Publications

Concerns related to climate change have shifted global attention towards advanced sustainable and decarbonized energy systems. While renewable resources such as wind and solar energy offer environmentally friendly alternatives their inherent variability and intermittency present significant challenges to grid stability and reliability. The integration of renewable energy sources requires innovative solutions to effectively balance supply and demand in the electricity grid. This review explores the critical role of electrolyzer systems in addressing these challenges by providing ancillary services to modern electricity grids. Electrolyzers traditionally used only for hydrogen production have now emerged as versatile tools capable of responding quickly to grid load variations. They can consume electricity during excess periods or when integrated with fuel cells generate electricity during peak demand contributing to grid stability. Therefore electrolyzer systems can fulfill the dual function of producing hydrogen for the end-user and offering grid balancing services ensuring greater economic feasibility. This review paper aims to provide a comprehensive view of the electrolyzer systems’ role in the provision of ancillary services including frequency control voltage control congestion management and black start. The technical aspects market projects challenges and future prospects of using electrolyzers to provide ancillary services in modern energy systems are explored.

Building a hydrogen economy is perceived as a way to achieve the decarbonization goals set out in the Paris Agreement to limit global warming as well as to meet the goals resulting from the European Green Deal for the decarbonization of Europe. This article presents a literature review of various aspects of this economy. The full added value chain of hydrogen was analyzed from its production through to storage transport distribution and use in various economic sectors. The current state of knowledge about hydrogen is presented with particular emphasis on its features that may determine the positives and negatives of its development. It was noted that although hydrogen has been known for many years its production methods are mainly related to fossil fuels which result in greenhouse gas emissions. The area of interest of modern science is limited to green hydrogen produced as a result of electrolysis from electricity produced from renewable energy sources. The development of a clean hydrogen economy is limited by many factors the most important of which are the excessive costs of producing clean hydrogen. Research and development on all elements of the hydrogen production and use chain is necessary to contribute to increasing the scale of production and use of this raw material and thus reducing costs as a result of the efficiencies of scale and experience gained. The development of the hydrogen economy will be related to the development of the hydrogen trade and the centers of this trade will differ significantly from the current centers of energy carrier trade.

Hydrogen is the gas of the moment: an abundant element that can be created using renewable energy transported in gaseous or liquid form and offering the ability to provide energy with only water vapour as an emission. Hydrogen can also be used in a fuel blend in electricity generation gas turbines providing a low carbon option for providing the peak electricity to cover high demand and firming.<br/>While the electricity grid is itself transforming to decarbonising hard-to-abate industries such as cement and bauxite refineries are slower to reduce emissions constrained by their high temperature process requirements. Hydrogen offers a solution allowing onsite production process heat with waste heat recovery supporting blended gas turbine generation for onsite electricity supply.<br/>This article builds on decarbonisation pathway simulation results from an ANEM model of the electricity grid identifying the amount of peak demand energy required from gas turbines. The research then examines the quantity flow rate storage requirements and emissions reduction if this peak generation were supplied by open cycle hydrogen capable gas turbines.

Ever more stringent emission regulations for vehicles encourage increasing numbers of battery electric vehicles on the roads. A drawback of storing electric energy in a battery is the comparable low energy density low driving range and the higher propensity to deplete the energy storage before reaching the destination especially at low ambient temperatures. When the battery is depleted stranded vehicles can either be towed or recharged with a mobile recharging station. Several technologies of mobile recharging stations already exist however most of them use fossil fuels to recharge battery electric vehicles. The proposed novel zero emission solution for mobile charging is a combined high voltage battery and hydrogen fuel cell charging station. Due to the thermal characteristics of the fuel cell and high voltage battery (which allow only comparable low coolant temperatures) the thermal design for this specific application (available heat exchanger area zero vehicle speed air flow direction) becomes challenging and is addressed in this work. Experimental methods were used to obtain reliable thermal and electric power measurement data of a 30 kW fuel cell system which is used in the Mobile Hydrogen Powersupply. Subsequently simulation methods were applied for the thermal design and optimisation of the coolant circuits and heat exchangers. It is shown that an battery electric vehicle charging power of 22 kW requires a heat exchanger area of 1 m2 of which 60 % is used by the fuel cell heat exchanger and the remainder by the battery heat exchanger to achieve steady state operation at the highest possible ambient temperature of 436 °C. Furthermore the simulation showed that when the charging power of 22 kW is solely provided by the high voltage battery the highest possible ambient temperature is 42 °C. When the charging power is decreased operation up to the maximum ambient temperatures of 45 °C can be achieved. The results of maximum charging power and limiting ambient temperature give insights for further system improvements which are: sizing of fuel cell or battery trailer design and heat exchanger area operation strategy of the system (power split between high voltage battery and fuel cell) as well as possible dynamic operation scenarios.

