Publications

In future energy supply systems hydrogen and electricity may be generated in decarbonized industrial clusters using a common infrastructure for natural gas supply electricity grid and transport and geological storage of CO2. The novel contribution of this article consists of using sequential combustion in a steam methane reforming (SMR) hydrogen plant to allow for capital and operating cost reduction by using a single post-combustion carbon capture syste Read More

The Swiss government has signed the Paris Climate Agreement and various measures need to be implemented in order to reach the target of a 50% reduction in CO2 emissions in Switzerland by 2030 compared with the value for 1990. Considering the fact that the production of cement in Switzerland accounts around 2.5 million ton for CO2 emissions of which corresponds to roughly 7% of the country's total CO2 emissions the following article ex Read More

Safe and long term operation of nuclear reactors is one of the most discussed challenges in nuclear power engineering. The radiation degradation of nuclear design materials limits the operational lifetime of all nuclear installations or at least decreases its safety margin. This paper is a review of experimental PALS/PLEPS studies of different nuclear reactor pressure vessel (RPV) steels investigated over last twenty years in our laboratories. Positron annihil Read More

The generation of hydrogen from water using light is currently one of the most promising alternative energy sources for humankind but faces significant barriers for large-scale applications due to the low efficiency of existing photo-catalysts. In this work we propose a new route to fabricate nano-hybrid materials able to deliver enhanced photo-catalytic hydrogen evolution combining within the same nanostructure a plasmonic antenna nanoparticl Read More

The storage of hydrogen gas in underground lined rock caverns (LRCs) enables the implementation of the first fossil-free steelmaking process to meet the large demand for crude steel. Predicting the response of rock mass is important to ensure that gas leakage due to rupture of the steel lining does not occur. Analytical and numerical models can be used to estimate the rock mass response to high internal pressure; however the fitness of these models u Read More

Purpose- To present an overview of the research and development carried out in a European funded framework 7 (FP7) project called SafeHPower for the implementation of neutron radiography to inspect fatigue cracks in vehicle and storage hydrogen fuel tanks. Project background– Hydrogen (H2) is the most promising replacement fuel for road transport due to its abundance efficiency low carbon footprint and the absence of harmful emissions. For the Read More

Hydrogen production is critical to many modern chemical processes – ammonia synthesis petroleum refining direct reduction of iron and more. Conventional approaches to hydrogen manufacture include steam methane reforming and autothermal reforming which today account for the lion's share of hydrogen generation. Without CO2 capture these processes emit about 8.7 kg of CO2 for each kg of H2 produced. In this study a molten carbonate fuel cell Read More

This paper proposes the use of the Point Method (PM) to analyse Environmentally Assisted Cracking (EAC) processes in steels containing U-shaped notches. The PM a methodology included within the Theory of Critical Distances (TCD) has been extensively validated by many authors for the analysis of fracture and fatigue phenomena of different types of materials containing notches. However it has never been applied to other critical or subcritical cracking p Read More

This paper has experimentally proved that hydrogen accumulates in large quantities in metal-ceramic and pocket electrodes of alkaline batteries during their operation. Hydrogen accumulates in the electrodes in an atomic form. After the release of hydrogen from the electrodes a powerful exothermic reaction of atomic hydrogen recombination with a large energy release occurs. This exothermic reaction is the cause of thermal runaway in alkaline batteries Read More

Hydrogen storage is a materials science challenge because for all six storage methods currently being investigated materials with either a strong interaction with hydrogen or without any reaction are needed. Besides conventional storage methods i.e. high pressure gas cylinders and liquid hydrogen the physisorption of hydrogen on materials with a high specific surface area hydrogen intercalation in metals and complex hydrides and storage of hy Read More

The effect of hydrogen on tensile behavior and fracture mechanisms of V-alloying and V-free high-nitrogen austenitic steels was evaluated. Two steels with the chemical compositions of Fe-23Cr–17Mn–0.1C–0.6N (0V-HNS) and Fe-19Cr–22Mn–1.5V–0.3C–0.9N (1.5V-HNS) were electrochemically hydrogen-charged in NaCl water-solution for 100 hours. According to X-ray diffraction analysis and TEM researches V-alloying promotes particle strengthening of the 1. Read More

2020: a great year for hydrogen! Among other things 2020 has been exceptional for H2 technology deployment and policy development. The European Commission’s hydrogen strategy is just one of many crowning achievements! What does the future hold?

