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A Numerical Investigation on De-NOx Technology and Abnormal Combustion Control for a Hydrogen Engine with EGR System
Sep 2020
Publication
The combustion emissions of the hydrogen-fueled engines are very clean but the problems of abnormal combustion and high NOx emissions limit their applications. Nowadays hydrogen engines use exhaust gas recirculation (EGR) technology to control the intensity of premixed combustion and reduce the NOx emissions. This study aims at improving the abnormal combustion and decreasing the NOx emissions of the hydrogen engine by applying a three-dimensional (3D) computational fluid dynamics (CFD) model of a single-cylinder hydrogen-fueled engine equipped with an EGR system. The results indicated that peak in-cylinder pressure continuously increased with the increase of the ignition advance angle and was closer to the top dead center (TDC). In addition the mixture was burned violently near the theoretical air–fuel ratio and the combustion duration was shortened. Moreover the NOx emissions the average pressure and the in-cylinder temperature decreased as the EGR ratio increased. Furthermore increasing the EGR ratio led to an increase in the combustion duration and a decrease in the peak heat release rate. EGR system could delay the spontaneous combustion reaction of the end-gas and reduce the probability of knocking. The pressure rise rate was controlled and the in-cylinder hot spots were reduced by the EGR system which could suppress the occurrence of the pre-ignition in the hydrogen engine.
An Experimental Study of the Possibility of In Situ Hydrogen Generation within Gas Reservoirs
Aug 2021
Publication
Hydrogen can be generated in situ within reservoirs containing hydrocarbons through chemical reactions. This technology could be a possible solution for low-emission hydrogen production due to of simultaneous CO2 storage. In gas fields it is possible to carry out the catalytic methane conversion (CMC) if sufficient amounts of steam catalyst and heat are ensured in the reservoir. There is no confirmation of the CMC’s feasibility at relatively low temperatures in the presence of core (reservoir rock) material. This study introduces the experimental results of the first part of the research on in situ hydrogen generation in the Promyslovskoye gas field. A set of static experiments in the autoclave reactor were performed to study the possibility of hydrogen generation under reservoir conditions. It was shown that CMC can be realized in the presence of core and ex situ prepared Ni-based catalyst under high pressure up to 207 atm but at temperatures not lower than 450 ◦C. It can be concluded that the crushed core model improves the catalytic effect but releases carbon dioxide and light hydrocarbons which interfere with the hydrogen generation. The maximum methane conversion rate to hydrogen achieved at 450 ◦C is 5.8%
Hydrogen Production from Water Electrolysis: Role of Catalysts
Feb 2021
Publication
As a promising substitute for fossil fuels hydrogen has emerged as a clean and renewable energy. A key challenge is the efcient production of hydrogen to meet the commercial-scale demand of hydrogen. Water splitting electrolysis is a promising pathway to achieve the efcient hydrogen production in terms of energy conversion and storage in which catalysis or electrocatalysis plays a critical role. The development of active stable and low-cost catalysts or electrocatalysts is an essential prerequisite for achieving the desired electrocatalytic hydrogen production from water splitting for practical use which constitutes the central focus of this review. It will start with an introduction of the water splitting performance evaluation of various electrocatalysts in terms of activity stability and efciency. This will be followed by outlining current knowledge on the two half-cell reactions hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in terms of reaction mechanisms in alkaline and acidic media. Recent advances in the design and preparation of nanostructured noble-metal and non-noble metal-based electrocatalysts will be dis‑ cussed. New strategies and insights in exploring the synergistic structure morphology composition and active sites of the nanostructured electrocatalysts for increasing the electrocatalytic activity and stability in HER and OER will be highlighted. Finally future challenges and perspectives in the design of active and robust electrocatalysts for HER and OER towards efcient production of hydrogen from water splitting electrolysis will also be outlined.
Life Cycle Assessment of Carbon Footprint in Public Transportation - A Case Study of Bus Route NO. 2 in Tainan City, Taiwan
Apr 2019
Publication
Human activities have exacerbated global greenhouse effects resulting in extreme climate changes that have caused disasters and food and water shortages in recent years. Transport activities are the one of the main causes of global greenhouse gas (GHG) emissions. Therefore policy makers must develop some strategies to reduce GHG emissions. One of the Taiwan’s transportation policies intended to reduce CO2 emissions is to replace all traditional diesel fuel urban buses with alternative energy buses. This paper uses a case study of bus route NO. 2 in Tainan City and follows the international standard ISO/TS 14067 and PAS2050 to measure the carbon footprints of different energy buses. The purpose is to measure the environmental benefits of alternative energy buses. The results of the bus carbon footprints from high to low were LNG buses 63.14g CO2e/pkm; traditional diesel buses 54.6g CO2e/pkm; liquefied petroleum gas buses 47.4g CO2e/pkm; plug-in electric buses 37.82g CO2e/pkm and hydrogen fuel cell bus es 29.17g CO2e/pkm respectively. It was also found that the use of hydrogen fuel cell buses would potentially reduce CO2e emissions in Tainan City by 1244081 tons which at this time is only city bus No. 2. If all the Taiwan city buses were switched to hydrogen fuel cell buses this would potentially reduce CO2e by 227832.39 tons. The effect of the reduction in carbon emissions from the use of hydrogen fuel cells buses in all Taiwanese urban areas is the equivalent of planting 22.78 million trees. It is thus suggested that the government use hydrogen fuel cell buses as the future of the country’s major alternative energy buses since they are the most environmentally friendly alternative to reducing CO2 emissions.
A Technical, Economic and Environmental Analysis of Combining Geothermal Energy with Carbon Sequestration for Hydrogen Production
Jul 2014
Publication
Among numerous techniques for the hydrogen production without harmful emissions especially avoiding the carbon dioxide emissions hydrogen technologies driven by geothermal energy represent an attractive solution. This paper is interested in the process by which the electricity generated from geothermal power plant that is operated using CO2 as heat transmission fluid is exploited for hydrogen production through water electrolysis. A numerical simulation is used to evaluate the potential for hydrogen production and to estimate the levelized cost of electrolytic hydrogen. We also present brief analysis of environmental issues including the carbon tax. The results show that the process has a good potential for geothermal hydrogen production is capable of producing about 22 kg/h of electrolytic hydrogen for the geothermal source of carbon dioxide mass flow rate of 40 kg/s and a temperature of 296 K. In economic regard the electric energy system costs are the major component of the total hydrogen production cost (more than 90%). The estimated cost of hydrogen is 8.24 $/kg H2. By including the carbon tax the cost of hydrogen production becomes far more competitive.
Efficiency, Economic and Environmental Impact Assessment of a Newly Developed Rail Engine using Hydrogen and Other Sustainable Fuel Blends
Jan 2023
Publication
Locomotives still use antiqued engines such as internal combustion engines operated by fossil fuels which cause global warming due to their significant emissions. This paper continues investigating the newly hybridized locomotive engine containing a gas turbine system solid oxide fuel cell system energy saving system and on-board hydrogen production system. This new engine is operated using five fuel blends composed of five alternative fuels such as hydrogen methane methanol ethanol and dimethyl ether. The current investigation involves exergy analysis exergo-economic analysis and exergo-environmental analysis to assess the engine from three perspectives: efficiency/irreversibility cost and environmental impact. The study results show that the net power of this new engine is 4948.6 kW and it has an exergetic efficiency of 62.7% according to the fuel and product principle. This engine weighs about 9 tons and costs about $10.2M with a levelized cost rate of 147 $/h and 14.06 mPt/h of overall component-related environmental rate. The average overall specific fuel and product exergy costs are about 37 $/GJ and 60 $/GJ and the minimum values are 13.3 $/GJ and 21.8 $/GJ using methane and hydrogen blend respectively. Also the average overall specific fuel and product exergo-environmental impact are about 15 and 23 mPt/MJ respectively. The on-board hydrogen production has an average exergy cost of 274 $/GJ and an environmental impact of 52 mPt/MJ. Hydrogen blended with methane or methanol is found to be more economic and has less environmental impact.
Economic and Technical Analysis of Power to Gas Factory Taking Karamay as an Example
May 2022
Publication
Power to gas (PTG) refers to the technology of converting power into energy-storage gas which can absorb excess power when there is excess power and release energy-storage gas when needed. Based on the carbon dioxide (CO2 ) emission of Karamay City in Northwest China this study designed a process flow of the CO2 absorption process and the hydrogen and CO2 methanation process in PTG technology. The results show that the efficiency of the CO2 absorption process was 91.5% and the methanation efficiency was 77.5%. The heat recovery module was set during the process and the total heat recovered was 17.85 MW. The cost of producing synthetic natural gas (SNG) in the PTG factory was 1782 USD/ton. In terms of cost the cost of hydrogen production from electrolyzed water accounted for the largest proportion. In terms of product profit the sale of pure oxygen was the largest part of the profit. At present the carbon emission reduction index profit brought by SNG production accounted for a small proportion. In the future with technological progress industrial upgrading and the improvement in the carbon trading market PTG technology is expected to become one of the ways to achieve carbon-emission-reduction targets.
Risk Assessment of the Low-carbon Transition of Austria’s Steel and Electricity Sectors
Dec 2018
Publication
To limit global temperature increase below +2°C societies need to reduce greenhouse gas emissions radically within the next few decades. Amongst other mitigation measures this requires transforming process-emission intensive industries towards emission neutrality. One way to this end is the renewables-based electrification of industries. We present results of a recent coproduction process which brought together stakeholders from industry policy administration and science to co-create climate-neutral transition pathways for the steel and electricity sectors in Austria. The results summarized here are the definition of reliable pathways and the identification of associated risks pertaining to pathway implementation including a macro-economic quantification. We find that risks to implementation (barriers) are at least as important as risks of implementation (negative consequences). From the quantitative analysis we find that provided that barriers can be reduced macroeconomic costs of the transition are only moderate and that stakeholders might overestimate risks when neglecting economy-wide feedbacks.
Blowout Prediction on a Salt Cavern Selected for a Hydrogen Storage Pilot
Oct 2022
Publication
To prevent climate change Europe and the world must shift to low-carbon and renewable energies. Hydrogen as an energy vector provides viable solutions for replacing polluting and carbon-emitting fossil fuels. Gaseous hydrogen can be stored underground and coupled with existing natural gas pipe networks. Salt cavern storage is the best suited technology to meet the challenges of new energy systems. Hydrogen storage caverns are currently operated in the UK and Texas. A preliminary risk analysis dedicated to underground hydrogen salt caverns highlighted the importance of containment losses (leaks) and the formation of gas clouds following blowouts whose ignition may generate dangerous phenomena such as jet fires unconfined vapor cloud explosions (UVCEs) or flashfires. A blowout is not a frequent accident in gas storage caverns. A safety valve is often set at a 30 m depth below ground level; it is automatically triggered following a pressure drop at the wellhead. Nevertheless a blowout remains to be one of the significant accidental scenarios likely to occur during hydrogen underground storage in salt caverns. In this paper we present modelling the subterraneous and aerial parts of a blowout on an EZ53 salt cavern fully filled with hydrogen.
Effect of Au Plasmonic Material on Poly M-Toluidine for Photoelectrochemical Hydrogen Generation from Sewage Water
Feb 2022
Publication
This study provides H2 gas as a renewable energy source from sewage water splitting reaction using a PMT/Au photocathode. So this study has a dual benefit for hydrogen generation; at the same time it removes the contaminations of sewage water. The preparation of the PMT is carried out through the polymerization process from an acid medium. Then the Au sputter was carried out using the sputter device under different times (1 and 2 min) for PMT/Au-1 min and PMT/Au-2min respectively. The complete analyses confirm the chemical structure such as XRD FTIR HNMR SEM and Vis-UV optical analyses. The prepared electrode PMT/Au is used for the hydrogen generation reaction using Na2S2O3 or sewage water as an electrolyte. The PMT crystalline size is 15 nm. The incident photon to current efficiency (IPCE) efficiency increases from 2.3 to 3.6% (at 390 nm) and the number of H2 moles increases from 8.4 to 33.1 mmol h−1 cm−2 for using Na2S2O3 and sewage water as electrolyte respectively. Moreover all the thermodynamic parameters such as activation energy (Ea) enthalpy (∆H*) and entropy (∆S*) were calculated; additionally a simple mechanism is mentioned for the water-splitting reaction.
Biohydrogen—A Green Fuel for Sustainable Energy Solutions
Oct 2022
Publication
Energy plays a crucial role in the sustainable development of modern nations. Today hydrogen is considered the most promising alternative fuel as it can be generated from clean and green sources. Moreover it is an efficient energy carrier because hydrogen burning only generates water as a byproduct. Currently it is generated from natural gas. However it can be produced using other methods i.e. physicochemical thermal and biological. The biological method is considered more environmentally friendly and pollution free. This paper aims to provide an updated review of biohydrogen production via photofermentation dark fermentation and microbial electrolysis cells using different waste materials as feedstocks. Besides the role of nanotechnology in enhancing biohydrogen production is examined. Under anaerobic conditions hydrogen is produced during the conversion of organic substrate into organic acids using fermentative bacteria and during the conversion of organic acids into hydrogen and carbon dioxide using photofermentative bacteria. Different factors that enhance the biohydrogen production of these organisms either combined or sequentially using dark and photofermentation processes are examined and the effect of each factor on biohydrogen production efficiency is reported. A comparison of hydrogen production efficiency between dark fermentation photofermentation and two-stage processes is also presented.
Application and Limitations of Batteries and Hydrogen in Heavy Haul Rail using Australian Case Studies
Oct 2022
Publication
Decarbonisation of heavy haul rail is an essential contributor to a zero-emissions future. However the transition from diesel to battery locomotives is not always practical given the unique characteristics of each haul. This paper demonstrates the limitations of state-of-the-art batteries using real-world data from multiple locomotives operating in Australian rail freight. An energy model was developed to assess each route’s required energy and potential regenerated energy. The tractive and regenerative battery energy mass and cost were determined using data from the energy model coupled with battery specifications. The feasibility of implementing lithium iron phosphate (LFP) nickel manganese cobalt (NMC) and lithium titanium oxide (LTO) chemistries was explored based on cost energy density cycle lifespan and locomotive data. LFP was identified as the most suitable current battery solution based on current chemistries. Further examination of the energy demands and associated mass/volume constraints concluded that three platforms are required for heavy haul rail decarbonisation i) a battery electric locomotive for low-energy demands which can be coupled with either ii) a battery electric tender for medium energy demands or iii) a hydrogen fuel cell electric tender for higher energy demands. A future-looking techno-economic assessment of battery and hydrogen fuel cell platforms concludes that the lowest cost solution for low-energy hauls is a battery-only system and for high-energy hauls a battery-hydrogen system.
OIES Podcast: Global Trade of Hydrogen: What is the Best Way to Transfer Hydrogen Over Long Distances?
Aug 2022
Publication
In this podcast David Ledesma talks with Rahmat Poudineh Senior Research Fellow and Aliaksei Patonia Research Fellow on issues and options with respect to long distance transportation of the hydrogen.