Japan has formulated a net-zero emissions target by 2050. Existing scenarios consistent with this target generally depend on carbon dioxide removal (CDR). In addition to domestic mitigation actions the import of low-carbon energy carriers such as hydrogen and synfuels and negative emissions credits are alternative options for achieving net-zero emissions in Japan. Although the potential and costs of these actions depend on global energy system transition characteristics which can potentially be informed by the global integrated assessment models they are not considered in current national scenario assessments. This study explores diverse options for achieving Japan's net-zero emissions target by 2050 using a national energy system model informed by international energy trade and emission credits costs estimated with a global energy system model. We found that demand-side electrification and approximately 100 Mt-CO2 per year of CDR implementation equivalent to approximately 10% of the current national CO2 emissions are essential across all net-zero emissions scenarios. Upscaling of domestically generated hydrogen-based alternative fuels and energy demand reduction can avoid further reliance on CDR. While imports of hydrogen-based energy carriers and emission credits are effective options annual import costs exceed the current cost of fossil fuel imports. In addition import dependency reaches approximately 50% in the scenario relying on hydrogen imports. This study highlights the importance of considering global trade when developing national net-zero emissions scenarios and describes potential new roles for global models.

One of the most important problems in the widespread use of electric vehicles is the lack of charging infrastructure. Especially in tourist areas where historical buildings are located the installation of a power grid for the installation of electric vehicle charging stations or generating electrical energy by installing renewable energy production systems such as large-sized PV (photovoltaic) and wind turbines poses a problem because it causes the deterioration of the historical texture. Considering the need for renewable energy sources in the transportation sector our aim in this study is to model an electric vehicle charging station using PVPS (photovoltaic power system) and FC (fuel cell) power systems by using irradiation and temperature data from historical regions. This designed charging station model performs electric vehicle charging meeting the energy demand of a house and hydrogen production by feeding the electrolyzer with the surplus energy from producing electrical energy with the PVPS during the daytime. At night when there is no solar radiation electric vehicle charging and residential energy demand are met with an FC power system. One of the most important advantages of this system is the use of hydrogen storage instead of a battery system for energy storage and the conversion of hydrogen into electrical energy with an FC. Unlike other studies in our study fossil energy sources such as diesel generators are not included for the stable operation of the system. The system in this study may need hydrogen refueling in unfavorable climatic conditions and the energy storage capacity is limited by the hydrogen fuel tank capacity.

Modernizing public transportation is crucial given the ongoing call for sustainable mobility. Growing concerns about climate change and the increasingly stringent emissions standards have compelled public transport operators to embrace alternative propulsion vehicles on a broader scale. For the past years the Battery Electric Buses (BEBs) have been the vehicle of choice for public transportation. However an emerging contender in this sector is the Fuel Cell Electric Bus (FCEB). This paper aims to evaluate the way one such vehicle would perform in terms of energy efficiency while being exploited in an urban scenario generated from collected data.