An energy system centred on renewable energy can help resolve many of Africa’s social economic health and environmental challenges. A profound energy transition is not only feasible it is essential for a climate-safe future in which sustainable development prerogatives are met. Renewables are key to overcoming energy poverty providing needed energy services without damaging human health or ecosystems and enabling a transformation of e Read More

Anion exchange membrane water electrolysis (AEMWE) has acquired substantial consideration as a cost-effective hydrogen production technology. The anion ionomer content in the catalyst layers during hydrogen and oxygen evolution reaction (HER and OER) is of ultimate significance. Herein an in-situ half-cell analysis with reference electrodes was carried out for simultaneous potential measurements and identification of the influence of the anion excha Read More

The cost of storing and transporting hydrogen have been one of the main challenges for the realization of the hydrogen economy. Liquid organic hydrogen carriers (LOHC) are a promising novel solution to tackle these challenges. In this paper we compare the LOHC concept to compressed gas truck delivery and on-site production of hydrogen via water electrolysis. As a case study we consider transportation of by-product hydrogen from chlor-alkali and chl Read More

An increase in human activities and population growth have significantly increased the world’s energy demands. The major source of energy for the world today is from fossil fuels which are polluting and degrading the environment due to the emission of greenhouse gases. Hydrogen is an identified efficient energy carrier and can be obtained through renewable and non-renewable sources. An overview of renewable sources of hydrogen production w Read More

DFT calculations at B3LYP/6-31g(dp) with the D3 version of Grimme’s dispersion are performed to investigate the application of TM-encapsulated Mg12O12 nano-cages (TM= Mn Fe and Co) as a hydrogen storage material. The molecular dynamic (MD) calculations are utilized to examine the stability of the considered structures. TD-DFT method reveals that the TM-encapsulation converts the Mg12O12 from an ultraviolet into a visible optical active m Read More

Smart energy hubs (Smart Hubs) equipped with Vehicle-to-Grid (V2G) charging photovoltaic (PV) energy generation and hydrogen storage capabilities are an emerging technology with potential to alleviate the impact of electric vehicles (EV) on the electricity grid. Their operation however is characterised by intermittent PV energy generation as well as uncertainties in EV traffic and driver preference. These uncertainties when combined with the need t Read More

Understanding the mechanism of hydrogen embrittlement (HE) of austenitic steels and developing an effective strategy to improve resistance to HE are of great concern but challenging. In this work first-principles studies were performed to investigate the HE mechanism and the improved resistance of Al-containing austenite to HE. Our results demonstrate that interstitial hydrogen atoms have different site preferences in Al-free and Al-containing au Read More

Hydrogen embrittlement (HE) of metals has remained a mystery in materials science for more than a century. To try to clarify this mystery tensile tests were conducted at room temperature (RT) on a 316 stainless steel (SS) in air and hydrogen of 70 MPa. With an aim to directly observe the effect of hydrogen on ordering of 316 SS during deformation electron diffraction patterns and images were obtained from thin foils made by a focused ion beam from t Read More

Alkaline water electrolysis (AWE) is a mature hydrogen production technology and there exists a range of economic assessments for available technologies. For advanced AWEs which may be based on novel polymer-based membrane concepts it is of prime importance that development comes along with new configurations and technical and economic key process parameters for AWE that might be of interest for further economic assessments. This pap Read More

As fossil fuels continue to be extracted and used issues such as environmental pollution and energy scarcity are surfacing. For the transportation industry the best way to achieve the goal of “carbon neutrality” is to research efficient power systems and develop new alternative fuels. As the world’s largest product of chemicals ammonia is a new renewable fuel with good combustion energy. It can be used as an alternative fuel to reduce carbon emissions becau Read More

Liquid hydrogen (LH2) compared to compressed gaseous hydrogen offers advantages for large-scale transport and storage of hydrogen with higher densities. Although the gas industry has good experience with LH2 only little experience is available for the new applications of LH2 as an energy carrier. Therefore the European FCH JU funded project PRESLHY conducted pre-normative research for the safe use of cryogenic LH2 in non-industrial set Read More

This paper addresses how a global climate target may influence iron and steel production technology deployment and scrap use. A global energy system model ETSAP-TIAM was used and a Scrap Availability Assessment Model (SAAM) was developed to analyse the relation between steel demand recycling and the availability of scrap and their implications for steel production technology choices. Steel production using recycled materials has a continuous Read More

The hydrogen economy refers to an economic and industrial structure that uses hydrogen as its main energy source replacing traditional fossil-fuel-based energy systems. In particular the widespread adoption of hydrogen fuel cell vehicles (HFCVs) is one of the key factors enabling a hydrogen economy and aggressive investment in hydrogen refuelling infrastructure is essential to make large-scale adoption of HFCVs possible. In this study we address t Read More

