United States
Validation of Flacs-Hydrogen CFD Consequence Prediction Model Against Large Scale H2 Explosion Experiments in the Flame Facility
Sep 2005
Publication
The FLACS CFD-tool for consequence prediction has been developed continuously since 1980. The initial focus was explosion safety on offshore oil platforms in recent years the tool is also applied to study dispersion hydrogen safety dust explosions and more. A development project sponsored by Norsk Hydro Statoil and Ishikawajima Heavy Industries (IHI) was carried out to improve the modelling and validation of hydrogen dispersion and explosions. In t Read More
Risk Assessment for Hydrogen Codes and Standards
Sep 2005
Publication
The development and promulgation of codes and standards are essential to establish a market-receptive environment for commercial hydrogen-based products and systems. The focus of the U.S. Department of Energy (DOE) is to conduct the research and development (R&D) needed to strengthen the scientific basis for technical requirements incorporated in national and international standards codes and regulations. In the U.S. the DOE and its i Read More
Analysis of Buoyancy-driven Ventilation of Hydrogen from Buildings
Sep 2007
Publication
When hydrogen gas is used or stored within a building as with a hydrogen-powered vehicle parked in a residential garage any leakage of unignited H2 will mix with indoor air and may form a flammable mixture. One approach to safety engineering relies on buoyancy-driven passive ventilation of H2 from the building through vents to the outside. To discover relationships between design variables we combine two types of analysis: (1) a simplified 1-D steady-stat Read More
Analysis of Jet Flames and Unignited Jets from Unintended Releases of Hydrogen
Sep 2007
Publication
A combined experimental and modeling program is being carried out at Sandia National Laboratories to characterize and predict the behavior of unintended hydrogen releases. In the case where the hydrogen leak remains unignited knowledge of the concentration field and flammability envelope is an issue of importance in determining consequence distances for the safe use of hydrogen. In the case where a high-pressure leak of hydrogen is ignited a cl Read More
Collaborative Activities On Hydrogen Safety under the International Energy Agency’s Hydrogen Implementing
Sep 2005
Publication
In October 2004 the International Energy Agency Hydrogen Implementing Agreement (www.ieahia.org) approved the initiation of a collaborative task on hydrogen safety. During the past twelve months a work plan has been established and several member countries have committed to participate. Because of the nature of the International Energy Agency which is an international agreement between governments it is hoped that such collaboration will c Read More
Evaluation of Safety Distances Related to Unconfined Hydrogen Explosions
Sep 2005
Publication
A simple approximate method for evaluation of blast effects and safety distances for unconfined hydrogen explosions is presented. The method includes models for flame speeds hydrogen distribution blast parameters and blast damage criteria. An example of the application of this methodology for hydrogen releases in three hypothetical obstructed areas with different levels of congestion is presented. The severity of the blast effect of unconfined hydr Read More
Addressing Hydrogen Embrittlement of Metals in the Sae J2579 Fuel Cell Vehicle Tank Standard
Sep 2013
Publication
The SAE Technical Information Report (TIR) J2579 (Technical Information Report for Fuel Systems in Fuel Cell and Other Hydrogen Vehicles) has been created to address the safety performance of hydrogen storage and handling systems on vehicles. Safety qualification of the compressed hydrogen storage system is demonstrated through performance testing on prototype containment vessels. The two performance tests currently included in the SAE J2579 for Read More
Study of Hydrogen Diffusion and Deflagration in a Closed System
Sep 2007
Publication
A total of 12 ventilation experiments with various combinations of hydrogen release rates and ventilation speeds were performed in order to study how ventilation speed and release rate effect the hydrogen concentration in a closed system. The experiential facility was constructed out of steel plates and beams in the shape of a rectangular enclosure. The volume of the test facility was about 60m3. The front face of the enclosure was covered by a Read More
Facilitating the Safest Possible Transition from Fossil to Hydrogen Fuels- Hydrogen Executive Leadership Panel
Sep 2005
Publication
In recent years federal and state safety authorities have worked to bring emergency planners and responders together with industry the scientific community and consumers to ensure high levels of safety with gas and liquid pipelines and more recently with liquefied natural gas terminals. The U.S. Department of Transportation (DOT) is the federal authority on the safe transportation of energy and the National Association of State Fire Marshals (NASFM) repr Read More
Modeling of Sudden Hydrogen Expansion from Cryogenic Pressure Vessel Failure
Sep 2011
Publication
We have modelled sudden hydrogen expansion from a cryogenic pressure vessel. This model considers real gas equations of state single and two-phase flow and the specific “vessel within vessel” geometry of cryogenic vessels. The model can solve sudden hydrogen expansion for initial pressures up to 1210 bar and for initial temperatures ranging from 27 to 400 K. For practical reasons our study focuses on hydrogen release from 345 bar with temperatur Read More