In a first-of-its-kind project for Alberta ATCO Gas and Pipelines Ltd. (ATCO) began delivering a 5% blend of hydrogen (H2) in natural gas into a subsection of the existing Fort Saskatchewan natural gas distribution system (approximately 2100 customers). The project was commissioned in October 2022 with the intention of increasing the blend to 20% H₂ in 2023. As part of project due diligence ATCO in partnership with DNV undertook Quantitative Risk Assessments (QRAs) to understand any risks associated with the introduction of blended gas into its existing distribution system and to its customers. This paper describes key findings from the QRAs through the comparison of risks associated with H2 blended natural gas at concentrations of 5% and 20% H₂ and the current natural gas configuration. The impact of operating pressure and hydrogen blend composition formed a sensitivity study completed as part of this work. To provide context and to help interpret the results an individual risk (IR) level of 1 × 10-6 per year was utilised as a reference threshold for the limit of the ‘broadly acceptable’ risk level and juxtaposed against comparable risk scenarios. Although adding hydrogen increases the IR of ignited releases from mains services meters regulators and end user appliances the ignited release IR was always well below the broadly acceptable reference criterion for all operating pressures and blend cases considered as part of the project. The IR associated with carbon monoxide poisoning dominates the overall IR and the results demonstrate that the reduction in carbon monoxide poisoning associated with the introduction of H₂ blended natural gas negates any incremental risk associated with ignited releases due to H₂ blended gas. The paper also explains how the results of the QRA were incorporated into Engineering Assessments as per the requirements of CSA Z662:19 [1] to justify the conversion of existing natural gas infrastructure to H₂ blended gas infrastructure.

The complexity of Fuel Cell (FC) systems demands a profound and sustained understanding of the various phenomena occurring inside of it. Thus far FCs especially Proton Exchange Membrane Fuel Cells (PEMFCs) have been recognized as being among the most promising technologies for reducing Green House Gas (GHG) emissions because they can convert the chemical energy bonded to hydrogen and oxygen into electricity and heat. However their efficiency remains limited. To enhance their efficiency two distinct factors are suggested. First the quality of materials plays a significant role in the development of more robust and efficient FCs. Second the ability to identify mitigate and reduce the occurrence of faults through the use of robust control algorithms is crucial. Therefore more focused on the second point this paper compiles distinguishes and analyzes several publications from the past 25 years related to faults and their diagnostic techniques in FCs. Furthermore the paper presents various schemes outlining different symptoms their causes and corresponding fault algorithms.

Natural gas is the most growing fossil fuel due to its environmental advantages. For the economical transportation of natural gas to distant markets physical (i.e. liquefaction and compression) or chemical (i.e. direct and indirect) monetisation options must be considered to reduce volume and meet the demand of different markets. Planning natural gas supply chains is a complex problem in today’s turbulent markets especially considering the uncertainties associated with final market demand and competition with emerging renewable and hydrogen energies. This review study evaluates the latest research on mathematical programming (i.e. MILP and MINLP) as a decisionmaking tool for designing and planning natural gas supply chains under different planning horizons. The first part of this study assesses the status of existing natural gas infrastructures by addressing readily available natural monetisation options quantitative tools for selecting monetisation options and single-state and multistate natural gas supply chain optimisation models. The second part investigates hydrogen as a potential energy carrier for integration with natural gas supply chains carbon capture utilisation and storage technologies. This integration is foreseen to decarbonise systems diversify the product portfolio and fill the gap between current supply chains and the future market need of cleaner energy commodities. Since natural gas markets are turbulent and hydrogen energy has the potential to replace fossil fuels in the future addressing stochastic conditions and demand uncertainty is vital to hedge against risks through designing a responsive supply chain in the project’s early design stages. Hence hydrogen supply chain optimisation studies and the latest works on hydrogen–natural gas supply chain optimisation were reviewed under deterministic and stochastic conditions. Only quantitative mathematical models for supply chain optimisation including linear and nonlinear programming models were considered in this study to evaluate the effectiveness of each proposed approach.