Hydrogen currently is mainly a local or regional commodity. If hydrogen is to become a truly global-traded commodity it needs to be transported over long transoceanic distances in an economical way. However unlike natural gas shipping compressed or liquefied hydrogen over long distances is very inefficient and expensive. At the same time hydrogen can be converted into multiple carriers with a higher energy density and higher transport capacity such as liquid ammonia toluene/methylcyclohexane (MCH) or methanol. These chemicals have their own advantages and drawbacks and their techno-economic characteristics in terms of boil-off gas and thermodynamic and conversion losses play a key role in the efficiency of transoceanic transportation of the hydrogen.
On the other hand apart from techno-economic features there are other factors to consider for long distance transportation of the hydrogen via its careers. Here such issues as safety public acceptance as well as legal and regulatory constraints may come into play. Another factor is the availability of the industries and infrastructures already developed around any of possible hydrogen carriers as well as their potential industrial applicability beyond hydrogen. Finally technological progress in other decarbonization applications and most importantly full commercialization of CCUS solutions is likely to dramatically change the approach towards long distance hydrogen transportation.
The podcast can be found on their website.
Hydrogen currently is mainly a local or regional commodity. If hydrogen is to become a truly global-traded commodity it needs to be transported over long transoceanic distances in an economical way. However unlike natural gas shipping compressed or liquefied hydrogen over long distances is very inefficient and expensive. At the same time hydrogen can be converted into multiple carriers with a higher energy density and higher transport capacity such as liquid ammonia toluene/methylcyclohexane (MCH) or methanol. These chemicals have their own advantages and drawbacks and their techno-economic characteristics in terms of boil-off gas and thermodynamic and conversion losses play a key role in the efficiency of transoceanic transportation of the hydrogen.
On the other hand apart from techno-economic features there are other factors to consider for long distance transportation of the hydrogen via its careers. Here such issues as safety public acceptance as well as legal and regulatory constraints may come into play. Another factor is the availability of the industries and infrastructures already developed around any of possible hydrogen carriers as well as their potential industrial applicability beyond hydrogen. Finally technological progress in other decarbonization applications and most importantly full commercialization of CCUS solutions is likely to dramatically change the approach towards long distance hydrogen transportation.
The podcast can be found on their website.
Techno-Economic Analysis of Hydrogen Storage Technologies for Railway Engineering: A Review
Sep 2022
Publication
According to the specific requirements of railway engineering a techno-economic comparison for onboard hydrogen storage technologies is conducted to discuss their feasibility and potentials for hydrogen-powered hybrid trains. Physical storage methods including compressed hydrogen (CH2 ) liquid hydrogen (LH2 ) and cryo-compressed hydrogen (CcH2 ) and material-based (chemical) storage methods such as ammonia liquid organic hydrogen carriages (LOHCs) and metal hydrides are carefully discussed in terms of their operational conditions energy capacity and economic costs. CH2 technology is the most mature now but its storage density cannot reach the final target which is the same problem for intermetallic compounds. In contrast LH2 CcH2 and complex hydrides are attractive for their high storage density. Nevertheless the harsh working conditions of complex hydrides hinder their vehicular application. Ammonia has advantages in energy capacity utilisation efficiency and cost especially being directly utilised by fuel cells. LOHCs are now considered as a potential candidate for hydrogen transport. Simplifying the dehydrogenation process is the important prerequisite for its vehicular employment. Recently increasing novel hydrogen-powered trains based on different hydrogen storage routes are being tested and optimised across the world. It can be forecasted that hydrogen energy will be a significant booster to railway decarbonisation.
A Mini-review on Recent Trends in Prospective Use of Porous 1D Nanomaterials for Hydrogen Storage
Nov 2021
Publication
The sustainable development of hydrogen energy is a priority task for a possible solution to 26 the global energy crisis. Hydrogen is a clean and renewable energy source that today is used 27 exclusively in the form of compressed gas or in liquefied form which prevents its widespread 28 use. Storing hydrogen in solid-state systems will not only increase the bulk density and 29 gravimetric capacity but will also have a positive impact on safety issues. From this point of 30 view the current review considers the latest research in the field of application of 1D 31 nanomaterials for solid-state hydrogen storage and also discusses the mechanisms of its 32 adsorption and desorption. Despite the high publication activity the use of 1D nanomaterials for 33 hydrogen storage has not been fully studied. In the current review modern developments in the 34 field of hydrogen storage using 1D nanomaterials and composites based on them are investigated 35 in detail and their problems and future prospects are discussed.
Next Steps for the Gas Grid- Future Gas Series Part 1
Sep 2014
Publication
Policy Connect Carbon Connect and sector and Parliamentary experts have collaborated to present options for the gas grid to play a useful role in the UK’s transition to a low carbon energy system through the widespread use of low carbon gas. The report calls on Government to support the transition to a more flexible gas grid that uses various forms of gas including low carbon gases such as hydrogen and biomethane.
Far Off-shore Wind Energy-based Hydrogen Production: Technological Assessment and Market Valuation Designs
Jan 2020
Publication
This article provides a techno-economic study on coupled offshore wind farm and green hydrogen production via sea water electrolysis (OWF-H2). Offshore wind energy wind farms (OWF) and water electrolysis (WE) technologies are described. MHyWind (the tool used to perform simulations and optimisations of such plants) is presented as well as the models of the main components in the study. Three case studies focus on offshore wind farms either stand-alone or connected to the grid via export cables coupled with a battery and electrolysis systems either offshore or onshore. Exhaustive searches and optimisations performed allowed for rules of thumb to be derived on the sizing of coupled OWF-H2 plants that minimize costs of hydrogen production (LCoH2 in €/kgH2): Non-connected OWF-H2 coupled to a battery offers the lowest LCoH2 without the costs of H2 transportation when compared to cases where the WE is installed onshore and connected to the OWF. Using a simple power distribution heuristic increasing the number of installed WE allows the system to take advantage of more OWF energy but doesn’t improve plant efficiency whereas a battery always does. Finally within the scope of this study it is observed that power ratios of optimized plant architectures (leading to the lowest LCoH2) are between 0.8-0.9 for PWE/POWF and 0.3-0.35 for PBattery/POWF.
Building the Green Hydrogen Market - Current State and Outlook on Green Hydrogen Demand and Electrolyzer Manufacturing
Jul 2022
Publication
Over the past two years requirements to meet climate targets have been intensified. In addition to the tightening of the climate targets and the demand for net-zero achievement by as early as 2045 there have been discussions on implementing and realizing these goals. Hydrogen has emerged as a promising climate-neutral energy carrier. Thus over the last 1.5 years more than 25 countries have published hydrogen roadmaps. Furthermore various studies by different authorities have been released to support the development of a hydrogen economy. This paper examines published studies and hydrogen country roadmaps as part of a meta-analysis. Furthermore a market analysis of electrolyzer manufacturers is conducted. The prospected demand for green hydrogen from various studies is compared to electrolyzer manufacturing capacities and selected green hydrogen projects to identify potential market ramp-up scenarios and to evaluate if green hydrogen demand forecasts can be filled.
Effects of Compression Ratios on Combustion and Emission Characteristics of SI Engine Fueled with Hydrogen-Enriched Biogas Mixture
Aug 2022
Publication
The effects of hydrogen-enriched biogas on combustion and emissions of a dual-fuel sparkignition engine with different hydrogen concentration ratios were studied numerically. A 1-cylinder spark ignition was used to perform a numerical simulation. To reveal the influence of the compression ratios on combustion and emissions of a gaseous engine the crankshaft of the engine was modified to generate different compression ratios of 8.5 9.0 9.4 10.0 and 10.4. The biogas contained 60 and 40% methane (CH4 ) and carbon dioxide (CO2 ) respectively while the hydrogen fractions used to enrich biogas were 10 20 and 30% of the mixture by volume. The ignition timing is fixed at 350 CA◦ . The results indicate that the in-cylinder pressure combustion temperature and combustion burning speed increase gradually with increasing hydrogen concentration due to the combustion characteristics of hydrogen in blends. As increasing the compression ratio NOx emissions increase proportionally while CO2 emissions decrease gradually. Almost no combustion process occurs as operating the compression ratio below 8.5 when using pure biogas. However adding 20% of hydrogen fraction could improve the combustion process significantly even at a low compression ratio.
Assessment of Hydrogen Fuel for Rotorcraft Applications
Jun 2022
Publication
This paper presents the application of a multidisciplinary approach for the preliminary design and evaluation of the potential improvements in performance and environmental impact through the utilization of compressed (CGH2) and liquefied (LH2) hydrogen fuel for a civil tilt-rotor modelled after the NASA XV-15. The methodology deployed comprises models for rotorcraft flight dynamics engine performance flight path analysis hydrogen tank and thermal management system sizing. Trade-offs between gravimetric efficiency energy consumption fuel burn CO2 emissions and cost are quantified and compared to the kerosene-fuelled rotorcraft. The analysis carried out suggests that for these vehicle scales gravimetric efficiencies of the order of 13% and 30% can be attained for compressed and liquid hydrogen storage respectively leading to reduced range capability relative to the baseline tilt-rotor by at least 40%. At mission level it is shown that the hydrogen-fuelled configurations result in increased energy consumption by at least 12% (LH2) and 5% (CGH2) but at the same time significantly reduced life-cycle carbon emissions compared to the kerosene counterpart. Although LH2 storage at cryogenic conditions has a higher gravimetric efficiency than CGH2 (at 700 bar) it is shown that for this class of rotorcraft the latter is more energy efficient when the thermal management system for fuel pressurization and heating prior to combustion is accounted for.
Planetary Boundaries Assessment of Deep Decarbonisation Options for Building Heating in the European Union
Jan 2023
Publication
Building heating is one of the sectors for which multiple decarbonisation options exist and current geopolitical tensions provide urgency to design adequate regional policies. Heat pumps and hydrogen boilers alongside alternative district heating systems are the most promising alternatives. Although a host of city or country-level studies exist it remains controversial what role hydrogen should play for building heating in the European Union compared with electrification and how blue and green hydrogen differ in terms of costs and environmental impacts. This works assesses the optimal technology mix for staying within planetary boundaries and the influence of international cooperation and political restrictions. To perform the analysis a bottom-up optimisation model was developed incorporating life cycle assessment constraints and covering production storage transport of energy and carbon dioxide as well as grid and non-grid connected end-users of heat. It was found that a building heating system within planetary boundaries is feasible through large-scale electrification via heat pumps although at a higher cost than the current system with abatement costs of around 200 €/ton CO2. Increasing interconnector capacity or onshore wind energy is found to be vital to staying within boundaries. A strong trade-off for hydrogen was identified with blue hydrogen being cost-competitive but vastly unsustainable (when applied to heating) and green hydrogen being 2–3 times more expensive than electrification while still transgressing several planetary boundaries. The insights from this work indicate that heat pumps and renewable electricity should be prioritised over hydrogen-based heating in most cases and grid-stability and storage aspects explored further while revealing a need for policy instruments to mitigate increased costs for consumers.
Safety Compliance Verification of Fuel Cell Electric Vehicle Exhaust
Sep 2021
Publication
NREL has been developing compliance verification tools for allowable hydrogen levels prescribed by the Global Technical Regulation Number 13 (GTR-13) for hydrogen fuel cell electric vehicles (FCEVs). As per GTR-13 FCEV exhaust is to remain below 4 vol% H2 over a 3-second moving average and shall not at any time exceed 8 vol% H2 and that this requirement is to be verified with an analyzer that has a response time of less than 300 ms. To be enforceable a means to verify regulatory requirements must exist. In response to this need NREL developed a prototype analyzer that meets the GTR metrological requirements for FCEV exhaust analysis. The analyzer was tested on a commercial fuel cell electric vehicle (FCEV) under simulated driving conditions using a chassis dynamometer at the Emissions Research and Measurement Section of Environment and Climate Change Canada and FCEV exhaust was successfully profiled. Although the prototype FCEV Exhaust Analyzer met the metrological requirements of GTR-13 the stability of the hydrogen sensor was adversely impacted by condensed water in the sample gas. FCEV exhaust is at an elevated temperature and nearly saturated with water vapor. Furthermore condensed water is present in the form of droplets. Condensed water in the sample gas collected from FCEV exhaust can accumulate on the hydrogen sensing element which would not only block access of hydrogen to the sensing element but can also permanently damage the sensor electronics. In the past year the design of the gas sampling system was modified to mitigate against the transport of liquid water to the sensing element. Laboratory testing confirmed the effectiveness of the modified sampling system water removal strategy while maintaining the measurement range and response time required by GTR-13. Testing of the upgraded analyzer design on an FCEV operating on a chassis dynamometer is scheduled for the summer of 2021.
Recent Advances in Methane Pyrolysis: Turquoise Hydrogen with Solid Carbon Production
Aug 2022
Publication
Beside steam reforming methane pyrolysis is an alternative method for hydrogen production. ‘Turquoise’ hydrogen with solid carbon is formed in the pyrolysis process contrary to ‘grey’ or ‘blue’ hydrogen via steam methane reforming where waste carbon dioxide is produced. Thermal pyrolysis is conducted at higher temperatures but catalytic decomposition of methane (CDM) is a promising route for sustainable hydrogen production. CDM is generally carried out over four types of catalyst: nickel carbon noble metal and iron. The applied reactors can be fixed bed fluidized bed plasma bed or molten-metal reactors. Two main advantages of CDM are that (i) carbon-oxide free hydrogen ideal for fuel cell applications is formed and (ii) the by-product can be tailored into carbon with advanced morphology (e.g. nanofibers nanotubes). The aim of this review is to reveal the very recent research advances of the last two years achieved in the field of this promising prospective technology.
Roadmap to Achieving Sustainable Development via Green Hydrogen
Jan 2023
Publication
The conversion to renewable energy can be achieved when cities and communities start to depend on sustainable resources capable of providing for the basic needs of the community along with a reduction in the daily problems and issues that people face. These issues such as poverty hunger sanitation and economic difficulties are highlighted in the Sustainable Development Goals (SDGs) which aim to limit and eradicate these problems along with other environmental obstacles including climate change and Greenhouse Gases (GHGs). These SDGs containing 17 goals target each sector and provide propositions to solve such devastating problems. Hydrogen contributes to the targets of these sustainable developments since through its implementation in different industries the levels of GHG will drop and thus contribute to the climate change which Earth is facing. Further through the usage of such resources many job opportunities will also be developed thus enhancing the economy and lifting the status of society. This paper classifies the four different types of hydrogen and outlines the differences between them. The paper then emphasizes the importance of green hydrogen use within the shipping industry transportation and infrastructure along with economic and social development through job opportunities. Furthermore this paper provides case studies tackling green hydrogen status in the United Kingdom United States of America and European Union as well as Africa United Arab of Emirates and Asia. Finally challenges and recommendations concerning the green hydrogen industry are addressed. This paper aims to relate the use of green hydrogen to the direct and indirect goals of SDG.
Clean Energy Futures: An Australian Based Foresight Study
Aug 2022
Publication
Political decarbonisation commitments and outcompeting renewable electricity costs are disrupting energy systems. This foresight study prepares stakeholders for this dynamic reactive change by examining visions that constitute a probable plausible and possible component of future energy systems. Visions were extrapolated through an expert review of energy technologies and Australian case studies. ‘Probable–Abundant’ envisages a high penetration of solar and wind with increased value of balancing services: batteries pumped hydro and transmission. This vision is exemplified by the South Australian grid where variable and distributed sources lead generation. ‘Plausible–Traded’ envisages power and power fuel exports given hydrogen and high-voltage direct-current transmission advances reflected by public and private sector plans to leverage rich natural resources for national and intercontinental exchanges. ‘Possible–Zero’ envisages the application of carbon removal and nuclear technologies in response to the escalating challenge of deep decarbonisation. The Australian critical minerals strategy signals adaptations of high-emission industries to shifting energy resource values. These visions contribute a flexible accessible framework for diverse stakeholders to discuss uncertain energy systems changes and consider issues from new perspectives. Appraisal of preferred futures allows stakeholders to recognise observed changes as positive or negative and may lead to new planning aspirations.
