage tank the minimum distance between the hydrogen gas tank storage and protection wall should be 3.6 m.
Knowledge and Technology Transfer via Publications, Patents, Standards: Exploring the Hydrogen Technological Innovation System
Nov 2022
Publication
Clean technologies play a crucial role in reducing greenhouse gas emissions and protecting the climate. Hydrogen is a promising energy carrier and fuel that can be used in many applications. We explore the global hydrogen technological innovation system (TIS) by analyzing the three knowledge and technology transfer channels of publications patents and standards. Since the adoption of hydrogen technologies requires trust in their safety this study specifically also focuses on hydrogen safety. Our results show that general and hydrogen safety research has increased significantly while patenting experienced stagnation. An analysis of the non-patent literature in safety patents shows little recognition of scientific publications. Similarly publications are under-represented in the analyzed 75 international hydrogen and fuel cell standards. This limited transfer of knowledge from published research to standards points to the necessity for greater involvement of researchers in standardization. We further derive implications for the hydrogen TIS and recommendations for a better and more impactful alignment of the three transfer channels.
Potential of Producing Green Hydrogen in Jordan
Nov 2022
Publication
Green hydrogen is becoming an increasingly important energy supply source worldwide. The great potential for the use of hydrogen as a sustainable energy source makes it an attractive energy carrier. In this paper we discuss the potential of producing green hydrogen in Jordan. Aqaba located in the south of Jordan was selected to study the potential for producing green hydrogen due to its proximity to a water source (i.e. the Red Sea). Two models were created for two electrolyzer types using MATLAB. The investigated electrolyzers were alkaline water (ALK) and polymeric electrolyte membrane (PEM) electrolyzers. The first model was used to compare the required capacity of the PV solar system using ALK and PEM from 2022 to 2025 depending on the learning curves for the development of these technologies. In addition this model was used to predict the total investment costs for the investigated electrolyzers. Then a techno-economic model was constructed to predict the feasibility of using this technology by comparing the use of a PV system and grid electricity as sources for the production of hydrogen. The net present value (NPV) and levelized cost of hydrogen (LCOH) were used as indicators for both models. The environmental effect according to the reduction of CO2 emissions was also taken into account. The annual production of hydrogen was 70.956 million kg. The rate of hydrogen production was 19.3 kg/s and 1783 kg/s for ALK and PEM electrolyzers respectively. The LCOH was 4.42 USD/kg and 3.13 USD/kg when applying electricity from the grid and generated by the PV system respectively. The payback period to cover the capital cost of the PV system was 11 years of the project life with a NPV of USD 441.95 million. Moreover CO2 emissions can be reduced by 3042 tons/year by using the PV as a generation source instead of fossil fuels to generate electricity. The annual savings with respect to the reduction of CO2 emissions was USD 120135.
Hydrogenerally - Episode 9: Nuclear Hydrogen
Jan 2023
Publication
In this episode of the podcast Debra Jones Chemistry Knowledge Transfer Manager and Ray Chegwin Nuclear Knowledge Transfer Manager from Innovate UK KTN talk about nuclear uses for hydrogen with special guest Allan Simpson Technical Lead at the National Nuclear Laboratory.
The podcast can be found on their website.
The podcast can be found on their website.
Feasibility of Hydrogen Production from Steam Reforming of Biodiesel (FAME) Feedstock on Ni-supported Catalysts
Jan 2015
Publication
The catalytic steam reforming of biodiesel was examined over Ni-alumina and Ni–ceria–zirconia catalysts at atmospheric pressure. Effects of temperatures of biodiesel preheating/vaporising (190–365 ◦C) and reforming (600–800 ◦C) molar steam to carbon ratio (S/C = 2–3) and residence time in the reformer represented by the weight hourly space velocity ‘WHSV’ of around 3 were examined for 2 h. Ni supported on calcium aluminate and on ceria–zirconia supports achieved steady state hydrogen product stream within 90% of the equilibrium yields although 4% and 1% of the carbon feed had deposited on the catalysts respectively during the combined conditions of start-up and steady state. Addition of dopants to ceria–zirconia supported catalyst decreased the performance of the catalyst. Increase in S/C ratio had the expected positive effects of higher H2 yield and lower carbon deposition.
Thermodynamic and Technical Issues of Hydrogen and Methane-Hydrogen Mixtures Pipeline Transmission
Feb 2019
Publication
The use of hydrogen as a non-emission energy carrier is important for the innovative development of the power-generation industry. Transmission pipelines are the most efficient and economic method of transporting large quantities of hydrogen in a number of variants. A comprehensive hydraulic analysis of hydrogen transmission at a mass flow rate of 0.3 to 3.0 kg/s (volume flow rates from 12000 Nm3/h to 120000 Nm3/h) was performed. The methodology was based on flow simulation in a pipeline for assumed boundary conditions as well as modeling of fluid thermodynamic parameters for pure hydrogen and its mixtures with methane. The assumed outlet pressure was 24 bar (g). The pipeline diameter and required inlet pressure were calculated for these parameters. The change in temperature was analyzed as a function of the pipeline length for a given real heat transfer model; the assumed temperatures were 5 and 25 ◦C. The impact of hydrogen on natural gas transmission is another important issue. The performed analysis revealed that the maximum participation of hydrogen in natural gas should not exceed 15%–20% or it has a negative impact on natural gas quality. In the case of a mixture of 85% methane and 15% hydrogen the required outlet pressure is 10% lower than for pure methane. The obtained results present various possibilities of pipeline transmission of hydrogen at large distances. Moreover the changes in basic thermodynamic parameters have been presented as a function of pipeline length for the adopted assumptions.