Thanks to investments in diversifying the supply of natural gas Poland did not encounter any gas supply issues in 2022 when gas imports from Russia were ceased due to the Russian Federation’s armed intervention in Ukraine. Over the past few years the supply of gas from routes other than the eastern route has substantially grown particularly the supplies of liquefied natural gas (LNG) via the LNG terminal in Swinouj´scie. The growing proportion of LNG in Poland’s gas supply ´ leads to a rise in ethane levels in natural gas as verified by the review of data taken at a specific location within the gas system over the years 2015 2020 and 2022. Using measurements of natural gas composition the effectiveness of the steam hydrocarbon reforming process was simulated in the Gibbs reactor via Aspen HYSYS. The simulations confirmed that as the concentration of ethane in the natural gas increased the amount of hydrogen produced and the heat required for reactions in the reformer also increased. This article aims to analyze the influence of the changes in natural gas quality in the Polish transmission network caused by changes in supply structures on the mass and heat balance of the theoretical steam reforming reactor. Nowadays the chemical composition of natural gas may be significantly different from that assumed years ago at the plant’s design stage. The consequence of such a situation may be difficulties in operating especially when controlling the quantity of incoming natural gas to the reactor based on volumetric flow without considering changes in chemical composition.

Transforming Europe into a climate neutral economy and society by 2050 requires extraordinary efforts and the mobilisation of all sectors and economic actors coupled with all the creative and brain power one can imagine. Each sector has to fundamentally rethink the way it operates to ensure it can be transformed towards this new net-zero paradigm without jeopardising other environmental and societal objectives both within the EU and globally. Given the scale of the transformation ahead our ability to meet climate neutrality targets directly depends on our ability to innovate. In this context Research & Innovation programmes have a key role to play and it is crucial to ensure they are fit for purpose and well equipped to support the next wave of breakthrough innovations that will be required to achieve climate neutrality in the EU and globally by 2050. The objective of this study is to contribute to these strategic planning discussions by not only identifying high-risk and high-impact climate mitigation solutions but most importantly look beyond individual solutions and consider how systemic interactions of climate change mitigation approaches can be integrated in the development of R&I agendas.

The rapid growth of global aviation emissions has significantly impacted the environment leading to an urgent need to use carbon reduction methods. This paper analyzes global aviation’s carbon dioxide (CO2) N2O and CH4 emission changes under different hydrogen energy application paths. The global warming potential over a 100-year period (GWP100) method is used to convert the emissions of N2O and CH4 into CO2-equivalent. Here we report the results: if the global aviation industry begins using hydrogen turbine engines by 2040 it could reduce cumulative CO2-equivalent emissions by 2.217E+10 tons by 2080 which is 2.12% higher than starting hydrogen fuel cell engines in 2045. However adopting hydrogen fuel cell engines 10 years earlier shows greater reduction capabilities than hydrogen turbine engines achieving an accumulated reduction of 3.006E+10 tons of CO2-equivalent emissions. Therefore the timing of adoption notably affects hydrogen fuel cell engines more than hydrogen turbine engines. Delaying adoption makes hydrogen fuel cell engines’ performance lag hydrogen turbine engines.

National Nuclear Laboratory (NNL) is aiming to demonstrate through a research and development programme that nuclear enabled hydrogen can be used to support future clean energy systems. Demonstrating the safe operation of hydrogen facilities co-generating with a nuclear reactor will be key to enabling the deployment and success of nuclear enabled hydrogen technologies in the future. During the deployment continuity of supply will be paramount and possibly requires inter-seasonal storage. Co-generation is a means of using a source of energy in this case a nuclear reactor to efficiently produce power and thermal energy. Since a great deal of the heat energy is lost to the environment in a power plant making use of wasted energy for other useful output like the production of hydrogen and direct heating would be advantageous to plant economics and energy system flexibility. The civil nuclear industry is regulated around the world. This approach ensures that all the activities related to the production of power from nuclear and the hazards associated with ionising radiation are controlled in a manner which protects workers members of the public property and the environment. Nuclear safety assessments follow a rigorous process and are required as part of the Nuclear Site Licence. A fundamental requirement which is cited in the UK legislation is that the risks associated with all activities at the licensed site be reduced to As Low As Reasonably Practicable (ALARP). The principle places a requirement on duty holders to implement measures to reduce risk where doing so is considered reasonable and proportionate. The inclusion of risks for hazardous materials associated with the hydrogen production facilities need to be considered and this requires harmonisation of two different safety and regulatory governance regimes which have not previously interacted in this way. The safety demonstration for nuclear facilities is provided through the Safety Case.