Hydrogen Safety and Permitting Hydrogen Fueling Stations
Sep 2007
Publication
Two key aspects of hydrogen safety are (1) incorporating data and analysis from research development and demonstration (RD&D) into the codes and standards development process; and (2) adopting and enforcing these codes and standards by state and local permitting officials. This paper describes work that the U.S. Department of Energy (DOE) is sponsoring to address these aspects of hydrogen safety. For the first DOE is working with the automo Read More
Predictions of Solid-State Hydrogen Storage System Contamination Processes
Sep 2009
Publication
Solid state materials such as metal and chemical hydrides have been proposed and developed for high energy density automotive hydrogen storage applications. As these materials are implemented into hydrogen storage systems developers must understand their behavior during accident scenarios or contaminated refueling events. An ability to predict thermal and chemical processes during contamination allows for the design of safe and effecti Read More
Risk-Informed Separation Distances For Hydrogen Refuelling Stations
Sep 2007
Publication
The development of an infrastructure for the future hydrogen economy will require the simultaneous development of a set of codes and standards. As part of the U.S. Department of Energy Hydrogen Fuel Cells & Infrastructure Technologies Program Sandia National Laboratories is developing the technical basis for assessing the safety of hydrogen-based systems for use in the development/modification of relevant codes and standards. This work includes exp Read More
Safety Considerations for Hydrogen Test Cells
Sep 2009
Publication
The properties of hydrogen compared to conventional fuels such as gasoline and diesel are substantially different requiring adaptations to the design and layout of test cells for hydrogen fuelled engines and vehicles. A comparison of hydrogen fuel properties versus conventional fuels in this paper provides identification of requirements that need to be adapted to design a safe test cell. Design examples of actual test cells are provided to showcase the Read More
Experimental Study of Hydrogen Release Accidents in a Vehicle Garage
Sep 2009
Publication
Storing a hydrogen fuel-cell vehicle in a garage poses a potential safety hazard because of the accidents that could arise from a hydrogen leak. A series of tests examined the risk involved with hydrogen releases and deflagrations in a structure built to simulate a one-car garage. The experiments involved igniting hydrogen gas that was released inside the structure and studying the effects of the deflagrations. The “garage” measured 2.72 m high 3.64 m wid Read More
For a Successful Arrival of the Hydrogen Economy Improve Now the Confidence Level of Risk Assessments
Sep 2009
Publication
For large-scale distribution and use of energy carriers classified as hazardous material in many countries as a method to assist land use planning to grant licenses to design a safe installation and to operate it safely some form of risk analysis and assessment is applied. Despite many years of experience the methods have still their weaknesses even the most elaborated ones as e.g. shown by the large spread in results when different teams perform an Read More
The Hydrogen Safety Program of the US Department of Energy
Sep 2005
Publication
Demonstrated safety in the production distribution and use of hydrogen will be critical to successful implementation of a hydrogen infrastructure. Recognizing the importance of this issue the U.S. Department of Energy has established the Hydrogen Safety Program to ensure safe operations of its hydrogen research and development program as well as to identify and address needs for new knowledge and technologies in the future hydrogen economy. Activitie Read More
The Potential of Hydrogen Hydrate as a Future Hydrogen Storage Medium
Dec 2020
Publication
Hydrogen is recognized as the “future fuel” and the most promising alternative of fossil fuels due to its remarkable properties including exceptionally high energy content per unit mass (142 MJ/kg) low mass density and massive environmental and economical upsides. A wide spectrum of methods in H2 production especially carbon-free approaches H2purification and H2storage have been investigated to bring this energy source closer to the tech Read More
Research Requirements to Move the Bar Forward Using Aqueous Formate Salts as H2 Carriers for Energy Storage Applications
Nov 2020
Publication
In this perspective on hydrogen carriers we focus on the needs for the development of robust active catalysts for the release of H2 from aqueous formate solutions which are non-flammable non-toxic thermally stable and readily available at large scales at reasonable cost. Formate salts can be stockpiled in the solid state or dissolved in water for long term storage and transport using existing infrastructure. Furthermore formate salts are readily regenerat Read More
Current Status of Automotive Fuel Cells for Sustainable Transport
May 2019
Publication
Automotive proton-exchange membrane fuel cells (PEMFCs) have finally reached a state of technological readiness where several major automotive companies are commercially leasing and selling fuel cell electric vehicles including Toyota Honda and Hyundai. These now claim vehicle speed and acceleration refueling time driving range and durability that rival conventional internal combustion engines and in most cases outperform battery Read More
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