Hydrogen Production from Sea Wave for Alternative Energy Vehicles for Public Transport in Trapani (Italy)
Oct 2016
Publication
The coupling of renewable energy and hydrogen technologies represents in the mid-term a very interesting way to match the tasks of increasing the reliable exploitation of wind and sea wave energy and introducing clean technologies in the transportation sector. This paper presents two different feasibility studies: the first proposes two plants based on wind and sea wave resource for the production storage and distribution of hydrogen for public transportation facilities in the West Sicily; the second applies the same approach to Pantelleria (a smaller island) including also some indications about solar resource. In both cases all buses will be equipped with fuel-cells. A first economic analysis is presented together with the assessment of the avoidable greenhouse gas emissions during the operation phase. The scenarios addressed permit to correlate the demand of urban transport to renewable resources present in the territories and to the modern technologies available for the production of hydrogen from renewable energies. The study focuses on the possibility of tapping the renewable energy potential (wind and sea wave) for the hydrogen production by electrolysis. The use of hydrogen would significantly reduce emissions of particulate matter and greenhouse gases in urban districts under analysis. The procedures applied in the present article as well as the main equations used are the result of previous applications made in different technical fields that show a good replicability.
Cost and Capacity Requirements of Electrification or Renewable Gas Transition Options that Decarbonize Building Heating in Metro Vancouver, British Columbia
Jun 2022
Publication
Northern countries face a unique challenge in decarbonizing heating demands. This study compares two pathways to reduce carbon emissions from building heating by (1) replacing natural gas heaters with electric heat pumps or (2) replacing natural gas with renewable gas. Optimal annual system cost and capacity requirements for Metro Vancouver Canada are assessed for each pathway under nine scenarios. Results show that either pathway can be lower cost but the range of costs is more narrow for the renewable gas pathway. System cost is sensitive to heat demand with colder temperatures favouring the renewable gas pathway and milder temperatures favouring the electrification pathway. These results highlight the need for a better understanding of heating profiles and associated energy system requirements.
Estimation of Liquid Hydrogen Fuels in Aviation
Sep 2022
Publication
As the demand for alternative fuels to solve environmental problems increases worldwide due to the greenhouse gas problem this study predicted the demand for liquid hydrogen fuel in aviation to achieve ‘zero‐emission flight’. The liquid hydrogen fuel models of an aircraft and all aviation sectors were produced based on the prediction of aviation fleet growth through the classification of currently operated aircraft. Using these models the required amount of liquid hydrogen fuel and the total cost of liquid hydrogen were also calculated when various environmental regulations were satisfied. As a result it was found to be necessary to convert approximately 66% to 100% of all aircraft from existing aircraft to liquid hydrogen aircraft in 2050 according to regulations. The annual liquid hydrogen cost was 4.7–5.2 times higher in the beginning due to the high production cost but after 2030 it will be maintained at almost the same price and it was found that the cost was rather low compared to jet fuel.
Policy and Pricing Barriers to Steel Industry Decarbonisation: A UK Case Study
Aug 2022
Publication
Global climate targets have highlighted the need for a whole-systems approach to decarbonisation one that includes targeted national policy and industry specific change. Situated within this context this research examines policy and pricing barriers to decarbonisation of the UK steel industry. Here the techno-economic modelling of UK green steelmaking provides a technical contribution to analysis of pricing barriers and policy solutions to these barriers in the UK specifically but also to the broader industrial decarbonisation literature. Estimated costs and associated emissions projections reveal relevant opportunities for UK steel in contributing to national climate and emissions targets. Modelling demonstrates that green steelmaking options have been put at price disadvantages compared to emissions-intensive incumbents and that fossil-free hydrogen-based steel-making has lower emissions and lower levelised costs than carbon capture and storage options including top gas recycling blast furnace (TGR-BF) with CCS and HIsarna smelter with CCS. Two primary policy recommendations are made: the removal of carbon pricing discrepancies and reductions in industrial electricity prices that would level the playing field for green steel producers in the UK. The research also provides relevant policy considerations for the international community in other industrial decarbonisation efforts and the policies that must accompany these decarbonisation choices.
Impacts of Greenhouse Gas Neutrality Strategies on Gas Infrastructure and Costs: Implications from Case Studies Based on French and German GHG-neutral Scenarios
Sep 2022
Publication
The European Union’s target to reach greenhouse gas neutrality by 2050 calls for a sharp decrease in the consumption of natural gas. This study assesses impacts of greenhouse gas neutrality on the gas system taking France and Germany as two case studies which illustrate a wide range of potential developments within the European Union. Based on a review of French and German GHG-neutral scenarios it explores impacts on gas infrastructure and estimates the changes in end-user methane price considering a business-as-usual and an optimised infrastructure pathway. Our results show that gas supply and demand radically change by mid-century across various scenarios. Moreover the analysis suggests that deep transformations of the gas infrastructure are required and that according to the existing pricing mechanisms the end-user price of methane will increase driven by the switch to low-carbon gases and intensified by infrastructure costs.
Review of Energy Challenges and Horizons of Hydrogen City Buses
Sep 2022
Publication
This paper discusses fuel cell electric vehicles and more specifically the challenges and development of hydrogen-fueled buses for people accessing this transportation in cities and urban environments. The study reveals the main innovations and challenges in the field of hydrogen bus deployment and identifies the most common approaches and errors in this area by extracting and critically appraising data from sources important to the energy perspective. Three aspects of the development and horizons of fuel cell electric buses are reviewed namely energy consumption energy efficiency and energy production. The first is associated with the need to ensure a useful and sustainable climate-neutral public transport. Herewith the properties of the hydrogen supply of electric buses and their benefits over gasoline gas and battery vehicles are discussed. The efficiency issue is related to the ratio of consumed and produced fuel in view of energy losses. Four types of engines–gasoline diesel gas and electrical–are evaluated in terms of well-to-wheel tank-to-wheel delivery and storage losses. The third problem arises from the production operating and disposal constraints of the society at the present juncture. Several future-oriented initiatives of the European Commission separate countries and companies are described. The study shows that the effectiveness of the FCEBs depends strongly on the energy generation used to produce hydrogen. In the countries where the renewables are the main energy sources the FCEBs are effective. In other regions they are not effective enough yet although the future horizons are quite broad.
Recent Development of Hydrogen and Fuel Cell Technologies: A Review
Aug 2021
Publication
Hydrogen has emerged as a new energy vector beyond its usual role as an industrial feedstock primarily for the production of ammonia methanol and petroleum refining. In addition to environmental sustainability issues energy-scarce developed countries such as Japan and Korea are also facing an energy security issue and hydrogen or hydrogen carriers such as ammonia and methylcyclohexane seem to be options to address these long-term energy availability issues. China has been eagerly developing renewable energy and hydrogen infrastructure to meet their sustainability goals and the growing energy demand. In this review we focus on hydrogen electrification through proton-exchange membrane fuel cells (PEMFCs) which are widely believed to be commercially suitable for automotive applications particularly for vehicles requiring minimal hydrogen infrastructure support such as fleets of taxies buses and logistic vehicles. This review covers all the key components of PEMFCs thermal and water management and related characterization techniques. A special consideration of PEMFCs in automotive applications is the highlight of this work leading to the infrastructure development for hydrogen generation storage and transportation. Furthermore national strategies toward the use of hydrogen are reviewed thereby setting the rationale for the hydrogen economy.
Cost, Footprint, and Reliability Implications of Deploying Hydrogen in Off-grid Electric Vehicle Charging Stations: A GIS-assisted Study for Riyadh, Saudi Arabia
Jul 2022
Publication
For the first time we quantify cost footprint and reliability implications of deploying hydrogen-based generation in off-grid electric vehicle charging stations (CS) using an optimization model coupled with a geographic information system (GIS) analysis for the city of Riyadh Saudi Arabia. We also account for the challenges associated with wind energy deployment as a candidate generation technology within city centers. The analysis was restricted to carbon-free technologies: photovoltaics (PV) wind battery and hydrogen fuel-cells. At current prevailing technology costs hydrogen can reduce the required footprint of off-grid CSs by 25% at a small incremental cost increase without impacting the charging reliability. By 2030 however hydrogen will simultaneously provide the footprint and cost advantages. If we allow as little as 5% of the annual load to be unmet the required footprint of the CS decreases by 60%. The levelized cost of energy values for the CS by 2030 can range between 0.13 and 0.20 $/kWh depending on learning-curve assumptions. The footprints calculated are then mapped to five land parcel categories in Riyadh: gas station hospital mall school and university. Incorporating hydrogen in CS design increases the number of parcels that could accommodate CSs by 15e45% via reducing the required PV array (i.e. footprint).
Charting a Course for Decarbonizing Maritime Transport
Apr 2021
Publication
As the backbone of global trade international maritime transport connects the world and facilitates economic growth and development especially in developing countries. However producing around three percent of global greenhouse gas (GHG) emissions and emitting around 15 percent of some of the world’s major air pollutants shipping is a major contributor to climate change and air pollution. To mitigate its negative environmental impact shipping needs to abandon fossil-based bunker fuels and turn to zero-carbon alternatives. This report the “Summary for Policymakers and Industry” summarizes recent World Bank research on decarbonizing the maritime sector. The analysis identifies green ammonia and hydrogen as the most promising zero-carbon bunker fuels within the maritime industry at present. These fuels strike the most advantageous balance of favorable features relating to their lifecycle GHG emissions broader environmental factors scalability economics and technical and safety implications. The analysis also identifies that LNG will likely only play a limited role in shipping’s energy transition due to concerns over methane slip and stranded assets. Crucially the research reveals that decarbonizing maritime transport offers unique business and development opportunities for developing countries. Developing countries with large renewable energy resources could take advantage of the new and emerging future zero-carbon bunker fuel market estimated at over $1 trillion to establish new export markets while also modernizing their own domestic energy and industrial infrastructure. However strategic policy interventions are needed to hasten the sector’s energy transition.
Hydrogen Deep Ocean Link: A Global Sustainable Interconnected Energy Grid<br/><br/><br/>
Mar 2022
Publication
The world is undergoing a substantial energy transition with an increasing share of intermittent sources of energy on the grid which is increasing the challenges to operate the power grid reliably. An option that has been receiving much focus after the COVID pandemic is the development of a hydrogen economy. Challenges for a hydrogen economy are the high investment costs involved in compression storage and long-distance transportation. This paper analyses an innovative proposal for the creation of hydrogen ocean links. It intends to fill existing gaps in the creation of a hydrogen economy with the increase in flexibility and viability for hydrogen production consumption compression storage and transportation. The main concept behind the proposals presented in this paper consists of using the fact that the pressure in the deep sea is very high which allows a thin and cheap HDPE tank to store and transport large amounts of pressurized hydrogen in the deep sea. This is performed by replacing seawater with pressurized hydrogen and maintaining the pressure in the pipes similar to the outside pressure. Hydrogen Deep Ocean Link has the potential of increasing the interconnectivity of different regional energy grids into a global sustainable interconnected energy system.
Hydrogen Production Technologies: Current State and Future Developments
Mar 2013
Publication
Hydrogen (H2) is currently used mainly in the chemical industry for the production of ammonia and methanol. Nevertheless in the near future hydrogen is expected to become a significant fuel that will largely contribute to the quality of atmospheric air. Hydrogen as a chemical element (H) is the most widespread one on the earth and as molecular dihydrogen (H2) can be obtained from a number of sources both renewable and nonrenewable by various processes. Hydrogen global production has so far been dominated by fossil fuels with the most significant contemporary technologies being the steam reforming of hydrocarbons (e.g. natural gas). Pure hydrogen is also produced by electrolysis of water an energy demanding process. This work reviews the current technologies used for hydrogen (H2) production from both fossil and renewable biomass resources including reforming (steam partial oxidation autothermal plasma and aqueous phase) and pyrolysis. In addition other methods for generating hydrogen (e.g. electrolysis of water) and purification methods such as desulfurization and water-gas shift reactions are discussed.
Progress and Challenges in Multi-stack Fuel Cell System for High Power Applications: Architecture and Energy Management
Jan 2023
Publication
With the development of fuel cells multi-stack fuel cell system (MFCS) for high power application has shown tremendous development potential owing to their obvious advantages including high efficiency durability reliability and pollution-free. Accordingly the state-of-the-art of MFCS is summarized and analyzed to advance its research. Firstly the MFCS applications are presented in high-power scenarios especially in transportation applications. Then to further investigate the MFCS MFCS including hydrogen and air subsystem thermal and water subsystem multi-stack architecture and prognostics and health monitoring are reviewed. It is noted that prognostics and health monitoring are investigated rarely in MFCS compared with previous research. In addition the efficiency and durability of MFCS are not only related to the application field and design principle but also the energy management strategy (EMS). The reason is that the EMS is crucial for lifespan cost and efficiency in the multi-stack fuel cell system. Finally the challenge and development potential of MFCS is proposed to provide insights and guidelines for future research.
Going Global: An Update on Hydrogen Valleys and their Role in the New Hydrogen Economy
Sep 2022
Publication
Hydrogen is a key cornerstone of the green transformation of the global economy and a major lever to diversify energy supplies and accelerate the clean energy transition. Hydrogen will be essential to replace natural gas coal and oil in hard-to-decarbonise sectors in industry mobility and energy. Hydrogen Valleys will become an important cornerstone in producing importing transporting and using clean hydrogen in Europe.
Low-carbon Planning for Park-level Integrated Energy System Considering Optimal Construction Time Sequence and Hydrogen Energy Facility
Apr 2023
Publication
With the increasing concern about global energy crisis and environmental pollution the integrated renewable energy system has gradually become one of the most important ways to achieve energy transition. In the context of the rapid development of hydrogen energy industry the proportion of hydrogen energy in the energy system has gradually increased. The conversion between various energy sources has also become more complicated which poses challenges to the planning and construction of park-level integrated energy systems (PIES). To solve this problem we propose a bi-level planning model for an integrated energy system with hydrogen energy considering multi-stage investment and carbon trading mechanism. First the mathematical models of each energy source and energy storage in the park are established respectively and the independent operation of the equipment is analyzed. Second considering the operation state of multi-energy coordination a bi-level planning optimization model is established. The upper level is the capacity configuration model considering the variable installation time of energy facilities while the lower level is the operation optimization model considering several typical daily operations. Third considering the coupling relationship between upper and lower models the bi-level model is transformed into a solvable single-level mixed integer linear programming (MILP) model by using Karush–Kuhn–Tucker (KKT) condition and big-M method. Finally the proposed model and solution methods are verified by comprehensive case studies. Simulation results show that the proposed model can reduce the operational cost and carbon emission of PIES in the planning horizon and provide insights for the multi-stage investment of PIES.