The imperative to address traditional energy crises and environmental concerns has accelerated the need for energy structure transformation. However the variable nature of renewable energy poses challenges in meeting complex practical energy requirements. To address this issue the construction of a multifunctional large-scale stationary energy storage system is considered an effective solution. This paper critically examines the battery and hydrogen hybrid energy storage systems. Both technologies face limitations hindering them from fully meeting future energy storage needs such as large storage capacity in limited space frequent storage with rapid response and continuous storage without loss. Batteries with their rapid response (90%) excel in frequent short-duration energy storage. However limitations such as a selfdischarge rate (>1%) and capacity loss (~20%) restrict their use for long-duration energy storage. Hydrogen as a potential energy carrier is suitable for large-scale long-duration energy storage due to its high energy density steady state and low loss. Nevertheless it is less efficient for frequent energy storage due to its low storage efficiency (~50%). Ongoing research suggests that a battery and hydrogen hybrid energy storage system could combine the strengths of both technologies to meet the growing demand for large-scale long-duration energy storage. To assess their applied potentials this paper provides a detailed analysis of the research status of both energy storage technologies using proposed key performance indices. Additionally application-oriented future directions and challenges of the battery and hydrogen hybrid energy storage system are outlined from multiple perspectives offering guidance for the development of advanced energy storage systems.

Rapid urbanization and globalization are causing a rise in the energy demand within the residential sector. Currently majority of the energy demand for the residential sector being supplied from fossil fuels these sources account for greenhouse gas emissions responsible for anthropogenic-driven climate change. About 85 % of the world’s energy demands are being met by non-renewable sources of energy. An immediate need to shift towards renewable energy sources to generate electricity is the need of the hour. These long-standing renewable energy sources including solar hydropower and wind energy have been crucial pillars of sustainable energy for years. However as their implementation has matured we are increasingly recognizing their limitations. Issues such as the scarcity of suitable locations and the significant carbon footprint associated with constructing renewable energy infrastructure are becoming more apparent. Hydrogen has been found to play a vital role as an energy carrier in framing the energy picture in the 21st century. Currently about 1 % of the global energy demands are being met by hydrogen energy harnessed through renewable methods. Its low carbon emissions when compared to other methods lower comparative production costs and high energy efficiency of 40–60 % make it a suitable choice. Integrating hydrogen production systems with other renewable source of energy such as solar and wind energy have been discussed in this review in detail. With the concepts of green buildings or net zero energy buildings gaining attraction integration of hydrogen-based systems within residential and office sectors through the use of devices such as micro–Combined Heat and Power devices (mCHP) have proven to be effective and efficient. These devices have been found to save the consumed energy by 22 % along with an effective reduction in carbon emissions of 18 % when used in residential sectors. Using the rejected energy from other processes these mCHP devices can prove to be vital in meeting the energy demands of the residential sector. Through the support of government schemes mCHP devices have been widely used in countries such as Japan and Finland and have benefitted from the same. Hydrogen storage is critical for efficient operation of the integrated renewable systems as improper storage of the hydrogen produced could lead to human and environmental disasters. Using boron hydrides or ammonia (121 kg H2/m3 ) or through organic carriers hydrogen can be stored safely and easily regenerated without loss of material. A thorough comparison of all the renewable sources of energy that are used extensively is required to evaluate the merits of using hydrogen as an energy carrier which has been addressed in this review paper. The need to address the research gap in application of mCHP devices in the residential sector and the benefits they provide has been addressed in this review. With about 2500 GW of energy ready to be harnessed through the mCHP devices globally the potential of mCHP systems globally are discussed in detail in this paper. This review discusses challenges and solutions to hydrogen production storage and ways to implement hydrogen technology in the residential sector. This review allows researchers to build a renewable alternative with hydrogen as a clean energy vector for generating electricity in residential systems.