The dislocation and twinning evolution behaviors in high manganese steels Fe-22Mn-0.6C and Fe-17Mn-1.5Al-0.6C have been investigated under tensile deformation with and without diffusive hydrogen. The notched tensile tests were interrupted once primary cracks were detected using the applied direct current potential drop measurement. In parallel the strain distribution in the vicinity of the crack was characterized by digital image correlation usi Read More

The use of hydrogen as energy carrier is a promising option to decarbonize both energy and transport sectors. This paper presents an advanced techno-economic model for calculation of optimal dispatch of large-scale multi MW electrolysis plants in order to obtain a more accurate evaluation of the feasibility of business cases related to the supply of this fuel for different end uses combined with grid services' provision. The model is applied to the Spanis Read More

Solid oxide fuel cells (SOFCs) produce electricity with high electrical efficiency and fuel flexibility without pollution for example CO2 NOx SOx and particles. Still numerous issues hindered the large‐scale commercialization of fuel cell at a large scale such as fuel storage mechanical failure catalytic degradation electrode poisoning from fuel and air for example lifetime in relation to cost. Computational fluid dynamics (CFD) couples various physical fields w Read More

In the transition to a climate neutral future the transportation sector needs to be sustainably decarbonized. Producing advanced fuels (such as biomethane) and bio-based valorised products (such as pyrochar) may offer a solution to significantly reduce greenhouse gas (GHG) emissions associated with energy and agricultural circular economy systems. Biological and thermochemical bioenergy technologies together with power to gas (P2G) systems can gene Read More

Frontier Economics has been engaged by the Commonwealth Department of the Environment and Energy (now Industry Science Energy and Resources) (the Department) to undertake an indicative analysis of the economics of blending hydrogen in Australian natural gas distribution networks. Our analysis is limited to a specific gas distribution network servicing urban areas of Melbourne.We have investigated the economics of blending hydrogen in a natural g Read More

Heat is one of the UK’s largest energy-consuming and carbon-emitting sectors and potentially the most difficult to decarbonise. The UK’s Clean Growth Strategy identifies that heat decarbonisation in buildings and industry will likely involve shifting away from natural gas to alternative energy vectors like electricity and hydrogen. This will mean transition of existing cooking appliances away from natural gas resulting in social implications that require Read More

There is a need for alternative marine fuels in order to reduce the environmental and climate impacts of shipping in the short and long term. This study assesses the prospects for seven alternative fuels for the shipping sector in 2030 including biofuels by applying a multi-criteria decision analysis approach that is based on the estimated fuel performance and on input from a panel of maritime stakeholders and by considering explicitly the influence of Read More

The Swedish steel industry stands before a potential transition to drastically lower its CO2 emissions using direct hydrogen reduction instead of continuing with coke-based blast furnaces. Previous studies have identified hydrogen direct reduction as a promising option. We build upon earlier efforts by performing a technological innovation system study to systematically examine the barriers to a transition to hydrogen direct reduction and by providing deep Read More

Recently hot stamping technology has been increasingly used in automotive structural parts with ultrahigh strength to meet the standards of both high fuel efficiency and crashworthiness. However one issue of concern regarding these martensitic steels which are fabricated using a hot stamping procedure is that the steel is highly vulnerable to hydrogen delayed cracking caused by the diffusible hydrogen flow through the surface reaction of the coating in a Read More

The objective of this project is to take into account the mechanical constraints formed by diffusion of hydrogen or tritium in watertight palladium alloy cathode. To know the origin of these it was necessary to discriminating the damaging effects encountered. Effectively hydrogen and isotope induce deformation embrittlement stress corrosion cracking and cathodic corrosion in different regions of cathode. Palladium can be alloyed with silver o Read More

In a future fossil-free circular economy the petroleum-based plastics industry must be converted to non-fossil feedstock. A known alternative is bio-based plastics but a relatively unexplored option is deriving the key plastic building blocks hydrogen and carbon from electricity through electrolytic processes combined with carbon capture and utilization technology. In this paper the future demand for electricity and carbon dioxide is calculated under th Read More

Synthetic natural gas (SNG) is one of the promising energy carriers for the excessive electricity generated from variable renewable energy sources. SNG production from renewable H2 and CO2  via catalytic CO2 methanation has gained much attention since CO2 emissions could be simultaneously reduced. In this study Ni–Fe/(MgAl)Ox alloy catalysts for CO2 methanation were prepared via hydrotalcite precursors using a rapid coprecipitation method. Th Read More