Analysis of Performance, Emissions, and Lubrication in a Spark-ignition Engine Fueled with Hydrogen Gas Mixtures
Oct 2022
Publication
Hydrogen is one of the main alternative fuels with the greatest potential to replace fossil fuels due to its renewable and environmentally friendly nature. Due to this the present investigation aims to evaluate the combustion characteristics performance parameters emissions and variations in the characteristics of the lubricating oil. The investigation was conducted in a spark-ignition engine fueled by gasoline and hydrogen gas. Four engine load conditions (25% 50% 75% and 100%) and three hydrogen gas mass concentration conditions (3% 6% and 9%) were defined for the study. The investigation results allowed to demonstrate that the injection of hydrogen gas in the gasoline engine causes an increase of 3.2% and 4.0% in the maximum values of combustion pressure and heat release rates. Additionally hydrogen causes a 2.9% increase in engine BTE. Hydrogen's more efficient combustion process allowed for reducing CO HC and smoke opacity emissions. However hydrogen gas causes an additional increase of 14.5% and 30.4% in reducing the kinematic viscosity and the total base number of the lubricating oil. In addition there was evidence of an increase in the concentration of wear debris such as Fe and Cu which implies higher rates of wear in the engine's internal components.
Powering Europe with North Sea Offshore Wind: The Impact of Hydrogen Investments on Grid Infrastructure and Power Prices
Oct 2022
Publication
Hydrogen will be a central cross-sectoral energy carrier in the decarbonization of the European energy system. This paper investigates how a large-scale deployment of green hydrogen production affects the investments in transmission and generation towards 2060 analyzes the North Sea area with the main offshore wind projects and assesses the development of an offshore energy hub. Results indicate that the hydrogen deployment has a tremendous impact on the grid development in Europe and in the North Sea. Findings indicate that total power generation capacity increases around 50%. The offshore energy hub acts mainly as a power transmission asset leads to a reduction in total generation capacity and is central to unlock the offshore wind potential in the North Sea. The effect of hydrogen deployment on power prices is multifaceted. In regions where power prices have typically been lower than elsewhere in Europe it is observed that hydrogen increases the power price considerably. However as hydrogen flexibility relieves stress in high-demand periods for the grid power prices decrease in average for some countries. This suggests that while the deployment of green hydrogen will lead to a significant increase in power demand power prices will not necessarily experience a large increase.
A Review of Hydrogen/rock/brine Interaction: Implications for Hydrogen Geo-storage
Dec 2022
Publication
Hydrogen (H2) is currently considered a clean fuel to decrease anthropogenic greenhouse gas emissions and will play a vital role in climate change mitigation. Nevertheless one of the primary challenges of achieving a complete H2 economy is the large-scale storage of H2 which is unsafe on the surface because H2 is highly compressible volatile and flammable. Hydrogen storage in geological formations could be a potential solution to this problem because of the abundance of such formations and their high storage capacities. Wettability plays a critical role in the displacement of formation water and determines the containment safety storage capacity and amount of trapped H2 (or recovery factor). However no comprehensive review article has been published explaining H2 wettability in geological conditions. Therefore this review focuses on the influence of various parameters such as salinity temperature pressure surface roughness and formation type on wettability and consequently H2 storage. Significant gaps exist in the literature on understanding the effect of organic material on H2 storage capacity. Thus this review summarizes recent advances in rock/H2/brine systems containing organic material in various geological reservoirs. The paper also presents influential parameters affecting H2 storage capacity and containment safety including liquid–gas interfacial tension rock–fluid interfacial tension and adsorption. The paper aims to provide the scientific community with an expert opinion to understand the challenges of H2 storage and identify storage solutions. In addition the essential differences between underground H2 storage (UHS) natural gas storage and carbon dioxide geological storage are discussed and the direction of future research is presented. Therefore this review promotes thorough knowledge of UHS provides guidance on operating large-scale UHS projects encourages climate engineers to focus more on UHS research and provides an overview of advanced technology. This review also inspires researchers in the field of climate change to give more credit to UHS studies.
Spatially-resolved Analysis of the Challenges and Opportunities of Power-to-Gas (PtG) in Baden-Württemberg until 2040
Mar 2017
Publication
The increasing penetration of renewable energies will make new storage technologies indispensable in the future. Power-to-Gas (PtG) is one long-term storage technology that exploits the existing gas infrastructure. However this technology faces technical economic environmental challenges and questions. This contribution presents the final results of a large research project which attempted to address and provide answers to some of these questions for Baden-Württemberg (south west Germany). Three energy scenarios out to 2040 were defined one oriented towards the Integrated Energy and Climate Protection Concept of the Federal State Government and two alternatives. Timely-resolved load profiles for gas and electricity for 2015 2020 2030 and 2040 have been generated at the level of individual municipalities. The profiles include residential and industrial electrical load gas required for heating (conventional and current-controlled CHP) as well as gas and electricity demand for mobility. The installation of rooftop PV-plants and wind power plants is projected based on bottom up cost-potential analyses which account for some social acceptance barriers. Residential load profiles are derived for each municipality. In times with negative residual load the PtG technology could be used to convert electricity into hydrogen or methane. The detailed analysis of four structurally-different model regions delivered quite different results. While in large cities no negative residual load is likely due to the continuously high demand and strong networks rural areas with high potentials for renewables could encounter several thousand hours of negative residual load. A cost-effective operation of PtG would only be possible under favorable conditions including high full load hours a strong reduction in costs and a technical improvement of efficiency. Whilst these conditions are not expected to appear in the short to mid-term but may occur in the long term in energy systems with very high shares of renewable energy sources
Stoichiometric Equilibrium Model based Assessment of Hydrogen Generation through Biomass Gasification
Sep 2016
Publication
Hydrogen produced from renewable energy sources is clean and sustainable. Biomass gasification has a significant role in the context of hydrogen generation from biomass. Assessment of the performance of biomass gasification process regarding the product gas yield and composition can be performed using mathematical models. Among the different mathematical models thermodynamic equilibrium models are simple and useful tools for the first estimate and preliminary comparison and assessment of gasification process. A stoichiometric thermodynamic equilibrium model is developed here and its performance is validated for steam gasification and air-steam gasification. The model is then used to assess the feasibility of different biomass feedstock for gasification based on hydrogen yield and lower heating value.
Alternative and Innovative Solid Oxide Electrolysis Cell Materials: A Short Review
Jun 2021
Publication
Solid oxide electrolysis cell is the leading technology for production of green hydrogen by high temperature electrolysis. However optimization of existing reference materials constituting the cell and development of innovative materials remain critical for solid oxide electrolysis cell. In particular they are key to reach performance and durability targets compatible with a commercialization for the three main markets identified as follows: large-scale H2 production Power-to-X and Power-to-Power. This short review summarizes the latest progress in research and development of alternative and innovative materials for solid oxide electrolysis cells with a main focus on cathode-supported cell materials. A brief description of the layers constituting the solid oxide electrolysis cell is provided with the associated current state-of-the-art materials. A further emphasis on the most promising alternative and innovative materials for each layer follows based on the major aspects from an industrial perspective to reach a competitive hydrogen production cost for the main targeted markets: performance durability scaling up/manufacturing ability and operational flexibility.
Hybrid PEM Fuel Cell Power Plants Fuelled by Hydrogen for Improving Sustainability in Shipping: State of the Art and Review on Active Projects
Feb 2023
Publication
The interest in hybrid polymer electrolyte membrane fuel cells (PEMFC) fuelled by hydrogen in shipping has seen an unprecedented growth in the last years as it could allow zero-emission navigation. However technical safety and regulatory barriers in PEMFC ship design and operation are hampering the use of such systems on a large scale. While several studies analyse these aspects a comprehensive and up-to-date overview on hydrogen PEMFCs for shipping is missing. Starting from the survey of past/ongoing projects on FCs in shipping this paper presents an extensive review on maritime hydrogen PEMFCs outlining the state of the art and future trends for hydrogen storage and bunkering powertrain and regulations. In addition to the need for a clear regulatory framework future studies should investigate the development of an efficient fuel supply chain and bunkering facilities ashore. As for the onboard power system health-conscious energy management low-temperature heat recovery and advancements in fuel processing have emerged as hot research topics.
Economic Feasibility of Green Hydrogen in Providing Flexibility to Medium-voltage Distribution Grids in the Presence of Local-heat Systems
Nov 2022
Publication
The recent strong increase in the penetration of renewable energy sources (RESs) in medium-voltage distribution grids (MVDNs) has raised the need for congestion management in such grids as they were not designed for this new condition. This paper examines to what extent producing green hydrogen through electrolyzers can profitably contribute to congestion alleviation in MVDNs in the presence of high amounts of RES as well as flexible consumers of electricity and a local heat system. To address this issue an incentive-based method for improving flexibility in MVDNs is used which is based on a single-leader–multiple-followers game formulated by bi-level mathematical programming. At the upper level the distribution system operator who is the leader of this game determines dynamic prices as incentives at each node based on the levels of generation and load. Next at the lower level providers of flexibility including producers using electrolyzers price-responsive power consumers heat consumers as well as heat producers respond to these incentives by reshaping their output and consumption patterns. The model is applied to a region in the North of The Netherlands. The obtained results demonstrate that converting power to hydrogen can be an economically efficient way to reduce congestion in MVDNs when there is a high amount of RES. However the economic value of electrolyzers as providers of flexibility to MVDNs decreases when more other options for flexibility provision exist.
Solid Air Hydrogen Liquefaction, the Missing Link of the Hydrogen Economy
Mar 2023
Publication
The most challenging aspect of developing a green hydrogen economy is long-distance oceanic transportation. Hydrogen liquefaction is a transportation alternative. However the cost and energy consumption for liquefaction is currently prohibitively high creating a major barrier to hydrogen supply chains. This paper proposes using solid nitrogen or oxygen as a medium for recycling cold energy across the hydrogen liquefaction supply chain. When a liquid hydrogen (LH2) carrier reaches its destination the regasification process of the hydrogen produces solid nitrogen or oxygen. The solid nitrogen or oxygen is then transported in the LH2 carrier back to the hydrogen liquefaction facility and used to reduce the energy consumption cooling gaseous hydrogen. As a result the energy required to liquefy hydrogen can be reduced by 25.4% using N2 and 27.3% using O2. Solid air hydrogen liquefaction (SAHL) can be the missing link for implementing a global hydrogen economy.
Assessment of Hydrogen Delivery Options: Feasibility of Transport of Green Hydrogen within Europe
Oct 2022
Publication
The RePowerEU plan [1] and the European Hydrogen Strategy [2] recognise the important role that the transport of hydrogen will play in enabling the penetration of renewable hydrogen in Europe. To implement the European Hydrogen Strategy it is important to understand whether the transport of hydrogen is cost effective or whether hydrogen should be produced where it is used. If transporting hydrogen makes sense a second open question is how long the transport route should be for the cost of the hydrogen to still be competitive with locally produced hydrogen. JRC has performed a comprehensive study regarding the transport of hydrogen. To investigate which renewable hydrogen delivery pathways are favourable in terms of energy demand and costs JRC has developed a database and an analytical tool to assess each step of the pathways and used it to assess two case studies. The study reveals that there is no single optimal hydrogen delivery solution across every transport scenario. The most cost effective way to deliver renewable hydrogen depends on distance amount final use and whether there is infrastructure already available. For distances compatible with the European territory compressed and liquefied hydrogen solutions and especially compressed hydrogen pipelines offer lower costs than chemical carriers do. The repurposing of existing natural gas pipelines for hydrogen use is expected to significantly lower the delivery cost making the pipeline option even more competitive in the future. By contrast chemical carriers become more competitive the longer the delivery distance (due to their lower transport costs) and open up import options from suppliers located for example in Chile or Australia.
Review of the Effects of Fossil Fuels and the Need for a Hydrogen Fuel Cell Policy in Malaysia
Feb 2023
Publication
The world has relied on fossil fuel energy for a long time producing many adverse effects. Long-term fossil fuel dependency has increased carbon emissions and accelerated climate change. In addition fossil fuels are also depleting and will soon be very costly. Moreover the expensive national electricity grid has yet to reach rural areas and will be cut off in inundation areas. As such alternative and carbon-free hydrogen fuel cell energy is highly recommended as it solves these problems. The reviews find that (i) compared to renewable energy such as solar biomass and hydropower a fuel cell does not require expensive transmission through an energy grid and is carbon-free and hence it is a faster agent to decelerate climate change; (ii) fuel cell technologies have reached an optimum level due to the high-efficiency production of energy and they are environmentally friendly; (iii) the absence of a policy on hydrogen fuel cells will hinder investment from private companies as they are not adequately regulated. It is thus recommended that countries embarking on hydrogen fuel cell development have a specific policy in place to allow the government to fund and regulate hydrogen fuel cells in the energy generation mix. This is essential as it provides the basis for alternative energy governance development and management of a country.
The Effects of Fuel Type and Cathode Off-gas Recirculation on Combined Heat and Power Generation of Marine SOFC Systems
Dec 2022
Publication
An increasing demand in the marine industry to reduce emissions led to investigations into more efficient power conversion using fuels with sustainable production pathways. Solid Oxide Fuel Cells (SOFCs) are under consideration for long-range shipping because of its high efficiency low pollutant emissions and fuel flexibility. SOFC systems also have great potential to cater for the heat demand in ships but the heat integration is not often considered when assessing its feasibility. This study evaluates the electrical and heat efficiency of a 100 kW SOFC system for marine applications fuelled with methane methanol diesel ammonia or hydrogen. In addition cathode off-gas recirculation (COGR) is investigated to tackle low oxygen utilisation and thus improve heat regeneration. The software Cycle Tempo is used to simulate the power plant which uses a 1D model for the SOFCs. At nominal conditions the highest net electrical efficiency (LHV) was found for methane (58.1%) followed by diesel (57.6%) and ammonia (55.1%). The highest heat efficiency was found for ammonia (27.4%) followed by hydrogen (25.6%). COGR resulted in similar electrical efficiencies but increased the heat efficiency by 11.9% to 105.0% for the different fuels. The model was verified with a sensitivity analysis and validated by comparison with similar studies. It is concluded that COGR is a promising method to increase the heat efficiency of marine SOFC systems.
Study on the Effect of Second Injection Timing on the Engine Performances of a Gasoline/Hydrogen SI Engine with Split Hydrogen Direct Injecting
Oct 2020
Publication
Split hydrogen direct injection (SHDI) has been proved capable of better efficiency and fewer emissions. Therefore to investigate SHDI deeply a numerical study on the effect of second injection timing was presented at a gasoline/hydrogen spark ignition (SI) engine with SHDI. With an excess air ratio of 1.5 five different second injection timings achieved five kinds of hydrogen mixture distribution (HMD) which was the main factor affecting the engine performances. With SHDI since the HMD is manageable the engine can achieve better efficiency and fewer emissions. When the second injection timing was 105◦ crank angle (CA) before top dead center (BTDC) the Pmax was the highest and the position of the Pmax was the earliest. Compared with the single hydrogen direct injection (HDI) the NOX CO and HC emissions with SHDI were reduced by 20% 40% and 72% respectively.