This paper intends to give an impression of new technologies and processes that are in development for application to achieve decarbonization and about which less or no experience on associated hazards exists in the process industry. More or less an exception is hydrogen technology because its hazards are relatively known and there is industry experience in handling it safely but problems will arise when it is produced stored and distributed on a large scale. So when its use spreads to communities and it becomes as common as natural gas now measures to control the risks will be needed. And even with hydrogen surprise findings have been shown lately e.g. its BLEVE behavior when in a liquified form stored in a vessel heated externally. Substitutes for hydrogen are not without hazard concern either. The paper will further consider the hazards of energy storage in batteries and the problems to get those hazards under control. Relatively much attention will be paid to the electrification of the process industry. Many new processes are being researched which given green energy will be beneficial to reduce greenhouse gases and enhance sustainability but of which hazards are rather unknown. Therefore as last chapter the developments with respect to the concept of hazard identification and scenario definition will be considered in quite detail. Improvements in that respect are also being possible due to the digitization of the industry and the availability of data and considering the entire life cycle all facilitated by the data model standard ISO 15926 with the scope of integration of life-cycle data for process plants including oil and gas production facilities. Conclusion is that the new technologies and processes entail new process and personal hazards and that much effort is going into renewal but safety analyses are scarce. Right in a period of process renewal attention should be focused on possibilities to implement inherently safer design.

Climate change and environmental degradation are growing concerns in today’s society which has led to greater awareness and responsibility regarding the need to adopt sustainable practices. The European Union has established the goal of achieving climate neutrality by 2050 which implies a significant reduction in greenhouse gas emissions in all sectors. To achieve this goal renewable energies the circular economy and energy efficiency are being promoted. A major source of emissions is the use of fossil fuels in different types of ships (from transport ships to those used by national navies). Among these it highlights the growing interest of the defense sector in trying to reduce these emissions. The Spanish Ministry of Defense is also involved in this effort and is taking steps to reduce the carbon footprint in military operations and improve sustainability in equipment acquisition and maintenance. The objective of this study is to identify the most promising alternative fuel among those under development for possible implementation on Spanish Navy ships in order to reduce greenhouse gas emissions and improve its capabilities. To achieve this a multi-criteria decision-making method will be used to determine the most viable fuel option. The data provided by the officers of the Spanish Navy is of great importance thanks to their long careers in front of the ships. The analysis revealed that hydrogen was the most suitable fuel with the highest priority ahead of LNG and scored the highest in most of the sections of the officials’ ratings. These fuels are less polluting and would allow a significant reduction in emissions during the navigation of ships. However a further study would also have to be carried out on the costs of adapting to their use and the safety of their use.

To meet the new regulation for the deployment of alternative fuels infrastructure which sets targets for electric recharging and hydrogen refuelling infrastructure by 2025 or 2030 a large infrastructure comprising trucksuitable hydrogen refuelling stations will soon be required. However further standardisation is required to support the uptake of hydrogen for heavy-duty transport for Europe’s green energy future. Hydrogen-powered vehicles require pure hydrogen as some contaminants can reduce the performance of the fuel cell even at very low levels. Even if previous projects have paved the way for the development of the European quality infrastructure for hydrogen conformity assessment sampling systems and methods have yet to be developed for heavy-duty hydrogen refuelling stations (HD-HRS). This study reviews different aspects of the sampling of hydrogen at heavy-duty hydrogen refuelling stations for purity assessment with a focus on the current and future specifications and operations at HD-HRS. This study describes the state-of-the art of sampling systems currently under development for use at HD-HRS and highlights a number of aspects which must be taken into consideration to ensure safe and accurate sampling: risk assessment for the whole sampling exercise selection of cylinders methods to prepare cylinders before the sampling filling pressure and venting of the sampling systems.

