Electronic Structure and d-Band Center Control Engineering over Ni-Doped CoP₃ Nanowall Arrays for Boosting Hydrogen Production

To address the challenge of highly efficient water splitting into H_2, successful fabrication of novel porous three-dimensional Ni-doped CoP₃ nanowall arrays on carbon cloth was realized, resulting in an effective self-supported electrode for the electrocatalytic hydrogen-evolution reaction. The synthesized samples exhibit rough, curly, and porous structures, which are beneficial for gaseous transfer and diffusion during the electrocatalytic process. As expected, the obtained Ni-doped CoP₃ nanowall arrays with a doping concentration of 7% exhibit the promoted electrocatalytic activity. The achieved overpotentials of 176 mV for the hydrogen-evolution reaction afford a current density of 100 mA cm⁻², which indicates that electrocatalytic performance can be dramatically enhanced via Ni doping. The Ni-doped CoP₃ electrocatalysts with increasing catalytic activity should have significant potential in the field of water splitting into H₂. This study also opens an avenue for further enhancement of electrocatalytic performance through tuning of electronic structure and d-band center by doping.