Environmental Assessment of Hydrogen Utilization in Various Applications and Alternative Renewable Sources for Hydrogen Production: A Review
May 2023
Publication
Rapid industrialization is consuming too much energy and non-renewable energy resources are currently supplying the world’s majority of energy requirements. As a result the global energy mix is being pushed towards renewable and sustainable energy sources by the world’s future energy plan and climate change. Thus hydrogen has been suggested as a potential energy source for sustainable development. Currently the production of hydrogen from fossil fuels is dominant in the world and its utilization is increasing daily. As discussed in the paper a large amount of hydrogen is used in rocket engines oil refining ammonia production and many other processes. This paper also analyzes the environmental impacts of hydrogen utilization in various applications such as iron and steel production rocket engines ammonia production and hydrogenation. It is predicted that all of our fossil fuels will run out soon if we continue to consume them at our current pace of consumption. Hydrogen is only ecologically friendly when it is produced from renewable energy. Therefore a transition towards hydrogen production from renewable energy resources such as solar geothermal and wind is necessary. However many things need to be achieved before we can transition from a fossil-fuel-driven economy to one based on renewable energy
Potential Global Warming Impact of 1 kW Polymer Electrolyte Membrane Fuel Cell System for Residential Buildings on Operation Phase
Mar 2023
Publication
This study established global warming potential(GWP) emission factors through a life cycle assessment on the operation phases of two different 1 kW polymer electrolyte membrane fuel cell (PEMFC) systems for residential buildings (NG-PEMFC fed with hydrogen from natural gas reforming; WE-PEMFC fed with hydrogen from photovoltaics-powered water electrolyzer). Their effectiveness was also compared with conventional power grid systems in Korea specifically in the area of greenhouse gas emissions. The operation phases of the NG-PEMFC and the WE-PEMFC were divided into burner reformer and stack and into water electrolysis and stack respectively. The functional unit of each fuel cell system was defined as 1 kWh of electricity production. In the case of NG-PEMFC the GWP was 3.72E-01 kg-CO2eq/kWh the embodied carbon emissions due to using city gas during the life cycle process was about 20.87 % the carbon emission ratio according to the reformer's combustion burner was 6.07 % and the direct carbon emission ratio of the air emissions from the reformer was 73.06 % indicating that the carbon emission from the reformer contributed over 80 % of the total GWP. As for the WE-PEMFC the GWP was 1.76E-01 kg-CO2eq/kWh and the embodied carbon emissions from photovoltaic power generation during the life cycle process contributed over 99 % of the total GWP.
Potential Role of Renewable Gas in the Transition of Electricity and District Heating Systems
Dec 2019
Publication
With the constant increase in variable renewable energy production in electricity and district heating systems integration with the gas system is a way to provide flexibility to the overall energy system. In the sustainable transition towards a zero-emission energy system traditional natural gas can be substituted by renewable gasses derived from anaerobic digestion or thermal gasification and hydrogen. In this paper we present a methodology for modelling renewable gas options and limits on biomass resources across sectors in the energy optimisation model Balmorel. Different scenarios for socio-economic pathways to emission neutral electricity and district heating systems in Denmark Sweden Norway and Germany show that a renewable based energy system benefits from a certain percentage of gas as a supplement to other flexibility options like interconnectors. Especially upgraded biogas from anaerobic digestion serves as a substitute for natural gas in all scenarios. Allocating only 10% of available biomass to the electricity and district heating sector leads to full exploitation of the scarce biomass resource by boosting biogas and syngas with hydrogen. The need for renewable gasses is highest in Germany and least in Norway where hydro-power provides flexibility in terms of storable and dispatchable electricity production. The scenarios show that a required ‘‘late sprint" from fossils to achieve a zero-emission energy system in 2050 causes (1) significant higher accumulated emissions and (2) a system which strongly relies on fuels also in an emission free system instead of stronger integration of the electricity and district heating systems through electrification as well as stronger integration of the power systems across countries through interconnectors.
Moving Toward the Low-carbon Hydrogen Economy: Experiences and Key Learnings from National Case Studies
Sep 2022
Publication
The urgency to achieve net-zero carbon dioxide (CO2) emissions by 2050 as first presented by the IPCC special report on 1.5°C Global Warming has spurred renewed interest in hydrogen to complement electrification for widespread decarbonization of the economy. We present reflections on estimates of future hydrogen demand optimization of infrastructure for hydrogen production transport and storage development of viable business cases and environmental impact evaluations using life cycle assessments. We highlight challenges and opportunities that are common across studies of the business cases for hydrogen in Germany the UK the Netherlands Switzerland and Norway. The use of hydrogen in the industrial sector is an important driver and could incentivise large-scale hydrogen value chains. In the long-term hydrogen becomes important also for the transport sector. Hydrogen production from natural gas with capture and permanent storage of the produced CO2 (CCS) enables large-scale hydrogen production in the intermediate future and is complementary to hydrogen from renewable power. Furthermore timely establishment of hydrogen and CO2 infrastructures serves as an anchor to support the deployment of carbon dioxide removal technologies such as direct air carbon capture and storage (DACCS) and biohydrogen production with CCS. Significant public support is needed to ensure coordinated planning governance and the establishment of supportive regulatory frameworks which foster the growth of hydrogen markets.
Pressure Management in Smart Gas Networks for Increasing Hydrogen Blending
Jan 2022
Publication
The injection of hydrogen into existing gas grids is acknowledged as a promising option for decarbonizing gas systems and enhancing the integration among energy sectors. Nevertheless it affects the hydraulics and the quality management of networks. When the network is fed by multiple infeed sites and hydrogen is fed from a single injection point non-homogeneous hydrogen distribution throughout the grid happens to lead to a reduction of the possible amount of hydrogen to be safely injected within the grid. To mitigate these impacts novel operational schemes should therefore be implemented. In the present work the modulation of the outlet pressures of gas infeed sites is proposed as an effective strategy to accommodate larger hydrogen volumes into gas grids extending the area of the network reached by hydrogen while keeping compliance with quality and hydraulic restrictions. A distribution network operated at two cascading pressure tiers interfaced by pressure regulators constitutes the case study which is simulated by a fluid-dynamic and multi-component model for gas networks. Results suggest that higher shares of hydrogen and other green gases can be introduced into existing distribution systems by implementing novel asset management schemes with negligible impact on grid operations.
Just Energy Transition: Learning from the Past for a More Just and Sustainable Hydrogen Transition in West Africa
Dec 2022
Publication
The rising demand for energy and the aim of moving away from fossil fuels and to low-carbon power have led many countries to move to alternative sources including solar energy wind geothermal energy biomass and hydrogen. Hydrogen is often considered a “missing link” in guaranteeing the energy transition providing storage and covering the volatility and intermittency of renewable energy generation. However due to potential injustice with regard to the distribution of risks benefits and costs (i.e. in regard to competing for land use) the large-scale deployment of hydrogen is a contested policy issue. This paper draws from a historical analysis of past energy projects to contribute to a more informed policy-making process toward a more just transition to the hydrogen economy. We perform a systematic literature review to identify relevant conflict factors that can influence the outcome of hydrogen energy transition projects in selected Economic Community of West African States countries namely Nigeria and Mali. To better address potential challenges policymakers must not only facilitate technology development access and market structures for hydrogen energy policies but also focus on energy access to affected communities. Further research should monitor hydrogen implementation with a special focus on societal impacts in producing countries.
Hydrogen Fuel Cell Power System—Development Perspectives for Hybrid Topologies
Mar 2023
Publication
In recent years the problem of environmental pollution especially the emission of greenhouse gases has attracted people’s attention to energy infrastructure. At present the fuel consumed by transportation mainly comes from fossil energy and the strong traffic demand has a great impact on the environment and climate. Fuel cell electric vehicles (FCEVs) use hydrogen energy as a clean alternative to fossil fuels taking into account the dual needs of transportation and environmental protection. However due to the low power density and high manufacturing cost of hydrogen fuel cells their combination with other power supplies is necessary to form a hybrid power system that maximizes the utilization of hydrogen energy and prolongs the service life of hydrogen fuel cells. Therefore the hybrid power system control mode has become a key technology and a current research hotspot. This paper first briefly introduces hydrogen fuel cells then summarizes the existing hybrid power circuit topology categorizes the existing technical solutions and finally looks forward to the future for different scenarios of hydrogen fuel cell hybrid power systems. This paper provides reference and guidance for the future development of renewable hydrogen energy and hydrogen fuel cell hybrid electric vehicles.
Analysis of CO2 Emissions Reduction on the Future Hydrogen Supply Chain Network for Dubai Buses
Apr 2023
Publication
There is an impetus to decarbonize transportation sector and mitigate climate change. This study examines the effect of adopting hydrogen (H2) as a fuel for Dubai Buses at different penetration scales on carbon dioxide (CO2) emissions reduction. A H2 supply-chain system dynamics model is developed to conduct life cycle cost and environmental analysis and evaluate the efficacy of different carbon prices and subsidies. Gray green and mixed H2 production scenarios were considered. The results show that gray hydrogen reduces 7.1 million tons of CO2 which is half of green hydrogen buses. Replacing diesel fleet at end of lifetime with mixed hydrogen bus fleet was the optimal approach to promote green hydrogen at pump reaching $4/kg in a decade. This gradual transition reduces 62% of the well-to-wheel CO2 emissions of the new bus fleet and creates mass for economies of scale as carbon prices and subsidies cannot promote green hydrogen alone.
Life Cycle Cost Analysis for Scotland Short-Sea Ferries
Feb 2023
Publication
The pathway to zero carbon emissions passing through carbon emissions reduction is mandatory in the shipping industry. Regarding the various methodologies and technologies reviewed for this purpose Life Cycle Cost Analysis (LCCA) has been used as an excellent tool to determine economic feasibility and sustainability and to present directions. However insufficient commercial applications cause a conflict of opinion on which fuel is the key to decarbonisation. Many LCCA comparison studies about eco-friendly ship propulsion claim different results. In order to overcome this and discover the key factors that affect the overall comparative analysis and results in the maritime field it is necessary to conduct the comparative analysis considering more diverse case ships case routes and various types that combine each system. This study aims to analyse which greener fuels are most economically beneficial for the shipping sector and prove the factors influencing different results in LCCA. This study was conducted on hydrogen ammonia and electric energy which are carbon-free fuels among various alternative fuels that are currently in the limelight. As the power source a PEMFC and battery were used as the main power source and a solar PV system was installed as an auxiliary power source to compare economic feasibility. Several cost data for LCCA were selected from various feasible case studies. As the difficulty caused by the storage and transportation of hydrogen and ammonia should not be underestimated in this study the LCCA considers not only the CapEx and OpEx but also fuel transport costs. As a result fuel cell propulsion systems with hydrogen as fuel proved financial effectiveness for short-distance ferries as they are more inexpensive than ammonia-fuelled PEMFCs and batteries. The fuel cost takes around half of the total life-cycle cost during the life span.
How to Connect Energy Islands: Trade-offs Between Hydrogen and Electricity Infrastructure
Apr 2023
Publication
In light of offshore wind expansions in the North and Baltic Seas in Europe further ideas on using offshore space for renewable-based energy generation have evolved. One of the concepts is that of energy islands which entails the placement of energy conversion and storage equipment near offshore wind farms. Offshore placement of electrolysers will cause interdependence between the availability of electricity for hydrogen production and for power transmission to shore. This paper investigates the trade-offs between integrating energy islands via electricity versus hydrogen infrastructure. We set up a combined capacity expansion and electricity dispatch model to assess the role of electrolysers and electricity cables given the availability of renewable energy from the islands. We find that the electricity system benefits more from connecting close-to-shore wind farms via power cables. In turn electrolysis is more valuable for far-away energy islands as it avoids expensive long-distance cable infrastructure. We also find that capacity investment in electrolysers is sensitive to hydrogen prices but less to carbon prices. The onshore network and congestion caused by increased activity close to shore influence the sizing and siting of electrolysers.
A Comparison of Well-to-Wheels Energy Use and Emissions of Hydrogen Fuel Cell, Electric, LNG, and Diesel-Powered Logistics Vehicles in China
Jul 2023
Publication
Global energy and environmental issues are becoming increasingly serious and the promotion of clean energy and green transportation has become a common goal for all countries. In the logistics industry traditional fuels such as diesel and natural gas can no longer meet the requirements of energy and climate change. Hydrogen fuel cell logistics vehicles are expected to become the mainstream vehicles for future logistics because of their “zero carbon” advantages. The GREET model is computer simulation software developed by the Argonne National Laboratory in the USA. It is extensively utilized in research pertaining to the energy and environmental impact of vehicles. This research study examines four types of logistics vehicles: hydrogen fuel cell vehicles (FCVs) electric vehicles LNG-fueled vehicles and diesel-fueled vehicles. Diesel-fueled logistics vehicles are currently the most abundant type of vehicle in the logistics sector. LNG-fueled logistics vehicles are considered as a short-term alternative to diesel logistics vehicles while electric logistics vehicles are among the most popular types of new-energy vehicles currently. We analyze and compare their well-to-wheels (WTW) energy consumption and emissions with the help of GREET software and conduct lifecycle assessments (LCAs) of the four types of vehicles to analyze their energy and environmental benefits. When comparing the energy consumption of the four vehicle types electric logistics vehicles (EVs) have the lowest energy consumption with slightly lower energy consumption than FCVs. When comparing the nine airborne pollutant emissions of the four vehicle types the emissions of the FCVs are significantly lower than those of spark-ignition internal combustion engine logistics vehicles (SI ICEVs) compression-ignition direct-injection internal combustion engine logistics vehicles (CIDI ICEVs) and EVs. This study fills a research gap regarding the energy consumption and environmental impact of logistics vehicles in China.
Decarbonisation of Geographical Islands and the Feasibility of Green Hydrogen Production Using Excess Electricity
May 2023
Publication
Islands face limitations in producing and transporting energy due to their geographical constraints. To address this issue the ROBINSON project funded by the EU aims to create a flexible self-sufficient and environmentally friendly energy system that can be used on isolated islands. The feasibility of renewable electrification and heating system decarbonization of Eigerøy in Norway is described in this article. A mixed-integer linear programming framework was used for modelling. The optimization method is designed to be versatile and adaptable to suit individual scenarios with a flexible and modular formulation that can accommodate boundary conditions specific to each case. Onshore and offshore wind farms and utility-scale photovoltaic (PV) were considered to generate renewable electricity. Each option was found to be feasible under certain conditions. The heating system composed of a biomass gasifier a combined heat and power system with a gas boiler as backup unit was also analyzed. Parameters were identified in which the combination of all three thermal units represented the best system option. In addition the possibility of green hydrogen production based on the excess electricity from each scenario was evaluated.
Critical Parameters Controlling Wettability in Hydrogen Underground Storage - An Analytical Study
Sep 2022
Publication
Hypothesis.<br/>The large-scale implementation of hydrogen economy requires immense storage spaces to facilitate the periodic storage/production cycles. Extensive modelling of hydrogen transport in porous media is required to comprehend the hydrogen-induced complexities prior to storage to avoid energy loss. Wettability of hydrogen-brine-rock systems influence flow properties (e.g. capillary pressure and relative permeability curves) and the residual saturations which are all essential for subsurface hydrogen systems.<br/>Model.<br/>This study aims to understand which parameters critically control the contact angle for hydrogen-brine-rock systems using the surface force analysis following the DLVO theory and sensitivity analysis. Furthermore the effect of roughness is studied using the Cassie-Baxter model.<br/>Findings.<br/>Our results reveal no considerable difference between H2 and other gases such as N2. Besides the inclusion of roughness highly affects the observed apparent contact angles and even lead to water-repelling features. It was observed that contact angle does not vary significantly with variations of surface charge and density at high salinity which is representative for reservoir conditions. Based on the analysis it is speculated that the influence of roughness on contact angle becomes significant at low water saturation (i.e. high capillary pressure).