Hydrogen energy is critical in replacing fossil fuels and achieving net zero carbon emissions by 2050. Three measures can be implemented to promote hydrogen energy: reduce the cost of low-carbon hydrogen through technological improvements increase the production capacity of low-carbon hydrogen by stimulating investment and enhance hydrogen use as an energy carrier and in industrial processes by demand-side policies. This article examines how effective these measures are if successfully implemented in boosting the hydrogen market and reducing global economy-wide carbon emissions using a global computable general equilibrium model. The results show that all the measures increase the production and use of low-carbon hydrogen whether implemented alone or jointly. Notably the emissions reduced by joint implementation of all the measures in 2050 become 2.5 times the sum of emissions reduced by individual implementation indicating a considerable multiplier effect. This suggests supply and demand side policies be implemented jointly to maximize their impact on reducing emissions.

The war in Ukraine caused Europe to more than double its imports of liquefied natural gas (LNG) in only one year. In addition imported LNG remains a crucial source of energy for resource-poor countries such as Japan where LNG imports satisfy about a quarter of the country’s primary energy demand. However an increasing number of countries are formulating stringent decarbonization plans. Liquefied hydrogen and liquefied ammonia coupled with carbon capture and storage (LH2-CCS LNH3-CCS) are emerging as the front runners in the search for low-carbon alternatives to LNG. Yet little is currently known about the full environmental profile of LH2-CCS and LNH3-CCS because several characteristics of the two alternatives have only been analyzed in isolation in previous work. Here we show that the potential of these fuels to reduce greenhouse gas (GHG) emissions throughout the supply chain is highly uncertain. Our best estimate is that LH2-CCS and LNH3-CCS can reduce GHG emissions by 25%–61% relative to LNG assuming a 100 year global warming potential. However directly coupling LNG with CCS would lead to substantial GHG reductions on the order of 74%. Further under certain conditions emissions from LH2-CCS and LNH3-CCS could exceed those of LNG by up to 44%. These results question the suitability of LH2-CCS and LNH3-CCS for stringent decarbonization purposes.

The utilization of hydrogen fuel in gas turbines brings significant changes to the thermophysical properties of flue gas including higher specific heat capacities and an enhanced steam content. Therefore hydrogen-fueled gas turbines are susceptible to health degradation in the form of steam-induced corrosion and erosion in the hot gas path. In this context the fault diagnosis of hydrogen-fueled gas turbines becomes indispensable. To the authors’ knowledge there is a scarcity of fault diagnosis studies for retrofitted gas turbines considering hydrogen as a potential fuel. The present study however develops an artificial neural network (ANN)-based fault diagnosis model using the MATLAB environment. Prior to the fault detection isolation and identification modules physics-based performance data of a 100 kW micro gas turbine (MGT) were synthesized using the GasTurb tool. An ANN-based classification algorithm showed a 96.2% classification accuracy for the fault detection and isolation. Moreover the feedforward neural network-based regression algorithm showed quite good training testing and validation accuracies in terms of the root mean square error (RMSE). The study revealed that the presence of hydrogen-induced corrosion faults (both as a single corrosion fault or as simultaneous fouling and corrosion) led to false alarms thereby prompting other incorrect faults during the fault detection and isolation modules. Additionally the performance of the fault identification module for the hydrogen fuel scenario was found to be marginally lower than that of the natural gas case due to assumption of small magnitudes of faults arising from hydrogen-induced corrosion.