Plastic pre-strains were applied to the metastable 304L austenitic stainless steel at both room temperature (20 °C) and higher temperatures (i.e. 50 80 and 100 °C) and then the hydrogen embrittlement (HE) susceptibility of the steel was evaluated by cathodically hydrogen-charging and tensile testing. The 20 °C pre-strain greatly strengthened the steel but simultaneously significantly increased the HE susceptibility of the steel since α′ martensite was induc Read More

Interest in hydrogen as a carbon-neutral energy carrier is on the rise around the globe including in Europe. In particular power-to-gas as a technology to transform electricity to hydrogen is receiving ample attention. This article scrutinises current updates in the energy law framework of the EU to explain the legal pre-conditions for the various possible applications of power-to-gas technology. It highlights the influence of both electricity and gas legislatio Read More

Taiwan stands out globally in the manufacture of scooters. If fuel cell technology could be applied to the scooter Taiwan could gain an advantage in the trend for commercial applications for fct. In 2011 The Bureau of Standards Metrology and Inspection proposed this project “the Demonstration of Hydrogen Fuel Cell Scooters.” Thirty rental fuel cell scooters are to run a long distance. Evaluation during everyday use of the cells performance will be made an Read More

The presence of a conductive layers of hot-formed oxide on the surface of bars for pre or post-compressing structures can promote localized attacks as a function of pH. The aggressive local environment in the occluded cells inside localized attacks has as consequence the possibility of initiation of stress corrosion cracking. In this paper the stress corrosion cracking behavior of high strength steels proposed for tendons was studied by means of Con Read More

The report documents current knowledge of the social issues surrounding hydrogen projects. It reviews leading practice stakeholder engagement and communication strategies and findings from focus groups and research activities across Australia.The full report can be found at this link.

Deployed at scale hydrogen could account for almost one-fifth of total final energy consumed by 2050. This would reduce annual CO2 emissions by roughly 6 gigatons compared to today’s levels and contribute roughly 20% of the abatement required to limit global warming to two degrees Celsius.On the demand side the Hydrogen Council sees the potential for hydrogen to power about 10 to 15 million cars and 500000 trucks by 2030 with many uses in othe Read More

There is significant interest in Australia both federally and at the state level to develop a hydrogen production industry. Australia’s Chief Scientist Alan Finkel recently prepared a briefing paper for the COAG Energy Council outlining a road map for hydrogen. It identifies hydrogen has the potential to be a significant source of export revenue for Australia in future years assist with decarbonising Australia’s economy and could establish Australia as a leader in lo Read More

This policy statement provides:An overview of our key priorities for the short to medium-term and then moves on to look at how we have continued to abide by the three key principles set out in Scotland's Energy Strategy published in 2017 in our policy design and delivery. Those principles are:a whole-system view;an inclusive energy transition; anda smarter local energy model.An overview of how we have committed to ensuring a green economic recov Read More

Structural integrity of reactor pressure vessel (RPV) in light water reactors (LWR) is of highest importance regarding operation safety and lifetime. The fracture behaviour of low-alloy RPV steels with different dynamic strain aging (DSA) & environmental assisted cracking (EAC) susceptibilities in simulated LWR environments was evaluated by elastic plastic fracture mechanics tests (EPFM) and by metallo- and fractographic post-test analysis. Exposure to h Read More

Fuel cells are the most clean and efficient power source for vehicles. In particular proton exchange membrane fuel cells (PEMFCs) are the most promising candidate for automobile applications due to their rapid start-up and low-temperature operation. Through extensive global research efforts in the latest decade the performance of PEMFCs including energy efficiency volumetric and mass power density and low temperature startup ability have achi Read More

Alloying and structural modification are two effective ways to enhance the hydrogen storage kinetics and decrease the thermal stability of Mg and Mg-based alloys. In order to enhance the characteristics of Mg2Ni-type alloys Cu and La were added to an Mg2Ni-type alloy and the sample alloys (Mg24Ni10Cu2)100−xLax (x = 0 5 10 15 20) were prepared by melt spinning. The influences of La content and spinning rate on the gaseous and e Read More

Recent advances on synthesis characterization and hydrogen absorption properties of ultrasmall metal nanoparticles (defined here as objects with average size ≤3 nm) are briefly reviewed in the first part of this work. The experimental challenges encountered in performing accurate measurements of hydrogen absorption in Mg- and noble metal-based ultrasmall nanoparticles are addressed. The second part of this work reports original results obtained for Read More

Chemical looping water splitting or chemical looping hydrogen is a very promising technology for the production of hydrogen. In recent years extensive research has enabled remarkable leaps towards a successful integration of the chemical looping technology into a future hydrogen infrastructure. Progress has been reported with iron based oxygen carriers for stable hydrogen production capacity over consecutive cycles without significant signs of de Read More