Geochemical Effects on Storage Gases and Reservoir Rock during Underground Hydrogen Storage: A Depleted North Sea Oil Reservoir Case Study
May 2023
Publication
In this work geochemical modelling using PhreeqC was carried out to evaluate the effects of geochemical reactions on the performance of underground hydrogen storage (UHS). Equilibrium exchange and mineral reactions were considered in the model. Moreover reaction kinetics were considered to evaluate the geochemical effect on underground hydrogen storage over an extended period of 30 years. The developed model was first validated against experimental data adopted from the published literature by comparing the modelling and literature values of H2 and CO2 solubility in water at varying conditions. Furthermore the effects of pressure temperature salinity and CO2% on the H2 and CO2 inventory and rock properties in a typical sandstone reservoir were evaluated over 30 years. Results show that H2 loss over 30 years is negligible (maximum 2%) through the studied range of conditions. The relative loss of CO2 is much more pronounced compared to H2 gas with losses of up to 72%. Therefore the role of CO2 as a cushion gas will be affected by the CO2 gas losses as time passes. Hence remedial CO2 gas injections should be considered to maintain the reservoir pressure throughout the injection and withdrawal processes. Moreover the relative volume of CO2 increases with the increase in temperature and decrease in pressure. Furthermore the reservoir rock properties porosity and permeability are affected by the underground hydrogen storage process and more specifically by the presence of CO2 gas. CO2 dissolves carbonate minerals inside the reservoir rock causing an increase in the rock’s porosity and permeability. Consequently the rock’s gas storage capacity and flow properties are enhanced
Brief Review on High-Temperature Electrochemical Hydrogen Sensors
Dec 2022
Publication
Hydrogen sensors especially those operating at high temperatures are essential tools for the emerging hydrogen economy. Monitoring hydrogen under process conditions to control the reactions for detecting confined species is crucial to the safe widespread use and public acceptance of hydrogen as fuel. Hydrogen sensors must have a sensitivity ranging from traces of hydrogen (parts per million (ppm)) up to levels near the lower explosive limit (LEL = 4% H2 in the air) for safety reasons. Furthermore they need to operate in cryogenic ambient and high-temperature environments. Herein emphasis is given to hydrogen sensors based on solid oxide electrolytes (operating at high temperatures) in particular oxygen ion and proton conductors. The review is devoted to potentiometric amperometric and combined amperometric-potentiometric hydrogen sensors. Experimental results already reported in the international literature are presented and analyzed to reveal the configuration principle of operation and the applied solid electrolytes and electrodes of the high-temperature hydrogen sensors. Additionally an amperometric sensor able to detect hydrogen and steam in atmospheric air through a two-stage procedure is presented and thoroughly discussed. The discussion reveals that high-temperature hydrogen sensors face different challenges in terms of the electrodes and solid electrolytes to be used depending on the operating principle of each sensor type.
Alkaline Electrolysis for Hydrogen Production at Sea: Perspectives on Economic Performance
May 2023
Publication
Alkaline electrolysis is already a proven technology on land with a high maturity level and good economic performance. However at sea little is known about its economic performance toward hydrogen production. Alkaline electrolysis units operate with purified water to split its molecules into hydrogen and oxygen. Purified water and especially that sourced from the sea has a variable cost that ultimately depends on its quality. However the impurities present in that purified water have a deleterious effect on the electrolyte of alkaline electrolysis units that cause them to drop their energy efficiency. This in turn implies a source of economic losses resulting from the cost of electricity. In addition at sea there are various options regarding the electrolyte management of which the cost depends on various factors. All these factors ultimately impact on the levelized cost of the produced hydrogen. This article aims to shed some light on the economic performance of alkaline electrolysis units operating under sea conditions highlighting the knowledge gaps in the literature and initiating a debate in the field.
Paving the Way: Analysing Energy Transition Pathways and Green Hydrogen Exports in Developing Countries - The Case of Algeria
Apr 2024
Publication
The measures needed to limit global warming pose a particular challenge to current fossil fuel exporters who must not only decarbonise their local energy systems but also compensate for the expected decline in fossil fuel revenues. One possibility is seen in the export of green hydrogen. Using Algeria as a case study this paper analyses how different levels of ambition in hydrogen exports energy efficiency and fuel switching affect the costoptimal expansion of the power sector for a given overall emissions reduction path. Despite falling costs for photovoltaics and wind turbines the results indicate that in countries with very low natural gas prices such as Algeria a fully renewable electricity system by 2050 is unlikely without appropriate policy measures. The expansion of renewable energy should therefore start early given the high annual growth rates required which will be reinforced by additional green hydrogen exports. In parallel energy efficiency is a key factor as it directly mitigates CO2 emissions from fossil fuels and reduces domestic electricity demand which could instead be used for hydrogen production. Integrating electrolysers into the power system could potentially help to reduce specific costs through load shifting. Overall it seems advisable to analyse hydrogen exports together with local decarbonisation in order to better understand their interactions and to reduce emissions as efficiently as possible. These results and the methodology could be transferred to other countries that want to become green hydrogen exporters in the future and are therefore a useful addition for researchers and policy makers.
Emerging Trends and Challenges in Pink Hydrogen Research
May 2024
Publication
Pink hydrogen is the name given to the technological variant of hydrogen generation from nuclear energy. This technology aims to address the environmental challenges associated with conventional hydrogen production positioning itself as a more sustainable and eco-efficient alternative while offering a viable alternative to nuclear power as a source of electricity generation. The present research analyzes the landscape of pink hydrogen research an innovative strand of renewable energy research. The methodology included a comprehensive search of scientific databases which revealed a steady increase in the number of publications in recent years. This increase suggests a growing interest in and recognition of the importance of pink hydrogen in the transition to cleaner and more sustainable energy sources. The results reflect the immaturity of this technology where there is no single international strategy and where there is some diversity of research topic areas as well as a small number of relevant topics. It is estimated that the future development of Gen IV nuclear reactors as well as Small Modular Reactor (SMR) designs will also favor the implementation of pink hydrogen.
Case Studies towards Green Transition in EU Regions: Smart Specialisation for Transformative Innovation
Oct 2022
Publication
This report analyses five case study reports in-depth across five EU countries as part of a broader analytical and critical exercise. This analytical work seeks to contribute to the development of new models for regional and local authorities aiming to boost support for Green Transition of their economies through smarter innovation policies using the smart specialisation (S3) approach. The work covered five regions from across the European Union representing a diversity of approaches to using S3 for Green Transition: the Basque Country in Spain the Centro region in Portugal the region of East and North Finland the region of Western Macedonia in Greece and the region of West Netherlands. The case studies included in this report consists of three sections on (i) Profile of the region and key development challenges; (ii) Innovation strategies and policies for green transition: incorporating societal challenges; (iii) Understanding and monitoring innovationled green transition. Drawing together the different elements presented the conclusion provides a summary overview of the case and the authors’ opinion on it.
Evaluating Partners for Renewable Energy Trading: A Multidimensional Framework and Tool
Apr 2024
Publication
The worsening climate crisis has increased the urgency of transitioning energy systems from fossil fuels to renewable sources. However many industrialized countries are struggling to meet their growing demand for renewable energy (RE) through domestic production alone and therefore seek to import additional RE using carriers such as hydrogen ammonia or metals. The pressing question for RE importers is therefore how to select trading partners i.e. RE exporting countries. Recent research has identified a plethora of different selection criteria reflecting the complexity of energy systems and international cooperation. However there is little guidance on how to reduce this complexity to more manageable levels as well as a lack of tools for effective partner evaluation. This article aims to fill these gaps. It proposes a new multidimensional framework for evaluating and comparing potential RE trading partners based on four dimensions: economy and technology environment and development regulation and governance and innovation and cooperation. Focusing on Germany as an RE importer an exploratory factor analysis is used to identify a consolidated set of composite selection criteria across these dimensions. The results suggest that Germany’s neighboring developed countries and current net energy exporters such as Canada and Australia are among the most attractive RE trading partners for Germany. A dashboard tool has been developed to provide the framework and composite criteria including adjustable weights to reflect the varying preferences of decision-makers and stakeholders. The framework and the dashboard can provide helpful guidance and transparency for partner selection processes facilitating the creation of RE trade networks that are essential for a successful energy transition.
Impact of Hydrogen Mixture on Fuel Consumption and Exhaust Gas Emissions in a Truck with Direct‑Injection Diesel Engine
May 2023
Publication
Hydrogen addition affects the composition of exhaust gases in vehicles. However the effects of hydrogen addition to compression ignition engines in running vehicles have not been evaluated. Hydrogen‑mixed air was introduced into the air intake of a truck equipped with a direct‑ injection diesel engine and running on a chassis dynamometer to investigate the effect of hydrogen addition on fuel consumption and exhaust gas components. The reduction in diesel consumption and the increase in hydrogen energy share (HES) showed almost linear dependence where the percentage decrease in diesel consumption is approximately 0.6 × HES. The percentage reduction of CO2 showed a one‑to‑one relationship to the reduction in diesel consumption. The reduction in emissions of CO PM and hydrocarbons (except for ethylene) had one to one or a larger correlation with the reduction of diesel consumption. On the other hand it was observed that NOx emissions increased and the percentage increase of NOx was 1.5~2.0 times that of HES. The requirement for total energy supply was more when hydrogen was added than for diesel alone. In the actual running mode only 50% of the energy of added hydrogen was used to power the truck. As no adjustments were made to the engine in this experiment a possible disadvantage that could be improved by adjusting the combustion conditions.
Quantitative Risk Assessment Methodology for Hydrogen Tank Rupture in a Tunnel Fire
Dec 2022
Publication
This study presents a methodology of a quantitative risk assessment for the scenario of an onboard hydrogen storage tank rupture and tunnel fire incident. The application of the methodology is demonstrated on a road tunnel. The consequence analysis is carried out for the rupture of a 70 MPa 62.4-litre hydrogen storage tank in a fire that has a thermally activated pressure relief device (TPRD) failed or blocked during an incident. Scenarios with two states of charge (SoC) of the tank i.e. SoC = 99% and SoC = 59% are investigated. The risks in terms of fatalities per vehicle per year and the cost per incident are assessed. It is found that for the reduction in the risk with the hydrogen-powered vehicle in a road tunnel fire incident to the acceptable level of 10−5 fatality/vehicle/year the fireresistance rating (FRR) of the hydrogen storage tank should exceed 84 min. The FRR increase to this level reduces the societal risk to an acceptable level. The increase in the FRR to 91 min reduces the risk in terms of the cost of the incident to GBP 300 following the threshold cost of minor injury published by the UK Health and Safety Executive. The Frequency–Number (F–N) of the fatalities curve is developed to demonstrate the effect of mitigation measures on the risk reduction to socially acceptable levels. The performed sensitivity study confirms that with the broad range of input parameters including the fire brigade response time the risk of rupture of standard hydrogen tank-TPRD systems inside the road tunnel is unacceptable. One of the solutions enabling an inherently safer use of hydrogen-powered vehicles in tunnels is the implementation of breakthrough safety technology—the explosion free in a fire self-venting (TPRD-less) tanks.
Towards Sustainable Transport: Techno-Economic Analysis of Investing in Hydrogen Buses in Public Transport in the Selected City of Poland
Dec 2022
Publication
The production storage and use of hydrogen for energy purposes will become increasingly important during the energy transition. One way to use hydrogen is to apply it to power vehicles. This green technological solution affects low-emissions transport which is beneficial and important especially in cities. The authors of this article analyzed the use of hydrogen production infrastructure for bus propulsion in the city of Katowice (Poland). The methods used in the study included a greedy algorithm and cost methods which were applied for the selection of vehicles and identification of the infrastructure for the production storage and refueling of hydrogen as well as to conduct the economic analysis during this term. The article presented the complexity of the techno-economic analysis of the infrastructure and its installation. The key element was the selection of the number of vehicles to the hydrogen production possibilities of an electrolyser and capabilities of the storage and charging infrastructure.
Global Warming Potential and Societal-governmental Impacts of the Hydrogen Ecosystem in the Transportation Sector
Apr 2024
Publication
The environmental and societal challenges of our contemporary society are leading us to reconsider our approaches to vehicle design. The aim of this article is to provide the reader with the essential knowledge needed to responsibly design a vehicle equipped with a hydrogen fuel cell system. Two pivotal aspects of hydrogen-electric powertrain eco-design are examined. First the global warming potential is assessed for both PEMFC systems and Type IV hydrogen tanks accounting for material extraction production and end-of-life considerations. The usage phase was omitted from the study in order to facilitate data adaptation for each type of use. PEMFC exhibits a global warming potential of about 29.2 kgCO2eq/kW while the tank records 12.4 kgCO2eq/kWh with transportation factors considered. Secondly the societal and governmental impacts are scrutinized with the carbon-intensive hydrogen tank emerging as having the most significant societal and governmental risks. In fact on a scale of 1–5 with 5 representing the highest level of risk the PEMFC system has a societal impact and governance risk of 2.98. The Type IV tank has a societal impact and governance risk of 3.31. Although uncertainties persist regarding the results presented in this study the values obtained provide an overview of the societal and governmental impacts of the hydrogen ecosystem in the transportation sector. The next step will be to compare for the same usage which solution between hydrogen-electric and 100% battery is more respectful of humans and the environment.
Dynamic Process Modeling of Topside Systems for Evaluating Power Consumption and Possibilities of Using Wind Power
Dec 2022
Publication
Norwegian offshore wind farms may be able to supply power to offshore oil and gas platforms in the near future thanks to the expeditious development of offshore wind technology. This would result in a reduction in CO2 emissions from oil and gas offshore installations which are currently powered predominantly by gas turbines. The challenge with using wind power is that offshore oil and gas installations require a fairly constant and stable source of power whereas wind power typically exhibits significant fluctuations over time. The purpose of this study is to perform a technical feasibility evaluation of using wind power to supply an offshore oil and gas installation on the basis of dynamic process simulations. Throughout the study only the topside processing system is considered since it is the most energy-intensive part of an oil and gas facility. An offshore field on the Norwegian Continental Shelf is used as a case study. The results indicate that when the processing system operates in steady-state conditions it cannot be powered solely by wind energy and another power source is required to compensate for low wind power generation intervals. An alternative would be to store wind energy during periods of high generation (e.g. by producing hydrogen or ammonia) and use it during periods of low generation. Utilizing energy storage methods wind energy can be continuously used for longer periods of time and provide a suitable constant power source for the studied case. Higher constant power can also be provided by increasing the efficiency of energy recovery and storage processes. Alternatively these two technologies may be integrated with gas turbines if the required storage cannot be provided or higher power is required. It was estimated that the integration of wind energy could result in noticeable reductions in CO2 emissions for the case study. Additionally according to the results the production storage and reuse of hydrogen and ammonia on-site may be viable options for supplying power.