We conduct a techno-economic assessment of two low-emissions steel production technologies and evaluate their deployment in emissions mitigation scenarios utilizing the MIT Economic Projection and Policy Analysis (EPPA) model. Specifically we assess direct reduced iron-electric arc furnace with carbon capture and storage (DRI-EAF with CCS) and H2-based direct reduced iron-electric arc furnace (H2 DRI-EAF) which utilizes low carbon hydrogen to reduce CO2 emissions. Our techno-economic analysis based on the current state of technologies found that DRI-EAF with CCS increased costs ~7% relative to the conventional steel technology. H2 DRI-EAF increased costs by ~18% when utilizing Blue hydrogen and ~79% when using Green hydrogen. The exact pathways for hydrogen production in different world regions including the extent of CCS and hydrogen deployment in steelmaking are highly speculative at this point. In illustrative scenarios using EPPA we find that using base cost assumptions switching from BF-BOF to DRI-EAF or scrap EAF can provide significant emissions mitigation within steelmaking. With further reductions in the cost of advanced steelmaking we find a greater role for DRI-EAF with CCS whereas reductions in both the cost of advanced steelmaking and hydrogen production lead to a greater role for H2 DRI-EAF. Our findings can be used to help decision-makers assess various decarbonization options and design economically efficient pathways to reduce emissions in the steel industry. Our cost evaluation can also be used to inform other energy-economic and integrated assessment models designed to provide insights about future decarbonization pathways.

This paper presents a new economic profitability model for a power-to-gas plant producing green hydrogen at the site of an existing wind power plant injected into the gas grid. The model is based on a 42 MW wind power plant for which an optimal electrolyzer of 10 MW was calculated based on the 2500 equivalent full load hours per year and the projection of electricity prices. The model is calculated on an hourly level for all variables of the 25 years of the model. With the calculated breakeven electricity price of 74.23 EUR/MWh and the price of green hydrogen production of 99.44 EUR/MWh in 2045 the wind power plant would produce 22410 MWh of green hydrogen from 31% of its total electricity production. Green hydrogen injected into the gas system would reduce the level of CO2 emissions by 4482 tons. However with the projected prices of natural gas and electricity the wind power plant would cover only 20% of the income generated by the electricity delivered to the grid by producing green hydrogen. By calculating different scenarios in the model the authors concluded that the introduction of a premium subsidy model is necessary to accelerate deployment of electrolyzers at the site of an existing wind power plant in order to increase the wind farm profitability.

Hydrogen production and storage in hybrid systems is a promising solution for sustainable energy transition decoupling the energy generation from its end use and boosting the deployment of renewable energy. Nonetheless the optimal and cost-effective design of hybrid hydrogen-based systems is crucial to tackle existing limitations in diffusion of these systems. The present study explores net-zero energy management via a multi-objective optimization algorithm for an outdoor test facility equipped with a hydrogen-based hybrid energy production system. Aimed at enabling efficient integration of hydrogen fuel cell system the proposed solution attempts to maximize the renewable factor (RF) and carbon mitigation in the hybrid system as well as to minimize the grid dependency and the life cycle cost (LCC) of the system. In this context the techno-enviroeconomic optimization of the hybrid system is conducted by employing a statistical approach to identify optimal design variables and conflictive objective functions. To examine interactions in components of the hybrid system a series of dynamic simulations are carried out by developing a TRNSYS code coupled with the OpenStudio/EnergyPlus plugin. The obtained results indicate a striking disparity in the monthly RF values as well as the hydrogen production rate and therefore in the level of grid dependency. It is shown that the difference in LCC between optimization scenarios suggested by design of experiments could reach $15780 corresponding to 57% of the mean initial cost. The LCOE value yielded for optimum scenarios varies between 0.389 and 0.537 $/kWh. The scenario with net-zero target demonstrates the lowest LCOE value and the highest carbon mitigation i.e. 828 kg CO2/yr with respect to the grid supply case. However the LCC in this scenario exceeds $57370 which is the highest among all optimum scenarios. Furthermore it was revealed that the lowest RF in optimal scenarios is equal to 66.2% and belongs to the most economical solution.