Water Electrolysis: From Textbook Knowledge to the Latest Scientific Strategies and Industrial Developments
May 2022
Publication
Replacing fossil fuels with energy sources and carriers that are sustainable environmentally benign and affordable is amongst the most pressing challenges for future socio-economic development. To that goal hydrogen is presumed to be the most promising energy carrier. Electrocatalytic water splitting if driven by green electricity would provide hydrogen with minimal CO2 footprint. The viability of water electrolysis still hinges on the availability of durable earth-abundant electrocatalyst materials and the overall process efficiency. This review spans from the fundamentals of electrocatalytically initiated water splitting to the very latest scientific findings from university and institutional research also covering specifications and special features of the current industrial processes and those processes currently being tested in large-scale applications. Recently developed strategies are described for the optimisation and discovery of active and durable materials for electrodes that ever-increasingly harness first principles calculations and machine learning. In addition a technoeconomic analysis of water electrolysis is included that allows an assessment of the extent to which a large-scale implementation of water splitting can help to combat climate change. This review article is intended to cross-pollinate and strengthen efforts from fundamental understanding to technical implementation and to improve the ‘junctions’ between the field’s physical chemists materials scientists and engineers as well as stimulate much-needed exchange among these groups on challenges encountered in the different domains.
Life Cycle Assessment of Natural Gas-based Chemical Looping for Hydrogen Production
Dec 2014
Publication
Hydrogen production from natural gas combined with advanced CO2 capture technologies such as iron-based chemical looping (CL) is considered in the present work. The processes are compared to the conventional base case i.e. hydrogen production via natural gas steam reforming (SR) without CO2 capture. The processes are simulated using commercial software (ChemCAD) and evaluated from a technical point of view considering important key performance indicators such as hydrogen thermal output net electric power carbon capture rate and specific CO2 emissions. The environmental evaluation is performed using Life Cycle Analysis (LCA) with the following system boundaries considered: i) hydrogen production from natural gas coupled to CO2 capture technologies based on CL ii) upstream processes such as: extraction and processing of natural gas ilmenite and catalyst production and iii) downstream processes such as: H2 and CO2 compression transport and storage. The LCA assessment was carried out using the GaBi6 software. Different environmental impact categories following here the CML 2001 impact assessment method were calculated and used to determine the most suitable technology. Sensitivity analyses of the CO2 compression transport and storage stages were performed in order to examine their effect on the environmental impact categories.
Carbon-neutral Cement: The Role of Green Hydrogen
Mar 2024
Publication
Business-as-usual (BAU) cement production is associated with a linear model that contributes significantly to global warming and is dependent on volatile energy markets. A novel circular model is proposed by adding three power-to-gas system components to current production systems: a calcium-looping (CaL) CO2 capture unit; water electrolysis for hydrogen and oxygen generation; and a methanation unit for synthetic natural gas (SNG) production. The paper presents the first analysis of the combined industrial-scale operation of these components in a closed loop where the SNG fuels the cement kiln and the CaL unit while the O2 produced feeds it. The circular hybrid and BAU models are compared in three feasibility scenarios. It is concluded that the circular model outperforms the other alternatives environmentally opening a potential pathway for the cement industry to achieve near net-zero CO2 emissions reduce energy dependence and improve economic efficiency.
Numerical Investigation of a Fuel Cell-Powered Agricultural Tractor
Nov 2022
Publication
In recent years growing awareness about environmental issues is pushing humankind to explore innovative technologies to reduce the anthropogenic sources of pollutants. Among these sources internal combustion engines in non-road mobile machinery (NRMM) such as agricultural tractors are one of the most important. The aim of this work is to explore the possibility of replacing the conventional diesel engine with an electric powertrain powered by a hybrid storage system consisting of a small battery pack and a fuel-cell system. The battery pack (BP) is necessary to help the fuel cell manage sudden peaks in power demands. Numerical models of the conventional powertrain and a fuel-cell tractor were carried out. To compare the two powertrains work cycles derived from data collected during real operative conditions were exploited and simulated. For the fuel-cell tractor a control strategy to split the electric power between the battery pack and the fuel cell was explored. The powertrains were compared in terms of greenhouse gas emissions (GHG) according to well-to-wheel (WTW) equivalent CO2 emission factors available in the literature. Considering the actual state-of-the-art hydrogen production methods the simulation results showed that the fuel-cell/battery powertrain was able to accomplish the tasks with a reduction of about 50% of the equivalent CO2 emissions compared to traditional diesel-powered vehicles.
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