How do Variations in Ship Operation Impact the Techno-economic Feasibility and Environmental Performance of Fossil-free Fuels? A Life Cycle Study
Aug 2023
Publication
Identifying an obvious non-fossil fuel solution for all ship types for meeting the greenhouse gas reduction target in shipping is challenging. This paper evaluates the technical viability environmental impacts and economic feasibility of different energy carriers for three case vessels of different ship types: a RoPax ferry a tanker and a service vessel. The energy carriers examined include battery-electric and three electro-fuels (hydrogen methanol and ammonia) which are used in combination with engines and fuel cells. Three methods are used: preliminary ship design feasibility life cycle assessment and life cycle costing. The results showed that battery-electric and compressed hydrogen options are not viable for some ships due to insufficient available onboard space for energy storage needed for the vessel's operational range. The global warming reduction potential is shown to depend on the ship type. This reduction potential of assessed options changes also with changes in the carbon intensity of the electricity mix. Life cycle costing results shows that the use of ammonia and methanol in engines has the lowest life cycle cost for all studied case vessels. However the higher energy conversion losses of these systems make them more vulnerable to fluctuations in the price of electricity. Also these options have higher environmental impacts on categories like human toxicity resource use (minerals and metals) and water use. Fuel cells and batteries are not as cost-competitive for the case vessels because of their higher upfront costs and shorter lifetimes. However these alternatives are less expensive than alternatives with internal combustion engines in the case of higher utilization rates and fuel costs.
Influence of Longitudinal Wind on Hydrogen Leakage and Hydrogen Concentration Sensor Layout of Fuel Cell Vehicles
Jul 2023
Publication
Hydrogen has the physical and chemical characteristics of being flammable explosive and prone to leakage and its safety is the main issue faced by the promotion of hydrogen as an energy source. The most common scene in vehicle application is the longitudinal wind generated by driving and the original position of hydrogen concentration sensors (HCSs) did not consider the influence of longitudinal wind on the hydrogen leakage trajectory. In this paper the computational fluid dynamics (CFD) software STAR CCM 2021.1 is used to simulate the hydrogen leakage and diffusion trajectories of fuel cell vehicles (FCVs) at five different leakage locations the longitudinal wind speeds of 0 km/h 37.18 km/h and 114 km/h and it is concluded that longitudinal wind prolongs the diffusion time of hydrogen to the headspace and reduces the coverage area of hydrogen in the headspace with a decrease of 81.35%. In order to achieve a good detection effect of fuel cell vehicles within the longitudinal wind scene based on the simulated hydrogen concentration–time matrix the scene clustering method based on vector similarity evaluation was used to reduce the leakage scene set by 33%. Then the layout position of HCSs was optimized according to the proposed multi-scene full coverage response time minimization model and the response time was reduced from 5 s to 1 s.
Performance Analysis of Hybrid Solar/H2/Battery Renewable Energy System for Residential Electrification
Mar 2019
Publication
Due to the privileged location of Ecuador in terms of solar radiation the analysis and use of renewable energy system (RES) using solar energy has been of great interest during the last years. At the same time the supply support of RES in terms of direct current (DC) can be faced by using fuel cell (FC) systems which can give to the systems fully autonomy from fossil fuels. The aim of this paper is to propose the design of a hybrid photovoltaic-fuel cell-battery (PV-FC-B) system to supply the required electrical energy for residential use in the city of Guayaquil. The feasibility analysis constitutive elements of the system and adjusted variables are computed and presented using a computational tool. The results evidence that this system is not economically viable since the cost of energy (COE) in Ecuador is low compared to the COE of the proposed system. However a more detailed analysis considering the inherent benefits of no emission of pollutant gases is required to have a complete outlook.
Battery and Hydrogen Energy Storage Control in a Smart Energy Network with Flexible Energy Demand Using Deep Reinforcement Learning
Sep 2023
Publication
Smart energy networks provide an effective means to accommodate high penetrations of variable renewable energy sources like solar and wind which are key for the deep decarbonisation of energy production. However given the variability of the renewables as well as the energy demand it is imperative to develop effective control and energy storage schemes to manage the variable energy generation and achieve desired system economics and environmental goals. In this paper we introduce a hybrid energy storage system composed of battery and hydrogen energy storage to handle the uncertainties related to electricity prices renewable energy production and consumption. We aim to improve renewable energy utilisation and minimise energy costs and carbon emissions while ensuring energy reliability and stability within the network. To achieve this we propose a multi-agent deep deterministic policy gradient approach which is a deep reinforcement learning-based control strategy to optimise the scheduling of the hybrid energy storage system and energy demand in real time. The proposed approach is model-free and does not require explicit knowledge and rigorous mathematical models of the smart energy network environment. Simulation results based on real-world data show that (i) integration and optimised operation of the hybrid energy storage system and energy demand reduce carbon emissions by 78.69% improve cost savings by 23.5% and improve renewable energy utilisation by over 13.2% compared to other baseline models; and (ii) the proposed algorithm outperforms the state-of-the-art self-learning algorithms like the deep-Q network.
A Brief on Nano-Based Hydrogen Energy Transition
Sep 2023
Publication
Considering the clean renewable and ecologically friendly characteristics of hydrogen gas as well as its high energy density hydrogen energy is thought to be the most potent contender to locally replace fossil fuels. The creation of a sustainable energy system is currently one of the critical industrial challenges and electrocatalytic hydrogen evolution associated with appropriate safe storage techniques are key strategies to implement systems based on hydrogen technologies. The recent progress made possible through nanotechnology incorporation either in terms of innovative methods of hydrogen storage or production methods is a guarantee of future breakthroughs in energy sustainability. This manuscript addresses concisely and originally the importance of including nanotechnology in both green electroproduction of hydrogen and hydrogen storage in solid media. This work is mainly focused on these issues and eventually intends to change beliefs that hydrogen technologies are being imposed only for reasons of sustainability and not for the intrinsic value of the technology itself. Moreover nanophysics and nano-engineering have the potential to significantly change the paradigm of conventional hydrogen technologies.
Towards Green Hydrogen? - A Comparison of German and African Visions and Expectations in the Context of the H2Atlas-Africa Project
Sep 2023
Publication
Green hydrogen promises to be critical in achieving a sustainable and renewable energy transition. As green hydrogen is produced with renewables green hydrogen could become an energy storage medium of the future and even substitute the current unsustainable grey or blue hydrogen used in the industry. Bringing this transition into reality for instance in Germany there are visions to rapidly build hydrogen facilities in Africa and export the produced green hydrogen to Europe. One problem however is that these visions presumably conflict with the visions of actors within Africa. Therefore this study aims to provide an initial assessment of African stakeholders’ visions for future energy exports and renewable energy expectations. By comparing visions from Germany and Africa this assessment was conducted to identify differences in green energy and hydrogen visions that could lead to conflict and similarities that could be the basis for cooperation. The National Hydrogen Strategy outlines the German visions which clarifies that Germany will have to import green hydrogen to meet its green transition target. In this context of future energy export demand a partnership between German and African researchers on assessing green hydrogen potentials in Africa started. The African visions were explored by surveying the partners from different African countries working on the project. The results revealed that while both sides see the need for an immediate transition to renewable energy the African side is not envisioning the immediate export of green hydrogen. Based on the responses the partners are primarily concerned with improving the continent’s still deficient energy access for both the population and industry. Nevertheless this African perspective greatly emphasises cross-border cooperation where both sides can realise their visions. In the case of Germany that German investment could build infrastructure which would benefit the receiving African country or countries and open up the possibility for the envisioned green hydrogen export to Europe.
Oxy-fuel Combustion-based Blue Hydrogen Production with the Integration of Water Electrolysis
Jun 2023
Publication
Blue hydrogen is gaining attention as an intermediate step toward achieving eco-friendly green hydrogen production. However the general blue hydrogen production requires an energy-intensive process for carbon capture and storage resulting in low process efficiency. Additionally the hydrogen production processes steam methane reforming (SMR) and electrolysis emits waste heat and byproduct oxygen respectively. To solve these problems this study proposes an oxy-fuel combustion-based blue hydrogen production process that integrates fossil fuel-based hydrogen production and electrolysis processes. The proposed processes are SMR + SOEC and SMR + PEMEC whereas SMR solid oxide electrolysis cell (SOEC) and proton exchange membrane electrolysis cell (PEMEC) are also examined for comparison. In the proposed processes the oxygen produced by the electrolyzer is utilized for oxy-fuel combustion in the SMR process and the resulting flue gas containing CO2 and H2O is condensed to easily separate CO2. Additionally the waste heat from the SMR process is recovered to heat the feed water for the electrolyzer thereby maximizing the process efficiency. Techno-economic sensitivity and greenhouse gas (GHG) analyses were conducted to evaluate the efficiency and feasibility of the proposed processes. The results show that SMR + SOEC demonstrated the highest thermal efficiency (85.2%) and exergy efficiency (80.5%) exceeding the efficiency of the SMR process (78.4% and 70.4% for thermal and exergy efficiencies respectively). Furthermore the SMR + SOEC process showed the lowest levelized cost of hydrogen of 6.21 USD/kgH2. Lastly the SMR + SOEC demonstrated the lowest life cycle GHG emissions. In conclusion the proposed SMR + SOEC process is expected to be a suitable technology for the transition from gray to green hydrogen.
Modern Hydrogen Technologies in the Face of Climate Change—Analysis of Strategy and Development in Polish Conditions
Aug 2023
Publication
The energy production market based on hydrogen technologies is an innovative solution that will allow the industry to achieve climate neutrality in the future in Poland and in the world. The paper presents the idea of using hydrogen as a modern energy carrier and devices that in cooperation with renewable energy sources produce the so-called green hydrogen and the applicable legal acts that allow for the implementation of the new technology were analyzed. Energy transformation is inevitable and according to reports on good practices in European Union countries hydrogen and the hydrogen value chain (production transport and transmission storage use in transport and energy) have wide potential. Thanks to joint projects and subsidies from the EU initiatives supporting hydrogen technologies are created such as hydrogen clusters and hydrogen valleys and EU and national strategic programs set the main goals. Poland is one of the leaders in hydrogen production both in the world and in Europe. Domestic tycoons from the energy refining and chemical industries are involved in the projects. Eight hydrogen valleys that have recently been created in Poland successfully implement the assumptions of the “Polish Hydrogen Strategy until 2030 with a perspective until 2040” and “Energy Policy of Poland until 2040” which are in line with the assumptions of the most important legal acts of the EU including the European Union’s energy and climate policy the Green Deal and the Fit for 55 Package. The review of the analysis of the development of hydrogen technologies in Poland shows that Poland does not differ from other European countries. As part of the assumptions of the European Hydrogen Strategy and the trend related to the management of energy surpluses electrolyzers with a capacity of at least 6 GW will be installed in Poland in 2020–2024. It is also assumed that in the next phase planned for 2025–2030 hydrogen will be a carrier in the energy system in Poland. Poland as a member of the EU is the creator of documents that take into account the assumptions of the European Union Commission and systematically implement the assumed goals. The strategy of activities supporting the development of hydrogen technologies in Poland and the value chain includes very extensive activities related to among others obtaining hydrogen using hydrogen in transport energy and industry developing human resources for the new economy supporting the activities of hydrogen valley stakeholders building hydrogen refueling stations and cooperation among Poland Slovakia and the Czech Republic as part of the HydrogenEagle project.
Numerical Study on the Use of Ammonia/Hydrogen Fuel Blends for Automotive Sparking-ignition Engines
Jun 2023
Publication
The importance of new alternative fuels has assumed great relevance in the last decades to face the issues of global warming and pollutant emissions from energy production. The scientific community is responsible for developing solutions to achieve the necessary environmental restriction policies. In this context ammonia appears as a potential fuel candidate and energy vector that may solve the technological difficulties of using hydrogen (H2 ) directly in internal combustion engines. Its high hydrogen content per unit mass higher energy density than liquid hydrogen well-developed infrastructure and experience in handling and storage make it suitable to be implemented as a long-term solution. In this work a virtual engine model was developed to perform prospective simulations of different operating conditions using ammonia and H2 -enriched ammonia as fuel in a spark-ignition (SI) engine integrating a chemical kinetics model and empirical correlations for combustion prediction. In addition specific conditions were evaluated to consider and to understand the governing parameters of ammonia combustion using computational fluid dynamics (CFD) simulations. Results revealed similar thermal efficiency than methane fuel with considerable improvements after appropriate H2 - enrichment. Moreover increasing the intake temperature and the turbulence intensity inside the cylinder evinced significant reductions in combustion duration. Finally higher compression ratios ensure efficiency gains with no evidence of abnormal combustion (knocking) even at high compression ratios (above 16:1) and low engine speeds (800 rpm). Numerical simulations showed the direct influence of the flame front surface area and the turbulent combustion velocity on efficiency reflecting the need for optimizing the SI engines design paradigm for ammonia applications.
The Impact of Country-specific Investment Risks on the Levelised Costs of Green Hydrogen Production
Jun 2024
Publication
Green hydrogen is central to the global energy transition. This paper introduces a renewable hydrogen production system model that optimizes hydrogen production on a worldwide 50 km × 50 km grid considering country-specific investment risks. Besides the renewable energy’s impact on the hydrogen production system (HPS) design we analyze the effect of country-specific interest rates on the levelized cost of hydrogen (LCOH) production. Over one-third (40.0%) of all cells have an installed solar PV capacity share between 50% and 70% 76.4% have a hybrid (onshore wind and solar PV) configuration. Hydrogen storage is deployed rather than battery storage to balance hydrogen production via electrolysis and hydrogen demand. Hybrid HPSs can significantly reduce the LCOH production compared to non-hybrid designs whereas country-specific interest rates can lead to significant increases diminishing the relative competitiveness of countries with abundant renewable energy resources compared to countries with fewer resources but fewer investment risks.
Optimisation of Size and Control Strategy in Utility-scale of Green Hydrogen Production Systems
Aug 2023
Publication
The optimisation of green hydrogen production systems is challenging. Moreover an accurate simulation of the system is required for effective optimisation. This study presents a novel method for optimising utility-scale hybrid photovoltaice-wind systems for hydrogen production using accurate simulation models. The optimisation objective is to minimise the levelised cost of hydrogen (LCOH) using genetic algorithms. Different types of systems (such as islanded systems grid-connected systems with or without the possibility of purchasing electricity from the grid and grid-connected systems considering power curtailment) are evaluated and optimised. Each combination of components and control strategy is simulated during the system lifetime (20 yrs) in time steps of 5 min considering the degradation of renewable generators during the system lifetime and different real-time pricing curves and renewable resource curves for each year of the system lifetime. Accurate models are used in the simulations including electrolyser efficiency dependent on the input power and cold-start extra ageing. An application example located in Zaragoza (Spain) is shown obtaining LCOH from 4.74 to 16.06 V/kg depending on the type of project and electrolyser.
Co-Combustion of Hydrogen with Diesel and Biodiesel (RME) in a Dual-Fuel Compression-Ignition Engine
Jun 2023
Publication
The utilization of hydrogen for reciprocating internal combustion engines remains a subject that necessitates thorough research and careful analysis. This paper presents a study on the co-combustion of hydrogen with diesel fuel and biodiesel (RME) in a compression-ignition piston engine operating at maximum load with a hydrogen content of up to 34%. The research employed engine indication and exhaust emissions measurement to assess the engine’s performance. Engine indication allowed for the determination of key combustion stages including ignition delay combustion time and the angle of 50% heat release. Furthermore important operational parameters such as indicated pressure thermal efficiency and specific energy consumption were determined. The evaluation of dual-fuel engine stability was conducted by analyzing variations in the coefficient of variation in indicated mean effective pressure. The increase in the proportion of hydrogen co-combusted with diesel fuel and biodiesel had a negligible impact on ignition delay and led to a reduction in combustion time. This effect was more pronounced when using biodiesel (RME). In terms of energy efficiency a 12% hydrogen content resulted in the highest efficiency for the dual-fuel engine. However greater efficiency gains were observed when the engine was powered by RME. It should be noted that the hydrogen-powered engine using RME exhibited slightly less stable operation as measured by the COVIMEP value. Regarding emissions hydrogen as a fuel in compression ignition engines demonstrated favorable outcomes for CO CO2 and soot emissions while NO and HC emissions increased.
Comparative Techno-economic Analysis of Large-scale Renewable Energy Storage Technologies
Jun 2023
Publication
Energy storage is an effective way to address the instability of renewable energy generation modes such as wind and solar which are projected to play an important role in the sustainable and low-carbon society. Economics and carbon emissions are important indicators that should be thoroughly considered for evaluating the feasibility of energy storage technologies (ESTs). In this study we study two promising routes for large-scale renewable energy storage electrochemical energy storage (EES) and hydrogen energy storage (HES) via technical analysis of the ESTs. The levelized cost of storage (LCOS) carbon emissions and uncertainty assessments for EESs and HESs over the life cycle are conducted with full consideration of the critical links for these routes. In order to reduce the evaluation error we use the Monte Carlo method to derive a large number of data for estimating the economy and carbon emission level of ESTs based on the collected data. The results show that lithium ion (Li-ion) batteries show the lowest LCOS and carbon emissions at 0.314 US$ kWh-1 and 72.76 gCO2e kWh-1 compared with other batteries for EES. Different HES routes meaning different combinations of hydrogen production delivery and refueling methods show substantial differences in economics and the lowest LCOS and carbon emissions at 0.227 US$ kWh-1 and 61.63 gCO2e kWh-1 are achieved using HES routes that involve hydrogen production by alkaline electrolyzer (AE) delivery by hydrogen pipeline and corresponding refueling. The findings of this study suggest that HES and EES have comparable levels of economics and carbon emissions that should be both considered for large-scale renewable energy storage to achieve future decarbonization goals.
A Comparative Study on Energy Efficiency of the Maritime Supply Chains for Liquefied Hydrogen, Ammonia, Methanol and Natural Gas
Jun 2023
Publication
To cope with climate change emerging fuels- hydrogen ammonia and methanol- have been proposed as promising energy carriers that will replace part of the liquefied natural gas (LNG) in future maritime scenarios. Energy efficiency is an important indicator for evaluating the system but the maritime supply system for emerging fuels has yet to be revealed. In this study the energy efficiency of the maritime supply chain of hydrogen ammonia methanol and natural gas is investigated considering processes including production storage loading transport and unloading. A sensitivity analysis of parameters such as ambient temperature storage time pipeline length and sailing time is also carried out. The results show that hydrogen (2.366%) has the highest daily boil-off gas (BOG) rate and wastes more energy than LNG (0.413%) with ammonia and methanol both being lower than LNG. The recycling of BOG is of great importance to the hydrogen supply chain. When produced from renewable energy sources methanol (98.02%) is the most energy efficient followed by ammonia with hydrogen being the least (89.10%). This assessment shows from an energy efficiency perspective that ammonia and methanol have the potential to replace LNG as the energy carrier of the future and that hydrogen requires efficient BOG handling systems to increase competitiveness. This study provides some inspirations for the design of global maritime supply systems for emerging fuels.
Can Hydrogen Storage in Metal Hydrides be Economically Competitive with Compressed and Liquid Hydrogen Storage? A Techno-economical Perspective for the Maritime Sector
Aug 2023
Publication
The aim of this work is to evaluate if metal hydride hydrogen storage tanks are a competitive alternative for onboard hydrogen storage in the maritime sector when compared to compressed gas and liquid hydrogen storage. This is done by modelling different hydrogen supply and onboard storage scenarios and evaluating their levelized cost of hydrogen variables. The levelized cost of hydrogen for each case is calculated considering the main components that are required for the refueling infrastructure and adding up the costs of hydrogen production compression transport onshore storage dispensing and the cost of the onboard tanks when known. The results show that the simpler refueling needs of metal hydride-based onboard tanks result in a significant cost reduction of the hydrogen handling equipment. This provides a substantial leeway for the investment costs of metal hydride-based storage which depending on the scenario can be between 3400 - 7300 EUR/kgH2 while remaining competitive with compressed hydrogen storage.
CFD Thermo‑Hydraulic Evaluation of a Liquid Hydrogen Storage Tank with Different Insulation Thickness in a Small‑Scale Hydrogen Liquefier
Aug 2023
Publication
Accurate evaluation of thermo‑fluid dynamic characteristics in tanks is critically important for designing liquid hydrogen tanks for small‑scale hydrogen liquefiers to minimize heat leakage into the liquid and ullage. Due to the high costs most future liquid hydrogen storage tank designs will have to rely on predictive computational models for minimizing pressurization and heat leakage. Therefore in this study to improve the storage efficiency of a small‑scale hydrogen liquefier a three‑ dimensional CFD model that can predict the boil‑off rate and the thermo‑fluid characteristics due to heat penetration has been developed. The prediction performance and accuracy of the CFD model was validated based on comparisons between its results and previous experimental data and a good agreement was obtained. To evaluate the insulation performance of polyurethane foam with three different insulation thicknesses the pressure changes and thermo‑fluid characteristics in a partially liquid hydrogen tank subject to fixed ambient temperature and wind velocity were investigated nu‑ merically. It was confirmed that the numerical simulation results well describe not only the temporal variations in the thermal gradient due to coupling between the buoyance and convection but also the buoyancy‑driven turbulent flow characteristics inside liquid hydrogen storage tanks with differ‑ ent insulation thicknesses. In the future the numerical model developed in this study will be used for optimizing the insulation systems of storage tanks for small‑scale hydrogen liquefiers which is a cost‑effective and highly efficient approach.
Expansion of Next-Generation Sustainable Clean Hydrogen Energy in South Korea: Domino Explosion Risk Analysis and Preventive Measures Due to Hydrogen Leakage from Hydrogen Re-Fueling Stations Using Monte Carlo Simulation
Apr 2024
Publication
Hydrogen an advanced energy source is growing quickly in its infrastructure and technological development. Urban areas are constructing convergence-type hydrogen refilling stations utilizing existing gas stations to ensure economic viability. However it is essential to conduct a risk analysis as hydrogen has a broad range for combustion and possesses significant explosive capabilities potentially leading to a domino explosion in the most severe circumstances. This study employed quantitative risk assessment to evaluate the range of damage effects of single and domino explosions. The PHAST program was utilized to generate quantitative data on the impacts of fires and explosions in the event of a single explosion with notable effects from explosions. Monte Carlo simulations were utilized to forecast a domino explosion aiming to predict uncertain events by reflecting the outcome of a single explosion. Monte Carlo simulations indicate a 69% chance of a domino explosion happening at a hydrogen refueling station if multi-layer safety devices fail resulting in damage estimated to be three times greater than a single explosion
The Effect of Ventilation on the Hazards of Hydrogen Release in Enclosed Areas of Hydrogen-fueled Ship
Aug 2023
Publication
This paper presents a systematic investigation that encompasses the safety assessment of a fuel preparation room (FPR) intended for a hydrogen-fueled ship. The primary objective is to determine the appropriate ventilation strategy to mitigate the risks associated with potential hydrogen leakage. The study focuses on a case involving an FPR measuring 10.2 m × 5.3 m × 2.65 m which is part of a 750 DWT hydrogen-powered fishing vessel. To identify the potential events leading to hydrogen dispersion an event tree analysis is conducted. Additionally existing regulations and guidelines related to the safety assessments of hydrogen leakage in enclosed areas are summarized and analyzed. Computational fluid dynamics FLACS-CFD are utilized for the consequence analysis in order to evaluate the impact of ventilation on hydrogen dispersion and concentration within the FPR. The research findings indicate significant effects of ventilation on the hazards and safety assessments of FPRs and high-pressure fuel gas supply systems. The study highlights that hydrogen vapor tends to accumulate at the ceiling and in the corners and spaces created by the equipment. The position and size of ventilation openings greatly influence the dispersion of hydrogen leakage. Proper ventilation design including top inlet ventilation and outlet ventilation on the opposite side helps to maintain a safe FPR by facilitating the efficient dispersion of hydrogen vapor. Moreover locating inlet ventilation on the same side as the outlet ventilation is found to hinder dispersion while the cross-ventilation achieved by placing inlets and outlets on opposite sides enhances airflow and dispersion. Consequently it is recommended to prioritize the structural design of FPRs and implement enhanced safety measures. Additionally updating the relevant regulations to address these concerns is strongly advised.
Green Hydrogen Production and Its Land Tenure Consequences in Africa: An Interpretive Review
Sep 2023
Publication
Globally a green hydrogen economy rush is underway and many companies investors governments and environmentalists consider it as an energy source that could foster the global energy transition. The enormous potential for hydrogen production for domestic use and export places Africa in the spotlight in the green hydrogen economy discourse. This discourse remains unsettled regarding how natural resources such as land and water can be sustainably utilized for such a resource-intensive project and what implications this would have. This review argues that green hydrogen production (GHP) in Africa has consequences where land resources (and their associated natural resources) are concerned. It discusses the current trends in GHP in Africa and the possibilities for reducing any potential pressures it may put on land and other resource use on the continent. The approach of the review is interpretive and hinges on answering three questions concerning the what why and how of GHP and its land consequences in Africa. The review is based on 41 studies identified from Google Scholar and sources identified via snowballed recommendations from experts. The GHP implications identified relate to land and water use mining-related land stress and environmental ecological and land-related socioeconomic consequences. The paper concludes that GHP may not foster the global energy transition as is being opined by many renewable energy enthusiasts but rather could help foster this transition as part of a greener energy mix. It notes that African countries that have the potential for GHP require the institutionalization of or a change in their existing approaches to land-related energy governance systems in order to achieve success.
An Analysis of Hybrid Renewable Energy-Based Hydrogen Production and Power Supply for Off-Grid Systems
Jun 2024
Publication
Utilizing renewable energy sources to produce hydrogen is essential for promoting cleaner production and improving power utilization especially considering the growing use of fossil fuels and their impact on the environment. Selecting the most efficient method for distributing power and capacity is a critical issue when developing hybrid systems from scratch. The main objective of this study is to determine how a backup system affects the performance of a microgrid system. The study focuses on power and hydrogen production using renewable energy resources particularly solar and wind. Based on photovoltaics (PVs) wind turbines (WTs) and their combinations including battery storage systems (BSSs) and hydrogen technologies two renewable energy systems were examined. The proposed location for this study is the northwestern coast of Saudi Arabia (KSA). To simulate the optimal size of system components and determine their cost-effective configuration the study utilized the Hybrid Optimization Model for Multiple Energy Resources (HOMER) software (Version 3.16.2). The results showed that when considering the minimum cost of energy (COE) the integration of WTs PVs a battery bank an electrolyzer and a hydrogen tank brought the cost of energy to almost 0.60 USD/kWh in the system A. However without a battery bank the COE increased to 0.72 USD/kWh in the same location because of the capital cost of system components. In addition the results showed that the operational life of the fuel cell decreased significantly in system B due to the high hours of operation which will add additional costs. These results imply that long-term energy storage in off-grid energy systems can be economically benefited by using hydrogen with a backup system.
Carbon Footprint of Hydrogen-powered Inland Shipping: Impacts and Hotspots
Aug 2023
Publication
The shipping sector is facing increasing pressure to implement clean fuels and drivetrains. Especially hydrogen fuel cell drivetrains seem attractive. Although several studies have been conducted to assess the carbon footprint of hydrogen and its application in ships their results remain hard to interpret and compare. Namely it is necessary to include a variety of drivetrain solutions and different studies are based on various assumptions and are expressed in other units. This paper addresses this problem by offering a three-step meta-review of life cycle assessment studies. First a literature review was conducted. Second results from the literature were harmonized to make the different analyses comparable serving cross-examination. The entire life cycle of both the fuels and drivetrains were included. The results showed that the dominant impact was fuel use and related fuel production. And finally life-cycle hot spots have been identified by looking at the effect of specific configurations in more detail. Hydrogen production by electrolysis powered by wind has the most negligible impact. For this ultra-low carbon pathway the modes of hydrogen transport and the use of specific materials and components become relevant.
Impact of International Transportation Chains on Cost of Green E-hydrogen: Global Cost of Hydrogen and Consequences for Germany and Finland
Jun 2023
Publication
Widely available and low-cost solar photovoltaics and wind power can enable production of renewable electricity-based hydrogen at many locations throughout the world. Hydrogen is expected to emerge as an important energy carrier constituting some of the final energy demand; however its most important role will be as feedstock for further processing to e-fuels e-chemicals and e-steel. Apart from meeting their own hydrogen demand countries may have opportunities to export hydrogen to countries with area limitations or higher production costs. This paper assesses the feasibility of e-hydrogen imports to Germany and Finland from two case regions with a high availability of low-cost renewable electricity Chile and Morocco in comparison to domestic supply. Special attention is paid to the transport infrastructure which has a crucial impact on the economic viability of imports via two routes shipping and pipelines. This study has found that despite lower e-hydrogen production costs in Morocco and Chile compared to Germany and Finland additional transportation costs make imports of e-hydrogen economically unattractive. In early 2020s imported fuel costs are 39–79% and 34–100% higher than e-hydrogen produced in Germany and Finland respectively. In 2050 imported e-hydrogen is projected to be 39–70% more expensive than locally produced e-hydrogen in Germany and 43–54% in the case of Finland. e-Hydrogen may become a fuel that is mostly produced domestically and may be feasible for imports only in specific locations. Local e-hydrogen production may also lower dependence on imports enhance energy security and add jobs.
From Waste to Energy: Enhancing Fuel and Hydrogen Production through Pyrolysis and In-Line Reforming of Plastic Wastes
Jun 2024
Publication
Plastics have become integral to modern life playing crucial roles in diverse industries such as agriculture electronics automotive packaging and construction. However their excessive use and inadequate management have had adverse environmental impacts posing threats to terrestrial and marine ecosystems. Consequently researchers are increasingly searching for more sustainable ways of managing plastic wastes. Pyrolysis a chemical recycling method holds promise for producing valuable fuel sustainably. This study explores the process of the pyrolysis of plastic and incorporates recent advancements. Additionally the study investigates the integration of reforming into the pyrolysis process to improve hydrogen production. Hydrogen a clean and eco-friendly fuel holds significance in transport engines power generation fuel cells and as a major commodity chemical. Key process parameters influencing the final products for pyrolysis and in-line reforming are evaluated. In light of fossil fuel depletion and climate change the pyrolysis and in-line reforming strategy for hydrogen production is anticipated to gain prominence in the future. Amongst the various strategies studied the pyrolysis and in-line steam reforming process is identified as the most effective method for optimising hydrogen production from plastic wastes.
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